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HomeMy WebLinkAbout20140976.tiff SITE SPECIFIC DEVELOPMENT PLAN AND USE BY SPECIAL REVIEW (USR) APPLICATION FOR PLANNING DEPARTMENT USE DATE RECEIVED: RECEIPT#/AMOUNT# 1$ CASE#ASSIGNED: APPLICATION RECEIVED BY PLANNER ASSIGNED: Parcel Number 0 7 9 7 . 2 3 . 2 _ 0 0 . 0 1 9 (12 digit number-found on Tax I.D.information,obtainable at the Weld County Assessor's Office,or www co weld co.us) Legal Description SUBX13-0026 , Section 23 , Township 6 North, Range 62 West Zone District:AG , Total Acreage:3.1 , Flood Plain: N/A , Geological Hazard: N/A Airport Overlay District: N/A FEE OWNER(S) OF THE PROPERTY: Name:(Owner) Betty J and Ronald L Pappenheim Work Phone# Home Phone# Email Address:20112 County Rd 76 Address: City/State/Zip Code Eaton, CO 80615 Name:(Leasee) Bill Barrett Corporation -Attn: Tracey Fallang Work Phone# Home Phone# Email Address: 1099 18th St, Suite 2300 Address: City/State/Zip Code Denver, CO 80202 Name: Work Phone# Home Phone# Email Address: Address: City/State/Zip Code APPLICANT OR AUTHORIZED AGENT (See Below:Authorization must accompany applications signed by Authorized Agent) Name:Vincent Harris Work Phone# 303-202-5010 Home Phone# Email vince@baselinecorp.com Address:700 12th Street Address: Suite 220 City/State/Zip Code Golden, CO 80401 PROPOSED USE: Natural gas compressor station with related equipment including but not limited to compressors, tanks, meters, mufflers, communications tower, etc. I (We) hereby depose and state under penalties of perjury that all statements, proposals, and/or plans submitted with or contained within the application are true and correct to the best of my (our)knowledge. Signatures of all fee owners of property must sign this application. If an Authorized Agent signs, a letter of authorization from all fee owners must be included with the application. If a corporation is the fee owner, notarized evidence must be included indicating the signatory has to legal authority to sign for the corporation. /J—( 12/10/2013 Signature: Owner or Authorized Agent Date Signature: Owner or Authorized Agent Date WELD COUNTY RIGHT-OF-WAY USE PERMIT Weld County Public Works Dept. Phone: (970)304-6496 1111 H Street After Hours: (970)356-4000 P.O. Box 758 Emergency Services: (970)304-6500 x 2700 Greeley,CO 80632 GAY -qv0. Inspection: (970) 304-6480 Permit Number: RW13-00362 Issuance of this permit binds applicant and its contractors to all requirements,provisions,and ordinances of Weld County,Colorado. A copy of this permit must be on site at all times during construction hours. Approved MUTCD traffic control/warning devices are required at all times. Permit Type: Standard Permit fee: $200.00 Project Name: Bronco Compressor Station USR#: n/a Application Date: 08/21/2013 Start date: 09/05/2013 Expiration date: 12/04/2013 Applicant Information: Contractor Information: Name: John Ed Singleton Name: Bill Mundt Company: Bill Barrett Corporartion Company: Mundt Energy Services Phone: 970-353-0407 Phone: 970-313-7744 Email: jsingleton@billbarrettcorp.com Email: Location: WCR: 68 Between: 79.75 And: 83 Address: Subivision: Legal: 23* / 6N / 62W Impacted Surface(s): ❑ Asphalt/Chip seal/RAP RIGravel 0 Treated Gravel IO Outside Roadway 0 Other Use Type: ['Communication 0 Electrical I lGas/Oil 0 Water Service 0 Sanitary Sewer ❑ Irrigation ❑Storm Water Misc NATURAL GAS pipelines Classification of Work: 0 Abandonment 0 Misc.Occupation O Relocation O Potholing pOther Bore CR 68 x 3 ❑Maintenance 0 Culvert Installation O Road Improvements 0 Tree Trimming RI New Service O Overhead Installation El Underground Installation O Surveying Description of ROW use: Installation of(1)-4",(1)-6",and (1)-10" NATURAL GAS pipelines under CR 68 approx 2950 ft east of CR 79.75. Restoration: 0 Asphalt(HMA) p Class 6 Road Base O Fugitive Dust Chemical O Compaction Testing 0 Mulching 0 Structural Fill O Flow Fill P Native Material 0 Reseeding O Erosion Control El Other remove locates Weekend Hours No Daily work hours are from DAYLIGHT to 1/2 HOUR BEFORE DARK Special Requirements Contractor to notify inspection 24 hrs prior to starting work in ROW. Approved by: Digitally signed by Amy Joseph Weld County Public Works Date: _/^ DN:cn=Amy seph,o=Weld County oQl�(11�J PublicWorksb ou, 9/4/2013 email=ajoseph@o.weld.co.us,c=US Date:2013.09.0410:42:49-06'00' Rev.July 2010 Print Date-Time: 9/4/2013 10:40:20AM Report ID: PW00001v003 Page 1 of 7 RIGHT-OF-WAY USE PERMIT REQUIREMENTS The Right-of-Way Use Permit is a tool to help regulate unauthorized obstructions of excavations in and use of the County's rights-of-way and easements including, but not limited to, all construction activities within the Weld County right-of-way, whether gravel or paved, and including all public drainage easements. A Right-of-Way Use Permit grants a permit holder permission to occupy,excavate,survey,or construct facilities within the County rights- of-way or easement, and provide for the subsequent restoration upon completion. (Weld County Code-Chapter 12, Sec. 12-4-10) The Permit granted herein is issued solely for the Permittee's installation of the Project which is to be used for the purpose described on page 1 of the Right-of-Way Use Permit. Permittee is prohibited from changing the use of the Project in any way without a new permit. If Permittee intends to change the use of the Project herein permitted, Permittee must re-apply to Weld County for a new permit. For example if this Permit is issued for a pipeline used to transfer non-waste water, the pipeline cannot later be utilized to transfer natural gas, petroleum, or waste water before obtaining a new permit. PERMITTEE'S RESPONSIBILITIES: The grant of this Permit herein is specifically conditioned upon Permittee's and its Contractor's compliance with the following requirements: GENERAL PROVISIONS 1. Permit Issuance. Permittee must submit a complete Right-of-Way Use Application and include required submittals for review and consideration of its Project. If Project is approved a Right-of-Way Use Permit will be issued to the Permittee. It is the responsibility of the Permittee to inform its Contractor of all Permit requirements, Provisions,and Special Provisions. (a) Commencement of construction prior to receiving an approved Permit will result in applicable penalties (see emergency repair section for exclusions). (b) Contractor must have a copy of the Permit, Provisions, and any Special Provisions on site during construction of the Project. (c) Issued Permit expires three(3) months from date issued unless otherwise stated. The Permittee may apply for an extension if work is not completed before the permit expires. All applicable fees must be paid before extension will be issued. (d) Project specific Special Provisions may be included within or attached to the Permit as additional requirements. 2. Traffic Control Plan. A Traffic Control Plan (TCP) must be submitted and approved prior to Permittee's commencement of work. Permittee shall provide all necessary traffic control in accordance with the Manual on Uniform Traffic Control Devices(MUTCD). (a) Flaggers shall be provided at any locations where there is encroachment into a travelling lane. (b) Full road closures exceeding three(3)days shall require approval of the Board of County Commissioners. 3. Inspection. Inspection of the work performed in the Weld County right-of-way is required. Weld County Public Works will be notified 24 hours prior to commencing any and all work. Final inspections are required. Weld County shall have the right to order Permittee or its Contractor to stop work anytime Weld County believes that a violation of this Permit has occurred or if there is a danger to the safety of the public if the work continues. 4. Insurances. Permittee and its Contractor shall secure and maintain insurance policies and/or provide proof of adequate self-insurance that will protect itself, its subcontractors, members of the public who use the right-of-way associated with this road, and Weld County, its officers, employees, agents and the Board of County Commissioners of Weld County, Colorado from claims for bodily injury, death, or property damage, which may arise from the installation and/or construction of the Project contemplated herein, or caused by the facilities which are installed and/or constructed as permitted herein. Weld County, Colorado, must be named as an "Additional Named Insured" in all liability insurance policies (Weld County Code-Chapter 12, Sec. 12-4-80). The following insurance policies are required and shall be delivered to the Weld County Public Works Department: (a) Statutory Worker's Compensation. (Revised 7/2013) Page 2 of 7 (b) Contractor's public liability and property damage in the following sums: Bodily Injury: Property Damage: Each person $1,000,000 Each accident $1,000,000 Each accident $1,000,000 Aggregate $2,000,000 (c) Automobile public liability and property damage in the following sums: Bodily Injury: Property Damage: Each person $1,000,000 Each accident $1,000,000 Each accident $1,000,000 5. Surety Bonds. If determined necessary by Weld County's Department of Public Works, Permittee shall provide a surety bond or other security for the total amount required to restore the right-of-way under which the Project is to be installed or constructed, based upon current Weld County Public Works Department contract prices for the performance of such work. Said security shall remain in effect for a period of two (2) years after inspection of completed construction by Weld County Public Works Department. Whether or not covered by a bond, Permittee shall reimburse Weld County for any and all expenses incurred by it as a result of, or related to, the failure by Permittee or its Contractor to perform all installation, construction, maintenance or other work pursuant to this Permit, in a workmanlike manner. 6. Additional Permits. Permittee shall be responsible for obtaining all other State, Federal, or Local permits which may be required of Permittee and/or its Contractor to install and/or maintain its Project. Permittee shall provide evidence of such other permits upon request by the Weld County Public Works Department. 7. Determination of Placement. Weld County reserves the right to determine the specific placement of the Project within its right-of-way. 8. Suspension of Work. Weld County's Department of Public Works shall have the authority to suspend work, wholly or in part, because of the failure of Permittee to properly execute the work in accordance with this Permit. Notwithstanding the issuance of this Permit, Weld County reserves the right to make or to require Permittee to make any changes,additions, repairs or required relocation of any facilities within the dedicated rights-of-way at any time. 9. Setback Requirements. By accepting this Permit, Permittee hereby waives its right to require industry setback requirements which it might otherwise require from other utilities which may be placed in Weld County's rights-of- way, and relinquishes its authority over the placement of all other electric, power, gas, communications or other conduits, pipelines, appurtenances, or irrigation structures which Weld County may allow to be placed in its Right-of- Way. Weld County must approve location prior to construction. 10. Existing Utilities. Permittee or its contractor shall be responsible for locating all existing utilities. (Contact the Utility Notification Center of Colorado at 811 or 1-800-922-1987 at least two days in advance of digging.) Permittee must remove all utility locates such as flags and marker pins from the Right-of-Way once the construction is complete. 11. No Damage to Other Proiects. No culverts, irrigation structures, drain lines, utility lines, or any other Projects or facilities within the right-of-way are to be cut or damaged. In the event Permittee or its Contractor damages an existing facility, Permittee shall first notify the owner and either immediately repair and replace the damaged facility or pay the owner to repair and replace the same in accordance with the desires of the owner. 12. Emergencies. Permittee shall report all emergency repairs to Weld County Public Works immediately upon being advised that an emergency exists. During such repairs, Permittee shall utilize proper traffic control measures. Permittee shall apply for a Right-of-Way Use Permit and make the required repairs as soon as practicable after the Weld County Public Works Department is notified of the emergency situation and the need for such repairs. In no event shall such repairs be completed later than 24 hours after receiving such notification, unless adverse weather conditions prohibit the repair process. 13. Changes-Permittee's Financial Responsibility. In the event changes are made to the roadway or its appurtenances within the right-of-way that would necessitate removal or relocation of Permittee's Project, Permittee shall do so promptly at its own expense upon the request of the County. (Revised 7/2013) Page 3 of 7 14. Permittee Responsible for All Project Related Expenses. The construction, operation, maintenance and repair of the Project installed by Permittee, and all other improvements described in this Permit, shall be at its own expense and without the aid or use of Weld County's funds. 15. Permittee Solely Responsible. Permittee (or its successors and assigns, if accepted by Weld County), remains solely responsible for all matters pertaining to the Project.These responsibilities include, but are not limited to the following: repair and maintenance of the physical components of the Project; removal of the physical components of the Project upon abandonment of the use or following the request of Weld County to remove the Project; cooperation with Weld County and other Permittees whose projects are placed in Weld County's Right-of-Way. 16. Successors and Assigns of Permittee. It is mutually understood and agreed that this Permit and all the terms and conditions hereof shall extend to and be binding upon the Permittee and its successors,and assigns. CONSTRUCTION PROVISIONS 1. Daily Construction Requirements. At the end of each day during the installation and construction of the Project, Permittee shall observe the following requirements: (a) All materials shall be removed a minimum of ten feet(10')from outside edge of the road shoulder; (b) All excavations upon the traveled portions of the right-of-way shall be back-filled in accordance with the Compaction requirements set forth below unless otherwise approved by Weld County; (c) All traffic signs must be in place per the approved Traffic Control Plan or removed or covered if not applicable to nightly activities. 2. Equipment-Equipment Crossings. (a) Movement of cleated or track equipment is restricted to the immediate work area. Equipment shall be transported to a proper unloading area. No cleated or track equipment may work on or move over asphalt surfaces without mats. (b) Equipment crossings, in line with the Project, shall be built up level with the road surface with a practicable anti-tracking material to prevent damage to the road surfaces and shoulder areas. A minimum of a fifteen inch (15")culvert shall be placed in ditch areas under tracking pad to maintain proper drainage. 3. Site Markers. Permittee shall mark the site of the installation of the Project, whether permanent or temporary, with markers acceptable to Weld County Public Works Department. Markers shall be placed as far from edge of road as to not interfere with normal road maintenance. 4. Future Line Location. The installation of non-ferrous lines in the Right-of-Way shall require a suitable means to facilitate future line location such as, but not limited to, metallic warning tape installed above the line. 5. Abandonment. The abandonment of an existing Project in the Right-of-Way shall be subject to conditions as determined by the Weld County Public Works Department based on the age, condition, material type, and size. Permittee shall cut,cap, and fill Project(s)that are not required to be removed. 6. Minimum Cover. All depth requirements are minimums and are subject to Special Provisions requirements. (a) All road bores shall be a minimum depth of four feet (4') plus the diameter of the line below the lowest point of the Right-of-Way. Private use Projects shall increase this depth to a minimum of six feet (6') plus the diameter of the line. (b) All underground Projects running parallel within the roadway or Right-of-Way shall have a minimum of four feet(4')of cover. (c)Culverts must have a minimum of twelve inches(12")of cover. 7. Asphalt-Concrete Surfaces. Asphalt or Concrete surfaces are not to be cut unless approved by the Weld County Public Works Department. If an asphalt or concrete surface cut is granted, the cut shall be repaired with a flowable fill cement (refer to Compaction Requirements) and hot bituminous pavement and/or concrete placed at a thickness of existing plus one(+1). (Revised 7/2013) Page 4 of 7 8. Compaction Requirements. (a) All compaction of backfills and road surfaces shall be compacted in accordance with the Weld County Engineering and Construction Criteria guidelines. (b) All backfills located within an existing asphalt or concrete surface or under the asphalt or concrete not currently in place but will be as part of a new road construction, must be compacted using flow-fill cement in the upper three feet(3')of backfill. (c) If any wet or non-compactable materials are produced from excavations, they shall be completely removed from the Right-of-Way and replaced with compactable materials. The Right-of-Way shall then be returned to the original grades and cross sections. Weld County Public Works Department shall have the authority to determine what materials shall be discarded and what materials shall be acceptable as replacement. (d) On gravel roads where excavation materials are stacked on the road surfaces, road base of 3/4 inch Surface Gravel as specified in Chapter 7 of the Weld County Engineering and Construction Criteria specifications for Surface Gravel shall be spread over the road surfaces at a rate of 900 tons per mile upon completion of the work. Shoulders on paved roads or barrow ditches where excavation is done shall require 300 tons per mile upon completion. These amounts are minimums to coat the road surfaces and do not supersede any requirements within the Permit. (e) On gravel roads where excavation is done within the roadway, backfilling lifts greater than eight inches (8"), but not exceeding twelve inches (12"), shall be permitted providing that Permittee has suitable equipment to properly compact the depth of lift placed. Weld County Public Works shall determine if Permittee's equipment and the depth of backfill lift is appropriate. Ninety-five percent (95%) of a standard proctor shall be required at any trench depth or in replacement of any materials within the traveled portion of the Right-of-Way. Eighty-five percent (85%) of a standard proctor shall be required at any trench depth or in replacement of any materials off the traveled portions of the Right-of-Way. Installations running parallel within a gravel roadway will require a final placement of a minimum of six inches(6")of Surface Gravel after all of the Project has been placed and compaction test results are in compliance. (f) Potholes in gravel surfaces shall be filled completely with road base and compacted. Potholes in asphalt or concrete surfaces shall be filled with a cement/grout to existing thickness plus 1(+1)or filled with a compactable base material and the final placement a HMA or concrete material of existing thickness plus one(+1). 8. Reseeding. Permittee shall reseed, with a seed mix approved by Weld County Public Works Department,all areas within the Right-of-Way in which vegetation was removed or disturbed during the installation of its Project. 9. Points of Access. Permittee shall install manholes and other points of access to underground lines within the boundaries of the right-of-way outside the normal wheel path of the roadway so that they do not obstruct maintenance operations within the rights-of-way. Permittee shall, at its sole expense, adjust access points, when requested to do so by Weld County. 10. Survey Monuments. Permittee or its Contractor shall preserve or replace all survey monuments or benchmarks at each work site. If such monuments or bench marks are destroyed, Permittee shall hire a Registered Land Surveyor to replace destroyed monuments or bench marks. If Permittee chooses to preserve such monuments or benchmarks, it shall also hire a Registered Land Surveyor to complete such preservation. 11. Permittee's Obligations Regarding Surveys. (a) All surveying performed within the boundaries of the Right-of-Way shall be conducted with proper safety equipment and advanced warning signs; (b) Surveying permit holders can be issued an annual permit. (c) Any excavation within the boundaries of the Right-of-Way will be backfilled with the same material or better than what was excavated. (d) Weld County Public Works Department offers free monument boxes and lids to Permittee to establish, upgrade or perpetuate the location of an aliquot corner of any section on a paved road. Permittee shall furnish the location of the section corners being preserved to the Surveying Department when obtaining monument boxes. (Revised 7/2013) Page 5 of 7 12. Permittee's Obligations Regarding the Completion of Project. (a) Permittee shall place Surface Gravel, as specified in Chapter 7 of the Weld County Engineering and Construction Criteria, on all surfaces where any damage has occurred to the road surface from equipment, trenching, or storage of material. Weld County shall determine the damaged areas, remedial work required, and timing of said work. (b) Permittee shall complete road restoration including, but not limited to, clean-up (including utility markers), repair of damaged facilities, trench compaction, and replacement of gravel shall be kept within one (1) mile of new excavation. (c) All disturbed portions of the Right-of-Way or damaged road surfaces are to be returned to their original condition prior to demobilizing. If the Right-of-Way is not returned to original conditions, Weld County may perform or contract such remedial work and Permittee shall pay for all work or forfeit its surety bond in order to pay for all work done. GENERAL MATTERS 1. Terms. A. All references herein to "Right-of-Way" refer to a strip of land that is granted to the County through an easement of other mechanism for transportation purposes,such as a roadway or highway. B. All references herein to "Permittee" are to any persons and/or entities applying for and being issued a Right-of- Way Use Permit granting permission to occupy and/or install their Project within Weld County's rights-of-way. C. All references here into "Project" refer to the Permittee's pipelines, conduits, sleeves and/or appurtenances for natural gas\oil\electric\water\sewer\irrigation\communications\which are placed in Weld County's rights-of-way pursuant to this Permit. D. All references herein to"Contractor"are to any persons or business entities retained by Permittee to install the Project in Weld County right-of-way. E. All references herein to "Permit" refer to the Right-of-Way Use Permit, its Provisions, and any attached Special Provisions. 2. Weld County's Limited Interest in Right-of-Way. Weld County owns a limited interest in the Right-of- Way and therefore, does not, by the issuance of this Permit, warrant the right-of-way. Permittee is responsible for determining the ownership of properties traversed by its lines, the location of all property boundary lines, and the ownership of all right-of-ways. Therefore, Permittee shall obtain from the fee title owner(s) of the Right-of-Way or others having proprietary interests in the Right-of-Way such authority or rights as Permittee may need, in addition to this Permit for Permittee's use of the Right-of-Way. Permittee acknowledges and agrees that the authorization granted herein by Weld County is subject to Permittee's securing such authority or rights. 3. Weld County's Rights. Permittee acknowledges and agrees that the Right-of-Way exists as a public right-of- way for the primary benefit of the travelling public, and that the rights granted herein to Permittee and to other public and private utilities and entities, are subject to Weld County's rights and obligations to preserve and maintain the Right-of-Way as such. A. Subject to the right granted herein to Permittee, Weld County reserves the remaining use of the Right-of-Way for existing and future construction,operation, maintenance, repair, replacement relocation and abandonment of its own use and facilities. B. Weld County reserves the right to revoke this Permit at any time if Permittee or its Contractor fails to comply with the requirements of this Permit. Should this Permit be terminated for non-compliance by Permittee or its Contractor, any lines or facilities installed prior to the termination shall remain the responsibility of the Permittee and may be removed or maintained by Permittee at the sole discretion of Weld County. (Revised 7/2013) Page 6 of 7 C. Weld County reserves the right to allow other public and private utilities and entities to utilize the Right-of-Way and may impose location requirements and restrictions on Permittee in anticipation of requests by future public and private utilities and entities to occupy the Right-of-Way. D. Weld County reserves the right to reconstruct, widen and/or maintain the road(s) or right(s)-of-way affected by this Permit. In the event this work requires Permittee to incur expense in order to preserve, re- locate or maintain its Project, Permittee shall do so upon notification from Weld County at its sole cost. 4. Indemnification. Except for the negligence of Weld County, Permittee shall indemnify and save harmless Weld County, its, officers, employees, agents, successors and assigns from any damage or loss sustained by them or any of them, which arises by reason of Permittee's negligence with respect to the installation, upgrade and/or maintenance of the Project. 5. Hold Harmless. Permittee agrees to protect Weld County and save and hold Weld County harmless from any and all third party claims and damages which the installation and/or maintenance of Permittee's Project and related facilities may directly or indirectly cause. Additionally, Permittee releases Weld County from any and all claims and damages to property owned by Permittee resulting from any act, either by or on the part of Weld County or by or on the part of any third party. 6. No Assignment. Permittee shall not assign any or all of its rights under this Permit without first obtaining written consent to such assignment from Weld County,which consent shall not be unreasonably withheld. However, in the event Permittee contracts with a third party contractor to perform the work associated with the installation of the Project, Permittee remains solely responsible for Contractor's compliance with the terms and conditions of this Permit. 7. Entire Permit Agreement. The parties hereby agree that neither has made or authorized any agreement with respect to the subject matter of this instrument other than expressly set forth herein, and no oral representation, promise, or consideration different from the terms herein contained shall be binding on either party hereto, or its agents or employees. This Permit embodies all agreements between the parties hereto and there are no promises, terms,conditions,or obligations referring to the subject matter whereof other than as contained herein. 8. Effect of Invalidity of Provision. If any term or provision of this Permit, or the application thereof to any person or circumstances shall, to any extent, be held invalid or unenforceable, the remainder of this Permit, or the application of such terms or provisions, to a person or circumstances other than those as to which it is held invalid or unenforceable, shall not be affected, and every other term and provision of this Permit shall be deemed valid and enforceable to the extent permitted by law. 9. No Waiver of Immunity. No term or condition of this Permit shall be construed or interpreted as a waiver, express or implied, of any of the immunities, rights, benefits, protections or other provisions, of the Colorado Governmental Immunity Act§§24-10-101 et seq.,as applicable now or hereafter amended. 10. No Third Party Beneficiary. It is expressly understood and agreed that the enforcement of the terms and conditions of this Permit,and all rights of action relating to such enforcement,shall be strictly reserved to Weld County and nothing in this Permit shall give or allow any claim or right of action whatsoever by any other person not included in this Permit. It is mutually understood and agreed that this Permit and all the terms and conditions hereof shall extend to and be binding upon the Permittee and its successors, and assigns. (Revised 7/2013) Page 7 of 7 December 5, 2013 VBASELINE Engineering Planning •Surveying Weld County Public Works 1111 H Street Greeley, CO 80632 RE: Bill Barrett Compressor Station INTRODUCTION/OVERVIEW This letter is intended to serve as the site drainage overview for the above referenced project. Baseline is processing an application for improvements to serve a parcel generally described as part of the Northwest Quarter, Section 23, Township 6 North, 62 West in Weld County Colorado along the south side of County Road 68. Currently this site is native rangeland and is 100% pervious consisting of native vegetation. An existing oil and gas well pad know as Pappenheim 6-62-23 is located near County Road 68. Total acreage of the parcel is approximately 385 acres. An application for a 3.1 acre subdivision exemption is being processed. A new Compressor Site is proposed that will encompass approximately 2 acres, not including the new access road. EXISTING SITE DESCRIPTION The existing site is situated on the south side of County Road 68, approximately 20 miles east of Greeley. The site and surrounding area is undeveloped rangeland. No existing drainage issues are apparent. PROPOSED SITE DESCRIPTION Under the proposed conditions the majority of the overall site will remain unchanged. The proposed improvements will include re-grading and access improvements over a disturbed area of approximately 4 acres or 1% of the total site. The access road pavement (impervious surface) will be gravel and total approximately 0.5 acres or 0.1% of the total site. DRAINAGE CONDITIONS The site drains to the east towards a private drive approximately 2,000 feet downstream and ultimately to Sanborn Draw. Proposed site grading will maintain historic drainage patterns and flow through native pasture land prior to leaving the site. There are no known issues with the current drainage. Corporate Headquarters High Plains Rocky Mountains Downtown Golden Downtown Greeley Ski Village 700 12th Street, Suite 220 710 11th Avenue, Suite 105 1815 Central Park Drive,#370 Golden, Colorado 80401 Greeley, Colorado 80631 Steamboat Springs, Colorado 80477 Ph 303.940.9966 Ph 970 353.7600 Ph 970.879.1825 Fax 303.940.9959 Fax 970 353.7601 Fax 866.242 9106 Pagel 2 Drainage Letter WAIVERS FROM CRITERIA Due to the size of the existing parcel, 385 acres, the minimal amount of disturbance (1%), the small percentage of impervious surface (0.1%) being added within the basin, in addition to the remote nature of the project, a waiver from stormwater detention is being requested. CONCLUSION The proposed drainage system will continue to follow historic drainage paths. The runoff from the site will pass through undisturbed native pasture prior to out-falling into Sanborn Draw at near historic runoff rates. This drainage letter has been prepared in conformance with the Weld County Storm Drainage Criteria Addendum to the Urban Storm Drainage Manual and the County Engineering and Construction Criteria. We appreciate your consideration and please feel free to contact us with any questions. Sincerely, Baseline Engineering Corporation O.L../agtp..., i\IE,1*.:,'/// Ui cr a.5.15 9, o o9820 cn: ''�S4.y NA_EN.•° Noah J Nemmers PE Manager of Civil Engineering\ Golden COMPRESSOR SITE SURFACE USE AGREEMENT AND LEASE This Agreement is entered into and effective this 15th day of October, 2013, by and between Ronald L. Pappenheim and Betty J. Pappenheim ("Surface Owners") of 20112 WCR 76, Eaton, Colorado 80615 and Bill Barrett Corporation ("Operator") of 1099 18" Street, #2300, Denver. CO 80202,collectively hereinafter referred to as the("Parties"or individually as"Party"). WITNESSETH, That the Surface Owners, for and in consideration of the covenants and agreements hereinafter contained,the receipt and sufficiency of which are hereby acknowledged,have granted,demised,leased and let,and by these presents do grant,demise,lease and let exclusively unto the said Operator, the land hereinafter described, ("Leased Land"),with the exclusive right to use all that certain tract of land situated in the County of Weld,State of Colorado with an access road thereto described and set forth on the attached Exhibit"A"covering approximately 2.06 gross acres,more or less, and located in Section 23,T6N,R62W. 1. Term. This Agreement shall be effective as of the Effective Date stated above and shall have an initial term of ten(10)years. Further,this Agreement may be renewed for a second term of ten (10),and a third term of ten(10)years upon thirty(30)days'notice to the Surface Owners by Operator. such notice being deemed satisfactorily delivered if properly addressed to the Surface Owners using the address provided below and placed in the United States mail,postage prepaid,or a similar commercial provider. Within thirty (30) days after providing Surface Owners notice of the lease extension, Operator shall transmit by wire transfer,certified mail,or delivery by a commercial carrier,payment in the amount of Fifty Thousand Dollars ($55,000.00) as full settlement, satisfaction of all damages growing out of,incident to,or in connection with the usual and customary operations as required with a compressor site. Further, Operator shall have a continuous right to use the Leased Land for the purposes granted in this Agreement. Upon the termination of the initial term,or the second term if this lease is extended pursuant to this provision,the Operator agrees to furnish the Surface Owners with a release of the rights granted by this Agreement. 2. Consideration. (a) Compressor Site. Prior to actual construction of the compressor site on the Leased Land, the Operator shall pay Surface Owners, as damages, the full sum of Fifty Thousand Dollars($55,000.00)as full settlement and satisfaction of all damages growing out of,incident to,or in connection with the usual and customary operations as required with the installation of a compressor site. (b) As part of the consideration for this Agreement,the Operator agrees to hold the Surface Owners harmless from any and all claims,damages,suits, or obligations claimed or asserted against the Surface Owners by reason of the Operator's operation or business on the Leased Land and against any and all parties asserting such claims,and to defend the Surface Owners in any and all suits brought against the Surface Owners by reason of the Operator's operations on the Leased Land,all at the Operator's expense. Operator shall pay any taxes which may be levied upon or assessed against structures.fixtures, or other equipment which may be built or installed on the Leased Land by Operator. Except for cases of unreasonable surface use and/or negligence by the Operator, the Surface Owners, for itself and their successors and assigns, do hereby, in consideration of the amount to be paid, release, relinquish and discharge the Operator, its affiliates, successors and assigns from all claims, demands, damages and causes of action that the Surface Owners may have by reason of the construction and maintenance of the compressor site, and all other rights granted pursuant to this Agreement and the Surface Owners accept the consideration to be paid as full compensation therefore. 3. Use of Lands. This is a surface lease only and shall not be construed to limit the Operator's rights as the owner of minerals in and under the Leased Land. Without restricting or limiting the general and exclusive rights, privileges, powers, purposes, and uses granted to the Operator by the enumeration of the matters set out below, it is specifically agreed that the Leased Land leased pursuant to this Agreement may be used,occupied,and enjoyed by the Operator for the following purposes: With a copy,which shall not constitute notice to: Bill Barrett Corporation 1099 18th Street,Suite 2300 Denver,CO 80202 Attention: Francis B.Barron,Executive Vice President-General Counsel Phone:(303)293-9100 Fax: (303)291-0420 Any Party may change an address to which notice is to be given by delivering notice to the other Party. Until a change of address is provided to the other Party,the address provided herein shall be deemed to be correct for any notices provided in this Agreement. 6. Confidentiality. The parties hereto agree that the specific terms and conditions of this agreement are strictly confidential and shall not be disclosed except per court order,tax purposes or as necessary to effectuate the provisions herein. The parties shall execute a Memorandum of Compressor Site Surface Use Agreement and the Operator shall place same of record in Weld County,Colorado to provide notice to of the existence of this Agreement to subsequent purchasers of any portion of the property. 7. Binding Agreement. This Agreement,and any extension thereof,is intended to run with the land and shall be binding upon and shall inure to the benefit of the parties and their respective heirs, representatives,successors,agents,and assigns. 8. Arms-Length Transaction. The parties hereto agree that the terms and conditions of this agreement have been negotiated and entered into in good faith and at arms length. No term or condition is the result of either Parties'knowledge or relationship with the other. 9. Amendment. This Agreement may be amended or modified only by an agreement in writing signed by both Parties and expressly identified as an amendment or modification. • 10. Counterparts. This Agreement may be executed in multiple counterparts,each of which shall be deemed an original,but all of which together shall constitute one and the same instrument. 11. Complete Agreement. This Agreement constitute the entire agreement among the Parties pertaining to the subject matter hereof, and supersede all prior agreements, understandings, negotiations and discussions, whether oral or written, of the Parties pertaining to the subject matter hereof. IN WITNESS WHEREOF,the parties have set their hands on the day and year first written above. Surface Owners: / �By:iii/te.---6 • Name:Ronald L Pap ei N e:Bert; .P enheim Operator: 13111 Barrett Corporation By: Name:Mitchell Reneau Title:Senior Vice-President Land ACKNOWLEDGEMENT STATE OF COLORADO }SS COUNTY OF WELD } BEFORE me. the undersigned, a Notary Public in and fore said County and State, on this /544" day of t�GTO8E,e .2013,personally appeared Ronald L.Pappenheim and Betty J.Pappenheim,known to be the identical person(s)who executed the within and foregoing instrument,and acknowledged to me that they executed the same as a free and voluntary act and deed,for the uses and purposes therein set forth.Given under my hand and seal the day and year last above written. Ai/ No Public L� My Commission Expires 7-7-c O/Cp F.RUT `yitt It ( NOTAR), O 10 2' -•- :o tII 9PUBLIC i ; e tltt `0 P ACKNOWLEDGEMENT STATE OF COLORADO )SS COUNTY OF On the day of ,2013,before me the undersigned authority,appeared Mitchell Reneau,to me personally known, who, being sworn,did say that he is the Senior Vice-President Land for Bill Barren Corporation,a Delaware corporation, and that the foregoing instrument was signed in behalf of said corporation and appeared acknowledged to me that said instrument to be the free act and deed of the corporation. Notary Public My Commission Expires - `-- _ __ _ _ _ BRONCO COMPRESSOR WELD COUNTY ROAD 68 CLOP / oi to Et- _ __ ♦ ZQ f ice- _-- /' /� E C o t3 I X '• /' /'' ',"t//� . -� / -�' /� C - _ _ U �i i 07m-iii rimr,SE deet- ____t sat .,..____- BY SPECIAL REVIEW USR13-XXXX iCL - �/ ' ./.....171:6.•••••°- -__-_ ---______:-----,=-_------ --- ;; •�� �� PART OF THE NORTH HALF OF THE NORTHWESTQUARTER OF I 1 ;' �'�e� I I W co on X / 00 0 ---- on C:i SECTION 23, TOWNSHIP 6 NORTH, RANGE 62 WEST OF THE P.M., I U X X `:_______ 1 X W COUNTY OF WELD, STATE OF COLORADO ( X 00000 O I X 00000 O X 1OF2 X W � \ I x X X x I I ``♦ • ` p ( ' I I I i I 1 a ' 1 I I W / � 0-9 � ♦ N 1 1 , I ( I I 1 1 I I a I ' I I I x I / `. I ♦♦-� Xlie o a I1 i 1 I i a I l I I I I i I I 1 I I •�-_ - I 1 1 1 1 1 , , 1 I I 1 I --"- I I I 1 1 1 I 1 1 1 1 1 1 1 1 1 I I 1 I I 1 I / I , I I I I I 1 1 1 1 , 1 1 1 1 / I I I : It ' ll lit ! I ! i I X ; R. 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GRADES SHOWN ARE FINISHED GRADES, UNLESS OTHERWISE STATED. / / , i 1 I 1 ' , 1 I I I I ( ! \ 11 �x \�' 11 ' I I /'�� //� x / / / I I I 1 ' I I I I I I 1 , I \ I I I ..i I III\ /rO 9/ i- 2. THE ACCESS DRIVES ARE PROPOSED TO BE PROPOSED TO BE SURFACED WITH 6" / / I I I I I I I I I I , , , , 1 1 I 1 11 A \` I,7,-f //� / MINIMUM OF CDOT CLASS 6 ROAD BASE. / / I I 1 1 1 I , I , I I , '4111 \ / /,,, .- /// / / i / ' Ii i I ; 1 I 1 1 '' I ' ; '' ' Lit 1 I\� `\ ���� • i♦ I/ / / l I !) I 1 1 , I \ , , 1 1 1\1 I \ I �- h ���- ' ',/� $ / 3. NORTH AMERICAN GREEN SC250 EROSION CONTROL FABRIC AS APPROVED OR / / i I 1 1 i 1 , I , 1 '• 1 '1 1I 1 }� 1 \ '\ �` _ -- �- s _ _ / \._..._=. _____IkC���� %• �%i // .' SIMILAR TO BE INSTALLED AS PER MANUFACTURES SPECIFICATIONS ON ALL / ( I 1 I I l 1 1 1 I I ( 1 1 ' ,\I �`-1-.. : _ 1 -_�_ _�i i%- �. / / 1 I 1 1 I ' 1 I 1 , 1 I 11 ` ^ / ---- / , SLOPES 4:1 OR GREATER. 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I \ I I > \ \ 1 1 I I I I 1 'I ; i 1 ' \ \ o' I I I / X - n o 1 I 1 • \ .�� \ \ 1 1 I \ \ 1 1 \ N. .S I 1 1 , / 1 I 1 O x I I I 1 I \ I i�• -.' \ S. 11 1 1 1 \ \ 1 1 1 1 1 , �\ \ \\ \. J a 1 I I I \ 1 1 1 1 1 \ \ I , i I A 1 7 I I \ ` �\ 1\ 1 , 1 I r✓'' �' \ 'II \\ \I \ \ 1 1 ' I ' % \` \ \ `• I 1 I i' / / 1 ! / \ \ \ , - I I \ I I \ I I \ \ / / I , \ ' I , \ \ I 1‘ kk \ • 0 1 ' 1 I / i I I '' •\ •\ \9 \ \\ \ ' 1 / I \ 1 \ \ \ 1 \ \ I ♦• \ \ PREPARED UNDER THE DIRECT I I I / / / // l \ •\ S. 1 o I I 1 / 1 1 I \a 1 \ r / \ // / / /' `\ I 1 1 \ \ \ I 1 I 1 1 \ \ • SUPERVISION OF 1 1 CD i I X I/ I I o �\ \ o I • / \`\ ; / �.\` \ \ \ \ 1 1 1 1 1 1 1 \\ \♦ ` U0 \ II I ' II i I I I I .► \\ _ _.' \\ �' I I \ I ' ,' �,.�- �` 1 1 I 1 1 1 \ \\ \ ` `�- o • • • k I I\ I I I , I 1 I I ` • iI lI 1 I I ��- 1 I I ; \♦ `\ `\ `\ `��--- GRAPHIC SCALE 0 •\I I •'I •' 1 ' 0 I 1 •`• X I I /—�� S. I I , ----� t ` 1\ t \ ♦ • \ \ 200 0 200 400 m I \ I I I \ i 1 -�- 1 1 ! 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PL 232 O K I I� I 'lr X X X -X k1X X 21 / I \\ I 11 ,1 1 `\ \�.r ' 1 1 \ \ 1 - / z I —— — ; I } I 22 I 1 • \ I I I I , l \`\ \\\ I ; I I C11C1 OVERALL GRADING PLAN DR2WIND s dw9 Q �` I I I I \ i `mil I 1 1 1 I I 1 I 1 ^\ ``� ; 1 ; \ \ I I ' , ... SHEET OF 1 CL \ 1 ( I I \ ,/ 1 / I 1 1 I 1 1 / / E. ``\ 1 1 I\ ♦ -`���_- -___� 1 I I C 1 ♦ \ 1 ' _�' / z ( i 1 \ ` / 1 1 I i I I I , - /'� • N.`\ I. `. \ `\ , - .--_- '� / 1 1 / / USE BY SPECIAL REVIEW QUESTIONNAIRE Proposed Construction of BBC's Bronco Compressor Station Facility NW/4, Sec. 23, 6N-62W of the 6th Principal Meridian Weld County, CO REVISED: January 7, 2013 Applicant: Bill Barrett Corporation 1099 18th Street, Suite 2300 Denver, CO 80202 B Bill Barrett Corporation S Bill Barrett Corporation Table of Contents Vicinity Map Section 1 1. Proposed Use of Property 2. Consistency with the I ntent of the Comprehensive Plan 3. Consistency with the I ntent of the Zoning and Zone District 4. Type of Uses Surrounding the Site 5. Project Details a. Number of people using the site b. Number of employees housed at the site c. H ours of operation d. Type and number of structures to be built on site e. Type and number of animals on site f. Kind of vehicles(type, size, weight) and how often g. Fire protection h. Water source i. Sewage disposal system j. Storage(what type) 6. Proposed Landscaping 7. Proposed Reclamation 8. Storm Water Drainage 9. Construction Process 10. Waste M anagement 11. Dust Abatement Plan S Bill Barrett Corporation Table of Contents Continued Section 2 1. Notification Requirements 2. Operational Standards 3. Required Permits 4. Traffic 5. Fire and Emergency Response 6. Spill Prevention, Control and Countermeasure 7. Noise Abatement Plan Vicinity M ap for the BBC Bronco Compressor Station Facility 392 4 - . WCR 74 - m Co rn cc cc L.) 4 SITE . . _ c J WCR 68 c _ ''c: a cc o un rn o u U yI _,y N - (Section 23, Township 6N, Range 62W) Section 1 1. Proposed Use of Property Bill Barrett Corporation (BBC) has obtained a Compressor Site Surface Use Agreement and Lease from Ronald and Betty Pappenheim to utilize approximately 300 feet by 300 feet of zoned agricultural land for the purposes of constructing and operating a new natural gas compressor station. In addition a new access road will be constructed. A Subdivision Exemption will be processed prior to this USR application in order to create a 4.7 acre lot for the facility. The new compressor station is located adjacent to the existing BBC Pappenheim 6-62-23 well pad. The specific siting of the compressor station was the landowner's preference since the topography surrounding the site will help reduce the visual and noise impact on the neighbors to the west and the north-east. The two facilities will share an access point on WCR 68. Compression assures consistent wellhead pressures to maximize resource recovery and production efficiency. Compression is also necessary to develop pressure for delivery into a sales line which will be located approximately 3,500 feet away from the proposed station. Compression at the site will be used to provide pressure for gas lift operations of nearby wells and wells anticipated to be brought on in the future (currently projected at upwards of 80 wells). The proposed facility will be a permanent facility, operating year-round, 24/7, lasting the approximate 30-year lifespan of the currently projected drilling and production life of BBC's holdings in the area. The facility will be monitored remotely, i.e. it will be unmanned. Pipelines associated with the facility are as follows: Size/ Material Location Pressure Use 10-inch/Steel Into Station <100 psi Suction 8-inch/Steel Into Station <100 psi Suction 6-inch/Steel Out of Station >200 and<400 psi Discharge 4-inch/Steel Out of Station >500 and< 1000 psi Discharge The proposed facility is located in the NW corner of Section 23, Township 6N, Range 62 West on WCR 68 approximately 7 '/2 miles west of the Morgan County line. Ownership l nformation As seen on Assessor Record: Contact: Pappenheim Ronald L Tracey Fallang, Regulatory Manager Pappenheim Betty J Bill Barrett Corporation 20112 County Rd 76 1099 18th Street, Suite 2300 Eaton, CO 80615 Denver, CO 80202 2. Consistency with the I ntent of the Comprehensive Plan BBC has reviewed the Comprehensive Plan as outlined in Chapter 22 of the Weld County Code and believes this project is consistent with its guiding principles. Section 22-2- 10(D) emphasizes extraction of natural resources as an important part of the economy and should minimize impacts to agricultural lands. The proposed 4.7 acre facility will be located on lands leased by BBC that are currently non-irrigated rangeland that is located in a rural area with existing oil and gas activity. The placement and size of the facility will allow for the current agricultural use to persist. 3. Consistency with the I ntent of the Zoning and Zone District The natural gas compressor station is classified by Weld County as an Oil and Gas Support and Services facility. Section 23-3-40.A.2 of the Weld County Code states that these facilities are uses allowed to be constructed, occupied, operated and maintained in the A (Agricultural) Zone District only upon approval of a Use by Special Review permit in accordance with the requirements and procedures set forth in Article II, Division 4 of Chapter 23. 4. Type of Uses Surrounding the Site The proposed Bronco Station is surrounded by agricultural properties and is located in an area with existing oil and gas activity. The compression of natural gas is a necessary component of the oil and gas industry. 5. Project Details a. Number of people using the site During the construction phase upwards of 20 personnel could be on site at peak construction. The construction phase is slated to last approximately eight (8) weeks. During the operations phase, the site will be visited by up to two (2)people (pumper, mechanic) each day for maintenance for short periods of time. In addition, at least once a month, for a period of two to three days, the site would be visited by approximately three (3) trucks for a scheduled monthly maintenance. b. Number of employees housed at the site Upon completion of construction, the Bronco Compressor Station will be operated remotely so there will be no full time personnel on site. c H ours of operation The facility will operate 24 hours a day, seven days a week. However, typical access in and out of the facility will occur during daylight hours except during maintenance situations in which the station is not operating at peak efficiency or other situations that could require immediate attention. d. Type and number of structuresto be built on site Phase I • (2) 1680 HP compressors, each with an on-skid, self-framing building (27'x52'x20') • (4)400 bbl water tanks (12'x20') • (1) Combustor(24"x20') • (1)Vapor recovery unit(10' x 15') and tower(24"x 30') • (1)Flash gas vessel(36"x 25') • (2)Flare stacks (3"x 20') • (1) Connex Storage Container/Control Room (20' x 12'x 40') • (3)Pig launchers • (2) Pig receivers • (1) Slug catcher • (1) Gas lift separator and meter • (1) Sales gas separator and meter • (1)Fuel gas separator and meter • (2) Inlet separators • (1) 500 gallon methanol storage tank • (1) 25' communications tower Phase I I (installation of additional compressor and tanks as needed) • (1) 1680 HP compressor, contained within its own building (30'x50'x29') • (2) 500 gallon engine oil storage tanks • (2) 500 gallon glycol storage tanks e. Type and number of animals on site None. f. Kind of vehides(type, size, weight) and how often Facility traffic will flow to and from the site daily at intermittent times during mostly daylight hours. Type of vehicles accessing the site will consist of one truck (3/4 ton). Please see the Traffic Memo. g. Fire protection The property falls within the Briggsdale Fire Protection District. A referral packet will be sent to the district by Weld County upon application for the USR. h. Water source No full time personnel are on site. No water source is required for this facility. Employees that use the site will use bottled drinking water. i. Sewage disposal system A sewage disposal system is not required. A portable toilet will be located on site and serviced at regular intervals. j. Storage A climate controlled Connex Storage Container will be utilized to store parts necessary for station maintenance and operation and to also serve as a control room with data processing equipment(SCADA, data-recorders, etc.). 6. Proposed Landscaping After the compressors are installed, reclamation for those portions not necessary for operations would be completed according to Colorado Oil and Gas Conservation Commission (COGCC)regulations. The compressor site and accompanying equipment area would be graveled and graded for positive drainage (and a 4-ft, 3-strand barbed wire fence will surround the facility). No further landscaping is proposed. 7. Proposed Redamation When use of the facility is terminated, all above-ground facilities will be removed, while any underground pipe would be purged and capped and left in place with a nitrogen charge. The land will be reclaimed according to surface owner requests or according to COGCC regulations. 8. Storm Water Drainage The facility is located on a relatively flat parcel. All necessary grade work will be performed to prepare the site for its intended use. However,based on the layout of the site, it is not expected that this pad will require a large amount of grading work. The site will be surfaced with gravel. Please see the Drainage Memo included with this application. 9. Construction Process Construction of the compressor pad is anticipated to commence upon the approval of this USR. The total construction time is expected to be eight(8) weeks. 10. Waste M anagement Plan BBC maintains a corporate Waste Management Plan that covers the management of wastes typically associated with our operations. This plan is used to determine how to best manage common wastes. The objective of the plan is to ensure that generation of wastes is minimized and materials are reused or recycled whenever possible. When that is not possible the plan is utilized to ensure that wastes are managed in accordance with all Local, State, and Federal regulations. BBC personnel are trained on waste management practices. BBC anticipates that the following wastes will be generated at the site: • Used oil • Used antifreeze (ethylene glycol) • Tank bottoms • Spent filters • Light bulbs • Spent batteries • Rags and absorbent socks and pads • Hydrocarbon impacted soil from minor leaks and vehicle traffic • Used packaging material, including cardboard, scrap lumber from crates, metal strapping, etc. A small dumpster will be placed on site and municipal solid waste will be managed by Redi Services, LLC or Waste Management Incorporated. The dumpster will be emptied weekly or bi-weekly. A RCRA Universal Waste program will be set up and managed by Clean Harbors Incorporated for the proper management or recycling of universal wastes such as spent batteries and light bulbs. Used oil, antifreeze, filters, rags and pads will be managed by either January Environmental Services Incorporated or Tri-State Oil Reclaimers. When necessary, tank bottoms will be removed and sent to an authorized disposal facility. This activity will be coordinated by Clean Harbors Incorporated. In addition, Redi Services,LLC or Reck Flyers will provide portable toilet service on location. Spills and releases will be managed in accordance with the facility's SPCC Plan and BBC's Emergency Response Plan. Hydrocarbon impacted soils will be removed from the facility as needed and disposed of at Waste Management Incorporated's landfill in Ault, Colorado. In the event a change in contractors is necessary in the management or disposal of waste, a state authorized provider would be utilized. 11. Dust Abatement Plan During the construction phase of the project, BBC will use water or magnesium chloride trucks for dust suppression. Soil erosion will be mitigated through the appropriate use of best management practices contained within BBC's Storm Water Management Plan. After construction is completed, BBC will gravel the access and the compressor pad location and water or magnesium chloride application will be applied on an as-needed basis. SECTION 2 1. Notification Requirements County Notices Section 23-2-210(B)(1): Upon application completeness, agency notice submittal (28 day comment period). This step is completed by Weld County staff. Section 23-2-210(B)(6), a sign shall be posted by the County on this proposed site. This step is completed by Weld County staff. Section 23-2-210(8)(4): Notice to owners of property within 500 feet of the parcel. As per 23-2-260(B)(9), the list attached was created from Assessor records of Weld County on November 22, 2013. 2. Operational Standards Noise Control: The operation of the facility shall comply with the noise standards enumerated in Section 25-12-101, C.R.S. The facility will adhere to all applicable COGCC noise regulations. Minimal noise emissions are expected from this site. Noise sources are expected to be limited to vehicle traffic and electric-drive injection pumps which will be housed inside buildings. Air and Water Quality: All activities will be in compliance with the permit and control provisions of the Colorado Air Quality Control Program, Title 25, Article 7, and C.R.S. as applicable. No waste water will be discharged on the surface of the site. Human wastes will be contained to the portable toilet on site. Lighting: Lighting on the site will be downcast and shielded lighting will be provided on the proposed building. Lighting is for nighttime security and emergency work only. Lighting will be on a timer and motion detection. Any source of lighting on the site shall be shielded so that light rays will not shine directly onto adjacent properties where such would cause a nuisance or interfere with the use on the adjacent properties. In addition,neither direct nor reflected light from any light source on site will create a traffic hazard to operators of motor vehicles on the adjacent access road. Weed Control: The facility will be kept free of weeds, rubbish, and other waste material. The area shall be treated if necessary and as practicable to prevent invasion of undesirable species and noxious weeds. 3. Required Permits Weld County: A Use by Special Review Permit requires approval by the Board of County Commissioners. Access to the site from WCR 68 was previously coordinated with the Weld County Department of Public Works. Access permit AP13-00144 is already approved for the existing access to this site. A copy is included with this submittal. A Weld County Right-of-Way Use Permit(RW13-00362) for the pipelines has been approved and constructed. A grading permit is expected to be required. Briggsdale Fire Protection District: The Site Plan and Use by Special Review Application will be referred to and reviewed by the Briggsdale Fire Protection District. Oversize Load Permits: If necessary, oversize load permits will be obtained prior to moving any new equipment onto the site. BBC will submit any additional permits necessary for county approval prior to the commencement of construction. 4. Traffic Please see the Traffic Memo located in the Appendix. 5. Fire and Emergency Response There is adequate provision for the protection of the health, safety and welfare of the inhabitants of the neighborhood and the county. All roads leading to and those in the site area are designed and maintained to support fire apparatus. Sufficient turnaround room to accommodate fire apparatus is present. All storage tanks will be permanently mounted with foam nozzles according to API (American Petroleum Institute) standards. BBC support personnel in the field are on call at all times to provide technical assistance in fire prevention and suppression. Emergency I nformation General Information: The purpose of this document is to provide ownership information in case of an emergency at the proposed Bronco Compressor Station. It may be used by outside agencies, company employees, and contract labor to help secure a safe and swift recovery from such emergency situations: a. Name and Address Corporate Office Bill Barrett Corporation 1099 18th Street, Suite 2300 Denver, CO 80202 (303)293-9100 Regional Office-DJ Operations Bill Barrett Corporation 6513 West 4th Street Greeley, CO 80634 (970) 353-0407 b. Type of Facility. Compressor station c. Location and Access: Located on WCR 68 approximately 7 %2 miles west of the Morgan County line in the Northwest quarter of Section 23, Township 6 North, Range 62 West. Emergency Contact Lid: The following is a list of Bill Barrett Corporation personnel and organizations that may be contacted in the event an emergency occurs at the facility. Contact Office Phone Cell Phone John Ed Singleton—Area Superintendent 970-353-0407 x6006 720-633-3900 Dathan Bulot—Production Superintendent 970-353-0407 x6009 970-593-2137 Jay Bauer—Facilities Engineer 303-312-8101 303-638-9558 Dustin Watt—EHS Coordinator 970-353-0407 x6005 303-656-1838 24-Hour Emergency Number 1-800-880-6359 6. Containment/SPCC Plan If required, an SPCC plan will be created for the facility prior to commencing operations. It is BBC's policy to create and maintain SPCC plans at all of its non-transportation related facilities in accordance with 40 CFR Section 11. Upon completion of the SPCC plan, a signed copy will be provided,per the request of Weld County. 7. Noise Abatement Plan A noise abatement plan was prepared by Noise Solutions. This report will be submitted after the seven-day completeness review. WELD COUNTY ACCESS PERMIT C. Weld County Public Works Dept. 34i� yJ► Phone: (970)304-6496 1111 H Street After Hours: (970)356-4000 P.O. Box 758 -o Astir (i Emergency Services: (970)304-6500 x 2700 ir Greeley, CO 80632 GBH Q- Inspection: (970)304-6480 Z/C W° Permit Number: AP13-00144 Issuance of this permit binds applicant and its contractors to all requirements,provisions,and ordinances of Weld County,Colorado. Project Name: pappenheim 6-62-23 Pad Expiration date: 10/29/2013 Applicant Information: Property Owner Information: Name: Mary Pobuda Name: Betty&Ronald Pappenheim Company: Bill Barrett Corp Company: Phone: 303-312-8511 Phone: Email: mpobuda@billbarrettcorp.com Email: Location: Proposed Use: Access is on WCR: 68 Temporary: Nearest Intersection WCR: 68 &WCR: 83 Single Residential: Distance From Intersection: 3698.1 Industrial: Number of Existing Accesses: 1 Small Commercial: Planning Process: Oil&Gas: El Large Commercial: Road Surface Type&Construction Information: Subdivision: Road Surface: Gravel Field (Agricultural Culvert Size&Type: 16"CMP Only)/Exempt: Start Date: 05/20/2013 Finish Date: 10/29/2013 Materials to Construct Access: Native Soil&Gravel Required Attached Documents Submitted: Access Pictures: Traffic Control Plan: Certificate of Insurance: Yes A copy of this permit must be on site at all times during construction hours Daily work hours are Monday through Friday DAYLIGHT to 1/2 HOUR BEFORE DARK(applies to weekends if approved) Approved MUTCD traffic control/warning devices are required before work begins and must remain until completion of work Special Requirements or Comments Approved by: Janet Carter,Weld County Public Works Date: 5/7/2013 Print Date-Time: 5/7/2013 11:57:11AM Report ID: PW00008v002 Page 1 of 1 �,�o CO& ti,k Weld County Public Works Dept. .s -°-L 1111 H Street ACCESS PERMIT „4 $ _,� ,:co P.O. Box 758 G `� Greeley, Co 80632 APPLICATION FORM 84/C w�Q� Phone: (970)304-6496 Fax: (970)304-6497 CCO)-(A. ((-- -(`, l' - Applicant Property Owner(If different than Applicant) Name Mary Pobuda Name Betty& Ronald Pappenheim Company Bill Barrett Corp Address 20112 County Road 76 Address 1099 18th Street,Suite 2300 City Eaton State CO Zip 80615 City Denver State CO Zip 80202 Phone Business Phone 303.312.8511 Fax Fax 303.291.0420 E-mail E-mail mpobuda@billbarrettcorp.com A= Existing Access A= Proposed Access Parcel Location&Sketch The access is on WCR 68 Nearest Intersection:WCR 68 &WCR 83 WCR (;s Distance from Intersection .7 miles Parcel Number 079723200019 1 Fi 1 Section/Township/Range 23/6N/62W T Sec 23 3 Is there an existing access to the property? ® NO N Number of Existing Accesses one Road Surface Type&Construction Information Asphalt_ Gravel X Treated Other WCR Culvert Size &Type 16" CM P Materials used to construct Access Native soil &gravel Construction Start Date 5/20/13 Finish Date 3 days after start Proposed Use ❑Temporary(Tracking Pad Required)/$75 ❑ Single Residential/$75 ❑ Industrial/$150 X Small Commercial or Oil&Gas/$75 ❑ Large Commercial/$150 ❑ Subdivision/$150 ❑ Field (Agriculture Only)/Exempt Is this access associated with a Planning Process? ❑ No ❑ USR ❑ RE ❑ PUD X Other Oil &Gas\ Required Attached Documents -Traffic Control Plan -Certificate of Insurance -Access Pictures (From the Left, Right, &into the access) By accepting this permit,the undersigned Applicant,under penalty of perjury,verifies that they have received all pages of the permit application;they have read and understand all of the permit requirements and provisions set forth on all pages;that they have the authority to sign for and bind the Applicant,if the Applicant is a corporation or other entity;and that by virtue of their signature the Applicant is bound by and agrees to comply with all said permit requirements and provisions,all Weld County ordinances,and state laws regarding f cilities cons ruction. r Signature� L \ Printed Name Mary Pobuda Date L 'IL( '( )l Lat40°, Inc. 1635 Foxtrail Drive, Suite 325 Loveland, CO 970-776-3321 ACCESS ROAD MAP-A SECTION: 23 TOWNSHIP: 6N PAPPENHEIM 6-62-23 PAD RANGE: 62W _ ~ Ir 4692,'x``11 . - , r- "-� / , 4750 .1 �) \ ,,,1' • , \CI , 1 • Jy 1 5 v ... �• 14 I i • ) r } � / Praha Sch [f-' \ '1 / PROPOSED ACCESS V• 1 ,s'N t ... . '`'� D'sk ) /�4 ENTRANCE ±50' 0.7 MILES �r ,BM _ - - 4673 ', 'r 1 I 62, CDUNTY RDAJI 88 r 125 „ I` \: L..- ./I �l); ,sWfndmcn A I {.. II _ r.�O 1 1 � �, i [ :-(jil`,\/\\\:d.:- a o PAPPENHEZAI 6-62-23 PAD .. . < ii:L7)\..,,, ',,- ..D.:',J `r5 ,� , Il 2‘‘Sil„,\I-Is.'-1''..:)1,1 if, T4721 x- r- - 1, 2.:i( Oi II .I ' 1 . ' . „ „ ) \-// il \ ,\.\ \r, I. �J �:I:\ rte. � ) iii 1;;,:c: �� --I n 16, i :\; 1_,:7.:°_.0: W r d 0 .. -- l'---"'""7'-'==' 1(1 ''i'li i i } 4675 1 t • • ' i y r t h p r' ) `-Vtindrn'i}f d 1 __JP L 'k\c, '\\ ,\ \ \1 \,,, I ---„, a, \ . 1 `, ' a% n r c `,\ 464\n )\) r�� / a o / / 1 t.�,) \ ` ` J) l f *q (f `yam (^-� (/ v-- ( 1.(\ ( ' \_./ *I (d-) \ . (- -\ \ \ `\ik'', r. f fl , ti r_ 46O1• a`'t I 46� 4 / I { 4 I / / {. i1, i 1 ! i (`\ (� 1 , ' r`--` , Cam""-� `' u � 1 / f 4 ?p, ni l, - \ �� y ° (+/r\ 4 %o { l,�\,..? ---,,,. ,,, w, .tom,i1 . i -. 864 \o- ,- S\ \ ' c:/—)\I t? I DIRECTIONS: 0 2000 FROM THE INTERSECTION OF COUNTY ROAD 83 & COUNTY ROAD 68 GO WEST 0.7 MILE ON COUNTY ROAD 68 TO PROPOSED ACCESS ROAD TO THE SOUTH. 1'=2000' DATE: 2/25/2013 PROJECT#: 2013018 Lat40°, Inc. 1635 Foxtrail Drive, Suite 325 Loveland, CO 970-776-3321 ACCESS ROAD MAP-B SECTION: 23 TOWNSHIP: 6N PAPPENHEIM 6-62-23 PAD RANGE: 62W L cke p 4 \\:\ . '*4400a0P•'°.11"°Il lik\ ( \ PROPOSED ACCESS WITH 80' APPROACH AND 16" CMP LAT: 40.48018'N LONG: 104.29396'W (0.3 MILES) 0,7 MILES TO COUNTY ROAD 83 COUNTY ROAD 66 = �- ` _ . (OA MILES) — �.s. •r e J� ALTERNATE ACCESS T I ALTERNATE ACCESS OPTION "B" TIES TO EXISTING PROPOSED ACCESS 00 ACCESS ROAD 'mow „ " , I OPTION "B" 20' WOE OPTION A 20 WIDE I I 0.2 MILES +�,� 390' L_. ---� I '�S 0 1 PAPPENRElh! 6-62-23 PAD 350' X 575' ,..„.•••••.) I DISTURBED AREA „,,,- I (•0'ell:IJ i Iit dip;i0 ooirv.„_ rum4.444...if (4\:4 1 ‘..\i'st.‘. \-,,, k I )\44144N i 4:72/" j#44 - i I \ ' . 1/4'4.‘9..r -\\WW.."‘ 1 0 500 I I 1"=500' PROPOSED PERMANENT ACCESS WILL BE A CLAY BASE WITH A 1.5" GRAVEL TOP 20' WIDE BUILT TO DATE: 2/25/2013 BLM GOLD BOOK STANDARDS. THE MAXIMUM GRADE WILL NOT EXCEED 6% PROJECT.#: 2013018 • Lat40°, Inc. 1635 Foxtrail Drive, Suite 325 Loveland, CO 970-776-3321 ACCESS PICTURES SECTION: 23 TOWNSHIP: 6N PAPPENHEIM 6-62-23 PAD RANGE: 62W DATE: 2/7/2013 1 I �� " ------------ • ` I;- ,UIyyti< ?�.� A'Y'E7• [jf ''-r ""1";`, 7r fii >> '•!..:0.,) rT,t'A 4'''.: ' i j -�'17.Y yr A,, yG, - VIEW EAST (CR 68) 1 3 e v YY 4 '{ '5y t pqy� ��2 �1'yp *40.06044 .0. --, N a #a' i fib - VIEW SOUTH • r �', 4. VIEW WEST (CR 68) DATE: 2/25/2013 PR0JECT#: 2013018 Q Bill Barrett Corporation Page 1 of 1 1099 18TH STREET, SUITE 2300 DENVER,CO 80202 Vendor No. Vendor Name Check Date Check Number Check Total 25749 WELD COUNTY Apr-11-2013 199418 $75.00 VOUCHER VENDOR INV # INV DATE TOTAL PRIOR PMTS NET AMOUNT & DISCOUNTS AMOUNT 04-AP-5358 CK040313A 04/03/13 75.00 0 .00 75.00 ACCESS PERMIT FEE PAPPENHEIM 6-62-23 PAD TOTAL INVOICES PAID 75.00 Account Payable Inquiries 303-312-8578 PAYEE: DETACH THIS STATEMENT BEFORE DEPOSITING THIS CHECK HAS A COLORED FACE ON WHITE STOCK AND AN ARTIFICIAL WATERMARK ON THE BACK. US BANK El No. 199418 93-455 HAVRE,MONTANA 59401 929 Bill Barrett Corporation 24-HOUR BANKING 1-800-673-3555 1099 18TH STREET, SUITE 2300 DENVER,CO 80202 VOID AFTER 90 DAYS CHECK NUMBER DATE PAY EXACTLY EXACTYE575dO1SOOCtS 199418 Apr-11-2013 $75.00 SEVENTY-FIVE DOLLARS AND NO CENTS To THE WELD COUNTY By ORDER PUBLIC WORKS CFO OF 1111 H STREET GREELEY, CO 80632 ll'0000 1994 Lao I:0929045541: L 50080 68 288 611' BHUGHES Material Safety Data Sheet Baker Petrolite Section 1. Chemical Product and Company Identification Product Name METHANOL _Code PFR23 Supplier Baker Petrolite Version 4.0 A Baker Hughes Company 12645 W. Airport Blvd. (77478) P.O. Box 5050 Sugar Land,TX 77487-5050 For Product Information/MSDSs Call: 800-231-3606 (8:00 a.m. -5:00 p.m. cst, Monday- Friday)281-276-5400 _ Material Uses Solvent. Effective Date 1/31/2006 24 Hour CHEMTREC 800-424-9300 (U.S. 24 hour) Print Date 1/31/2006 Emergency Baker Petrolite 800-231-3606 Numbers (001)281-276-5400 CANUTEC 613-996-6666 (Canada 24 hours) CHEMTREC Intl 01-703-527-3887 (International 24 hour) National Fire Protection Flammability Association(U.S.A.) Health 41* Instability Specific Hazard Section 2. Hazards Identification Physical State and State: Clear. Liquid., Color: Colorless., Odor: Slight Alcohol-like. Appearance CERCLA Reportable Methanol, 754 gal. of this product. Quantity Hazard Summary WARNING. May cause chronic effects. Flammable liquid. Vapors can form an ignitable or explosive mixture with air. Can form explosive mixtures at temperatures at or above the flash point. Vapors can flow along surfaces to a distant ignition source and flash back. Static discharges can cause ignition or explosion when container is not bonded. May be irritating to eyes, skin and respiratory tract. May be toxic by skin absorption. May be toxic if inhaled. Routes of Exposure Skin (Permeator), Skin (Contact), Eyes, Inhalation. Potential acute health effects Eyes May cause eye irritation. Skin May be irritating to skin. May be toxic if absorbed through the skin. Inhalation May be toxic if inhaled. May be irritating to lungs. Ingestion Not considered a likely route of exposure, however, may be toxic if swallowed. Medical Conditions Exposure to this product may aggravate medical conditions involving the following: nervous aggravated by system, gastrointestinal tract, respiratory tract, skin/epithelium, eyes. Exposure See Toxicological Information (section 11) Additional Hazard Repeated or prolonged contact may cause dermatitis (inflammation) and defatting of the skin Identification Remarks (dryness). lContinued on Next Page 'METHANOL Page: 2/7 Section 3. Composition and Information on Ingredients Name CAS# %by Weight Methanol 67-56-1 60- 100 See Section 8 for information on permissible exposure limits and threshold limit values. Section 4. First Aid Measures Eye Contact Flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower eyelids. Get medical attention immediately. Skin Contact Remove and launder or clean contaminated clothing and shoes. Wash with soap and water for at least 15 minutes or until no evidence of material remains. Get medical attention if irritation occurs. Inhalation Remove to fresh air. Oxygen may be administered if breathing is difficult. If not breathing, administer artificial respiration and seek medical attention. Get medical attention if symptoms appear. Ingestion Get medical attention immediately. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Wash out mouth with water if person is conscious. Never induce vomiting or give anything by mouth to a victim who is unconscious or having convulsions. Notes to Physician Not available. Additional First Aid Not available. Remarks Section 5. Fire Fighting Measures Flammability of the Flammable liquid. Vapors can form an ignitable or explosive mixture with air. Can form explosive Product mixtures at temperatures at or above the flash point. Vapors can flow along surfaces to a distant ignition source and flash back. Static discharges can cause ignition or explosion when container is not bonded. OSHA Flammability IB Class Products of These products are carbon oxides(CO, CO2). Combustion Fire Hazards in Open Flames/Sparks/Static. Heat. Presence of Various Substances Fire Fighting Media In case of fire, use foam, dry chemicals, or CO2 fire extinguishers. Evacuate area and fight fire and Instructions from a safe distance. Water spray may be used to keep fire-exposed containers cool. Keep water run off out of sewers and public waterways. Note that flammable vapors may form an ignitable mixture with air. Vapors may travel considerable distances and flash back if ignited. Protective Clothing Do not enter fire area without proper personal protective equipment, including NIOSH approved (Fire) self-contained breathing apparatus. Special Remarks on Not available. Fire Hazards IContinued on Next Page 'METHANOL Page: 3/7 Section 6. Accidental Release Measures Spill Put on appropriate personal protective equipment. Keep personnel removed and upwind of spill. Shut off all ignition sources; no flares, smoking, or flames in hazard area. Approach release from upwind. Shut off leak if it can be done safely. Contain spilled material. Keep out of waterways. Dike large spills and use a non-sparking or explosion-proof means to transfer material to an appropriate container for disposal. For small spills add absorbent (soil may be used in the absence of other suitable materials) scoop up material and place in a sealed, liquid- proof container. Note that flammable vapors may form an ignitable mixture with air. Vapors may travel considerable distances from spill and flash back, if ignited. Waste must be disposed of in accordance with federal, state and local environmental control regulations. Other Statements If RQ (Reportable Quantity) is exceeded, report to National Spill Response Office at 1-800-424- 8802. Additional Accidental Not available. Release Measures Remarks Section 7. Handling and Storage Handling and Storage Put on appropriate personal protective equipment. Avoid contact with eyes, skin, and clothing. Avoid breathing vapors or spray mists. Use only with adequate ventilation. Store in a dry, cool and well ventilated area. Keep away from heat, sparks and flame. Keep away from incompatibles. Keep container tightly closed and dry. To avoid fire or explosion, ground container equipment and personnel before handling product. Additional Handling Not available. and Storage Remarks Section 8. Exposure Controls/Personal Protection Exposure Limits Methanol ACGIH (United States). Skin TWA: 262 mg/m3 8 hour/hours. STEL: 328 mg/m3 15 minute(s). TWA: 200 ppm 8 hour/hours. STEL: 250 ppm 15 minute(s). OSHA PEL 1989(United States). Skin TWA: 200 ppm 8 hour/hours. STEL: 250 ppm 15 minute(s). TWA: 260 mg/m3 8 hour/hours. STEL: 325 mg/m3 15 minute(s). Additional Information The OSHA permissible exposure levels shown above are the OSHA 1989 levels or from on Exposure Limits subsequent OSHA regulatory actions.Although the 1989 levels have been vacated the 11th Circuit Court of Appeals, Baker Petrolite Corporation recommends that these lower exposure levels be observed as reasonable worker protection. Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors or particles below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Personal Protection Personal Protective Equipment recommendations are based on anticipated known manufacturing and use conditions. These conditions are expected to result in only incidental exposure. A thorough review of the job tasks and conditions by a safety professional is recommended, however,to determine the level of personal protective equipment appropriate for these job tasks and conditions. Continued on Next Page METHANOL Page: 4/7 Eyes Chemical safety goggles. Body Wear long sleeves to prevent repeated or prolonged skin contact. Respiratory Respirator use is not expected to be necessary under normal conditions of use. In poorly ventilated areas, emergency situations or if exposure levels are exceeded, use NIOSH approved full face respirator. Hands Chemical resistant gloves. Neoprene gloves. Butyl rubber gloves. Feet Chemical resistant boots or overshoes. Other information Not available. Additional Exposure Not available. Control Remarks Section 9. Physical and Chemical Properties Physical State and Clear. Liquid. Odor Slight Alcohol-like. Appearance pH Not available. Color Colorless. Specific gravity 0.79-0.802 @ 16°C (60°F) Density 6.58-6.68 lbs/gal @ 16°C (60°F) Flash Points Closed cup: 11.1°C (52°F). (TCC) Flammable Limits L.E.L. 6% U.E.L. 36.5% Autoignition 385°C (725°F) Temperature Initial Boiling Point Not available. Boiling Point 65°C (149°F) Vapor Density 1.11 (Air= 1) Vapor Pressure 96- mm Hg @ 20°C (68°F) Evaporation Rate 5(compared with Butyl acetate). VOC Not available. Viscosity Not available. Pour Point -97.8°C (-144°F) Freezing Point Solubility(Water) Soluble Physical Chemical Not available. Comments Section 10. Stability and Reactivity Stability and Reactivity The product is stable. Conditions of Not available. Instability Incompatibility with Oxidizing material. Various Substances Hazardous Not applicable. Decomposition Products Hazardous Hazardous polymerization is not expected to occur. Polymerization Continued on Next Page METHANOL Page: 5/7 Special Stability& Not available. Reactivity Remarks Section 11. Toxicological information Component Toxicological Information Acute Animal Toxicity Methanol ORAL (LD50): Acute: 5628 mg/kg [Rat]. 7300 mg/kg [Mouse]. DERMAL(LD50): Acute: 15800 mg/kg [Rabbit]. VAPOR(LC50): Acute: 64000 ppm 4 hour/hours [Rat]. 50000 ppm 4 hour/hours[Mouse]. Chronic Toxicity Data 1) Methanol Methanol is a component of this product. Because methanol is eliminated from the body more slowly than ethanol, it can have cumulative toxicity with repeated exposures(ACGIH, 1992). Acute dermal, oral, and inhalation exposure to methanol can cause Central Nervous System effects, optic nerve effects, diminished vision, and brain effects(necrosis and hemorrhaging). (Bennett, I.L. et al, 1953) Ingestion of methanol can cause Central Nervous System depression, metabolic acidosis, blurred vision and blindness, gastrointestinal effects, and coma and death. (Clayton, G.D. and Clayton, F.E., 1982, Patty's Industrial Hygiene and Toxicology, Vol2C) Dermal exposure to methanol can cause Central Nervous System depression, blurred vision, and gastrointestinal effects. (Downie, A et al, 1992, Occupational Medicine, 42, pp 47-9) Chronic inhalation of methanol can cause Central Nervous System depression, blurred vision, and gastrointestinal effects. (Frederick, L.J. et al, 1984, AIHA Journal, 45, pp 51-5) Chronic inhalation of methanol has caused liver effects in laboratory animals. (Poon, R et al, 1994, Toxocology and Industrial Health 10: 231-245) Chronic oral exposure has caused Central Nervous System effects and eye effects in laboratory animals. [Youssef, A. F. et al (1993) Neurotoxicology and Teratology 15: 223-227; Baumbach, G.L. et al (1977) Archives of Ophthalmology 95: 1859-1865; Hayreh, M.S. et al (1977) Archives of Ophthalmology 95: 1851-1858; Hayreh, M.S. et al (1980) Ocular toxicity of methanol: An experimental study— Raven Press, New York, pages 35-53; and Martin-Amat, G. et al (1977)Archives of Ophthalmology 95: 1847-1850] Methanol has produced in vivo mutagenicity in animal studies. (Pereira, M.A. et al, 1982)and (Ward, J. B. et al, 1983) Methanol was mutagenic in yeast (RTECS). Methanol has caused chromosome aberrations in yeast (RTECS) and grasshoppers (Saha & Khudabaksh, 1974). Methanol has caused birth defects in rats exposed by the oral (Infurna et al, 1981) and inhalation (Nelson et al, 1984; Nelson et al, 1985) routes. Exencephaly (a defect in the skull bone structure that leaves the brain exposed) and cleft palate (a fissure or unformed bone structure in the roof of the mouth (palate), lip, or facial area, occurring during the embryonic stage of development)were increased in fetal mice exposed to methanol at an airborne concentration of 5,000 ppm or higher for 7 hours/day on days 6 to 15 of gestation. Embryotoxicity and fetotoxicity were seen with maternal exposure to airborne concentrations of 7,500 ppm and above, and reduced fetal weights with concentrations of 10,000 ppm or greater. The NOAEL was 1,000 ppm. Effects similar to those seen in the 10,000 ppm dosage group were also seen in offspring of mice given a dose of 4 g/kg orally(Rogers et al, 1993). Product Toxicological Information Acute Animal Toxicity ORAL (LD50): Acute: 5628 mg/kg [Rat]. DERMAL (LD50): Acute: 15800 mg/kg [Rabbit]. VAPOR(LC50): Acute: 64000 ppm 4 hour/hours [Rat]. Target Organs nervous system, gastrointestinal tract, respiratory tract, skin/epithelium, eyes. Other Adverse Effects Not available. IContinued on Next Page 'METHANOL Page: 6/7 Section 12. Ecological Information Ecotoxicity Not available. BOD5 and COD Not available. Biodegradable/OECD Not available. Toxicity of the Products Not available. of Biodegradation Special Remarks Not available. Section 13. Disposal Considerations Responsibility for proper waste disposal rests with the generator of the waste. Dispose of any waste material in accordance with all applicable federal, state and local regulations. Note that these regulations may also apply to empty containers, liners and rinsate. Processing, use, dilution or contamination of this product may cause its physical and chemical properties to change. Additional Waste Not available. Remarks Section 14. Transport Information DOT Classification METHANOL, 3, UN1230, II FLAMMABLE UQthfl 3 DOT Reportable Methanol, 754 gal. of this product. Quantity Marine Pollutant Not applicable. Additional DOT Not available. Information Emergency Response 131 Guide Page Number Section 15. Regulatory Information HCS Classification Target organ effects. Flammable liquid. Irritant. U.S. Federal Regulations Environmental Extremely Hazardous Substances: Not applicable to any components in this product. Regulations SARA 302/304 Emergency Planning and Notification substances: Not applicable to any components in this product. Hazardous Substances(CERCLA 302): Methanol, 754 gal.of this product.; SARA 311/312 MSDS distribution-chemical inventory- hazard identification:fire; immediate health hazard; delayed health hazard; Clean Water Act(CWA) 307 Priority Pollutants: Not applicable to any components in this product. Clean Water Act(CWA) 311 Hazardous Substances: Not applicable to any components in this product. Clean Air Act(CAA) 112(r)Accidental Release Prevention Substances: Not applicable to any components in this product. Continued on Next Page METHANOL Page: 7/7 Threshold Not applicable. Planning Quantity(TPQ) TSCA Inventory All components are included or are exempted from listing on the US Toxic Substances Control Status Act Inventory. This product does not contain any components that are subject to the reporting requirements of TSCA Section 12(b) if exported from the United States. State Regulations State specific information is available upon request from Baker Petrolite. International Regulations Canada All components are compliant with or are exempted from listing on the Canadian Domestic Substance List. WHMIS (Canada) B-2, D-1 B, D-2A, D-2B European Union All components are included or are exempted from listing on the European Inventory of Existing Commercial Chemical Substances or the European List of Notified Chemical Substances. International inventory status information is available upon request from Baker Petrolite for the following countries:Australia, China, Korea (TCCL), Philippines(RA6969), or Japan. Other Regulatory No further regulatory information is available. Information Section 16. Other Information Other Special File 973 Considerations 06/19/03- Changes to Sections 1, 2, 3, 5, 8, 9, 14, and 15 06/10/04- Changes to Section 8. 01/31/06- Changes to Sections 2, 3, 5, 8, 9 and 15. In April, 2005, a number of format changes were made. The most notable of these were switching Sections 2 and 3, moving the exposure limits to Section 8, and moving the flash point from Section 5 to Section 9. Baker Petrolite Disclaimer NOTE: The information on this MSDS is based on data which is considered to be accurate. Baker Petrolite, however, makes no guarantees or warranty, either expressed or implied of the accuracy or completeness of this information. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of this product. This MSDS was prepared and is to be used for this product. If the product is used as a component in another product, this MSDS information may not be applicable. B Bill Barrett Corporation SAFETY DATA SHEET PRODUCED WATER SECTION 1 -PRODUCT IDENTIFICATION PRODUCT NAME: PRODUCED WATER MANUFACTURER/DISTRIBUTOR BILL BARRETT CORPORATION SYNONYMS PRODUCTION WATER 1099 18TH ST.,STE. 2300 SALT WATER DENVER,CO 80202 SALT WATER BRINE (303) 293-9100 FORMATION WATER EMERGENCY PHONE NUMBERS: CHEMTREC CAS# MIXTURE 1-800-424-9300 REVISION DATE: 12-27-2012 RECOMMENDED USE: NONE, WASTE SECTION 2 -HAZARDS IDENTIFICATION Hazard Classification: Flammable Liquid Hazard Category 4—Mixture is predominantly water but may contain flammable hydrocarbon liquids and vapors Health Hazard: Skin Irritation Category 3 Eye Irritation Category 2B Carcinogenicity Category IA—mixture may contain benzene. Human epidemiology studies indicate that prolonged and/or repeated overexposure to benzene may cause damage to the blood-producing system and serious blood disorders, including leukemia. Respiratory Irritation Category 3 Reproductive Toxicity Category 2-mixture may contain benzene. Animal testing suggests that that prolonged and/or repeated overexposure to benzene may damage the embryo/fetus. Environmental Hazard: Acute Aquatic Toxicity—Unclassified Chronic Aquatic Toxicity-Unclassified GHS Label Elements: • Page 1 of 7 PRODUCED WATER Revision Date:12-27-12 B Bill Barrett Corporation SAFETY DATA SHEET Signal Word: DANGER! Hazard Statements: Danger! Flammable liquid. Keep away from heat/sparks/open flame. Wear protective gloves and eye/face protection. Breathing the mist may be irritating to the respiratory tract. May cause temporary eye and skin irritation. Product may contain a small amount of hydrocarbons with a trace amount of benzene which may cause cancer and heritable genetic damage. OSHA Regulatory Status: This produce is hazardous according to OSHA 29CFR 1910.1200 SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL NAME CAS# CONCENTRATION* Water 7732-18-5 80-95% Calcium chloride 10043-52-4 0-20% Potassium chloride 7447-40-7 0-20% Sodium chloride 7647-14-5 0-20% Benzene 71-43-2 0.1-1% Petroleum hydrocarbons 8002-05-9 <1% *MAY CONTAIN SMALL AMOUNTS OF CONDENSATE OR CRUDE OIL AS A CONTAMINANT. ALL CONCENTRATIONS ARE IN PRECENT BY WEIGHT UNLESS INGREDIENT IS A GAS. GAS CONCENTRATIONS ARE IN PERCENT BY VOLUME. SECTION 4-FIRST AID MEASURES Inhalation: If symptomatic, move to fresh air. Seek medical attention if symptoms persist. Skin Contact: Remove contaminated clothing and shoes. Wash skin with soap and water. Seek medical attention if symptoms occur. Eye Contact: Any materials that contact the eye should be washed out immediately with water. If easy to do so, remove contact lenses. Flush for a minimum of 15 minutes and seek medical attention if symptoms persist. Ingestion: First aid is normally not required. However, if greater than% liter(pint)ingested, seek medical attention. Do not give fluid or induce vomiting. SECTION 5 -FIREFIGHTING MEASUREs Bulk of product is water and will not ignite. However,sufficient hydrocarbon and hydrocarbon vapor may be present on the surface of the liquid and/or in the headspace of a tank to cause a flash fire. Suitable Extinguishing Media: Extinguish with foam,dry powder,water fog or carbon dioxide. Unsuitable Extinguishing Media: Water should not be used directly on burning liquid. Water should be used to cool adjacent tanks and vessels. Not Applicable Special Fire Fighting Procedures: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fight fire from upwind direction whenever possible. If safe to do so,cut off supply and allow flame to burn out. Hazardous Combustion Products: Carbon oxides Page 2 of 7 PRODUCED WATER Revision Date:12-27-12 B Bill Barrett Corporation SAFETY DATA SHEET SECTION6-ACCIDENTAL RELEASE MEASURES Personal Precautions: Keep away from sources of ignition, no smoking. Stay upwind and keep unneccesary personnel away. Wear protective clothing as described in Section 8 of this data sheet Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not allow to enter drains, sewers or waterways. Methods for Containment Stop the flow of material if safe to do so. Dike spilled material with non-combustible material like vermiculite,sand or earth to prevent entry into a drain, sewer, or water way. Methods for Cleaning Up: Recover free liquid by pumping with an explosion-proof pump or hand pump. Soak up the product using dirt,sand, vermiculite or other appropriate absorbent and place into a container for later disposal. Other Information: Ensure work area is adequately ventilated and avoid excess skin contact with spilled material. SECTION 7-HANDELING AND STORAGE Handling: Handle as a flammable liquid. Tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, discharging and sampling from storage tanks. Bond and ground containers during product transfer to reduce the possibility of static-initiated fire or explosion. Keep away from heat, sparks, and open flame. Electrical equipment should be approved for classified area.Wear appropriate personal protective equipment(see section 8). Smoking, eating or drinking should be prohibited when working with the equipment. Workers should wash thoroughly with soap and water and discard contaminated clothing after entering or handling the equipment. Workers should wash hands and face before eating, drinking and smoking. Storage: Keep containers in well-ventilated area away from flame, sparks, excessive temperatures and open flames. Keep the containers closed and clearly labeled. Empty product containers or vessels may contain explosive vapors. Do not pressurize, cut, heat,weld or expose such containers to sources of ignition. Do not enter storage areas and confined spaces without adequate ventilation. Use appropriate respiratory protection if there is the potential to exceed the exposure limit(s).Vapors containing benzene may accumulate during storage and transport. SECTION 8-EXPOSURE CONTROLS/PERSONAL PROTECTION Chemical Name Source Type Exposure Limits Notes Benzene ACGIH STEL 2.5 ppm TWA 0.5 ppm OSHA Ceiling 25 ppm STEL 5 ppm TWA 1 ppm Petroleum NIOSH IDLH 1100 ppm Engineering Controls: Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable)or to an acceptable level (in Page 3 of 7 PRODUCED WATER Revision Date:12-27-12 Bill Barrett Corporation SAFETY DATA SHEET countries where exposure limits have not been established), an approved respirator must be worn. If respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, 1998. Respirator type: Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Contact health and safety professional or manufacturer for specific information. Eye Protection: Risk of contact: Wear approved safety goggles. Hand Protection: It is a good industrial hygiene practice to minimize skin contact. If skin contact cannot be avoided nitrile gloves should be worn. If dermal contact is expected for a prolonged period of time gloves should be upgraded to Viton. Skin Protection: Normal working clothing should be worn. Wash contaminated clothing prior to rescue or after use. Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. SECTION 9- PHYSICAL AND CHEMICAL PROPERTIES Property Characteristic Color: Brown to yellow Odor: Faint hydrocarbon Physical State: Liquid pH: 4.9-8.5 Melting Point: Not available Freezing Point: <0° (32°F) Boiling Point: 100°C(212°F) (Approximate) Flash Point: No data available Flammability(Solid): Not applicable Flammability Limit—Upper(%) Not applicable Flammability Limit—Lower(%) Not applicable Evaporation Rate No date available Vapor Pressure: 13.6 mmHg @20°C Vapor Density(Air=1) <1 Specific Gravity >1 (4°C) Solubility in Water: Soluble Solubility(Other): No Data Available Partition Coefficient(n- No Data Available Octanol/water): Autoignition Temperature: No Data Available Viscosity: No Data Available Explosive Properties: No Data Available SECTION 10 - STABILITY AND REACTIVITY Stability: Stable under the prescribed storage conditions Conditions to Avoid: Keep away from heat, sparks, and open flame. Page 4 of 7 PRODUCED WATER Revision Date:12-27-12 Bill Barrett Corporation SAFETY DATA SHEET Incompatible Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon dioxide, impartial combustion may generate carbon monoxide. SECTION 11 -TOXICOLOGICAL INFORMATION Components Chemical Name Test Results Calcium chloride(10043-52-4) Acute Oral LD50 Rat: 1000 mg/kg Acute Other LD50 Mouse: 42 mg/kg Potassium Chloide (7447-40-7) Acute Oral LD50 Rat: 2600 mg/kg Benzene (71-43-2) Acute Inhalation LC50 Mouse: 9980 mg/I Acute Inhalation LC50 Rat: 10000 mg/I 7 Hours Acute Oral LD50 Mouse: 4700 mg/kg Acute Oral LD50 Rat: 3306 mg/kg Acute Other LD50 Mouse: 340 mg/kg Acute Other LD50 Mouse: 0.000001 ml/kg Acute Other LD50 Rat: 2.89 mg/kg Petroleum Acute Oral LD50 > (Rat):4300 mg/kg Exposure is most likely via inhalation of vapors or dermal contact. Symptoms of exposure may include skin irritation, irritation of eyes, nose and throat, dizziness, and drowsiness. Contact with eyes may cause severe irritation. SECTION 12 - ECOLOGICAL INFORMATION Components Chemical Name Test Results Calcium chloride (10043-52-4) EC50 Water flea (Daphnia magna): 52 mg/I 48 hours LC50 Fathead minnow(Pimephales promelas): 3930- 5360 mg/I 96 hours Potassium Chloide (7447-40-7) EC50 Water flea (Daphnia magna): 83 mg/I 48 hours LC50 Western mosquitofish (Gambusia affinis):435 mg/I 96 hours Sodium Chloride(7647-14-5) EC50 Water flea (Daphnia magna): 340.7 -469.2 mg/I 48 hours LC50 American eel (Anguilla rostrata): 0 -27260 mg/I 96 hours Benzene (71-43-2) EC50 Water flea (Daphnia magna): 8.76 - 15.6 mg/I 48 hours EC50 Water flea (Daphnia magna): 8.76 - 15.6 mg/I 48 Hours LC50 Rainbow trout,donaldson trout(Oncorhynchus mykiss): 5 mg/I 96 Hours Mobility: No data available. Persistence and Degradability: No data available. Page 5 of 7 PRODUCED WATER Revision Date:12-27-12 B Bill Barrett Corporation SAFETY DATA SHEET Bioaccumulation Potential: No data available. SECTION 13 -DISPOSAL CONSIDERATIONS General Information: This product, in its present state,when discarded or disposed of, is not a hazardous waste according to Federal regulations(40 CFR 261.4(b)(4)).Dispose of waste and residues in accordance with local authority requirements. Disposal Methods: No specific disposal method required. Since emptied containers retain product residue, follow label warnings even after container is emptied. SECTION 14-TRANSPORT INFORMATION DOT: Not regulated. TDG: Not regulated. IATA: Not regulated. IMDG: Not regulated. SECTION 15 -REGULATORY INFORMATION WHMIS Classification: This is not a WHMIS controlled product. This product or all components are listed or exempt from listing on the following inventory: TSCA US Federal Regulations CERCLA Hazardous Substance List(40 CFR 302.4): Not regulated. SARA Title III Section 302 Extremely Hazardous Substances(40 CFR 355,Appendix A): Not regulated. Section 311/312(40 CFR 370): X Acute(Immediate)Chronic(Delayed) Fire Reactive Pressure Generating Section 313 Toxic Release Inventory(40 CFR 372): Not regulated. Clean Air Act(CAA)Section 112(r)Accidental Release Prevention (40 CFR 68.130): Not regulated. Clean Water Act Section 311 Hazardous Substances(40 CFR 117.3): Not regulated. Drug Enforcement Act: Not regulated. TSCA TSCA Section 4(a) Final Test Rules&Testing Consent Orders: Not regulated. TSCA Section 5(a)(2) Final Significant New Use Rules(SNURs)(40CFR 721, Subpt. E): Not regulated. TSCA Section 5(e)PMN-Substance Consent Orders: Not regulated. TSCA Section 12(b)Export Notification (40 CFR 707, Subpt. D): Not regulated. State Regulations California Safe Drinking Water and Toxic Enforcement Act of 1986(Proposition 65): Not regulated. Massachusetts Right-To-Know List: Petroleum Michigan Critical Materials List(Michigan Natural Resources and Environmental Protection Act(Act.451 of 1994)): Not regulated. Minnesota Hazardous Substances List: Petroleum New Jersey Right-To-Know List: Petroleum Page 6 of 7 PRODUCED WATER Revision Date:12-27-12 B Bill Barrett Corporation SAFETY DATA SHEET Pennsylvania Right-To-Know List: Petroleum Rhode Island Right-To-Know List: Petroleum 16- OTHER INFORMATION HAZARD RATINGS Health Hazard Fire Hazard Instability Special Hazard NFPA 1 1 0 NONE Hazard rating:0-Minimal;1-Slight;2-Moderate;3-Serious;4-Severe NFPA Label colored diamond code:Blue-Health;Red-Flammability;Yellow-Instability;White-Special Hazards Health Hazard Flammability Physical Hazard Personal Protection HMIS 1 1 0 -- Hazard rating:0-Minimal;1-Slight;2-Moderate;3-Serious;4-Severe HMIS Label colored bar code:Blue-Health;Red-Flammability;Orange-Physical Hazards;White—Special Issue Date:12-27-2012 Disclaimer:This information is provided without warranty.The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment. SDS DATE:12-27-12 SDS UPDATE:12-27-12 SDS PREPARED BY Bill Barrett Corp Page 7 of 7 PRODUCED WATER Revision Date:12-27-12 U.S. DEPARTMENT OF LABOR OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION MATERIAL SAFETY CRUDE OIL DATA SHEET IDENTITY (As Used on Label and List): Crude Oil SECTION I Manufacturer's Name: Bill Barrett Corporation 303-293-9100 Denver,CO Address: 1099 18th St., Suite 2300 City, State ZIP: Denver,CO 80202 Date Prepared: October 08,2002 SECTION II - Hazardous Ingredients/Identity Information Other Limits Hazardous Components %(Optional) OSHA PEL ACGIH TLV Recommended Hydrocarbons (aromatic& paraffinic) n/a 3000 ppm** n/a **TLV for gasoline Benzene 1 ppm * 10 ppm n/a * Short Term Exposure Limit (STEL) 5 ppm/averaged over any 15 minute period Hydrogen Sulfide 10 ppm * 10 ppm n/a * 50 ppm peak/10 minutes once only, if no other measurable exposure occurs STEL: 15 ppm WARNING: Flammable. Can cause skin irritation on prolonged or repeated contact. Vapor harmful. May give off sulfur containing gases. Cancer hazard. Harmful or fatal if liquid aspirated into lungs. SECTION III - Physical/Chemical Characteristics Boiling Point: n/a Specific Gravity (H2O = 1): 0.75 to 1 Vapor Pressure (mm Hg.): n/a Melting Point: n/a Vapor Density (AIR = 1): > 1 Evaporation Rate (Butly Acetate = 1) n/a Solubility in Water: Negligible, below 0.1% Appearance and Odor: Yellow to dark brown liquid. Typical petroleum odor. Page 1 SECTION IV-Fire and Explosion Hazard Data Flash Point (Method Used): Flammable-flash point varies widely Flammable Limits- % by volume Lower Explosive Limit (LEL): 5% (-45° F) Upper Explosive Limit (UEL): 40% (200° F) Extinguishing Media: Dry chemicals, carbon dioxide, foam, steam or water fog. Special Fire Fighting Procedures: Firefighters should wear positive pressure, self contained breathing apparatus. Run-off to sewer may cause a fire or explosion hazard. Unusual Fire and Explosion Hazards: Vapor may explode if ignited in enclosed area. Product gives off vapors that are heavier than air which can travel considerable distances to a source of ignition and flashback. SECTION V-Reactivity Data Stability: Stable Conditions to avoid: n/a Incompatibility (Materials to Avoid): Keep out of sewers and waterways.Avoid strong oxidizers. Hazardous Decomposition or Byproducts: Burning can produce carbon monoxide and/or carbon dioxide and other harmful products. Hazardous Polymerization: Will not occur. Conditions to Avoid: n/a SECTION VI - Health Hazard Data Route(s) of Entry: Inhalation?: Yes Skin?: Yes Ingestion?: No Health Hazards (Acute and Chronic): Skin irritation on prolonged contact. Irritant to eyes. Carcinogenicity: NTP?: No IARC Monographs?: No OSHA Regulated?: No Signs and Symptoms of Exposure: Skin irritation, dermatitis. Eye Irritation. Medical Conditions Generally Aggravated by Exposure: Dermatitis or other chronic skin conditions. Page 2 Emergency and First Aid Procedures: Flush eyes with plenty of water. Wash exposed skin with plenty of soap and water. SECTION VII -Precautions for Safe Handling and Use Steps to be Taken in Case Material Is Released or Spilled: Isolate area. Use appropriate protective equipment. .. Remove or shut off all sources of ignition. .. Shut off leaking valves or containers only if safe to do so. .. Contain and remove by mechanical means. Waste Disposal Method: Disposal must be in accordance with applicable Federal, State and local regulations. Determine waste classification at time of disposal. Enclosed controlled incineration is recommended. Precautions to Be Taken in Handling and Storing: Avoid skin contact. Wear protective clothing and gloves. Use eye protection. Other Precautions: Wash thoroughly after handling. SECTION VIII -Control Measures Respiratory Protection (Specify Type): Use NIOSH-MSHA approved positive pressure self contained breathing apparatus. Ventilation - Local Exhaust: Work with product in well ventilated areas only Special: n/a Mechanical (General): NFPA Class 1, Division 1, Group D, electrical Other: n/a Protective Gloves: Use rubberized material to prevent breakthrough Eye Protection: Safety glasses with side-shields, face shield or splash goggles Other Protective Clothing or Equipment: Rubberized boots, aprons or coveralls should be worn to prevent skin contact. Work/Hygienic Practices: Use eye protection and protective gloves, work in well ventilated area. Wash hands after handling product. Soiled clothing should be removed and laundered. Page 3 Product#: 345280 Name: ARCTICTHERM®E50 Desa BULK From: BRENNTAGPACIFIC INC. To: Friday,January 04,2013 MATERIAL SAFETY DATA SHEET page of BRENNTAGa NF PA 704 DESIGNATION Fire HAZARD RATING Health Brenntag MSDS#: BPI-00575 3_H me ig 1 2=Iv)oderate Reactivity I MSDS Revision/Issue Date: 05124/11 1—Slight -- Supercedes Revision Date: New 0-Insignificant Special 1. CHEMICAL PRODUCT IDENTIFICATION & COMPANY IDENTIFICATION PRODUCT IDENTIFIER: ArcticTherm''' E-50 GENERAL USE: A heat transfer fluid containing corrosion inhibitors for aqueous heat exchange systems. PRODUCT DESCRIPTION: An inhibited Ethylene Glycol solution. Synonyms include: 1,2-dihydroxyethane, 1,2-ethanediol, ethylene alcohol, ethylene dihydrate, glycol, glycol alcohol, M.E.G. and monoethylene glycol. INFORMATION PROVIDED BY: Brenntag Pacific,Inc. EMERGENCY PHONE NUMBERS 10747 Patterson Place Santa Fe Springs,CA 906/0 CHEMTREC: 800-424-9300 For MSDS call: PHONE: 562-903-9626 2. COMPOSITION & INFORMATION ON INGREDIENTS ACGIH OSHA. cOMPONE3k1T CAS# OSHA HAZARD WT% TLVavrA7 STEL PELITyvA° STEL Ethylene Glycol 107-21-1 Eye,Skin&Respiratory 50±3 None None None None Irritant; Kidney, Liver, Cardiovascular&Central Ceiling: Nervous System toxin 100 mg/m.3 (aerosols) (A4) ND/\-Na Duda Available N/A=Not Applicable 3. HAZARDS IDENTIFICATION EMERGENCY A clear, reddish orange liquid having a slight characteristic odor. The vapors, mists and liquid are moderately OVERVIEW: irritating to the eyes, skin and respiratory tract. It is toxic by ingestion_ (The Ethylene Glycol lethal oral dose for humans is reported to be about 100 ml.) POTENTIAL HEALTH EFFECTS INHALATION: Inhalation of vapors, mists or aerosols may be moderately irritating to the nose, throat, mucous membranes and lungs. Symptoms of exposure may include sneezing, coughing, nausea, vomiting, headache, dizziness and other central nervous system effects. Ethylene Glycol may be very toxic, in particulate form, upon inhalation. EYE CONTACT: Exposure to the vapors, mists or liquid may cause eye irritation. Symptoms of exposure may include tearing, redness, swelling and a painful stinging / burning sensation. Exposure is not expected to cause corneal damage or visual impairment, when promptly treated. SKIN CONTACT: Exposure to the mists or liquid may cause moderate skin irritation. Symptoms of exposure may include redness, swelling and a stinging sensation. Exposure to this product may cause an allergic skin reaction. This product is not expected to be absorbed through the intact skin in harmful amounts. INGESTION: Ingestion may cause mild to moderate irritation to the entire gastrointestinal tract. Symptoms of exposure may include abdominal pain, nausea, vomiting, dizziness, drowsiness and other symptoms related to central nervous system depression and a narcotic effect. Later, it can cause liver changes and potentially lethal kidney damage. CHRONIC: The chronic health effects associated with prolonged or repeated exposure to this product may include kidney, central nervous system and heart damage. Repeated skin contact may, in a very small proportion of cases, cause sensitization with the development of an allergic contact dermatitis. IMPORTANT: While Brenntag believesthe information containedhereintobexro rat e,Brenntag nakesno representation or warranty,express or implied,regarding,and assumes no liability for,the awaraj or con,leteness ofthe information. The Buyer assunes all responsibility for handling,using and/or reselling the Product in accordance with the applicable federal,state,and local law.This MSDS shall not in any way limit or preclude the operation and effect of any ofthe provisions of Brenntag's terror and conditions of sale. Product#: 345280 Name: ARCTICTHERM®E50 Des: BULK From: BRENNTAGPACIFIC INC. To: Friday,January 04,2013 PRODUCT IDENTIFIER: ArcticTherm E-50 page 2 of 6 4. FIRST AID MEASURES INHALATION: If inhaled, immediately move to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Call a physician. EYE CONTACT: In case of contact, immediately flush eyes with plenty of clean running water for at least 15 minutes, lifting the upper and lower lids occasionally. Remove contact lenses, if worn. Get medical attention if irritation persists. SKIN CONTACT: In case of contact, flush skin with plenty of clean running water. Remove contaminated clothing and shoes and wash before reuse. If irritation occurs and persists, get medical attention. INGESTION If large quantities of this product are swallowed, call a physician immediately. Induce vomiting, as directed by medical personnel. Never give anything by mouth to an unconscious person. NOTE TO PHYSICIANS: The recommended treatment for Ethylene Glycol poisoning includes elimination of Ethylene Glycol and metabolites, correction of metabolic acidosis and prevention of kidney injury. A continuous infusion of a 5% Sodium Bicarbonate solution with frequent monitoring of electrolytes and fluid balance is used to achieve correction of metabolic acidosis and forces diuresis. 5. FIRE FIGHTING MEASURES Flashpoint and Method: Greater than 93.30 C. (200O F.) Tagliabue Closed Tester (ASTM D 56-79) Flammable Limits(in air,%by volume) Lower: Not determined Upper: Not determined Autoignition Temperature: Not determined GENERAL HAZARD: This product is an aqueous, inhibited glycol solution. This product is not a combustible liquid per OSHA or WHMIS criteria, but it can ignite at elevated temperatures and it will burn. The Uniform Fire Code physical hazard classification for this product is: Combustible Liquid, Class III-B. When heated, this product may produce hazardous fumes or hazardous decomposition products. FIRE FIGHTING INSTRUCTIONS: EXTINGUISHING MEDIA: Water fog,foam, CO2 or dry chemical. Use a water spray or fog to cool the containers exposed to the heat of a fire. FIRE FIGHTING EQUIPMENT: Fire fighters should wear full protective equipment, including self-contained breathing apparatus. HAZARDOUS COMBUSTION PRODUCTS: When heated to dryness and decomposition, it emits toxic carbon monoxide, carbon dioxide, phosphorus oxides, nitrogen oxides, sulfur oxides, potassium oxide, sodium oxide, boron oxide and molybdenum oxide plus irritating smoke. 6. ACCIDENTAL RELEASE MEASURES LAND SPILL: Wearing recommended protective equipment and clothing, dike the spill and pick up the bulk of liquid using pumps or a vacuum truck, or absorb the liquid in sand or a commercial absorbent. Place in approved containers for recovery, disposal, or satellite accumulation. Neutralize the alkalinity, of the remaining liquid, using a dilute acid solution appropriate for neutralizing alkaline liquids. Liberally cover the spill area with sodium bicarbonate. Flush the spill area with water; collect the rinsates for disposal or sewer, as appropriate. WATER SPILL: Wear recommended protective equipment and clothing if contact with hazardous material can occur, Stop or divert water flow. Dike contaminated water and remove for disposal and/or treatment. As appropriate, notify ail downstream users of possible contamination I lIPORTAITI ciuita v lv tic a,,uiatc.Biciuila 11kI .Jlly lcpicJcutatiunvl V\at!ally,ciplwo or impl ied,regarding,and assurms no liability for,the accuracy or cotnpletenessofthe information. The Buyer assimesall responsibility for handling,using and/or reselling the Product in accordance with the applicable federal,state,and local law.This MSDSshall not in any way limit or preclude the operation and effect of any of the provisions of Brenntag's terms and conditions of sale. Product#: 345280 Name: ARCTICTHERM®E50 Des: BULK From: BRENNTAGPACIFIC INC. To: Friday,January 04,2013 PRODUc r IDENTIFIER: ArcticTherrn E-50 page s of 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient STORAGE PRESSURE: Ambient GENERAL; Store in a cool, dry,well-ventilated area away from incompatible materials and products. Protect eyes, skin, and clothing from contact with this product. Wear recommended protective equipment. Avoid breathing vapors, mists or aerosols. Use with adequate ventilation. Keep the containers tightly closed when not in use. Wash thoroughly after handling this product. The empty containers may be hazardous. They may contain organic residues that can be ignited and will burn. Do not cut, puncture, drill or weld on or near the empty containers. 8. EXPOSURE CONTROLS /PERSONAL PROTECTION CONTROL Use a local or general, mechanical exhaust ventilation system if emissions, in the work area, are above the MEASURES: ACGIH Ceiling level for Ethylene Glycol. RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT RESPIRATOR: Respiratory protection is not normally required when this product is used as directed. If emissions in the work area are above the ACG1H Ceiling level or may cause irritation, wear a NIOSH-approved full facepiece or half mask respirator equipped with a good mist/particulate and organic vapor cartridges, or supplied air. EYES: Wear chemical goggles (recommended by ANSI Z87 1-1979). GLOVES: Wear Neoprene or Butyl Rubber gloves. CLOTHING& Wear a Neoprene or Butyl Rubber apron when handling this product. An eye wash station should be available EQUIPMENT: in the work area. FOOTWEAR: Wear Neoprene or Butyl Rubber boots, if contact is likely. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear, reddish orange Bulk Density(poundsnta): Not applicable Physical State: Liquid Vapor Pressure: About 0.5 mm Hg @ 20° C. Odor: Slight characteristic odor Vapor Density(air=s): 2.1 (100%Ethylene Glycol) Odor Threshold: No data available Evaporation Rate(n-Butyl Acetate=1): Less than 1 Molecular Formula: Mixture VOC Content: Approximately 529 grams/Liter Molecular Weight: Not applicable %Volatile: Approximately 98 Boiling Point: Greater than 100° C. (212° F.) Solubility in H2O: Complete Freezing/Melting Point: Less than-17.7*C. (0°F.) Octanol/Water Partition Coefficient: No data available Specific Gravity: Approximately 1.068 a 20°C. pH(as is): 9.9 to 10.9 Density{poundslgaiion}: Approximately 8.91 pH(1%solution): 9.3 to 10.2 10. STABILITY AND REACTIVITY GENERAL: This product is stable and hazardous polymerization will not occur. CONDITIONS TO AVOID: None known INCOMPATIBLE MATERIAL: Strong oxidizing&reducing agents and materials reactive with hydroxyl compounds. HAZARDOUS DECOMPOSITION PRODUCTS: When heated to dryness and decomposition, it emits toxic oxides of carbon, phosphorus, nitrogen, sulfur, potassium, sodium, boron and molybdenum plus irritating smoke. SENSITIVITY TO MECHANICAL IMPACT: This product is not sensitive to mechanical impact. SENSITIVITY TO STATIC DISCHARGE: This product is not sensitive to static discharge. IMPORTANT: While Brennt believes the information containe d herein to be accurate,Brenntag makes no representation or warranty,express or impl ied,regarding,and assurms no liability for,the accuracy or completeness of the information. The Buyer assunes all responsibility for handling,using andior reselling the Product in accordance with the applicable federal,state,and local law.This MSDSshall not in any way limit or preclude the operation and effect of any of the provisions of Brenntag's terms and conditions of sale. Product#: 345280 Name: ARCTICTHERM®E50 Des: BULK From: BRENNTAGPACIFIC INC. To: Friday,January 04,2013 PRODUCT IDENTIFIER: ArcticTherrn E-50 page 4 of 5 11 TOXICOLOGICAL INFORMATION Components: Ethylene Glycol Eye Contact: Rabbit:500 mg/24 hours: Mild Skin Contact: Rabbit:555 mg open; Mild Oral Rat LD5o: 4,700 mg/kg Dermal Rabbit LD5u: 9,539 uUkg Inhalation Rat LC5o: 10.876 mg/kg Human Data: Oral Human LDLp:398 mg/kg;Central Nervous System,Gastrointestinal& Liver effects Other ToxIcological Data: Inhalation Human TCLo: 10,000 mg/m' Carcinogenicity: No data available Teratogenicity: Oral Rat TDB,:8,580 mg/kg(female 8-15 Days pregnant)Effects on Embryo or Fetus—Fetotoxicity;Specific Developmental Abnormalities—Musculoskeletal system Mutagenicity: Human DNA Inhibition;lymphocyte:320 mmol/Liter Synergistic Products: None reported Target Organs: Eyes, Skin,Mucous membranes, Lungs,Liver,Kidneys, Cardiovascular&Central Nervous Systems Medical Conditions Aggravated By Exposure: Skin, Respiratory, Liver,Kidney or Heart disorders 12. ECOLOGICAL INFORMATION ENVIRONMENTAL FATE: The environmental fate of this product is expected to be: Land: biodegradation with some leaching into the groundwater. Water: biodegradation. Air: not expected to volatilize due to low vapor pressure. This product is not expected to bioaccumulate. ENVIRONMENTAL CONSIDERATIONS: The aquatic toxicity for Ethylene Glycol is: Rating 1 (TLM96: 1,000 to 100 ppm). LC 50(24 hours)to goldfish: Greater than 5,000 mg/liter. Toxicity threshold for Scenedesmus quadricauda(green algae)is Greater than 10,000 mg/liter. Toxicity threshold for Entosiphon sulcatum(protozoa) is Greater than 10,000 mgfliter. 13. DISPOSAL CONSIDERATIONS RCRA 40 CFR 261 CLASSIFICATON: Non-Hazardous Waste U.S.EPA WASTE NUMBER/DESCRIPTION: Not applicable If this product is disposed of as shipped, it does not meet the criteria of a hazardous waste as defined under 40 CFR 251, in that it does not exhibit the characteristics of hazardous waste of Subpart C, nor is it listed as a hazardous waste under Subpart D As a non-hazardous liquid waste, it should be disposed of in accordance with all local, state and federal regulations. Consult state or local officials for proper disposal method. 14. TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME: Not Restricted(In non-bulk); Bulk(in containers greater than 1,122.7 gallons)See"Other Shipping Information", Hazard Class: Not applicable UN Number: Not applicable Packing Group: Not applicable Primary Label: None Required Subsidiary Label(s): None Required Primary/Subsidiary Placards: None Required DOT Reportable Quantity(RU): 5,00D pounds (Ethylene Glycol) RQ for Product= 10.000 pounds (1,122.7 gallons) Marine Pollutant: No 2008 North American Emergency Response Guidebook No.: Not applicable (In containers holding more than 1,122.7 gallons= 171) TDG PROPER SHIPPING NAME: NOT RESTRICTED Hazard Class: Not applicable UN Number: Not applicable Packing Group: Not applicable Primary Label: None Required Subsidiary Label(s): None Required Primary/Subsidiary Placards: None Required TDG Reportable Quantity(RU):a Not applicable TDG Schedule XII: Not applicable Regulated Limit(RL):us Not listed RL for Product: Not applicable Other Shipping Information: RQ,Environmentally hazardous substances,liquid,n.o.s.(Ethylene Glycol),9,UN3082,PG III. # Canadian Transportation of Dangerous Goods Regulations(TDGR),Part IX,Table I,Quantities or levels for Immediate Reporting:releases of reportable quantities.RQ, that meet the definition of a"dangerous occurrence"(a lhreal to life,health,property,or the environment)mrrt he reported to the appropriate authorities as outlined in TDGR 9.13(1)and 9.14(1). tf# Reporting to Environment Canada is required for any releases exceeding the regulated limits, RL,of 9.2 materials(primary or secondary). The regulated limits are found in Schedule XIII of the TDGR. IMPORTANT: While Brennt believes the information containe d herein to be accurate,Brenntag makes no representation or warranty,express or impl ied,regarding,and assurms no liability for,the accuracy or completeness of the information. The Buyer assunes all responsibility for handling,using andior reselling the Product in accordance with the applicable federal,state,and local law.This MSDSshall not in any way limit or preclude the operation and effect of any of the provisions of Brenntag's terms and conditions of sale. Product#: 345280 Name: ARCTICTHERM®E50 Des: BULK From: BRENNTAGPACIFIC INC. To: Friday,January 04,2013 PRODUC r IDENTIFIER: ArcticTherrn E-50 page 5 of 15. REGULATORY INFORMATION COMPONENTS: Ethylene Glycol OSHA Target Organs: Eyes, Skin,Mucous membranes, Lungs, Liver, Kidneys,Cardiovascular& Central Nervous System Carcinogenic Potential: Regulated by OSHA: No Listed on NTP Report: No Listed by IARC: No IARC Group: Not listed ACGIH Appendix A: Not listed Al Confirmed Human: Not applicable A2 Suspected Human: Not applicable U.S. EPA Requirements Release Reporting CERCLA (40 CFR 302) Listed Substance: Yes Reportable Quantity: 5,000 pounds Category: D RCRA Waste No None listed Unlisted Substance: Not applicable Reportable Quantity: Not applicable Characteristic: Not applicable RCRA Waste No.. Not applicable SARA TITLE III Section 302&303(40 CFR 355): Listed Substance: Not listed Reportable Quantity: Not applicable Planning Threshold. Not applicable Section 311&312(40 CFR 370): Hazard Categories(product): Fire: N Sudden Release of Pressure: N Reactive: N Acute Health: Y Chronic Health: Y Planning threshold: 10,000 pounds Section 313(40 CFR 312): Listed Toxic Chemical: Yes Reporting Threshold: 10,000 pounds U.S.TSCA Status Listed(40 CFR 710): Yes State Regulations State of California: Safe Drinking Water and Toxins Enforcement Act,198e(Proposition 85): Carcinogen: No Reproductive Toxin: No Other Regulations State Right To Know Laws: MA, NJ,PA,CA Canadian Regulations Product Information: Controlled Product: Yes WHMIS Hazard Symbols: Material Causing Other Toxic Effects WHMIS Class& Division: D.2A; D.2B Ingredient Information: IDL Substance: Yes DSL or NDSL Lists: DSL IMPORTANT: While Brennt believes the information containe d herein to be accurate,Brenntag makes no representation or warranty,express or impl ied,regarding,and assurms no liability for,the accuracy or completeness of the information. The Buyer assunes all responsibility for handling,using and/or reselling the Product in accordance with the applicable federal,state,and local law.This MSDSshall not in any way limit or preclude the operation and effect of any of the provisions of Brenntag's terms and conditions of sale. Product#: 345280 Name: ARCTICTHERM®E50 Des: BULK From: BRENNTAGPACIFIC INC. To: Friday,January 04,2013 PRODUCT IDENTIFIER: ArcticTherrn E-50 page 6 of 6 16. OTHER INFORMATION EPA Registration number: Not applicable Approved Product Uses: Not applicable Special Notes: This product is not formulated or manufactured to contain any material, which the State of California has found to cause cancer and/or birth defects or other reproductive harm. Note: Ethylene Glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by lavage or in drinking water at high concentrations or doses. Ethylene Glycol should be regarded as an animal teratogen. There is currently no available information to suggest that Ethylene Glycol has caused birth defects in humans. Two chronic feeding studies, using rats and mice, have not produced any evidence that Ethylene Glycol causes dose-related increases in tumor incidence or a different pattern of tumors compared with untreated controls. Numerous in vitro genotoxicity studies showing that it does not produce mutagenic or clastogenic effects have supported the absence of a carcinogenic potential for Ethylene Glycol. Special Instructions: Store in a cool, dry,well-ventilated area away from incompatible materials and products. The empty containers may be hazardous. they may contain organic residues that can be ignited and will burn. Do not cut, puncture, drill or weld on or near these containers. MSDS Revision Information: Information Revised This Issue Date: New product MSDS. Form Revision made 2/19/09 MSDS Distributed by: Brenntag Pacific, Inc. Prepared By: Edward Doheny 1 Date Prepared: May 24, 2011 This Material Safety Data Sheet is provided as an information resource only. It should not be taken as a warranty or representation for which Brenntag Pacific, Inc.assumes legal liability. While Brenntag Pacific, Inc. believes the information contained herein is accurate and compiled from sources believed to be reliable,it is the responsibility of the user to investigate and verify its validity. The buyer assumes air responsibility or using and handling the product in accordance with applicable federal,state,and local regulations. IMPORTANT: While Brennt believes the information containe d herein to be accurate,Brenntag makes no representation or warranty,express or impl ied,regarding,and assurms no liability for,the accuracy or completeness of the information. The Buyer assunes all responsibility for handling,using and/or reselling the Product in accordance with the applicable federal,state,and local law.This MSDS shall not in any way limit or preclude the operation and effect of any of the provisions of Brenntag's terms and conditions of sale. BHUGHES Material Safety Data Sheet Baker Petrolite Section 1. Chemical Product and Company Identification Product Name CRW5494 CORROSION INHIBITOR Code CRW5494 Supplier Baker Petrolite Version 6.0 A Baker Hughes Company 12645 W. Airport Blvd. (77478) P.O. Box 5050 Sugar Land,TX 77487-5050 For Product Information/MSDSs Call: 800-231-3606 (8:00 a.m. -5:00 p.m. cst, Monday- Friday)281-276-5400 Material Uses Corrosion Inhibitor Effective Date 06/01/2010 24 Hour CHEMTREC 800-424-9300 (U.S. 24 hour) Print Date 06/01/2010 Emergency Baker Petrolite 800-231-3606 Numbers (001)281-276-5400 CANUTEC 613-996-6666 (Canada 24 hours) CHEMTREC Intl 01-703-527-3887 (International 24 hour) National Fire Protection Flammability Association(U.S.A.) 3 Health,.2 u Instability .� N .,/ Specific Hazard Section 2. Hazards Identification Physical State and State: Liquid., Color: Amber., Odor: Pungent/Mercaptan Appearance CERCLA Reportable Methanol, 2790 gal. of this product. Quantity Hazard Summary WARNING. May cause chronic effects. Flammable liquid. Vapors can form an ignitable or explosive mixture with air. Can form explosive mixtures at temperatures at or above the flash point. Vapors can flow along surfaces to a distant ignition source and flash back. Static discharges can cause ignition or explosion when container is not bonded. May be irritating to eyes, skin and respiratory tract. May be toxic by skin absorption. May cause central nervous system (CNS) effects if inhaled.The head space of containers and manufacturing equipment containing this product may accumulate hydrogen sulfide vapors. Hydrogen sulfide is a toxic and flammable gas that can be harmful or fatal. Routes of Exposure Skin (Permeator), Skin (Contact), Eyes, Inhalation. Potential acute health effects Eyes May be severely irritating to the eyes. Prolonged contact may cause burns. Skin May be severely irritating to the skin. May cause burns on prolonged contact. May be toxic if absorbed through the skin. Inhalation May cause central nervous system (CNS) effects if inhaled. May be severely irritating to the lungs. Ingestion Not considered a likely route of exposure, however, may be toxic if swallowed. Medical Conditions Exposure to this product may aggravate medical conditions involving the following: nervous aggravated by system, gastrointestinal tract, respiratory tract, skin/epithelium, eyes. Exposure See Toxicological Information (section 11) Continued on Next Page CRW5494 CORROSION INHIBITOR Page: 2/9 Additional Hazard The NIOSH IDLH (Immediately Dangerous to Life and Health) value for hydrogen sulfide is 100 Identification Remarks ppm. Hydrogen sulfide odor is not a good warning property. The human sense of smell may become "fatigued" after a few minutes of exposure to hydrogen sulfide and no longer be able to detect the odor. See section 11 for more detailed information on health effects and symptoms. Repeated or prolonged contact may cause dermatitis (inflammation) and defatting of the skin (dryness). See section 11 for more detailed information on health effects and symptoms. Section 3. Composition/Information on Ingredients Name CAS# %by Weight Isopropanol 67-63-0 40-70 Methanol 67-56-1 15-40 Phosphates Trade secret. Trade secret. Quaternary ammonium chloride Trade secret. Trade secret. Polyoxyalkylene phosphate Trade secret. Trade secret. Hydrogen sulfide 7783-06-4 <0.1 The 0.1% (1000 ppm) maximum hydrogen sulfide (H2S) content shown above is for the liquid phase. The headspace of containers of this product may contain levels of H2S higher than this.See Section 8 for information on permissible exposure limits and threshold limit values. Section 4. First Aid Measures Eye Contact Immediately flush the eye(s) continuously with lukewarm, gently flowing water for at least 20-60 minutes while holding the eyelid(s)open. Get medical attention immediately. Skin Contact Remove contaminated clothing and shoes immediately. Wash affected area with soap and mild detergent and large amounts of lukewarm, gently flowing water until no evidence of chemical remains(for at least 20-60 minutes). Get medical attention if irritation occurs. Inhalation Remove to fresh air. Oxygen may be administered if breathing is difficult. If not breathing, administer artificial respiration and seek medical attention. Get medical attention if symptoms appear. Ingestion Get medical attention immediately. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Wash out mouth with water if person is conscious. Never induce vomiting or give anything by mouth to a victim who is unconscious or having convulsions. Notes to Physician Not available. Additional First Aid If breathing has stopped or the heart has stopped, trained personnel should immediately Remarks administer artificial respiration or cardiopulmonary resuscitation, as required. Section 5. Fire Fighting Measures . Flammability of the Flammable liquid. Vapors can form an ignitable or explosive mixture with air. Can form explosive Product mixtures at temperatures at or above the flash point. Vapors can flow along surfaces to a distant ignition source and flash back. Static discharges can cause ignition or explosion when container is not bonded. OSHA Flammability IB Class Products of These products are carbon oxides (CO, CO2) nitrogen oxides (NO, NO2 etc.) sulfur oxides (SO2, Combustion SO3 etc.)Oxides of phosphorous. Hydrogen chloride fumes. Hydrogen sulfide.. Fire Hazards in Open Flames/Sparks/Static. Heat. Presence of Various Substances Continued on Next Page CRW5494 CORROSION INHIBITOR Page: 3/9 Fire Fighting Media In case of fire, use foam, dry chemicals, or CO2 fire extinguishers. Evacuate area and fight fire and Instructions from a safe distance. Water spray may be used to keep fire-exposed containers cool. Keep water run off out of sewers and public waterways. Note that flammable vapors may form an ignitable mixture with air. Vapors may travel considerable distances and flash back if ignited. Protective Clothing Do not enter fire area without proper personal protective equipment, including NIOSH approved (Fire) self-contained breathing apparatus. Special Remarks on This product contains a thiophosphate ingredient which may liberate hydrogen sulfide or low Fire Hazards molecular weight mercaptans on thermal decomposition or contact with water. Section 6. Accidental Release Measures Spill Put on appropriate personal protective equipment. Keep personnel removed and upwind of spill. Shut off all ignition sources; no flares, smoking, or flames in hazard area. Approach release from upwind. Shut off leak if it can be done safely. Contain spilled material. Keep out of waterways. Dike large spills and use a non-sparking or explosion-proof means to transfer material to an appropriate container for disposal. For small spills add absorbent (soil may be used in the absence of other suitable materials) scoop up material and place in a sealed, liquid- proof container. Note that flammable vapors may form an ignitable mixture with air. Vapors may travel considerable distances from spill and flash back, if ignited. Waste must be disposed of in accordance with federal, state and local environmental control regulations. Other Statements If RQ (Reportable Quantity) is exceeded, report to National Spill Response Office at 1-800-424- 8802. Additional Accidental Released material may contain residual sulfides. Spray residual material left after initial clean up Release Measures with weak (approximately 5 percent) hydrogen peroxide to oxidize sufides. Recover as much Remarks solution as possible. Section 7. Handling and Storage Handling and Storage Put on appropriate personal protective equipment. Avoid contact with eyes, skin, and clothing. Avoid breathing vapors or spray mists. Use only with adequate ventilation. Store in a dry, cool and well ventilated area. Keep away from heat, sparks and flame. Keep away from incompatibles. Keep container tightly closed and dry. To avoid fire or explosion, ground container equipment and personnel before handling product.Hydrogen sulfide accumulates in the headspace of containers of this product. During sealed transfer of this product under well- ventilated conditions, where inhalation exposure potential is minimal, respiratory protection is not expected to be necessary. However, if after a thorough hazard assessment respiratory protection is deemed necessary an appropriate supplied air respirator must be utilized. Additional Handling Avoid inhalation of vapors near openings on storage containers and manufacturing equipment. and Storage Remarks This product should be transferred under negative pressure. Section 8. Exposure Controls/Personal Protection Exposure Limits Isopropanol ACGIH (United States). TWA:490 mg/m3 8 hours. STEL: 980 mg/m3 15 minute(s). TWA: 200 ppm 8 hours. STEL:400 ppm 15 minute(s). OSHA PEL 1989(United States). TWA:400 ppm 8 hours. STEL: 500 ppm 15 minute(s). TWA: 980 mg/m3 8 hours. STEL: 1225 mg/m3 15 minute(s). Methanol ACGIH (United States). Skin TWA: 262 mg/m3 8 hours. Continued on Next Page CRW5494 CORROSION INHIBITOR Page: 4/9 STEL: 328 mg/m3 15 minute(s). TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minute(s). OSHA PEL 1989(United States). Skin TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minute(s). TWA: 260 mg/m3 8 hours. STEL: 325 mg/m3 15 minute(s). Phosphates Not available. Quaternary ammonium chloride Not available. Polyoxyalkylene phosphate Not available. Hydrogen sulfide ACGIH (United States). TWA: 1 ppm 8 hours. STEL: 1.39 ppm 15 minute(s). OSHA(United States). TWA: 10 ppm 8 hours. OSHA PEL 1989(United States). STEL: 15 ppm 15 minute(s). CEIL: 20 ppm Additional Information The OSHA permissible exposure levels shown above are the OSHA 1989 levels or from on Exposure Limits subsequent OSHA regulatory actions.Although the 1989 levels have been vacated the 11th Circuit Court of Appeals, Baker Petrolite Corporation recommends that these lower exposure levels be observed as reasonable worker protection. Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors or particles below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Personal Protection Personal Protective Equipment recommendations are based on anticipated known manufacturing and use conditions. These conditions are expected to result in only incidental exposure. A thorough review of the job tasks and conditions by a safety professional is recommended, however,to determine the level of personal protective equipment appropriate for these job tasks and conditions. Eyes Chemical safety goggles. Body Wear long sleeves to prevent repeated or prolonged skin contact. Respiratory Hydrogen sulfide accumulates in the headspace of containers of this product. During sealed transfer of this product under well-ventilated conditions, where inhalation exposure potential is minimal, respiratory protection is not expected to be necessary. However, if after a thorough hazard assessment respiratory protection is deemed necessary an appropriate supplied air respirator must be utilized. Hands Chemical resistant gloves. Nitrile or Neoprene gloves. Feet Chemical resistant boots or overshoes. Other information Not available. Additional Exposure Prior to handling containers of this product, make sure to be wearing a hydrogen sulfide (H2S) Control Remarks monitor that is in sound working condition. `Continued on Next Page ICRW5494 CORROSION INHIBITOR Page: 5/9 Section 9. Physical and Chemical Properties Physical State and Liquid. Odor Pungent/Mercaptan Appearance pH Not available. Color Amber. Specific gravity 0.816-0.828 @ 16°C (60°F) Density 6.8-6.9 lbs/gal @ 16°C (60°F) Flash Points Closed cup: 13°C (55.4°F). (SFCC) Flammable Limits L.E.L. Not available. U.E.L. Not available. Autoignition Not available. Temperature Initial Boiling Point Not available. Boiling Point Not available. Vapor Density >1 (Air= 1) Vapor Pressure Not Available or Not Applicable for Solids. Evaporation Rate Not Available or Not Applicable for Solids. VOC Not available. Viscosity Not available. Pour Point -40°C (-40°F) Solubility(Water) Soluble Physical Chemical Not available. Comments Section 10. Stability and Reactivity Stability and Reactivity The product is stable. Conditions of Not available. Instability Incompatibility with Oxidizing material. Various Substances Hazardous Not applicable. Decomposition Products Hazardous Hazardous polymerization is not expected to occur. Polymerization Special Stability& May liberate hydrogen sulfide or low molecular weight mercaptans on dilution with water. A Reactivity Remarks respirator suitable for H2S may be necessary in the event of a spill or contact with water. Methanol and isopropanol are incompatible and may react with acetyl bromide, alkyl aluminum solutions, beryllium hydride, boron trichloride, nitric acid, cyanuric chloride, dichloromethane, diethylzinc, metals (granulated forms of aluminum and magnesium — including aluminum and zinc salts), phosphorus Ill oxide, and potassium tert-butoxide. IContinued on Next Page ICRW5494 CORROSION INHIBITOR Page: 6/9 Section 11. Toxicological information Component Toxicological Information Acute Animal Toxicity Isopropanol ORAL (LD50): Acute: 5045 mg/kg [Rat]. 3600 mg/kg [Mouse]. 4710 mg/kg [Male rat]. DERMAL (LD50): Acute: 12800 mg/kg [Rabbit]. VAPOR (LC50): Acute: 16970 ppm 4 hours[Rat]. 12000 ppm 8 hours [Rat]. Methanol ORAL (LD50): Acute: 5628 mg/kg [Rat]. 7300 mg/kg [Mouse]. DERMAL (LD50): Acute: 15800 mg/kg [Rabbit]. VAPOR(LC50): Acute: 64000 ppm 4 hours[Rat]. 50000 ppm 4 hours[Mouse]. Phosphates Not available. Quaternary ammonium chloride ORAL (LD50): Acute: 295 mg/kg [Rat]. DERMAL(LD50): Acute: 1664 mg/kg [Rat]. Polyoxyalkylene phosphate Not available. Hydrogen sulfide GAS(LC50): Acute: 634 ppm 1 hours[Mouse]. 470 mg/m3 6 hours[Rat]. Chronic Toxicity Data 1) Isopropanol Isopropanol is a component of this product. Ingestion has produced hyperglycemia (high blood sugar) in humans (Lacouture, P, et al, 1983, "American Journal of Medicine" and Chan K-M, et al, 1993, "Clinical Chemistry"). Also, ingestion can produce Central Nervous System effects and gastointestinal symptoms. [IPCS (1990) Environmental Health Criteria 103: 2-propanol. International Program on Chemical Safety, WHO Geneva.] In a four month study, inhalation of isopropanol vapors for 20 hours per week by laboratory animals produced bronchitis, pneumonia, and blood effects (International Program of Chemical Safety, 1990, Environmental Health Criteria 103: 2-propanol, World Health Organization). Ataxia (a jerky or shaky movement that occurs during voluntary muscle movement) and microscopic hyaline droplets (fungal or branched structures) in the kidneys were seen in rats exposed to isopropanol at concentrations up to 5000 ppm for 6 hours per day, 5 days per week, for 13 weeks(Burleighflayer et al, 1994). Inhalation of high levels of isopropanol (4,000 and 8,000 ppm for 8 hours) has produced congestion in the liver, lungs, and spleen of laboratory animals(Laham S, et al, 1980, "Drug and Chemical Toxicology). Oral and inhalation animal studies isopropanol has been shown to cause fetotoxic and reproductive effects at levels which did not show any maternal toxicity. These effects include reductions in fetal litter weight, reductions in live births and significant skeletal malformations in rats. [Nelson, BK et al (1988), Food and Chemical Toxicology, 26(3), pps 247-254], [Tyl, R.W. et al (1994), Fundamental and Applied Toxicoology, 22, pps 139-151], [Bevan, C., et al (1995), Journal of Applied Toxicology, 15(2), pps 117-123. Chronic inhalation has produced testicular effects in laboratory animals. (Kapp, Jr., R.W., et al, 1996, Regulatory Toxicology and Pharmacology 23:183-192, and Burleigh-Flayer, H., et al, 1997, Fundamental and Applied Toxicology: 36:95-111) 2) Methanol Methanol is a component of this product. Because methanol is eliminated from the body more slowly than ethanol, it can have cumulative toxicity with repeated exposures(ACGIH, 1992). Acute dermal, oral, and inhalation exposure to methanol can cause Central Nervous System effects, optic nerve effects, diminished vision, and brain effects(necrosis and hemorrhaging). (Bennett, I.L. et al, 1953) Continued on Next Page CRW5494 CORROSION INHIBITOR Page: 7/9 Ingestion of methanol can cause Central Nervous System depression, metabolic acidosis, blurred vision and blindness, gastrointestinal effects, and coma and death. (Clayton, G.D. and Clayton, F.E., 1982, Patty's Industrial Hygiene and Toxicology, Vol2C) Dermal exposure to methanol can cause Central Nervous System depression, blurred vision, and gastrointestinal effects. (Downie, A et al, 1992, Occupational Medicine, 42, pp 47-9) Chronic inhalation of methanol can cause Central Nervous System depression, blurred vision, and gastrointestinal effects. (Frederick, L.J. et al, 1984, AIHA Journal, 45, pp 51-5) Chronic inhalation of methanol has caused liver effects in laboratory animals. (Poon, R et al, 1994, Toxocology and Industrial Health 10: 231-245) Chronic oral exposure has caused Central Nervous System effects and eye effects in laboratory animals. [Youssef, A. F. et al (1993) Neurotoxicology and Teratology 15: 223-227; Baumbach, G.L. et al (1977) Archives of Ophthalmology 95: 1859-1865; Hayreh, M.S. et al (1977) Archives of Ophthalmology 95: 1851-1858; Hayreh, M.S. et al (1980) Ocular toxicity of methanol: An experimental study— Raven Press, New York, pages 35-53; and Martin-Amat, G. et al (1977)Archives of Ophthalmology 95: 1847-1850] Methanol has produced in vivo mutagenicity in animal studies. (Pereira, M.A. et al, 1982)and (Ward, J. B. et al, 1983) Methanol was mutagenic in yeast (RTECS). Methanol has caused chromosome aberrations in yeast (RTECS) and grasshoppers(Saha & Khudabaksh, 1974). Methanol has caused birth defects in rats exposed by the oral (Infurna et al, 1981) and inhalation (Nelson et al, 1984; Nelson et al, 1985) routes. Exencephaly (a defect in the skull bone structure that leaves the brain exposed) and cleft palate (a fissure or unformed bone structure in the roof of the mouth (palate), lip, or facial area, occurring during the embryonic stage of development) were increased in fetal mice exposed to methanol at an airborne concentration of 5,000 ppm or higher for 7 hours/day on days 6 to 15 of gestation. Embryotoxicity and fetotoxicity were seen with maternal exposure to airborne concentrations of 7,500 ppm and above, and reduced fetal weights with concentrations of 10,000 ppm or greater. The NOAEL was 1,000 ppm. Effects similar to those seen in the 10,000 ppm dosage group were also seen in offspring of mice given a dose of 4 g/kg orally(Rogers et al, 1993). 3) Phosphates Not available. 4) Quaternary ammonium chloride A quaternary ammonium chloride is a component of this product. It has produced skin corrosion in laboratory animals. 5) Polyoxyalkylene phosphate Not available. 6) Hydrogen sulfide The most serious danger from hydrogen sulfide is its acute effects. Hydrogen sulfide may be absorbed through the skin; however, the major source of toxic exposure is inhalation. Slight poisoning can occur with exposure to airborne concentrations of 10 to 500 ppm, producing a headache lasting several hours. Levels higher than 50 ppm for 1 hour can cause painful eye irritation, tearing, and extreme sensitivity to light. Exposures to concentrations around 250 ppm can produce pulmonary edema after prolonged exposure. Exposure to airborne levels of 50-700 ppm produces loss of consciousness. Exposure to concentrations of 600 ppm for 30 minutes or 800 ppm for 5 minutes may be fatal. Possible chronic exposure to low levels of hydrogen sulfide are not well documented, but have been linked with cardiac arrhythmias, neurotoxicity and chronic eye irritation. Hydrogen sulfide has been associated with chromosome aberrations in chemical industry workers and in the bone marrow cells of rats. Product Toxicological Information Acute Animal Toxicity Not available. Target Organs nervous system, gastrointestinal tract, respiratory tract, skin/epithelium, eyes. Other Adverse Effects Not available. IContinued on Next Page ICRW5494 CORROSION INHIBITOR Page: 8/9 Section 12. Ecological Information Ecotoxicity Not available. BOD5 and COD Not available. Biodegradable/OECD Not available. Toxicity of the Products Not available. of Biodegradation Special Remarks An EcoToxTM Report, and/or the material's environmental fate is available upon request at the following number: 1-800-235-4249,then press 4. Section 13. Disposal Considerations Responsibility for proper waste disposal rests with the generator of the waste. Dispose of any waste material in accordance with all applicable federal, state and local regulations. Note that these regulations may also apply to empty containers, liners and rinsate. Processing, use, dilution or contamination of this product may cause its physical and chemical properties to change. Additional Waste Not available. Remarks Section 14. Transport Information DOT Classification FLAMMABLE LIQUID, N.O.S. (Contains: Methanol, Isopropanol), 3, UN1993, II FLAMMABLE LIQUID 3 DOT Reportable Methanol, 2790 gal. of this product. Quantity Marine Pollutant Not applicable. Additional DOT Not available. Information Emergency Response 128 Guide Number Section 15. Regulatory Information HCS Classification Target organ effects. Flammable liquid. Irritant. U.S. Federal Regulations Environmental Extremely Hazardous Substances: Hydrogen sulfide; Regulations SARA 313 Toxic Chemical Notification and Release Reporting: Methanol; SARA 302/304 Emergency Planning and Notification substances: Hydrogen sulfide; Hazardous Substances(CERCLA 302): Methanol, 2790 gal. of this product.; SARA 311/312 MSDS distribution -chemical inventory- hazard identification:fire; immediate health hazard; delayed health hazard; Clean Water Act(CWA)307 Priority Pollutants: Hydrogen sulfide; Clean Water Act(CWA)311 Hazardous Substances: Not applicable to any components in this product. Clean Air Act(CAA) 112(r)Accidental Release Prevention Substances: Hydrogen sulfide; Continued on Next Page CRW5494 CORROSION INHIBITOR Page: 9/9 Threshold Not applicable. Planning Quantity(TPQ) TSCA Inventory All components are included or are exempted from listing on the US Toxic Substances Control Status Act Inventory. This product does not contain any components that are subject to the reporting requirements of TSCA Section 12(b) if exported from the United States. State Regulations State specific information is available upon request from Baker Petrolite. International Regulations Canada All components are compliant with or are exempted from listing on the Canadian Domestic Substance List. WHMIS (Canada) B-2, D-1 B, D-2A, E European Union All components are included or are exempted from listing on the European Inventory of Existing Commercial Chemical Substances or the European List of Notified Chemical Substances. International inventory status information is available upon request from Baker Petrolite for the following countries:Australia, China, Korea (TCCL), Philippines(RA6969), or Japan. Other Regulatory No further regulatory information is available. Information Section 16. Other Information Other Special 236 Considerations 04/16/03- Changes to Sections 2, 3, 5, 8 and 15. 04/15/04- Changes to Sections 3, 9, 14 and 15. 06/05/07- Changes to Sections 2, 3, 5, 8, 9, and 15. 04/21/08- Changes to Sections 2, 3, 5, 6, 7, 8 and 11, 05/19/09- Changes to Sections 3 (CN)and 4. 06/01/10- Change to Section 8 Baker Petrolite Disclaimer NOTE: The information on this MSDS is based on data which is considered to be accurate. Baker Petrolite, however, makes no guarantees or warranty, either expressed or implied of the accuracy or completeness of this information. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of this product. This MSDS was prepared and is to be used for this product. If the product is used as a component in another product, this MSDS information may not be applicable. Conoco Universal Gear Lubricant (All Grades) Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: Universal Gear Lubricant(All Grades) MSDS Code: 775809 Synonyms: Conoco Universal Gear Lubricant, SAE 80W-90 Conoco Universal Gear Lubricant, SAE 80W-140 Conoco Universal Gear Lubricant, SAE 85W-140 Intended Use: Automotive Gear Oil Responsible Party: ConocoPhillips Lubricants 600 N. Dairy Ashford Houston,Texas 77079-1175 Customer Service: 888-766-7676 Technical Information: 800-255-9556 MSDS Information: Internet: http://w3.conocophillips.com/NetMSDS/ Emergency Telephone Numbers: Chemtrec: 800-424-9300(24 Hours) California Poison Control System: 800-356-3219 2. HAZARDS IDENTIFICATION Emergency Overview NFPA This material is not considered hazardous according to OSHA criteria. 1 0♦0 Appearance: Clear Amber Physical Form: Liquid Odor: Petroleum Potential Health Effects Eye: Contact may cause mild eye irritation including stinging,watering, and redness. Skin: Contact may cause mild skin irritation including redness and a burning sensation. Not expected to be a skin irritant under normal conditions of use. Prolonged or repeated contact can defat the skin, causing drying and cracking of the skin,and possibly dermatitis (inflammation). No harmful effects from skin absorption are expected. Inhalation(Breathing): No information available on acute toxicity. Ingestion(Swallowing): No harmful effects expected from ingestion. Signs and Symptoms: Effects of overexposure may include irritation of the digestive tract, nausea and diarrhea. Inhalation of oil mist or vapors at elevated temperatures may cause respiratory irritation. Pre-Existing Medical Conditions: Conditions aggravated by exposure may include skin disorders. See Section 11 for additional Toxicity Information. 775809-Universal Gear Lubricant(All Grades) Page 1/7 Date of Issue: 04-Feb-2008 Status: Final 775809-Universal Gear Lubricant(All Grades) Page 2/7 Date of Issue: 04-Feb-2008 Status: Final 3. COMPOSITION / INFORMATION ON INGREDIENTS Component CAS Concentration(wt%) Lubricant Base Oil (Petroleum) VARIOUS >55 Additives PROPRIETARY <45 4. FIRST AID MEASURES Eye: If irritation or redness develops from exposure, flush eyes with clean water. If symptoms persist, seek medical attention. Skin: Remove contaminated shoes and clothing and cleanse affected area(s)thoroughly by washing with mild soap and water or a waterless hand cleaner. If irritation or redness develops and persists, seek medical attention. Inhalation(Breathing): If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, seek medical attention. Ingestion(Swallowing): First aid is not normally required; however, if swallowed and symptoms develop, seek medical attention. Notes to Physician: Acute aspirations of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. 5. FIRE-FIGHTING MEASURES NFPA 704 Hazard Class Health: 0 Flammability: 1 Instability: 0 (0-Minimal, 1-Slight, 2-Moderate, 3-Serious,4-Severe) Unusual Fire&Explosion Hazards: This material may burn, but will not ignite readily. If container is not properly cooled, it can rupture in the heat of a fire. Extinguishing Media: Dry chemical, carbon dioxide,foam,or water spray is recommended. Water or foam may cause frothing of materials heated above 212°F. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Fire Fighting Instructions: For fires beyond the incipient stage, emergency responders in the immediate hazard area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces, or when explicitly required by DOT,a self contained breathing apparatus should be worn. In addition,wear other appropriate protective equipment as conditions warrant(see Section 8). Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done with minimal risk.Avoid spreading burning liquid with water used for cooling purposes. See Section 9 for Flammable Properties including Flash Point and Flammable(Explosive) Limits 775809-Universal Gear Lubricant(All Grades) Page 3/7 Date of Issue: 04-Feb-2008 Status: Final 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release. The use of explosion-proof electrical equipment is recommended. Stay upwind and away from spill/release. Notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out.Wear appropriate protective equipment, including respiratory protection, as conditions warrant(see Section 8). See Sections 2 and 7 for additional information on hazards and precautionary measures. Environmental Precautions: Stop spill/release if it can be done with minimal risk. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Use water sparingly to minimize environmental contamination and reduce disposal requirements. Spills into or upon navigable waters,the contiguous zone, or adjoining shorelines that cause a sheen or discoloration on the surface of the water, may require notification of the National Response Center(phone number 800-424- 8802). Methods for Containment and Clean-Up: Notify fire authorities and appropriate federal, state, and local agencies. Immediate cleanup of any spill is recommended. Dike far ahead of spill for later recovery or disposal. Absorb spill with inert material such as sand or vermiculite, and place in suitable container for disposal. 7. HANDLING AND STORAGE Precautions for safe handling: Wash thoroughly after handling. Use good personal hygiene practices and wear appropriate personal protective equipment. Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. Do not wear contaminated clothing or shoes. "Empty"containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat,flame, sparks, or other sources of ignition.They may explode and cause injury or death. "Empty"drums should be completely drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. Before working on or in tanks which contain or have contained this material, refer to OSHA regulations,ANSI Z49.1, and other references pertaining to cleaning, repairing,welding,or other contemplated operations. Conditions for safe storage: Keep container(s)tightly closed. Use and store this material in cool,dry,well-ventilated areas away from heat and all sources of ignition. Store only in approved containers. Keep away from any incompatible material (see Section 10). Protect container(s)against physical damage. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Component ACGIH OSHA Other: Lubricant Base Oil (Petroleum) TWA: 5mg/m3 TWA: 5 mg/m3 STEL: 10 mg/m3 as Oil Mist, if generated as Oil Mist, if generated Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies,for further information. Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits,additional engineering controls may be required. Personal Protective Equipment(PPE): Eye/Face:The use of eye protection that meets or exceeds ANSI Z.87.1 is recommended to protect against potential eye contact, irritation, or injury. Depending on conditions of use, a face shield may be necessary. Skin: The use of gloves impervious to the specific material handled is advised to prevent skin contact. Users should check with manufacturers to confirm the performance of their products. Suggested protective materials: Nitrile. 775809-Universal Gear Lubricant(All Grades) Page 4/7 Date of Issue: 04-Feb-2008 Status: Final Respiratory:Where there is potential for airborne exposure above the exposure limit a NIOSH certified air purifying respirator equipped with R or P95 filters may be used. A respiratory protection program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed whenever workplace conditions warrant a respirator's use. Air purifying respirators provide limited protection and cannot be used in atmospheres that exceed the maximum use concentration (MUC)as directed by regulation or the manufacturer's instructions, in oxygen deficient(less than 19.5 percent oxygen)situations, or other conditions that are immediately dangerous to life and health (IDLH). Suggestions provided in this section for exposure control and specific types of protective equipment are based on readily available information. Users should consult with the specific manufacturer to confirm the performance of their protective equipment. Specific situations may require consultation with industrial hygiene,safety, or engineering professionals. D. PHYSICAL AND CHEMICAL PROPERTIES Note: Unless otherwise stated, values are determined at 20°C(68°F)and 760 mm Hg (1 atm). Data represent typical values and are not intended to be specifications. Appearance: Clear Amber Physical Form: Liquid Odor: Petroleum Odor Threshold: No data pH: Not applicable Vapor Pressure: <1 mm Hg Vapor Density(air=1): >1 Boiling Point/Range: No data Melting/Freezing Point: No data Solubility in Water: Negligible Partition Coefficient(n-octanol/water)(Kow): No data Specific Gravity: 0.88-0.91 @ 60°F(15.6°C) Bulk Density: 7.33-7.58 lbs/gal Viscosity: 14.0-28.6 cSt @ 100°C; 130-393 cSt @ 40°C Percent Volatile: Negligible Evaporation Rate(nBuAc=1): <1 Flash Point: Minimum 302°F/ 150°C Test Method: Pensky-Martens Closed Cup (PMCC),ASTM D93, EPA 1010 LEL(vol% in air): No data UEL(vol % in air): No data Autoignition Temperature: No data 10. STABILITY AND REACTIVITY Stability: Stable under normal ambient and anticipated conditions of storage and handling. Conditions to Avoid: Extended exposure to high temperatures can cause decomposition. Materials to Avoid(Incompatible Materials):Avoid contact with strong oxidizing agents and strong reducing agents. Hazardous Decomposition Products: Combustion can yield oxides of carbon, nitrogen, sulfur and phosphorus. Hazardous Polymerization: Not known to occur. 775809-Universal Gear Lubricant(All Grades) Page 5/7 Date of Issue: 04-Feb-2008 Status: Final 11. TOXICOLOGICAL INFORMATION Chronic Data: Lubricant Base Oil (Petroleum) Carcinogenicity: The petroleum base oils contained in this product have been highly refined by a variety of processes including severe hydrocracking/hydroprocessing to reduce aromatics and improve performance characteristics. All of the oils meet the IP-346 criteria of less than 3 percent PAH's and are not considered carcinogens by NTP, IARC, or OSHA. Acute Data: Component Oral LD50 Dermal LD50 Inhalation LC50 (Lubricant Base Oil (Petroleum) >5 g/kg >2 g/kg No data 12. ECOLOGICAL INFORMATION Lubricant oil basestocks are complex mixtures of hydrocarbons(primarily branched chain alkanes and cycloalkanes)ranging in carbon number from C15 to C50. The aromatic hydrocarbon content of these mixtures varies with the severity of the refining process. White oils have negligible levels of aromatic hydrocarbons, whereas significant proportions are found in unrefined basestocks. Olefins are found only at very low concentrations.Volatilization is not significant after release of lubricating oil basestocks to the environment due to the very low vapor pressure of the hydrocarbon constituents. In water, lubricating oil basestocks will float and will spread at a rate that is viscosity dependent.Water solubilities are very low and dispersion occurs mainly from water movement with adsorption by sediment being the major fate process. In soil, lubricating oil basestocks show little mobility and adsorption is the predominant physical process. Both acute and chronic ecotoxicity studies have been conducted on lubricant base oils. Results indicate that the acute aquatic toxicities to fish, Daphnia, Ceriodaphnia and algal species are above 1000 mg/I using either water accommodated fractions or oil in water dispersions. Since lubricant base oils mainly contain hydrocarbons having carbon numbers in the range C15 to C50, it is predicted that acute toxicity would not be observed with these substances due to low water solubility. Results from chronic toxicity tests show that the no observed effect level (NOEL) usually exceeds 1000 mg/I for lubricant base oils with the overall weight of experimental evidence leading to the conclusion that lubricant base oils do not cause chronic toxicity to fish and invertebrates. Large volumes spills of lubricant base oils into water will produce a layer of undissolved oil on the water surface that will cause direct physical fouling of organisms and may interfere with surface air exchange resulting in lower levels of dissolved oxygen. Petroleum products have also been associated with causing taint in fish even when the latter are caught in lightly contaminated environments. Highly refined base oils sprayed onto the surface of eggs will result in a failure to hatch. Extensive experience from laboratory and field trials in a wide range of crops has confirmed that little or no damage is produced as a result of either aerosol exposure or direct application of oil emulsion to the leaves of crop plants. Base oils incorporated into soil have resulted in little or no adverse effects on seed germination and plant growth at contamination rates up to 4%. 13. DISPOSAL CONSIDERATIONS The generator of a waste is always responsible for making proper hazardous waste determinations and needs to consider state and local requirements in addition to federal regulations. This material, if discarded as produced,would not be a federally regulated RCRA"listed"hazardous waste and is not believed to exhibit characteristics of hazardous waste. See Sections 7 and 8 for information on handling, storage and personal protection and Section 9 for physical/chemical properties. It is possible that the material as produced contains constituents which are not required to be listed in the MSDS but could affect the hazardous waste determination.Additionally, use which results in chemical or physical change of this material could subject it to regulation as a hazardous waste. This material under most intended uses would become"Used Oil"due to contamination by physical or chemical impurities.Whenever possible, Recycle Used Oil in accordance with applicable federal and state or local regulations. Container contents should be completely used and containers should be emptied prior to discard. 14. TRANSPORTATION INFORMATION U.S. Department of Transportation (DOT) Shipping Description: Not regulated Note: If shipped by land in a packaging having a capacity of 3,500 gallons or more, the provisions of 49 CFR, Part 130 apply. (Contains oil) 775809-Universal Gear Lubricant(All Grades) Page 6/7 Date of Issue: 04-Feb-2008 Status: Final 14. TRANSPORTATION INFORMATION International Maritime Dangerous Goods(IMDG) Shipping Description: Not regulated Note: Federal compliance requirements may apply. See 49 CFR 171.12. International Civil Aviation Org./International Air Transport Assoc. (ICAO/IATA) UN/ID#: Not regulated LTD. QTY Passenger Aircraft Cargo Aircraft Only Packaging Instruction#: --- Max. Net Qty. Per Package: 15. REGULATORY INFORMATION CERCLA/SARA-Section 302 Extremely Hazardous Substances and TPQs(in pounds): This material does not contain any chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372. CERCLA/SARA-Section 311/312 (Title III Hazard Categories) Acute Health: No Chronic Health: No Fire Hazard: No Pressure Hazard: No Reactive Hazard: No CERCLA/SARA-Section 313 and 40 CFR 372: This material does not contain any chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372. EPA(CERCLA) Reportable Quantity(in pounds): This material does not contain any chemicals with CERCLA Reportable Quantities. California Proposition 65: Warning: This material may contain detectable quantities of the following chemicals, known to the State of California to cause cancer, birth defects or other reproductive harm, and which may be subject to the requirements of California Proposition 65(CA Health &Safety Code Section 25249.5): Component Type of Toxicity Ethyl Acrylate Cancer Lead/Lead Compounds Cancer Developmental Toxicant Female Reproductive Toxicant Male Reproductive Toxicant Arsenic(Inorganic Arsenic Compounds) Cancer Cadmium/Cadmium Compounds Cancer Developmental Toxicant Male Reproductive Toxicant Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations(CPR)and the MSDS contains all the information required by the Regulations. WHMIS Hazard Class None National Chemical Inventories: All components are either listed on the US TSCA Inventory, or are not regulated under TSCA. All components are either on the DSL,or are exempt from DSL listing requirements. 775809-Universal Gear Lubricant(All Grades) Page 7/7 Date of Issue: 04-Feb-2008 Status: Final U.S. Export Control Classification Number: EAR99 16. OTHER INFORMATION Issue Date: 04-Feb-2008 Status: Final Previous Issue Date: 05-Aug-2003 Revised Sections or Basis for Revision: Product Name/Synonyms(Section 1) NFPA ratings(Section 2) Physical Properties(Section 9) MSDS Code: 775809 MSDS Legend: ACGIH =American Conference of Governmental Industrial Hygienists;CAS=Chemical Abstracts Service Registry;CEILING=Ceiling Limit(15 minutes);CERCLA=The Comprehensive Environmental Response,Compensation,and Liability Act;EPA=Environmental Protection Agency;IARC= International Agency for Research on Cancer; LEL=Lower Explosive Limit;NE=Not Established; NFPA=National Fire Protection Association;NTP= National Toxicology Program;OSHA=Occupational Safety and Health Administration; PEL=Permissible Exposure Limit(OSHA);SARA=Superfund Amendments and Reauthorization Act;STEL=Short Term Exposure Limit(15 minutes);TLV=Threshold Limit Value(ACGIH);TWA=Time Weighted Average(8 hours); UEL=Upper Explosive Limit;WHMIS=Worker Hazardous Materials Information System(Canada) Disclaimer of Expressed and implied Warranties: The information presented in this Material Safety Data Sheet is based on data believed to be accurate as of the date this Material Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE,THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT,THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above,and the product,are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. Hello