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HomeMy WebLinkAbout20140705.tiff STATE OF COLORADO John W.Hickenlooper,Governor Larry Wolk,MD,MSPH doe cozo.p Executive Director and Chief Medical Officer 0 Dedicated to protecting and improving the health and environment of the people of Colorado r i � r� r 4300 Cherry Creek Dr.S. Laboratory Services Division `1676 Denver,Colorado 80246-1530 8100 Lowry Blvd. Phone(303)692-2000 Denver,Colorado 80230-6928 Colorado Department Located in Glendale,Colorado (303)692-3090 of Public Health www.colorado.gov/cdphe and Environment Weld County -Clerk to the Board 1150 O Street PO Box 758 Greeley, CO 80632 March 5, 2014 Dear Sir or Madam: On March 8, 2014,the Air Pollution Control Division will publish a public notice for Whiting Oil and Gas Corporation—Razor 27-3414H, in the The Greeley Tribune. A copy of this public notice and the public comment packet are enclosed. Thank you for assisting the Division by posting a copy of this public comment packet in your office. Public copies of these documents are required by Colorado Air Quality Control Commission regulations. The packet must be available for public inspection for a period of thirty(30) days from the date the public notice is published. Please send any comment regarding this public notice to the address below. Colorado Dept. of Public Health & Environment APCD-SS-B 1 4300 Cherry Creek Drive South Denver, Colorado 80246-1530 Attention: Clara Gonzales Regards, LI Clara Gonzales Public Notice Coordinator RECEIVED Stationary Sources Program Air Pollution Control Division MAR 07204f Enclosure WELD COUNTY COMMISSIONERS ublic��t ex✓tc,Lo +(_C; VLtWL-,t 3• IR. 1.4 3•'1•Iy 2014-0705 STATE OF COLORADO John W.Hickenlooper,Governor -LarryWolk,MD,MSPH of coto 1� _ R� Executive Director and Chief Medical Officer tiQ:, - Dedicated to protecting and improving the health and environment of the people of Colorado t;" oo y, 4300 Cherry Creek Dr.S. Laboratory Services Division \a 1876 -- Denver,Colorado 80246-1530 8100 Lowry Blvd. — Phone(303)692-2000 Denver,Colorado 80230-6928 Colorado Department Located in Glendale,Colorado (303)692-3090 of Public Health www.colorado.gov/cdphe and Environment Website Title: Whiting Oil and Gas Corporation—Razor 27-3414H—Weld County Released To: The Greeley Tribune On: March 5, 2014 Published: March 8, 2014 PUBLIC NOTICE OF A PROPOSED PROJECT OR ACTIVITY WARRANTING PUBLIC COMMENT Notice is hereby given that an application for a proposed project or activity has been submitted to the Colorado Air Pollution Control Division for the following source of air pollution: Applicant: Whiting Oil and Gas Corporation Facility: Razor 27-3414H Crude Oil Exploration and Production Facility Section 27,TI0N, R58W Weld County The proposed project or activity is as follows: Gas Venting from a Separator that is controlled by a flare The Division has determined that this permitting action is subject to public comment per Colorado Regulation No. 3, Part B, Section III.C due to the following reason(s): • permitted emissions exceed public notice threshold values in Regulation No. 3, Part B, Section III.C.I.a (25 tpy in a non-attainment area and/or 50 tpy in an attainment area) • the source is requesting a federally enforceable limit on the potential to emit in order to avoid other requirements The Division has made a preliminary determination of approval of the application. A copy of the application, the Division's analysis,and a draft of Construction Permit 13 WE2179 have been filed with the Weld County Clerk's office. A copy of the draft permit and the Division's analysis are available on the Division's website at www.colorado.gov/cdphe/AirPublicNotices The Division hereby solicits submission of public comment from any interested person concerning the ability of the proposed project or activity to comply with the applicable standards and regulations of the Commission. The Division will receive and consider written public comments for thirty calendar days after the date of this Notice. Any such comment must be submitted in writing to the following addressee: David Thompson Colorado Department of Public Health and Environment 4300 Cherry Creek Drive South, APCD-SS-BI Denver, Colorado 80246-1530 cdphe.commentsapcd@state.co.us { i ID A STATE OF COLORADO R4,o? cot% COLORADO DEPARTMENT OF PUBLIC HEALTH AND ENVIRONMENT .f tyr%AIR POLLUTION CONTROL DIVISIONTELEPHONE: (303)692-3150 .' ,,,sr.. •1876• CONSTRUCTION PERMIT PERMIT NO: 1 3WE21 79 Issuance 1 DATE ISSUED: ISSUED TO: Whiting Oil and Gas Corporation. THE SOURCE TO WHICH THIS PERMIT APPLIES IS DESCRIBED AND LOCATED AS FOLLOWS: Oil and gas facility, known as the Razor 27-3414H Tank Battery, located in Section 27, Township 10N, Range 58W, in Weld County, Colorado. THE SPECIFIC EQUIPMENT OR ACTIVITY SUBJECT TO THIS PERMIT INCLUDES THE FOLLOWING: Facility AIRS Equipment Point Description ID SEP-1 004 Separator controlled by a 30' flare stack. Flare has a minimum combustion efficiency of 95%. The flare is not enclosed. THIS PERMIT IS GRANTED SUBJECT TO ALL RULES AND REGULATIONS OF THE COLORADO AIR QUALITY CONTROL COMMISSION AND THE COLORADO AIR POLLUTION PREVENTION AND CONTROL ACT C.R.S.(25-7-101 et seq),TO THOSE GENERAL TERMS AND CONDITIONS INCLUDED IN THIS DOCUMENT AND THE FOLLOWING SPECIFIC TERMS AND CONDITIONS: REQUIREMENTS TO SELF-CERTIFY FOR FINAL AUTHORIZATION 1. YOU MUST notify the Air Pollution Control Division (the Division)no later than fifteen days after issuance of this permit, by submitting a Notice of Startup form to the Division. The Notice of Startup form may be downloaded online at www.cdphe.state.co.us/ap/downloadforms.html. Failure to notify the Division of startup of the permitted source is a violation of Air Quality Control Commission(AQCC)Regulation No. 3, Part B, Section III.G.1 and can result in the revocation of the permit. 2. Within one hundred and eighty days(180)after issuance of this permit, compliance with the conditions contained in this permit shall be demonstrated to the Division. It is the owner or operator's responsibility to self-certify compliance with the conditions. Failure to demonstrate compliance within 180 days may result in revocation of the permit. (Reference: Regulation No. 3, Part B, III.G.2). 3. This permit shall expire if the owner or operator of the source for which this permit was issued: (i)does not commence construction/modification or operation of this source within 18 months after either, the date of issuance of this construction permit or the date on which such construction or activity was scheduled to commence as set forth in the permit application associated with this permit; (ii)discontinues construction fora period of eighteen months or more; (Hi) does not complete construction within a reasonable time of the AIRS ID: 123/9B6O/004 Page 1 of 8 Wellhead Version 2012-1 Dof De en f Public PollutionHealthand Control DivisionEnvironment estimated completion date. The Division may grant extensions of the deadline per Regulation No. 3, Part B, III.F.4.b. (Reference: Regulation No. 3, Part B, III.F.4.) 4. The operator shall complete all initial compliance testing and sampling as required in this permit and submit the results to the Division as part of the self-certification process. (Reference: Regulation No. 3, Part B, Section III.E.) 5. The following information for all permitted equipment except fugitive emissions from equipment leaks shall be provided to the Division within fifteen (15) days after issuance of permit. • manufacturer • model number • serial number This information shall be included with the Notice of Startup submitted for the equipment. (Reference: Regulation No. 3, Part B, III.E.) 6. The operator shall retain the permit final authorization letter issued by the Division, after completion of self-certification,with the most current construction permit. This construction permit alone does not provide final authority for the operation of this source. EMISSION LIMITATIONS AND RECORDS 7. Emissions of air pollutants shall not exceed the following limitations (as calculated in the Division's preliminary analysis). (Reference: Regulation No. 3, Part B, Section II.A.4) Annual Limits: Facility AIRS Tons per Year Equipment ID Point NO, VOC CO Emission Type Flare 004 5.2 43.8 10.3 Point See Notes to Permit Holder#4"for information on emission factors and methods used to calculate limits. Facility-wide emissions of each individual hazardous air pollutant shall be less than 8.0 tpy. Facility-wide emissions of total hazardous air pollutants shall be less than 20.0 tpy. Compliance with the annual limits shall be determined by recording the facility's annual criteria pollutant emissions, (including all HAPs above the de-minimis reporting level)from each emission unit, on a rolling twelve (12) month total. By the end of each month a new twelve-month total shall be calculated based on the previous twelve months' data. The permit holder shall calculate emissions each month and keep a compliance record on site or at a local field office with site responsibility, for Division review. This rolling twelve-month total shall apply to all permitted emission units, requiring an APEN, at this facility. 8. The emission points in the table below shall be operated and maintained with the control equipment as listed in order to reduce emissions to less than or equal to the limits established in this permit (Reference: Regulation No.3, Part B, Section III.E.) AIRS ID: 123/9B6C/004 Page 2 of 8 I ol. De en f Public Health and Environment Air Pollution Control Division Facility AIRS Pollutants Equipment Point Control Device Controlled ID SEP-1 004 Separator controlled by a 30' flare stack VOC & HAPs PROCESS LIMITATIONS AND RECORDS 9. This source shall be limited to the following maximum processing rates as listed below. Monthly records of the throughput shall be maintained by the applicant and made available to the Division for inspection upon request. (Reference: Regulation 3, Part B, II.A.4) Process/Consumption Limits Facility AIRS Process Parameter Annual Limit Equipment ID Point SEP-1 004 Natural gas flaring 47.45 MMSCF/yr The owner or operator shall calculate monthly process rates based on the calendar month. Compliance with the annual throughput limits shall be determined on a rolling twelve (12) month total. By the end of each month a new twelve-month total is calculated based on the previous twelve months'data. The permit holder shall calculate throughput each month and keep a compliance record on site or at a local field office with site responsibility,for Division review. STATE AND FEDERAL REGULATORY REQUIREMENTS 10. The permit number and AIRS ID number shall be marked on the subject equipment for ease of identification. (Reference: Regulation Number 3, Part B, III.E.) (State only enforceable) 11. Visible emissions shall not exceed twenty percent(20%)opacity during normal operation of the source. During periods of startup, process modification, or adjustment of control equipment visible emissions shall not exceed 30%opacity for more than six minutes in any sixty consecutive minutes. (Reference: Regulation No. 1, Section II.A.1. & 4.) 12. No owner or operator of a smokeless flare or other flare for the combustion of waste gases shall allow or cause emissions into the atmosphere of any air pollutant which is in excess of 30% opacity for a period or periods aggregating more than six minutes in any sixty consecutive minutes. (Reference: Regulation No. 1, Section II.A.5.) 13. These sources are subject to the odor requirements of Regulation No. 2. (State only enforceable) OPERATING & MAINTENANCE REQUIREMENTS 14. Upon startup of these points, the applicant shall follow the operating and maintenance (O&M) plan and record keeping format approved by the Division, in order to demonstrate compliance on an ongoing basis with the requirements of this permit. Revisions to your O&M plan are subject to Division approval prior to implementation. (Reference: Regulation No. 3, Part B, Section III.G.7.) COMPLIANCE TESTING AND SAMPLING Initial Testing Requirements AIRS ID: 123/9B6C/004 Page 3 of 8 D RA)F f Public Health and Environment Air Pollution Control Division 15. The operator shall complete an initial site specific extended gas analysis of the natural gas produced at this site in order to verify the VOC, benzene,toluene,ethylbenzene,xylenes, n- hexane,and 2,2,4-trimethylpentane content(weight fraction)of this emission stream used in the permit application. Results of testing shall be used to determine site-specific emission factors using Division approved methods. Results of site-specific sampling and analysis shall be submitted to the Division as part of the self-certification and used to demonstrate compliance with the emissions factors chosen for this emissions point. 16. The owner or operator shall demonstrate compliance with Condition 12 using EPA Method 9 to measure opacity from the flare. (Reference: Regulation No. 1, Section II.A.5). Periodic Testing Requirements 17. On an annual basis,the operator shall complete a site specific extended gas analysis of the natural gas produced at this site that is routed to the flare in order to verify the VOC content (weight fraction) of this emission stream used in the permit application. Results of testing shall be used to determine site-specific emission factors using Division approved methods. ADDITIONAL REQUIREMENTS 18. A revised Air Pollutant Emission Notice(APEN)shall be filed:(Reference: Regulation No. 3, Part A, II.C) a. Annually whenever a significant increase in emissions occurs as follows: For any criteria pollutant: For sources emitting less than 100 tons per year, a change in actual emissions of five (5)tons per year or more, above the level reported on the last APEN; or For any non-criteria reportable pollutant: If the emissions increase by 50%or five (5)tons per year,whichever is less, above the level reported on the last APEN submitted to the Division. b. Whenever there is a change in the owner or operator of any facility, process, or activity; or c. Whenever new control equipment is installed,or whenever a different type of control equipment replaces an existing type of control equipment; or d. Whenever a permit limitation must be modified; or e. No later than 30 days before the existing APEN expires. 19. Federal regulatory program requirements (i.e. PSD, NANSR or Title V Operating Permit) shall apply to this source at any such time that this source becomes major solely by virtue of a relaxation in any permit condition. Any relaxation that increases the potential to emit above the applicable Federal program threshold will require a full review of the source as though construction had not yet commenced on the source. The source shall not exceed the Federal program threshold until a permit is granted. (Regulation No. 3 Part D). GENERAL TERMS AND CONDITIONS 20. This permit and any attachments must be retained and made available for inspection upon request. The permit may be reissued to a new owner by the APCD as provided in AQCC Regulation No. 3, Part B, Section II.B upon a request for transfer of ownership and the submittal of a revised APEN and the required fee. AIRS ID: 123/9B6C/004 Page 4 of 8 of De ent f Public Health and Environment Air Pollution Control Division 21. If this permit specifically states that final authorization has been granted,then the remainder of this condition is not applicable. Otherwise, the issuance of this construction permit does not provide"final"authority for this activity or operation of this source. Final authorization of the permit must be secured from the APCD in writing in accordance with the provisions of 25-7-114.5(12)(a) C.R.S. and AQCC Regulation No. 3, Part B, Section III.G. Final authorization cannot be granted until the operation or activity commences and has been verified by the APCD as conforming in all respects with the conditions of the permit. Once self-certification of all points has been reviewed and approved by the Division, it will provide written documentation of such final authorization. Details for obtaining final authorization to operate are located in the Requirements to Self-Certify for Final Authorization section of this permit. 22. This permit is issued in reliance upon the accuracy and completeness of information supplied by the applicant and is conditioned upon conduct of the activity, or construction, installation and operation of the source, in accordance with this information and with representations made by the applicant or applicant's agents. It is valid only for the equipment and operations or activity specifically identified on the permit. 23. Unless specifically stated otherwise, the general and specific conditions contained in this permit have been determined by the APCD to be necessary to assure compliance with the provisions of Section 25-7-114.5(7)(a), C.R.S. 24. Each and every condition of this permit is a material part hereof and is not severable. Any challenge to or appeal of a condition hereof shall constitute a rejection of the entire permit and upon such occurrence,this permit shall be deemed denied ab initio. This permit may be revoked at any time prior to self-certification and final authorization by the Air Pollution Control Division (APCD) on grounds set forth in the Colorado Air Quality Control Act and regulations of the Air Quality Control Commission (AQCC), including failure to meet any express term or condition of the permit. If the Division denies a permit, conditions imposed upon a permit are contested by the applicant, or the Division revokes a permit,the applicant or owner or operator of a source may request a hearing before the AQCC for review of the Division's action. 25. Section 25-7-114.7(2)(a), C.R.S. requires that all sources required to file an Air Pollution Emission Notice (APEN) must pay an annual fee to cover the costs of inspections and administration. If a source or activity is to be discontinued, the owner must notify the Division in writing requesting a cancellation of the permit. Upon notification, annual fee billing will terminate. 26. Violation of the terms of a permit or of the provisions of the Colorado Air Pollution Prevention and Control Act or the regulations of the AQCC may result in administrative, civil or criminal enforcement actions under Sections 25-7-115 (enforcement), -121 (injunctions), -122 (civil penalties), -122.1 (criminal penalties), C.R.S. By: David Thompson Permit Engineer Permit History Issuance Date Description Issuance 1 This Issuance Issued to Whiting Oil and Gas Corporation, Inc. . AIRS ID: 123/9B6C/004 Page 5 of 8 D of De en f Public Health and Environment Air Pollution Control Division Notes to Permit Holder: 1) The permit holder is required to pay fees for the processing time for this permit.An invoice for these fees will be issued after the permit is issued.The permit holder shall pay the invoice within 30 days of receipt of the invoice. Failure to pay the invoice will result in revocation of this permit(Reference: Regulation No.3, Part A, Section VI.B.) 2) The production or raw material processing limits and emission limits contained in this permit are based on the consumption rates requested in the permit application. These limits may be revised upon request of the permittee providing there is no exceedance of any specific emission control regulation or any ambient air quality standard. A revised air pollution emission notice (APEN) and application form must be submitted with a request for a permit revision. 3) This source is subject to the Common Provisions Regulation Part II, Subpart E, Affirmative Defense Provision for Excess Emissions During Malfunctions. The permittee shall notify the Division of any malfunction condition which causes a violation of any emission limit or limits stated in this permit as soon as possible, but no later than noon of the next working day, followed by written notice to the Division addressing all of the criteria set forth in Part II.E.1 of the Common Provisions Regulation. See: http://www.cd phe.state.co.us/req u lations/airrecs/100102aacccom mon provisionsrea.odf. 4) The following emissions of non-criteria reportable air pollutants are estimated based upon the process limits as indicated in this permit. This information is listed to inform the operator of the Division's analysis of the specific compounds emitted if the source(s) operate at the permitted limitations. Uncontrolled Emission Are the Controlled AIRS Rate emissions Emission Point Pollutant CAS# BIN (lb/yr) reportable? Rate(Ib/yr) Benzene 71432 A 3,908 Yes 195 Toluene 108883 C 4,149 Yes 207 004 Ethylbenzene 100414 C 664 No 33 Xylenes 1130207 C 1,062 Yes 53 n-Hexane 110543 C 33,951 Yes 1,698 5) The emission levels contained in this permit are based on the following emission factors: Point 004: Weight Emission Emission CAS# Pollutant Fraction of Factors Factors Source Gas(%) Uncontrolled Controlled NOx 0.1380 0.1380 TCEQ Factor Ib/MMBtu Ib/MMBtu CO 0.2755 0.2755 TCEQ Factor Ib/MMBtu Ib/MMBtu VOC 36,927 1846.35 Engineering lb/mmscf lb/mmscf Calculation 71432 Benzene 0.239 82 4.1 Engineering lb/mmscf lb/mmscf Calculation 108883 Toluene 0.598 87 4.4 Engineering lb/mmscf lb/mmscf Calculation 100414 Ethylbenzene 0.080 14 0.7 Engineering lb/mmscf lb/mmscf Calculation AIRS ID: 123/9B6C/004 Page 6 of 8 ID Ill ol•4t , De ent f Public Health and Environment Air Pollution Control Division Weight Emission Emission CAS# Pollutant Fraction of Factors Factors Source Gas(%) Uncontrolled Controlled 1330207 Xylenes 0.062 22 1.1 Engineering lb/mmscf lb/mmscf Calculation 110543 n-hexane 1.223 716 35.6 Engineering lb/mmscf lb/mmscf Calculation Note: The uncontrolled VOC and HAP emissions for this point were calculated using the February 7, 2013 analysis of a gas sample collected from the Razor 14-1143H well.The controlled VOC and HAP emissions factors for point 004 are based on the flare control efficiency of 95%. Compliance with emissions limits in this permit will be demonstrated by using the TOC emission factors listed in the table above with representative component counts, multiplied by the VOC content from the most recent gas analysis. 6) In accordance with C.R.S. 25-7-114.1, each Air Pollutant Emission Notice (APEN) associated with this permit is valid for a term of five years from the date it was received by the Division. A revised APEN shall be submitted no later than 30 days before the five-year term expires. Please refer to the most recent annual fee invoice to determine the APEN expiration date for each emissions point associated with this permit. For any questions regarding a specific expiration date call the Division at(303)-692- 3150. 7) This facility is classified as follows: Applicable Status Requirement Operating Permit Synthetic Minor of: VOCs, HAPs, n-Hexane PSD Synthetic Minor of: VOCs, HAPs, n-Hexane MACT HH Major Source Requirements: Not Applicable Area Source Requirements: Not Applicable 8) Full text of the Title 40, Protection of Environment Electronic Code of Federal Regulations can be found at the website listed below: http://ecfr.gpoaccess.gov/ Part 60: Standards of Performance for New Stationary Sources NSPS 60.1-End SubpartA—Subpart KKKK NSPS Part 60, Appendixes Appendix A—Appendix I Part 63: National Emission Standards for Hazardous Air Pollutants for Source Categories MACT 63.1-63.599 SubpartA—SubpartZ MACT 63.600-63.1199 Subpart AA—Subpart DDD MACT 63.1200-63.1439 Subpart EEE—Subpart PPP MACT 63.1440-63.6175 Subpart QQQ—Subpart YYYY MACT 63.6580-63.8830 Subpart ZZZZ—Subpart MMMMM MACT 63.8980-End Subpart NNNNN—Subpart XXXXXX AIRS ID: 123/9B6C/004 Page 7 of 8 D RA Fen f Public Health and Environment Air Pollution Control Division 9) An Oil and Gas Industry Construction Permit Self-Certification Form is included with this permit packet. Please use this form to complete the self-certification requirements as specified in the permit conditions. Further guidance on self-certification can be found on our website at:. www.colorado.gov/cdphe/oilgasperm its AIRS ID: 123/9B6C1004 Page 8 of 8 Construction Permit Application Preliminary Analysis Summary Section 1 —Applicant Information Company Name: Whiting Oil and Gas Corporation Permit Number: 13WE2179 Source Location: Section 27 T10N R58W Equipment Description: Point 004: Plant flare with a minimum combustion efficiency of 95%. AIRS ID: 123/9B6C/004 Date: 8/22/13 Review Engineer: David Thompson Control Engineer: Chris Laplante Section 2—Action Completed Grandfathered Modification APEN Required/Permit Exempt x CP1 Transfer of Ownership APEN Exempt/Permit Exempt *If tank is a true minor source at a true minor facility, it shall be granted "Final Approval" Section 3—Applicant Completeness Review Was the correct APEN submitted for this source type? X Yes No Is the APEN signed with an original signature? X Yes No Was the APEN filled out completely? X Yes No Did the applicant submit all required paperwork? X Yes No Did the applicant provide ample information to determine emission rates? X Yes No If you answered "no"to any of the above, when did you mail an Information Request letter to the source? On what date was this application complete? April 30, 2009 Section 4—Source Description AIRS Point Equipment Description 004 Separator controlled by a 40'flare stack. Flare has a minimum combustion efficiency of 95%. The flare is not enclosed. Is this a portable source? Yes X No Is this location in a non-attainment area for any criteria Yes x No pollutant? If"yes", for what pollutant? PKo CO Ozone Is this location in an attainment maintenance area for Yes x No any criteria pollutant? If"yes", for what pollutant? (Note: These pollutants are subject to minor source PM,() CO Ozone RACT per Regulation 3, Part B, Section III.D.2) Is this source located in the 8-hour ozone non- attainment region? (Note: If"yes" the provisions of Yes X No Regulation 7, Sections XII and XVII.C may apply) Page 1 Section 5—Emission Estimate Information AIRS Point Emission Factor Source 004 Site-specific using VOC weight fraction (Refer to Section 14 for calculations) Did the applicant provide actual process data for the emission inventory? X Yes No Basis for Potential to Emit(PTE' AIRS Point Process Consumption/Throughput/Production 004 130,000 scf/day=>47,452,920 scf/yr=47.45 mmscf/yr Basis for Actual Emissions Reported During this APEN Filing (Reported to Inventors/) AIRS Point Process Consumption/Throughput/Production Data Year 004 130,000 scf/day =>47,452,920 scf/yr=47.45 mmscf/yr Basis for Permitted Emissions (Permit Limits' AIRS Point Process Consumption/Throughput/Production 004 130,000 scf/day =>47,452,920 scf/yr=47.45 mmscf/yr Does this facility use control devices? X Yes No AIRS Point Process Control Device Description % Reduction Granted 004 01 30'flare stack 95 Section 6—Emission Summary (tons per year) Point NO„ VOC CO SOx PM10 Single Total HAP HAP PTE: 004 5.2 876.1 10.3 --- ___ 16.98 21.9 (n-hexane) Uncontrolled point 004 5.2 876.1 10.3 --- --- 16.98 21.9 source emission rate: (n-hexane) TOTAL(TPY) 5.2 876.1 10.3 --- ___ 16.98 21.9 (n-hexane) Controlled point 004 5.2 43.8 10.3 --- --- 0.85 1.1 source emission rate: (n-hexane) TOTAL PERMITTED 5.2 43.8 10.3 0.85 1.1 (TPY) (n-hexane) Section 7—Non-Criteria/Hazardous Air Pollutants Uncontrolled Are the Controlled Emission Pollutant CAS# BIN Emission Rate emissions (Iblyr) reportable? Rate(Ibtyr) Flare/separator-Point 004 Benzene 71432 A 3,908 Yes 195 Toluene 108883 C 4,149 Yes 207 Ethylbenzene 100414 C 664 No 33 Xylenes 1130207 C 1,062 Yes 53 n-Hexane 110543 C 33,951 Yes 1,698 Note: Regulation 3, Part A, Section II.B.3.b APEN emission reporting requirements for non-criteria air pollutants are based on potential emissions without credit for reductions achieved by control devices used by the operator. Page 2 Section 8—Testing Requirements Will testing be required to show compliance with any emission rate or regulatory Yes x No standard? If"yes", complete the information listed below AIRS Point Process Pollutant Regulatory Basis Test Method Flare/ 01 VOC, State only requirement Site-specific gas Separator HAPS analysis Section 9—Source Classification What is this facility classification? True X Synthetic Major Minor Minor Classification relates to what programs? X Title V X PSD NA NSR X MACT Is this a modification to an existing permit? Yes X No If"yes"what kind of modification? Minor Synthetic Major Minor Section 10—Public Comment Does this permit require public comment per CAQCC Regulation 3? X Yes No If"yes",for which pollutants?Why? VOC For Reg. 3, Part B, III.C.1.a (emissions increase > 25/50 tpy)? Yes x No For Reg. 3, Part B, III.C.1.c.iii (subject to MACT)? Yes x No For Reg. 3, Part B, III.C.1.d (synthetic minor emission limits)? X Yes No Section 11 —Modeling Is modeling required to demonstrate compliance with National Ambient Yes X No Air Quality Standards (NAAQS)? If"yes", for which pollutants?Why? NOx emissions are less than 40 TPY. AIRS Point Section 12—Regulatory Review Regulation 1 - Particulate, Smoke, Carbon Monoxide and Sulfur Dioxide Section II.A.1 - Except as provided in paragraphs 2 through 6 below, no owner or operator of a source shall allow or cause the emission into the atmosphere of any air pollutant which is in excess of 20% opacity. This standard is based on 24 consecutive opacity readings taken at 15-second intervals for six minutes. The approved reference test method for visible emissions measurement is EPA Method 9 (40 CFR, Part 60, Appendix 004 A (July, 1992)) in all subsections of Section II. A and B of this regulation. Section II.A.5-Smokeless Flare or Flares for the Combustion of Waste Gases No owner or operator of a smokeless flare or other flare for the combustion of waste gases shall allow or cause emissions into the atmosphere of any air pollutant which is in excess of 30% opacity for a period or periods aggregating more than six minutes in any sixty consecutive minutes. Regulation 2—Odor Section I.A - No person, wherever located, shall cause or allow the emission of odorous at contaminants from any single source such as to result in detectable odors which are 004 measured in excess of the following limits: For areas used predominantly for residential or commercial purposes it is a violation if odors are detected after the odorous air has been diluted with seven (7) or more volumes of odor free air. Page 3 i2ggi#Jatiori 3-APENs. Conativction Permits. Oparatting,Permits. PSD Part A-APEN Requirements Criteria Pollutants: For criteria pollutants, Air Pollutant Emission Notices are required for: 004 each individual emission point in an attainment area with uncontrolled actual emissions of two tons per year or more of any individual criteria pollutant (pollutants are not summed) for which the area is attainment. (Applicant is required to file an APEN since emissions exceed 2 tons per year VOC) Part B—Construction Permit Exemptions 004 Applicant is required to obtain a permit since uncontrolled VOC emissions from this facility are greater than the 5.0 TPY threshold(Reg. 3, Part B, Section ILD.3.a) 81111. ion 6 New Source-Performance Standards. 004 None ulation 7—Volat le Oceanic Compounds Reattiat on 6—Hazardous A oU�tant$ 004 None Section 13—Aerometric Information Retrieval System Coding Information Pollutant/ Fugitive Emission Factor Control Point Process Process Description Emission Factor CAS# (Y/N) Source (%) 35,400.5 Engineering Ib/MMscf VOC No Calculation 95 0.138 NOx No TCEQ NA ib/MMBtu 0.2755 CO No TCEQ NA Ib/MMBtu 82.4485 Benzene No Engineering 95 01 Flare Ib/MMscf Calculation 004 87.5303 Toluene No Engineering 95 Ib/MMscf Calculation 14.0066 Ethlybenzene No Engineering 95 Ib/MMscf Calculation 22.4106 Engineering Ib/MMscf Xylenes No Calculation 95 716.2718 n-hexane No Engineering 95 lb/MMscf Calculation SCC 31000205-Flares Page 4 Section 14—Miscellaneous Application Notes AIRS Point 004 Flare Operator provided an extended gas analysis and emissions were calculated using EPA Emission Inventory Improvement Program Publication, Volume II, Chapter 10-Displacement equation (10.4-3) where: Ex=Q " MW "Xx/C Ex=emissions of pollutant x Q =Volumetric flow rate/volume of gas processed MW= Molecular weight of gas = SG of gas " MW of air Xx = mass fraction of x in gas C = molar volume of ideal gas (379 scf/lb-mol) at 60F and 1 atm Emissions generated from the flare are: Uncontrolled Total (Ib/yr) Controlled Total (Ib/yr) NOx 10400 10400 VOC 1752200 87600 CO 20600 20600 Benzene 3912 196 Toluene 4153 208 Ethylbenzene 665 33 Xylenes 1063 53 n-hexane 33987 1699 224-TMP 0 0 An gas analysis was provided in the application dated 02/07/13. 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