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Home My WebLink About20150069.tiff SITE SPECIFIC DEVELOPMENT PLAN AND USE BY SPECIAL REVIEW (USR) APPLICATION FOR PLANNING DEPARTMENT USE DATE RECEIVED: RECEIPT # /AMOUNT # 1$ CASE # ASSIGNED: APPLICATION RECEIVED BY PLANNER ASSIGNED: Parcel Number 0 2 9 1 - 1 3 - 0 - 0 0 - 0 0 9 (12 digit number - found on Tax I.D. information, obtainable at the Weld County Assessor's Office, or tee./.co.weld.co.u!s) Lot A of RECX14-0095 being part of the Legal Description W2NW4 of S13-10-61 West of the 6th P.M Section 13 , Township 10 North, Range 61 West Zone District: , Total Acreage: 25.0 , Flood Plain: , Geological Hazard: Airport Overlay District: FEE OWNER(S) OF THE PROPERTY: Name: Grassland Water Solutions Work Phone # 970-356-5560 Home Phone # Email mseume@grasslandwatersolutions.com Address: 1400 16th Street Mall, Suite 400 Address: City/State/Zip Code Denver, CO, 80202 Name: Work Phone # Home Phone # Email Address: Address: City/State/Zip Code Name: Work Phone # Home Phone # Email Address: Address: City/State/Zip Code APPLICANT OR AUTHORIZED AGENT (See Below: Authorization must accompany applications signed by Authorized Agent) Name: M3 Construction Work Phone # 816-519-0056 Home Phone # Email Address: 2861 W 120th Ave, Suite 250 Address: City/State/Zip Code Westminster, CO, 80234 PROPOSED USE: NGL Water Solutions (lessee) would like to propose the expansion and operation of its C9 Facility on this site. This is a class II oilfield waste disposal facility (saltwater injection facility and a water recycling facility), operating 24 hours per day, 7 days a week, 365 days per year with unlimited truck trips to the facility I (We) hereby depose and state under penalties of perjury that all statements, proposals, and/or plans submitted with or contained within the application are true and correct to the best of my (our)knowledge. Signatures of all fee owners of property must sign this application. If an Authorized Agent signs, a letter of authorization from all fee owners must be included with the application. If a corporation is the fee owner, notarized evidence must be includ i icati that the si atory has to legal authority to sign for the corporation. #` i nature. wner Auth 'zed Agent Dat Signature: Owner or Authorized Agent Date To Whom It May Concern: As an authorized representative of NGL Water Solutions DJ, LLC, I grant Theodore A. Lopez, Jr. of M3 Construction, LLC to act on our behalf for the transfer of ownership of the existing USR13-0066 from Circle B, LLC to NGL Water Solutions DJ, LLC. Signature: c. Written: oilat / k fil, di al VariseP Title: I Date: M. /NV Construction, LLC 11864 Bradburn Blvd. ! ' Westminster, CO 80031 Phone: (720) 708-6535 October 16, 2014 Mr. Kim Ogle 1555 North 17th Avenue Greeley, Colorado 80631 Re: 7-Dy Completeness Review for the NGL Water Solutions DJ, LLC, C-9 Facility Dear Mr. Ogle, This letter is in response to the Weld County Department of Planning Services 7-day completeness review for the NGL Water Solutions DJ, LLC, C-9 Facility. The following items are to address each review comment as referenced per the weld county letter dated September 23, 2014. We have attached a copy of the comments from the Planning Department for reference. Environmental Health Department review comments dated 9/24/14 have been received. - Waste Handling plan- submitted. - Sewage Disposal Information- Submitted, design and septic permit application is in progress and will be prepared after BCC approval. - Dust Abatement Plan- submitted.c - Potable water Information: In a 24-hour period, there will be 5 total employees that will operate this facility. Bottled water will be provided for onsite personnel. Non- potable water will be obtained from storage tanks near the site for toilets, ect. All spigots will be marked "non-potable". - APEN/Air Emission Permit Application- the APEN has been submitted to the state, please reference included state permitting documents. - Design, Secondary Containment, and Unloading Pad Information- Please reference the included secondary containment narrative. - Groundwater Monitoring Plan- Please reference the included groundwater monitoring plan. - Emergency Action Plan- M3 Construction has contacted the Weld County OEM (Roy Rudisill) and the Pawnee Fire District and discussed the requirements for the site Emergency Action and Safety Plan. This component is in progress and will be prepared after BCC approval. - Closure Plan- This component is in progress and will be prepared after BCC approval. The USR application legal description has been revised to state Lot A of RECX14-0095 being part of the W2NW4 of section 13, township 10 North, Range 61 West of the 6th P.M., Weld County, Colorado. The USR application request, under the proposed use section, has been revised to state class it oilfield waste disposal facility (saltwater injection facility and a water recycling facility) operating 24 hours per day, 7 days each week, 365 days per year with unlimited truck trip to the facility. Updated and Accurate site and grading plan has been included. All property Deeds associated with this parcel have been included. Detail Response to the Special Use Permit Questionnaire has been included. Waste Handling Plan has been submitted- please reference the Weld County, Environmental Health Memorandum dated 9/24/14. Dust Abatement Plan has been submitted- please reference the Weld County, Environmental Health Memorandum dated 9/24/14. Onsite Waste Water Treatment System- This component is in progress and will be prepared after BCC approval. Potable water permit: Please reference the Special Use Permit Questionnaire. In a 24-hour period, there will be 5 total employees that will operate this facility. Bottled water will be provided for onsite personnel. Detailed Closure Plan- This component is in progress and will be prepared after BCC approval. List of MSDS and MSDS Sheets have been included. Secondary containment narrative is included. Ground Water Monitoring Plan- Please reference the attached CGRS letter and ground monitoring plan. State permitting documents with APEN and Emissions permit have been include. SPCC- Please reference the attached CGRS letter and SPCC plan. Emergency Action Plan- M3 Construction has contacted the Weld County OEM (Roy Rudisill) and the Pawnee Fire District and discussed the requirements for the site Emergency Action and Safety Plan. This component is in progress and will be prepared after BCC approval. Request for Partial vacation of USR12-0077 for the pawnee water management upload and storage facility located on Lot B of RECX14-0095 has will be submitted to Weld County. E-Copy of application materials has been included. Sincerely, tidiA4 .4 /1/7:0, Theodore A. Lopez, Jr., Owner M3 Construction, LLC CC: Doug White — HSWS Greg Blais — HSWS Rae Chrisman — HSWS Kery Valencia — M3 Construction 186I - 2011 DEPARTMENT OF PLANNING SERVICES PLANNING DIVISION 1555 N. 17TH AVENUE W E L DEC O NTY Y GREELEY, CO 80531 1____J 970-353-6100 EXT 3549 FAX 970-304-6498 kogle@weldgov.com September 23, 2014 Ted Lopez M3 Construction 2861 West 120th Avenue, Suite 250 Westminster, Colorado 80234 Subject: 7-day Completeness Review for the NGL Water Solutions DJ, LLC, C-9 Facility Dear Ted: The Departments of Planning Services, Planning Services --- Development Review Engineer, Building Inspection, and Environmental Health and have reviewed the submitted materials for the proposed Site Specific Development Plan and Special Review Permit for a Mineral Resource Development Facility, Oil and Gas Support and Service (Class II Oilfield Waste Disposal Facility - Saltwater Injection Facility, water recycling facility and truck tanker washout) operating 24 hours per day, 7 days each week, 365 days per year with unlimited truck trips to the facility in the A (Agricultural) Zone District, located on land described as Lot A of RECX14-0095 being part of the W2NW4 of Section 13, Township 10 North, Range 61 West of the 6th P.M., Weld County, Colorado. Comments concerning this land use application are as follows: Building Inspection: No comments at this juncture The Environmental Health Department did not have an opportunity to review the application for completeness at this juncture, please email or telephone Heather to discuss and seek further direction. The contact for this land use application will be Heather Barbare with Environmental Health, (970) 304- 6415, extension 2223. The Planning Services — Development Review Engineer has reviewed the 7-Day Completeness Review and for completeness and has determined there is sufficient documentation to proceed with the application. The following items were submitted: Site Plan -- Submitted Traffic Study -- A traffic study was submitted by Aldridge Transportation Consultants dated 7/14/ 14. Drainage Report -- A water quality capture volume calc was submitted by Wernsman Engineering dated 7/22/14 Geotechnical Report — Not in a Geohazard Area. A GeoHazard Area and a Geologic Hazard Permit is not required. Flood Hazard Development Standards — Not in a FEMA Floodplain. A Flood Hazard Development Permit is not required. Improvements - Improvements/Road Maintenance Agreement is required. A draft of the agreement will be provided to the applicant after approval of the application at the BOCC hearing Access Permit — An access permit application has been submitted with photos. The contact for this land use application will be Wayne Howard 970.356.4000 extension 3551 . The Department of Planning Services has reviewed the submitted materials for the C-9 High Sierra Water Solutions nka NGL Water Solutions, DJ, LLC facility and will be looking for the following documents: One original application form Please amend to state the Legal Description as Lot A of RECX14-0095 being part of the W2NW4 of Section 13, Township 10 North, Range 61 West of the 6th P.M., Weld County, Colorado Please amend your request to state: A Class II Oilfield Waste Disposal Facility - Saltwater Injection Facility and a water recycling facility) operating 24 hours per day, 7 days each week, 365 days per year with unlimited truck trips to the facility. Please submit an updated and accurate site map delineating the tank farms, by type (SWD v. Recycle); the sump, the French drains, offload pad, offload bays, site lighting, gate at entrance if any, proposed access - back to back cattle guards with 100 feet of pavement or 300 feet of pavement; Facility sign; Facility Office et cetera. Please submit all property Deeds associated with this parcel, including the Deed describing Lot A of RECX14-0095. Per the Certificate of Conveyances signature page, there should be 10 property Deeds. Please provide detailed responses to the Special Use Permit Questionnaire in narrative format. Please submit a Waste Handling Plan, identify the waste stream products Please submit a Dust Abatement Plan Please submit a Onsite Wastewater Treatment Systems Plan Please submit a potable water permit through the Division of Water Resources. Please submit a Detailed Closure Plan. Please submit a list of all chemicals stored on site. Complete MSDS cut sheets as applicable. Please submit a Secondary Containment narrative. Provide documentation of secondary containment for all storage and treatment tanks. Containment shall be concrete (pad and wall including pad beneath tanks). Containment volume shall be of sufficient capacity to contain the volume of the largest single tank including sufficient freeboard for precipitation. The department will consider containment other than concrete provided a co pe certifies that the alternative liner material meets or exceeds the expected function of concrete with regards to spill containment. A Colorado registered professional engineer shall design the structure. Typically, containment plans should be submitted prior to release of building permits. Unloading trucks tank and coupling must be over a concrete unloading pad. The design shall demonstrate how all spilled waste, stormwater, and wash down water will be contained within the receiving areas and sumps. The design shall also include the method in which seams will be sealed to prevent leakage through the pad. A leak detection system shall be designed and installed beneath all newly constructed concrete unloading pad(s) and associated sump(s). A Colorado registered professional engineer shall design the structure. Please submit a Groundwater Monitoring Plan. Groundwater Monitoring Plan to detect release from surface activities. In addition to plan, facility will provide monitoring well drilling and development information and monitor quarterly for chlorides, sulfates, pH, TPH, TDS, PAHs, and BTEX. Department may later approve change in monitoring frequency to semi-annual (do not include an assumed reduction of frequency in the plan). Typically, this is submitted prior to recording the plat and a development standard is included to comply with approved monitoring plan. Please provide all documents associated with State permitting, including evidence of an Air Pollution Emission Notice (APEN) and Emissions Permit application from the Air Pollution Control Division, et cetera. Please submit a SPCC, spill prevention control and countermeasure plan. Please reach out to the Fire District and the Office of Emergency Management to initiate discussions on what will be required for development of an Emergency Action and Safety Plan with the Office of Emergency Management and the Fire District prior to operation. (Department of Planning Services) As a condition of approval, NGL Water Solutions DJ, LLC will be requesting a partial vacation of USR12- 0077 for the Pawnee Water Management upload and storage facility located on Lot B of RECX14-0095 Please provide one (1 ) digital or electronic copy of completed application materials. Please submit the application fee in the amount of $2500.00 dollars payable to the Department of Planning Services. This phase of the planning process is a content review of the submitted materials, NOT a technical review. Comments made during this phase of the process will not be all-inclusive. County staff will perform a detailed technical review of the project once the submittal application is deemed acceptable and is promoted to the review phase of the planning process. With documents and formatted materials received as specified herein and re-submitted to this office for case initiation and set-up, staff will commence with the referral process. Should you have additional questions or require clarification on any of the points presented herein, please contact this office. Thank you. Sincerely, Kim Ogle Planning Services ec: W. Howard, Planning-Engineering H. Barbaro, Environmental Health F. Piacentino, Building File: PRE14-0164 MEMORANDUM deti TO: Kim Ogle, Planning Services DATE: September 24, 2014 — FROM: Heather Barbare, Environmental Health SUBJECT: PRE14-0164, NGL C-9, 7 Day Completeness Review Weld County Environmental Health has received the submittal application for the 7-Day Completeness Review. This phase of the planning process is a content review of the submitted materials, NOT a technical review. We will perform a detailed technical review of the project once the submittal application is deemed acceptable and is promoted to the review phase of the planning process. ➢ Waste Handling Plan — Submitted. ➢ Dust Abatement Plan -- Submitted. A Sewage Disposal Information — Submitted. Application indicates a septic system will be designed. ➢ Potable Water Information — Insufficient Information Submitted. Pre-Application indicates bottle water will be provided, however Application does not provide enough information about number of employees onsite at one time to indicated bottled water would be allowed. ➢ APEN/Air Emissions Permit Application- Not Submitted. Can be submitted as COA prior to recording the Plat and prior to construction. ➢ Design, Secondary Containment, and Unloading Pad Information — Not Submitted. Can be submitted as COA prior to construction. ➢ Groundwater Monitoring Plan - Not Submitted. Can be submitted as COA prior to recording the Plat and prior to construction. ➢ Spill Prevention, Control, and Countermeasure Plan — Not Submitted. Can be submitted as COA prior to recording the Plat and prior to construction. A Emergency Action Plan — Not Submitted. Contact Weld County OEM. ➢ Closure Plan — Not Submitted. Can be submitted as COA prior to recording the Plat and prior to construction. A Other - None Environmental Health does not have adequate information for Use by Special Review. NGLWS C9 SWD Facility Expansion: Site Specific Development Plan and Use by Special Review (USR) Questionnaire 1. Explain, in detail, the proposed use of the property NGL Water Solutions proposes to amend the current USR to allow for the construction and operation of its C9 SWD facility. The 30,000 BBL facility will operate as a self-contained class II oilfield waste disposal facility (saltwater injection and water recycling facility) operating 24 hours per day, 7 days per week, 365 days per year with unlimited trucks trip to the facility. 2. Explain how this proposal is consistent with the intent of the Comprehensive Plan pursuant to Chapter 22 of the Weld County Code. Section 22-2-70 of the Weld County Code describes allowing industrial development that is compatible with the surrounding environment. The site will not hinder the agricultural landscape of its surrounding neighbors due to it operating as a self-contained facility. 3. Explain how this proposal is consistent with the intent of the Weld County Code, Chapter 23 (Zoning) and the zone district in which it is located. This facility is classified as a mineral resource development facility per Chapter 23 section A.1 of the Weld County Code. The site will not interfere with the neighboring agricultural landscape, nor will it keep its neighbors from conducting agricultural activities. This site is, and will remain fully contained. 4. What type of uses surround the site (explain how the proposed use is consistent and compatible with surrounding land uses). The property surrounding this site is a mix of agricultural, and Oil/Gas infrastructure. As described above, this site will be fully contained and will not hinder the production, or landscape, of its neighbors. 5. Describe, in detail, the following: a. Number of people who will use this site In a 24-hour period, there will be 5 total employees that will operate the facility. There will be a maximum of 250 truck trips to this facility in a 24-hour period, with an average of fewer than 25O. NGL Water Solutions requests allowance of unlimited truck trips per day to compensate for this fluctuation. b. Number of employees proposed to be employed at this site In a 24-hour period, there will be 5 total employees that will operate this facility. c. Hours of operation NGL Water Solutions requests 24-hour operations at this facility to handle the growing demand in the region. d. Type and number of structures to be erected (built) on this site A 13,464 sf tank farm is proposed to be constructed on this site as well as a 4,000 pump house and a 17,388 sf offload pad. e. Type and number of animals, if any, to be on this site No animals will be on this site. f. Kind of vehicles (type, size, weight) that will access this site and how often Liquid transportation trucks weighing up to forty (40) tons will visit this site. A maximum of 250 truck trips will be made to this site per 24-hour period. g. Who will provide fire protection to the site Pawnee Fire Department will provide fire protection for this site. h. Water source on the property (both domestic and irrigation) Bottled water will be brought in to this site for domestic use. Non-potable water will be obtained from storage tanks near the site for toilets, etc. All spigots will be marked "non-potable." i. Sewage disposal system on the property (existing and proposed) A proposed septic system designed by CDS Engineering will handle all sewage disposal at this site. j. If storage or warehousing is proposed, what type of items will be stored A 40'x100' pump house building will store pumps and other equipment. Tankage in the concrete tank farm will store produced water and oily water. k. Explain where storage and/ or stockpile of wastes will occur on this site. Due to this facility's operation as a fully self-contained facility, there will be no stockpile of wastes on this site. All produced water will be recycled or injected. 6. Explain the proposed landscaping for the site. The landscaping shall be separately submitted as a landscape plan map as part of the application submittal. There is no proposed landscaping for this site. 7. Explain any proposed reclamation procedures when termination of the Use by Special Review activity occurs. The existing disposal system tank farm and associated berm will be removed once the existing well is terminated. All tanks and associated piping will be removed and disposed of off-site. The existing berm will be removed and the berm area will be re-graded to match site grading for required drainage patterns. Any contaminated soils will be removed and disposed of off-site at an approved facility. S. Explain the storm water drainage will be handled on the site. The proposed plan will collect on site flows and direct them around the proposed improvements to the water quality pond in the south west corner of the site. When the water quality pond reaches capacity at elevation 5046 storm-water will flow to the south as sheet flow. Storm water will travel approximately 435 feet south on the lot to further dissipate flows before they travel onto the neighboring property to the south. 9. Explain how long it will take to construct the site and when construction and landscaping is scheduled to begin Contingent upon the final USR and permit approval, construction will start as soon as possible thereafter. The total project duration is approximately 6 months long and is expected to complete in early April 2015. 10. Explain were storage and/stockpile of wastes will occur on this site Due to this facility's operation as a fully self-contained facility, there will be no stockpile of wastes on this site. All produced water will be recycled or injected. Waste Handling Plan: All waste disposed of from this site is collected once a week from Waste Management. Address: 11655 CR 59 Keenesburg, CO 80643 Phone: (303) 732-0218 Account No. : 855-1008888-2534-4 Dust Abatement Plan: The sites will be posted for a maximum speed of 5 mph. An annual road treatment of Magnesium Chloride has been, and will continue to be practiced for soil stabilization and dust control on all site road ways. Construction, LLC hi2861 W. 120th Ave., Suite 250 Westminster, CO 80234 -40r Phone: (720) 708-6535 • October 16, 2014 Heather Barbare, Environmental Heath 1555 North 17th Avenue Greeley, Colorado 80631 Re: 7-Dy Completeness Review for the NGL Water Solutions DJ, LLC, C-9 Facility Potable water Information: In a 24-hour period, there will be 5 total employees that will operate this facility. Bottled water will be provided for onsite personnel. Non-potable water will be obtained from storage tanks near the site for toilets, ect. All spigots will be marked "non- potable" C9 Secondary Containment Narrative The purpose of this document is to provide supplementary information to the containment storage calculations provided below. There are two containment areas on the C9 SWD facility, a tank farm containment and offload containment. The tank farm and offload containments are not hydraulically connected, thus the containment volumes are calculated separately. Both containments are constructed out of concrete, designed by a Colorado Professional Engineer. The required volume for each containment area is determined as the 125% of the largest tank that would be observed in that containment area plus the 25-year return interval, 24-hour storm. The design of the tank farm containment consists of a tank pad, tank farm sump and tank farm perimeter wall (all concrete). An underdrain system will be installed to convey water from the tank pad to a sump contained in the southeast corner of the tank farm . The wall height of the tank farm perimeter wall is adequate to store 125% of the largest tank (1000 bbl) plus precipitation. The design of the offload pad consists of two surfaces—the offload approach and offload departure pads—sloped towards an offload trench. The offload trench is designed to convey all fluid at a 2% slope towards the offload sump. The combined volume of the offload pad, offload trench, and offload sump is adequate containment storage as defined above (125% of the largest tank plus precipitation). During offload of each truck, the truck tank, and coupling is over part of either the approach or departure pad or the offload trench. Any construction joints will be sealed to prevent leaking through containment, additionally a 30 mm liner will be installed underneath the offload trench and offload sump containment. Additionally, a 3" PVC pipe will be installed under the offload sump to monitor any leaks in the containment. Secondary Containment Calculations bbl := 42 gal Tank Pad Containment L := 153.5 ft Length of the Tank Pad W:= 88.666 ft Width of the Tank Pad Ata faun := L • W= 13610.2 ft2 Eq. [11 Plan Area of the Tank Pad L_PDS-based point precipitation frequency estimates with 90% confidence intervals (in inches)1 DII Average recurrence interval (years) _ 1 2 if 5 f 10 25 l 50 100 ih 200 500 1000 5-min0.242 0.292 0.389 0.483 0.633 0.764 0.910 1.07 1.31 1.50 (0.203-0.292) (0.245-0.353) (0.324-0.472), (0.399-0.590), (0.508.0 834); (0.590.1.02)] (0.670-1.25) '0.745-1.53!1(0.863-1.93 (0.952-2.23) 0355 10-min (0297.0.428) (0.358-0.95181(0.4074-0.691) (0.584.0.863), (0:44 1.22) (0.864-1.49) (0.980-1.83) (1.09-2.23) [(1269282) ( ler. -.20 I0570 707 926 12 33 57 (1.39-3.26) ; 0.433 0.522 0.695 0.862 1.13 1.36 1.62 1.91 2.34 2.69 15-min $(0.362-0.522 (0.578-0.843) (0.713-1.05) (0.907-1.49) (1.05-1.82) (1.20-2.23) (1.33-2.72) _(1 54-3.44) I (1.70-3.98) 30-min0.581 0.700 0.930 1.16 1.52 1.83 2.19 258 1 3.16 3.63 (0.487-0.701) (0.585-0.846)1 (0.774-1.13) (0.955-1.41) j (1.22.2 00) i (1.42-2.45) (1.61-3.01) (1.79-3.68) (2 08-4.65) 1I (2.30-5.38) 0.722 0.858 1.13 1.41 1.86 2.27 2.73 3.25 4.01 4.65 60-ruin (0.605-0.871) (0.717-1.04) (0.942-1.37) (1.16-1.72) (1.50-2.47) (1.76-3.04) (2.01-3.77) (2.26-4.64) (2.65-5.92) 1(2.949.88) 2-hr 0.863 1.01 1.33 1.66 2.21 2.71 3.27 3.91 4.86 5.66 (0.727-1.03) (0.854-122) (1.12-1.61) (1.38-2.01) (1.80-2.92) (2.12-3.61) (2.44-4.49) (2.75-5.55) (325-7.12) (3.62-8.30) 3-hr 0.946 1.10 1.44 119 2.38 2.93 3.55 4.26 5.32 6.21 (0.800-1.13) (0.930-1.32) (121-1.72) (1.49-2.16) (1.95-3.15) (2.30-3.89) (2.66-4.86) (3.02-6.02) (3.58-7 75) (4 00-9.07) L 6-hr 1.08 I 1.28 I 1.67 2.07 tI 2.73 3.32 3.98 4.73 5.83 1 6.76 (0.923-128) l (1.09-1.52) (1.42-1.99) (1.74-2.48) (2.24-3.54) (2.62-4.35) (100-5.37) (3.37-6.59) (3.95-8.39) (4.39-9.76) 12-hr 1.27 1.51 1.97 2.41 3.09 3.69 4.34 5.06 6.11 L 6.96 (1.09-1.49) (1.29-1.78) (1.68-2.33) (2.03-2.86) _(2.54-3.94) (2.92-4.75) (329-5.76) (3.63-6.95) , (4.17-8.66) (4.58-9.96) 24-hr 1.51 1.78 2.27 2.73 I 344 4.05 4.71 5.44 6.48 7.33 (130-1.76) a (1.53-2.08) [ (1.95-266) (2.32.322) L(2.84-4.32) J (323-5.15) (3.604.18) (3.944.37) (4.47-9.08) (4.87-10.4) , 1.75 2.06 2.61 3.11 3.85 4.47 5.12 5.83 6.83 7.63 2-day (1.51-2.02) (1.78-2.38) (225.3.04) (2.66-163) a (3.18-4.75) (3.58-5.60) (3.934.62) (425-7.79) (4.75-9.44) (5.12-10.7) 1.91 2.22 ' 2.78 3.28 4.03 4.66 5.32 6.03 7.04 7.85 (1.66-2.20) (1.93-2.57) (2.41-3.22) (2.82-3.82) (3.35-4.95) , (3.75-5.80)J (4.114.84) (4.42-8.02) (4.92-9.67) (5.30-10.9) 2.04 2.36 2.93 3.44 4.19 4.82 549 6.20 7.21 8.02 4-day (1.77-2.34) (2.05-2.71) (2.54-3.38) (2.96-3.99) (3.49-5.12) (3.90-5.98) (4.25-7.02) (4.57-8.21) (5.06-9.86) (5.44-11.1) 7-day 2.31 2.69 3.35 3.91 4.71 5.35 6.01 6.71 7.65 8.39 (2.02-2.63) (2.36-3.08) (2.92-3.84) 1 (339.4.51) (3.93-5.67) (4.34-6.56i (4.68-7.59) (4.96-8.75) (5.41-10.3) (5.74-11.5) 10-day 2.55 1 298 3.71 _ 4.31 5.15 5.80 646 7.14 8.04 822 (2.24-2.90) (2.62-3.40) (3.24-4.23) (3,75.4.95) (4.50-6.15) (4.71-7.05) (5.04-8.09) (5.30-9,24) (5.70-10.8) I(6.00-11.9 ;1 20-d 3.26 3.77 4.81 5.29 6.21 6.91 7.59 8.28 9.16 9.81 ay 1 (2.88-3.67) (3.34.4.28) (4.06-5.22) (4.63-6.03) (5.21-7.31) (5.65-829) (5.97-9.38) (6.19-10.6)_ (6.56-12.1) (6.83-13.3) 3.83 441 5.33 6.08 7.08 7.83 8.56 9.28 10.2 10.9 30-day-dayI(3.40-4.30) (191-4.95) (4.716.01) ll (5.344.89) (5.96-820) (6.43-9.33) (6.75-10.5) (6.98-11.8) (7.34-13.4) (7.61.14.6) 45-day 4.50 5.18 6.25 7.11 8.23 9.07 9.87 10.6 11.6 12.3 (4.02-5.04) (4.61-5.80) (5.55-7.02) (6.26.8.02) (6.95-9.56) (7.47-10.7) (7.82-12.0) (8.05-13.4) (8.41-15.1) (8.68-16.4) 5.05 5.83 1 7.05 60-day1 1-dey , (4.52-5.63)5.63) (5.21-6.50) (627-7.89) (7.09-9.02) (7.85-10.7) (8.42-12.0) (8.79-13.4) 1 (9.02-4.9) (9.38-16.7) (9.66-18.1) I Precipitation frequency (PF) estimates in this table are based on frequency analysis of partial duration series (PDS). Numbers in parenthess are PF estimates at lower and upper bounds of the 90% confidence interval. The probabilty that precipitation frequency estimates (for a given duration and average recurrence interval) will be greater than the upper bound (or less than the lower bound) is 5%. Estimates at upper bounds are not checked against probable maximum precipitation (PMP) estimates and may be higher than currently valid PMP values. Please refer to NOAA Atlas 14 document for more information. 'precipitation := 3.44 in 25-yr, 24-hour storm intensity V precipitation :='precipitation .Atankfarm= 3901.6 ft 3 Eq. [2] Vprecipitatian = 694.9 bbl 25-yr, 24-hour storm volume in tank farm Vdargesttank := 1000 bbl Volume of largest tank in tank farm View = 1.25 • Viargestta,,,k + VpTecipitat = 1944.9 bbl Eq [3] Req'd tank farm contain 2 71- • ( 15.5 ft) = 188.7 t2 E Footprint of 15.5' tanks A15.5tank = 4 f q [4] P 2 Al2tank • (12 ft) = 113.1 ft2 Eq [5] Footprint of 12' tanks 4 n15.5tank := 17 Number of 12' and 15.5' tanks n12tank := 10 Aeff containment :=Atankfarme (n15.Stank 'A15.stank + ni2tank •Al2tank) = 9271.5 ft 2 Eq [6] Effective containment area of the tank farm Hcontainment := V t°ta = 1.2 ft Eq [7] Required Wall Hight for Tank Farm Aef f containment Result is a tank farm wall height of 1.5' per preferred structural wall height. Unloading Pad Containment Required Storage for Unloading Pad Loffload :Y 107.5 ft Length of offload pad W offload = 160 ft Width of offload pad Aunload := Loffload • W offload = 17200 ft 2 Footprint of offload pad Eq. [8] Volume of V precipitation := 'precipitation •Au,il°ad = 878.2 bbl precipitation from offload pad Vtruck := 150 bbl Voffioad_req'd := Vprecipitation + 1 '25 " V tck = 5983.4 ft3 Eq. [9] Total Required Offload Storage Storage Provided by Offload Pad Geomety 1. 17 ft • 80 ft • W°f fj°ud — 3 Eq. [10] Volume from _ — 7488 f t offload pad approach slope Voffload_approach : 2 `; Eq. [11] Volume from 1.17 ft • 25 ft • W V offload = 2340 ft offload pad departure slope offload_departure 2 Woffload_trencit := 2.5 ft Width of offload pad trench Lof fload_trench := W offload — 1 ft = 159 ft Length of offload pad trench soffload_trertclt := 0.02 `f t Slope of offload pad trench ft Dofftoad_trer,ch US := 10 in Depth of offload pad trench at upstream side 2 * Dof f load trench_US + S of f load_trench Lof• fload_trettc:h Voffload_trench := Woffload_trertch ' Loffload_trench ' ! ) I = 963.3 ft3 2 Eq. [ 12] Volume stored in offload pad area Storage Provided by Offload Sump Lof fload_sump := 20 ft Length of offload sump Wo ffload_ untp := 12 ft Width of offload sump Doffload_sump := 6 ft Depth of offload sump Vofftoad_sgum,p :' Loffload_sump • Woffload_sump • Dofftoad_sump = 1440 ft3 Eq. [13] Volume of offload sump Total Available Storage Vofftoad := Voffload_approach + Voffload_departure + Voffload_trench + Voffload_sump = 12231.3 ft3 Eq. [14] Story9 e := (Voffload >ifVoffload_reqd > "adequate" > "inadequate") = "adequate" FOR COMMERCIAL SITES, PLEASE COMPLETE THE FOLLOWING INFORMATION BUSINESS EMERGENCY INFORMATION Business Name: NGL Energy Partners Phone: 303-815-1010 Address: 3773 Cherry Creek Drive North, Suite 1000 City, ST, Zip: Denver, CO, 80209 Business Owner: NGL Energy Partners Phone: 303-815-1010 Home Address: 3773 Cherry Creek Drive North, Suite 1000 City, ST, Zip: Denver, CO, 80209 List three persons in the order to be called in the event of an emergency: NAME TITLE ADDRESS PHONE Josh Patterson Operation Managers 8207 W 20th St, Ste B, Greeley CO, 80634 303-868-1286 Josh Hamlen Operations 8207 W 20th Sts Ste B, Greeley CO, 80634 303-868-1286 Doug White Operations 3773 Cherry Creek Drive North, Suite 1000 303-815- 1010 Business Hours: Days: Type of Alarm: None Burglar Holdup Fire Silent Audible Name and address of Alarm Company: N/A Location of Safe: None MISCELLANEOUS INFORMATION: Number of entry/exit doors in this building: 4 Location(s): North , East, and South Side Is alcohol stored in building? No Location(s): Are drugs stored in building? No Location(s): Are weapons stored in building? No Location(s): The following programs are offerecn a public service of the Weld Coun riffs Office. Please indicate the programs of interest. Physical Security Check � �Crime Prevention Presentation UTILITY SHUT OFF LOCATIONS: Main Electrical: Electrical Room Gas Shut Off: N/A- There is no gas service to this facility Exterior Water Shutoff: TBD TBD Interior Water Shutoff: WELD COUNTY ACCESS PERMIT c_o4, Weld County Public Works Dept. �<>41 �'A Phone: (970) 304-6496 1111 H Street After Hours: (970) 356-4000 P.O. Box 758 -o le% r Emergency Services: (970) 304-6500 x 2700 Greeley, CO 80632 �� OQ� Inspection: (970) 304-6480 /C W Permit Number: API4-00407 Issuance of this permit binds applicant and its contractors to all requirements, provisions, and ordinances of Weld County, Colorado. Project Name: RECX14-0095 NGL C9 Facility Expiration date: 03/15/2015 Applicant Information: Property Owner Information: Name: Ted Lopez Name: Company: NGL Water Solutions do M3 Construction Company: Grassland Water Solutions Phone: 720-708-6535 Phone: 970-232-3316 Email: tlopez@m3-construct.com Email: mseume@grasslandwatersolutions.com Location: Proposed Use: Access is on WCR: 95 Temporary: Nearest Intersection WCR: 95 & WCR: 118 Single Residential: Distance From intersection: 1715 Industrial: Number of Existing Accesses: 1 Small Commercial: Planning Process: RE RECX14-0095 Oil & Gas: Ea Large Commercial: Road Surface Type & Construction Information: Subdivision: Road Surface: Gravel Field (Agricultural Culvert Size & Type: 15" CMP/RCP min. Only)/Exempt: Start Date: 09/01/2014 Finish Date: 03/01/2015 Materials to Construct Access: gravel Required Attached Documents Submitted: Traffic Control Plan: No Certificate of Insurance: Yes Access Pictures: No A copy of this permit must be on site at all times during construction hours Daily work hours are Monday through Friday DAYLIGHT to ' HOUR BEFORE DARK (applies to weekends if approved) Approved MUTCD traffic control/warning devices are required before work begins and must remain until completion of work Special_Requirements or Comments Parcel 029113200009. Utilize NEW access points on CR 95 for Lot A (2-O&G) located approx. 1715 ft. & 2060 ft. South of CR 118. Utilize existing access point on CR 95 for Lot B (1 -Small Commercial) located approx. 1395 ft South of CR 118. Permit approval conditional on USR approval. Approved by: Gabbert D1gre'rrgnedbyM°tgan Weld County Public Works Date: 10/3/2014 ON:cn-M organ Gabbers,o,nirdia ou, ernalLmgab berteweldgov.com, c=US Date:2014.10M3 1234:46-06'00' Print Date -Time: 10/3/2014 12:54:23PM Report ID: PW00008v001 Page 1 of 1 ` 2 4 2014 Energy Partners LP 8207 W. 20Th St., Suite B Greeley, CO 80634 July 9, 2014 FedEx: 805588854648 Colorado Department of Public Health and Environment Air Pollution Control Division 4300 Cherry Creek Drive South, APCD-SS-B 1 Denver, CO 80246-1530 Subject: C-9 Salt Water Disposal Facility General Permit Applications and Construction Permit Application NGL Water Solutions DJ, LLC Weld County, Colorado To Whom It May Concern: NGL Water Solutions DJ, LLC is submitting a construction permit, GP01 and GP05 application for the C-9 Salt Water Disposal Facility (Facility) located at W 1 NW to Section 13, T1ON, R61 W, Weld County, CO. The facility is a new facility with a maximum facility throughput of 30,000 bbl/day of trucked in water. Facility wide emission units will include: Desanding Tank (3 x 700 bbl) Sale Oil Tank (1 x 450 bbl) Sand and Oil Removal Tank (3 x 1000 bbl) Produced Water Unloading Sump Oil Heating Tank (1 x 450 bbl) 1-500 gal Diesel Tank Water Equalization Tanks (12 x 840 bbl) Electric Tank Heater Post-Filter Tanks (2 x 1000 bbl) Loadout Oil Tanks (4 x 450 bbl) Fugitives Slop Oil Tank (I x 450 bbl) Facility emission calculations, application forms, APENs, and supporting documentation are included in the attachments. A check for$3,529.00 in full payment of the APEN filing and general permit registration fees is attached. If you have any questions or need additional information, please contact me at 303- 536-4408 (jpatterson@highsierraenergy.com). Sincerely, NG Water Solutions D.1, LLC Josh Patterson VP of Operations Enclosures Appendix A— Permit Application Appendix B—APCD-102 and APEN Forms Appendix C—Regulatory Review Appendix D—Facility Emission Calculations and Supporting Documentation Appendix E—Process Description, Process Flow, Facility Location,and Plot Plan Appendix A Construction Permit Application Air Pollution Control Division (APCD) - Construction Permit Application PLEASE READ INSTRUCTIONS ON REVERSE SIDE. 1. Permit to be issued to: NGL Water Solutions DJ, LLC 2. Mailing Address: 8207 West 20th Street.Suite B Greeley,CO 80634 3. General Nature of Business: Oil and Gas Produced Water Storage SIC code(if known) 4. Air Pollution Source Description: C9 Salt Water Disposal Facility (List permit numbers if existing source, Permit Pending,GPOI Pending,GP05 Pending attach additional pages if needed) Is this a Portable Unit? No 5. Source Location Address(Include Location Map) If portable,include the initial location and home base location W ''A NW'/ SECTION 13.T l ON. 1(61W 6. Reason for Application:(Check all that apply) • New or Previously Unreported Source Administrative Permit Amendments ❑ Modification of Existing Source ❑ Transfer of Ownership(Complete Section 9& 10 below) ❑ Request for Synthetic Minor Permit ❑ Company Name Change(Complete Section 9 below) ❑ Other: ❑ Other: 7. Projected Startup Date: 2014 - /0- i`f Sig re of Legally Authorized Pe on of Company listed in Section I Date Signed Josh Patterson. VP of Operations Phone: 303-536-4408 Type or Print Name and Official Title of Person Signing Above Fax: 303-536-4096 8. Check appropriate box if you want: ® Copy of preliminary analysis conducted by Division ® To review a draft of the permit prior to issuance These sections are to he completed only if a company name change or transfer of ownership has occurred. 9. Permit previously issued to: 10.Transfer of Ownership Information Effective Date of Permit Transfer: As responsible party for the emission source(s)listed above. I certify that the business associated with this source has been sold,and agree to transfer the permit to said party. Signature of Legally Authorized Person of Company listed in Section 9 Date Signed Phone: Type or Print Name and Official Title of Person Signing Above Fax: Mail completed application, APENs,and filing fee to: Colorado Department of Public Health and Environment Imp:/rwww.cdphe.state.co.us,ap/stationary.Iuml Air Pollution Control Division Phone:(303)692-3150 4300 Cherry Creek Drive South,APCD-SS-B Denver,Colorado 80246-1530 Revised August2004 Appendix B APCD- 102 and APEN Forms AIR POLLUTANT EMISSION NOTICE (APEN) & Application for Construction Permit—Fugitive Component Leak Emissions Permit Number: I W E 17--+C [Leave blank unless APCD has already assigned a permit#&AIRS ID] Emission Source AIRS ID: (Z 3 / 9 DC) / CC) I Facility Equipment ID: Fugitives [Provide Facility Equipment ID to identify how this equipment is referenced within your organization.] Section 01—Administrative Information Section 02—Requested Action(Check applicable request boxes) Company Name: NGL Water Solutions DJ,LLC NAICS,or ® Request for NEW permit or newly reported emission source Source Name: Fugitives SIC Code: O Request MODIFICATION to existing permit(check each box below that applies) Source Location: C9 Salt Water Disposal Facility County: Weld El Change process or equipment O Change company name W'/A NW V.SECTION 13,T10N,R61W Elevation: Feet ❑ Change permit limit O Transfer of ownership El Other Mailing Address: 8207 West 20th Street,Suite B ZIP Code: 80634 O Request to limit HAPs with a Federally enforceable limit on PTE Greeley,CO ❑ Request APEN update only(check the box below that applies) Person To Contact: Josh Patterson Phone Number: 303-536-4408 ❑ Revision to actual calendar year emissions for emission inventory E-mail Address: jpattersonrahighsierraenergy.com Fax Number: 303-536-4096 ❑ Update 5-Year APEN term without change to permit limits or previouslyreported emissions Additional Info.& Section 03—General Information Notes: For existing sources,operation began on: / / For new or reconstructed sources,the projected startup date is: / / 2014 Normal Hours of Source Operation: 24 hours/day 7 days/week 52 weeks/year Brief description of equipment associated with these components: VOC Fugitives Will this equipment be operated in any NAAQS nonattainment area? Don't (http://www.cdphe.state.co.us/ap/attainmaintain.html) ® Yes El No ❑ know Section 04—Regulatory Information Colorado Department of Public Health and Environment Air Pollution Control Division(APCD) Is this equipment subject to NSPS 40 CFR Part 60,Subpart KKK? O Yes ® No Don ❑ kno't This notice is valid for five(5)years. Submit a revised APEN prior to Don't expiration of five-year term, or when a significant change is made Is this equipment subject to NESHAP 40 CFR Part 63,Subpart HH? O Yes ® No ❑ know (increase production,new equipment,change in fuel type,etc). List any other NSPS or NESHAP Subpart that applies to this equipment: Mail this form along with a check for S152.90 to: Colorado Department of Public Health&Environment APCD-SS-BI Section 05—Stream Constituents 4300 Cherry Creek Drive South ----- Denver,CO 80246-1530 sa.2 4 21‘1‘'‘ Identify the VOC&HAP content of each applicable stream. VOC Benzene Toluene Ethlbenzene \�lene n-llexane For guidance on how to complete this APEN form: Stream (K t.%) (NN t.%) (wt.%) (wt. %) (wt.%) (pct.%) Air Pollution Control Division: (30j4/2-3150 Gas Varies depending on tank contents(oil or water) Small Business Assistance Program(SBAP): (303)692-3148 or (303)692-3175 Heavy Oil(or Heavy Liquid) 100 1.92 3.38 0.08 1.27 15.22 APEN forms:hlip://www.cdphe.state.co.us/ap/downloadforms.html light Oil(or Light Liquid) 100 1.92 3.38 0.08 1.27 15.22 Application status:http://www.cdphe.state.co.us/ap/ss/sspept.html w ater/Oil 100 1.92 3.38 0.08 1.27 15.22 ® Submit a representatik c eas and liquid extended anal�,i,(including BTEX)to support emission calculations ® Check box to request copy of draft permit prior to issuance. ® Check box to request copy of draft permit prior to public notice. FORM APCD-203 1 4852 Page 1 of 2 Form_APCD-203_Fugitive_Component_Leaks_APEN AIR POLLUTANT EMISSION NOTICE(APEN) & Application for Construction Permit—Fugitive Component Leak Emissions Permit Number: IL I W a (Z1c Emission Source AIRS ID: 113 / 4 pps / CCU ( Section 06—Location Information(Provide Datum and either Lat/Long or UTM) Section 07—Leak Detection&Repair(LDAR)&Control Information Horizontal Datum UTM UTM Fasting or UTM Northing or Method of Collection for Check appropriate boxes to identify LDAR program conducted at this site: ' (NAD27,NAD83, Zone Longitude Latitude Location Data(e.g.map,GPS, 0 LDAR per NSPS KKK 0 No LDAR program WGS84) (12_or 13) (meters or degrees) (meters or degrees) GoogleEarth) ❑ Other If LDAR per NSPS KKK with 10,000 ppmv leak definition: ❑ Monthly monitoring.Control:88%gas valve,76%It.liq.valve,68%It.liq.pump ❑ Quarterly monitoring.Control:70%gas valve,61%It.liq.valve,45%It.liq.pump Section 08—Emission Factor Information Identify the emission factor used to estimate emissions under"E.F.",along with the units relating to the emission factor(e.g.lb/hr/component). ® Check this hos if you used Table 2-4 of U.S.EPA's 1995 Protocol for Equipment Leak Emission Estimates to estimate emissions. You do not need to enter the emission factors below if checked. Service _ Equipment Type Gas Heavy Oil(or Heavy Liquid) 1 Light Oil(or Light Liquid) Water/Oil Count' E.F. Units Count' E.F. Units Counts E.F. Units , Counts E.F. Units Connectors 647 17 220 1292 Flanges 301 0 0 810 Open-Ended Lines 17 3 2 68 Pump Seals 0 0 1 -1 Valves 7 3 37 364 Other 54 0 ______ 7 20 Count shall be the actual or estimated number of components in each type of service used to calculate the"Actual Calendar Year Emissions"below. ® Istimated Count ❑ 4wal(nuns;onJucted on the following date Section 09—Emissions Inventory Information& Emission Control Information ❑ Emission Factor Documentation attached Data year for actual calendar year emissions below(e.g.2007): I Control Device Description Control Emission Factor Actual Calendar Year Emissions2 Requested Permitted l;stimation Method Pollutant Efficiency Emissions or Primary Secondary (%Reduction) Uncontrolled Basis Units Uncontrolled Controlled Uncontrolled Controlled Emission Factor (Tons/Year) (Tons/Year) (Tons/Year) (Tons/Year) Source VOC 8.86 Benzene 0.27 Toluene 0.48 EPA-453/R-95- Ethylbenzene Identify in Section 07 Identify in Section 08 017,Table 2-4 Xylene 0.18 n-Hexane 2.17 Please use the APCD Non-Criteria Reportable Air Pollutant Addendum form to report pollutants not listed above. 2Annual emission fees will be based on actual emissions reported here. If left blank,annual emission fees will be based on requested emissions. 3 You may request permitted emissions in excess of actual emissions to account for component count and gas composition variability.If Requested Permitted Emissions is let)blank,emissions will be based on info.in Sec.03-09. Section 10 pplicant Certificate I ereby certify that all information contained herein and information submitted with this application is complete,true and correct. ( 7 (0 " f f Josh Patterson 4 2014 VP of Operations Signa }'e of Person Legally Au zed to Supply Data Date Name of Legally Authorized Perso ease print) Title JPage 2 of 2 Form_APCD-203_Fugitive_Component_Leaks_APEN AIR POLLUTANT EMISSION NOTICE (APEN) & Application for Construction Permit—Hydrocarbon Liquid Loading' Please use the Fuel Dispensing Station APEN to report emissions from service stations and fleet refueling stations. Permit Number: 1 LI WC\-1:1449 [Leave blank unless APCD has already assigned a permit#&AIRS ID] Emission Source AIRS ID: 17,3 / q DOS- / 00 l Facility Equipment ID: L-1 [Provide Facility Equipment ID to identify how this equipment is referenced within your organization.] Section 01—Administrative Information Section 02—Requested Action(Check applicable request boxes) Company Name: NGL Water Solutions DJ, LLC Action Applies To: 0 Individual Permit ❑ General Permit GP07 Source Name: L-1 NAICS,or I Request NEW permit or newly reported emission source Source Location: SIC Code: ❑ Request REGISTRATION for coverage under GP07&concurrent C9 Salt Water Disposal Facility request for CANCELLATION of individual permit number: W 1/2 NW 14 SECTION 13,T1 ON, R61W ❑ Request MODIFICATION to existing permit(check each box below that applies) Mailing Address: 8207 West 20th Street,Suite B County: Weld O Change process or equipment O Change company name Greeley,CO Elevation: Feet O Change permit limit O Transfer of ownership O Other Person To Contact: Josh Patterson ZIP Code: 80634 O Request to limit HAPs with a Federally enforceable limit on PTE E-mail Address: Request APEN update only.Note—Emissions data must be completed.Blank APENs jpatterson@highsierraenergy.com O will not be accepted Phone Number: 303-536-4408 Fax Number: 303-536-4096 Addl.Info.&Notes: Section 03—General Information Date operation began or projected startup date: / / 2014 Normal Hours of Source Operation: 24 hours/day 7 days/week 52 weeks/year General description of equipment and purpose: Oil Loadout ► Is this source located at an oil and gas exploration and production site? O Yes © No O Don't know If yes,does this source load less than 10,000 gallons of crude oil per day on an annual average,splash fill less than 6750 BBL of condensate per year Yes No Don't know or submerge fill less than 16,308 BBL of condensate per year? ❑ ❑ ► Is this source located at a facility that is considered a Major Source of Hazardous Air Pollutant(HAP)emissions? O YesA © No ❑ Don't know ► Will this equipment be operated in any NAAQS nonattainment area? (www.colorado.gov/cdphe/attainment) ® YesA ❑ No ❑ Don't know P. Does this source load gasoline into transport vehicles? O YesA WI No O Don't know A If"Yes",provide an applicability determination of state and federal rules. Colorado Department of Public Health and Environment Section 04-Loading Information Air Pollution Control Division(APCDI Product Loaded: ❑ Condensate 0 Crude Oil Other: This notice is valid for five(5)years. Submit a revised APEN prior to ► If this APEN is being filed for vapors displaced from cargo carrier,complete the following: expiration of five-year term, or when a significant change is made Annual Volume Loaded: Requested2: 328,500 bbl/year Actual calendar year: bbl/year (increase production,new equipment,change in fuel type,etc). This product is loaded from tanks at this facility into: Tank Trucks (e.g,"rail tank cars,"or"tank trucks") Mail this form along with a check for $152.90 per APEN & • If site-specific emission factor is used to calculate emissions(Not available for GP07),complete the following: $250.00 for each general permit registration to: Saturation Factor3: 0.6 Average Temperature of Bulk Liquid Loaded: 60 °F Colorado Department of Public Health&Environment True Vapor Pressure: 2.8 psia @ 60°F Molecular Weight of Displaced Vapors: 50 Lb/lb-mol APCD-SS-BI D. If this APEN is being filed for vapor losses from pressurized loading lines,complete the following: 4300 Cherry Creek Drive South Denver,CO 80246-1530 Loads per year: Requested2: #/yr. Actual Calendar Year: #/yr. Product Density: Lb/ft3 For guidance on how to complete this APEN form: Load Line Volume': Ft/truckload Vapor Recovery Line Volumes: Ft3/truckload Air Pollution Control Division: (303)692-3150 You may be charged an additional APEN fee for APEN re-submittal due to incorrectly filled-out APEN or missing information. Small Business Assistance Program(SBAP): 3 2 Requested values will become permit limitations for individual construction permits. gr ( 03)692-3148 or 'Please refer to AP-42,Table 5.2-1 for information on saturation factors(found online at:http:l/www.ena.aovlttn!chief/ap421ch115/indeN.html). (303)692-3175 4 List the total volume for all lines in each category and attach your calculations of these volumes. APEN forms:www.colorado.gov/cdphc/oilgasAPENS FORM APCD-208 4 Application status:www.colorado.eoNA:dnhe/permitstatus 314862 �4 Page I of 2 ','' 'Y FormAPCD-208-HydrocarbonLiquidLoadingAPEN-Ver.4-14-2014.docx AIR POLLUTANT EMISSION NOTICE (APEN) & Application for Construction Permit—Hydrocarbon Liquid Loading' Please use the Fuel Dispensing Station APEN to report emissions from service stations and fleet refueling stations. Permit Number: Iu WE,- tr+(, Emission Source AIRS ID: 17 3 / WOr / UOZ Section 05—Stack Information(Combustion stacks must be listed here) Section 06—Stack(Source,if no combustion)Location(Datum&either Lat/Long or UTM) Stack Discharge Operator Stack Base Horizontal Datum UTM UTM Easting or UTM Northing or Method of Collection for Stack Elevation Height Above Temp. Flow Rate Velocity Moisture Ground Level (°F) (ACFM) (ftlsec) ( „I (NAD27,NAD83, Zone Longitude Latitude Location Data(e.g.map, 1D No. (feet) (feet) WGS84) (12 or 13) (meters or degrees) (meters or degrees) GPS,GoogleEarth) I Direction of stack outlet(check one): ❑ Vertical O Vertical with obstructing raincap ❑ Horizontal O Down O Other(Describe): Exhaust Opening Shape&Size(check one): O Circular:Inner Diameter(inches)= O Other:Length(inches)= Width(inches)= Section 07—Control Device Information r❑ Loading occurs using a vapor balance system. ❑ Combustion De‘ice used for control of the loadout emissions. Rating: MMlttuihr ❑ Describe Any Other(Including VRU) Type: Make/ModeUSerial#: VOC&HAP Control Efficiency: Requested: % Manufacturer Guaranteed: ",, Minimum temp.to achieve requested control: °F Waste gas heat content: Btu/scf VOC&HAP Control Efficiency: Requested: % Constant pilot light? O Yes ❑ No Pilot burner rating: MMBtu'hr Section 08—Emissions Inventory Information O State Emission Factors(Required for general permit GP07-Optional for individual permit) ❑ Condensate _ VOC: 0.236 Lbs/BBL Benzene: 0.00041 Lbs/BBL n-Hexane: 0.0036 Lbs/BBL ❑ Crude Oil VOC: 0.104 Lbs/BBL Benzene: 0.00018 Lbs/BBL n-Hexane: 0.0016 Lbs/BBL Q Emission Factor Documentation attached(If using site specific emission factor) Data year for actual calendar year emissions below&throughput in Sec.04(e.g.2007): Control Device Description Emission Factor Actual Calendar Year Emissionss Requested Permitted Estimation Pollutant Control Efficiency Emissions Method or (%Reduction) Uncontrolled Controlled Uncontrolled Controlled Emission Primary Secondary Uncontrolled Basis Units (Tons/Year) _ (Tons/Year) (Tons/Year) (Tons/Year) Factor Source NOx VOC 2.01 lb/1000 gal 13.89 AP42 CO Identify in Section 07 Benzene 0.039 Ib/l00o gal _ 0.27 n-Hexane 0.306 lb/1000 gal 2.11 Eng. Cale Please use the APCD Non-Criteria Reportable Air Pollutant Addendum form to report pollutants not listed above. 'You may be charged an additional APEN fee for APEN re-submittal due to incorrectly filled-out APEN or missing information. 'Annual emission fees will be based on actual emissions reported here. Section 09—Applicant Certificatio er b, certify that all information contained herein and information submitte with this application is complete,true and correct. �{ 24 �� — Josh Patterson 4,-/- f4 VP of Operations Signatur erson Legally Authorized to Supply Data Da Name of Legally Authorizes a print) Title Page 2 of 2 FormAPCD-208-HydrocarbonLiquidLoadingAPEN-Ver.4-14-2014.docx NON-CRITERIA REPORTABLE AIR POLLUTANT EMISSION NOTICE ADDENDUM (See reverse side for guidance on completing this form) Permit Number: l - J[ \1-(r AIRS ID Number: iZ3I 9 Dos-1w - Company Name: NGL Water Solutions DJ, LLC Plant Location: C9 Salt Water Disposal Facility-W'/2 NW 1/4 SECTION 13,T10N, R61W County: Weld Zip Code: 80634 Person to Contact: Josh Patterson Phone Number: 303-536-4408 E-mail Address: jpatterson@highsierraenergy.com Fax Number: 303-536-4096 Chemical Abstract Control Equipment Emission Factor Emission Factor Uncontrolled Controlled Actual Service (CAS) Chemical Name / Reduction (%) (Include Units) Source Actual Emissions Emissions Number (lbs/year) (lbs/year) _ 108-88-3 Toluene NA 0.068 lb/1000 gal Eng. Calc. 939.85 NA 1330-20-7 Xylenes NA 0.026 lb/1000 gal Eng. Calc. 353.77 NA Cale da Year for which Ac D t Applies: Sig ture of Person Legally A horized to Supply Data Jt� Date Josh Patterson 4W14 VP of Operations Name of Person Legally Authorized to Supply Data (Please print) ` -iti Title of Person Legally Authorized to Supply Data Form Revision Date: April 14, 2014 AIR POLLUTANT EMISSION NOTICE(APEN) & Application for Construction Permit—Produced Water Tank Battery' Permit Number: GP05 [Leave blank unless APCD has already assigned a permit 4&AIRS ID] Emission Source AIRS ID: 12-3 1 q S / 00_3 Facility Equipment ID: Desand Tanks [Provide Facility Equipment ID to identify how this equipment is referenced within your organization.] Section 01—Administrative Information Section 02—Requested Action(Check applicable request boxes) Company Name: NGL Water Solutions DJ,LLC NAICS,or ® Request for NEW individual permit or newly reported emission source Source Name: Desand Tanks SIC Code: ❑ Request MODIFICATION to existing permit(check each box below that applies) Source Location: C9 Salt Water Disposal Facility County: Weld ❑ Change process or equipment O Change company name W'A NW''h SECTION 13,T10N,R61 W Elevation: Feet ❑ Change permit limit O Transfer of ownership El Other Mailing Address: 8207 West 20is Street,Suite B ZIP Code: 80634 ® Request for coverage under GENERAL PERMIT number GP05 Greeley,CO O Request APEN update only(check the box below that applies) Person To Contact: Josh Patterson Phone Number: 303-536-4408 ❑ Revision to actual calendar year emissions for emission inventory Update 5-Year APEN term without change to permit limits or previously E-mail Address: jpatterson@highsierraenergy.com Fax Number: 303-536-4096 O reported emissions Addl.Info. Section 03—General Information &Notes: For existing sources,operation began on: / / For new or reconstructed sources,the projected startup date is: / / 2014 Normal Hours of Source Operation: 24 hours/day 7 days/week 52 weeks/year General description of equipment and purpose: Desand Tanks:3 x 700 bbl ► Do these storage tanks contain less than 1%by volume crude oil on an annual average basis? ❑ Yes ® No ► Are these produced water tanks located at a commercial facility that accepts oil production wastewater for processing? ® Yes ❑ No Are these produced water tanks subject to Colorado Oil and Gas Conservation Commission(COGCC)805 series rules?If so, ❑ ► submit Form APCD-105. Yes ® No ► Is this source located in an ozone non-attainment area? ® Yes O No ❑ Don't Know Section 04—Tank Battery Information2 Colorado Department of Public Health and Environment Air Pollution Control Division(APCD) Number of tanks: 3 Total tank capacity(bbl): 2,100 Produced Water throughput: Requested;: 10,950,000 bbl/year Actual calendar year: bbl/year This notice is valid for five(5)years. Submit a revised APEN prior to expiration of five-year term, or when a significant change is made (increase production,new equipment,change in fuel type,etc). ► ,�Are Flash„4 emissions anticipated from these tanks? ❑ Yes ® No ► Is this tank located at an exploration&production(E&P)site?5 ❑ Yes ® No Mail this form along with a check for$152.90 per APEN for non- ID. Is this tank located at a non-E&P,midstream or downstream site?5 ® Yes ❑ No E&P, midstream and downstream sources or $152.90 for up to five(5)APENs for E&P sources and$250 for each general permit You will be charged an additional APEN fee if APEN is filled out incorrectly or missing information and needs re-submittal. registration to: 2See PS Memo 09-02 for information on produced water tank permitting. (http://www.coloradogw.rcdphe/psmemos) Colorado Department of Public Health&Environment _3 Requested values will become permit limitations. APCD-SS-BI ``''f-' Hydrocarbons contained in the produced water can"flash"into the vapor phase due to a reduction in pressure on the liquids. 4300 Cherry Creek Drive South a 24 21)/a 5 See PS Memo 09-02 for definitions of E&P,non-E&P,midstream and downstream. (http.//www.colorado.ao,./cdphe/psmemos) Denver,CO 80246-1530 For guidance on how to complete this APEN forte Additional Air Pollution Control Division: (303)692-3150 Information O Attach supporting documentation if site specific emissions factors developed and supplied on APEN. Small Business Assistance Program(SBAP): (303)692-3148 or Required: (303)692-3175 APEN forms:http://www,colorado.gov/cdphe/oilgasAPhNS Application status:http://www.colorado.cov/cdphe/nermitstatus FORM APCD-207 Page 1 of 2 31600 4 Desand Tanks Form APCD-207 Produced Water Tank A. AIR POLLUTANT EMISSION NOTICE (APEN)&Application for Construction Permit—Produced Water Tank Battervl Permit Number: GP05 Emission Source AIRS ID: 113 / 9Q,s- / O(j-c Section 05—Stack Information(Combustion stacks must be listed here) Section 06—Stack(Source,if no combustion) Location(Datum &either Latr1.on12 or t I \1) Stack Discharge Operator Stack Base Horizontal Datum UTM UTM Easting or UTM Northing or Method of Collection for Height Above Temp. Flow Rate Velocity Moisture Stack Elevation ° (NAD27,NAD83, Zone Longitude Latitude Location Data(e.g.map, ID No. (feet) Ground Level (°F) (ACFM) (ft/sec) (/o) WGS84) (12 or 13) (meters or degrees) gr ) (meters or degrees) GPS,GoogleEarth) (feeDirection of stack outlet(check one): ❑ Vertical O Vertical with obstructing raincap ❑ Horizontal O DoNA n O Other(Describe): Exhaust Opening Shape&Size(check one): O Circular:Inner Diameter(inches)= O Other:Length(inches)= Width(inches)= Section 07—Control Device Information ❑ Condenser used for control of the tank battery. ❑ Combustion Device used for control of the tank battery. Rating: \lblltui hr Type: Make/Model: Type: Make/Model/Serial#: Temperature(°F): Maximum: Average: VOC&HAP Control Efficiency: Requested: % Manufacturer Guaranteed: ", Requested VOC&HAP Control Efficiency: % Minimum temp.to achieve requested control: °F Waste gas heat content: Btu./scf ❑ VRU used for control of the tank battery. Constant pilot light? O Yes O No Pilot burner rating: \4M Hier hr Size: Make/Model: ❑ Closed loop system used for control of the tank battery. Requested VOC&HAP Control Efficiency: % Description: Annual time that VRU is bypassed(emissions vented): % ❑ Describe Any Other: Section 08—Emissions Inventory Information& Emission Control Information O Emission Factor Documentation attached Data year for actual calendar yr.emissions below&throughput in Sec.04(e.g.2007): V Control Device Description Control Emission Factor Actual Calendar Year Emissions4 Requested Permitted Estimation Method Pollutant - Efficiency Emissions or Primary Secondary (%Reduction) Uncontrolled Basis Units Uncontrolled Controlled Uncontrolled Controlled Emission Factor (Tons/Year) (Tons/Year) (Tons/Year) (Tons/Year) Source NOx VOC 3.48E-4 lb/bbl 1.91 EPA Tanks CO Benzene De minimis EPA Tanks Identify in Section 07 Toluene De minimis EPA Tanks 1 Ethylbenzene De minimis EPA Tanks Xylene De minimis EPA Tanks n-Hexane _ 5.30E-5 lb/bbl 0.29 EPA Tanks It Please use the APCD Non-Criteria Reportable Air Pollutant Addendum form to report pollutants not listed above. You will be charged an additional APEN fee if APEN is tilled out incorrectly or missing information and needs re-submittal. 'Annual emission fees will be based on actual emissions reported here. If left blank,annual emission fees will be based on requested emissions. Section 09— alicant Certification-I hereby certify that all information contained herein and information submitted with this application is complete,true and correct. If this is a registrati f coverage under gener ,I further certify that this source is and will be operated in full compliance with each condition of general permit GP05. 7 -10 -14 Josh Patterson VP of Operations Signatu o erson Legally Authorized to Supply Data Date Name of Legally Authorized Petkne 4p rint) Title FORM APCD-207 Page 2 of 2 ", lDesand Tanks—Form APCD-207 Produced Water Tank APEN AIR POLLUTANT EMISSION NOTICE (APEN) &Application for Construction Permit—Produced Water Tank Bpatttervl Permit Number: GP05 [Leave blank unless APCD has already assigned a permit#&AIRS ID] Emission Source AIRS ID: IZ3 I _/I..C)5 I c. -/ Facility Equipment ID: Sand and Oil Removal Tanks [Provide Facility Equipment ID to identify how this equipment is referenced within your organization.] Section 01—Administrative Information Section 02—Reauested Action(Check applicable request boxes) Company Name: NGL Water Solutions DJ,LLC NAICS,or ® Request for NEW individual permit or newly reported emission source Source Name: Sand and Oil Removal Tanks SIC Code: ❑ Request MODIFICATION to existing permit(check each box below that applies) Source Location: C9 Salt Water Disposal Facility County: Weld ❑ Change process or equipment O Change company name W'/:NW'/.SECTION 13,T10N,R61W Elevation: Feet ❑ Change permit limit O Transfer of ownership ❑ Other Mailing Address: 8207 West 20th Street,Suite B ZIP Code: 80634 ® Request for coverage under GENERAL PERMIT number GP05 Greeley,CO ❑ Request APEN update only(check the box below that applies) Person To Contact: Josh Patterson Phone Number: 303-536-4408 ❑ Revision to actual calendar year emissions for emission inventory Update 5-Year APEN term without change to permit limits or previously E-mail Address: jpatterson@highsierraenergy.com Fax Number: 303-536-4096 O reported emissions Addl.Info. Section 03—General Information &Notes: For existing sources,operation began on: / / For new or reconstructed sources,the projected startup date is: / / 2014 Normal Hours of Source Operation: 24 hours/day 7 days/week 52 weeks/year General description of equipment and purpose: Sand and Oil Removal Tanks:3 x 1000 bbl O. Do these storage tanks contain less than 1%by volume crude oil on an annual average basis? ❑ Yes ® No ► Are these produced water tanks located at a commercial facility that accepts oil production wastewater for processing? ® Yes ❑ No I, Are these produced water tanks subject to Colorado Oil and Gas Conservation Commission(COGCC)805 series rules?If so. ❑ Yes ® No submit Form APCD-105. ► Is this source located in an ozone non-attainment area? ® Yes ❑ No O Don't Know Section 04—Tank Battery Information2 Colorado Department of Public Health and Environment Air Pollution Control Division(APCD) Number of tanks: 3 Total tank capacity(bbl): 3,000 Produced Water throughput: Requested3: 10,950,000 bbl/year Actual calendar year: bbl/year This notice is valid for five(5)years. Submit a revised APEN prior to expiration of five-year term, or when a significant change is made „� (increase production,new equipment,change in fuel type,etc). Ili. Are"Flash emissions anticipated from these tanks? ❑ Yes ® No D. Is this tank located at an exploration&production(E&P)site?5 ❑ Yes ® No Mail this form along with a check for$152.90 per APEN for non- '''. Is this tank located at a non-E&P,midstream or downstream site?5 ® Yes ❑ No E&P, midstream and downstream sources or $152.90 for up to five(5)APENs for E&P sources and$250 for each general permit 1 You will be charged an additional APEN fee if APEN is filled out incorrectly or missing information and needs re-submittal. registration to: 2See PS Memo 09-02 for information on produced water tank permitting. (hap i/‘‘N%V.colorado,gov/cdnheiosmemos) Colorado Department of Public Health&Environment Requested values will become permit limitations. APCD-SS-B1"Hydrocarbons contained in the produced water can"flash"into the vapor phase due to a reduction in pressure on the liquids. 4300 Cherry Creek Drive South _5 See PS Memo 09-02 for definitions of E&P,non-E&P,midstream and downstream. (http://w "'V1 ..colorado.gov/cdphe/psmemos) Denver,CO 80246-1530 24 20k For guidance on how to complete this APEN form: Additional Air Pollution Control Division: (303)6150 Information ❑ Attach supporting documentation if site specific emissions factors developed and supplied on APEN. Small Business Assistance Program(SBAP): (303)692.3148 or Required: (303)692-3175 APEN forms:http://www.colorado.gov/cdphe/oilgasAPE:NS Application status:http://www.colorado.ttov/cdnhe/permitstatus FORM APCD-207 Page 1 of 2 31600 SandOilRemoval_Form APCD-207 Produced Water Tank APEN AIR POLLUTANT EMISSION NOTICE (APEN) & Application for Construction Permit—Produced Water Tank Battery' Permit Number: GP05 Emission Source AIRS ID: 173 / la.) / cn9 . Section 05—Stack Information (Combustion stacks must be listed here) Section 06—Stack(Source,if no combustion) Location(Datum&either Lat/Long or UTM) Stack Discharge Operator Stack Base Horizontal Datum UTM UTM Easting or UTM Northing or Method of Collection for Stack Elevation Height Above Temp. Flow Rate Velocity Moisture Ground Level (°F) (ACFM) (ft/sec) CYO (NAD27,NAD83, Zone Longitude Latitude Location Data(e.g.map, ID No. (feet) (feet) WGS84) (12 or 13) (meters or degrees) (meters or degrees) GPS,GoogleEarth) Direction of stack outlet(check one): ❑ Vertical ❑ Vertical+.itFt obstructing raincap E I lorizontal ❑ Dui+n ❑ Other(Describe): Exhaust Opening Shape&Size(check one): E Circular:Inner Diameter(inches)= 0 Other:Length(inches)= Width(inches)= Section 07—Control Device Information ❑ Condenser used for control of the tank battery. ❑ Combustion Device used for control of the tank battery. Rating: MMBtu/hr Type: Make/Model: Type: Make/Model/Serial#: Temperature(°F): Maximum: Average: VOC&HAP Control Efficiency: Requested: % Manufacturer Guaranteed: % Requested VOC&HAP Control Efficiency: % Minimum temp.to achieve requested control: °F Waste gas heat content: Btu/scf ❑ VRU used for control of the tank battery. Constant pilot light? ❑ Yes ❑ No Pilot burner rating: MMBtu/hr Size: Make/Model: ❑ Closed loop system used for control of the tank battery. Requested VOC&HAP Control Efficiency: % Description: Annual time that VRU is bypassed(emissions vented): % ❑ Describe Any Other: Section 08—Emissions Inventory Information& Emission Control Information O Emission Factor Documentation attached Data year for actual calendar yr.emissions below&throughput in Sec.04(eg.2007): 1 Control Device Description Control Emission Factor Actual Calendar Year Emissions4 Requested Permitted Estimation Method • Pollutant Efficiency Emissions or Primary Secondary (%Reduction) Uncontrolled Basis Units Uncontrolled Controlled Uncontrolled Controlled Emission Factor • (Tons/Year) (Tons/Year) (Tons/Year) , (Tons/Year) Source NOx VOC 3.56E-4 lb/bbl 1.95 EPA Tanks CO Benzene De minimis EPA Tanks Toluene Identify in Section 07 De minimis EPA Tanks Ethylbenzene De minimis EPA Tanks Xylene De minimis EPA Tanks n-Hexane 5.42E-5 0.30 EPA Tanks Please use the APCD Non-Criteria Reportable:Air Pollutant Addendum form to report pollutants not listed above. i You will be charged an additional APEN fee if APEN is filled out incorrectly or missing information and needs re-submittal. 4 Annual emission fees will be based on actual emissions reported here. If left blank,annual emission fees will be based on requested emissions. Section 09—Applicant Certification-I hereby certify that all information contained herein and information submitted with this application is complete,true and correct.If this is a registratio for coverage unde r 1 permit GP05,I further certify that this source is and will be operated in full compliance with-each condition of general permit GP05. -17. r0 -1R Josh Patterson VP of Operations Sign t of Person Legally thortzed to Supply Data Date Name of Legally Authorized> ke print) Title r•15,ar., FORM APCD-207 Page 2 of 2 ""` SandOilRemoval_Form APCD-207 Produced Water Tank APEN AIR POLLUTANT EMISSION NOTICE(APEN) & Application for Construction Permit—Produced Water Tank Battery Permit Number: GP05 [Leave blank unless APCD has already assigned a permit#&AIRS ID] Emission Source AIRS ID: IZ3 / 9L O / COS' Facility Equipment ID: Water Equalization Tanks [Provide Facility Equipment ID to identify how this equipment is referenced within your organization.] Section 01—Administrative Information Section 02—Requested Action(Check applicable request boxes) Company Name: NGL Water Solutions DJ,LLC NAICS,or ® Request for NEW individual permit or newly reported emission source Source Name: Water Equalization Tanks SIC Code: ❑ Request MODIFICATION to existing permit(check each box below that applies) Source Location: C9 Salt Water Disposal Facility County: Weld ❑ Change process or equipment O Change company name W''A NW'/.SECTION 13,T10N,R61W Elevation: Feet ❑ Change permit limit O Transfer of ownership ❑ Other Mailing Address: 8207 West 20th Street,Suite B ZIP Code: 80634 ® Request for coverage under GENERAL PERMIT number GP05 Greeley,CO O Request APEN update only(check the box below that applies) Person To Contact: Josh Patterson Phone Number: 303-536-4408 O Revision to actual calendar} :itni ns_1iF- riszatl< ventory Update 5-Year APEN term without change to permit limits or previously E-mail Address: jpatterson@highsierraenergy.com Fax Number: 303-536-4096 ❑ reported emissions Addl.Info. Section 03—General Information &Notes: For existing sources,operation began on: / / For new or reconstructed sources,the projected startup date is: / / 2014 Normal Hours of Source Operation: 24 hours/day 7 days/week 52 weeks/year General description of equipment and purpose: Water Equalization Tanks:12 x 840 bbl ► Do these storage tanks contain less than 1%by volume crude oil on an annual average basis? ❑ Yes ® No ► Are these produced water tanks located at a commercial facility that accepts oil production wastewater for processing? ® Yes ❑ No Are these produced water tanks subject to Colorado Oil and Gas Conservation Commission(COGCC)805 series rules?If so, ❑ I. submit Form APCD-105. Yes No ► Is this source located in an ozone non-attainment area? ® Yes ❑ No ❑ Don't Know Section 04—Tank Batten' Information2 Colorado Department of Public Health and Environment Air Pollution Control Divisi n(APCD) Number of tanks: 12 Total tank capacity(bbl): 10,080 3 This notice is valid for five(5)years. Submit a revised APEN prior to Produced Water throughput: Requested 3: 10,621,500 bbl/year Actual calendar year: bbl/year expiration of five-year term, or when a significant change is made D. Are"Flash"°emissions anticipated from these tanks? O Yes ® No (increase production,new equipment,change in fuel type,etc). ► Is this tank located at an exploration&production(E&P)site?s O Yes ® No Mail this form along with a check for$152.90 per APEN for non- Iii. Is this tank located at a non-E&P,midstream or downstream site?5 ® Yes O No E&P, midstream and downstream sources or $152.90 for up to five(5)APENs for E&P sources and$250 for each general permit I+ You will be charged an additional APEN fee if APEN is filled out incorrectly or missing information and needs re-submittal. registration to: -See PS Memo 09-02 for information on produced water tank permitting. (hup/NIA w.colorado.gov/cdnhe/nsmemos) Colorado Department of Public Health&Envit enment Requested values will become permit limitations, APCD-SS-B1 . 1261 4 Hydrocarbons contained in the produced water can"flash"into the vapor phase due to a reduction in pressure on the liquids. 4300 Cherry Creek Drive South 5 See PS Memo 09-02 for definitions of E&P,non-E&P,midstream and downstream. (hop.//w we colorado.gov/cdphe/nsmemos) Denver,CO 80246-1530 For guidance on how to complete this APEN form: Additional Air Pollution Control Division: (303)692-3150 Information ❑ Attach supporting documentation if site specific emissions factors developed and supplied on APEN. Small Business Assistance Program(SBAP): (303)692-3148 or Required: (303)692-3175 APEN forms:http://www.colorado.gov/cdphc/oiIgasAPENS Application status:htta://www.calorado.gov/cdphc/pennitstatus FORM APC D-207 Page 1 of 2 316 0 0 6 Water Equalization_Form APCD-207 Produced Water Tank APEN AIR POLLUTANT EMISSION NOTICE (APEN) & Application for Construction Permit—Produced Water Tank Battery' Permit Number: GP05 Emission Source AIRS ID: 17.3 / 9DO`5 / U05- Section 05—Stack Information(Combustion stacks must be listed here) Section 06—Stack(Source,if no combustion) Location(Datum&either Lat/Long or UTM) L — Stack Discharge Operator Stack Base Height Above Temp. Flow Rate Velocity Moisture Horizontal Datum UTM UTM Easting or UTM Northing or Method of Collection for Stack Elevation Ground Level (°F) (ACFM) ° (NAD27,NAD83, Zone Longitude Latitude Location Data(e.g.map, ID No. (feet) (feet) (ft/sec) (/°) WGS84) (12 or 13) (meters or degrees) (meters or degrees) GPS,GoogleEarth) Direction of stack outlet(check one): ❑ Vertical ❑ Vertical with obstructing raincap ❑ liuriiontal ❑ Down ❑ Other(Describe): Exhaust Opening Shape&Size(check one): O Circular:Inner Diameter(inches)= ❑ Other:Length(inches)= Width(inches)= Section 07—Control Device Information ❑ Condenser used for control of the tank battery. ❑ Combustion Device used for control of the tank battery. Rating: MMBtu/hr Type: Make/Model: Type: Make/Model/Serial#: Temperature(°F): Maximum: Average: VOC&HAP Control Efficiency: Requested: % Manufacturer Guaranteed: % Requested VOC&HAP Control Efficiency: % Minimum temp.to achieve requested control: °F Waste gas heat content: Btu/scf O VRU used for control of the tank battery. Constant pilot light? ❑ Yes O No Pilot burner rating: MMBtu/hr Size: Make/Model: ❑ Closed loop system used for control of the tank battery. Requested VOC&HAP Control Efficiency: % Description: Annual time that VRU is bypassed(emissions vented): % I O Describe Any Other: Section 08—Emissions Inventory Information&Emission Control Information O Emission Factor Documentation attached Data year for actual calendar yr.emissions below & throughput in Sec.04(e.g.2007): Control Device Description Control Emission Factor Actual Calendar Year Emissions4 Requested Permitted Estimation Method Pollutant Efficiency Emissions or Primary Secondary (%Reduction) Uncontrolled Basis Units Uncontrolled Controlled Uncontrolled Controlled Emission Factor (Tons/Year) (Tons/Year) (Tons/Year) (Tons/Year) Source NOx VOC 2.07E-4 lb/bbl 1.10 EPA Tanks CO Benzene De minimis EPA Tanks Identify in Section 07 Toluene De minimis EPA Tanks v Ethylbenzene De minimis EPA Tanks Xylene De minimis EPA Tanks n-Hexane 3.14E-5 lb/bbl 0.17 EPA Tanks Please use the APCD Non-Criteria Reportable Air Pollutant Addendum form to report pollutants not listed above. r You will be charged an additional APEN fee if APEN is filled out incorrectly or missing information and needs re-submittal. 'Annual emission fees will be based on actual emissions reported here. If left blank,annual emission fees will be based on requested emissions. Section 09—Applicant Certification-I hereby certify that all information contained herein and information submitted with this application is complete,true and correct. If this is a registration f c erage under general p 05,I further certify that this source is and will be operated in full compliance with each condition of general permit GP05. 7 -1O Josh Patterson ~ � _ VP of Operations Signature o erson Legally Authorize y ata Date Name of Legally Authorized apse print) Title FORM APCD-207 Page Equalization_Form Pa e 2 of 2 Water ualization Form APCD-207 Produced Water Tank APEN AIR POLLUTANT EMISSION NOTICE (APEN) & Application for Construction Permit—Produced Water Tank Battery' Permit Number: GP05 [Leave blank unless APCD has already assigned a permit 4&AIRS ID] Emission Source AIRS ID: (7 3 / 7Dc / ax. Facility Equipment ID: Post Filter Tanks [Provide Facility Equipment ID to identify how this equipment is referenced within your organization.] Section 01—Administrative Information Section 02—Requested Action(Check applicable request boxes) Company Name: NGL Water Solutions DJ,LLC NAICS,or ® Request for NEW individual permit or newly reported emission source Source Name: Post Filter Tanks SIC Code: O Request MODIFICATION to existing permit(check each box below that applies) Source Location: C9 Salt Water Disposal Facility County: Weld O Change process or equipment O Change company name W'/s NW'/,SECTION 13,TI0N,R6IW Elevation: Feet O Change permit limit O Transfer of ownership ❑ Other Mailing Address: 8207 West 20th Street,Suite B ZIP Code: 80634 ® Request for coverage under GENERAL PERMIT number GP05 Greeley,CO O Request APEN update only(check the box below that applies) Person To Contact: Josh Patterson Phone Number: 303-536-4408 O Revision to actual calendar year emissions for emission inventory E-mail Address: jpatterson@highsierraenergy.com Fax Number: 303-536-4096 ❑ Update 5-Year APEN term without change to permit limits or previously reported emissions Addl.Info. Section 03—General Information &Notes: For existing sources,operation began on: / / For new or reconstructed sources,the projected startup date is: / / 2014 Normal Hours of Source Operation: 24 hours/day 7 days/week 52 weeks/year General description of equipment and purpose: Post Filter Tanks:2 x 1,000 bbl ► Do these storage tanks contain less than 1%by volume crude oil on an annual average basis? O Yes ® No ► Are these produced water tanks located at a commercial facility that accepts oil production wastewater for processing? ® Yes ❑ No P. these produced water tanks subject to Colorado Oil and Gas Conservation Commission(COGCC)805 series rules?If so. ❑ Yes ® No submit Form APCD-105. ► Is this source located in an ozone non-attainment area? ® Yes ❑ No O Don't Know Section 04—Tank Batter,Information Colorado Department of Public Health and Environment Air Pollution Control Division(APCD) Number of tanks: 2 Total tank capacity(bbl): 2,000 Produced Water throughput: Requested3: 10,621,500 bbl/year Actual calendar year: bbl/year This notice is valid for five(5)years. Submit a revised APEN prior to expiration of five-year term, or when a significant change is made 10 Are"Flash"4 emissions anticipated from these tanks? ❑ Yes ® No (increase production,new equipment,change in fuel type,etc). ► Is this tank located at an exploration&production(E&P)site?5 ❑ Yes ® No Mail this form along with a check for$152.90 per APEN for non- ► Is this tank located at a non-E&P,midstream or downstream site?5 ® Yes ❑ No E&P, midstream and downstream sources or $152.90 for up to five(5)APENs for E&P sources and$250 for each general permit 1 You will be charged an additional APEN fee if APEN is filled out incorrectly or missing information and needs re-submittal. registration to: 3 See PS Memo 09-02 for information on produced water tank permitting. (http ii.,‘‘N.colorado.gov/cdphe/psmemos) Colorado Department of Public Health&Environment Requested values will become permit limitations. APCD-SS-B1 ,... "Hydrocarbons contained in the produced water can"flash"into the vapor phase due to a reduction in pressure on the liquids. 4300 Cherry Creek Drive South JUL?�y'� 5 See PS Memo 09-02 for definitions of E&P,non-E&P,midstream and downstream. (htm:/fwww.cotorado.gov/cdphe/psmemos) Denver,CO 80246-1530 - 4 cu)4 For guidance on how to complete this APEN form: Additional Air Pollution Control Division: (303)692'3150 Information O Attach supporting documentation if site specific emissions factors developed and supplied on APEN. Small Business Assistance Program(SBAP): (303)692-3148 or Required: (303)692-3175 APEN forms:http://www.eolorado.gov/cdphe/oilgasAPENS Application status:http://www.colorado.jov/cdphe/pennitstatus FORM APCD-207 Page 1 of 2 316 0 0 7 Post Filter Tanks Form APCD-207 Produced Water lank APEN AIR POLLUTANT EMISSION NOTICE (APEN) & Application for Construction Permit—Produced Water Tank Battery' Permit Number: GP05 Emission Source AIRS ID: t2.3 / e' / OOG Section 05—Stack Information (Combustion stacks must be listed here) Section 06—Stack(Source,if no combustion)Location(Datum&either Lat/Long or U I M) Stack Discharge Operator Stack Base Horizontal Datum UTM UTM Easting or UTM Northing or Method of Collection for Stack Elevation Height Above Temp Flow Rate Velocity Moisture Ground Level (°P i (ACFM) (ft/sec) (�,o) (NAD27,NAD83, Zone Longitude Latitude Location Data(e.g.map, ID No. (feet) (feet) WGS84) (12 or 13) (meters or degrees) (meters or degrees) GPS,GoogleEarth) 1 Direction of stack outlet(check one): ❑ Vertical ❑ vertical with obstructing raincap ❑ I-iorizontal ❑ Dovtn ❑ Other(Describe): Exhaust Opening Shape&Size(check one): ❑ Circular:Inner Diameter(inches) ❑ Other:Length(inches)= Width(inches)_ Section 07—Control Device Information ❑ Condenser used for control of the tank battery. ❑ Combustion Device used for control of the tank battery. Rating: MM-113tuihr Type: Make/Model: Type: Make/Model/Serial#: Temperature(°F): Maximum: Average: VOC&HAP Control Efficiency: Requested: % Manufacturer Guaranteed: % Requested VOC&HAP Control Efficiency: % Minimum temp.to achieve requested control: °F Waste gas heat content: Btu'scf ❑ VRU used for control of the tank battery. Constant pilot light? ❑ Yes O No Pilot burner rating: MMBtu/hr Size: Make/Model: O Closed loop system used for control of the tank battery. Requested VOC&HAP Control Efficiency: % Description: Annual time that VRU is bypassed(emissions vented): % ❑ Describe Any Other: Section 08—Emissions Inventory Information& Emission Control Information ❑ Emission Factor Documentation attached Data year for actual calendar yr.emissions helm,. & throughput in Sec.04(e.g.2007): ( 4 Requested Permitted Estimation Method Control Device Description Control Emission Factor Actual Calendar Year Emissions Emissions` or Pollutant Efficiency Primary Secondar (%Reduction) Uncontrolled Basis Units Uncontrolled Controlled Uncontrolled Controlled Emission Factor (Tons/Year) (Tons/Year) (Tons/Year) (Tons/Year) Source _ NOx VOC 1.72E-4 lb/bbl 0.91 EPA Tanks CO Benzene De minimis EPA Tanks Toluene Identify in Section 07 De minimis EPA Tanks Ethylbenzene De minimis EPA Tanks Xylene De minimis EPA Tanks n-Hexane 2.62E-5 lb/bbl 0.14 EPA Tanks Please use the APCD Non-Criteria Reportable Air Pollutant Addendum form to report pollutants not listed above. 1 You will be charged an additional APEN fee if APEN is filled out incorrectly or missing information and needs re-submittal. 4Annual emission fees will be based on actual emissions reported here. If left blank,annual emission fees will be based on requested emissions. Section 09—Applicant Certification-I hereby certify that all information contained herein and information submitted with this application is complete,true and correct.If this is a registrati• fo coverage under gene . pe 05,I further certify that this source is and will be operated in full compliance with each condition of general permit GP05. 7-tra ' l 1 Josh Patterson VP of Operations Signatu e . Person Legally Authorized to Supp y to ata Date Name of Legally Authorized Perso I24t tt) Title FORM APCD-207 Page 2 of 2 't 1?9ofilter Tanks_Form APCD-207 Produced Water Tank APEN AIR POLLUTANT EMISSION NOTICE (APEN) &Application for Construction Permit—Produced Water Tank Battervl Permit Number: GP05 [Leave blank unless APCD has already assigned a permit#&AIRS ID] Emission Source AIRS ID: 1Z3 / CO 3S (57 Facility Equipment ID: Produced Water Unloading Sump [Provide Facility Equipment ID to identify how this equipment is referenced within your organization.] Section 01—Administrative Information Section 02—Requested Action(Check applicable request boxes) Company Name: NGL Water Solutions DJ,LLC NAICS,or ® Request for NEW individual permit or newly reported emission source Source Name: Produced Water Unloading Sump SIC Code: ❑ Request MODIFICATION to existing permit(check each box below that applies) Source Location: C9 Salt Water Disposal Facility County: Weld ❑ Change process or equipment ❑ Change company name W'/:NW'/4 SECTION 13,T10N,R61W Elevation: Feet ❑ Change permit limit O Transfer of ownership ❑ Other Mailing Address: 8207 West 20o,Street,Suite B ZIP Code: 80634 ® Request for coverage under GENERAL PERMIT number GP05 Greeley,CO ❑ Request APEN update only(check the box below that applies) Person To Contact: Josh Patterson Phone Number: 303-536-4408 O Revision to actual calendar year emissions for emission inventory Update 5-Year APEN term without change to permit limits or previously E-mail Address: jpatterson@highsierraenergy.com Fax Number: 303-536-4096 Elreported emissions Addl.Info. Section 03—General Information &Notes: For existing sources,operation began on: / / For new or reconstructed sources,the projected startup date is: / / 2014 Normal Hours of Source Operation: 24 hours/day 7 days/week 52 weeks/year General description of equipment and purpose: Produced Water Unloading Sump:10 x 10 x 11 ► Do these storage tanks contain less than 1%by volume crude oil on an annual average basis? O Yes ® No ► Are these produced water tanks located at a commercial facility that accepts oil production wastewater for processing? ® Yes ❑ No ► Are these produced water tanks subject to Colorado Oil and Gas Conservation Commission(COGCC)805 series rules?If so, ❑ Yes ® No submit Form APCD-105. ► Is this source located in an ozone non-attainment area? ® Yes ❑ No ❑ Don't Know Section 04—Tank Battery Information= Colorado Department of Public Health and Environment Air Pollution Control Division(APCD) Number of tanks: 1 Total tank capacity(bbl): 196 3 This notice is valid for five(5)years. Submit a revised APEN prior to Produced Water throughput: Requested 3: 10,950,000 bbl/year Actual calendar year: bbl/year expiration of five-year term, or when a significant change is made ► Are"Flash"°emissions anticipated from these tanks? ❑ Yes ® No (increase production,new equipment,change in fuel type,etc). D. Is this tank located at an exploration&production(E&P)site?5 ❑ Yes ® No Mail this form along with a check for$152.90 per APEN for non- III. Is this tank located at a non-E&P,midstream or downstream site?5 ® Yes ❑ No E&P, midstream and downstream sources or $152.90 for up to five(5)APENs for E&P sources and$250 for each general permit ' You will be charged an additional APEN fee if APEN is filled out incorrectly or missing information and needs re-submittal. registration to: 2 See PS Memo 09-02 for information on produced water tank permitting. (httn://vww.colorado.gov/cdphe/psmemos) Colorado Department of Public Health&Environment Requested values will become permit limitations. APCD-SS-Bl °Hydrocarbons contained in the produced water can"flash"into the vapor phase due to a reduction in pressure on the liquids. 4300 Cherry Creek Drive South 5 See PS Memo 09-02 for definitions of E&P,non-E&P,midstream and downstream. (http://w+w,v.colorado.gov/cdphe/psmemos) Denver,CO 80246-1530 For guidance on how to complete this APEN form: Additional Air Pollution Control Division: (303)692-3150 Information O Attach supporting documentation if site specific emissions factors developed and supplied on APEN. Small Business Assistance Program(SBAP): (303)692-3148 or Required: (303)692-3175 , APEN forms:hup: ++++++.colorado.gov/cdphc/oilgasAPENS 24 4014 Application status:hair.'++++++.colorado.gov/cdphc/permitstatus FORM APCD-207 Page 1 of 2 ;'7 316008 Sump_Form APCD-207 Produced Water Tank APEN AIR POLLUTANT EMISSION NOTICE (APEN) & Application for Construction Permit—Produced Water Tank Battery' Permit Number: GP05 Emission Source AIRS ID: -. / ?Dos' / ()07 Section 05—Stack Information (Combustion stacks must be listed here) Section 06-Stack(Source.if no combustion) Location (Datum&either [at bong or UTM) c Stack Discharge Operator Stack Base Horizontal Datum UTM UTM Fasting or UTM Northing or Method of Collection for Stack Elevation Height Above Temp. Flow Rate Velocity Moisture Ground Level (°F) (ACFM) (ft/sec) (%) (NAD27,NAD83, Zone Longitude Latitude Location Data(e.g.map, ID No. (feet) (feet) WGS84) (12 or 13) (meters or degrees) (meters or degrees) GPS,GoogleEarth) Direction of stack outlet(check one): ❑ Vertical 0 Vertical 1Aith obstructing raincap 0 t lorizontal ❑ Down ❑ Other(Describe): Exhaust Opening Shape&Size(check one): ❑ Circular:Inner Diameter(inches)= ❑ Other:Length(inches)= Width(inches)= Section 07—Control Device Information ❑ Condenser used for control of the tank battery. ❑ Combustion Device used for control of the tank battery. Rating: MMBtu/hr Type: Make/Model: Type: Make/Model/Serial#: Temperature(°F): Maximum: Average: VOC&HAP Control Efficiency: Requested: % Manufacturer Guaranteed: % Requested VOC&HAP Control Efficiency: °i° Minimum temp.to achieve requested control: °F Waste gas heat content: Btu/scf ❑ VRU used for control of the tank battery. Constant pilot light" ❑ Yes O No Pilot burner rating: MMBtu/hr Size: Make/Model: ❑ Closed loop system used for control of the tank battery. Requested VOC&HAP Control Efficiency: % Description: Annual time that VRI I is bypassed(emissions\cared): % ❑ Describe An... Other: Section 08—Emissions Inventory Information&Emission Control Information O Emission Factor Documentation attached Data year for actual calendar yr.emissions below&throughput in Sec.04(e.g.2007): 1 Control Device Description Control Emission Factor Actual Calendar Year Emissions° Requested Permitted Estimation Method Pollutant Efficiency Emissions or Primary Secondary (%Reduction) Uncontrolled Basis Units Uncontrolled Controlled Uncontrolled Controlled Emission Factor (Tons/Year) (Tons/Year) (Tons/Year) (Tons/Year) Source _ NOX VOC 3.33E-4 lb/bbl 1.82 EPA Tanks CO Benzene De minimis EPA Tanks Identify in Section 07 Toluene De minimis EPA Tanks Ethylbenzene De minimis EPA Tanks Xylene De minimis EPA Tanks n-Hexane 5.07E-5 lb/bbl 0.28 EPA Tanks Please use the APCD Non-( ritcria Reportable Air Pollutant Addendum form to report pollutants not listed above. 1 1 You will be charged an additional APEN fee if APEN is filled out incorrectly or missing information and needs re-submittal. 4 Annual emission fees will be based on actual emissions reported here. If left blank,annual emission fees will be based on requested emissions. Section 09—Applicant Certification-I hereby certify that all information contained herein and information submitted with this application is complete,true and correct.If this is a registratio •r coverage under ge al a it GP05,I further certify that this source is and will be operated in full compliance with each condition of general permit GP05. ► ,�� _ 7 -f Q -/ Josh Patterson VP of Operations Signat-r of Person egally Auth i e o Supply Data Date Name of Legally Authorized Person(PJ� int)' Title �''2014 FORM APCD-207 Page 2 of 2 r Sump_Form APCD 207 Produced Water Tank APEN AIR POLLUTANT EMISSION NOTICE (APEN) &Application for Construction Permit—Midstream Condensate Tank Battery Permit Number: GP01 [Leave blank unless APCD has already assigned a permit#&AIRS ID] Emission Source AIRS ID: 113 / 9CoS I 008' Facility Equipment ID: Oil Heating Tank [Provide Facility Equipment ID to identify how this equipment is referenced within your organization.] Section 01—Administrative Information Section 02—Requested Action(Check applicable request boxes) Company Name: NGL Water Solutions DJ,LLC NAICS,or ® Request for NEW individual permit or newly reported emission source Source Name: Oil Heating Tank SIC Code: ❑ Request MODIFICATION to existing permit(check each box below that applies) Source Location: C9 Salt Water Disposal Facility County: Weld ❑ Change process or equipment El Change company name W Y2 NW%SECTION 13,T10N,R61W Elevation: Feet ❑ Change permit limit ❑ Transfer of ownership ❑ Other Mailing Address: 8207 West 20th Street,Suite B ZIP Code: 80634 ® Request for coverage under GENERAL PERMIT number GP01 Greeley,CO El Request APEN update only(check the box below that applies) Person To Contact: Josh Patterson Phone Number: 303-536-4408 El Revision to actual calendar year emissions for emission inventory E-mail Address: jpatterson@highsierraenerp.com Fax Number: 303-536-4096 O Update 5-Year APEN term without change to permit limits or previously reported emissions Addl.Info. Section 03—General Information &Notes: For existing sources,operation began on: / / For new or reconstructed sources,the projected startup date is: / / 2014 Normal Hours of Source Operation: 24 hours/day 7 days/week 52 weeks/year General description of equipment and purpose: Oil Heating Tank:1 x 450 bbl ► Do any of the condensate storage tanks have a capacity?10,000 bbl? ❑ Yes A ® No ► Are you requesting≥20 ton/yr VOC emissions,or are uncontrolled actual emissions≥20 ton/yr? (If"Yes",Regulation No.7,Section XVII.C will apple) ❑ Yes ® No ► Is this unit located at a stationary source that is considered a Major Source of Hazardous Air Pollutant(HAP)emissions? ❑ Yes ® No ❑ Don't know D. Will this equipment be operated in any NAAQS nonattainment area? (http://www.cdphc.state.co.us/ap/attainmaintain.html) ® Yes B ❑ No ❑ Don't know A If"Yes",the tank(s)may be subject to Regulation No.7,Sections III,IV,&VI,and Regulation No.6,Part A,Subpart Kb or Ka. Provide an applicability determination of these rules. a If"Yes",the tank(s)may be subject to Regulation No.7,Section XII.A or XII.B. Provide an applicability determination of these rules. Colorado Department of Public Health and Environment Section 04—Tank Battery Information' Air Pollution Control Division(APCD) Number of tanks: 1 Total tank capacity(bbl): 450 This notice is valid for five(5)years. Submit a revised APEN prior to 2 expiration of five-year term, or when a significant change is made Condensate throughput: Requested : 328,500 bbl/year Actual calendar year: bbl/year (increase production,new equipment,change in fuel type,etc). Is actual annual average hydrocarbon liquid throughput≥500 bbl/day? ® Yes ❑ No Mail this form along with a check for$152.90 per APEN and$250 • If"yes"above,identify the gas-to-oil ratio: 0.06 cf/bbl for each general permit registration to: Are"flash"3 emissions anticipated from the tank(s)? El Yes ® No Colorado Department of Public Health&Environment APCD-SS-Bl API gravity: degrees 4300 Cherry Creek Drive South Reid Vapor Pressure: 3.2 psi True Vapor Pressure: psia 60°F Denver,CO 80246-1530 A��Q @ For guidance on how to complete this AP' N form: 'See PS Memo 05-01 for information on condensate tank permitting and identification of parameters used to calculate emissions. Air Pollution Control Division: • (3Q3''692-3150 (htto.//ww�s.cdphe state.co.us/ap/down/Ds05-0 pd t) 2 Small Business Assistance Program(SBAP): (303)692-3148 or Requested values will become permit limitations. (303)692-3175 3 Hydrocarbons can"flash"into the vapor phase due to a reduction in pressure on the hydrocarbon liquids. APEN forms:http://www.cdphc.state.co.us/ap/down loadforms.htrnl Additional ❑ Attach a pressurized pre-flash condensate extended gas analysis,RVP&API analysis of the post-flash oil Information ® Attach E&P Tanks input&emission estimate documentation(or equivalent simulation report/test results) ® Check box to request copy of draft permit prior to issuance. Required: ❑ Attach EPA TANKS emission analysis if emission estimates do not contain working/breathing losses ® Check box to request copy of draft permit prior to public notice. FORM APCD-204 Page 1 of 2 OilHeatingTank_FormAPCD-204-MidstreamCondensateTankAPEN-2-12-13 31598 AIR POLLUTANT EMISSION NOTICE (APEN) & Application for Construction Permit—Midstream Condensate Tank Battery Permit Number: GP01 Emission Source AIRS ID: 12.3 / ((Doc- / coy Section 05—Stack Information(Combustion stacks must be listed here) Section 06—Stack(Source.if no combustion)Location(Datum&either I at Long or UTM) 1 Stack Discharge i 1 Stack Elevation Height Above Temp. Flow Rate Velocity Moisture Ground Level (°F) (ACFM) (ft/sec) (%) (NAD27,NAD83. Zone Longitude Latitude Location Data(e.g.map, ID No. (feet) degrees)WGS84) (12 or 13) (meters or de ) (meters or degrees) GPS,GoogleEarth) i Direction of stack outlet(cheek one): ® Vertical ❑ Vertical with obstructing raincap ❑ liorii.ontal ❑ Down ❑ Other(Describe): Exhaust Opening Shape&Size(check one): ❑ Circular:Inner Diameter(inches)= ❑ Other:Length(inches)= Width(inches)= Section 07—Control Device Information E Condenser used for control of the tank battery. ❑ Combustion Device used for control of the tank battery. Rating: MMBtu/hr Type: Make/Model: Type: Make/ModellSerial#: Temperature(°F): Maximum: Average: VOC&HAP Control Efficiency: Requested: % Manufacturer Guaranteed: % Requested VOC&HAP Control Efficiency: Minimum temp.to achieve requested control: °F Waste gas heat content: Btu/set ❑ VRU used for control of the tank battery. Constant pilot light.' ❑ Yes O No Pilot burner rating: mMBut/hr Size: Make/Model: ❑ Closed loop system used for control of the tank battery. Requested VOC&HAP Control Efficiency: % Description: Annual time that VRU is bypassed(emissions vented): % ❑ Describe Any Other: Section 08—Emissions Inventory Information&Emission Control Information El Emission Factor Documentation attached Data year for actual calendar yr.emissions below&throughput in Sec.04(e.g.2007): U 7 Control Device Description Control Emission Factor Actual Calendar Year Emissions4 Requested Permitted Estimation Method Pollutant Efficiency Emissions or Primary Secondary (%Reduction) Uncontrolled Basis Units Uncontrolled Controlled Uncontrolled Controlled Emission Factor (Tons/Year) (Tons/Year) (Tons/Year) (Tons/Year) Source NOx VOC 1.51E-2 lb/bbl 2.49 E&P Tanks CO Benzene De minimis E&P Tanks Toluene Identify in Section 07 De minimis E&P Tanks Ethylbenzene De minimis E&P Tanks Xylene De minimis E&P Tanks n-Hexane 2.29E-3 lb/bbl 0.38 E&P Tanks Please use the APCD Non-Criteria Reportable Air Pollutant Addendum form to report pollutants not listed above. "Annual emission fees will be based on actual emissions reported here. If left blank,annual emission fees will be based on requested emissions 5If Requested Permitted Emissions is left blank,the APCD will calculate emissions based on the information supplied in sections 03-08. Section 09—Applicant Certification-I hereby certify that all information contained herein and information submitted with this application is complete,true and correct.If this is a regis a- for coverage under n al rmit rther certify that this source is and will be operated in full compliance with each condition of general permit GP0I. -7`1 0 — 1 Li Josh Patterson -- . VP of Operations Sign re Perso Legally Aut orized to ata Date Name of Legally Authorized Person(PleaC 1. I' Title --1.z42014 Page 2 of 2 OilHeatingTank_Fo '� D-204-MidstreamCondensateTankAPEN-2-12-1 3 AIR POLLUTANT EMISSION NOTICE (APEN)& Application for Construction Permit—Midstream Condensate Tank Battery Permit Number: G P01 [Leave blank unless APCD has already assigned a permit#&AIRS ID] Emission Source AIRS ID: I 2,3 / 9coc / COCI Facility Equipment ID: Oil Tanks [Provide Facility Equipment ID to identify how this equipment is referenced within your organization.] Section 01—Administrative Information Section 02—Requested Action(Check applicable request boxes) Company Name: NGL Water Solutions DJ,LLC NAICS,or ® Request for NEW individual permit or newly reported emission source Source Name: Oil Tanks SIC Code: O Request MODIFICATION to existing permit(check each box below that applies) Source Location: C9 Salt Water Disposal Facility County: Weld ❑ Change process or equipment ❑ Change company name W'/:NW'/.SECTION 13,T10N,R61W Elevation: Feet ❑ Change permit limit ❑ Transfer of ownership ❑ Other Mailing Address: 8207 West 20th Street,Suite B ZIP Code: 80634 ® Request for coverage under GENERAL PERMIT number GP01 Greeley,CO O Request APEN update only(check the box below that applies) Person To Contact: Josh Patterson Phone Number: 303-536-4408 O Revision to actual calendar year emissions for emission inventory E-mail Address: jpatterson@highsierraenergy.com Fax Number: 303-536-4096 ❑ Update 5-Year APEN term without change to permit limits or previously reported emissions Addl.Info. Section 03—General Information &Notes: For existing sources,operation began on: / / For new or reconstructed sources,the projected startup date is: / / 2014 Normal Hours of Source Operation: 24 hours/day 7 days/week 52 weeks/year General description of equipment and purpose: Oil Tanks:4 x 450 bbl ► Do any of the condensate storage tanks have a capacity≥10,000 bbl? ❑ Yes A ® No ► Are you requesting≥20 ton/yr VOC emissions,or are uncontrolled actual emissions≥20 ton/yr? (If"Yes",Regulation No.7,Section XVII.C will apply) ❑ Yes ® No ► Is this unit located at a stationary source that is considered a Major Source of Hazardous Air Pollutant(HAP)emissions? O Yes ® No O Don't know I. Will this equipment be operated in any NAAQS nonattainment area? (http://wN%w.cdphe.state.co.us/ap/attainmaintain.html) ® Yes B O No O Don't know A If"Yes",the tank(s)may be subject to Regulation No.7,Sections III,IV,&VI,and Regulation No.6,Part A,Subpart Kb or Ka. Provide an applicability determination of these rules. B If"Yes",the tank(s)may be subject to Regulation No.7,Section XII.A or XII.B. Provide an applicability determination of these rules. Colorado Department of Public Health and Environment Section 04—Tank Battery Information' Air Pollution Control Division(APCD) Number of tanks: 4 Total tank capacity(bbl): 1,800 This notice is valid for five(5)years. Submit a revised APEN prior to expiration of five-year term, or when a significant change is made Condensate throughput: Requested2: 328,500 bbl/year Actual calendar year: bbl/year (increase production,new equipment,change in fuel type,etc). Is actual annual average hydrocarbon liquid throughput≥500 bbl/day? ® Yes El No • If"yes"above,identify the gas-to-oil ratio: 0.08 cf/bbl Mail this form along with a check for$152.90 per APEN and$250 „3 for each general permit registration to: Are`flash emissions anticipated from the tank(s)? O Yes ® No Colorado Department of Public Health&Environment APCD-SS-B1 A`9 API gravity: degrees 4300 Cherry Creek Drive South juL Reid Vapor Pressure: 3.2 psi True Vapor Pressure: psia @ 60°F Denver,CO 80246-1530 n / For guidance on how to complete this APEN forl� See PS Memo 05-01 for information on condensate tank permitting and identification of parameters used to calculate emissions. Air Pollution Control Division: (303)692-3150 (http://www,.eclphe.state.co.usiap/downiosf)5-0 I.pdt) Small Business Assistance (SBAP):am 2 Requested values will become permit limitations. gr ( ) (303)692-3148 or (303)692-3175 3 Hydrocarbons can"flash"into the vapor phase due to a reduction in pressure on the hydrocarbon liquids. APEN forms:http://www.cdphe.state.co.us/ap/downloadtbrms.html Additional ® Attach a pressurized pre-flash condensate extended gas analysis,RVP&API analysis of the post-flash oil Information ® Attach E&P Tanks input&emission estimate documentation(or equivalent simulation report/test results) ® Check box to request copy of draft permit prior to issuance. Required: O Attach EPA TANKS emission analysis if emission estimates do not contain working/breathing losses ® Check box to request copy of draft permit prior to public notice. FORM APCD-204 Page 1 of 2 315 9 9 9 OilTanks_FormAPCD-204-MidstreamCondensateTankAPEN-2-12-13 AIR POLLUTANT EMISSION NOTICE (APEN) & Application for Construction Permit—Midstream Condensate Tank Battery Permit Number: GPO1 Emission Source AIRS ID: (73 / q / Dnq Section 05—Stack Information(Combustion stacks must be listed here) Section 06—Stack(Source,if no combustion)Location(Datum&either 1.at/Long or UTM) Stack Discharge Operator Stack Base horizontal Datum UTM UTM Easting or UTM Northing or Method of Collection for Height Above Temp Flow Rate Velocity Moisture Stack Elevation " t NAD27,NAD83, Zone Longitude Latitude Location Data(e.g.map, ID No. (feet) Ground Level (°F) (ACFM) (ft/sec) (%) WGS84)) (12 or 13) (meters or degrees) (meters or degrees) GPS,GoogleEarth) Direction of stack outlet(check one): ® Vertical ❑ Vertical with obstructing raincap ❑ Horizontal El Down ❑ Other(Describe): Exhaust Opening Shape&Size(check one): ❑ Circular:Inner Diameter(inches)_ ❑ Other:Length(inches)= Width(inches)= Section 07—Control Device Information ❑ Condenser used for control of the tank battery. ❑ Combustion Device used for control of the tank battery. Rating: MMBtu/hr Type: Make/Model: Type: Make/Model/Serial#: [I Temperature(°F): Maximum: Average: VOC&HAP Control Efficiency: Requested: % Manufacturer Guaranteed: % Requested VOC&HAP Control Efficiency: % Minimum temp.to achieve requested control: °F Waste gas heat content: Btu/scf ❑ VRU used for control of the tank battery. Constant pilot light? ❑ Yes ❑ No Pilot burner rating: MMBtu/hr Size: Make/Model: ❑ Closed loop system used for control of the tank battery. Requested VOC&HAP Control Efficiency: % Description: Annual time that VRU is bypassed(emissions vented): % ❑ Describe Any Other: Section 08—Emissions Inventory Information& Emission Control Information ® Emission Factor Documentation attached Data year for actual calendar yr.emissions helm% &throughput in Sec.04(e.g.200 ): i 7 Control Device Description Control Emission Factor Actual Calendar Year Emissions Requested Permitted Estimation Method Pollutant Efficiency Emissions or Primary Secondary (%Reduction) Uncontrolled Basis Units Uncontrolled Controlled Uncontrolled Controlled Emission Factor (Tons/Year) r (Tons/Year) (Tons/Year) (Tons/Year) Source NOx VOC 1.93E-2 lb/bbl 3.17 E&P Tanks CO Benzene De minimis E&P Tanks Toluene Identify in Section 07 De minimis E&P Tanks Ethylbenzene De minimis E&P Tanks Xylene De minimis E&P Tanks n-Hexane 2.99E-3 lb/bbl 0.49 E&P Tanks Please use the APCD Non-Criteria Reportable.kir Pollutant Addendum form to report pollutants not listed ahoy e. "Annual emission fees will be based on actual emissions reported here. If left blank,annual emission fees will be based on requested emissions, 5If Requested Permitted Emissions is left blank,the APCD will calculate emissions based on the information supplied in sections 03-08. Section 09—Applicant Certification-I hereby certify that all information contained herein and information submitted with this application is complete,true and correct.If this is a registra' n coverage under geney ' GP01,I further certify that this source is and will be operated in full compliance with each condition of general permit GPO I. •pw- i'� '•[0 - 19 Josh Patterson VP of Operations Signal of Person Legally Autho • to Supply Data Date Name of Legally Authorized Pers1(pl t print) Title Page 2 of 2 oilTar>is_FormAPCD-204-MidstreamCondensateTankAPEN-2-12-13 AIR POLLUTANT EMISSION NOTICE(APEN) & Application for Construction Permit—Midstream Condensate Tank Battery Permit Number: GP01 [Leave blank unless APCD has already assigned a permit#&AIRS ID] Emission Source AIRS ID: 1Z3 / R Q3.c / OI U Facility Equipment ID: Slop Oil Tank [Provide Facility Equipment ID to identify how this equipment is referenced within your organization,] Section 01—Administrative Information Section 02—Requested Action(Check applicable request boxes) Company Name: NGL Water Solutions DJ,LLC NAICS,or ® Request for NEW individual permit or newly reported emission source Source Name: Slop Oil Tank SIC Code: ❑ Request MODIFICATION to existing permit(check each box below that applies) Source Location: C9 Salt Water Disposal Facility County: yield E Change process or equipment ❑ Change company name W'A NW'A SECTION 13,TI0N,R61W Elevation: Feet ❑ Change permit limit O Transfer of ownership O Other Mailing Address: 8207 West 20th Street,Suite B ZIP Code: 80634 ® Request for coverage under GENERAL PERMIT number GP01 Greeley,CO ❑ Request APEN update only(check the box below that applies) Person To Contact: Josh Patterson Phone Number: 303-536-4408 ❑ Revision to actual calendar year emissions for emission inventory E-mail Address: jpatterson@highsierraenergy.com Fax Number: 303-536-4096 ❑ Update 5-Year APEN term without change to permit limits or previouslyreported emissions Addl.Info. Section 03—General Information &Notes: For existing sources,operation began on: / / For new or reconstructed sources,the projected startup date is: / / 2014 Normal Hours of Source Operation: 24 hours/day 7 days/week 52 weeks/year General description of equipment and purpose: Slop Oil Tank: 1 x 450 bbl ► Do any of the condensate storage tanks have a capacity>10,000 bbl? ❑ Yes" El No ► Are you requesting≥20 ton/yr VOC emissions,or are uncontrolled actual emissions>20 ton/yr? (If"Yes",Regulation No.7,Section XVII.C will apply) ❑ Yes ® No ► Is this unit located at a stationary source that is considered a Major Source of Hazardous Air Pollutant(HAP)emissions? ❑ Yes ® No O Don't know ► Will this equipment be operated in any NAAQS nonattainment area? (http:/h'Ncw,cdphe.state.co,us/ap/attainmai Main.html) ® Yes B O No O Don't know A If"Yes",the tank(s)may be subject to Regulation No.7,Sections III,IV,&VI,and Regulation No.6,Part A,Subpart Kb or Ka. Provide an applicability determination of these rules. B If"Yes",the tank(s)may be subject to Regulation No.7,Section XII.A or XII.B. Provide an applicability determination of these rules, Colorado Department of Public Health and Environment Section 04—Tank Battery Information' Air Pollution Control Division(APCD) Number of tanks: I Total tank capacity(bbl): 450 This notice is valid for five(5)years. Submit a revised APEN prior to Z expiration of five-year term, or when a significant change is made Condensate throughput: Requested : 328,500 bbl/year Actual calendar year: bbl/year (increase production,new equipment,change in fuel type,etc). Is actual annual average hydrocarbon liquid throughput≥500 bbl/day? ® Yes ❑ No • If"yes"above,identify the gas-to-oil ratio: 0.04 cf/bbl Mail this form along with a check for$152.90 per APEN and S250 for each general permit registration to: Are"flash"3 emissions anticipated from the tank(s)? ❑ Yes ® No Colorado Department of Public Health&Environment APCD-SS-B1 - API gravity: degrees 4300 Cherry Creek Drive South Reid Vapor Pressure: 3.2 psi True Vapor Pressure: psia @ 60°F Denver,CO 80246-1530 _l'u—l'u For guidance on how to complete this APE]P 4 am 'See PS Memo 05-01 for information on condensate tank permitting and identification of parameters used to calculate emissions. Air Pollution Control Division: '093)6 -3150 (http./'sxww.cdphe.state.co u,/ap/down/ps05-01.pd t) Small Business Assistance Program(SBAP): (30392-3148 or 2 Requested values will become permit limitations. (303)692-3175 3 Hydrocarbons can"flash"into the vapor phase due to a reduction in pressure on the hydrocarbon liquids. APEN forms:http://www.cdphe.statc.co.us/an-d(1\1111(lad Ibrms.html Additional O Attach a pressurized pre-flash condensate extended gas analysis,RVP&API analysis of the post-flash oil Information ® Attach E&P Tanks input&emission estimate documentation(or equivalent simulation report/test results) ® Check box to request copy of draft permit prior to issuance. Required: ❑ Attach EPA TANKS emission analysis if emission estimates do not contain working/breathing losses ® Check box to request copy of draft permit prior to public notice. FORM APCD-204 Page 1 oft 316000 SlopOilTank_FormAPCD-204-MidstreamCondensaterankAPEN-2-12-13 AIR POLLUTANT EMISSION NOTICE (APEN) & Application for Construction Permit—Midstream Condensate Tank Battery Permit Number: GP01 Emission Source AIRS ID: (Z3 19GbS / 010 Section 05—Stack Information(Combustion stacks must be listed here) Section 0(i—Stack(Source,if no combustion) Location(Datum&either Lat/Long or UTM) Stack Discharge Operator Stack Base Horizontal Datum UTM UTM Easting or UTM Northing or Method of Collection for Height Above Temp. Flow Rate Velocity Moisture Stack Elevation (NAD27,NAD83, Zone Longitude Latitude Location Data(e.g.map, ID No. (feet) Ground Level (°F) (ACFM) (ft/sec) (%) WGS84) (12 or 13) (meters or de (feet) grees) (meters or degrees) GPS,GoogleEarth) r Direction of stack outlet(check one): ® Vertical ❑ Vertical with obstructing raincap ❑ I turiiontal ❑ Donn ❑ Other(Describe): Exhaust Opening Shape&Size(check one): ❑ Circular:Inner Diameter(inches)= ❑ (.)ther:Length(inches)= Width(inches)= Section 07—Control Device Information ❑ Condenser used for control of the tank battery. ❑ Combustion Device used for control of the tank battery. Rating: \l\113tu hr Type: Make/Model: Type: Make/Model/Serial#: Temperature(°F): Maximum: Average: VOC&HAP Control Efficiency: Requested: % Manufacturer Guaranteed: ",, Requested VOC&HAP Control Efficiency: % Minimum temp.to achieve requested control: °F Waste gas heat content: Btu set ❑ VRU used for control of the tank battery. Constant pilot light? ❑ Yes ❑ No Pilot burner rating: MMI3tu-hr Size: Make/Model: ❑ Closed loop system used for control of the tank battery. Requested VOC&HAP Control Efficiency: % Description: Annual time that VRU is bypassed(emissions vented): % ❑ Describe Any Other: Section 08—Emissions Inventory Information& Emission Control Information ® Emission Factor Documentation attached Data year for actual calendar yr.emissions below&throughput in Sec.04(e.g.2007): Control Device Description Control Emission Factor Actual Calendar Year Emissions4 Requested Permitted Estimation Method Pollutant Efficiency Emissions or Primary Secondary (%Reduction) Uncontrolled Basis Units Uncontrolled Controlled Uncontrolled Controlled Emission Factor (Tons/Year) (Tons/Year) (Tons/Year) (Tons/Year) Source NOx VOC 1.02E-2 lb/bbl 1.67 E&P Tanks CO Benzene De minimis E&P Tanks Toluene Identify in Section 07 De minimis E&P Tanks Ethylbenzene De minimis E&P Tanks Xylene De minimis E&P Tanks n-Hexane 1.57E-3 lb/bbl 0.26 E&P Tanks Please use the APCD Non-Criteria Reportable Air Pollutant Addendum form to report pollutants not listed above. 1 'Annual emission lees will be based on actual emissions reported here. If left blank,annual emission fees will be based on requested emissions. s If Requested Permitted Emissions is left blank,the APCD will calculate emissions based on the information supplied in sections 03-08. Section 09—Applicant Certification-I reby certify that all information contained herein and information submitted with this application is complete,true and correct.If this is a registr i or coverage under gener P01,I further certify that this source is and will be operated in full compliance with-each condition of general permit GPO 1. 7-10 - 14 Josh Patterson Jilt 24 2014 VP of Operations Signat of Person Legally Authon d to Supply Data Date Name of Legally Authorized Person(lease print) Title Page 2 of 2 SlopOilTank_FormAPCD-204-MidstreamCondensateTankAPEN-2-12-13 AIR POLLUTANT EMISSION NOTICE (APEN) & Application for Construction Permit—Midstream Condensate Tank Batter, Permit Number: GP0I [Leave blank unless APCD has already assigned a permit#&AIRS ID] Emission Source AIRS ID: I Z3 / Q( 5" / O1 1 Facility Equipment ID: Sale Oil Tank [Provide Facility Equipment ID to identify how this equipment is referenced within your organization.] Section 01—Administrative Information Section 02—Requested Action(Check applicable request boxes) Company Name: NGL Water Solutions DJ,LLC NAICS,or ® Request for NEW individual permit or newly reported emission source Source Name: Sale Oil Tank SIC Code: ❑ Request MODIFICATION to existing permit(check each box below that applies) Source Location: C9 Salt Water Disposal Facility County: Weld ❑ Change process or equipment ❑ Change company name W'/2 NW'/SECTION 13,T10N,R61W Elevation: Feet ❑ Change permit limit 0 Transfer of ownership ❑ Other Mailing Address: 8207 West 20th Street,Suite B ZIP Code: 80634 ® Request for coverage under GENERAL PERMIT number GP01 Greeley,CO ❑ Request APEN update only(check the box below that applies) Person To Contact: Josh Patterson Phone Number: 303-536-4408 ❑ Revision to actual calendar year emissions for emission inventory Update 5-Year APEN term without change to permit limits or previously E-mail Address: jpatterson@highsierraenergy.com Fax Number: 303-536-4096 ❑ reported emissions Addl.Info. Section 03—General Information &Notes: For existing sources,operation began on: / / For new or reconstructed sources,the projected startup date is: / / 2014 Normal Hours of Source Operation: 24 hours/day 7 days/week 52 weeks/year General description of equipment and purpose: Sale Oil Tank:1 x 450 bbl ► Do any of the condensate storage tanks have a capacity≥10,000 bbl? ❑ Yes A Z No ► Are you requesting≥20 ton/yr VOC emissions,or are uncontrolled actual emissions 2 20 ton/yr? (If"Yes",Regulation No.7,Section XVII.C will apple) E Yes ® No ► Is this unit located at a stationary source that is considered a Major Source of Hazardous Air Pollutant(HAP)emissions? ❑ Yes ® No ❑ Don't know ► Will this equipment be operated in anyNAAQS nonattainment area? (Imp://www.cdphe.state.co.us/ap/attainmaintain.html) ® Yes B 0 No E Don't know A If"Yes",the tank(s)may be subject to Regulation No.7,Sections III,IV,&VI,and Regulation No.6,Part A,Subpart Kb or Ka. Provide an applicability determination of these rules. B If"Yes",the tank(s)may be subject to Regulation No.7,Section XII.A or XII.B. Provide an applicability determination of these rules, Colorado Department of Public Health and Environment Section 04—Tank Battery Information[ Air Pollution Control Division(APCD) Number of tanks: 1 Total tank capacity(bbl): 450 This notice is valid for five(5)years. Submit a revised APEN prior to Z expiration of five-year term, or when a significant change is made Condensate throughput: Requested 2: 328,500 bbl/year Actual calendar year: bbl/year (increase production,new equipment,change in fuel type,etc). Is actual annual average hydrocarbon liquid throughput≥500 bbl/day? ® Yes ❑ No Mail this form along with a check for$152.90 per APEN and$250 • If"yes"above,identify the gas-to-oil ratio: 0.04 cf/bbl for each general permit registration to: Are"flash"3 emissions anticipated from the tank(s)? 0 Yes ® No Colorado Department of Public Health& ironment APCD-SS-BI API gravity: degrees 4300 Cherry Creek Drive South 4 242014 Reid Vapor Pressure: 3.2 psi True Vapor Pressure: psis @ 60°F Denver,CO 80246-1530 For guidance on how to complete this APEN fort! 'See PS Memo 05-01 for information on condensate tank permitting and identification of parameters used to calculate emissions. Air Pollution Control Division: (303)692-3150 (littp IA%%VW cdphe.siaie.co.us/an/down/as05-01.adt) Small Business Assistance Program(SBAP): (303)692-3148 or Requested values will become permit limitations. (303)692-3175 'Hydrocarbons can"flash"into the vapor phase due to a reduction in pressure on the hydrocarbon liquids. APEN forms:http://www.cdphe.state.co.us/ap/downloadlorms.html Additional 0 Attach a pressurized pre-flash condensate extended gas analysis,RVP&API analysis of the post-flash oil Information ® Attach E&P Tanks input&emission estimate documentation(or equivalent simulation report/test results) IN Check box to request copy of draft permit prior to issuance. Required: 0 Attach EPA TANKS emission analysis if emission estimates do not contain working/breathing losses 0 Check box to request copy of draft permit prior to public notice. FORM APCD-204 Page 1 oft SaleOilTank_FormAPCD-204-MidstreamCondensateTankAPEN-2-12-13 316001 AIR POLLUTANT EMISSION NOTICE (APEN) & Application for Construction Permit—Midstream Condensate Tank Batter, Permit Number: GP01 Emission Source AIRS ID: 17.3 / c T 5- / Of Section 05—Stack Information(Combustion stacks must be listed here) Section 06—Stack(Source.if no combustion)Location(Datum&either Lat/Long or UTM) Stack Discharge Operator Stack Base Horizontal Datum UTM UTM Easting or UTM Northing or Method of Collection for Stack Elevation Height Above Temp. Flow Rate Velocity Moisture ° o (NAD27,NAD83, Zone Longitude Latitude Location Data(e.g.map, ID No. (feet) Ground Level (°F) (ACFM) (ft/sec) (%) WGS84) (12 or 13) (meters or degrees)(feet) g ) (meters or degrees) GPS,GoogleEarth) Direction of stack outlet(check one): ® Vertical ❑ Vertical with obstructing raincap ❑ I lorizontal ❑ I)oo.n ❑ Other(Describe): Exhaust Opening Shape&Size(check one): ❑ Circular:Inner Diameter(inches)= ❑ Other:Length(inches)= Width(inches)= Section 07—Control Device Information ❑ Condenser used for control of the tank battery. ❑ Combustion Device used for control of the tank battery. Rating: MMBtu/hr Type: Make/Model: Type: Make/Model/Serial#: Temperature(°F): Maximum: Average: VOC&HAP Control Efficiency: Requested: % Manufacturer Guaranteed: % Requested VOC&HAP Control Efficiency: Minimum temp.to achieve requested control: °F Waste gas heat content: Btu/scf O VRU used for control of the tank battery. Constant pilot light? ❑ Yes ❑ No Pilot burner rating: MMBtu/hr Size: Make/Model: ❑ Closed loop system used for control of the tank battery. Requested VOC&HAP Control Efficiency: "<, Description: Annual time that VRU is bypassed(emissions vented): to ❑ Describe Any Other: Section 08—Emissions Inventory Information& Emission Control Information El Emission Factor Documentation attached Data year for actual calendar yr.emissions behm & throughput in Sec.04(e.g.2007): I Control Device Description Control Emission Factor Actual Calendar Year Emissions' Requested Permitted Estimation Method 5 Pollutant Efficiency Emissions or Primary Secondary (%Reduction) Uncontrolled Basis Units Uncontrolled Controlled Uncontrolled Controlled Emission Factor (Tons/Year) (Tons/Year) (Tons/Year) (Tons/Year) Source NOx VOC 1.02E-2 Ib/bbl 1.67 E&P Tanks CO Benzene De minimis E&P Tanks Toluene Identify in Section 07 De minimis E&P Tanks Ethylbenzene De minimis E&P Tanks Xylene De minimis E&P Tanks n-Hexane 1.57E-3 lb/bbl 0.26 E&P Tanks Please use the APCD\on-Criteria Reportable Air Pollutant Addendum form to report pollutants not listed above. Annual emission fees will be based on actual emissions reported here. If left blank,annual emission fees will be based on requested emissions. $If Requested Permitted Emissions is left blank,the APCD will calculate emissions based on the information supplied in sections 03-08. Section 09—Ai) licant Certific ' n-1 rtify that all information contained herein and information submitted with this application is complete,true and correct. If this is a registrar' n coverage unde r I rmit GPO I,I further certify that this source is and will be operated in full compliance with each condition of general permit GP01. ~ ""2 -f0 - 111- Josh Patterson VP of Operations Signatu of Person Legally A on to Supply Data Date Name of Legally Authorized Person( ittt) Title 14 Page 2 of 2 SaleOilT#1 tkffdafmAPCD-204-MidstreamCondensateTankAPEN-2-12-13 Form APCD-100 Colorado Department of Public Health and Environment 11;.,k Air Pollution Control Division �• La76_� Oil & Gas Industry Colorado Department of Public I tcalth Construction Permit Application Completeness Checklist and En ironment Ver.September 28.2009 Company Name: NGL Water Solutions DJ, LLC Source Name: C9 Salt Water Disposal Facility Date: July 2014 Yes No Are you requesting a facility wide permit for multiple emissions points? ® ❑ In order to have a complete application, the following attachments must be provided, unless stated otherwise. If application is incomplete, it will be returned to sender and filing fees will not be refunded. Attachment Application Element Applicant APCD A APEN Filing Fees ® ❑ B Air Pollutant Emission Notice(s)(APENs)& ® ❑ Application(s) for Construction Permit(s)—APCD Form Series 200 C Emissions Calculations and Supporting Documentation ® ❑ D Company Contact Information - Form APCD-101 ® ❑ E Ambient Air Impact Analysis ❑ ❑ ® Check here if source emits only VOC (Attachment E not required) F Facility Emissions Inventory—Form APCD-102 ® ❑ n Check here if single emissions point source(Attachment F not required) Process description, flow diagram and plot plan of emissions unit and/or ® ❑ facility ❑ Check here if single emissions point source(Attachment G not required) H Operating& Maintenance(O&M) Plan —APCD Form Series 300 ❑ ❑ ® Check here if true minor emissions source or application is for a general permit(Attachment H not required) 1 Regulatory Analysis ® ❑ ❑ Check here to request APCD to complete regulatory analysis (Attachment I not required) Colorado Oil and Gas Conservation Commission(COGCC) 805 Series Rule ❑ ❑ Requirements— Form APCD-105 ® Check here if source is not subject to COGCC 805 Series requirements (Attachment J not required) Send Complete Application to: Colorado Department of Public Health & Environment APCD-SS-B1 4300 Cherry Creek Drive South Denver,Colorado 80246-1530 Check box if facility is an existing Title V source: n Send an additional application copy Check box if refined modeling analysis included: n Send an additional application copy Page 1 of 1 Form APCD -lDU Construction Permit Application Completeness Checklist Form APCD-101 Colorado Department of Public Health and Environment ,Y.c. • Air Pollution Control Division I. 60 6 (.plum&Depaztrnent of Public I lealth Company Contact Information Form Andlltvuonotent Ver.September 10,2008 Company Name: NGL Water Solutions DJ, LLC Source Name: C9 Salt Water Disposal Facility Permit Compliance Contact': Josh Patterson Josh Patterson Contact:: 8207 West 20th Street, Suite B 8207 West 20th Street, Suite B Address: Street Address: Street Greeley CO 80634 Greeley CO 80634 City State Zip City State Zip Phone 303-536-4408 Humb 303-536-4408 Number: er• Fax 303-536-4096 Fax Number: 303-536-4096 Number: E-mail: jptterson@highsierraenergy.com I E-mail: jpatterson@highsierraenergy.com Billing Billing Contact: Josh Patterson Contact: Josh Patterson !Permit (Annual Fees.? Fees)-4 8207 West 20th Street, Suite B 8207 West 20th Street,Suite B Address: Street Address: Street Greeley CO 80634 Greeley CO 80634 City State Zip City State Zip Phone 303-536-4408 uomber• 303-536-4408 Number: N Fax Fax 303-536-4096 303-536-4096 Number: Number: E-mail: jpaerson@highsierraenergy.com E-mail: jpaerson@highsierraenergy.com Check how would you like to receive your permit fee invoice? Mail: ® E-mail: ❑ Fax: O Footnotes: The permit contact should be the point of contact for technical information contained in the permit application. This may be a company representative or a consultant. The compliance contact should be the point of contact for discussing inspection and compliance at the permitted facility. The billing contact(Permit fees)should be the point of contact that should receive the invoice for fees associated with processing the permit application& issuing the permit.(Reg.3,Part A,Section VI.B) ' The billing contact(Annual fees)should be the point of contact that should receive the invoices issued on an annual basis for fees associated with actual emissions reported on APENs for the facility.(Reg.3,Part A.Section VI.C) Page 1 of I Form AI'CD-IOI Company Cantata Information ‘4•N ENEESIO - } ©0111111111110 . . �IJIIIIIIIIIllU • • _ _ ©N0UMNI U a � �IIo0000I00110 _ . X00061 MISi1© 1 111111111 ©IIIIIIIIIIII� _ 1 ®IIIIIIIIIIIIB ' w iEIIIIIIIIIIIII _ I iI11111111111IC _ o ®IIIIIIIIIIII� _ _ t.! EMIIIIMMII - �IIIIo000I1110 3 IMIS 11111110 -_z ©IIIIIIIIIhlU � _ w LIIIIIIIIIIIU ®IIIIIIIIIIH E0000000HHU • r INISO NINIM • 11111111111 EIIIIIIIIIIIIe 3 _ I OM ��IIIIIIIIIIII� = jE LL �IIIIIIIIIIIIO = ! ! i ��IIIIIIIIIIIIO a �_ lj �IIIIIIIIIIII© _ MIIIIIIIIIIIII T 1 IT .bi 1;1y L P11.1112] I a u igam—. '-` C ` C Et r °1 Appendix C Regulatory Review CI)PHE Air Quality Control Regulations Regulation 1 - Emission Control for Particulate Matter,Smoke, Carbon Monoxide and Sulfur Oxides The Facility is subject to Regulation I. (5 CCR 1001-3), and all combustion sources will meet the opacity requirements under this rule. Regulation 2 - Odor Regulation 2 (5 CCR 1001-4 Part A.1) States 'No person, wherever located, .shall cause or allow the emission of odorous air contaminants from any single source such as to result in detectable odors which are measured in excess of the following limits...'. The Facility is subject to this regulation and NGL Water Solutions DJ, LLC will comply with the requirements of this regulation. Regulation 3—Stationary Source Permitting The Facility is subject to Regulation 3 (5 CCR 1001-5) because it meets the definition as a source of air pollutants. Per Regulation 3,a new source located within a nonattainment area must comply with Section 11.B. An Air Pollutant Emission Notice(APEN) is required for each individual emissions point in a nonattainment area with uncontrolled actual emissions of one ton per year or more of any individual criteria pollutant for which the area is nonattainment. Because the Facility is located within an 8-hour ozone control area, an APEN is required for each emission point with VOC emissions greater than I ton per year, and 2 tons per year for all other criteria pollutants. The diesel storage tank is exempt per II.D.I.fff. This application is being submitted in compliance with the applicable sections of Regulation 3. Regulation 6—Standards of Performance for New Stationary Sources The Facility is subject to Regulation 6 (5 CCR 1001-8) Part A, `Federal regulations adopted by reference'. See below for Federal NSPS for applicability review. Regulation 7—Emissions of Volatile Organic Compounds The Facility is subject to Regulation 7 (5 CCR 1001-9) under Sections 111 and VI. Section 111 outlines general requirements for storage and transfer of volatile organic liquids. Section VI specifies requirements for the storage and transfer of petroleum liquid. The tanks storing oil at the Facility are subject to the requirements under Sections III,and VI. NGL Water Solutions DJ, LLC will comply with applicable requirements of this regulation. The facility is located in an Ozone nonattainment area and is therefore, potentially subject to Sections X11. According to section XII.A, the requirements of this section XII.A shall not apply to any owner or operator in any calendar year in which the APENs for all of the atmospheric condensate storage tanks associated with the affected operations owned or operated by such person reflect a total of less than 30 tons-per-year of actual uncontrolled emissions of VOCs in the 8-Hour Ozone Control Area. Regulation 8 —Control of Hazardous Air Pollutants The Facility is subject to Regulation 8 (5 CCR 1001-10) Part E, `Federal regulations adopted by reference'. See Section 5 below for Federal applicability review. Dispersion modeling — Potential NOx and CO emissions are below the significant emissions rate (SER); therefore modeling is not required in accordance with CDPHE PS Memo 10-01. Potentially Applicable Federal Air Quality Regulations Prevention of Significant Deterioration (PSD) Total potential emissions of any criteria pollutant from the Facility are less than 250 ton/year. Potential greenhouse gas (GHG) emissions at the Facility are below PSD major source threshold levels. Therefore, it is not subject to the PSD or the non-attainment NSR permitting programs. New Source Performance Standards(NSPS): The Facility includes sources which may potentially be subject to NSPS requirements included in Title 40 of the Code of Federal Regulations (CFR) Part 60. A review of each potentially applicable subpart is included below. Subpart A Subpart A, General Provisions, applies to any stationary source that contains an affected facility to which an NSPS standard is applicable. Subpart Dc There are only electric heaters operating at the Facility, therefore,this subpart does not apply. Subpart Kb Subpart Kb applies to volatile organic liquid storage vessels constructed, reconstructed, or modified after July 23,1984, with a capacity greater than or equal to 75 m3 (471 bbl). This subpart does not apply to storage vessels with a capacity greater than 151 m3 (949 bbl) storing liquid with a max true vapor pressure less than 3.5 kPa,or storage vessels with a capacity greater than 75 m3 but less than 151 m3, storing liquid with a max true vapor pressure less than 15.0 kPa. The oil tanks are less than the 75 m3 applicability threshold, therefore, this subpart does not apply to the oil tanks. There are several water tanks at the facility with storage capacities between 75 m3(471 bbl)and 151 m3 (949.7 bbl) or greater than 151 m3 (949.7 bbl).The maximum true vapor pressure is less than the 15.0 kPa applicability threshold for tanks between 75 m3 and 151 mi and less than the 3.5 kPa applicability threshold for tanks greater than 151 m3. Therefore, this subpart does not apply to any of the water tanks. Subpart GG There are no turbines at this facility.Therefore, this facility is not subject to 40CFR60.330 Subpart KKK The facility does not meet the definition of an"onshore natural gas processing plant" as defined by this subpart. Therefore,the facility is not subject to 40CFR60.630 Subpart LLL There are no sweetening units at this facility. Therefore, this subpart is not applicable. Subpart IIII,JJJJ There are no SI or CI internal combustion engines at the facility. Therefore, this subpart is not applicable. Subpart KKKK There are no turbines at this facility. Therefore, this subpart is not applicable. Subpart 0000 The storage tanks at this facility were constructed, modified or reconstructed after August 23, 2011. However, the potential to emit, as defined by this subpart, is less than 6 tons per year per tank. In addition, the oil loadout limitation for the facility that will be contained in the construction permit will establish a practically enforceable limit on the tank throughputs to demonstrate that emissions from the tanks cannot exceed the OOOO threshold. Therefore, the tanks are not affected facilities under this regulation. There are no continuous high-bleed pneumatics at the facility. Therefore, the pneumatics are not affected facilities under this regulation. Maximum Achievable Control Technology (MACT): The Facility will be a true minor source of HAPs. Thus, there are no sources at the Facility which are subject to MACT major requirements. Because there are no dehydrators or engines at the facility, area source requirements for MACT HH and MACT 7.7.7.7 do not apply. Greenhouse Gases (GHG): Because this is a water storage facility and there are no combustion sources, GHG are expected to be negligible. Appendix D Facility Emission Calculations and Supporting Documentation Calculation Methods The facility receives post flash produced water from oil and gas operations. Emissions were estimated as follows: 1. Hydrocarbon Liquid Storage Tanks— Emissions were calculated using E&P TANKS with a sample analysis from a similar facility. The sample is considered representative because the facility receives similar trucked in liquids. Margin was added to the input parameters to allow for operational flexibility and to provide a conservative estimate. 2. Produced Water Storage Tanks— Emissions were calculated using EPA TANKS using a mixed composition of water and condensate. The liquid sample from a similar facility showed that the condensate portion of the liquid has a Reid Vapor Pressure of 3.2 psig at 100°F, corrected API Gravity of 47.0 at 60°F, and a molecular weight of 147.12 lb/lb- mol. The sample is representative of the oil coming into the facility. While the composition is similar to crude oil, gasoline RVP10 was conservatively used for the hydrocarbon portion of the liquid because any light end hydrocarbons present in the initial offload of the liquids would be present at the produced water system tanks. 3. Loadout— Working loss emissions from truck loading were estimated using the USEPA loadout equation from AP-42 Section 5.2, using the respective annual maximum volume of condensate loaded. 4. Fugitive Emissions —Process piping fugitive emissions were estimated using USEPA emission factors and estimated component counts. zk88888888 t -5= o o o o o o 3 I $8888888 Q 5^#j NI 8fM1V m u� „ - MO Ifi O ilk§�F;ki� 7i�iryirrc, $ i i iga3 gg 1• i3 I 1�,. _pry.__ �882VR888 ffi ° Kill a xbWTO P `a cyy i b� u Y • [ .a" 8So - 000 }PR"f°2 888 §§§Rs§§§ b1k laABgp�g88 164gAAggg lkw.;mRs $$ . ssg esFse aV kE; ? u i bt t a . aggggg4g6 ;S;s6o a 3^� 8402 1y�gq�i ai8sls ft ftin8- 8 8 H O + E>' 4 M066 O - Q 6666 11 >�, k Rk 9 '''I 'm r a � i$ VIVVVI n 4 OC PPDOR Qn a � R 122 s!pad A ii g P R11 6_ $ g'r?e?eei ,`fin ¢8 iii€ t Iff ' , b $ BA Ikzzz Wtf i MMT 2 og 2o$i � bE 2 X fi b 1 i§ $ a $ i H 5 I L . 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C C O 73 Q) y o ar w frl O 2 a ' - o .0 d C 0- IX -0 C > a ce U) C cii CC J. o C ro cn a 0 m c i .Tr O O c > o_ cn 00 _o 'O o p m a C7 U O O a 4 E O a o 18 Q W o 0 a 6 EiP TANK V2.0 Calculation Report- Developed by DB Robinson i Associates Ltd. 2014.06.17 • Project Setup Information • Project File : F:\_C9 Grasslands S1ID\TANES Runs i Results\450 bbl Oil Heating Tank (P4) .ept Model : Stable Oil Tank Calculation Method : AP42 Control Efficiency : 100.0% Filed Name : C9 Oil Heat Tank (1 x 450 bbl) Well Name : C9 Date : 2014.06.17 * Data Input +► Separator Pressure : 23.00[psig] Separator Temperature : 85.00[F] Ambient Pressure : 14.70[psia] Ambient Temperature : 70.00[F] C10+ SG : 0.9240 C10+ MW : 194.40 -- Stable Oil No. Component mol A 1 H2S 0.0000 2 02 0.0000 3 CO2 0.0000 4 N2 0.0000 5 Cl 0 0000 6 C2 0.0000 7 C3 0.0000 8 i-C4 0.0000 9 n-C4 0.0000 10 i-05 0.8300 11 n-05 0.8300 12 C6 4.8800 13 C7 14.4100 14 C8 9.9600 15 C9 14.9200 16 C10+ 39.7800 17 Benzene 0.8100 18 Toluene 4.2100 19 E-Benzene 0.2700 20 Xylenes 4.7700 21 n-C6 4.3300 22 224Trimethylp 0.0000 -- Sales Oil ------------___�------ Production Rate : 900[bbl/day] Days of Annual Operation : 365 [days/year] API Gravity : 47.0 Reid Vapor Pressure : 3.20[psia] Bulk Temperature : 100.00[F] -- Tank and Shell Data - Diameter : 12.00[ft] Shell Height : 22.50(ft] Cone Roof Slope ; 0.30 Average Liquid Height : 10.00[ft] Vent Pressure Range : 0.03(psi] Solar Absorbance : 0.54 -- Meteorological Data City : Denver, CO page 1 ECP TANK V2.0 Calculation Report— Developed by DB Robinson 6 Associates Ltd. 2014.06.17 Ambient Pressure 14.70[psia) Ambient Temperature : 70.00(F) Min Ambient Temperature 1 36.20(F) Max Ambient Temperature . 64.30(F) Total Solar Insolation : 1568.00[Btu/ft^2•dayJ + Calculation Results • -- Emission Summary ---- ----- — Item Uncontrolled Uncontrolled (ton/yr] (1b/hr] Total RAPs 0.560 0.128 Total HC 2.487 0.568 VOCs, C2+ 2.487 0.568 VOCs, C3+ 2.487 0.568 Uncontrolled Recovery Info. Vapor 58.1500 x1E-3 [MSCFD) HC Vapor 58.1500 x1E-3 (MSCFD] GOR 0.06 [SCF/bbl] -- Emission Composition --—------No Component Uncontrolled Uncontrolled (ton/yr) (lb/hr) 1 H2S 0.000 0.000 2 O2 0.000 0.000 3 CO2 0.000 0.000 4 N2 0.000 0.000 5 Cl 0.000 0.000 6 C2 0.000 0.000 7 C3 0.000 0.000 8 i-C4 0.000 0.000 9 n-C4 0.000 0.000 10 i-05 0.226 0.052 11 n-05 0.184 0.042 12 C6 0 511 0.117 13 C7 0.683 0.156 14 C8 0.194 0.044 15 C9 0.124 0.028 16 C10+ 0.002 0.000 17 Benzene 0.048 0.011 18 Toluene 0.095 0.022 19 E-Benzene 0.003 0.001 20 Xylenes 0.040 0.009 21 n-C6 0.378 0.086 22 224Trimethylp 0.000 0.000 Total 2.488 0.568 -- Stream Data No. Component MW Stable Oil Sales Oil Total Emissions mol * mol '. mol % 1 H2S 34.80 0.0508 0.0000 0.0000 2 O2 32.00 0.0000 0.0000 0.0000 3 CO2 44.01 0.2437 0.0000 0.0000 4 N2 28.01 0.0102 0.0000 0.0000 5 Cl 16.04 0.9543 0.0000 0.0000 6 C2 30.07 0.6701 0.0000 0.0000 7 C3 44.10 2.1827 0.0000 0.0000 8 i-C4 58.12 1.1269 0.0000 0.0000 9 n-C4 58.12 4.6091 0.0000 0.0000 10 i-05 72.15 3.1066 0.8291 11.1943 11 n-05 72.15 5.0558 0.8293 9.0929 12 C6 86.16 4.1726 4 8785 21.7249 13 C7 100.20 10.3655 14.4091 25.1387 14 C8 114.23 10 8426 9.9603 6.2461 page 2 E&P TANX V2.0 Calculation Report--- Developed by DE Robinson 4 Associates Ltd. 2014.06.17 15 C9 128.28 5.5127 14 9210 3.5889 16 C10+ 194.40 45.9695 39.7835 0.0347 17 Benzene 78.11 0.5685 0.8099 2.2011 18 Toluene 92.13 0.2132 4.2100 3.6874 19 E-Benzene 106.17 0.0711 0.2700 0.0860 20 Xylenes 106.17 0.6802 4.7703 1.3452 21 n-C6 86.18 3.5939 4.3290 15.6599 22 224Trimethylp 114.24 0.0000 0.0000 0.0000 MW 139.45 139.45 88.82 Stream Mole Ratio 1.0000 0.9999 0.0001 Heating Value [BTU/SCF] 4817.75 Gas Gravity [Gas/Air] 3.07 Bubble Pt. @ 100F[psial 1.48 1 48 RVP @ 100F [psis] 10.09 10.09 SG @ 100F 0.807 0.807 page 3 m rsl / M "C IA C.) 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N O !' a) o O P CU IL > C G U. d g o n _ g cn�C ; q C. 0 f, t K e- Q i a (9 v .r, ..I. 0 -r N J N ;iJ (q N O) M CC 0O N N N N V O a-,ea _ a a a E w w L 0 03 LL O F2 O L''' H co C ,a E O • E N 4 cn E g o cno w t Y °n' rCO Cl) g' Z a C ' m E (0 a ca s cl ca (/) = J C D 'a Y as C E H g M 12 �w E W C J FS W Of y o V <1' Q1 y X Y LL Ti CO CO _ O CO y 0O C a > - x v C 6" a i- O -14 a� M. C t I— O O L N t CL - m o O O d OG co u) 4' 01 CC o C 0 O y m c O a. N N o m 4 O U Z E E $ •< W o O .5t... _. v EC, TANK V2.0 Calculation Report--- Developed by DB Robinson & Associates Ltd. 2014.06.17 ••• Project Setup Information • Project File : F:\_C9 Grasslands SWD\TANKS Runs i Results\450 bbl Oil Tank (T3) .opt Model : Stable Oil Tank Calculation Method : AP42 Control Efficiency : 100.0% Filed Name : C9 Oil Seat Tank (1 x 450 bbl) Well Name : C9 Date : 2014.06.17 * Data Input • Separator Pressure : 23.00(psig] Separator Temperature : 85.00[1'] Ambient Pressure 14.70[psia] Ambient Temperature : 70.00[!] C10+ SG : 0.9240 C10+ MW : 194.40 -- Stable Oil --- - --- ---------------- No. Component mol M 1 H2S 0.0000 2 02 0.0000 3 CO2 0.0000 4 N2 0.0000 5 Cl 0.0000 6 C2 0.0000 7 C3 0.0000 8 i-C4 0.0000 9 n-C4 0.0000 10 i-05 0.8300 11 n-05 0.8300 12 C6 4.8800 13 C7 14.4100 14 CS 9.9600 15 C9 14.9200 16 C10+ 39.7800 17 Benzene 0.8100 18 Toluene 4.2100 19 E-Benzene 0.2700 20 Xylenes 4.7700 21 n-C6 4.3300 22 224Trimethylp 0.0000 -- Sales Oil - Production Rate : 225(bbl/day] Days of Annual Operation : 365 [days/year] API Gravity : 47.0 Reid Vapor Pressure • 3.20[psia] Bulk Temperature : 70.00[F] -- Tank and Shell Data --------- ------ --------- Diameter : 12.00[ft) Shell Height : 22.50[ft] Cone Roof Slope : 0.30 Average Liquid Height : 10.00[ft] Vent Pressure Range : 0.03[psi] Solar Absorbance : 0.54 -- Meteorological Data ---- ------ ---- City : Denver, CO page 1 E&P TANK V2.0 Calculation Report-- Developed by D8 Robinson & Associates Ltd. 2014.06.17 Ambient Pressure • 14.70(psia] Ambient Temperature . 70.00(F) Min Ambient Temperature 36.20[F) Max Ambient Temperature 64.30[F] Total Solar Insolation 1568.00(8tu/ft"2•day) * Calculation Results + -- Emission Summary -- — — Item Uncontrolled Uncontrolled (ton/yr] [1b/hr] Total HAPs 0.180 0.041 Total HC 0.792 0.181 VOCs, C2+ 0.792 0.181 VOCs, C3+ 0.792 0.181 Uncontrolled Recovery Info. Vapor 18.8100 x1E-3 [MSCFD] HC Vapor 18.8100 x1E-3 [MSCFD] GOR 0.08 [SCF/bbl] -- Emission Composition --No Component Uncontrolled Uncontrolled [ton/yr] [1b/hr] 1 H2S 0.000 0.000 2 02 0.000 0.000 3 CO2 0 000 0.000 4 N2 0.000 0.000 5 Cl 0.000 0.000 6 C2 0 000 0.000 7 C3 0.000 0.000 8 i-C4 0.000 0.000 9 n-C4 0.000 0.000 10 i-05 0.086 0.020 11 n-05 0.068 0.016 12 C6 0.171 0.039 13 C7 0.207 0.047 14 C8 0.053 0.012 15 C9 0.031 0 007 16 C10+ 0.000 0.000 17 Benzene 0.015 0.003 18 Toluene 0.027 0.006 19 E-Benzene 0.001 0.000 20 Xylenes 0.010 0.002 21 n-C6 0.123 0.028 22 224Trimethylp 0.000 0.000 Total 0.792 0.181 -- Stream Data No. Component MW Stable Oil Sales Oil Total Emissions mol % mol % mol % 1 H2S 34.80 0.0508 0.0000 0.0000 2 02 32.00 0.0000 0.0000 0.0000 3 CO2 44.01 0.2437 0.0000 0.0000 4 N2 28.01 0.0102 0.0000 0.0000 5 Cl 16.04 0.9543 0.0000 0.0000 6 C2 30.07 0.6701 0.0000 0.0000 7 C3 44.10 2.1827 0.0000 0.0000 8 i-C4 58.12 1.1269 0.0000 0.0000 9 n-C4 58.12 4.6091 0.0000 0.0000 10 i-05 72.15 3.1066 0.8286 13.2102 11 n-05 72.15 5.0558 0.8289 10.3988 12 C6 86.16 4.1726 4.8780 22.5161 13 C7 100.20 10.3655 14.4090 23.5142 14 C8 114.23 10.8426 9.9605 5.2671 page 2 ESP TANN V2.0 Calculation Report--- Developed by DB Robinson i Associates Ltd. 2014 06.17 15 C9 128.28 5.5127 14.9214 2.7479 16 C10+ 194.40 45.9695 39.7844 0.0162 17 Benzene 78.11 0.5685 0.8098 2.1879 18 Toluene 92.13 0 2132 4.2101 3.2715 19 E-Benzene 106.17 0.0711 0.2700 0.0694 20 Xylenes 106.17 0.6802 4.7704 1.0686 21 n-C6 86.18 3.5939 4.3287 15.7320 22 224Trimethylp 114 24 0.0000 0.0000 0.0000 MW 139.45 139.45 87.50 Stream Mole Ratio 1.0000 0.9999 0.0001 Heating Value [BTU/SCF] 4752.21 Gas Gravity [Gas/Air] 3.02 Bubble Pt. @ 100F[psia] 1.48 1.48 RVP @ 100F [psia] 10.09 10.09 SG @ 100F 0.807 0.807 page 3 E6P TANK V2.0 Calculation Report-- Developed by DB Robinson 6 Associates Ltd. 2014.06.17 • Project Setup Information Project File : F:\_C9 Grasslands SWD\TANKS Runs 6 Results\450 bbl Slop-Sale Oil Tank (T4, T5) .ept Model : Stable Oil Tank Calculation Method : AP42 Control Efficiency : 100.0% Filed Name : C9 Slop/Sale Oil Tanks (1 x 450 bbl) . Modeled for one tank Wall Name : C9 Data : 2014.06.17 * Data Input Separator Pressure : 23.00[paig] Separator Temperature : 85.00[1] Ambient Pressure : 14.70[paia] Ambient Temperature : 70.00[F] C10+ SG : 0.9240 C10+ MW : 194.40 -- Stable Oil --------No. Component mol Q 1 H2S 0.0000 2 O2 0.0000 3 CO2 0.0000 4 N2 0.0000 5 Cl 0.0000 6 C2 0.0000 7 C3 0.0000 8 i-C4 0.0000 9 n-C4 0.0000 10 i-05 0.8300 11 n-05 0.8300 12 C6 4.8800 13 C7 14.4100 14 C8 9.9600 15 C9 14.9200 16 C10+ 39.7800 17 Benzene 0.8100 18 Toluene 4.2100 19 E-Benzene 0.2700 20 Xylenes 4.7700 21 n-C6 4.3300 22 224Trimethylp 0.0000 -- Sales Oil ----------------------------- Production Rate : 900[bbl/day] Days of Annual Operation : 365 [days/year] API Gravity : 47.0 Reid Vapor Pressure : 3.20(paia) Bulk Temperature : 70.00[1] -- Tank and Shell Data ----------------- -------- ---_-- Diameter : 12.00(ft] Shell Height : 22.50[ft] Cone Roof Slope : 0.30 Average Liquid Height : 10.00[ft] Vent Pressure Range : 0.03[psi] Solar Absorbance : 0.54 -- Meteorological Data ------ -- - ----- City : Denver, CO page 1 E&P TANK V2.0 Calculation Report— Developed by DB Robinson i Associates Ltd. 2014.06.17 Ambient Pressure 14.70(psia) Ambient Temperature 70.00[F) Min Ambient Temperature . 36.20[F) Max Ambient Temperature : 64.30[F) Total Solar Insolation : 1568.00[Btu/ft^2•day) • Calculation Results • -- Emission Summary ------- — ---- Item Uncontrolled Uncontrolled [ton/yr] (lb/hr] Total HAPs 0.370 0.084 Total HC 1.668 0.381 VOCs, C2+ 1.668 0.381 VOCs, C3+ 1.668 0.381 Uncontrolled Recovery Info. Vapor 39.5800 x1E-3 [MSCFDJ HC Vapor 39.5800 x1E-3 [MSCFD] GOR 0.04 [SCE/bbl) -- Emission Composition ---------- -- No Component Uncontrolled Uncontrolled [ton/yr) [1b/hr] 1 H2S 0.000 0.000 2 02 0.000 D.000 3 CO2 0.000 0.000 4 N2 0.000 0.000 5 Cl 0.000 0.000 6 C2 0.000 0.000 7 C3 0.000 0.000 8 i-C4 0.000 0.000 9 n-C4 0.000 0.000 10 i-05 0.182 0.042 11 n-CS 0.143 0.033 12 C6 0.361 0-082 13 C7 0.435 0.099 14 C8 0.111 0.025 15 C9 0.064 0.015 16 C10+ 0.001 0.000 17 Benzene 0.033 0.008 18 Toluene 0.057 0.013 19 E-Benzene 0.001 0.000 20 Xylenes 0.022 0.005 21 n-C6 0.258 0.059 22 224Trimethylp 0.000 0.000 Total 1 668 0.381 -- Stream Data NO. Component MW Stable Oil Sales Oil Total Emissions mol + mol N mol % 1 H2S 34.80 0.0508 0.0000 0.0000 2 02 32.00 0.0000 0.0000 0.0000 3 CO2 44.01 0.2437 0.0000 0.0000 4 N2 28.01 0.0102 0.0000 0.0000 5 Cl 16.04 0.9543 0.0000 0.0000 6 C2 30.07 0.6701 0.0000 0.0000 7 C3 44.10 2.1827 0.0000 0.0000 8 i-C4 58.12 1.1269 0.0000 0.0000 9 n-C4 58.12 4.6091 0.0000 0.0000 10 i-05 72.15 3.1066 0.8293 13.2102 11 n-CS 72.15 5.0558 0.8294 10.3988 12 C6 86.16 4.1726 4.8790 22.5161 13 C7 100.20 10.3655 14.4095 23.5142 14 C8 114.23 10 8426 9.9603 5.2671 page 2 E4P TANK V2.0 Calculation Report- Developed by DB Robinson 4 Associates Ltd. 2014.06.17 15 C9 128.28 5.5127 14.9207 2.7479 16 C10+ 194.40 45.9695 39.7823 0.0162 17 Benzene 78.11 0.5685 0.8099 2.1879 18 Toluene 92.13 0.2132 4.2101 3.2715 19 E-Benzene 106.17 0.0711 0.2700 0.0694 20 Aylenes 106.17 0.6802 4.7702 1.0686 21 n-C6 86.18 3.5939 4.3293 15.7320 22 224Trimethylp 114.24 0.0000 0.0000 0.0000 MW 139.45 139.45 87.50 Stream Mole Ratio 1.0000 0.9999 0.0001 Heating Value [BTU/SCE) 4752.21 Gas Gravity [Gas/Air) 3.02 Bubble Pt. @ 100F[psia] 1 48 1.48 RVP @ 100F [psia) 10.09 10 09 SG @ 100F 0.807 0.807 page 3 NGL Water Solutions DJ, LLC Facility: C9 Salt Water Disposal Facility Permit #: TBD AIRS ID: TBD Emission Unit ID SUMP Description Produced Water Unloading Sump Dimensions Width 10 ft Length 10 ft Depth 11 ft Volume 1 100 (ft ') Capacity 196 bbl (ft s X 0.1781 bbl/ft3) Capacity 8228 gal Effective diameter 11 28 ft Throughput (gal/yr) 459.900.000 Emissions' Pollutant lb/yr TPY VOC 3647 24 1 82 Benzene 69.99 0 03 Toluene 123 44 0 06 Ethylbenzene 3.02 0.00 Xylenes 46 46 0 02 n-Hexane 555.25 0.28 Methanol 0.00 0 00 'Emissions were calculated using EPA TANKS 4.0.9d and are working losses only, because the sump is below ground HAPS Speciation • Analyte Mass % Benzene 1 92% Toluene 3.38% Ethylbenzene 0 08% Xylenes 1 27% n-Hexane 15.22% Methanol 0.00% • Speciation from E&P Tank Results m 3 el a r- x VD \ % d E a t.) 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V v a a) NGL Water Solutions DJ, LLC Facility: C9 Salt Water Disposal Facility Permit #: TBD AIRS ID: TBD Emission Unit ID L-1 Description Oil Loadout Throughput (gal/yr) 13,797,000 Saturation Factor, S' 0 6 Vapor Pressure, P (psia) " 2 8 Vapor Molecular Weight, M (lb/lb-mol) "" 50 Liquid Temperature, T ("F) 60 Liquid Temperature, T (°R) 520 ' From AP-42 Table 5.2-1, for tank trucks in submerged loading dedicated normal service • From AP42 Table 7.1-2, Crude Oil (RVP 5). 60 deg Loading Loss (lb VOC/1000 gal) = (12.46.S*P*M)/T AP42 Section 5.2 (1/95) Loading Loss (lb VOC/1000 gal) = 2.01 Loading Loss Throughput Emissions Pollutant lb/1000 gal gal/yr lb/yr TPY VOC 2.01 13,797,000 2777018 13.89 Benzene 0.039 13.797,000 532.90 0.27 Toluene 0 068 13,797,000 939 85 0.47 Ethylbenzene 0 002 13,797.000 22.98 0.01 n-Hexane 0 306 13,797.000 4227 66 2.11 Xylenes 0 026 13,797,000 353.77 0.18 Methanol 0.00 13,797,000 0.00 0.00 NGL Water Solutions W,LLC Facility: C9 Salt Water Disposal Facility Permit IS; TBD AIRS ID: TBO Process Piping Fugitives Calculation Component Tvp. Emission Factors' �urie Percent VOC Npun of Total HC Total VOC Emissions total VOC Count Operation Emosrnns Emission, 41b/hr/source) hr, V6/hr) Ilb/hr) TIFF Valve-gas(oil tanks) 0.009971 7 100.00% 8760 0 07 0.07 0.30 Flanges-gas(oil tanks) 0.000860 21 100.00% 8760 0 02 0.02 0.08 Connectors-gas(oil tanks) 0.000441 87 100.00% 8760 0.04 0.04 0 17 Others-gas(otl tanks) 0.019401 14 100.00% 8760 0.27 0.27 1.19 Open-Ended tines-gas loll tanks) 0.004409 17 100.00% 8760 0.07 0.07 0.33 Pump Seals-gas(oil tanks) 0.005291 0 100.00% 8760 0.00 0.00 0.00 Valve-gas)PW tanks) 0.009971 0 3.00% 8760 0.00 0.00 0.00 Flanges gas IPW tanks) 0.000860 280 3.00% 8760 0.24 0.01 0.03 Connectors-gas(PW tanks) 0.000441 560 3.00% 8760 0 25 0.01 0.03 Others-gas(PW tanks) 0.019401 40 300% 8760 0 78 0.02 0.10 Open-Ended lines-gas(PW tanks) 0.004409 0 300% 8760 0.00 0.00 0.00 Pump Seals-gas(PW tanks) 0.005291 0 3 00% 8760 000 0.00 0.00 Valve-Light Oil 0.005512 37 100.00% 8760 0.20 0.20 0.89 Flanges-light Oil 0.000243 0 100 00% 8760 0.00 0.00 0.00 Connectors-light Oil 0.000463 220 100 00% 8760 0.10 030 0.45 Others-Light OIl 0.016515 7 100.00% 8760 0.12 0.12 0.51 Open-Ended tines-Light Oil 0.000309 Z 100.00% 8760 0.00 0.00 0.00 Pump Seals-tight Oil 0.028660 1 100.00% 8760 0 03 0.03 0.13 Valve-Water/Oil 0.000216 364 100.00% 8760 008 0.08 0.34 Flanges-Water/Oil 0.000006 810 100 00% 8760 0.00 0.00 0.02 Connectors-Water/Oil 0.000243 1292 100 00% 8760 0.31 0.31 1.38 Others-Water/Oil 0.030865 20 100 00% 8760 0.62 0.62 2.70 Open-Ended Lines-Water/Oil 0.000551 68 10000% 8760 0.04 0.04 0.16 Pump Seals•Water/011 0.000053 4 10000% 8760 0.00 000 0.00 Valve-Heavy Oil 0.000019 3 100 00% 8760 0.00 0.00 0.00 Flanges-Heavy Oil 0 000001 0 100 00% 8760 0.00 0.00 0.00 Connectors-Heavy Oil 0.000017 17 100.00% 8760 0.00 0.00 0.00 Others-Heavy Oll 0000071 0 100 00% 8760 0.00 0.00 0.00 Open-Ended Lines-Heavy Oil 0.003086 3 100 00% 8760 0.01 0.01 0.04 Pump Seals-Heavy Oil 0.028660 0 100.00% 8760 0.00 0.00 0.00 •EPA-453/R-95-017,Table 2.4 3851 1 TOTALS: 3.25 2.02 8.86 HAPs Component Wt% Ib/hr tonlyr lb/yr 87 1.92% 0.06 0 27 546 Reportable Sol 3.38% 0.11 048 963 Reportable E8 0.08% 0.00 0.01 24 Not Reportable Iyl 1.27% 0.04 0.18 363 Reportable n-Hen 15.22% 0.49 2.17 4333 Reportable Tank Description l of Tanks VOC wt% Oil Vessels 100 00% Produced Water Vessels 3.00% Offload and Sump 100.0O% Diesel Tank 100.00% Emulsion Breaker Drum . 100.00% Fugitive component counts based on hard counts from similar facilities Gas Service Component Gas Service Oil Gas Service Oily Water Heavy Oil Light Oil Water/Oil Tanks PW Tanks Vessels Connectors 87 560 0 17 220 1292 Flanges 21 280 0 0 0 810 Open-ended lines 17 0 0 3 2 68 Pump Seals 0 0 0 0 1 a Valves 7 0 0 3 37 364 Other 14 40 0 0 7 20 Total 146 880 0 23 267 2558 Emissions presented take no credit for the AVO program NGL Water Solutions DJ, LLC C9 Salt Water Disposal Facility Slop Oil Tank and Sale Oil Tank Emission Composition from E&P Tanks Molecular Weight VOC Weight Liquid Constituent Weight Mole% (Ib/Ibmole Corrected (Ib/Ib-mol) Liquid) % Weight Methane 16.04 0 00% 0 00 0.00% NA Ethane 30.07 0.00% 0.00 0.00% NA Total HC(Non-VOC) 0.00% 0.00 0.00% NA Propane 44.10 0.00% 0.00 0.00% 0.00% Iso-Butane 58.12 0.00% 0.00 0.00% 0.00% N-Butane 58.12 0.00% 0.00 0.00% 0.00% 'so-Pentane 72.15 13.21% 9.53 10.70% 10.70% N-Pentane 72.15 10.40% 7.50 8.42% 8.42% i-Hexanes 8616 22.52% 19.40 21.78% 21.78% n-Hexane 86.18 15.73% 13.56 15.22% 15.22% Heptanes 100.20 23.51% 23.56 26.46% 26 46% Octanes 114.23 5.27% 6.02 6.76% 6 76% Nonanes 128 28 2.75% 3.53 3.96% 3.96% Decanes+ 194.40 0.02% 0.03 0.04% 0 04% Benzene 78.11 2.19% 1.71 1.92% 1 92% Toluene 92.13 3.27% 3.01 3.38% 3 38% Ethylbenzene 106.17 0.07% 0.07 0.08% 0.08% Xylenes 106.17 1.07% 1 13 1 27% 1.27% 2-2-4 TMP 114.24 0.00% 0.00 0.00% 0.00% Total NMNE VOC 100.00% 89.06 100.00% 100.00% Hydrogen Sulfide 34.80 0 00% 0.00 0.00% NA Carbon Dioxide 44.01 0.00% 0.00 0.00% NA Nitrogen 28 01 0.00% 0.00 0.00% NA Totals 93.40% 89.06 93.34% 100.00% • Weight Percent corrected to remove Non-VOC Hydrocarbons, Carbon Dioxide,Nitrogen, and H2S content. NGL Water Solutions Dl,lLC C9 Salt Water Disposal Facility Specific Gravity Calc Composition used in E&P TANK modeling analysis (Wt%•SG) C10+ C10+ MW MW Specific C10+ Component Mole% Mole% Wt% Wt% MW Cale C10r Gravity Average normalized C 1 0.00% 0.00% 16.04 0.00 0.300 0 C 2 0.00% 0.00% 30.07 0.00 0.356 0 C 3 0.00% 0.00% 44.10 0.00 0.507 0 C 4 0.00% 0.00% 58.12 0.00 0.563 0 C 4 0.00% 0.00% 58.12 0.00 0.584 0 C 5 0.00% 0.00% 72.15 0.00 0.624 0 C 5 1.66% 0.79% 72.15 L20 0.631 0.0050 C 6 10.02% 5.70% 86.18 8.64 0.664 0.0378 C 7 18.62% 12.31% 95.88 17.85 0.709 0.0873 C 8 15.00% 11.30% 107.35 16.10 0.740 0.0836 C 9 14.92% 12.62% 116.95 17.45 0.785 0.0991 C 10 6.81% 17 12% 6.39% 11.16% 134.00 9.13 22.95 0.779 0.0498 0.0869 C 11 5 33% 13.40% 5 49% 9.59% 147.00 7.84 1.9.70 0.790 0.0434 0.0758 C 12 4.23% 1064% 4.75% 8.30% 161.00 6.81 17.12 0.801 0.0380 0.0665 C 13 3.17% 7 97% 386% 6.74% 175.00 5.55 13.95 0.812 0.0313 0.0547 C 14 3.19% 8.02% 4 17% 7.28% 190.00 6.06 15.24 0.823 0.0343 0.0599 C 15 219% 5.51% 306% 5.34% 206.00 4.51 11.34 0.833 0.0255 0.0445 C 16 1 95% 4.90% 2.91% 5.08% 222.00 4.33 10.89 0.840 0.0244 0.0427 C 17 1.47% 3.70% 2.32% 4,05% 237.00 3.48 8.76 0.848 0.0197 0.0344 C 18 1.07% 2.69% 1 80% 3.14% 251.00 2.69 6.75 0.853 0.0154 0.0268 C 19 1 31% 3.29% 2.32% 4.05% 263.00 3.45 8.66 0.858 0.0199 0.0348 C 20 0.99% 2.49% 1.85% 3.23% 275.00 2.72 6.85 0.863 0.0160 0.0279 Cu1 1.24% 3.12% 2.43% 4.24% 291.00 3.61 9.07 0,868 0.0211 0.0368 C 22 0.90% 2.26% 1.85% 3.23% 305.00 2.75 6.90 0.873 0.0162 0.0282 C 23 0.86% 2 16% 1 85% 3.23% 318.00 2.73 6.88 0.878 0.0162 0.0284 C 24 0.71% 1 79% 1 58% 2.76% 331.00 2.35 5.91 0.882 0.0139 0.0243 C 25 0.68% 1.71% 1.58% 2.76% 345.00 2.35 5.90 0.886 0.0140 0.0245 C 26 0.66% 1.66% 1.58% 2.76% 359.00 2.37 5.96 0.890 0.0141 0.0246 C 27 0.63% 1 58% 1.58% 2.76% 374.00 2.36 5.92 0.894 0.0141 0.0247 C 28 0 34% 0.85% 0.90% 1.57% 388.00 1.32 3.32 0.897 0.0081 0.0141 C 29 0.33% 0.83% 0 90% 1.57% 402.00 1.33 3.34 0.900 0.0081 0.0141 C 30 plus 1.71% 4 30% 4.08% 7.13% 478.00 8.17 20.55 0.917 0.0374 0.0654 Total 100.0% 100.0% 147.12 0.794 C10+ 39.77% 100.0% 57.25% 100.0% 85.89 216.0 0.840 CIO+with margin of: 10% 56.57 194.4 0.924 Parameters(MW and SG)from above calculations correlate with sample results shown below: Specific Average MW Gravity 14716 0,794 mol96 Composition less HAP Benzene C6 0.81% C6= 4.88% Toluene C7 4.21% C7= 14.41% Ethylbenzene C8 0.27% C8= 9.96% Xylenes C8 4.77% C10+= 39.77% n hexane C6 4.33% Representative Liquid Analysis Normalized to 63.23% %of Hydrocarbons Mass% Vol°A, Mol% Mass% Vol% Mol% 1.954 300 propane P3 0.035 0.053 0.095 0.06% 0.08% 0.15% 2.072 361.4 14 i-butane 0.066 0.088 0.135 0.10% 0 14% 0.21% 2.173 402.94 P4 n-butane 0.346 0.443 0.706 0.55% 0.70% 1.12% 2.543 470.415 i-pentane 0.654 0.784 1.076 1.03% 1.24% 1 70% 2.744 497.74 P5 n-pentane 1.079 1.28 1.776 1.71% 2.02% 2.81% 3.54 564.38 16 2,3-dimethylbutane 0.27 0.303 0.372 0.43% 0.48% 0.59% 3.609 568.916 2-methylpentane 0.977 1.11 1.345 1.55% 1.76% 2.13% 3.848 583.3216 3-methylpentane 0.629 0.703 0.867 0.99% 1.11% 1.37% 4,157 600 P6 n-hexane 1.988 2.239 2.739 3.14% 3.54% 4.33% 4.645 622.7317 2,2-dimethylpentane 0.064 0.071 0.076 0.10% 0.11% 0.12% 4.729 626.29 N6 methylcyclopentane 0.849 0.842 1 198 1.34% 1.33% 1.89% 4.787 628.72 17 2,4-dimethylpentane 0.152 0.167 0.18 0.24% 0.26% 0.28% 5.364 650.54 A6 benzene 0.335 0.283 0.509 0.53% 0.45% 0.81% 5.453 653.6 O7 2-methyl-c-hexene-3 0.036 0.039 0.044 0.06% 0.06% 0.07% 5.599 658.5 N6 cyclohexane 0.958 0.914 1 352 1.52% 1.45% 2.14% 5.841 666.26 17 2-methylhexane 0.937 1025 1.11 1.48% 1.62% 1.76% 5.893 667.89 17 2,3-dimethylpentane 0.254 0.272 0.301 0.40% 0.43% 0.48% 5.993 670.92 X6 t-amylmethylether 0.25 0.247 0.291 0.40% 0.39% 0.46% 6.13 674.99 17 3-methylhexane 0.953 1.03 1,129 1.51% 1.63% 1.79% 6.348 681.21 N7 1c,3-dimethylcyclopentane 0.261 0.26 0.316 0.41% 0.41% 0.50% 6.449 684 N7 1t,3-dimethylcyclopentane 0.307 0.305 0.372 0 49% 0 48% 0.59% 6.551 686.76 N7 1t,2-dimethylcyclopentane 0.381 0.377 0.461 0.60% 0.60% 0.73% 7.069 700 P7 n-heptane 2.582 2.804 3.059 4.08°k 4.43% 4.84% 7.971 722.71 N7 methylcyclohexane 2.789 2.691 3.372 4.41% 4.26% 5.33% 8.002 723.44 -- unknown 0.041 0.043 0.049 0.06% 0.07% 0.08% 8.048 724.49 18 2,2-dimethylhexane 0.162 0.173 0.169 0.26% 0.27% 0.27% 8.487 734.34 N7 ethylcyclopentane 0.231 0.224 0.279 0.37% 0.35% 0.44% 8.59 736.56 18 2,4-dimethylhexane 0.2 0.213 0.208 0.32% 0.34% 0.33% 8.881 742.65 -- unknown 0.17 0.18 0.177 0.27% 0.28% 0.28% 8.935 743.75 N8 1 c,2t,4-trimethylcyclopentane 0.046 0.045 0.049 0.07% 0.07% 0.08% 9.254 750.11 O7 O37 0.132 0.134 0.159 0.21% 0.21% 0.25% 9.754 759.58 A7 toluene 2.068 1.771 2.665 3.27% 2.80% 4.21% 9.973 763.56 18 2,3-dimethylhexane 0.129 0.134 0.134 0 20% 0.21% 0.21% 10.017 764.34 18 2-methyl-3-ethylpentane 0.075 0.078 0.078 0.12% 0.12% 0.12% 10.338 769.9618 2-methylheptane 1.089 1158 1132 1.72% 1.83% 1.79% 10.403 771.05 18 4-methylheptane 0.325 0.343 0.338 0.51% 0.54% 0.53% 10_476 772.3 18 3,4-dimethylhexane 0.056 0.058 0.059 0.09% 0.09% 0.09% 10.762 777.05 N8 1c,2c,4-trimethylcyclopentane 0.796 0.776 0.843 1.26% 1 23% 1.33% 10.813 777 88 3-methylh€18 0.05 0 052 0.052 0 08% 0.08% 0.08% 10.842 778.36 18 3-ethylhexane 0.83 0.864 0.863 1.31% 1.37% 1.36% 10.928 779.75 N8 1t,4-dimethylcyclohexane 0.359 0.349 0.379 0.57% 0.55% 0.60% 11 197 784.02 N8 1,1-dimethylcyclohexane 0.142 0.135 0.151 0.22% 0.21% 0.24% 11.385 786 93 19 2.2,5-trimethylhexane 0.035 0 036 0.032 0.06% 0.06% 0.05% 11.576 789.83 N8 3t-ethylmethylcyclopentane 0.052 0 05 0.055 0.08% 0.08% 0.09% 11.859 794.03 N8 1t,2-dimethylcyclohexane 0.325 0.311 0.343 0.51% 0.49% 0.54% 12.274 800 P8 n-octane 2.581 2.728 2.682 4.08% 4.31% 4.24% 13.339 819.05 19 2,3,4-trimethylhexane 0.086 0.086 0.079 0.14% 0.14% 0.12% 13.617 823.75 O9 O52 0.25 0.258 0.235 0.40% 0.41% 0.37% 14.025 830.45-- unknown 0.798 0.846 0.75 1 26% 1.34% 1.19% 14.06 831.02 19 2,2,3-trimethylhexane 0.177 0.184 0.164 0.28% 0.29% 0.26% 14.35 835.63 N8 N4 0 236 0.225 0.25 0.37% 0.36% 0.40% 14.505 838.05 19 3,3-&3,5-dimethylheptane 0 337 0.345 0.312 0.53% 0.55% 0.49% 14.604 839.59 19 2,6-dimethylheptane 0.069 0.073 0.064 0.11% 0.12% 0.10% 15.36 850.94 N8 N7 0.291 0.277 0.308 0.46% 0.44% 0.49% 15.439 852.09 A8 ethylbenzene 0.155 0.133 0.173 0.25% 0.21% 0.27% 16.147 862.11 A8 1,3-dimethylbenzene 2.181 1.874 2.439 3.45% 2.96% 3.86% 16.212 863.01 AB 1,4-dimethylbenzene 0.516 0.445 0.577 0.82% 0.70% 0.91% 16 276 863.88 19 2,3-dimethylheptane 0.036 0.037 0.034 0.06% 0.06% 0.05% 16.425 865.92 19 3,4-dimethylheptane 0.101 0.103 0.094 0.16% 0.16% 0.15% 16.714 869.79 19 3,4-dimethylheptane 0.387 0.393 0.358 0.61% 0.62% 0.57% 16.809 871.06 19 15 0.468 0.476 0.433 0.74% 0.75% 0.68% 17.171 875 79 -- unknown 0.111 0.118 0.103 0.18% 0 19% 0 16% 17.295 877 39 19 3-ethylheptane 0.518 0.53 0 48 0.82% 0.84% 0 76% 17.623 881 54 N9 lc.21.4c-tnmethylcyclohexane 0.037 0.036 0 035 0.06% 0 06% 0.06% 17.738 882 98 N9 1c,2t,3c-tnmethylcyclohexane 0 58 0 568 0.545 0.92% 0 90% 0.86% 17.976 885 93 N9 N18 0.04 0.038 0.037 0.06% 0 06% 0 06% 18 093 887.36 N9 N19 0 344 0.328 0.324 054% 0 52% 0 51% 18.222 888.93 N9 N20 0.211 0.201 0 199 0.33% 0.32% 031% 18 812 895.95 N9 N22 0 044 0.042 0 041 0.07% 0 07% 0 06% 19.162 900 P9 n-nonane 2.104 2.177 1 948 3 33% 3.44% 3 08% 19.231 901 69 N9 1,1-methylethylcyclohexane 0 18 0.166 017 0.28% 0.26% 0.27% 19 408 906.01 N9 N25 0 07 0.066 0 066 0 11% 0.10% 0.10% 19 705 913.17 A9 i-propylbenzene 0.05 0.043 0 049 0.08% 0.07% 0.08% 19 806 915.58 110 111 0.134 0 136 D 111 0 21% 0 22% 0 18% 19.911 918.06 -- unknown 0.065 0.069 0.054 0.10% 0 11% 0 09% 19.986 919.83 110 112 0.036 0 037 0.03 0.06% 0.06% 0.05% 20 114 922 84 2.4-dimeth 110 0.194 0 198 0 162 0 31% 0 31% 0.26% 20 208 925.02 110 2,2-dimethyloctane 0.039 0 039 0 032 0 06% 0.06% 0.05% 20.489 931 51 110 2,5-dimethyloctane 0.524 0 533 0.437 0.83% 0.84% 0 69% 20 68 935.87 -- unknown 0.1 0 106 0.083 0.16% 0 17% 0 13% 20.733 937 07 N9 n-butylcyclopentane 0.054 0 051 0 05 0 09% 0.08% 0 08% 20.927 941 44 110 3,3-dimethyloctane 0 333 0.335 0-278 0.53% 0 53% 0 44% 21.193 947.34 110 3,6-dimethyloctane 0117 0 118 0.098 0.19% 0 19% 015% 21.25 948.6 — unknown 0.083 0 088 0.07 0 13% 0 14% 0.11% 21.571 955 61 A9 1,4-methylethylbenzene 0 384 0.331 0.379 0 61% 0.52% 0.60% 21 649 957 31 -- unknown 0 145 0.154 0.144 0 23% 0 24% 0 23% 21.747 959 41 N10 N33 0 049 0 045 0.041 0 08% 0.07% 0.06% 21 819 960 95 -- unknown 0.035 0.037 0 029 0 06% 0.06% 0.05% 21.854 961.7 A9 1,3,5-trimethylbenzene 0.148 0.127 0 146 0.23% 0.20% 0.23% 21.926 963.24 110 115 0 46 0.462 0 384 0 73% 0.73% 0.61% 22.031 965.48 110 116 0.037 0.037 0 031 0 06% 0.06% 0.05% 22.092 966.77 110 5-methylnonane 0.127 0 129 0 106 D 20% 0.20% 0.17% 22 178 968 59 110 4-methylnonane 0.316 0.317 0 264 0 50% 0.50% 0.42% 22.291 970 94 A9 1,2-methylethylbenzene 0.384 0 323 0.379 0.61% 0.51% 0 60% 22.409 973 41 110 3-ethyloctane 0.051 0 051 0.043 0.08% 0.08% 0.07% 22 509 975.48 N10 N35 0.049 0 046 0 042 0 08% 0.07% 0 07% 22 559 976.52 110 3-methylnonane 0.275 0.278 0.229 0.43% 0.44% 0.36% 22.634 978.07 N10 N36 0 037 0 034 0.031 0.06% 0.05% 0.05% 22.848 982.45 A9 1,2,4-tnmethylbenzene 0 034 0 029 0 034 0.05% 0.05% 0 05% 22.974 985.01 110 120 0 893 0 896 0 745 1.41% 1 42% 1 18% 23.06 986 75 110 121 0.185 0.186 0 154 0.29% 0 29% 0 24% 23.393 993 42 O10 2.3-dimethyloctene-2 0.048 0 048 004 0.08% 0 08% 0.06% 23 461 994.76 N10 1 t-methyl-2-n-propyicyclohexane 0 075 0 069 0.063 0.12% 0.11% 0.10% 23 726 1000 P10 n-decane 1 803 1 834 1 505 2.85% 2.90% 2.38% 23 994 1008.73 A9 1.2,3-trimethylbenzene 0 102 0 085 0.101 0.16% 0.13% 0.16% 24 053 1010 63 A1D 1.3-methyl-i-propylbenzene 0 079 0.068 0.07 0 12% 0.11% 0 11% 24.162 1014 14 111 127 0 043 0 043 0.032 0 07% 0 07% 0.05% 24.213 1015.8 111 128 0.039 0 04 0.03 0 06% 006% 0.05% 24 242 1016 72 -- unknown 0 046 0.049 0.035 0 07% 0.08% 0.06% 24.434 1022.86 N10 sec-butylcyclohexane 0.077 0 07 0 065 0.12% 0.11% 0 10% 24.487 1024 54 111 130 0.095 0 095 0 072 0.15% 0.15% 0.11% 24.548 1026 47 A10 1.2-methyl-i-propylbenzene 0.307 0 26 0 271 0.49% 0 41% 0.43% 24 71 1031 59 -- unknown 0 067 0.071 0.06 0.11% 0 11% 0 09% 24.748 1032.79 N11 N40 0.252 0.234 0.194 0 40% 0.37% 0 31% 24 877 1036.83 111 132 0 067 0 062 0.052 0 11% 0 10% 0.08% 24 932 1038.53 -- unknown 0.079 0 084 0.061 0.12% 0 13% 0.10% 24.997 1040.55 A10 1 3-diethylbenzene 0.049 0 042 0 044 0.08% 0.07% 0.07% 25 087 1043.34 A10 1.3-methyl-n-propylbenzene 0 271 0.234 0 24 0.43% 0 37% 0 38% 25.213 1047 23 A1D 1.4-diethylbenzene 0.079 0.068 0.07 0.12% 0 11% 0 11% 25.247 1048.29 A10 1.3-dimethyl-5-ethylbenzene 0.032 0.027 0 028 0 05% 0.04% 0.04% 25.316 1050.38 A10 n-butylbenzene 0.138 0.119 0 122 0 22% 0 19% 0 19% 25.395 1052 81 111 134 0 038 0.039 0.029 0.06% 0.06% 0 05% 25 485 1055.55 N11 N41 0.14 0 129 0.107 0 22% 0.20% 0.17% 25 592 1058 82 111 135 0 034 0 035 0 026 0 05% 0.06% 0 04% 25 669 1061 14 111 136 0.169 0 17 0 129 0.27% 0.27% 0.20% 25 769 1064 13 111 138 0.161 0 161 0 122 0.25% 0.25% 0 19% 25.885 1067.61 A10 1.4.dimethyl-2-ethylbenzene 0.241 0 204 0 213 0 38% 0 32% 0.34% 25.926 1068.85 A10 A3 0.042 0.036 0.037 0.07% 0.06% 0 06% 25 981 1070.5 111 139 0 074 0 074 0.056 0.12% 0.12% 0.09% 26.082 1073.51 111 140 0.171 0 171 0.13 0.27% 0 27% 0 21% 26.173 1076.18 A10 1,2-dimethyl-4-ethylbenzene 0.081 0 069 0 072 0 13% 0 11% 0 11% 26 483 1085.29 111 143 0 092 0.093 0.07 0.15% 0 15% 0 11 26 603 1088.79 -- unknown 0.062 0 066 0.047 0 10% 0 10% 0 07% 26.663 1090.53 O11 undecene-1 0.055 0 055 0 042 0.09% 0.09% 0.07% 26.72 1092 2 A10 1.2-dimethyl-3-ethylbenzene 0 058 0 048 0.051 0.09% 0.08% 0.08% 26 788 1094 17 All 1,4-methyl-t-butylbenzene 0.07 0 061 0.056 0.11% 0.10% 0.09% 26.863 1096 31 Al 1 1,2-ethyl-i-propylbenzene 0.069 0 058 0 055 0 11% 0.09% 0.09% 26 991 1100 P11 n-undecane 1 628 1 625 1.236 2.58% 2.57% 1.95% 27.097 1104 16 A10 1,2,4,5-tetramethylbenzene 0.039 0 033 0 035 0.06% 0 05% 0.06% 27.155 1106.44 All 1,2-methyl-n-butytbenzene 0.053 0.044 0 043 0.08% 0 07% 0.07% 27.258 1110 47 Al 0 1,2,3,5-tetramethylbenzene 0 037 0 031 0 033 0.06% 0.05% 0.05% 27.287 111 1 6— unknown 0.06 0 063 0 053 0.09% 0.10% 0.08% 27.458 1118.22 — unknown 0.068 0 072 006 0 11% 0 11% 0 09% 27.491 1119 51 All 1,2-methyl-t-butylbenzene 0.065 0.054 0 052 0 10% 0 09% 0.08% 27 647 1125.51 — unknown 0.04 0 043 0 032 0 06% 0.07% 0.05% 27.763 1129 97 A10 5-methylindan 0.149 0 125 0 134 0.24% 0 20% 0.21% 27.948 1137 04 All 1,2-ethyl-n-propylbenzene 0.237 0.197 0.19 0 37% 0 31% 0.30% 28.039 1140 46 All 1,3-methyl-n-butylbenzene 0.032 0.026 0.025 0.05% 0 04% 0.04% 28.155 1144 84 A11 s-pentylbenzene 0.05 0 042 0.04 0.08% 0 07% 0.06% 28.348 115211 N12 1t-M-2-(4-MP)cyclopentane 0086 0.08 0.061 0 14% 0 13% 0.10% 28.401 1154 1 Al2 1,2-di-i-propylbenzene 0.042 0 035 0 031 0 07% 006% 0 05% 28 468 1156 59 -- unknown 0 107 0 114 0 078 0.17% 0 18% 0 12% 28.503 1157.881,4-di-i-prcAl2 0 119 0.099 0.087 0.19% 0 16% 0 14% 28.605 1161 69 A10 tetrahydronaphthalene 0 119 0.091 0.107 0.19% 0 14% 0.17% 28.719 1165 91 112 145 0 175 0 173 0 122 0.28% 0 27% 0 19% 28.756 1167 28 A10 naphthalene 0 04 0.029 0.037 0.06% 0 05% 0,06% 28.893 1 172 31 Al2 1,4-ethyl-t-butytbenzene 0.174 0 145 0.127 0.28% 0 23% 0.20% 29.137 1181 23 112 147 0.04 0.04 0 028 0 06% 0 06% 0.04% 29.231 1184 64 112 148 0.062 0 061 0.043 0.10% 0.10% 0.07% 29.337 1188.45 Al2 1.3-di-n-propylbenzene 0 117 0.098 0.086 0.19% 0.15% 0.14% 29.46 1192.88 O12 dodecene-1 0.065 0 064 0 046 0.10% 0.10% 0.07% 29.658 1200 P12 n-dodecane 1 414 1 394 0 985 2 24% 2.20% 1.56% 29.721 1202 79 -- unknown 0 037 0.04 0 026 0 06% 0 06% 004% 29 777 1205 28 -- unknown 0 036 0.038 0 025 0 06% 0 06% 0.04% 29.923 1211.78 Al2 1.3.5-tnethylbenzene 0 044 0 037 0 032 0 07% 006% 0 05% 30.01 1215 61 -- unknown 0.298 0 316 0.218 0.47% 0.50% 0.34% 30.085 1218 92 -- unknown 0 052 0.055 0.038 0.08% 0.09% 0 06% 30.193 1223 65 -- unknown 0 051 0 054 0 038 0.08% 0.09% 0.06% 30 313 1228 91 -- unknown 0.034 0.036 0.025 0.05% 0.06% 0 04% 30.352 1230.59 Al2 1,2,4-tnethylbenzene 0.047 0 039 0.034 0.07% 006% 0 05% 30.634 1242 83 Al2 1.4-methyl-n-pentylbenzene 0 128 0.107 0 094 0.20% 0 17% 0 15% 30.674 1244.55 -- unknown 0 049 0 052 0 036 0.08% 0 08% 0.06% 30.887 1253 69 Al2 n-hexylbenzene 0.095 0.079 0 07 0 15% 0 12% 0.11% 30 934 1255.72 — unknown 0.095 0 1 0O69 0.15% 0 16% 0.11% 31 042 1260.33 — unknown 0 187 0.198 0.137 0 30% 0 31% 0.22% 31.151 1264.97 -- unknown 0 154 0 163 0 112 0 24% 0 26% 0.18% 31.201 1267 07 -- unknown 0 035 0.037 0 025 0.06% 0.06% 0 04% 31.309 1271 64 113 150 0 128 0.125 0.082 0 20% 0 20% 0 13% 31.406 1275.74 All 1,2.3,4,5-pentamethylbenzene 0.216 0.16 0173 0.34% 0.25% 027% 31.696 1287 89 -- unknown 0 207 0.22 0.166 0.33% 0.35% 0.26% 31.788 1291.68 O13 lndecene-1 0 034 0 033 0 022 0 05% 0 05% 0.03% 31.81 1292.61 -- unknown 0 043 0 045 0 028 0.07% 0.07% 0.04% 31 896 1296 16 All 1-methylnaphthalene 0 036 0.027 0 03 0.06% 0.04% 0.05% 31 988 1300 P13 n-Iridecane 1 189 1.167 0 765 1 88% 1 85% 1.21% 32.064 1303.68 + C14+ 0 106 0.103 0 064 0.17% 0.16% 0.10% 32.292 1314.8 + C14+ 0.039 0.038 0.024 0.06% 0.06% 0.04% 32.348 1317 52 + C14+ 0 041 0 04 0.025 0 06% 0.06% 0.04% 32.387 1319.41 + C14+ 0.085 0 083 0.051 0.13% 0.13% 0 08% 32.745 1336.63 + C14+ 0.06 0.058 0.036 0.09% 0.09% 0.06% 32.827 1340 54 + C14+ 0 055 0 054 0 033 0.09% 0.09% 0.05% 32,987 1348 17 + C14+ 0 158 0.154 0 094 0 25% 0 24% 0.15% 33.058 1351.5 + C14+ 0.091 0 088 0.054 0.14% 0 14% 0.09% 33.119 1354 4 + C14+ 0 063 0 061 0.038 0 10% 0 10% 0.06% 33.225 1359 41 + C14+ 0 099 0.096 0 059 0 16% 0.15% 0.09% 33 331 1364 41 + C14+ 0 121 0 118 0 072 0 19% 0 19% 0.11% 33 479 1371 34 + C14+ 0 118 0.115 0.071 0.19% 0.18% 0 11% 33 542 1374.25 + C14+ 0.036 0.035 0.021 0.06% 006% 0.03% 33 655 1379.51 + C14+ 0.22 0 214 0 132 0.35% 0.34% 0.21% 34 098 1400 + C14+ 0 954 0 929 0 571 1 51% 1 47% 0,90% 34 166 1400 + C14+ 0 041 0 04 0 024 0.06% 0 06% 0 04% 34 184 1400 + C14+ 0 053 0.051 0 032 0.08% 0 08% 0 05% 34 286 1400 + O14+ 0.062 0 061 0 037 0.10% 0.10% 0.06% 34 437 1400 + C14+ 0.099 0 097 0.059 0.16% 0 15% 0.09% 34 517 1400 + C14+ 0 073 0 071 0 044 0.12% 0.11% 0 07% 34 844 1400 + C14+ 0 047 0 045 0.028 0.07% 0.07% 0 04% 35 12.5 1400 + C14+ 0 137 0 133 0 082 0.22% 0 21% 0 13% 35.234 1400 + C14+ 0 057 0 055 0 034 0 09% 0 09% 0 05% 35.357 1400 + C14+ 0.319 0 311 0 191 0.50% 0.49% 0 30% 35.48 1400 + C14+ 0.071 0 069 0.042 0.11% 0 11% 0 07% 35.624 1400 + C14+ 0.049 0 048 0 03 0 08% 0 08% 0 05% 35.718 1400 + C14+ 0.044 0 043 0.026 0.07% 0.07% 004% 36.05 1400 + C14+ 0.906 0.881 0.542 1.43% 1 39% 0.86% 36 13 1400 + C14+ 0 038 0.037 0.023 0 06% 006% 0.04% 36.223 1400 + C14+ 0 044 0.043 0.026 0 07% 0 07% 0 04% 36.314 1400 + C14+ 0 052 0.051 0.031 0.08% 0 08% 0 05% 36.559 1400 + C14+ 0.034 0.034 0.021 0 05% 0 05% 0 03% 36.669 1400 + C14+ 0.047 0.045 0.028 0.07% 0 07% 0 04% 36.896 1400 + C14+ 0 044 0.043 0.027 0 07% 0.07% 0.04% 37 076 1400 + C14+ 0 048 0 047 0 029 0 08% 0 07% 0.05% 37.109 1400 + O14+ 0 094 0.092 0.056 0 15% 0 15% 0 09% 37.203 1400 + C14+ 0 091 0O89 0.055 0 14% 0.14% 0.09% 37 296 1400 + C14+ 0 062 0.061 0.037 0.10% 0.10% 0.06% 37 344 1400 + C14+ 0.063 0.061 0.038 0 10% 0.10% 0.06% 37.59 1400 + C14+ 0.039 0.038 0 023 0 06% 0 06% 0.04% 37 734 1400 + C14+ 0 041 0.04 0 025 0 06% 0.06% 0.04% 37 876 1400 + C14+ 0 756 0.736 0 453 1.20% 1.16% 0.72% 38 657 1400 + C14+ 0.067 0.065 004 0 11% 0 10% 0.06% 38.77 1400 + C14+ 0.209 0.204 0 125 0 33% 0.32% 0.20% 38.88 1400 + C14+ 0.046 0.045 0.028 0.07% 0.07% 0 04% 38.975 1400 + C14+ 0.084 0.082 0 05 0 13% 0.13% 0 08% 39 121 1400 + C14+ 0.051 0 049 0 03 0.08% 0.08% 0.05% 39.671 1400 + C14+ 0 645 0 628 0 386 1.02% 0.99% 0 61% 39.851 1400 + C14+ 0.232 0 226 0 139 0.37% 0.36% 0.22% 63.22 63.23 63.23 100.00% 100.00% 100.00% TECHNOLOGY LABORATORY, INC. // /7 ENTRE PROFESSIONAL OFFICE PARK 1012 Centre Avenue Fort Collins, Colorado 80526 (970) 490-1414 • CERTIFICATE OF ANALYSIS CGRS Sampled: 06/15/09 PO Box 1489 Received: 06/15/09 Fort Collins, CO 80522 Analyzed: 06/18/09 Sample ID: Separation Tank Project #: 1-8019-10695aa Laboratory ID: 8528-03 Matrix: Water HAZARDOUS AIR POLLUTANTS CAS Concentration Concentration Number Compound Analyzed m L 1%Wt/ Wt) 71-43-2 Benzene 1070 0.1070 108-88-3 Toluene 6246 0.6246 100-41-4 Ethylbenzene 931 0.0931 1330-20-7 Total Xylenes 10161 1.0161 1634-04-4 MTBE Non Detected 0.0000 91-20-3 Naphthalene 177 0.0177 540-84-1 Iso-Octane Non Detected 0.0000 110-54-3 n-Hexane 11909 1.1909 98-82-8 Isopropylbenzene 247 0.0247 QA/QC SURROGATE RECOVERIES Compound Lr-, Recovery % Rec. Limits Dibromofluoromethane 89 68-120 1,2 Dichloroethane-d., 86 70-119 Toluene-d, 9G 80-114 Page 2 of 20 TECHNOLOGY LABORATORY, INC. CENTRE PROFESSIONAL OFFICE PARK 1012 Centre Avenue • Fort Collins, Colorado 80526 (970) 490-1414 CERTIFICATE OF ANALYSIS CGRS, INC Sampled: 06/15/09 PO Box 1489 Received: 06/15/09 Fort Collins, CO 80522 Sample ID: Separation Tank-001 Project No.: 1-8019-10695aa Laboratory ID: 8528-03 Matrix: Water Date Parameter Result Units 0/u Wt/Wt Method Analyzed DRO (TEPH) 7942 mg/L 0.7942 EPA-8015B 06/17/09 Methanol <10.0 mg/L 0.0000 EPA-8015B 06/16/09 Modified GRO (TVPH) 438342 mg/L 43.8342 EPA-8260B 06/18/09 Page 4 of 20 Detailed Hydrocarbon Analysis Summary Report- Report Date:6/18/2009 11:38:08 AM RawFile:C:1Chem32111DATAITLIIDHA-061709-8528-02.D1DHA-061709-8528-02.CDF Acquired:06/17/09 11:15:44 Sample:Condensate-001 Analyzed.6/18/2009 11:31:41 AM Processed 233 Peaks Reference File:C:1Chem32111DHARef1PONA-VI.DHA Comments: Normalized to 63.2300% SUMMARY REPORT Group Type Total(Mass%) Total(Vol%1 Total(Mol°/41 Paraffins: 16.7489 17.7420 17.4960 I-Paraffins: 15.1992 16.0238 15.8027 Olefins: 0.6206 0.6299 0.5896 Napthenes. 10.3480 9.9832 11.7975 Aromatics: 9.7136 8.2373 10.2396 Total C14+: 6.9938 6.8074 4.1851 Total Unknowns. 3.3556 3.5592 2.8287 Oxygenates. Total. 0.2503(Mass%) 0.2473(Vol%) Total Oxygen Content: 0.0392(Mass%) Multisubstituted Aromatics: 6.4361(Mass%) 5.4603(Vol%) Average Molecular Weight: 118.2459 Relative Density:0.7395 Vapor Pressure: 1.9843 Calculated Octane Number:62.2351 IBP T10 T50 T90 FBP Boiling Point(Deg F) 82.11 195.80 391.50 T90 488.66 Percent Carbon.85.8715 Percent Hydrogen: 14.0893 Bromine Number(Cale):0.4324 Page 5of20 Created with novaPDF Printer(www.novaPDF.com). Please register to remove this message. Detailed Hydrocarbon Analysis Detail Report- Report Date:6/18/2009 11:38:35 AM RawFile:C:\Chem32\1\DATAITLIIDHA-061709-8528-02.D\DHA-061709-8528-02.CDF Acquired 06/17/09 11:15:44 Sample:Condensate-001 Analyzed:6/18/2009 11:31:41 AM Processed 233 Peaks Reference File:C:\Chem32\11DHARef\PONA-VI.DHA Normalized to 63.2300% Comments: Molecular Weight and Relative Density Data Group Avg Mw. Avg Rel. Density Cl 0.000 0.000 C2 0.000 0.000 C3 44.097 0.501 C4 58.124 0.575 C5 72.151 0.624 C6 85.075 0.697 C7 97.871 0.741 C8 111.527 0.755 C9 126.460 0.753 010 140.135 0.766 011 154.203 0.781 C12 167.767 0.790 C13 184.318 0.757 Total Sample: 118.00 0.74 Octane Number Research Octane Number: 62.20 (Calculated from Individual Component Values) Contribution to Total by: Paraffins: 12.90 'so-Paraffins: 18.20 Aromatics: 17.50 Napthenes: 12.50 Olefins: 0.82 Oxygenates: 0.40 Page 6 of 20 Created with novaPDF Printer(www.novaPDF.com). Please register to remove this message. Detailed Hydrocarbon Analysis Detail Report - Report Date.6/18/2009 11:38:35 AM RawFile:C:1Chem32111DATAITUIDHA-061709-8528-02.D1DHA-061709-8528-02.CDF Acquired:06/17/09 11:15:44 Sample:Condensate-001 Analyzed:6/18/2009 11:31:41 AM Processed 233 Peaks Reference File:C:1Chem32111DHARef1PONA-VI.DHA Comments: Normalized to 63.2300% Totals by Group Type & Carbon Number(in Mass Percent) Paraffins I-Paraffins Olefins Napthenes Aromatics Total Cl 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 C2 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 C3 0.03541 0.00000 0.00000 0.00000 0.00000 0.03541 C4 0.34550 0.06608 0.00000 0.00000 0.00000 0.41158 C5 1.07932 0.65402 0.00000 0.00000 0.00000 1.73334 C6 1.98812 1.87623 0.00000 1.80740 0.33487 6.00662 C7 2.58211 2.36062 0.16795 3.97004 2.06811 11.14883 C8 2.58079 2.91737 0.00000 2.24663 2.85199 10.59679 C9 2.10419 2.21533 0.25022 1.56046 1.10238 7.23258 C10 1.80340 3.72118 0.04782 0.28619 1.76131 7.61991 C11 1.62794 0.98366 0.05522 0.39113 0.82801 3.88597 C12 1.41356 0.27707 0.06493 0.08611 0.76687 2.60855 C13 1.18855 0.12768 0.03447 0.00000 0.00000 1.35069 Total: 16.74889 15.19925 0.62061 10.34797 9.71355 52.63026 Oxygenates 0.25034 Total C14+: 6.99378 Total Unknowns: 3.35562 Grand Total: 63.23000 Totals by Group Type & Carbon Number(in Volume Percent) Paraffins I-Paraffins Olefins Naothenes Aromatics Total c 1 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 C2 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 C3 0.05253 0.00000 0.00000 0.00000 0.00000 0.05253 C4 0.44320 0.08805 0.00000 0.00000 0.00000 0.53125 C5 1.27972 0.78372 0.00000 0.00000 0.00000 2.06343 C6 2.23857 2.11695 0.00000 1.75609 0.28289 6.39451 C7 2.80406 2.56525 0.17211 3.85725 1.77106 11.16972 C8 2.72763 3.07417 0.00000 2.16750 2.45148 10.42077 C9 2.17711 2.26289 0.25817 1.49502 0.93868 7.13187 C10 1.83420 3.75228 0.04798 0.26438 1.48350 7.38235 C11 1.62459 0.98188 0.05464 0.36300 0.66984 3.69395 C12 1.39379 0.27320 0.06357 0.07992 0.63984 2.45031 C13 1.16666 0.12539 0.03342 0.00000 0.00000 1.32547 Total: 17.74205 16.02378 0.62989 9.98316 8.23728 52.61617 Oxygenates 0.24726 Total C14+: 6.80737 Total Unknowns: 3.55920 Grand Total: 63.23000 Page 7of20 Created with novaPDF Printer(www.novaPDF.com). Please register to remove this message. Detailed Hydrocarbon Analysis Detail Report- Report Date:6/18/2009 11:38:35 AM RawFile:C:1Chem32111DATA1TLl.DHA-061709-8528-02.DlDHA-061709-8528-02.CDF Acquired:06117/09 11:15:44 Sample:Condensate-001 Analyzed:6/18/2009 11:31:41 AM Processed 233 Peaks Reference File:C:1Chem32111DHARef1PONA-VI.DHA Comments: Normalized to 63.2300% Totals by Group Type & Carbon Number(in Mol Percent) Paraffins I-Paraffins Olefins Napthenes Aromatics Total c 1 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 C2 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 C3 0.09532 0.00000 0.00000 0.00000 0.00000 0.09532 C4 0.70567 0.13497 0.00000 0.00000 0.00000 0.84064 C5 1.77589 1.07612 0.00000 0.00000 0.00000 2.85200 C6 2.73877 2.58463 0.00000 2.54946 0.50893 8.38179 C7 3.05910 2.79670 0.20306 4.80000 2.66453 13.52339 C8 2.68210 3.03189 0.00000 2.37677 3.18907 11.27982 C9 1.94762 2.05050 0.23531 1.46742 1.08882 6.78967 C10 1.50466 3.10476 0.04047 0.24221 1.56313 6.45524 C11 1.23638 0.74774 0.04249 0.30095 0.66414 2.99169 C12 0.98516 0.19315 0.04580 0.06074 0.56103 1.84587 C13 0.76531 0.08221 0.02244 0.00000 0.00000 0.86996 Total. 17,49599 15.80265 0.58956 11.79754 10.23964 55.92538 Oxygenates 0.29085 Total C14+. 4.18505 Total Unknowns: 2.82871 Grand Total: 63.23000 Page 8 of 20 Created with novaPDF Printer(www.novaPDF.com). Please register to remove this message. Detailed Hydrocarbon Analysis Detail Report- Report Date:6/18/2009 11.38:35 AM RawFile:C:\Chem32\1\DATA\TLI\DHA-061709-8528-02.DtDHA-061709-8528-02.CDF Acquired:06/17/09 11:15:44 Sample:Condensate-001 Analyzed:6/18/2009 11:31:41 AM Processed 233 Peaks Reference File:C:\Chem32111DHARef\PONA-VI.DHA Comments: Normalized to 63.2300% NOTE:Components with a Weight%of Less Than 0.01 Not Reported. Components Listed in Chromatographic Order Page: 5 Minutes Index Group Component Mass % Volume % Mol % 1.954 300.000 P3 propane 0.035 0.053 0.095 2.072 361.400 14 i-butane 0.066 0.088 0.135 2.173 402.940 P4 n-butane 0.346 0.443 0.706 2.543 470.400 15 i-pentane 0.654 0.784 1.076 2.744 497.740 P5 n-pentane 1.079 1.280 1.776 3.540 564.380 16 2,3-dimethylbutane 0.270 0.303 0.372 3.609 568.900 16 2-methylpentane 0.977 1.110 1.345 3.848 583.320 16 3-methylpentane 0.629 0.703 0.867 4.157 600.000 P6 n-hexane 1.988 2.239 2.739 4.645 622.730 17 2,2-dimethylpentane 0.064 0.071 0.076 4.729 626.290 N6 methylcyclopentane 0.849 0.842 1.198 4.787 628.720 17 2,4-dimethylpentane 0.152 0.167 0.180 5.364 650.540 A6 benzene 0.335 0.283 0.509 5.453 653.600 O7 2-methyl-c-hexene-3 0.036 0.039 0.044 5.599 658.500 N6 cyclohexane 0.958 0.914 1.352 5.841 666.260 17 2-methylhexane 0.937 1.025 1.110 5.893 667.890 17 2,3-dimethylpentane 0.254 0.272 0.301 5.993 670.920 X6 t-amylmethylether 0.250 0.247 0.291 6.130 674,990 17 3-methylhexane 0.953 1.030 1.129 6.348 681.210 N7 1c,3-dimethylcyclopentane 0.261 0.260 0.316 6.449 684.000 N7 lt,3-dimethylcyclopentane 0.307 0.305 0.372 6.551 686.760 N7 1t,2-dimethylcyclopentane 0.381 0.377 0.461 7.069 700.000 P7 n-heptane 2.582 2.804 3.059 7.971 722.710 N7 methylcyclohexane 2.789 2.691 3.372 8.002 723.440 _ unknown 0.041 0.043 0.049 8.048 724.490 18 2,2-dimethylhexane 0.162 0.173 0.169 8.487 734.340 N7 ethylcyclopentane 0.231 0.224 0.279 8.590 736.560 18 2,4-dimethylhexane 0.200 0.213 0.208 8,881 742,650 — unknown 0.170 0.180 0.177 8.935 743.750 N8 1c,2t,4-trimethylcyclopentane 0.046 0.045 0.049 9.254 750.110 O7 O37 0.132 0.134 0,159 9.754 759.580 A7 toluene 2.068 1.771 2.665 9.973 763.560 18 2,3-dimethylhexane 0.129 0.134 0.134 10.017 764.340 18 2-methyl-3-ethylpentane 0.075 0.078 0.078 10.338 769.960 18 2-methylheptane 1.089 1.158 1.132 10.403 771.050 18 4-methylheptane 0.325 0.343 0.338 10.476 772.300 18 3,4-dimethylhexane 0.056 0.058 0.059 10.762 777.050 N8 1c,2c,4-trimethylcyclopentane 0.796 0.776 0.843 Page 9 of 20 Created with novaPDF Printer(www.novaPDF.com). Please register to remove this message. Detailed Hydrocarbon Analysis Detail Report- Report Date:6/18/2009 11:38:35 AM RawFile:C:\Chem3211\DATAITLIIDHA-O61709-8528-02.D\DHA-061709-8528-02.CDF Acquired:06/17/09 11:15:44 Sample:Condensate-001 Analyzed:6/18/2009 11:31:41 AM Processed 233 Peaks Reference File:C:\Chem32\11DHARef1PONA-VI,DHA Comments: Normalized to 63.2300% NOTE:Components with a Weight%of Less Than 0.01 Not Reported. Components Listed in Chromatographic Order Page: 6 Minutes Index Group Component Mass % Volume % Mol % 10.813 777.880 18 3-methylheptane 0.050 0.052 0.052 10.842 778.360 18 3-ethylhexane 0.830 0.864 0.863 10.928 779.750 N8 1 t,4-dimethylcyclohexane 0.359 0.349 0.379 11.197 784.020 N8 1,1-dimethylcyclohexane 0.142 0.135 0.151 11.385 786.930 19 2,2,5-trimethylhexane 0.035 0.036 0.032 11.576 789.830 N8 3t-ethylmethylcyclopentane 0.052 0.050 0.055 11.859 794.030 N8 1t,2-dimethylcyclohexane 0.325 0.311 0.343 12.274 800.000 P8 n-octane 2.581 2.728 2.682 13.339 819.050 19 2,3,4-trimethylhexane 0.086 0.086 0.079 13.617 823.750 O9 O52 0.250 0.258 0.235 14.025 830.450 __ unknown 0.798 0.846 0.750 14.060 831.020 19 2.2,3-trimethylhexane 0.177 0.184 0.164 14.350 835.630 N8 N4 0.236 0.225 0.250 14.505 838.050 I9 3.3-&3.5-dimethylheptane 0.337 0.345 0.312 14.604 839.590 19 2.6-dimethylheptane 0.069 0.073 0.064 15.360 850.940 N8 N7 0.291 0.277 0.308 15.439 852.090 A8 ethylbenzene 0.155 0.133 0.173 16.147 862.110 A8 1,3-dimethylbenzene 2.181 1.874 2.439 16.212 863.010 /1/48 1,4-dimethylbenzene 0.516 0.445 0.577 16.276 863.880 19 2,3-dimethylheptane 0.036 0.037 0.034 16.425 865.920 19 3,4-dimethylheptane 0.101 0.103 0.094 16.714 869.790 19 3,4-dimethylheptane 0.387 0.393 0,358 16.809 871.060 19 15 0.468 0.476 0.433 17.171 875.790 _ unknown 0.111 0.118 0.103 17.295 877.390 19 3-ethylheptane 0.518 0.530 0.480 17.623 881.540 N9 1c,2t,4c-trimethylcyclohexane 0.037 0.036 0.035 17.738 882.980 Ng 1c,2t,3c-trimethylcyclohexane 0.580 0.568 0.545 17.976 885.930 N9 N18 0.040 0.038 0.037 18.093 887.360 N9 N19 0.344 0.328 0.324 18.222 888.930 N9 N20 0.211 0.201 0.199 18.812 895.950 N9 N22 0.044 0.042 0.041 19.162 900.000 pg n-nonane 2.104 2.177 1.948 19.231 901.690 N9 1,1-methylethylcyclohexane 0.180 0.166 0.170 19.408 906.010 N9 N25 0.070 0.066 0.066 19.705 913.170 A9 i-propylbenzene 0.050 0.043 0.049 19.806 915.580 110 111 0.134 0.136 0.111 19.911 918.060 _ unknown 0.065 0.069 0.054 19.986 919.830 110 112 0.036 0.037 0.030 Page 10 of 20 Created with novaPDF Printer(www.novaPDF.com). Please register to remove this message. Detailed Hydrocarbon Analysis Detail Report - Report Date:6/18/2009 11:38:35 AM PawFile:C:\Chem32111DATA\TLI\DHA-061709-8528-02.D1DHA-061709-8528-02.CDF Acquired:06/17/09 11:15:44 Sample.Condensate-001 Analyzed:6/18/2009 11:31:41 AM Processed 233 Peaks Reference File:C:\Chem32\11DHARef\PONA-VI.DHA Comments: Normalized to 63.2300% NOTE:Components with a Weight%of Less Than 0.01 Not Reported. Components Listed in Chromatographic Order Page: 7 Minutes Index Group p Component Mass % Volume % Mol % 20.114 922.840 110 2,4-dimethyloctane 0.194 0.198 0.162 20.208 925.020 110 2,2-dimethyloctane 0.039 0.039 0.032 20.489 931.510 110 2,5-dimethyloctane 0.524 0.533 0.437 20.680 935.870 __ unknown 0.100 0.106 0.083 20.733 937.070 N9 n-butylcyclopentane 0.054 0.051 0.050 20.927 941.440 110 3,3-dimethyloctane 0.333 0.335 0.278 21.193 947.340 110 3,6-dimethyloctane 0.117 0.118 0.098 21.250 948.600 -- unknown 0.083 0.088 0.070 21.571 955.610 A9 1,4-methylethylbenzene 0.384 0.331 0.379 21.649 957.310 _ unknown 0.145 0.154 0.144 21.747 959.410 N10 N33 0.049 0.045 0.041 21.819 960.950 -- unknown 0.035 0.037 0.029 21.854 961.700 A9 1,3,5-trimethylbenzene 0.148 0.127 0.146 21.926 963.240 110 115 0.460 0.462 0.384 22.031 965.480 110 116 0.037 0.037 0.031 22.092 966.770 110 5-methylnonane 0.127 0.129 0.106 22.178 968.590 110 4-methylnonane 0.316 0.317 0.264 22.291 970.940 A9 1,2-methylethylbenzene 0.384 0.323 0.379 22.409 973.410 110 3-ethyloctane 0.051 0.051 0.043 22.509 975.480 N10 N35 0.049 0.046 0.042 22.559 976.520 110 3-methylnonane 0.275 0.278 0.229 22.634 978.070 N10 N36 0.037 0.034 0.031 22.848 982.450 A9 1,2,4-trimethylbenzene 0.034 0.029 0.034 22.974 985.010 110 120 0.893 0.896 0.745 23.060 986.750 110 121 0.185 0.186 0.154 23.393 993.420 O10 2,3-dimethyloctene-2 0.048 0.048 0.040 23.461 994.760 N10 1t-methyl-2-n-propylcyclohexane0.075 0.069 0.063 23.726 1000.000 P10 n-decane 1.803 1.834 1.505 23.994 1008.730 A9 1,2,3-trimethylbenzene 0.102 0.085 0.101 24.053 1010.630 A10 1,3-methyl-i-propylbenzene 0.079 0.068 0.070 24.162 1014.140 111 127 0.043 0.043 0.032 24.213 1015.800 i11 128 0.039 0.040 0.030 24.242 1016.720 — unknown 0.046 0.049 0.035 24.434 1022.860 N10 sec-butylcyclohexane 0.077 0.070 0.065 24.487 1024.540 111 130 0.095 0.095 0.072 24.548 1026.470 A10 1,2-methyl-t-propylbenzene 0.307 0.260 0.271 24.710 1031.590 -- unknown 0.067 0.071 0.060 24.748 1032.790 N11 N40 0.252 0.234 0.194 Page 11 of 20 Created with novaPDF Printer(www.novaPDF.com). Please register to remove this message. Detailed Hydrocarbon Analysis Detail Report- Report Date:6/18/200911:38:35 AM RawFile:C\Chem3211tiDATA\TLI\DHA-061709.8528-02.Du HA-061709-8528-02.CDF Acquired:06/17/09 11:15:44 Sample:Condensate-001 Analyzed:6/18/2009 11:31:41 AM Processed 233 Peaks Reference File:C:\Chem32\11DHARef1PONA-VI.DHA Comments: Normalized to 63.2300% NOTE:Components with a Weight%of Less Than 0.01 Not Reported. Components Listed in Chromatographic Order Page: 8 Minutes Index Group Component Mass% Volume % Mol 24.877 1036.830111 132 0.067 0.062 0.052 24.932 1038.530 _ unknown 0.079 0.084 0.061 24.997 1040.550 A10 1.3-diethylbenzene 0.049 0.042 0.044 25.087 1043.340 A10 1,3-methyl-n-propylbenzene 0.271 0.234 0.240 25.213 1047.230 A10 1,4-diethylbenzene 0.079 0.068 0.070 25.247 1048.290 MO 1,3-dimethyl-5-ethylbenzene 0.032 0.027 0.028 25.316 1050.380 A10 n-butylbenzene 0.138 0.119 0.122 25.395 1052.810111 134 0.038 0.039 0.029 25.485 1055.550 N11 N41 0.140 0.129 0.107 25.592 1058.820 111 135 0.034 0.035 0.026 25.669 1061.140 111 136 0.169 0.170 0.129 25.769 1064.130 111 138 0.161 0.161 0.122 25.885 1067.610 A10 1,4,dimethyl-2-ethylbenzene 0.241 0.204 0.213 25.926 1068.850 A10 A3 0.042 0.036 0.037 25.981 1070.500 111 139 0.074 0.074 0.056 26.082 1073.510 111 140 0.171 0.171 0.130 26.173 1076.180 A10 1.2-dimethyl-4-ethylbenzene 0.081 0.069 0.072 26.483 1085.290111 143 0.092 0.093 0.070 26.603 1088.790 __ unknown 0.062 0.066 0.047 26.663 1090.530 O11 undecene-1 0.055 0.055 0.042 26.720 1092.200 MO 1,2-dimethyl-3-ethylbenzene 0.058 0.048 0.051 26.788 1094.170 A11 1,4-methyl-t-butylbenzene 0.070 0.061 0.056 26.863 1096.310 All 1,2-ethyl-i-propylbenzene 0.069 0.058 0.055 26.991 1100.000 P11 n-undecane 1.628 1.625 1.236 27.097 1104.160 A10 1.2,4,5-tetramethylbenzene 0.039 0.033 0.035 27.155 1106.440 All 1,2-methyl-n-butylbenzene 0.053 0.044 0.043 27.258 1110.470 A10 1,2,3,5-tetramethylbenzene 0.037 0.031 0.033 27.287 1111.600 — unknown 0.060 0.063 0.053 27.458 1118.220 _ unknown 0.068 0.072 0.060 27.491 1119.510 A11 1,2-methyl-t-butylbenzene 0.065 0.054 0.052 27.647 1125.510 -- unknown 0.040 0.043 0.032 27.763 1129.970 A10 5-methylindan 0.149 0.125 0.134 27.948 1137.040 All 1,2-ethyl-n-propylbenzene 0.237 0.197 0.190 28.039 1140.460 All 1,3-methyl-n-butylbenzene 0.032 0.026 0.025 28.155 1144.840 A11 s-pentylbenzene 0.050 0.042 0.040 28.348 1152.110 N12 lt-M-2-(4-MP)cyclopentane 0.086 0.080 0.061 28.401 1154.100 A12 1,2-di-i-propylbenzene 0.042 0.035 0.031 28.468 1156.590 _ unknown 0.107 0.114 0.078 Page 12 of 20 Created with novaPDF Printer(www.novaPDF.com). Please register to remove this message. Detailed Hydrocarbon Analysis Detail Report - Report Date:6/18/2009 11:38:35 AM RawFile:C:1Chem32111DATA\TLIIDHA-061709-8528-02.D\DHA-061709-8526-02.CDF Acquired:06/17/09 11.15.44 Sample:Condensate-001 Analyzed:6/18/2009 11.31.41 AM Processed 233 Peaks Reference File:C:IChem3211\DHARef\PONA-VI.DHA Comments. Normalized to 63.2300% NOTE:Components with a Weight%of Less Than 0.01 Not Reported. Components Listed in Chromatographic Order Page: 9 Minutes Index Group Component Mass`)/0 Volume °/0 Mol % 28.503 1157.880 A12 1,4-di-i-propylbenzene 0.119 0.099 0.087 28.605 1161.690 A10 tetrahydronaphthalene 0.119 0.091 0.107 28.719 1165.910 112 145 0.175 0.173 0.122 28.756 1167.280 A10 naphthalene 0.040 0.029 0.037 28.893 1172.310 Al2 1,4-ethyl-t-butylbenzene 0.174 0.145 0.127 29.137 1181.230 112 147 0.040 0.040 0.028 29.231 1184.640 112 148 0.062 0.061 0.043 29.337 1188.450 Al2 1,3-di-n-propylbenzene 0.117 0.098 0.086 29.460 1192.880 O12 dodecene-1 0.065 0.064 0.046 29.658 1200.000 P12 n-dodecane 1.414 1.394 0.985 29.721 1202.790 _ unknown 0.037 0.040 0.026 29.777 1205.280 - unknown 0.036 0.038 0.025 29.923 1211.780 Al2 1,3,5-triethylbenzene 0.044 0.037 0.032 30.010 1215.610 _ unknown 0.298 0.316 0.218 30.085 1218.920 _ unknown 0.052 0.055 0.038 30.193 1223.650 - unknown 0.051 0.054 0.038 30.313 1228.910 __ unknown 0.034 0.036 0.025 30.352 1230.590 Al2 1,2,4-triethylbenzene 0.047 0.039 0.034 30.634 1242.830 A12 1.4-methyl-n-pentylbenzene 0.128 0.107 0.094 30.674 1244.550 _ unknown 0.049 0.052 0.036 30.887 1253.690 A12 n-hexylbenzene 0.095 0.079 0.070 30.934 1255.720 _ unknown 0.095 0.100 0.069 31.042 1260.330 _ unknown 0.187 0.198 0.137 31.151 1264.970 _ unknown 0.154 0.163 0.112 31.201 1267.070 -_ unknown 0.035 0.037 0.025 31,309 1271.640 113 150 0.128 0.125 0.082 31.406 1275.740 All 1,2,3,4,5-pentamethylbenzene 0.216 0.160 0.173 31.696 1287.890 _ unknown 0.207 0.220 0.166 31,788 1291.680 O13 tridecene-1 0.034 0.033 0.022 31.810 1292.610 -- unknown 0.043 0.045 0.028 31.896 1296.160 All 1-methylnaphthalene 0.036 0.027 0.030 31.988 1300.000 P13 n-tridecane 1.189 1.167 0.765 32.064 1303.680 + C14+ 0.106 0.103 0.064 32.292 1314.800 + C14+ 0.039 0.038 0.024 32.348 1317.520 + C14+ 0.041 0.040 0.025 32.387 1319.410 + C14+ 0.085 0.083 0.051 32.745 1336.630 + C14+ 0.060 0.058 0.036 32.827 1340.540 + C14+ 0.055 0.054 0.033 Page 13 of 20 Created with novaPDF Printer(www.novaPDF.com). Please register to remove this message. Detailed Hydrocarbon Analysis Detail Report- Report Date:6/18/200911:38:35 AM RawFile:C:\Chem32\11DATA\TLI\DHA-061709-8528-02.D1DHA-061709-8528-02.CDF Acquired:06/17/09 11:15:44 Sample:Condensate-001 Analyzed:6/18/2009 11:31:41 AM Processed 233 Peaks Reference File:C:\Chem32111DHARef\PONA-VI.DHA Comments: Normalized to 63.2300% NOTE:Components with a Weight%of Less Than 0.01 Not Reported. Components Listed in Chromatographic Order Page: 10 Minutes Index Group Component Mass% Volume % Mol % 32.987 1348.170 + C14+ 0.158 0.154 0.094 33.058 1351.500 + C14+ 0.091 0.088 0.054 33.119 1354.400 + C14+ 0.063 0.061 0.038 33.225 1359.410 + C14+ 0.099 0.096 0.059 33.331 1364.410 + C14+ 0.121 0.118 0.072 33.479 1371.340 + C14+ 0.118 0.115 0.071 33.542 1374.250 + C14+ 0.036 0.035 0.021 33.655 1379.510 + C14+ 0.220 0.214 0.132 34.098 1400.000 + C14+ 0.954 0.929 0.571 34.166 1400.000 + C14+ 0.041 0.040 0.024 34.184 1400.000 + C14+ 0.053 0.051 0.032 34.286 1400.000 + C14+ 0.062 0.061 0.037 34.437 1400.000 + C14+ 0.099 0.097 0.059 34.517 1400.000 + C14+ 0.073 0.071 0.044 34.844 1400.000 + C14+ 0.047 0.045 0.028 35.125 1400.000 + C14+ 0.137 0.133 0.082 35.234 1400.000 + C14+ 0.057 0.055 0,034 35.357 1400.000 + C14+ 0.319 0.311 0.191 35.480 1400.000 + C14+ 0.071 0.069 0.042 35.624 1400.000 + C14+ 0.049 0.048 0.030 35.718 1400.000 + C14+ 0.044 0.043 0.026 36.050 1400.000 + C14+ 0.906 0.881 0.542 36.130 1400.000 + C14+ 0.038 0.037 0.023 36.223 1400.000 + C14+ 0.044 0.043 0.026 36.314 1400.000 + C14+ 0.052 0.051 0.031 36.559 1400.000 + C14+ 0.034 0.034 0.021 36.669 1400.000 + C14+ 0.047 0.045 0.028 36.896 1400.000 + C14+ 0.044 0.043 0.027 37.076 1400.000 + C14+ 0.048 0.047 0.029 37.109 1400.000 + C14+ 0.094 0.092 0.056 37.203 1400.000 + C14+ 0.091 0.089 0.055 37.296 1400.000 + C14+ 0.062 0.061 0.037 37.344 1400.000 + C14+ 0.063 0.061 0.038 37.590 1400.000 + C14+ 0.039 0.038 0.023 37.734 1400.000 + C14+ 0.041 0.040 0.025 37.876 1400.000 + C14+ 0.756 0.736 0.453 38.657 1400.000 + C14+ 0.067 0.065 0.040 38.770 1400.000 + C14+ 0.209 0.204 0.125 Page 14 of 20 Created with novaPDF Printer(www.novaPDF.carli). Please register to remove this message. Detailed Hydrocarbon Analysis Detail Report- Report Date:6/18/2009 11:38:35 AM RawFile:C:\Chem32\1\DATA\TLI\DHA-061709-8528-02.01DHA-061709-8528-02.CDF Acquired:06/17/09 11.15:44 Sample:Condensate-001 Analyzed:6/18/2009 11:31:41 AM Processed 233 Peaks Reference File:C:\Chem32111DHARef1PONA-VI.DHA Comments: Normalized to 63.2300% NOTE:Components with a Weight%of Less Than 0.01 Not Reported. Components Listed in Chromatographic Order Page: 11 Minutes Index Group Component Mass% Volume% Mol % 38.880 1400.000 + C14+ 0.046 0.045 0.028 38.975 1400.000 + C14+ 0.084 0.082 0.050 39.121 1400.000 + C14+ 0.051 0.049 0.030 39.671 1400.000 + C14+ 0.645 0.628 0.386 39.851 1400.000 + C14+ 0.232 0.226 0.139 Page 15 of 20 Created with novaPDF Printer(www.novaPDF.com). Please register to remove this message. OZ to g l abed - C-� Cam. auelday•u ; Z690'L= • L _ G� • au exay•u S9SL DF_ --• :F i ro ,� ri m auedoJd 8£5651 -.� 0 • I 4' .a 1 rt U r L+ . Ia r F ieu&s 00LL0 a6ed r aueuou•u': Ll9l'6tE_____ _______ r. G., C"-------2. Lam,LA 9 C" IN ''r$ I .P IM auel3o•u : £OLZ•Z1E�:4____________ co C., • LA 4.11 dt a. i4 O _, C A : I- cD n• . = C fV V ,1 [J C— ..____.----"' �� V W V • f' O O N O> 2 4 O - V, 0.' F 1 ft t' ,C V Q O 6 . N rpm �} N of `T L} l0 .O 1(1 11] tl �[ .=.f •t .[ !'5 iii t' 1'1 M R N N M2 2 V cr) IeubS OZ109l.e6ed auepapop-u S9S9 6Z..s.._._ -- __ _ I 4- y., aue3apun-u 1166'9Zf___o..= _ e; t .n ' Iv •J aueap-u • S9Z1 LZr- •t� it C) [Z tftiit CII i =MI 7, d .J 'Cr 4 4! N F L 411 `I [��C.(...) ..1 v �.. [3 O .ii .0 — el y r f. w n .r -r r a r� „ n, r4 ry ry ieu6is OZ 1O6 I.e68d •PLO L019. 4413 : LOZ," +•a Ilt`o6s «t +9t3 • 49L9'1r _� •ti�� 'b 1'• £c 44O : b065' £� #t fit: a4&3 • 13 9S68' +9l 3 : 1999'9, 4913 ' 9BSS' c +7` +PIO 66P0 8 C +4i 3 «143 $61.t- 6 9= +915 : 69S£'SS..r_ •Via . £5Z,'SS +9l o 9498' c b2 4 'e +91O C860' '' 8Z -.c iqL H7 QI L C, aueoapi,I•u 5886 LJ Ln un •.i C71 Q ti A 4 4- c4) . E • w+ . C. C o 'N aueDapop•u : S8S9'67c C. E --� 4 f- eu6g - _ Technology Laboratory Inc. Centre Professional Office Park 1012 Centre Avenue Fort Collins,CO 80526 970-490-1414 inf oOtecnlaousa.c:om Compositional Analysis of Liquid(Atmospheric Pressure) CGRS Date Sampled: 06/15/09 PO Box 1489 Date Received: 06/15/09 Fort Collins,CO Date Analyzed: 06/16/09 Sample ID: Condensate-001 1-8019-10695aa Lab ID: 8528-02 Molecular Specific Component Mole% Volume% Weight 04 Weight Gravity C 1 0.00 0.00 0.00 16.04 0.300 C 2 0.00 0.00 0.00 30.07 0.356 C 3 0.00 0.00 0.00 44.10 0.507 C 4 0.00 0.00 0.00 58.12 0.563 C 4 0.00 0.00 0.00 58.12 0.584 C 5 0.00 0.00 0.00 72.15 0.624 C 5 1.66 0.99 0.79 72.15 0.631 C 6 10.02 6.77 5.70 86.18 0.664 C 7 18.62 13.68 12.31 95.88 0.709 C 8 15.00 12.04 11.30 107.35 0.740 C 9 14.92 12.67 12.62 116.95 0.785 C 10 6.81 6.46 6.39 134.00 0.779 C 11 5.33 5.48 5.49 147.00 0.790 C 12 4.23 4.68 4.75 161.00 0.801 C 13 3.17 3.74 3.86 175.00 0.812 C 14 3.19 4.00 4.17 190.00 0.823 C 15 2.19 2.90 3.06 206.00 0.833 C 16 1.95 2.73 2.91 222.00 0.840 C 17 1.47 2.16 2.32 237.00 0.848 C 18 1.07 1.66 1.80 251.00 0.853 C 19 1.31 2.13 2.32 263.00 0.858 C 20 0.99 1.69 1.85 275.00 0.863 C 21 1.24 2.21 2.43 291.00 0.868 C 22 0.90 1.67 1.85 305.00 0.873 C 23 0.86 1.66 1.85 318.00 0.878 C 24 0.71 1.42 1.58 331.00 0.882 C 25 0.68 1,41 1.58 345.00 0.886 C 26 0.66 1.40 1.58 359.00 0.890 C 27 0.63 1.40 1.58 374.00 0.894 C 28 0.34 0.79 0.90 388.00 0.897 C 29 0.33 0.79 0.90 402.00 0.900 C 30 plus 1.71 3.50 4.08 478.00 0.917 Total 100.00 100.00 100.00 147.16 0.794 Average Specific Gravity Page 20 of 20 3ZA1VNV 1.NO0'01OH - m SISAIVNV 8314V al0H 5 _ O Cr CC O 711•1- C z LU � 004 o w r ■■■■ ■■�■■ e . dl\ I Jill< . cc I,-t.'^• Z/d x 2 o S03d m v i1 z PH3''Oo`rO¢N)S3SVO 03X1] z ry oo m /L.VJ nto > o , W VI /31JWJN/311MUN • a a w a n n E 0 0 u U, HdAllSlOl/11OLl1-Ol W M 00 ¢ Iv U lit cc iJU'tiled d/'L03/'aiiu6i 1-Maa �a I i _ (o3Alossla/env iviop SWUM 8 Vtlal CO O J SSt/Hd `- , Z HVd/OM/sz9 OOAS o z Q 0 -9 — dl3l/1V1Ol 09Z8/PZ93OA C7 w w Q a 2 e i 6991/ 4'£lb asealO V IIO 7 O }- c I - t'Bl6 Hdtll ■ ■ v• U 91' (OMO)Hd31 1 1 l' Sa3NIV1NO3 JO tl38wfN in N3H10 (M)sno3nov -� @ 3 (v)um (Sl 110$ xlalvf 31dfVS 0 - 3Q N 00 E CI -Ien 4.-/W O p u F- ili ZU .. � �� < [il v al. V. m> m CGz (n O 0 tD M� f-- .� ',r •-• < O z z �+ w o `� E d O w cn ' �' > 8 z z c.) uo F O y 0 z a 0 O r� F. rn p o [colic 7p HLr a V a y Z > 7 1 Q Q • N 70 m m x o `1 w 2 T d ... o aJ �) I' o f o E �� y O' a - � �� 0 0 0 U) x x Q v �� -y Qcc N 7 • - V ra 1- ,E ea vo a ¢ a o < g —2 4t I u c E a .4. (n �,no0 TECHNOLOGY LABORATORY, INC. CENTRE PROFESSIONAL OFFICE PARK / 1012 Centre Avenue Fort Collins, Colorado 80526 (970) 490-1414 CGRS Sampled: 06/15/09 PO Box 1489 Received: 06/15/09 Fort Collins, CO 80522 Analyzed: 06/24/09 Sample ID: Condensate-001 Project #: 1-8019-10695aa Laboratory ID: 8528-02 Matrix: Oil This oil sample was received in good condition and was sent to Questar Energy Services on June 23, 2009 for Reid Vapor Pressure Analysis. The results contained in this report relate only to those items tested. QN11 TECHNOLOGY 1A80RA RY,INC. Page 1 of 2 1110 D Street Rock Springs,Wy.82ytt} Ph:307.352-7292 Fax:307-352-7326 Questar Energy Services Applied Technology Services API Gravity Reid Vapor Pressure Producer: Tech Lab Inc Wel Name: Project # 8528-2 Field: N/A County and Snip: N/A Corrected API Gravity: 47.0 @ 60*F RVP: 3.2 #@00*F Date Sampled: 6/15O9 Da teAnalged: 624O9 Sampled By: N/A Analyzed By: Putnam Page 2 of 2 Appendix E Process Description, Process Flow, Facility Location, and Plot Plan Process description The Facility accepts production water from oil and gas exploration and production sites in Colorado and separates residual condensate and oil from the production water through a closed system of manifolded aboveground storage tanks. The refined production water is injected into an on-site class II injection well for disposal. The oil recovered at the facility is transported offsite for further refinement. A simplified process flow diagram is attached. e w cy , m [(to _ II! . . , Af ,, , ■ d ° A p il 7 , , \ § o 2 g c . . . . . . . _------ o §lit ! i s O [ E I e I . u | O �! | /_ § i I \� | | ,;- O ■ - - -r P, • | \, _ ' ! O . QI i i , '4'. -1cc G § | Q aA . g | O i �r ' k 3_I ) i /k' us §$ | I hZ t m o ! , « § a e § � j43 R d 0 o 99 | � o H i t| ! , 1 � ` 'a,—II } - - - - | w a i 0.|■!! | 1 O ' d_0,, ® ' , k j /` I ` `i`�� | i ' §H ; . . � ii!0 , . ! O r ( E | k � ; |`I|| R/ fl .0^..':.'44 . • ■ | | lig,...;!jU _ , b■| y , ( o ! , // I ! ' e g | o ! I1kJli I $ ; | § � | P. .O 0 } , . . . . ! |J ____ _.__ ALDRIDGE TRANSPORTATION CONSULTANTS, LLC Advanced"Transportation Planning and Traffic Engineering John M.W.Aldridge,PE,PTOE,AICP 1082 Chimney Rock Road Colorado Registered Professional Engineer Highlands Ranch,CO 80126 Professional Traffic Operations Engineer Tele:303-703-9112 American Institute of Certified Planners Fax:303-703-9152 Mobile:303-594-4132 Email:iohn(aiatceng.com July 14, 2014 Nick Valencia Project Manager M3 Construction, LLC 2861 W. 120th Ave. Suite 250 Westminster, CO 80234 RE: Traffic Study High Sierra Water Services C9 Saltwater Disposal Facility Dear Nick: This technical letter provides a traffic study of the potential impact occasioned by the development of a water disposal site on the east side of WCR-95 approximately one- quarter mile feet south of WCR-118 in the area of Grover, Colorado. The aerial photo shows the location. .. In this area, WCR-95 is a 611 two-lane gravel roadway that carries minimal traffic in the range of 0- i 200 vehicle per day according to the Weld County 2035 Transportation Plan. It is 26 feet wide and in good condition per the plan. The plan does not provide . any forecast volumes for , , this roadway. The water disposal facility will employ five persons per 24 hour period. It expects to serve approximately a maximum of 250 trucks per day spread out over a 24-hour period. The average will be less than 200 trucks per day. Although the average number of trucks IFITA ALDRIDGE TRANSPORTATION CONSULTANTS, LLC Page 2 of 2 will likely exceed the plan's daily capacity of 200 vpol, the peak hour capacity with approximately 10-20 trucks per hour would not be exceeded by any means. The access to WCR-95 will doubtless operate at LOS A. According to the plan, this is an untreated gravel road and not subject to fugitive dust abatement. The County will however replenish the gravel surface as needed. Based on this analysis, the present roadway surface and traffic control will adequately handle, without improvements, the additional truck traffic generated by the water disposal facility. Should you have any questions or need additional information please call me at 303-703- 9112. Respectfully s .• ii fitted: Aldridge T ans ortation Consultants, LLC John M.W. Aldrid( e, PE,PTOE, AICP Principal JMWA/me 1 This is a planning-level traffic capacity.Actual capacity is determined from a peak-hour analysis prescribed in the HCM 2010. CLOSURE PLAN NGL WATER SOLUTIONS DJ LLC, C 9 FACILITY TO: Weld County Dept. of Public Health and Environment Colorado Oil &Gas Conservation Commission FROM: NGL Water Solutions DJ, LLC RE: DETAILED CLOSURE PLAN—C9 Salt Water Disposal Facility DATE: November 21, 2014 Regarding our USR Application, we are providing the following detailed closure plan for our C1 facility located near Greeley, Colorado.This includes the plugging and abandonment of the well.There are several companies in the area that would plug and abandon the well in exchange for salvage rights to the casing and tubing.The well would be plugged according to specifications as set forth by the COGCC. This would take care of the well head and all the subsurface equipment related to the well bore. The following is a list of facility equipment that would need to be removed upon facility closure: Item Description Quantity Method of Disposal Offload Pumps 6 Pumps will be cleaned, parts will be sold Sump Pumps 3 or reused at other NGL facilities and Oil Transfer Pump 1 remaining housings and skids will be Filter Pump 1 scrapped. Charge Pumps 3 Injection Pump 3 DeSander Tank 2 Brine water and tank bottoms will be System Tanks 10 disposed of,tanks will be emptied and Clean Tanks 2 steam cleaned by confined space crews Oil Tanks 6 and the clean tanks will be reused or scrapped. Pump House Building 1 Building will be demolished, materials will be separated and recycled/reused or scrapped. All the above mentioned items are salvageable and could easily be sold as used equipment. After removal of buildings and equipment, all concrete will be removed from location. There will be approximately 3 weeks of concrete removal and grade work. The entire sire will be remediated back to its original state and seeded with grasses matching the grasses of neighboring sites. FACILITY EMERGENCY PLAN NGL WATER SOLUTIONS Di, LLC C9 SWD FACILITY Project Name: NGL 9 Facility Project Address: 57736 CR 95, Grover CO 80729 Emergency Telephone Numbers: Phone Number Facility Primary: Dan Garcia, Operations Manager (970) 397-9156 Facility Secondary: Josh Hamblen, Operations Manager (970) 218-1739 Fire District Pawnee Fire Department (970) 895-2237 319 Chatoga Ave, Grover, CO, 80729 Nearest Hospital Cheyenne Va (307)-778-7300 2360 E. Pershing Blvd, Cheyenne, WY, 82001 Other CDPHE Spill Line (877) 518-5608 National Response Center (800) 424-8802 CHEMTREC (Chemical Transportation Emergency Center) (800) 424-9300 Agency Notification Non -Emergency: Phone# Law Enforcement Agency: Ault Town Police 970-834-2852 Communication Center 970-350-9600 Office of Emergency Management/LEPC 970-304-6540 Surrounding Occupancies& Land Use Surrounding is primarily agricultural. Personal Protective Equipment Available: Location Rubber or neoprene boots: On Site Rubber Gloves: On Site Face Shield or similar protection: On Site Location of Emergency Equipment &Supplies: Phone# To be completed once site construction begins Location &Types of Water Supplies: Potable water is located inside of the office building in the bathroom and drinking fountain Transportation routes: Various chemicals/products will be delivered via routes through Greeley Coordination with First Responder Agencies: EHS representative and/or first responders will meet the day the Certificate of Occupation is presented to review emergency plan and tour facility. Please see Waste Handling Plan for chemicals kept on site. Safety and Training Review: Each year, all employees are provided with all necessary information concerning the proper handling of a chemical spill or accident. This information shall be in the form of a review sheet detailing proper procedures, which shall be signed and dated by each employee when all items are understood. Also, proper use of cleanup and containment tools and procedures will be demonstrated as necessary. Any new or updated information or procedures will be taught to employees immediately when applicable. c::::( ENVIRONMENTAL MWMW July 22,2014 Mr.Nick Valencia M3 Construction 2861 W. 120th Avenue, Suite 250 Westminster,Colorado 80234 Subject: Spill Prevention Control and Countermeasure(SPCC)Plan High Sierra Water Services,LLC C9 Facility WCR 30 and WCR 49 W %z NW/4,Section 13,T1ON,R61W Grover, Colorado CGRS Project: 1-12462-14629aa Dear Mr. Valencia: Please find the enclosed DRAFT SPCC Plan that CGRS, Inc. (CGRS), prepared for the above referenced High Sierra Water Services, LLC (High Sierra) C9 facility in Grover, Colorado. This plan has not been certified by a P.E. but its purpose is to provide you with the needed documentation to present to the appropriate personnel during the public hearing. Once the C9 site is constructed, CGRS will perform a formal SPCC inspection based on the site's layout and current equipment on site. The final plan will be certified by a P.E. CGRS, Inc., appreciates the opportunity to provide professional environmental services to High Sierra. If you have any questions,please call me at(800)288-2657. Sincerely, CGRS,Inc. Kelly Sutton Project Manager/Scientist Enclosures 1301 Academy Court Fort Collins, CO 80524 T 800-288-2657 F 970-493-7986 www.cgrs.com SPILL PREVENTION, CONTROL, AND COUNTERMEASURE PLAN HIGH SIERRA C9 Injection Facility, Weld County, Colorado CGRS Project Number: 1-12462-14629aa Prepared for: M3 Construction, LLC 2681 W 120th Avenue, Suite 250 Westminster, Colorado 80234 Prepared by: CGte'sgre-.1 CGRS, Inc. 1301 Academy Court Fort Collins, Colorado 80524 July 22, 2014 TABLE OF CONTENTS Section Description [SPCC Regulation Cross reference] Page 1.0 PLAN CERTIFICATION 1 1.1 Certifying Engineer Statement[112.3(d)] 1 1.2 Management Approval Statement[112.7] 1 2.0 GENERAL 2 2.1 SPCC Plan Description[112.7(a)(1)] 2 2.2 SPCC Plan Location[112.3(e)] 2 2.3 Amendment and Review Procedures[112.5] 3 2.4 Facilities Not Yet Operational [112.7] 3 2.5 Deviation from Requirements [112.7(a)(2)] 3 2.6 Facility Description[112.7(a)(3)] 3 2.7 Facility Storage [112.7(a)(3)(i)] 4 2.8 Discharge Prevention Measures[112.7(a)(3)(ii)] 5 2.9 Discharge Controls [112.7(a)(3)(iii) 6 2.10 Countermeasures:Discovery/Response/Cleanup [112.7(a)(3)(iv)] 7 2.11 Disposal [112.7(a)(3)(v)] 7 2.12 Notification Phone List[112.7(a)(3)(vi)] 7 2.13 Discharge Notification Form[112.7(a)(4)] 8 2.14 Discharge Procedures [112.7(a)(5)] 9 2.15 Discharge Prediction[112.7(b)] 9 2.16 Secondary Containment for Loading/Unloading Areas Other Than Rack[112.7(c)] 10 2.17 Statement of Impracticability[112.7(d)] 11 3.0 INSPECTIONS,TESTS AND RECORDS 11 3.1 Inspections and Record-Keeping[112.7(e)] 11 4.0 PERSONNEL TRAINING 11 4.1 Personnel Instruction[112.7(f)(1)] 11 4.2 Designated Individual for Spill Prevention[112.7(f)(2)] 11 4.3 Spill Prevention Briefings[112.7(0(3)] 11 5.0 SECURITY[112.7(g)] 12 5.1 Securing and Controlling Access 12 5.2 Securing Master Flow/Drain Valves 12 5.3 Preventing Unauthorized Access to Starter Controls 12 5.4 Securing Loading/Unloading Connections 12 5.5 Security Lighting 12 6.0 TANK TRUCK LOADING AND UNLOADING 12 6.1 Secondary Containment for Loading/Unloading Areas Including Racks[112.7(h)(1)] 12 6.2 Warning Barrier Systems [112.7(h)(2)] 12 6.3 Bottom Drains of Vehicles Examined[112.7(h)(3)] 13 7.0 OTHER GENERAL REQUIREMENTS 13 7.1 Brittle Fracture/Other Failure Evaluation—Field Constructed Aboveground Containers [112.7(i)] 13 7.2 Conformance with Stricter State Rules [112.7(j)] 13 7.3 Oil-filled Operational Equipment[112.7(k)] 13 8.0 FACILITY DRAINAGE 13 8.1 Drainage from Diked Areas [112.8(b)(1)] 13 8.2 Dike Drainage Valves—Manual,Open/Closed Designed[112.8(b)(2)] 13 8.3 Drainage System for Undiked Areas [112.8(b)(3)] 13 8.4 Final Drainage Diversion System[112.8(b)(4)] 14 8.5 Backup Pump for Lift Station and Transfer Systems [112.8(b)(5)] 14 9.0 BULK STORAGE TANKS 14 9.1 Containers Compatible with Materials Stored[112.8(c)(1)] 14 9.2 Secondary Containment[112.8(c)(2)] 14 9.3 Rainwater Drainage Procedure[112.8(c)(3)] 14 9.4 Buried Metal Tanks Corrosion Protection [112.8(c)(4)] 15 9.5 Partially Buried Tanks Protected Against Corrosion[112.8(c)(5)] 15 9.6 Integrity Testing[112.8(c)(6)] 15 9.7 Internal Coils[112.8(c)(7)] 16 9.8 Engineered to Avoid Discharges[112.8(c)(8)] 16 9.9 Plant Effluent Discharges to Navigable Water[112.8(c)(9)] 16 9.10 Oil Leaks Promptly Corrected[112.8(c)(10)] 16 9.11 Mobile or Portable Oil Storage Tanks[112.8(c)(11)] 16 10.0 FACILITY TRANSFER OPERATIONS 17 10.1 General 17 10.2 Buried Pipe Installations [112.8(d)(1)] 17 10.3 Terminal Pipe Connections Capped or Blank Flanged [112.8(d)(2)] 17 10.4 Aboveground Pipe Supports[112.8(d)(3)] 17 10.5 Testing and Inspection of Aboveground Pipes and Valves[112.8(d)(4)] 17 10.6 Warning for Trucks of Pipes [112.8(d)(5)] 18 11.0 SUBSTANTIAL HARM[112.20(e)] 18 FIGURES FIGURE 1: Site Location Map FIGURE 2A: Site Conditions Map FIGURE 2B: Site Conditions Map APPENDICES APPENDIX A: SPCC Review Log APPENDIX B: Aboveground Storage Tank Ullage Log APPENDIX C: DOT Requirements APPENDIX D: Emergency Spill Response Contacts APPENDIX E: Spill Documentation Form APPENDIX F: Inspection and Recording Forms APPENDIX G: SPCC Training Signoff Sheet APPENDIX H: Secondary Containment Volume Calculations APPENDIX I: Self-Determination Criteria SPCC Plan July 22,2014 High Sierra Water Services Page 1 C9 Injection Facility Weld County,Colorado 1.0 PLAN CERTIFICATION 1.1 Certifying Engineer's Statement 1112.3(d)l: The undersigned Registered Professional Engineer is familiar with the requirements of the Code of Federal Regulations,Title 40,Part 112 (40 CFR Part 112), and he or his agent has examined the facilities. The undersigned Registered Professional Engineer attests that this Spill Prevention, Control, and Countermeasure (SPCC) Plan has been prepared in accordance with good engineering practices including applicable industry standards, and in accordance with the requirements of 40 CFR Part 112; that procedures have been established for required inspections and testing; and that the Plan is adequate for the facilities. This certification in no way relieves the owner/operator of the duty to prepare and fully implement this SPCC plan in accordance with the requirements of 40 CFR Part 112. Date: Mr. Randy Kenyon,P.E. Colorado State Registration No: 41216 1.2 Management Approval Statement 1112.71: This SPCC Plan is fully supported by the management of High Sierra Water Services (High Sierra). High Sierra is committed to the prevention of discharges of oil to navigable waters or the environment, and maintains the highest standards for spill prevention, control, and countermeasures through periodic review, updating, and implementation of this Plan. High Sierra will implement this Plan and amend it as needed due to expansions, modifications and improvements at the High Sierra C9 injection facility and will provide the manpower, equipment, and materials required to expeditiously control and remove any quantity of oil discharged that may be harmful. Date: Mr.Josh Patterson Certifying Official High Sierra Water Services SPCC Plan July 22,2014 High Sierra Water Services Page 2 C9 Injection Facility Weld County,Colorado 2.0 GENERAL 2.1 SPCC Plan Description(112.7(a)(111 The following SPCC Plan has been developed as part of a comprehensive plan to minimize the potential for oil discharges at the High Sierra Water Services (High Sierra) C9 injection facility located in the city of Grover, Colorado. The plan is designed to guide personnel in their oil spill prevention activities and satisfy applicable federal requirements outlined in 40 CFR,Part 112,and Colorado Oil and Gas Conservation Commission(COGCC), Rule 906 for facilities that have total aggregate aboveground oil storage capacity greater than 1,320 gallons. 2.2 SPCC Plan Location 1112.3(01 The High Sierra C9 injection facility is manned 24 hours a day and in accordance with 40 CFR 112.3(e), a complete copy of the SPCC Plan is maintained on site for use by oil handling personnel. The High Sierra main office is located approximately 50 miles from the High Sierra C9 injection facility location. The plan is available for inspection by regulatory officials at all times. 2.3 Amendment and Review Procedures 1112.51 The SPCC Plan will be amended as needed by High Sierra whenever there is a change in the facility design, construction, operation,or maintenance,which materially affects the potential to discharge oil into navigable waters or adjoining shorelines. Any technical amendment to this SPCC Plan will be effective only if certified by a Professional Engineer in accordance with 40 CFR, Part 112.3(d). In addition, High Sierra will review and evaluate the current SPCC Plan at least once every five years. As a result of such review,the SPCC Plan will be updated and modified to include more effective prevention and control technology where applicable. All technical plan amendments will be certified by a Professional Engineer and fully implemented within six months of the date of the facility change. All administrative plan amendments will be made by the operator; however, administrative amendments do not require certification by a Professional Engineer. SPCC Plan reviews will be documented on a review log that will be maintained with the SPCC Plan. The following table outlines non-technical verses technical amendments and describes the management review process. The SPCC Plan Review Log form is provided in Appendix A. Non-Technical Amendments L Non-technical amendments are not required to be certified by a professional Engineer. ❑ Examples of non-technical amendments include, but are not limited to,phone numbers,name changes, or any non-technical text change or changes. SPCC Plan July 22,2014 High Sierra Water Services Page 3 C9 Injection Facility Weld County,Colorado Technical Amendments ❑ Technical amendments are certified by a Professional Engineer. ❑ Examples of technical amendments include, but are not limited to, commissioning or decommissioning containers; replacement, reconstruction, or movement of containers; reconstruction, replacement, or installation of piping systems; construction or demolition that may alter secondary containment structures; changes of product or service; or addition or deletion of standard operation or maintenance procedures related to discharge prevention measures. It is the responsibility of the operator to determine, and confirm with the regulatory authority as necessary, what constitutes a technical amendment. The preamble of the rule states that an amendment is required only"when there is a change that materially affects the facility's potential to discharge oil"(67 FR 47091). L An amendment made under this section will be prepared within six (6) months of the change and implemented as soon as possible but no later than six(6)months following preparation of the amendment. 2.4 Facilities Not Yet Operational 1112.71 The High Sierra C9 injection facility described in the SPCC Plan is expected to be fully operational in March 2015. Planned spill prevention improvements and procedures will be completed within six months of the date of the SPCC Plan. 2.5 Deviations from Requirements 1112.7(a)(2)l The High Sierra C9 injection facility does not include any deviations from the SPCC requirements. 2.6 Facility Description 1112.7(a)(3)1 High Sierra owns and operates the High Sierra C9 injection facility; an onshore oilfield water storage and Class II injection facility. Oilfield production water with small amounts of oil is transported to the site by tanker trucks that vary in size. The largest transport has a storage capacity of approximately 9,240 gallons. The production water delivered to the site is offloaded from the tank trucks in the offload bay,which includes a sloped concrete pad with a trenched drain, running to a sump that will collect surface runoff. The sump routes runoff from the concrete offloading pad to the de-sanding tanks where it is pumped back into oil skim tank. The water offloaded from the tanker trucks is pumped directly from the transports into one of two 29,400-gallon de-sanding tanks(T-10-01,T-10- 02) for particulate removal from the production water. The de-sanding tanks remove solids greater than 120 gm. From there the water moves via gravity into the oil separation tanks for initial oil removal from the production water. Any residual oil is skimmed from the tank and recovered. Recovered oil from the skim tank is pumped to the oil storage tanks, which consist of four 16,800-gallon aboveground storage tanks (ASTs), which are identified as AST T-50-01,T-50-02,T-50-03 and T-50-04. After initial separation,the water is transferred to the eight(8)manifolded 35,280-gallon water equalization ASTs (T-30-01 through T-33-02). The majority of the remaining oil within the SPCC Plan July 22,2014 High Sierra Water Services Page 4 C9 Injection Facility Weld County,Colorado production water is recovered during this process, and the recovered oil is transferred to ASTs T-50-01 through T- 50-03, then to the sale oil (16,800 gallons) tank (T-50-04) or to the waste oil tank(16,800 gallons) tank(T-50-05). The water is then transferred to the pump house where it is filtered and transferred to one of two 42,000-gallon(1000 BBL)"clean water"tanks,and subsequently injected into the subsurface injection well. Overall, the facility consists of a concrete offloading pad, pump house/office, one injection well, and a concrete secondary containment dike that stores two 29,400-gallon de-sanding tanks, two 42,000-gallon oil separation tanks, eight 35,280-gallon process system water tanks, four 16,800-gallon recovered crude oil storage tanks, one 16,800- gallon sale oil tank, one 16,800-gallon waste oil tank, and two 42,000-gallon clean water storage tank. All facility ASTs are contained within a secondary containment area. In addition,the facility contains a 10' x 10' by 7.5' deep sump which collects runoff from the offloading area which is manually pumped into the oil separation tank when necessary. The facility is located in the Southeast 1/4 of the Southeast 1/4 of Section 23, Township 12 North, Range 61 West, in Weld County, Colorado. The facility is located on the northwest corner of WCR 138 and WCR 95. The facility is surrounded by native grasses and agricultural land. The regional topography is relatively level with drainage to the south and south east. Surficial runoff within the concrete unloading area will be captured within the pad drain which drains to the sump. All other site runoff is generally sheet flow to the south and south east where the water will infiltrate into surficial soils. The nearest significant water body is Jackson Reservoir located approximately 40 miles to the south of the facility. Site location and area topographic and surface water features are depicted on Figure 1 (topographic map). General site conditions and facility details are shown on Figure 2. 2.7 Facility Storage I112.7(a)(31(i)1 The following table describes ASTs associated with storage of oil products at this facility: Tank Dimentions Capacity Tank ID# (gallons) Tank Process (Dia.(ft)/Height Construction Material ft De-Sanding Tank Fiberglass Reinforced Plastic AST within main concrete T-10-01 29,400 12/35 (unloading tank) secondary containment De-Sanding Tank Fiberglass Reinforced Plastic AST within main concrete T-10-02 29,400 (unloading tank) 12/35 secondary containment Fiberglass Reinforced Plastic AST within main concrete T-20-01 42,000 Oil Separation 15.5/30 secondary containment Fiberglass Reinforced Plastic AST within main concrete T-20-02 42,000 Oil Separation 15.5/30 secondary containment T-30-01 35 280 Water 15.5/ Fiberglass Reinforced Plastic AST within main concrete Equalization 25 secondary containment SPCC Plan July 22,2014 High Sierra Water Services Page 5 C9 Injection Facility Weld County,Colorado Water Fiberglass Reinforced Plastic AST within main concrete T-30-02 35,280 Equalization 15.5/25 secondary containment T-31-01 35,280 Water 15.5/25 Fiberglass Reinforced Plastic AST within main concrete Equalization secondary containment T-31-02 35,280 Water 15.5/25 Fiberglass Reinforced Plastic AST within main concrete Equalization secondary containment T-32-01 35,280 Water 15.5/25 Fiberglass Reinforced Plastic AST within main concrete Equalization secondary containment T-32-02 35,280 Water 15.5/25 Fiberglass Reinforced Plastic AST within main concrete Equalization secondary containment T-33-01 35,280 Water 15.5/25 Fiberglass Reinforced Plastic AST within main concrete Equalization secondary containment T-33-02 35,280 Water 15.5/25 Fiberglass Reinforced Plastic AST within main concrete Equalization secondary containment 1-40-01 42,000 Clean Tank 15.5/30 Fiberglass Reinforced Plastic AST within main concrete secondary containment 1-40-02 42,000 Clean Tank 15.5/30 Fiberglass Reinforced Plastic AST within main concrete secondary containment T-50-01 16,800 Oil Storage 12/20 Single-wall steel shop fabricated vertical AST within main concrete secondary containment T-50-02 16,800 Oil Storage 12/20 Single-wall steel shop fabricated vertical AST within main concrete secondary containment T-50-03 16,800 Oil Storage 12/20 Single-wall steel shop fabricated vertical AST within main concrete secondary containment T-50-04 16,800 Oil Storage 12/20 Single-wall steel shop fabricated vertical AST within main concrete secondary containment T-50-05 16,800 Sale Oil Storage 12/20 Single-wall steel shop fabricated vertical AST within main concrete secondary containment T-50-06 16,800 Waste Oil Storage 12/20 Single-wall steel shop fabricated vertical AST within main concrete secondary containment 2.8 Discharge Prevention Measures 1112.7(a)(3)(ii)1 High Sierra ensures that any releases due to spilling or overfilling do not occur. High Sierra only accepts disposal water when there is adequate capacity in the tanks to receive product. Monitoring of the transfer operation is done visually,with strict attention being paid to the volume received in accordance with available tank capacity. Manual tank gauging and sight confirmation of tank liquid levels are performed approximately every two hours with additional gauging as needed. Offloading procedures consist of a transfer pump,situated on the offloading pad that transfers fluid from the offloading tanker into the de-sanding/unloading ASTs. After the initial separation of the oil and water in the oil separation tank,the oil is transferred into the recovered crude storage ASTs. As aforementioned, tank filling does not begin until the plant operator has verified and documented the ullage(available capacity)based on manual tank gauge measurements and sight confirmation. In addition, electronic gauges are utilized that automatically shut down the pump transfer when approximately 90% of tank volume capacity is reached. After separation of the oil from the production water,the water is transferred to the manifolded water equilization ASTs, and subsequently transferred to the pump house for filtration. After filtration of the production water, the water is SPCC Plan July 22,2014 High Sierra Water Services Page 6 C9 Injection Facility Weld County,Colorado transferred to the"clean"water ASTs,and then back through the pump h ouse where it is injected into the subsurface via the injection well located south east of the pump house. Any water spilled within the pump house during pump maintenance or regular pump operation flows to a floor drain which drains into a sump located within the main secondary containment area. An example Ullage Log is provided in Appendix B. High Sierra requires all drivers to comply with DOT regulations in 49 CFR Part 177 regarding tank loading and unloading procedures. DOT requirements are provided in Appendix C. The following procedures are implemented when ASTs are being loaded: ❑ Vehicle's motor and lights are turned off,and the parking brake is set. ❑ The driver does not remain in the vehicle. ❑ Outlet valves are closed. ❑ Grounding procedures are followed. ❑ Ungrounded objects are removed from loading/unloading areas. ❑ Flow is started slowly. The fill pipe is touching both the truck hatch and bottom of compartment. El Transfer operator is present and attentive. After loading is complete,the following procedures are followed: ❑ All loading valves are closed and loading arms disengaged. Signs of spillage are noted and remedial action taken if necessary. ❑ All hatches are closed tightly. ❑ Internal safety valves are closed. 2.9 Discharge Controls I112.7(a)(3)(iii)l The ASTs and all associated piping and equipment are located within a diked secondary containment or the offloading pad, which will contain and control any potential discharges from the tanks, equipment, and transport trucks. Furthermore, any spills occurring within the pump house flow to the floor drain which drains to the sump. The cargo tankers could be considered mobile or portable oil storage tanks;however,the tankers are not owned by High Sierra and are generally situated on the offloading pad for short periods of time during deliveries. The design of the offloading pad is such that liquids would be contained on the pad and diverted to the sump,which is manually pumped into the flat tank as needed. High Sierra maintains spill response oil absorbent materials readily available at the facility that can be rapidly deployed to contain and abate potential discharges outside the secondary containment areas. High Sierra instructs oil handling personnel to assure that all 55-gallon oil drums are stored properly and within containment areas (if applicable) and that drum openings are sealed appropriately when not in use to prevent spills. High Sierra assures that all transfer equipment is compatible with the products being dispensed. Furthermore, drum SPCC Plan July 22,2014 High Sierra Water Services Page 7 C9 Injection Facility Weld County,Colorado fittings are securely attached to the appropriate bung openings and operated according to manufacturer recommendations. 2.10 Countermeasures:Discovery/Response/Cleanup I112.7(a)(3)(iv)1 High Sierra employees and contractors are aware of the need to immediately report all spills of oil products to Mr.Josh Patterson,the primary contact. If the primary contact is not available,the High Sierra Main Office will be notified. In the event of a large spill requiring emergency response(i.e.,spill spreads beyond the immediate spill area,enters surface water, requires special training or equipment, poses a danger of fire or explosion), emergency personnel from the Pawnee Fire Protection District are on hand by calling 911. Spill response will be initiated as soon as possible to stop additional spillage and to implement containment measures. High Sierra personnel and contractors maintain spill response supplies and oil absorbent materials readily available in their vehicles to respond to spills and begin immediate cleanup measures. Heavy equipment, including excavation vehicles and equipment, are available in the area provided by Mundt Oilfield Services. Pumps and vacuum tanker trucks are available in the area from either Wright Choice or Magna Energy Services. Manual tools,such as shovels and rakes, for use in containment and cleanup of spills will also be employed, if needed. Discovery,response, and cleanup activities are described in more detail in the following sections. 2.11 Disposal 1112.7(a)(3)(v)1 The final operation in spill response and cleanup is the disposal of impacted materials. Any plan for disposal used by High Sierra must be coordinated through the appropriate regulatory agency. If the impacted material is related to a release of oil or produced water from the injection facility storage system,the agency for oversight is the Colorado Oil and Gas Conservation Commission(COGCC). If from a source not regulated by COGCC(such as a tanker truck in transit), the agency for oversight is the Colorado Department of Public Health and Environment(CDPHE), Solid Waste Division. Impacted material must be disposed of at an appropriate facility permitted with the CDPHE, or other appropriate regulatory agency,to receive the type of waste being shipped and with shipment documented using proper manifest or bill-of-lading forms, if required. High Sierra will submit a follow-up written report to the appropriate agency within 60 days following a release,or in accordance with the requirements of the agency. 2.12 Notification Phone List 1112.7(a)(3)(vi)l A contact list and phone numbers for individuals, emergency response authorities, spill response/cleanup contractors and regulatory agencies to be notified in the event of leakage or spills is provided in Appendix D. Spills ultimately reaching navigable waters in harmful quantities as defined by 40 CFR Part 110.3 (that which violates applicable water quality standards or causes a sheen on the water surface)are required to be reported under 40 CFR Part 110.6. If a spill or release of exploration and production waste or produced fluids occurs and is greater than 1 BBL (42 gallons),it must be reported to the following regulatory agency within 24 hours: SPCC Plan July 22,2014 High Sierra Water Services Page 8 C9 Injection Facility Weld County,Colorado Colorado Oil and Gas Conservation Commission Environmental Release/Incident Report Hotline Denver,Colorado (1-877-518-5608) After hours or related to a container not regulated by COGCC contact: Colorado Department of Public Health and Environment Denver,Colorado (1-877-518-5608)(24-Hour) In the event of a large spill requiring emergency response (i.e. spill spreads beyond the immediate spill area, enters surface water,requires special training or equipment,poses a danger of fire or explosion),contact the following: Pawnee Fire Protection District Grover,Colorado 911 (24-Hour) (970)895-2237(Main Number) If the release reaches navigable water,contact the following: National Response Center Washington,DC (1-800-424-8802)(24-Hour) 2.13 Discharge Notification Form 1112.7(a)(4)1 An example form for spill documentation and reporting is provided in Appendix E. When contacting regulatory agencies,the following information should be provided: O name and owner/operator of facility; ❑ responsible company/person,including mailing address and telephone number; O name of person reporting the release; ❑ date and time of release; O legal description of release location; O type and amount of substance released; ❑ waterway affected,including amount reaching water; ❑ cause of release; ❑ action taken to control,contain,and remove release;and O other pertinent information specific to the release. In accordance with 40 CFR Part 112.4(a),if the facility has a discharge to navigable water of more than 1,000 gallons of oil in a single event or discharges more than 42 gallons of oil in each of two discharges occurring within any twelve month period, High Sierra will submit the following information to the EPA Regional Administrator within 60 days from the day of the discharge: SPCC Plan July 22,2014 High Sierra Water Services Page 9 C9 Injection Facility Weld County,Colorado ❑ Name of the facility; ❑ Callers name; ❑ Location of the facility; ❑ Maximum storage or handling capacity of the facility and normal daily throughput; ❑ Corrective action and countermeasures taken,description of equipment repairs and replacements; ❑ Description of the facility,including maps,flow diagrams,and topographic maps,as necessary; ❑ Description of the cause of the discharge,including a failure analysis of the system or subsystem that failed; ❑ Additional preventative measures taken or contemplated to minimize the possibility of recurrence;and ❑ Any other information as the Regional Administrator may reasonably require pertinent to the Plan or discharge. 2.14 Discharge Procedures f 112.7(a)(5)1 After identifying and locating a spill, the necessity for and feasibility of effective containment can be assessed. Containment must be initiated as soon as possible to prevent undue spreading of released product. The first action should be the elimination of any additional spillage. This may be accomplished by shutting off a pump or valve,placing a cap or a plastic or epoxy patch over the leak, putting a temporary plug in a puncture or tear, or other appropriate action. Oil absorbent materials maintained within the High Sierra or pumper/gauger subcontractor vehicles will be used to contain and clean up spilled product. If required,excavation equipment and/or manual tools,such as shovels and rakes, will be used to erect earthen berms along the leading edge of the spill to prevent spreading. Materials recovered during cleanup will be placed in appropriate containers or stockpiled using an impermeable liner and cover (such as polyethylene sheeting)to prevent cross-contamination with unexposed media prior to disposal. If free phase petroleum product is present or if the spill reaches surface water,the spill must be contained and removed. Mechanical methods of spill removal include suction hoses,excavation,the use of skimmers,and sorbent materials. The use of chemical or biological collecting agents is discouraged and may only be used with prior approval from both state and federal regulatory officials. High Sierra instructs all personnel who operate the injection facility systems on deployment measures needed to contain and cleanup a potential spill. 2.15 Discharge Prediction f112.7(b)1 A review of operations at the C9 injection facility indicates a low potential for equipment failure. Since the initial installation of the process and storage tanks,there have been no reported spills of petroleum products at the facility that have qualified as "spill events" under the federal definition. A detailed description of the storage containers and associated equipment where potential discharges could occur are summarized in facility specific spill prediction table below: SPCC Plan July 22,2014 High Sierra Water Services Page 10 C9 Injection Facility Weld County,Colorado Source Type of Failure Volume Estimated Direction of Secondary (gallons) Flow Rate Flow Containment De Sanding Rupture 29,400 Gradual to Stationary Concrete dike Tanks(2) instantaneous South Oil Storage Tanks Rupture 16 800 Gradual to Stationary to Concrete dike (6 instantaneous South Process System Rupture 35 280 Gradual to Stationary to Concrete dike Tanks(8) instantaneous South Clean Tanks(2) Rupture 42,000 Gradual to Stationary to Concrete dike instantaneous South Concrete Tanker truck Hose rupture, unloading to connection failure or 1 to 250** 3-100 gal/min East loading/unloading desanding tank overfill pad-containment drain Concrete Tanker truck Hose rupture, loading oil from connection failure or 1 to 50** 50-100 gal/min East loading/unloading ASTs(6) overfill pad-containment drain Gradual to Recessed full Sump Rupture 1 to 4,620 Stationary concrete secondary instantaneous containment *Predicted releases associated with AST filling activities are based on the attendant being present in close proximity to the pump controls, the loading valve or pump switch accessible, and attendant shutting the valve or pump switch within a conservative time frame of 15 seconds. ** Predicted releases associated with dispensing activities are based on the attendant being present and either releasing the nozzle or engaging the emergency shutoff switch if the nozzle is not accessible or has malfunctioned within a conservative time frame of 20 seconds. 2.16 Secondary Containment for Loading/Unloading Areas Other Than Rack 1112.7(c)1 The production water delivered to the site is offloaded from the tankers into the de-Sanding tank for initial separation of oil from the production water. The design of the unloading pad is such that liquids would be contained on the pad and into the drain if a spill were to occur. The drain routes any release to the 10' x 10' x 7.5' sump. Transfer pumps and piping used to fill all tanks are within the secondary containment dike or unloading pad containment. Secondary containment for oil transfer activities from the oil ASTs to the tanker trucks are provided by the concrete unloading/loading pad(s). Furthermore, overfills, valve or connection failures or dispensing spills at the recovered oil, process water ASTs, and the clean water AST would be contained within the concrete secondary containment. The walls and readily available spill response absorbent materials maintained on-site provide secondary containment for potential discharges that may occur within the pump house or outside any containment area. In the event of a spill outside the secondary containment areas, oil absorbent materials maintained on-site will be placed along the leading edge of the flow path and, if needed,excavating equipment will be used to erect soil berms SPCC Plan July 22,2014 High Sierra Water Services Page 11 C9 Injection Facility Weld County,Colorado to contain spills on-site until cleanup measures are completed. High Sierra instructs all operations personnel who operate the AST systems and are involved with oil handling activities on the location of the spill containment materials and deployment measures needed to contain and clean up spills. 2.17 Statement of Impracticability I112.7(d)l Not applicable;secondary containment is provided for all oil storage containers at the facility. 3.0 INSPECTIONS,TESTS AND RECORDS 3.1 Inspections and Record-Keeping f(112.7(e)l Inspections are an integral part of High Sierra operations. As described in more detail in Section 9.6, the AST systems are visually inspected every two hours in addition to each month and annually to ensure that there has been no failure of the tanks or associated equipment. Periodic certified inspections are also performed on the tanks,piping,and transfer equipment. Storage tank inspection reports which have been completed are signed by the appropriate supervisor or inspector and are made part of the current SPCC Plan. High Sierra management is responsible for all inspection reporting and documentation procedures. These records are kept on file with the SPCC Plan for a minimum period of three years. Inspection and recording forms are provided in Appendix F. 4.0 PERSONNEL TRAINING 4.1 Personnel Instruction I112.7(1)(1)l The AST systems are used only by a few employees who are properly trained in the operation and maintenance of the ASTs and associated equipment. Moreover, specific training to instruct all operations personnel on the contents and requirements of the SPCC Plan is regularly conducted and training is documented. Since the design of the systems are relatively simple and employee turnover is low,subsequent training is performed only occasionally. 4.2 Designated Individual for Spill Prevention 1112.7(f)(2)l The designated individual and Response Coordinator(RC) for spill prevention and reporting for High Sierra is Mr. Josh Patterson,who can be contacted at 970-356-5560(office). 43 Spill Prevention Briefings 1112.7(11(3)! High Sierra schedules and conducts spill prevention briefings at least annually, in coordination with regularly scheduled safety meetings, for all personnel involved with oil handling operations to assure adequate understanding of the SPCC Plan. These briefings highlight and describe spill events or failures, malfunctioning components, and recently developed precautionary measures. Employees acknowledge attendance and understanding of these briefings with their signatures on an attendance form. An SPCC training attendance form is provided in Appendix G. SPCC Plan July 22,2014 High Sierra Water Services Page 12 C9 Injection Facility Weld County,Colorado 5.0 SECURITY I112.7(g)l 5.1 Securing and Controlling Access The High Sierra C9 facility is manned and operates 24 hours per day, 7 days per week. Access is controlled by the facility entry and exit roads and the requirement of personnel to check in at the office upon arrival. Security is provided by the presence of High Sierra operations personnel 24 hours a day which provides a deterrent to unauthorized access. 5.2 Securing Master Flow/Drain Valves High Sierra locks master flow/drain valves on applicable ASTs when not in use, or in standby mode for extended periods of time. 5.3 Preventing Unauthorized Access to Starter Controls Starter controls for the AST transfer pumps are located in a control panel which is locked with switches in the off position when not in use, or in standby mode for extended periods of time. High Sierra limits access into the control panel to authorized personnel trained in the operation of the AST systems. 5.4 Securing Load ing/Unloadint!Connections Loading/unloading pipe connections are securely capped and valves locked when not in use. 5.5 Security Lighting Overhead lighting is present in all of the fuel and production water storage/transfer areas and outlying areas that will assist in the discovery of discharges occurring during hours of darkness both by operating personnel and non- operating personnel and to deter acts of vandalism. 6.0 TANK TRUCK LOADING/UNLOADING 6.1 Secondary Containment for Loading/Unloading Areas Including Racks 1112.7(h)(1)l The ASTs at the facility do not include loading/unloading racks. As described in Section 2.15, all loading and unloading connections and equipment on the ASTs are within the secondary containment dikes and loading/unloading areas. If a spill occurs from a tanker truck outside the containment areas, High Sierra maintains readily available and ample quantities of absorbent materials and equipment on-site that can be rapidly deployed to contain and abate any potential spill on-site. 6.2 Warning/Barrier Systems I112.7(h)(2)l SPCC Plan July 22,2014 High Sierra Water Services Page 13 C9 Injection Facility Weld County,Colorado Signs warning drivers to disconnect transfer lines before departure are posted in offloading/loading areas. 6.3 Bottom Drains of Vehicles Examined 1112.7(h)(3)l High Sierra assures that prior to filling and departure of any tank truck, the lowermost drain and all outlets of such vehicles are closely examined for leakage and,if necessary,tightened,adjusted,or replaced to prevent liquid leakage while in transit. 7.0 OTHER GENERAL REQUIREMENTS 7.1 Brittle Fracture/Other Failure Evaluation—Field Constructed Aboveground Containers 1112.7(i)1 The High Sierra C9 facility does not include field-constructed ASTs. 7.2 Conformance with Stricter State Rules 1112.7(1)1 No stricter State discharge prevention and containment procedures are applicable to this facility. 7.3 Oil-tilled Operational Equipment I112.7(k)] The High Sierra C9 facility has an electrical transformer located on the property. The transformer is not owned by High Sierra,but periodic checks are made to ensure the integrity of the structure and for the evidence of leaks. 8.0 FACILITY DRAINAGE 8.1 Drainage from Diked Areas I112.8(b)(1)l The C9 secondary containment area is constructed entirely of concrete,with storm drains that drain to the sump. All fluids that discharge outside of the ASTs and/or piping within the containment area are routed to the sump,which is pumped into the flat tank. The drain located on the unloading/loading pad also drains to the sump. No fluids are discharged outside of the secondary containment area. 8.2 Dike Drainage Valves—Manual,Open/Closed Designed 1112.8(b)(2)l There is no dike drainage valves associated with the AST secondary containment area. The AST secondary containment area routes all water to the sump. 83 Drainage System for Undiked Areas 1112.8(b)(3)l Secondary containment is provided for all aboveground tanks, piping and tanker truck transfer areas to prevent discharges to storm drainages outside the secondary contained areas. SPCC Plan July 22,2014 High Sierra Water Services Page 14 C9 Injection Facility Weld County,Colorado 8.4 Final Discharge Diversion System[112.8(b)(4)l In the event of a discharge outside secondary containment areas,oil absorbent materials maintained at the facility will be used to contain a spill on-site. If required,earthen berms will be erected with available excavating equipment along the leading edge of the spill to retain oil on-site until cleanup measures are completed. 8.5 Backup Pump for Lift Station and Transfer Systems 1112.8(b)(5)l High Sierra does not operate drainage lift stations at the C9 facility. 9.0 BULK STORAGE TANKS 9.1 Containers Compatible with Materials Stored f112.8(c)(1)1 The ASTs and any portable containers used for storage of water and petroleum products at the High Sierra C9 facility are shop manufactured for their intended use. The containers are constructed with materials compatible with the products stored and conditions of storage,such as pressure and temperature. 9.2 Secondary Containment[112.8(c)(2)1 All production water and oil ASTs are contained within the concrete secondary containment area. The containment area is drained by storm drains which route stormwater and any released fluids to the sump. The containment area is designed to hold the tank with the largest capacity(42,000-gallons)plus freeboard allowance for precipitation. The total calculated capacity of the containment area is 121,914 gallons. Considering the volume occupied by other tanks and freeboard allowance for a predicted 24-hour, 100-year storm event for the area, the adjusted available holding capacity is approximately 90,871 gallons. The unloading pad at the C9 facility drains into the sump located adjacent the secondary containment. The unloading pad is designed with adequate capacity to hold the volume of the largest tank of tanker truck (9,240 gallons)should a release occur. The secondary containment systems at the High Sierra C9 facility are designed to be impervious to contain spills from the largest tank without loss of oil until cleanup measures are implemented. High Sierra assures that excess precipitation is removed from the secondary containment areas to maintain adequate spill retention volume for the tanks. Secondary containment volume calculations are presented in Attachment 1. 9.3 Rainwater Drainage Procedure[112.8(c)(3)1 SPCC Plan July 22,2014 High Sierra Water Services Page 15 C9 Injection Facility Weld County,Colorado Precipitation that accumulates within the diked areas drains to the containment area sump, then pumped into the production water holding tanks. 9.4 Buried Metal Tanks Corrosion Protection [112.8(O(4)1 The facility does not currently operate buried tanks. 9.5 Partially Buried Tanks Protected Against Corrosion [112.8(O(5)1 The facility does not operate partially buried tanks. 9.6 Integrity Testing[I l2.8(c)(6)1 High Sierra assures that the ASTs and associated equipment are maintained in good condition. The ASTs, valves, transfer equipment, and aboveground piping components are readily accessible for visual inspection. Preventive spill measures include regular periodic inspections of the storage tanks and associated equipment and secondary containment systems following guidelines of the Steel Tank Institute (STI) Standard for the Inspection of Aboveground Storage Tanks SP001 September 2011 5th Edition. Based on the tank configurations, tank volumes, the tanks being in contact with the ground, and spill control provided by the secondary containment dikes, these activities include the following: ❑ On a monthly basis, the owner inspects the tanks, piping, and associated equipment for evidence of leakage. If needed, gaskets are replaced and threaded connections are tightened. Secondary containment areas are checked from the presence of spills or leaks, which is removed if present. The secondary containment sump pumps are checked to assure they are operable and water transfer piping is unobstructed. Tank gauge calibrations are checked by obtaining stick readings to verify gauge readings. Overfill equipment is tested to assure proper operation. ❑ On an annual basis, the owner inspects the condition of the tank containment structures. Tank foundations and supports are inspected for evidence of settling, cracking or distortion, proper water drainage and grounding. Inspections of the AST exteriors are performed to identify and repair damage to the tanks or surface coatings. Bolts on flanged manways,piping and equipment are inspected for tightness,wear and corrosion. Normal operating and emergency vents are inspected for proper operation and cleaned if needed. Tank liquid level sensing and overfill prevention devices are tested for proper operation. Electrical equipment, including grounding devices, control boxes and lights are inspected for proper operation. All tanks are Category 1 tanks (as defined by the STI SP001 standard), and should follow the inspection schedule for tanks between 5,001-50,000 gallons. At a maximum 20 year interval, formal internal inspections are performed by a Certified Tank Inspector. The formal internal inspections generally include inspection of mechanical damage,corrosion, cracking, etc, including the internal attachments and piping. Furthermore, shell thickness testing of the AST floor is performed. Additional inspection criteria may be deemed necessary by the certified inspector based on tank configurations and industry standards. SPCC Plan July 22,2014 High Sierra Water Services Page 16 C9 Injection Facility Weld County,Colorado The extent and frequency of future inspections will be based on the recommendations of the Certified Inspector. Any leaks discovered during inspection are promptly evaluated and reported to the General Manager. High Sierra assures that personnel who operate, maintain,and inspect the AST systems are properly trained in the operation and maintenance of the systems and characteristics of the fluids stored,which helps to reduce the probability for a spill. As noted in Section 3.1,monthly and annual inspection documentation forms are provided in Appendix F. 9.7 Internal Coils 1112.8(c)(7)l No heated tanks are onsite at the C9 injection facility. 9.8 Engineered to Avoid Discharges 1112.8(c)(8)l High Sierra only accepts disposal water when there is adequate capacity in the tanks to receive product. Monitoring of the transfer operation is done visually,with strict attention being paid to the volume received in accordance with available tank capacity. Manual tank gauging and sight confirmation of tank liquid levels are performed approximately every two hours with additional gauging as needed. Offloading procedures consist of a transfer pump situated on the pad that transfers fluid from the tanker into the flat tank,where solids are allowed to settle out and the oil is separated from the water and transferred into the oil tanks. Production water is then pumped into the manifolded system ASTs and then to the pump house where the water is filtered and transferred to the"clean water" tank. The"clean water"is then transferred back to the pump house and injected into the subsurface via the injection well located east of the facility. Tank filling does not begin until the plant operator has verified and documented the ullage (available capacity) based on manual tank monitoring and sight confirmation. Furthermore, all tanks are equipped with overfill pump shut off sensors, which automatically shut down the pumps once tanks reach approximately 90%available capacity. 9.9 Plant Effluent Discharges into Navigable Water[112.8(c)(9)l The facility does not have plant effluent discharges to navigable waters. 9.10 Oil Leaks Promptly Corrected 1112.8(c)(10)1 Any oil leaks identified through routine inspection are promptly corrected,reported to management,and abated. 9.11 Mobile or Portable Oil Storage Tanks 1112.8(c)(11)l The cargo tankers could be considered mobile or portable oil storage tanks;however,the tankers are not owned by High Sierra and are only on site for short periods during fluid transfer activities. Currently, there are no portable oil storage containers at the facility. Should any portable container containing over 55-gallons comes on site,they will be placed within a containment area and included in routine inspections. Oil-handling personnel are instructed to maintain appropriate seals and plugs on the container when not in use to prevent spills. If a spill occurs, spilled product will be contained within the building walls and cleaned up with readily available oil absorbent materials. SPCC Plan July 22,2014 High Sierra Water Services Page 17 C9 Injection Facility Weld County,Colorado 10.0 FACILITY TRANSFER OPERATIONS 10.1 General General safety features which are applicable to maintaining the integrity of transfer operations include: ❑ Valves and pipelines are examined monthly to assess the condition of the transfer equipment;and ❑ If corrosion damage is found,additional examination and corrective action are taken as indicated by the magnitude of the damage. 10.2 Buried Pipe Installations I112.8(d)(1)1 Most facility piping is aboveground and readily visible for inspection. However, piping related to the pump house including piping connecting the clean water AST to the pump house and piping from the pump houses to the injection well are underground. The piping is subject to additional protection per section 112.8(d)(I). Any replacement of the subsurface piping will be subject to corrosion protection or wrapping. Furthermore,any buried piping that is exposed will be inspected for deterioration. If corrosion damage or leakage at exposed piping is found,additional examination and corrective action will be taken commensurate with the magnitude of the damage. 10.3 Terminal Pipe Connections Capped or Blank Flanged I112.8(d)(2)1 There is no out-of-service piping associated with the AST systems. The terminal pipe connections where the tanker truck connects to unload oil from the oil ASTs are securely capped when not in use and are located inside spill containment enclosures with locking lids,which are labeled to identify what types of product are to be transferred. 10.4 Aboveground Pipe Supports 1112.8(d)(3)1 High Sierra maintains adequate bracing on aboveground pipe runs to avoid excess movement that can cause stress and abrasion. Piping on the ASTs is of heavy gauge steel construction and is securely attached with threaded fittings to the tank and ground. 10.5 Testing and Inspection of Aboveground Pipes and Valves 1112.8(d)(4)1 As discussed in section 9.6, valves and piping are examined monthly to assess the condition of the transfer equipment. The dispensing system equipment is maintained in good condition. If corrosion damage or leakage at valves or pipe connections is found, additional examination and corrective action will be taken commensurate with the magnitude of the damage. SPCC Plan July 22,2014 High Sierra Water Services Page 18 C9 Injection Facility Weld County,Colorado 10.6 Warning for Trucks of Pipes 1112.8(d)(5)1 No aboveground piping is exposed outside of the secondary containment,or exposed to vehicular traffic. The unloading pump and associated piping are protected by steel parking bumpers. High Sierra instructs personnel operating in the unloading area to be aware of piping and pumping equipment and to use caution when approaching the area. 11.0 SUBSTANTIAL HARM 1112.20(e)1 40 CFR 112.20 (f)(1) lists criteria under which "a facility could, because of its location, reasonably be expected to cause substantial harm to the environment by discharging oil into or on the navigable waters or adjoining shorelines..." if it meets any of the listed criteria. High Sierra does not meet the listed criteria, including: (1) does not transfer oil over water; and (2)has a total oil storage capacity of less than one million gallons. Because of the design of the tanks, limited spill history at the facility, no proximity to drinking water intakes, and the well-trained personnel at this facility, no Facility Response Plan should be required. The required Certification of Applicability of the Substantial Harm Criteria, Part 112.20, Appendix D, Attachment C-II,has been completed and is maintained at the facility in Appendix I of SPCC plan. FIGURES CM • 7r, ...,,,z ( s, _ _ _______ ,, ( I ( C''. et---\, ,it) .—.--- ____----..1,-----__ — -*•\' ,., a j ,) 1 „,----'-- __,..,- - ----/ _*.._ ayi -‘ •.( I t'''. ' ' '. ---- )i) 3,41 -•••.-_,...7.-----,....---. l 5 ""\• - c:7)5', !'''. '''''''''''..- \ \*. . ., , . '-"N",- "- s''''''‘...................................:,: -..._„. M 1011E ._- •e, __ _ - ) ..........s.? Is\\.• SITE `-") LOCATION 4\\. -1) . __ __ JAM._. ;a - 13 y L.. - .` .1 . 3. \ . () • -r_• g. ,.w.........• -r«ylll�• ;i• •.•�i.�. ,1 i • �'pion • • T k '1i w 1 C Y r ' Z4 _— _`'r 23 II • Ni i ././..) t i ...X- --'-- --' -''.*. - -.-..• .• •''-N/ \ '- ----. ' • Erse - �_ FIGURE 1 SITE LOCATION MAP HIGH SIERRA WATER SERVICES C9 FACILITY COLORADO W 112,NW 1/4 of Section 13,T10N,R6I W GROVER,COLORADO rZI PROJECT: DRAFT: 0 1000 2000 1-12462-14629aa MSP �CG ENVIRONMENTAL ImT� CONSTRUCTION DATE: REVIEW'. A\_ COMPLIANCE ■ QUADRANGLE LOCATION SCALE IN FEET 7/22/2014 i I as r O ce HIGH SIERRA qo 00, O C9 FACILITY 00( 00? 100_` 1O 0 ❑ q / s f/ ❑ LEGEND FIGURE 2A SITE CONDITIONS MAP Alp PROPOSED MONITORING WELL LOCATION HIGH SIERRA WATER SERVICES C9 FACILITY W 1/2,NW 1/4 of Section 13,T10N,R61 W GROVER,COLORADO PROJECT: DRAFT: ��++ o 50 100 150 200 1-12462-14629aa MSP CG ENVIRONMENTAL CONSTRUCTIOtO N 6t DATE: REVIEW: COMPLIANCE SCALE IN FEET 7/22/2014 �� GRAVEL DRIVEWAY GRAVEL Cr) Ci CONTAINMENT IX O WALL-\\ IX I- } Z _1000 W D O FUTURE _'IO 04 O O CI TANKS ;O O 1® W ,,, O O ❑ Q BUILDING ,l O 10 SUMP i 11 12 1® MAP SIZE TANK ! 1© 14 ID (BBLS) ID 1 1000 T-40-02 ELECTRICAL 2 1000 T-40-01 DRIVEWAY GRAVEL ❑ TRANSFORMER 3 840 T-33-02 4 840 T-33-01 5 840 T-32-02 ❑ 'S 6 840 T-32-01 s DRAIN—Ns, GRAVEL 7 840 T-31-02 8 840 T-31-01 ❑ 9 840 T-30-02 10 840 T-30-01 11 1000 T-20-02 ❑ 12 1000 T-20-01 13 700 T-10-02 14 700 T-10-01 15 400 T-50-01 16 400 T-50-02 b' CONCRETE 17 400 T-50-03 UNLOADING 18 400 T-50-04 PAD 19 400 T-50-05 20 400 T-50-06 21 400 T-50-07 LEGEND FIGURE 2B SITE CONDITIONS MAP S+ PROPOSED MONITORING WELL LOCATION HIGH SIERRA WATER SERVICES C9 FACILITY W 1/2,NW 1/4 of Section 13,T10N,R61 W GROVER,COLORADO PROJECT: DRAFT: ��++ 0 20 ao so ao too 1-12462-14629aa MSP CG� 4CONSTRMBAAL NVIRONUCIION DATE: REVIEW: al ilk COMPLIANCE SCALE IN FEET 7/22/2014 *kV APPENDIX A SPCC REVIEW LOG SPILL PREVENTION CONTROL AND COUNTERMEASURE PLAN REVIEW LOG FOR TECHNICAL AMENDMENTS: High Sierra Water Services C9 Saltwater Injection Facility In accordance with 40 CFR Part 112.5(b), a review and evaluation of this Spill Prevention Control and Countermeasure (SPCC)Plan will be conducted at least every five years. As a result of such a review and evaluation,the SPCC Plan will be amended within six months of completing said review and evaluation to include more effective and proven prevention and control technologies if: 1)such technologies will significantly reduce the likelihood of a spill event from the facility,and 2)if such technologies have been field-proven at the time of review. Any amendment to this SPCC Plan shall be certified by a Professional Engineer, in accordance with 40 CFR Part 112.3(d), within six months after a change in the facility design, construction, operation,or maintenance occurs which materially affects the facility's potential for the discharge of oil into or upon the navigable waters or the United States or adjoining shorelines(40 CFR Part 112.5(a)). Amendments to the plan shall be completed and implemented within six months of the facility changes. ❑ I have completed review and evaluation of the SPCC Plan for the High Sierra Water Services,C9 Saltwater Injection Facility,Grover,Colorado and(will/will not)amend the plan as a result. Date Name Signature Title Amendment(if applicable) Certifying Engineer Statement(if applicable) This plan amendment was prepared using sound engineering practices. I have examined the facility and find this plan conforms to the guidelines and provisions of 40 CFR Part 112. Date Name Signature ❑ I have completed review and evaluation of the SPCC Plan for the High Sierra Water Services,C9 Saltwater Injection Facility,Grover,Colorado and(will/will not)amend the plan as a result. Date Name Signature Title Amendment(if applicable) Certifying Engineer Statement(if applicable) This plan amendment was prepared using sound engineering practices. I have examined the facility and find this plan conforms to the guidelines and provisions of 40 Part CFR 112. Date Name Signature SPILL PREVENTION CONTROL AND COUNTERMEASURE PLAN REVIEW LOG FOR NON-TECHNICAL AMENDMENTS: High Sierra Water Services C9 Saltwater Injection Facility Review and Amendment Log Review/Amend Amend Plan Description of Review Date Signature (will/will not) Amendment Affected Page(s) APPENDIX B ABOVEGROUND STORAGE TANK ULLAGE LOG ABOVEGROUND STORAGE TANK ULLAGE LOG "Use a Separate Log Sheet for Each Tank" Use either this form or its equivalent to document ullage (available capacity) calculations before transferring product to the aboveground storage tank (AST). Use the correct tank chart to convert from inches to gallons. If ullage is calculated by an automatic tank gauge(ATG), it is acceptable to save the ATG inventory tape that shows the ullage in gallons. Facility name High Sierra Water Services, C9 Saltwater Injection Facility AST# Street W %2 NW/4,Sec. 13,T10N,R61W Product in tank address City Grover,Colorado ZIP Tank capacity (gallons) Date Gauge or stick Conversions to Available Capacity Quantity Added Initials reading gallons APPENDIX C DOT REQUIREMENTS Department of Transportation 49 CFR Page I DOT LOADING AND UNLOADING OF TRANSPORT VEHICLES 173.30 Loading and unloading of transport vehicles. A person who loads or unloads hazardous materials into or from a transport vehicle or vessel shall comply with the applicable loading and unloading requirements of parts 174, 175, 176,and 177 of this subchapter. [Amdt. 173-94,41 FR 16064,Apr. 15, 1976] 174.67 Tank car unloading. a) In unloading tank cars,the following rules must be observed(see subpart F of this part for gases): 1) Unloading operations must be performed only by reliable persons properly instructed in unloading hazardous materials and made responsible for careful compliance with this part. 2) Brakes must be set and wheels blocked on all cars being unloaded. 3) Caution signs must be placed on the track or cars to give necessary warning to persons approaching the cars from the open end of a siding and must be left up until after the cars are unloaded and disconnected from the discharge connection. The signs must be of metal or other comparable material,at least 30 cm(12 inches)high by 38 cm(15 inches)wide in size,and bear the words, "STOP—Tank Car Connected", or"STOP—Men at Work",the word"STOP"being in letters at least 10 cm (3.9 inches) high and the other words in letters at least 5 cm (2 inches) high. The letters must be white on a blue background. 4) Before a manhole cover or outlet valve cap is removed from a tank car, the car must be relieved of all interior pressure by cooling the tank with water or venting the tank by raising the safety valve or opening the dome vent at short intervals. However, if venting to relieve pressure will cause a dangerous amount of vapor to collect outside the car, venting and unloading must be deferred until the pressure is reduced by allowing the car to stand overnight or otherwise cooling the contents. These precautions are not necessary when the car is equipped with a manhole cover which hinges inward or with an inner manhole cover which does not have to be removed to unload the car,and when pressure is relieved by piping vapor into a condenser or storage tank. b) After the pressure is released,the seal must be broken and the manhole cover removed as follows: 1) Screw type. The cover must be loosened by placing a bar between the manhole cover lug and knob. After two complete turns, so that vent openings are exposed, the operation must be stopped, and if there is any sound of escaping vapor, the cover must be screwed down tightly and the interior pressure relieved as prescribed in paragraph (a)(4) of this section, before again attempting to remove the cover. 2) Hinged and bolted type. All nuts must be unscrewed one complete turn, after which same precautions as prescribed for screw type cover must be observed. 3) Interior type. All dirt and cinders must be carefully removed from around the cover before the yoke is unscrewed. c) When the car is unloaded through a bottom outlet valve,the manhole cover must be adjusted as follows: 1) Screw type. The cover must be put in place,but not entirely screwed down,so that air may enter the tank through the vent holes in threaded flange of the cover. 2) Hinged and bolted type. A non-metallic block must be placed under one edge of the cover. 3) Interior type. The screw must be tightened up in the yoke so that the cover is brought up within one-half inch of the closed position. d) When unloading through the bottom outlet of a car equipped with an interior manhole type cover, and in each case where unloading is done through the manhole (unless a special cover with a safety vent opening and a tight connection for the discharge outlet is used),the manhole must be protected by asbestos or metal covers against the entrance of sparks or other sources of ignition of vapor, or by being covered and surrounded with wet burlap or similar cloth material. The burlap or other cloth must be kept damp by the replacement or the application of water as needed. e) Seals or other substances must not be thrown into the tank and the contents may not be spilled over the car or tank. f) The valve rod handle or control in the dome must be operated several times to see that outlet valve in the bottom of tank is on its seat before valve cap is removed. g) The valve cap,or the reducer when a large outlet is to be used,must be removed with a suitable wrench after the set screws are loosened and a pail must be placed in position to catch any liquid that may be in the outlet chamber. If the valve cap or reducer does not unscrew easily,it may be tapped lightly with a mallet or wooden block in an upward direction. If leakage shows upon starting the removal,the cap or reducer may not be entirely unscrewed. Sufficient threads must be left engaged and sufficient time allowed to permit controlled escape of any accumulation of liquid in the outlet chamber. If the leakage stops or the rate of leakage diminishes materially,the cap or reducer may be entirely removed. If the initial rate of leakage Department of Transportation 49 CFR Page 2 continues, further efforts must be made to seat the outlet valve (see paragraph (f) of this section). If this fails, the cap or reducer must be screwed up tight and the tank must be unloaded through the dome. If upon removal of the outlet cap the outlet chamber is found to be blocked with frozen liquid or any other matter, the cap must be replaced immediately and a careful examination must be made to determine whether the outlet casing has been cracked. If the obstruction is not frozen liquid, the car must be unloaded through the dome. If the obstruction is frozen liquid and no crack has been found in the outlet casting, the car may, if circumstances require it, be unloaded from the bottom by removing the cap and attaching unloading connections immediately. Before opening the valve inside the tank car, steam must be applied to the outside of the outlet casting or wrap casting with burlap or other rags and hot water must be applied to melt the frozen liquid. h) Unloading connections must be securely attached to unloading pipes on the dome or to the bottom discharge outlets before any discharge valves are opened. i) Tank cars may not be allowed to stand with unloading connections attached after unloading is completed. Throughout the entire period of unloading,and while car is connected to unloading device,the car must be attended by the unloader. j) If necessary to discontinue unloading a tank car for any reason,all unloading connections must be disconnected. All valves must first be tightly closed,and the closures of all other openings securely applied. k) As soon as a tank car is completed unloaded,all valves must be made tight,the unloading connections must be removed and all other closures made tight, except that heater coil inlet and outlet pipes must be left open for drainage. The manhole cover must be reapplied by the use of a bar or wrench,the outlet valve reducer and outlet valve cap replaced by the use of a wrench having a handle at least 0.9 m (3.0 feet) long, and the outlet valve cap plug, end plug, and all other closures of openings and of their prospective housings must be closed by the use of a suitable tool. 1) Railroad defect cards may not be removed. m) If oil or gasoline has been spilled on the ground around connections,it must be covered with fresh,dry sand or dirt. n) All tools and implements used in connection with unloading must be kept free of oil,dirt,and grit. (49 U.S.C. 1803, 1804, 1808;49 CFR 1.53,app.A to part 1) [Amdt. 174-26,41 FR 16092, Apr. 15, 1976 as amended by Amdt. 174-26A,41 FR 40685, Sept. 20, 1976; Amdt. 174-43, 48 FR 27699,June 16, 1983;Amdt. 174-68,55 FR 52978,Dec 21, 1990;56 FR 66280,Dec.20, 1991] (174C/Rail: Handling and Loading Preface/174.67 Tank car unloading.,Heading) thru (174C/Rail: Handling and Loading Preface/174.67 Tank car unloading.,23) 177B Highway: Loading and Unloading Subpart B—Loading and Unloading Note: For prohibited loading and storage of hazardous materials,see 177.848 177.834 General requirements a) Packages secured in a vehicle. Any tank,barrel, drum, cylinder, or other packaging, not permanently attached to a motor vehicle,which contains any Class 3 (flammable liquid), Class 2 (gases). Class 8 (corrosive), Division 6.1 (poisonous), or Class 7 (radioactive)material must be secured against movement within the vehicle on which it is being transported,under conditions normally incident to transportation. b) No hazardous materials on pole trailers. No hazardous materials may be loaded into or on or transported in or on any pole trailer. c) No smoking while loading or unloading. Smoking on or about any motor vehicle while loading or unloading any Class 1 (explosive), Class 3 (flammable liquid), Class 4 (flammable solid), Class 5 (oxidizing), or Division 2.1 (flammable gas) materials is forbidden. d) Keep fire away,loading and unloading. Extreme care shall be taken in the loading or unloading of any Class 1 (explosive), Class 3 (flammable liquid),Class 4(flammable solid),Class 5 (oxidizing),or Division 2.1 (flammable gas)materials into or from any motor vehicle to keep fire away and to prevent persons in the vicinity from smoking lighting matches,or carrying any flame or lighted cigar,pipe,or cigarette. Department of Transportation 49 CFR Page 3 e) Handbrake set while loading and unloading. No hazardous material shall be loaded into or on,or unloaded from,any motor vehicle unless the handbrake be securely set and all other reasonable precautions be taken to prevent motion of the motor vehicle during such loading or unloading process. f) Use of tools,loading and unloading. No tools which are likely to damage the effectiveness of the closure of any package or other container, or likely adversely to affect such package or container, shall be used for the loading or unloading of any Class 1(explosive)material or other dangerous article. g) Prevent relative motion between containers. Containers of Class 1 (explosive), Class 3 (flammable liquid), Class 4 (flammable solid),Class 5 (oxidizing),Class 8 (corrosive),Glass 2 (gases)and Division 6.1 (poisonous)materials,must be so braced as to prevent motion thereof relative to the vehicle while in transit. Containers having valves or other fittings must be so loaded that there will be the minimum likelihood of damage thereto during transportation. h) Precautions concerning containers in transit; fueling road units. Reasonable care should be taken to prevent undue rise in temperature of containers and their contents during transit. There must be no tampering with such container or the contents thereof nor any discharge of the contents of any container between point of origin and point of billed destination. Discharge of contents of any container,other than a cargo tank, must not be made prior to removal from the motor vehicle. Nothing contained in this paragraph shall be so construed as to prohibit the fueling of machinery or vehicles used in road construction or maintenance. i) Attendance requirements. 1) Loading. A cargo tank must be attended by a qualified person at all times when it is being loaded. The person who is responsible for loading the cargo tank is also responsible for ensuring that it is so attended. 2) Unloading. A motor carrier who transports hazardous materials by a cargo tank must ensure that the cargo tank is attended by a qualified person at all times during unloading. However,the carrier's obligation to ensure attendance during unloading ceases when: (i) The carrier's obligation for transporting the materials is fulfilled; (ii) The cargo tank has been placed upon the consignee's premises;and (iii) The motive power has been removed from the cargo tank and removed from the premises. 3) A person "attends" the loading or unloading of a cargo tank if, throughout the process, he is awake, has an unobstructed view of the cargo tank,and is within 7.62 meters(25 feet)of the cargo tank. 4) A person is "qualified" if he has been made aware of the nature of the hazardous material which is to be loaded or unloaded,he has been instructed on the procedures to be followed in emergencies,he is authorized to move the cargo tank, and he has the means to do so. 5) A delivery hose,when attached to the cargo tank,is considered part of the vehicle. j) Prohibited loading combinations. In any single driven motor vehicle or in any single unit of a combination of motor vehicles,hazardous materials shall not be loaded together if prohibited by loading and storage chart, 177.848. This section shall not be so construed as to forbid the carrying of materials essential to safe operation of motor vehicles. (See Motor Carrier Safety Regulations part 393 of this title.) k) [Reserved] 1) Use of cargo heaters when transporting certain hazardous material. Transportation includes loading, carrying, and unloading. 1) When transporting Class 1 (explosive) materials. A motor vehicle equipped with a cargo heater of any type may transport Class 1 (explosive) materials only if the cargo heater is rendered inoperable by: (i) Draining or removing the cargo heater fuel tank;and(ii)disconnecting the heater's power source. 2) When transporting certain flammable material— (i) Use of combustion cargo heaters. A motor vehicle equipped with a combustion cargo heater may be used to transport Class 3(flammable liquid)or Division 2.1 (flammable gas)materials only if each of the following requirements are met: A) It is a catalytic heater. B) The heater's surface temperature cannot exceed 54 CC (130 EF) — either on a thermostatically controlled heater or on a heater without thermostatic control when the outside or ambient temperature is 16 EC(61 EF)or less. C) The heater is not ignited in a loaded vehicle. D) There is no flame,either on the catalyst or anywhere in the heater. E) The manufacturer has certified that the heater meets the requirements under paragraph (1)(2)(i) of this section by permanently marking the heater "MEETS DOT REQUIREMENTS FOR CATALYTIC HEATERS USED WITH FLAMMABLE LIQUID AND GAS." F) The heater is also marked "DO NOT LOAD INTO OR USE IN CARGO COMPARTMENTS CONTAINING FLAMMABLE LIQUID OR GAS IF FLAME IS VISIBLE ON CATALYST OR IN HEATER." G) Heater requirements under 393.77 of this title are complied with. Department of Transportation 49 CFR Page 4 (ii) Effective date for combustion heater requirements. The requirements under paragraph (1)(2)(i) of this section govern as follows: A) Use of a heater manufactured after November 14, 1975,is governed by every requirement under(1)(2)(i)of this section; B) Use of a heater manufactured before November 14, 1975,is governed only by the requirements under(1)(2)(i)(A),(C),(D), (F)and(G)of this section until October 1, 1976;and C) Use of any heater after September 30, 1976,is governed by every requirement under paragraph(1)(2)(i)of this section. (iii) Restrictions on automatic cargo-space heating temperature control devices. Restrictions on these devices have two dimensions: Restrictions upon use and restrictions which apply when the device must not be used. A) Use restrictions. An automatic cargo-space-heating temperature control device may be used when transporting Class 3 (flammable liquid)or Division 2.1 (flammable gas)materials only if each of the following requirements is met: 1) Electrical apparatus in the cargo compartment is non sparking or explosion proof. 2) There is no combustion apparatus in the cargo compartment. 3) There is no connection for return of air from the cargo compartment to the combustion apparatus. 4) The heating system will not heat any part of the cargo to more than 54 CC(129 CF). 5) Heater requirements under 393.77 of this title are complied with. B) Protection against use. Class 3 (flammable liquid) or Division 2.1 (flammable gas) materials may be transported by a vehicle, which is equipped with an automatic cargo-space-heating temperature control device that does not meet each requirement of paragraph(1)(2)(iii)(A)of this section,only if the device is first rendered inoperable,as follows: 1) Each cargo heater fuel tank,if other than LPG,must be emptied or removed. 2) Each LPG fuel tank for automatic temperature control equipment must have its discharge valve closed and its fuel feed line disconnected. (m)Tanks constructed and maintained in compliance with Spec.106A or 110A(Secs. 179.300, 179.301 of this subchapter)that are authorized for the shipment of hazardous materials by highway in part 173 of this subchapter must be carried in accordance with the following requirements: 1) Tanks must be securely chocked or clamped on vehicles to prevent any shifting. 2) Equipment suitable for handling a tank must be provided at any point where a tank is to be loaded upon or removed from a vehicle. 3) No more than two cargo carrying vehicles may be in the same combination of vehicles. 4) Compliance with Secs. 174.200 and 171.204 of this subchapter for combination rail freight, highway shipments and for trailer-on-flat-car service is required. (n) Specification 56, 57, IM 101,and IM 102 portable tanks,when loaded,may not be stacked on each other nor placed under other freight during transportation by motor vehicle. [29 FR 18795,Dec.29, 1964. Redesignated at 32 FR 5606,Apr. 5, 1967] Editorial Note: For Federal Register citations affecting 177.834, see the List of CFR Sections Affected appearing in the Finding Aids section of this volume. 177B Highway: Loading and Unloading Subpart B—Loading and Unloading Note: For prohibited loading and storage of hazardous materials, see /77.848 177.837 Class 3 (flammable liquid)materials (See also 177.834(a)to(j).) a) Engine stopped. Unless the engine of the motor vehicle is to be used for the operation of a pump,no Class 3 (flammable liquid)material shall be loaded into,or on,or unloaded from any motor vehicle while the engine is running. b) Bonding and grounding containers other than cargo tanks prior to and during transfer of lading. For containers which are not in metallic contact with each other, either metallic bonds or ground conductors shall be provided for the neutralization of possible static charges prior to and during transfers of Class 3 (flammable liquid) materials between such containers. Such bonding shall be made by first connecting an electric conductor to the container to be filled and subsequently connecting the conductor to the container from which the liquid is to come,and not in any other order. To provide against Department of Transportation 49 CFR Page 5 ignition of vapors by discharge of static electricity, the latter connection shall be made at a point well removed from the opening from which the Class 3 (flammable liquid)material is to be discharged. c) Bonding and grounding cargo tanks before and during transfer of lading. 1) When a cargo tank is loaded through an open filling hole, one end of a bond wire shall be connected to the stationary system piping or integrally connected steel framing,and the other end to the shell of the cargo tank to provide a continuous electrical connection. (If bonding is to the framing, it is essential that piping and framing be electrically interconnected.) This connection must be made before any filling hole is opened,and must remain in place until after the last filling hole has been closed. Additional bond wires are not needed around All-Metal flexible or swivel joints, but are required for nonmetallic flexible connections in the stationary system piping. When a cargo tank is unloaded by a suction-piping system through an open filling hole of the cargo tank,electrical continuity shall be maintained from cargo tank to receiving tank. 2) When a cargo tank is loaded or unloaded through a vapor-tight(not open hole)top or bottom connection,so that there is no release of vapor at a point where a spark could occur, bonding or grounding is not required. Contact of the closed connection must be made before flow starts and must not be broken until after the flow is completed. 3) Bonding or grounding is not required when a cargo tank is unloaded through a nonvapor-tight connection into a stationary tank provided the metallic filling connection is maintained in contact with the filling hole. d) Manholes and valves closed. A person shall not drive a cargo tanks and motor carrier shall not require or permit a person to drive a tank motor vehicle containing a Class 3(flammable liquid)material(regardless of quantity)unless: 1) All manhole closures on the cargo tank are closed and secured;and 2) All valves and other closures in liquid discharge systems are closed and free of leaks. [29 FR 18795,Dec.29, 1964. Redesignated at 32 FR 5606,Apr. 5, 1967] Editorial Note: For Federal Register citations affecting 177.837, see the List of CFR Sections Affected appearing in the Finding Aids section of this volume. APPENDIX D EMERGENCY SPILL RESPONSE CONTACTS AND PROCEDURES EMERGENCY SPILL RESPONSE CONTACTS High Sierra Water Services, C9 Saltwater Injection Facility; W 1/2 NW/4 Section 13,T10N,R61W Grover,Colorado In the event of leakage or spills,the following individuals and/or companies are to be contacted: Primary On-Site Contact Mr,Josh Patterson 970-356-5560 office VP Operations 970-868-1286 cell phone Alternate On-Site Contacts High Sierra Office 970-356-5560 office cell phone Local Emergency Contacts Are: CI Pawnee Fire Protection District—911 Li Emergency Response Contractors/Waste Disposal Vendors: Ll Li If a petroleum release occurs and is greater than 42 gallons, it must be reported to the following regulatory agencies within 24 hours: Colorado Oil and Gas Conservation Commission 1120 Lincoln Street,Suite 801 Denver,Colorado 80203 303-894-2100 If the release reaches navigable water,the following agency must be contacted: National Response Center Washington,DC 800-424-8802(24-hour phone) SPILL RESPONSE PROCEDURES High Sierra Water Services, C9 Saltwater Injection Facility; W 1/2 NW/4 Section 13,T10N,R61W Grover,Colorado ❑ After identifying and locating a spill,containment must be initiated as soon as possible to prevent undue spreading of released product. The first action should be the elimination of any additional spillage by pressing the emergency shutoff button, shutting off a pump or valve, placing a cap or a plastic or epoxy patch over the leak, putting a temporary plug in a puncture or tear,righting an overturned container,or other appropriate action. ❑ Spill response materials maintained at the facility will be used to contain and clean up spilled product. Place portable dike materials or erect berms with granular absorbent or earthen material along the leading edge of the spill to prevent spreading. Apply absorbent pads or granular absorbent to the spilled product for clean up. ❑ Using the Emergency Contact List for reference: 1. Alert and notify on-site supervisory personnel. 2. If the spill exceeds the capabilities of on-site facility personnel (ie: spill spreads beyond the immediate spill area, enters surface water, requires special training or equipment, poses a danger of fire or explosion), immediately contact the local fire authority by calling 911. 3. If the spill enters surface water,contact the National Response Center at(800)424-8802. ❑ Materials recovered during cleanup must be placed in appropriate containers (such as DOT rated drums) or stockpiled using an impermeable liner and cover (such as polyethylene sheeting) to prevent cross-contamination with unexposed media prior to disposal. APPENDIX E SPILL DOCUMENTATION FORM SPILL RESPONSE NOTIFICATION FORM Fill out this form as completely as possible prior to calling regulatory agencies. Refer to the Emergency Contact List for guidance on regulatory agencies to notify and telephone numbers. RELEASE INFORMATION Notification Person Name: Date: Time: Agency Being Notified: Phone Number: Facility Name: Address: City: State: Zip Code: Telephone Number: Fax Number: Owner/Operator Name: Address: City: State: Zip Code: Primary Contact Name/Position: Work Phone: Cell Phone: Other(24-Hour): Location of Release: Address: Section: Township: Range: County: Latitude: Degrees Minutes Seconds Longitude: Degrees Minutes Seconds Date/Time of Release: Date/Time of Discovery: Type of Oil Released: Quantity Released: Duration of Release: Describe Source and Cause of Release: Actions Taken to Stop,Contain,Remove and Mitigate Impacts of the Release: Impacted Media: Soil: Water: Air: Stormwater Sewer: Sanitary Sewer: (Check All That Dike/Berm: Oil-Water Separator: Other: Apply) Did Oil Reach a Waterway:Yes/ Quantity Released to Waterway: Waterway Name: No Number of Injuries: Number of Deaths: Was Evacuation Required: Yes/No Environmental Impacts: Was There Damage:Yes/No Damage Cost: $ Notification Person: Work Phone: Cell Phone Other(24-Hour) Any additional information about the incident that was not recorded elsewhere: Local Agency Notified: State Agency Contacted: Federal Agency Notified: State/Local Agency On-Scene: Other: APPENDIX F INSPECTION AND RECORDING FORMS ABOVEGROUND STORAGE TANK"MONTHLY"VISUAL INSPECTION FORM Facility Name/Address: High Sierra Water Services,C9 Saltwater Injection Facility W NW/4,Sec. Inspection Date: 13,T1ON,R61W Tanks Inspected(ID#'s): (1) Tank Containment Secondary containment system free of If"no,"describe and record action taken to correct problem and date done. tank product,water,debris and fire _No—Yes hazards? Secondary containment drain valve(s) _No Yes If"no,"describe and record action taken to correct problem and date done. operable and closed? N/A Containment entry/exit clear of If"no,"describe and record action taken to correct problem and date done. obstructions? No Yes _ (2) Leak Detection Visible leaks on tanks,tank seams, If"yes,"identify tank,describe,record corrective action taken,and date done. connections,fittings or valves? —No—Yes Visible leaks on aboveground pipes, If"yes,"describe,record corrective action taken and date done. fittings,flanges,pumps or valves? —No—Yes Concrete surfaces and ground free of If"no,"describe,record corrective action taken and date done. evidence of leakage or spillage? No Yes (3) Tank Components Ladder or platform structure secure If"no,"describe,record corrective action taken and date done. with no sign of severe corrosion or No Yes damage N/A Is tank gauge readable and in good If"no,"describe,have tank gauge calibrated and record date done. condition and do stick readings and No_Yes tank gauge readings match? Is overfill prevention equipment in If"no,"describe,record corrective action taken and date done. good operating condition? No_Yes Is audible/visual overfill alarm _No_Yes If"no,"describe,record corrective action taken and date done. operable? N/A Check tank openings:Are all openings If"no,"describe,seal openings and record date done. No Yes properly sealed — (4) Other Conditions Check tank for the presence of water at If"yes,"have water removed and record date done. lowest point: Is water present? No Yes If double-wall tank,check the If"yes,"describe,record corrective action taken and date done. interstitial space for liquid:Is liquid —No—Yes N/A present? If double-wall tank equipped with If"no,"describe,record corrective action taken and date done. interstitial monitoring equipment,is it No_Yes N/A operating properly? Are there other conditions that should If"yes,"describe,record corrective action taken and date done. be addressed for continued safe No Yes operation or that may affect the site — — SPCC plan'? Additional Comments: Inspector Name Signature Date ABOVEGROUND STORAGE TANK"ANNUAL"VISUAL INSPECTION FORM Page 1 of 2 Facility Name/Address: High Sierra Water Services,C9 Saltwater Injection Facility W'/:NW/4,Sec. Inspection Date: 13,T10N,R61W Tanks Inspected(ID#'s): Item Inspected Status Comments (1) Tank Containment Secondary containment structure If"no,"describe and record action taken to correct problem and date done. No Yes in satisfactory condition? — — Secondary containment drain If"no,"describe and record action taken to correct problem and date done. pipes and valves fit for _No—Yes N/A continued service? — (2) Tank Foundation and Supports Evidence of tank settlement or If"yes,"describe and record action taken to correct problem and date done. foundation washout? —No_Yes If"no,"describe and record action taken to correct problem and date done. Evidence of cracking or deterioration of the concrete pad No—Yes or tank foundation ring? Tank supports in satisfactory If"no,"describe and record action taken to correct problem and date done. condition? No_Yes Water able to drain away from If"no,"describe and record action taken to correct problem and date done. the tank? _No_Yes Grounding strap secured and in If"no,"describe and record action taken to correct problem and date done. good condition? No—Yes (3) Cathodic Protection Cathodic protection system _No_Yes Record rectifier reading if applicable: functional? —N/A (4) Tank External Coating Evidence of tank shell paint If"yes,"describe and record action taken to correct problem and date done. coating failure? _No_Yes (5) Tank Shell/Heads Noticeable tank shell/head If"yes,"describe and record action taken to correct problem and date done. distortions,buckling or bulging? —No—Yes Evidence of tank shell/head If"yes,"describe and record action taken to correct problem and date done. No Yes corrosion or cracking? — (6) Tank Manways,Piping and Equipment within Secondary Containment Flanged liquid level manway If"no,"describe and record action taken to correct problem and date done. bolts and seals tight,no signs of _No_Yes wear,corrosion of leakage? Flanged pipe connection bolts If"no,"describe and record action taken to correct problem and date done. and seals tight,no signs of wear, No—Yes corrosion or leakage? ABOVEGROUND STORAGE TANK"ANNUAL"VISUAL INSPECTION FORM Page 2 of 2 Item Inspected I Status I Comments (7) Tank Roof Standing water present on tank If"yes,"describe and record action taken to correct problem and date done. roof? —No—Yes Evidence of tank roof paint If"yes,"describe and record action taken to correct problem and date done. coating,cracking,pealing or _No—Yes blistering? Holes or other evidence of If"yes,"describe and record action taken to correct problem and date done. corrosion on roof? —No—Yes (8) Venting Normal and emergency vents If"no,"describe and record action taken to correct problem and date done. free of obstructions? _No_Yes Emergency vent operable and If"no,"describe and record action taken to correct problem and date done. lifts as required? No—Yes (9) Insulated Tanks If tank insulated,is insulation No_Yes If"yes,"describe and record action taken to correct problem and date done. missing or damaged? N/A Noticeable areas of moisture on _No_Yes If"yes,"describe and record action taken to correct problem and date done. the insulation? —N/A No_Yes If"yes,"describe and record action taken to correct problem and date done. Is there mold on the insulation? —N/A Is insulation sufficiently No_Yes If"no,"describe and record action taken to correct problem and date done. protected from water intrusion? N/A (10) Level and Overfill Prevention Instrumentation Has tank liquid level sensing If"yes,"record date done. device been tested to ensure No Yes If"no,"when will it be tested? proper operation? Does tank liquid level sensing If"no,"describe and record action taken to correct problem and date done. q No Yes device operate as required? — — Are overfill prevention devices If"no,"describe and record action taken to correct problem and date done. in proper working condition? No—Yes (11) Electrical Equipment Are tank grounding lines in If"no,"describe and record action taken to correct problem and date done. good condition? No_Yes Is electrical wiring for control If"no, describe and record action taken to correct problem and date done. boxes and lights in good —No—Yes condition? Additional Comments: Inspector Name Signature Date PORTABLE CONTAINER"MONTHLY"VISUAL INSPECTION FORM Facility Name/Address:High Sierra Water Services,C9 Saltwater Injection Facility W 1,4 NW/4,Sec. Inspection Date 13,TI0N,R61W Portable Container Area Inspected: Item Inspected Status Comments (1) Container Storage Area/Containment Containers are positioned within the No Yes designated storage area? — — Debris,spills or fire hazards present in No Yes the storage containment area? — — Is water present in outdoor storage _No_Yes containment area? _N/A Are dike drain valves operable and in a _No_Yes closed position? N/A Are storage area egress pathways clear and gates/doors operable? —No—Yes (2) Leak Detection Visible signs of leakage on or around the containers or on the floor of the No Yes storage area? (3) Container Condition Noticeable container distortions, No Yes buckling,denting or bulging? — — Are container openings properly sealed No Yes when not in use? I — — Comments: Inspector Name Signature Date APPENDIX G SPCC TRAINING SIGNOFF SHEET SPILL PREVENTION CONTROL AND COUNTERMEASURE PLAN SPILL PREPAREDNESS TRAINING COMPANY NAME: High Sierra Water Services,C9 Saltwater Injection Facility FACILITY ADDRESS: W 1/2 NW/4 Section 13,Ti ON, R61 W Grover,Colorado INSTRUCTOR: SUBJECT: SIGNATURES OFATTENDEES:Signature indicates awareness and understanding of the SPCC Plan and its contents. Signature Printed Name Date APPENDIX H SECONDARY CONTAINMENT VOLUME CALCULATIONS Above Ground Storage Tanks Secondary Containment Volume Calculations High Sierra Water Services, LLC C9 Facility W 1/2 NW/4 Section 13, T10N, R61W Grover, Colorado CGRS Project# 1-12462-14629aa High Sierra Water Services-C9 Saltwater Injection Facility 1. Volume of Largest Tank(cu.ft.) =Tank Volume x 0.1337cu. ft./gal. conversion factor 42,000 gals. x 0.1337 cu. ft./gal. = 5615.4 cubic feet 2. Total Diked Area Section 1 Section 1 Volume 27,000 cubic feet Enter Height 2 feet Enter Width 90 feet Enter Length 150 feet Total Volume 27,000 cubic feet = 201,987 gallons 3. Sump Volume Sump Sump Volume 750 cubic feet Enter Length 10 feet Enter Width 10 feet Enter Depth 7.5 feet Total Volume 750 cubic feet = 5,611 gallons 4. Base Area of Vertical Tanks (within the containment) Tank Sizes Size A Volume 452 cubic feet Size A (ASTs 10-01, 10-02, De-Sanding Tank) Enter Diameter 12 feet Enter Height 2 feet Quantity 2 each Size B Volume 755 cubic feet Size B (ASTs 20-01, 10-02, Oil Separation) Enter Diameter 15.5 feet Enter Height 2 feet Quantity 2 each Size C Volume 3,019 cubic feet Size C (ASTs 30-01 to 33-02, Water Equil.) Enter Diameter 15.5 feet Enter Height 2 feet Quantity 8 each Size D Volume 755 cubic feet Size D (ASTs 40-01, 40-02, Clean Tanks) Enter Diameter 15.5 feet Enter Height 2 feet Quantity 2 each Size E Volume 1,357 cubic feet Size E (ASTs 50-01, 50-07, Oil Storage) Enter Diameter 12 feet Enter Height 2 feet Quantity 6 each Above Ground Storage Tanks Secondary Containment Volume Calculations High Sierra Water Services, LLC C9 Facility W 1/2 NW/4 Section 13, T1 ON, R61W Grover, Colorado CGRS Project# 1-12462-14629aa Total Volume 6,338 cubic feet 47,416 gallons Above Ground Storage Tanks Secondary Containment Volume Calculations High Sierra Water Services, LLC C9 Facility W 1/2 NW/4 Section 13, T10N, R61W Grover, Colorado CGRS Project# 1-12462-14629aa 4. Available Diked Area = (Total Diked Area)— (Base Area of Tanks) = 27,750 - 6,338 = 21,412 cubic feet 160,182 gallons 5. Estimated Freeboard Allowance Section 1 Section 1 Volume 248 cubic feet Enter Height 0.4 feet Enter Width 10 feet Enter Length 62 feet Section 2 Section 2 Volume 2,756 cubic feet Enter Height 0.4 feet Enter Width 65 feet Enter Length 106 feet Total Freeboard 3,004 cubic feet = 22,473 gallons 6. Adjusted Available Diked Area = (Available Diked Area)—(Recommended Freeboard Allowance) = 21,412 - 3,004 = 18,408 cubic feet Available Volume in Diked Area = 137,709 gallons Note: Freeboard allowance is based on a historical 24-hour storm event for the region from the National Oceanic and Atmospheric Administration's(NOAA)Atlas 2,Volume Ill, Figure 31. Horizontally mounted tanks do not significantly impinge on available containment volumes. APPENDIX I SELF-DETERMINATION CRITERIA CERTIFICATION OF THE APPLICABILITY OF THE SUBSTANTIAL HARM CRITERIA CHECKLIST FACILITY NAME: High Sierra Water Services,C9 Saltwater Injection Facility FACILITY ADDRESS: W 1/2 NW/4 Section 13,TI0N,R61 W Grover,Colorado 1. Does the facility transfer oil over water to or from vessels and does the facility have a total oil storage capacity greater than or equal to 42,000 gallons? Yes No 0 2. Does the facility have a total oil storage capacity greater than or equal to 1 million gallons and does the facility lack secondary containment that is sufficiently large to contain the capacity of the largest aboveground oil storage tank plus sufficient freeboard to allow for precipitation within any aboveground oil storage tank area? Yes No 0 3. Does the facility have a total oil storage capacity greater than or equal to 1 million gallons and is the facility located at a distance(as calculated using the appropriate formula in Attachment C-III or a comparable formula') such that a discharge from the facility could cause injury to fish and wildlife and sensitive environments? For further description of fish and wildlife and sensitive environments, see Appendices I, II, and III to DOC/NOAA's "Guidance for Facility and Vessel Response Plans: Fish and Wildlife and Sensitive Environments"(see Appendix E,section 13,for availability)and the applicable Area Contingency Plan. Yes No 0 4. Does the facility have a total oil storage capacity greater than or equal to 1 million gallons and is the facility located at a distance(as calculated using the appropriate formula in Attachment C-III or a comparable formula') such that a discharge from the facility would shut down a public drinking water intake'? Yes No 0 5. Does the facility have a total oil storage capacity greater than or equal to 1 million gallons and has the facility experienced a reportable oil discharge in an amount greater than or equal to 10,000 gallons within the last 5 years? Yes No 0 CERTIFICATION I certify under penalty of law that I have personally examined and am familiar with the information submitted in this document,and that based on my inquiry of those individuals responsible for obtaining this information,I believe that the submitted information is true,accurate,and complete. Mr.Josh Patterson Name(please type or print) Signature VP Operations Title Date Form 40 CFR 112 Appendix C,Attachment C-II WERNSMAN ENGINEERING, INC. 1011 42nd STREET • EVANS, CO 80620 Phone (970) 353-4463 Fax (970) 353-9257 July 22, 2014 Ms. Jen Petrik Drainage Engineer Weld County Public Works P.O. Box 758 Greeley CO 80632 RE: Drainage letter for High Sierra's C9 facility on CR 95 near Grover CO Dear Ms. Petrik: This letter addresses the Water Quality Capture Volume (WQCV) requirements and existing and proposed drainage ways on the site The storm-water historically enters the site from the north-east and drains across the site to the south west. The proposed plan will collect on site flows and direct them around the proposed improvements to the water quality pond in the south west corner of the site. When the water quality pond reaches capacity at elevation 5046 storm-water will flow to the south as sheet flow. Storm water will travel approximately 435 feet south on the lot to further dissipate flows before they travel onto the neighboring property to the south. The proposed conditions imperviousness (including all future buildings but excluding the concrete containment areas that will retain storm water) is 10. The WQCV required for the site is 6263 cubic feet. The pond as shown on the grading plan provides approximately 9995 cubic feet of storage. If you have any further questions or comments regarding this matter, please contact this office. Sincerely, Eric Wernsman P.E. Total Site Imperviousness Calculations ENTIRE SITE AREAS C VALUE CXA C100 value C100 X A I VALUE I X A NEW BUILDING(s) 38350 0.73 27995.5 0.81 31063.5 90 3451500 CONCRETE/ASPHALT 17307 0.8 13845.6 0.96 16614.72 100 1730700 GRAVEL 105,968 0.65 68879.2 0 0 40 4238720 LANDSCAPE 927375 0.08 74190 0.35 324581.25 2 1854750 TOTAL 1089000 184910.3 372259.47 11275670 COMP C5= 0.17ICOMP C 100= 0.34= 10 ACRES(approx) 25 WOCV Calculations WOCV= a(0.91*I^3-1.199^2+0.78'1) a=1 for 40 hr drain time I=0.04 WOCV= 0.06901472 Volume req'd= WOCV*A a= 25 12 Volume req'd= 0.144 acre feet Volume req'd= 6263.086 cu ft STORAGE CALCULATIONS CONTOUR ELEVATIONS AREA DEPTH AVG AREA Volume Provided 5044.9 0 0.1 172 17.2 5045 344 1 9978 9978 5046 19612 TOTAL VOLUME OF 9995.2 C.F.PROVIDED (lciR H—Oo-70 7l WERNSMAN ';;h:.- $ ENGINEERING, INC. 1011 42nd STREET • EVANS, CO 80620 Phone (970) 353-4463 Fax (970) 353-9257 October 16, 2014 Ms.Jen Petrik Drainage Engineer Weld County Public Works P.O. Box 758 Greeley CO 80632 RE: Drainage letter for High Sierra's C9 facility on CR 95 near Grover CO Dear Ms. Petrik: This letter addresses the Water Quality Capture Volume (WQCV) requirements and existing and proposed drainage ways on the site The storm-water historically enters the site from the north-east and drains across the site to the south west. The proposed plan will collect on site flows and direct them around the proposed improvements to the water quality pond in the south west corner of the site. When the water quality pond reaches capacity at elevation 5046 storm-water will flow to the south as sheet flow. Storm water will travel approximately 435 feet south on the lot to further dissipate flows before they travel onto the neighboring property to the south. The proposed conditions imperviousness (including all future buildings but excluding the concrete containment areas that will retain storm water) is 10. The WQCV required for the site is 6124 cubic feet.The pond as shown on the grading plan provides approximately 25,910 cubic feet of storage. If you have any further questions or comments regarding this matter, please contact this office. Sincerely, ,/ f 2--- s--1.j Eric Wernsman P.E. Total Site Imperviousness Calculations ENURE SITE AREAS CVALUE CM C100 value C100XA IVALUE IXA NEW BUILDING(s) 38350 0.73 27995.5 0.81 31063.5 90 3451500 CONCRETE/ASPHALT(DOES NOT 17307 0.8 13845.6 0.96 16614.72 100 1730700 INCLUDE CONC CONTAINMENT GRAVEL 98,232 0.65 63850.8 0 0 40 3929280 LANDSCAPE 935111 0.08 74808.88 0.35 327288.85 2 1870222 TOTAL 1089000 180500.8 374967.07 10961702 COMP C5= 0.17ICOMP C 100= 0.3411= 10 ACRES(approx) 25 WQCV Calculations WQCV= a(0.919"3-1.199"2+0.789) a=1 for 40 hr drain time I=0.1 WQCV 0.08746874 Volumereq'd= WOCV•A a= 25 12 Volume req'd= 0.141 acre feet Volume req'd= 6124.603 cu ft STORAGE CALCULATIONS CONTOUR ELEVATIONS AREA DEPTH AVG AREA Volume Provided 5044 0 1 6605 6605 5045 13210 1 19305 19305 5048 25400 TOTAL VOLUME OF 25910 C.F.PROVIDED C( ENVIRONMENTAL NEV0CM S July 11,2014 Mr. Nick Valencia M3 Construction 2681 W. 120`"Ave, Ste. 250 Westminster,CO 80234 Via email;nvalencia4M3-consult.com Subject: Site Groundwater Monitoring Plan High Sierra Water Services: C9 Saltwater Disposal Facility 57748 WCR 95 Grover, Colorado SE1/4,SE1/4,Sec. 23,T12N,R61W CGRS Project No. 1-12462-14629ab Dear Mr. Valencia: This correspondence summarizes the water quality monitoring program and proposed groundwater monitoring well installation located at the above-referenced treatment and disposal facility. The well installation and baseline soil and groundwater quality sampling activities will be scheduled after basic site infrastructure has been constructed. A site location map is included as Figure I, and a proposed site conditions map illustrating the anticipated monitoring well locations is included as Figure 2. The Groundwater Monitoring Plan provides baseline groundwater quality data,which will facilitate early detection of an unknown subsurface release of exploration and production fluids related to facility processing activities. In addition to groundwater sampling, depth to groundwater will be measured in each monitoring well and the groundwater elevation, flow direction,and hydraulic gradient will be calculated using surveyed well elevations in order to monitor groundwater flow trends. Water quality samples will be collected and analyzed for constituents associated with oil and gas exploration and production activity. Water quality sampling activities for the High Sierra Water Services, C9 Saltwater Disposal facility will be performed on a quarterly basis. Water quality samples will be submitted to a contract laboratory for analysis of benzene,toluene, ethylbenzene, and xylenes (BTEX),total dissolved solids (TDS),and chlorides. A full description of CGRS' Methods and Procedures for field and reporting activities are provided in Attachment A. Four permanent groundwater monitoring wells (MW-I through MW-4) will be installed up-gradient, down-gradient and/or adjacent to facility operation areas (Figure 2). The proposed monitoring wells will be installed to a depth of approximately 30 feet below ground surface (bgs). The wells will be constructed with approximately 25 feet of 2-inch diameter, 10-slot PVC screen and approximately 5 feet of solid PVC riser. 10/20 silica sand will be applied around the screened portion of the wells to a depth of approximately 2 feet above the well screen, at which point the well borings will be sealed with a hydrated bentonite/grout mixture to the surface. In the case where water is encountered at shallower or deeper depths, the wells will be advanced at least ten feet into the groundwater table and the screened interval will be adjusted accordingly. Monitoring wells will be finished with locking j-plug well seals and either 4-inch square aluminum stick-up mounts or flush-mounted traffic rated manways. Pertinent information, such as soil sample descriptions of color,texture,consistency, moisture content,and soil vapor readings along with well construction details of each monitoring well will be provided in the associated quarterly groundwater monitoring report. CGRS will begin quarterly groundwater monitoring prior to when the facility commences full-scale operation in order to obtain adequate baseline water quality samples. It should be noted that after the installation of groundwater monitoring wells, and after site construction has been completed, a revised monitoring plan will be submitted (as applicable) to document any updated site conditions. 1301 Academy Court Fort Collins, CO 80524 T 800-288-2657 F 970-493-7986 www.cgrs.com Site Groundwater Monitoring Plan High Sierra Water Services:C9 Saltwater Disposal Facility 57748 Weld County Road 95 Grover,Weld County,Colorado SFI/4,SFI/4,Sec.23,112N,Rt,I W Should you have any questions or require additional information,please call Ms. Kelly Sutton at(800)288-2657. Sincerely, CGRS, Inc., (tak Kelly Sutton Project Manager/Scientist Reviewed By: Kenneth M. Rogowski Project Manager/Scientist Enclosures: Figure 1 —Site Location map Figure 2—Proposed Site Conditions Map Attachment A: CGRS' Field and Reporting Methods and Procedures - I 5 14 _ 13 1 ç • • Ihrta LW 23 ' 24 I } v � \ V ,/ saa ' srJs ,J 24 sin i ../ 23 \ PIPE .. - y SITE ✓ ,- LOCATION • SlM __ -12.5< .�� - Wit- - '3i% \ 1 . \ \ \-/ Well • 2 5 27 26 \l STJJ 11 • 6108 • • slJO VI", ,ul< ■ FIGURE 1 SITE LOCATION MAP HIGH SIERRA WATER SERVICES C9 FACILITY COLORADO SE 1/4,SE 1/4,Sec.23,TI2N,R61 W GROVER,COLORADO PROJECT. DRAFT:0 7000 2000 1-12462-14629ab MSP CG`v °la MBT°L cowsrwcnoN ■ QUADRANGLE LOCATION SCALE IN FEET DATE: REVIEW'. COMM.LNC! 7/10/2014 GRAVEL DRIVEWAY GRAVEL K67 CONTAINMENT WALL\ O N. > 0 1 2 w FUTURE 3 4 20 2 o TANKS 5 6 19 8 18 70 17 BUILDING 9 10 16 MAP SIZE TANK SUMP-, 11 12 15 ID (BBLS) ID 13 14 1 1000 T-40-02 n 2 1000 T-40-01 ELECTRICAL) 3 840 T-33-02 DRIVEWAY GRAVEL TRANSFORMER 4 840 T-33-01 5 840 T-32-02 __ 6 840 T-32-01 ' 7 840 T-31-02 ❑ 8 840 T-31-01 DRAIN GRAVEL 9 840 T-30-02 10 840 T-30-01 ❑ 11 1000 T-20-02 12 1000 T-20-01 ‘ 13 700 T-10-02 ❑ 14 700 T-10-01 15 400 T-50-01 16 400 T-50-02 �.ed 17 400 T-50-03 , CONCRETE 18 400 T-50-04 -UNLOADING 19 400 T-50-05 PAD 20 400 T-50-06 21 400 T-50-07 LEGEND FIGURE 2 SITE CONDITIONS MAP PROPOSED MONITORING WELL LOCATION HIGH SIERRA WATER SERVICES C9 FACILITY SE 1/4,SE 1/4,Sec.23,T12N,R61W GROVER,COLORADO PROJECT: DRAFT:0 20 a0 60 80 l00 1-12462-14629th MSP CG ENVIRONMENTAL OONEEWCTION DATE'. REVIEW: COMPLIANCE SCALE IN FEET 7/10/2014 ATTACHMENT A CGRS' Field and Reporting Methods and Procedures CGRS, INC. High Sierra Water Services—C9 Saltwater Disposal Facility METHODS AND PROCEDURES High Sierra Water Services, C9 Saltater Disposal Facility w SEl/4,SEl/4,Sec. 23,T12N,R61 W 57748 WCR 95 Grover,Colorado CGRS Project# 1-12462-14629ab Soil Borings Soil sampling will be conducted in accordance with ASTM:D 1586-08a. Using this procedure, a 2-inch O.D. split-spoon sampler will be driven into the soil by a 140-pound weight falling 30 inches. After an initial set of 6 inches, the number of blows required to drive the sample an additional 12 inches, known as the penetration resistance (N value), will be recorded. The N value is an index of the relative density of cohesionless soils and the consistency of cohesive soils. Soil Classification/Characterization As samples are obtained in the field, they will be visually inspected and classified in accordance with ASTM:D 1488-84. Representative portions of the samples will then be retained for further examination and for verification of the various strata, the N value, water level data, and pertinent information regarding the method of maintaining and advancing the boring will be provided. Charts illustrating the soil classification procedure, descriptive terminology, and symbols used on the logs will be provided. As samples are collected, they will be examined for evidence of petroleum hydrocarbons using visual appearance and by screening with portable photoionization detection equipment. Decontamination To avoid potential transport of contaminated materials to the project site, all drilling equipment and down- hole tools will be steam cleaned prior to mobilization. To prevent cross contamination between soil borings or monitoring wells, all down-hole equipment will also be steam cleaned and rinsed with water between soil borings. Monitoring Well Construction Monitoring wells will be installed utilizing the following general construction criteria: borehole diameter: minimum 2.0 inches push probe/6.25 inches conventional boring P1 well diameter: I inch for push probe/2 inches for conventional boring U estimated depth: ≥ 5 feet below static groundwater table U casing material: schedule 40,flush thread PVC -a- CGRS, INC. High Sierra Water Services—C9 Saltwater Disposal Facility ▪ well screen: 1 inch inside diameter (I.D.) for push probe / 2 inch I.D. for conventional boring, #0.01 slot PVC ▪ estimated screened interval: 10 feet above and 10 feet below the groundwater table (may be adjusted based on total depth and water table position) L annular pack: 10-20 silica sand E protective casing: 4"aluminum above grade mount, locking cap; or 8" steel flush mount traffic rated manway. ❑ annular seal: cement grout and bentonite pellets. Groundwater Sampling All borings where groundwater is encountered will be sampled from the suspected cleanest to the most contaminated according to the protocols listed below. AU pertinent information will be recorded on a sampling information form. Field Protocol Step I -Measure water level. Step 2 - A dedicated polyethylene bailer will be used to develop each well. Three bore volumes will be evacuated from each well prior to sampling. Step 3 -Collect water samples. Water samples will be collected using a polyethylene bailer. Step 4 - Store samples in a cooler on ice (-4° Celsius) for transport to the laboratory. Follow all documentation and chain-of-custody procedures. Step 5 - Clean equipment. Water level measurement equipment will be cleaned with ethanol followed by a distilled water rinse. Upon completion of soil or groundwater sampling, a chain of custody log will be initiated. A copy of the chain of custody will be returned to the project manager. Chemical Analysis An approved contract laboratory will provide stationary laboratory analysis. The following analyses will be performed: Soil Analyses: Initial well installation Chemical Parameters Method Used Benzene/Toluene/Ethylbenzene/Total Xylenes (BTEX) EPA -8260 B -b- CGRS, INC. High Sierra Water Services—C9 Saltwater Disposal Facility Soil Analyses: Initial well installation (Continued) Chemical Parameters Method Used Total Volatile Petroleum Hydrocarbons EPA—8260B Water Analyses (Quarterly Groundwater Sampling) Chemical Parameters Method Used Benzene/Toluene/Ethylbenzene/Total Xylenes (BTEX) EPA-8260 B Total Dissolved Solids(TDS) EPA- 160.1 Chlorides EPA -300.1 Groundwater Trend Analyses Groundwater concentrations are measured in site monitoring wells on a quarterly basis. Upon receiving groundwater analytical data from the laboratory the data is inserted into an historic groundwater analytical data table. Chlorides and sulfates concentrations will be evaluated to ensure that the current concentrations in each well do not exceed 1.25 times the average background conditions. If results indicate that this threshold is exceeded, then further analyses or investigation will be conducted. Any BTEX constituents discovered in a monitoring well water quality sample, which are above the Colorado Oil and Gas Conservation Commission (COGCC) levels, will be reanalyzed at the laboratory. The presence of BTEX will prompt a complete evaluation of site operations since the last sampling event, and prompt further subsurface investigation if warranted. Groundwater Elevation Measurements The following outlines our standard groundwater quality sampling methodology. Before purging any of the soil test borings or monitoring wells,water level measurements must be taken. Measuring Point Establish the measuring point for the well. The measuring point is marked on the north side of the top of the monitoring well riser. The top of the riser is normally a 2-inch schedule 40 PVC casing inside a locked protective casing. The measuring point should be described on the groundwater sample collection record. -c- CGRS, INC. High Sierra Water Services—C9 Saltwater Disposal Facility Access After unlocking or opening a monitoring well, the first task will be to obtain a water level measurement. Water level measurements will be made using an electronic water level indicator. Depth to water and total depth of the well will be measured for calculation of purge volume. Measurement To obtain a water level measurement, lower a decontaminated electronic water level probe into the monitoring well. Care must be taken to assure that the electronic probe hangs freely in the monitoring well and is not adhering to the well casing. The electronic probe will be lowered into the well until the audible sound of the unit is detected and the light on the electronic sounder illuminates. At this time, the precise measurement should be determined by repeatedly raising and lowering the probe to obtain an exact measurement. The water level measurement is then entered on the groundwater sampling collection record sheet or groundwater level data sheet to the nearest 0.01 feet. Decontamination The electronic probe shall be decontaminated immediately after use by wiping with isopropyl alcohol- soaked paper towels and rinsed with distilled water. Always proceed in order from the suspected cleanest well or soil test boring to the suspected most contaminated one. Purge Volume Computation All soil test borings, monitoring wells, and temporary monitoring wells will be purged prior to sample collection. Depending upon the rate of recovery, three to five volumes of groundwater present in a well or borehole shall be withdrawn prior to sample collection. If a well or borehole bails dry, the well or borehole should be allowed to recharge and a sample taken as soon as there is sufficient volume for the intended analysis. The volume of water present in each well or borehole shall be computed using the two measurable variables;length of water column in soil boring or monitoring well depth and diameter. Purging and Sample Collection Procedures Bailinn J Obtain a laboratory decontaminated disposable bailer and a spool of nylon rope or equivalent bailer cord. Tie a bowline knot or equivalent through the bailer loop. Test the knot for adequacy by creating tension between the line and the bailer. Tie again if needed. New rope and bailer will be used for every sample or purge event. New clean latex gloves will be used when touching the rope or bailer. -d- CGRS, INC. High Sierra Water Services—C9 Saltwater Disposal Facility o Spread a clean plastic sheet near the base of the well. The plastic sheet should be of sufficient size to prevent bailer or bailer rope from contacting the ground surface. L Place the bailer inside the well to verify that an adequate annulus is present between the bailer and the well casing to allow free movement of the bailer. ❑ Lower the bailer carefully into the well casing to remove the sample from the top of the water column,taking care not to agitate the water in the well. ❑ Pour the bailed groundwater into a bucket. Once the bucket is full,transfer the water to a barrel and contain on-site. ❑ Raise the bailer by grasping a section of cord, using each hand alternately. This bailer lift method will assure that the bailer cord will not come into contact with the ground or other potentially contaminated surfaces. Sampling o Instructions for obtaining samples for parameters are reviewed with the laboratory coordinator to insure that proper preservation and filtering requirements are met. L Appropriate sample containers will be obtained from the contract laboratory for each individual analyses requested. After samples are collected, they will be put on ice in coolers (4°C). Care will be taken to prevent breakage during transportation or shipment. I I Samples collected by bailing will be poured directly into sample containers from bailers. The sample should be poured slowly to minimize air entrapment into the sample bottle. During collection, bailers will not be allowed to contact the sample containers. I I Upon completion of sampling a chain-of-custody log will be initiated. Chain-of-custody records will include the following information: project name and number,shipped by, shipped sampling point, location, field ID number, date, time, sample type, number of containers, analysis required, and sampler's signature. The samples and chain-of-custody will be delivered to the laboratory. Upon arrival at the laboratory,the appropriate laboratory personnel will check in the samples. Laboratory identification numbers will be noted on the chain-of-custody record. Upon completion of the laboratory analysis,the completed chain-of-custody record will be returned to the project manager. Field Cleaning Procedures For all equipment to be reused in the field,the following cleaning procedures must be followed: -e- CGRS, INC. High Sierra Water Services—C9 Saltwater Disposal Facility o Disassemble the equipment to the extent practical. E Wash the equipment with distilled water and laboratory-grade detergent. ▪ Rinse with distilled water until all detergent is removed. ❑ Rinse the equipment with isopropyl alcohol, making sure all surfaces (inside and out) are rinsed. ❑ Triple rinse the equipment with distilled water. Laboratory Selection The project manager should consider the following factors when selecting a laboratory: ❑ Capabilities (facilities,personnel, instrumentation), including: ▪ Participation in inter-laboratory studies (e.g. EPA or other Federal or State agency sponsored analytical programs); ❑ Certifications(e.g. Federal or State); o References(e.g. other clients); and o Experience(UST, RCRA and other environmentally related projects). ❑ Service ❑ Turnaround time; and ❑ Technical input(e.g. recommendations on analytical procedures). The project manager is encouraged to gather pertinent laboratory-selection information prior to extensively defining analytical requirements under the project. A request may be made to a laboratory to provide a qualifications package that should address the points listed above. Once the project manager has reviewed the various laboratory qualifications, further specific discussions with the laboratory or laboratories should take place. In addition, more than one laboratory should be considered. For large-scale investigations, selection of one laboratory as a primary candidate and one or two laboratories as fall-back candidates should be considered. The quality of the laboratory service provided is dependent on various factors. The project manager should be able to control the quality of the information (e.g. samples) provided to the laboratory. It is extremely important that the project manager communicate to the laboratory all the requirements relevant to the project. This includes the number of samples and their matrices, sampling schedule, parameters and constituents of interest, required analytical methodologies, detection limits, holding times, deliverables, level of QA/QC, and required turnaround of analytical results. -f- CGRS, INC. High Sierra Water Services—C9 Saltwater Disposal Facility Field and Laboratory Quality Control General Quality control checks are performed to ensure that the data collected is representative and valid data. Quality control checks are the mechanisms whereby the components of QA objectives are monitored. Examples of items to be considered are as follows: I. Field Activities: ❑ Use of standardized checklists and field notebooks; L Verification of checklist information by an independent person; L Strict adherence to chain-of-custody procedures; L Calibration of field devices; ❑ Collection of replicate samples where applicable; and IL Submission of field blanks,where appropriate. 2. Analytical Activities: ❑ Method blanks; L Laboratory control samples: ❑ Calibration check samples; ❑ replicate samples; ❑ Matrix-spiked samples; ❑ "Blind"quality control samplers; ❑ Control charts; Surrogate samples; 1 Zero and span gases; and 1 Reagent quality control checks. Management of Waste Material During the advancement of soil borings, decontamination of field equipment and development of soil borings or temporary monitoring wells, waste materials will be generated. This section addresses both the management of solid waste(soils)and the liquid wastes generated. Soil generated during remedial activities will be containerized in 55-gallon drums or stockpiled on an impermeable membrane and covered with plastic,which ever is most appropriate. The waste characteristics of the soil will be determined by appropriate analytical methods and the soil disposed of in accordance with -g- CGRS, INC. High Sierra Water Services—C9 Saltwater Disposal Facility state and federal regulations. Water generated during field activities will be containerized in storage vessels that are compatible with the suspected or identified contaminant(s). If required, the water will be analyzed by appropriate analytical methods to determine its waste characteristics. If a water treatment system is available, wastewater will be treated on-site, thus eliminating the need for disposal. A portable aeration system can also be utilized to eliminate volatile contaminants in wastewater. In any event, the ultimate disposition of water will be in accordance with all applicable regulations. Reporting After data has been compiled and analyzed, CGRS submits a summary report to High Sierra Water Services and M3 Construction,LLC at the following address: M3 Construction, LLC 2681 W. 120` Ave, Ste#250 Westminster, CO 80234 Furthermore,CGRS submits an electronic copy to the following recipients and email addresses: Mr. Nick Valencia; M3 Construction, LLC; nvalcnciWa M3-consult.com Additional reports may be submitted upon the request of, or permission from, High Sierra Water Services. This includes the anticipated submittal of quarterly reports to the Weld County Department of Public Health and Environment. -h- Material Safety Data Sheets • Aries Chemical Incorperated: Aries 14065 • Chevron: Way Vistac ISO 68 Oil • Multi-Chem: EB-1595 Emulsion Breaker • Tesoro Crude Oil • Pro Treat: Wt-990 Corrosion Inhibitor • Petro-Canada: Diesel Fuel • Thatcher Company: Hydrochloric Acid • Valero Unleaded Gasoline • Wolf's Head Oil Company: Gear Oil ARIES CHEMICAL INCORPORATED 6604 DEPOT ST., P.O. BOX 519 BEAVER FALLS, NEW YORK 13305 315-346-1489 FAX:315-346-1658 Origination Date: 10-05-11 Revision Date: 14065 SECTION I - GENERAL INFORMATION TRADE NAME: EMERGENCY PHONE NO: Aries 14065 INFOTRAC (800) 535-5053 CHEMICAL NAME: DISTRIBUTOR'S D-U-N-S NO: N/A 14-861-3045 HAZARDOUS MATERIAL DESCRIPTION: UN1993, Flammable liquids, n.o.s. (2-BUTOXYETHANOL), 3, III EMERGENCY RESPONSE GUIDE #: 128 REPORTABLE QUANTITY: Methanol; 5,000 lbs. SYNONYMS: FORMULA: N/A Mixture CHEMICAL FAMILY: MOLECULAR WEIGHT: N/A N/A SECTION 2 - HAZARDOUS INGREDIENTS TWA INGREDIENTS % BY WT. CAS NO. OSHA ACGIH 2-Butoxyethanol 5 -10 111-76-2 Ethoxylated Nonylphenol 40 -70 68412-54-4 Methanol 30 -60 67-56-1 All components are listed on the TSCA(Toxic Substances Control Act) Inventory or are not required to be listed on the TSCA inventory. HAZARD HEALTH 2 REACTIVITY 0 RATING FIRE 2 SPECIAL 14065 Page 2 SECTION 3 - PHYSICAL AND CHEMICAL PROPERTIES SPECIFIC GRAVITY: pH: BOILING POINT: 1.001 4- 7 147-340 °F (63.9-171.1 °C) SOLUBILITY IN WATER: VAPOR PRESSURE: Miscible N/A PERCENT VOLATILE BY VOLUME: EVAPORATION RATE: N/A N/A APPEARANCE AND ODOR: Opaque, colorless - light yellow liquid with alcohol odor. SECTION 4 - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: FLAMMABLE LIMITS: 104 ° F (40 °C) LEL: N/A UEL: NI A AUTO IGNITION TEMPERATURE: 262.4 °F (128 °C) estimated EXTINGUISHING MEDIA: Water fog,foam, dry chemical, carbon dioxide. SPECIAL FIRE FIGHTING PROCEDURES: Flammable by OSHA criteria. Containers may explode when heated. In the event of fire and/or explosion do not breathe fumes. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. ALWAYS stay away from tanks engulfed in flame. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Withdraw immediately in case of rising sound from venting safety devices or any discoloration of tanks due to fire. Move containers from fire area if you can do it without risk. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. UNUSUAL FIRE AND EXPLOSION HAZARDS: Fire may produce irritating, corrosive and/or toxic gases. 14065 Page 3 SECTION 5 - HEALTH HAZARD DATA EFFECTS OF EXPOSURE: WARNING! Flammable liquid and vapor. Will be easily ignited by heat, spark or flames. Containers may explode when heated. Harmful if swallowed, inhaled or absorbed through skin. Components of the product may be absorbed into the body by inhalation, ingestion and through the skin. Prolonged exposure may cause chronic effects. Routes of exposure: Inhalation. Skin contact. Ingestion. Central nervous system. Eyes. Gastrointestinal tract. Blood. Kidney. Liver. Lungs. Respiratory system. Skin. 2- Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged and may cause blood damage. These effects have not been observed in humans. Chronic effects This product may be harmful if it is absorbed through the skin. Unconsciousness. Shortness of breath. Liver injury may occur. Kidney injury may occur. May cause delayed lung damage. May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Signs and symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Unconsciousness. Discomfort in the chest. Shortness of breath. Narcosis. Decrease in motor functions, Behavioral changes. Cough. Liver enlargement. Defatting of the skin. Rash. Irritation. INGESTION: This product may be harmful or fatal if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. This product may cause blindness if it is swallowed. May cause delayed lung damage. Components of the product may be absorbed into the body by ingestion. Do not ingest. Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Get medical attention immediately. SKIN CONTACT: Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Allergic reactions are possible. This product may be harmful if it is absorbed through the skin. Avoid contact with the skin. Wash off with warm water and soap. Remove and isolate contaminated clothing and shoes. Get medical attention if irritation develops or persists. For minor skin contact, avoid spreading material on unaffected skin. Wash clothing separately before reuse. EYE CONTACT: Liquid, aerosols and vapors of this product are irritating and can cause pain, tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes. Avoid contact with eyes. Immediately flush eyes with plenty of water for at least 15 minutes. If a contact lense is present, DO NOT delay irrigation or attempt to remove the lens. Get medical attention immediately. INHALATION: This product may be fatal if it is inhaled. May cause irritation of respiratory tract. Do not breathe dust/fume/gas/mist/vapors/spray. Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention immediately. NOTE TO PHYSICIAN: In case of shortness of breath, give oxygen. Keep victim warm. Symptoms may be delayed. OTHER: Take off contaminated clothing and shoes immediately. In case of shortness of breath, give oxygen. Keep victim warm. Call a physician if symptoms develop or persist. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. 14065 Page 4 TOXICOLOGICAL INFORMATION: Acute effects: Acute LD50: 13682 mg/kg estimated, Rat, Oral ; Acute LD50:24496 mg/kg;estimated, Rat, Dermal Acute LC50: 325 mg/I/4H estimated; Rat, Inhalation Component analysis—LD5O: Toxicology Data-Selected LD5Os and LC5Os: 2-Butoxyethanol- CAS# 111-76-2: Inhalation LC50 Rat: 2.21 mg/I/4H; Inhalation LC50 Rat: 450 ppm/4H; Oral LD50 Rat:470 mg/kg; Dermal LD50Rat:2270 mg/kg; Dermal LD50 Rabbit:220 mg/kg Methanol 67-56-1 Inhalation LC50 Rat: 83.2 mg/L/4H; Inhalation LC50 Rat: 64000 ppm/4H; Oral LD50 Rat:5628 mg/kg; Dermal LD50 Rabbit:15800 mg/kg Sensitization Not expected to be hazardous by OSHA criteria. Local effects Contact with eyes may cause irritation. Liver toxicity. Blood disorder may occur after ingestion.Components of the product may be absorbed into the body through the skin. Chronic effects: Hazardous by OSHA criteria. This product may be harmful if it is absorbed through the skin. Repeated absorption may cause disorder of central nervous system, liver, kidneys and blood. Prolonged or repeated exposure may cause lung injury. Prolonged exposure may cause chronic effects. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Subchronic effects: Kidney injury may occur. Blood disorder may occur after ingestion. Blood disorder may occur after prolonged inhalation. Blood disorder may occur after prolonged skin contact. Carcinogenicity Confirmed animal carcinogen with unknown relevance to humans. ACGIH -Threshold Limit Values -Carcinogens 2-Butoxyethanol 111-76-2 A3 -Confirmed animal carcinogen with unknown relevance to humans. Neurological effects Hazardous by OSHA criteria. Epidemiology Hazardous by OSHA criteria. Further information: Symptoms may be delayed. CARCINOGENICITY: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. SECTION 6 - REACTIVITY DATA STABILITY: HAZARDOUS POLYMERIZATION: Stable Will not occur CONDITIONS TO AVOID: Avoid temperature extremes, heat, flames and sparks. MATERIALS TO AVOID: Strong acids and strong oxidizing agents. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Does not occur. 14065 Page 5 SECTION 7 - SPILL OR LEAK PROCEDURE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Local authorities should be advised if significant spillages cannot be contained. Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering. Keep out of low areas. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Dike the spilled material, where this is possible. Prevent entry into waterways, sewers, basements or confined areas. Clean up in accordance with all applicable regulations. Should not be released into the environment. Large Spills: Dike far ahead of liquid spill for later disposal. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Small Spills: Wipe up with absorbent material(e.g. cloth,fleece). Clean contaminated surface thoroughly. WASTE DISPOSAL METHODS: Never return spills in original containers for re-use. Clean up in accordance with all applicable regulations. ENVIRONMENTAL TOXICITY DATA: Ecotoxicity: LC50 23541 mg/L estimated, Fish,96.00 Hours,Components of this product have been identified as having potential environmental concerns. Ecotoxicity-Freshwater Fish Species 111-76-2 96 Hr LC50 Lepomis macrochirus: 1490 mg/L[static] Data 2-Butoxyethanol Methanol 67-56-1 96 Hr LC50 Pimephales promelas: 28100 mg/L[flow-through]; 96 Hr LC50 Oncorhynchus mykiss: 13200 mg/L Ecotoxicity-Microtox Data 5 min EC50 Photobacterium phosphoreum:43000 mg/L; 15 min EC50 Methanol 67-56-1 Photobacteriur; phosphoreum:40000 mg/L; 25 min EC50 Photobacterium phosphoreum: 39000 mg/I Ecotoxicity Water Flea Data 2-Butoxyethanol 111-76-2 24 Hr EC50 water flea: 1720 mg/L; 24 Hr LC50 Daphnia magna: 1698-1940 mg/L Environmental effects Harmful to aquatic life. 2-Butoxyethanol CAS#111-76-2 96 Hr LC50 Lepomis macrochirus: 1490 mg/L[static] Methanol CAS#67-56-1 96 Hr LC50 Pimephales promelas: 28100 mg/L[flow-through]; 96 Hr LC50 Oncorhynchus mykiss: 13200 mg/L Ecotoxicity-Microtox Data Methanol CAS#67-56-1 5 min EC50 Photobacterium phosphoreum:43000 mg/L; 15 min EC50 Photobacteriur phosphoreum: 40000 mg/L;25 min EC50 Photobacterium phosphoreum:39000 mg/L Ecotoxicity-Water Flea Data 2-Butoxyethanol CAS#111-76-2 24 Hr EC50 water flea: 1720 mg/L;24 Hr LC50 Daphnia magna: 1698-1940 mg/L HAZARDOUS WASTE 40CFR261: U.S. -RCRA (Resource Conservation & Recovery Act) -U Series Wastes -Acutely Toxic Wastes & Other Hazardous Characteristics: Methanol 67-56-1 waste number U154 (Ignitable waste) Disposal instructions If discarded, this product is considered a RCRA ignitable waste, 0001. Do not allow this material to drain into sewers/water supplies. Dispose in accordance with all applicable regulations. HAZARDOUS WASTE NO: D001: Waste Flammable material with a flash point<140 F. 14065 Page 6 SECTION 8 - SPECIAL PROTECTIVE EQUIPMENT Exposure limits ACGIH COMPONENTS CAS# TWA STEL Ceiling Methanol 67-56-1 200 ppm 250 ppm Not established 2-Butoxyethanol 111-76-2 20 ppm Not established Not established OSHA COMPONENTS CAS# TWA STEL Ceiling Methanol 67-56-1 200 ppm Not established Not established 2-Butoxyethanol 111-76-2 50 ppm Not established Not established RESPIRATORY PROTECTION: Ensure adequate ventilation, especially in confined areas. EYE PROTECTION: Safety glasses with side-shields. Wear chemical goggles. PROTECTION CLOTHING: Protective gloves. Wear suitable protective clothing. Closed-toe shoes recommended. VENTILATION: When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. If exposure mayor does exceed occupational exposure limits use a NIOSH- approved respirator to prevent overexposure. When using do not smoke. Do not get this material in contact with eyes. Do not get this material in contact with skin. Wash hands and face before breaks and immediately after handling the product. OTHER: Emergency eyewash and safety shower should be located nearby. Keep away from food and drink. Handle in accordance with good industrial hygiene and safety practice. SECTION 9 - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Do not handle or store near an open flame, heat or other sources of ignition. Use only with adequate ventilation. Wash thoroughly after handling. Avoid prolonged exposure. Avoid release to the environment. Keep away from heat and sources of ignition (spark or flame). The pressure in sealed containers can increase under the influence of heat. Keep containers tightly closed in a cool, well-ventilated place. Store in a closed container away from incompatible materials. Use care in handling/storage. Store in accordance with local/regional/national/international regulation. 14065 Page 7 SECTION 10 - REGULATORY INFORMATION SECTION 313 - SUPPLIER NOTIFICATION THIS PRODUCT DOES NOT CONTAIN ANY TOXIC CHEMICALS WHICH ARE REPORTABLE UNDER SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). Labelling Contains: 2-Butoxyethanol, Ethoxylated Nonylphenol, Methanol US federal regulations: This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. U.S. -CERCLA/SARA-Section 313 -Emission Reporting 2-Butoxyethanol— CAS# 111-76-2 1.0 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1,2, or 3, R=alkyl C7 or less, or R = phenyl or alkyl substituted phenyl, R' = H or alkyl C7 or less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or sulfonate, Chemical Category N230) Methanol—CAS#67-56-1 1.0 % de minimis concentration U.S. -FDA-Direct Food Additives 2-Butoxyethanol— CAS# 111-76-2 21 CFR 173.315 Methanol —CAS#67-56-1 21 CFR 173.250 Occupational Safety and Health Administration (OSHA) 29 CFR 1910.1200 hazardous chemical —Yes CERCLA(Superfund) reportable quantity Methanol: 5000.0000 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard -Yes Delayed Hazard—Yes; Fire Hazard —Yes; Pressure Hazard —No; Reactivity Hazard -No WHILE ARIES CHEMICAL INC. BELIEVES THE DATA SET FORTH HEREIN IS ACCURATE AS OF THE DATE HEREOF, ARIES CHEMICAL MAKES NO WARRANTY WITH RESPECT THERETO AND EXPRESSLY DISCLAIMS ALL LIABILITY FOR REFINANCE THEREON OF SUCH DATA,AND IS OFFERED SOLELY FOR YOUR CONSIDERATION,INVESTIGATION,AND VERIFICATION. Material Safety Data Sheet Page 1 of 5 Material Safety Data Sheet SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Chevron Way Oil Vistac® Product Number(s): CPS232511, CPS232512 Synonyms: Chevron Way Oil Vistac® ISO 68, Chevron Way Oil Vistac® ISO 220 Company Identification ChevronTexaco Global Lubricants 6001 Bollinger Canyon Rd. San Ramon, CA 94583 United States of America www.chevronlubricants.com Transportation Emergency Response CHEMTREC: (800)424-9300 or (703) 527-3887 Health Emergency Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800) 231-0623 or (510) 231- 0623 Product Information email : lubemsds@Chevron.com Product Information: (800) LUBE TEK MSDS Requests: (800)414-6737 SECTION 2 COMPOSITION/ INFORMATION ON INGREDIENTS COMPONENTS CAS NUMBER AMOUNT Non-hazardous additive blend in refined oil Mixture 100 %weight SECTION 3 HAZARDS IDENTIFICATION IMMEDIATE HEALTH EFFECTS Eye: Not expected to cause prolonged or significant eye irritation. Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Contact with the skin is not expected to cause an allergic skin response. Not expected to be harmful to internal organs if absorbed through the skin. Ingestion: Not expected to be harmful if swallowed. Inhalation: Not expected to be harmful if inhaled. Contains a petroleum-based mineral oil. May cause respiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at airborne levels above the recommended mineral oil mist exposure limit. Symptoms of respiratory irritation may include coughing and difficulty breathing. SECTION 4 FIRST AID MEASURES Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and flush eyes with water. Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes if contaminated. To remove the material from skin, use soap and water. Discard contaminated clothing and shoes or thoroughly clean before reuse. Ingestion: No specific first aid measures are required. Do not induce vomiting. As a precaution, get medical advice. Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the air, move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES FIRE CLASSIFICATION: OSHA Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or combustible. NFPA RATINGS: Health: 0 Flammability: 1 Reactivity: 0 https://www.cbest.chevron.corn/msdsServer/controller?module=corn.chevron.lubes.msds.bus.BusMSDS... 5/11/2007 Material Safety Data Sheet Page 2 of 5 FLAMMABLE PROPERTIES: Flashpoint: (Cleveland Open Cup) 170 °C (338 °F) (Min) Autoignition: No Data Available Flammability (Explosive) Limits (% by volume in air): Lower: Not Applicable Upper: Not Applicable EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2)to extinguish flames. PROTECTION OF FIRE FIGHTERS: Fire Fighting Instructions: This material will burn although it is not easily ignited. For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self-contained breathing apparatus. Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this material undergoes combustion. Combustion may form oxides of: Sulfur, Phosphorus . SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures: Eliminate all sources of ignition in vicinity of spilled material. Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-combustible absorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at(800)424-8802 as appropriate or required. SECTION 7 HANDLING AND STORAGE General Handling Information: Avoid contaminating soil or releasing this material into sewage and drainage systems and bodies of water. Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. For more information, refer to OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77, 'Recommended Practice on Static Electricity', and/or the American Petroleum Institute (API) Recommended Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents'. Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION GENERAL CONSIDERATIONS: Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances. ENGINEERING CONTROLS: Use in a well-ventilated area. PERSONAL PROTECTIVE EQUIPMENT Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear safety glasses with side shields as a good safety practice. Skin Protection: No special protective clothing is normally required. Where splashing is possible, select protective clothing depending on operations conducted, physical requirements and other substances in the workplace. Suggested materials for protective gloves include: 4H (PE/EVAL), Nitrile Rubber, Silver Shield, Viton. Respiratory Protection: No respiratory protection is normally required. If user operations generate an oil mist, determine if airborne concentrations are below the occupational exposure limit for mineral oil mist. If not, wear an approved respirator that provides adequate protection from the measured concentrations of this material. For air-purifying respirators use a particulate cartridge. Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide adequate protection. Occupational Exposure Limits: https://www.cbest.chevron.corn/msdsServer/controller?module=corn.chevron.lubes.msds.bus.BusMSDS... 5/11/2007 Material Safety Data Sheet Page 3 of 5 Component Agency TWA STEL Ceiling Notation Non-hazardous additive blend in ACGIH 5 mg/m3 10 mg/m3 -- -- refined oil Non-hazardous additive blend in OSHA Z-1 5 mg/m3 -- -- -- refined oil SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Attention: the data below are typical values and do not constitute a specification. Color: Brown Physical State: Liquid Odor: Petroleum odor pH: Not Applicable Vapor Pressure: <0.01 mmHg @ 37.8 °C (100 °F) Vapor Density(Air= 1): >1 Boiling Point: >315°C (599°F) Solubility: Soluble in hydrocarbons; insoluble in water Freezing Point: Not Applicable Specific Gravity: 0.9 - 0.92 @ 15.6°C (60.1°F)/ 15.6°C (60.1°F) Viscosity: 61.2 cSt @ 40°C (104°F) (Min) Evaporation Rate: No Data Available SECTION 10 STABILITY AND REACTIVITY Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Incompatibility With Other Materials: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. Hazardous Decomposition Products: None known (None expected) Hazardous Polymerization: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION IMMEDIATE HEALTH EFFECTS Eye Irritation: The eye irritation hazard is based on evaluation of data for similar materials or product components. Skin Irritation: The skin irritation hazard is based on evaluation of data for similar materials or product components. Skin Sensitization: The skin sensitization hazard is based on evaluation of data for similar materials or product components. Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar materials or product components. Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials or product components. Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar materials or product components. ADDITIONAL TOXICOLOGY INFORMATION: This product contains petroleum base oils which may be refined by various processes including severe solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been listed in the National Toxicology Program (NTP)Annual Report nor have they been classified by the International Agency for Research on Cancer (IARC)as; carcinogenic to humans (Group 1), probably carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). These oils have not been classified by the American Conference of Governmental Industrial Hygienists (ACGIH) as: confirmed human carcinogen (A1), suspected human carcinogen (A2), or confirmed animal carcinogen with unknown relevance to humans (A3). SECTION 12 ECOLOGICAL INFORMATION ECOTOXICITY The toxicity of this material to aquatic organisms has not been evaluated. Consequently, this material should be kept out of sewage and drainage systems and all bodies of water. ENVIRONMENTAL FATE This material is not expected to be readily biodegradable. SECTION 13 DISPOSAL CONSIDERATIONS https://www.cbest.chevron.corn/msdsServer/controller?module=corn.chevron.lubes.msds.bus.BusMSDS... 5/11/2007 Material Safety Data Sheet Page 4 of 5 Use material for its intended purpose or recycle if possible. Oil collection services are available for used oil recycling or disposal. Place contaminated materials in containers and dispose of in a manner consistent with applicable regulations. Contact your sales representative or local environmental or health authorities for approved disposal or recycling methods. SECTION 14 TRANSPORT INFORMATION The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements (e.g., technical name)and mode-specific or quantity-specific shipping requirements. DOT Shipping Name: NOT REGULATED AS A HAZARDOUS MATERIAL FOR TRANSPORTATION UNDER 49 CFR DOT Hazard Class: NOT APPLICABLE DOT Identification Number: NOT APPLICABLE DOT Packing Group: NOT APPLICABLE Additional Information: NOT HAZARDOUS BY U.S. DOT. ADR/RID HAZARD CLASS NOT APPLICABLE. IMO/IMDG Shipping Name: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORTATION UNDER THE IMDG CODE IMO/IMDG Hazard Class: NOT APPLICABLE IMO/IMDG Identification Number: NOT APPLICABLE IMO/IMDG Packing Group: NOT APPLICABLE SECTION 15 REGULATORY INFORMATION EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: NO 2. Delayed (Chronic) Health Effects: NO 3. Fire Hazard: NO 4. Sudden Release of Pressure Hazard: NO 5. Reactivity Hazard: NO REGULATORY LISTS SEARCHED: 01-1=IARC Group 1 03=EPCRA 313 01-2A=IARC Group 2A 04=CA Proposition 65 01-2B=IARC Group 2B 05=MA RTK 02=NTP Carcinogen 06=NJ RTK 08=PA RTK No components of this material were found on the regulatory lists above. CHEMICAL INVENTORIES: AUSTRALIA: All the components of this material are listed on the Australian Inventory of Chemical Substances (AICS). CANADA: All the components of this material are on the Canadian Domestic Substances List (DSL). EUROPEAN UNION: All the components of this material are in compliance with the EU Seventh Amendment Directive 92/32/EEC. JAPAN: All the components of this product are on the Existing & New Chemical Substances (ENCS) inventory in Japan, or have an exemption from listing. KOREA: All the components of this product are on the Existing Chemicals List (ECL) in Korea. PHILIPPINES: All the components of this product are listed on the Philippine Inventory of Chemicals and Chemical Substances (PICCS). UNITED STATES: All of the components of this material are on the Toxic Substances Control Act (TSCA) Chemical Inventory. NEW JERSEY RTK CLASSIFICATION: Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to be identified as follows: PETROLEUM OIL (Lubricating oil) WHMIS CLASSIFICATION: This product is not considered a controlled product according to the criteria of the Canadian Controlled Products Regulations. SECTION 16 OTHER INFORMATION NFPA RATINGS: Health: 0 Flammability: 1 Reactivity: 0 HMIS RATINGS: Health: 1 Flammability: 1 Reactivity: 0 (0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, `- Chronic Effect https://www.cbest.chevron.corn/msdsServer/controller?module=corn.chevron.lubes.msds.bus.BusMSDS... 5/11/2007 Material Safety Data Sheet Page 5 of 5 Indicator). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings). REVISION STATEMENT: This revision updates the following sections of this Material Safety Data Sheet: 1-16 Revision Date: 10/10/2003 ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT: TLV-Threshold Limit Value TWA-Time Weighted Average STEL-Short-term Exposure Limit PEL- Permissible Exposure Limit CAS -Chemical Abstract Service Number ACGIH - American Conference of Government IMO/IMDG- International Maritime Dangerous Goods Code Industrial Hygienists API -American Petroleum Institute MSDS- Material Safety Data Sheet CVX-Chevron NFPA-National Fire Protection Association (USA) DOT- Department of Transportation (USA) NTP- National Toxicology Program (USA) IARC-International Agency for Research on Cancer OSHA-Occupational Safety and Health Administration Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI MSDS Standard (Z400.1) by the Chevron Energy Research &Technology Company, 100 Chevron Way, Richmond, California 94802. The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. https://www.cbest.chevron.cotn/msdsServer/controller?module=con.chevron.lubes.msds.bus.BusMSDS... 5/11/2007 Material Safety Data Sheet Crude Oil NFPA: Flammability HMIS III: HEALTH 3 11 2.0 0 3 . PHYSICAL 30 0= Insignificant, 1 =Slight,2=Moderate, Specific Hazard T C S O RO 3= High,4=Extreme SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name Crude Oil Synonyms Sour Crude Oil, Sweet Crude Oil, Light Crude Oil, Heavy Crude Oil, Generic Crude Oil, 888100008800 MSDS Number 888100008800 Version 1.4 Product Use Description Refining feedstock Company For: Tesoro Refining & Marketing Co. 19100 Ridgewood Parkway, San Antonio, TX 78259 Tesoro Call Center : (877) 783-7676 Chemtrec (800)424-9300 (Emergency Contact) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Regulatory status : This material is considered hazardous by the Occupational Safety and Health Administration (OSHA) Hazard Communication Standard (29 CFR 1910.1200). Signal Word : DANGER Hazard Summary : Flammable. Toxic. May cause fire. May cause cancer. May release hydrogen sulfide. Hydrogen sulfide (H2S) has a rotten egg "sulfurous"odor. This odor should not be used as a warning property of toxic levels because H2S can overwhelm and deaden the sense of smell. Also, the odor of H2S in heavy oils can easily be masked by the petroleum-like odor of the oil. Therefore, the smell of H2S should not be used as an indicator of a hazardous condition - H2S meters or colorimetric indicating tubes are typically used to determine the concentration of H2S. Potential Health Effects Eyes : May cause eye irritation. Skin : Practically non-toxic if absorbed following acute (single) exposure. May cause skin irritation with prolonged or repeated contact. Liquid may be absorbed through the skin in toxic amounts if large areas of skin are repeatedly exposed. Rare, precancerous warts on the forearms, backs of hands and scrotum have been reported from prolonged or repeated skin contact. MATERIAL SAFETY DATA SHEET Crude Oil Page 2of 12 Ingestion : Aspiration hazard if liquid is inhaled into lungs, particularly from vomiting after ingestion. Aspiration may result in chemical pneumonia, severe lung damage, respiratory failure and even death. Ingestion may cause gastrointestinal disturbances, including irritation, nausea, vomiting and diarrhea, and central nervous (brain) effects similar to alcohol intoxication. In severe cases, tremors, convulsions, loss of consciousness, coma, respiratory arrest and death may occur. Inhalation : May cause respiratory tract irritation. Central nervous system (brain) effects may include headache, dizziness, loss of balance and coordination, unconsciousness, coma, respiratory failure, and death. Irritating and toxic hydrogen sulfide gas may be present. Greater than 15- 20 ppm continuous exposure can cause mucous membrane and respiratory tract irritation. 50 - 500 ppm can cause headache, nausea, and dizziness. Continued exposure at these levels can lead to loss of reasoning and balance, difficulty in breathing, fluid in the lungs, and possible loss of consciousness. Greater than 500 ppm can cause rapid unconsciousness due to respiratory paralysis and death by suffocation unless the victim is removed from exposure and successfully resuscitated. Greater than 1000 ppm can cause immediate unconsciousness and death if not promptly revived. After-effects from overexposure are not anticipated except what would be expected if the victim was without oxygen for more than 3 to 5 minutes (asphyxiation). The "rotten egg" odor of hydrogen sulfide is not a reliable indicator for warning of exposure, since olfactory fatigue (loss of smell) readily occurs, especially at concentrations above 50 ppm. At high concentrations, the victim may not even recognize the odor before becoming unconscious. Chronic Exposure : This material contains polynuclear aromatic hydrocarbons (PNAs), some of which are animal carcinogens. Similar products produced skin cancer and systemic toxicity in laboratory animals following repeated applications. The significance of these results to human exposures has not been determined - see Section 11 Toxicological Information. Contains benzene, which can cause blood disease, including anemia and leukemia. Suspect reproductive hazard - contains material which may injure unborn child. Target Organs : Skin, Eyes, Central nervous system, Respiratory system, Kidney, Liver SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS-No. Weight% Petroleum; Crude oil 8002-05-9 100% N-hexane 110-54-3 0-1.5% Hydrogen Sulfide 7783-06-4 Variable Sulfur 7704-34-9 Trace-5% Benzene 71-43-2 0.1 -3% Cumene 98-82-8 Variable Trace< 1% Naphthalene 91-20-3 Variable Trace< 1% Xylene 1330-20-7 Variable Trace< 1% 2/ 12 MATERIAL SAFETY DATA SHEET Crude Oil Page 3of 12 Ethylbenzene 100-41-4 Variable Trace< 1% Polycyclic Aromatic Compounds Variable Toluene 108-88-3 Variable Trace< 1% SECTION 4. FIRST AID MEASURES Inhalation . Move to fresh air. Administer oxygen or artificial respiration if needed. Seek medical attention immediately. Skin contact : Take off all contaminated clothing immediately. Wash off immediately with soap and plenty of water. Seek medical attention if irritation or skin thermal burns occur. Eye contact : In case of eye contact, immediately flush with low pressure, cool water for at least 15 minutes, opening eyelids to ensure flushing. Hold the eyelids open and away from the eyeballs to ensure that all surfaces are flushed thoroughly. Seek medical attention immediately. Ingestion : Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Seek medical attention immediately. If vomiting does occur naturally, keep head below the hips to reduce the risks of aspiration. Small amounts of material which enter the mouth should be rinsed out until the taste is dissipated. SECTION 5. FIRE-FIGHTING MEASURES Form : Liquid Flash point : Variable. < 100°F (38°) Lower explosive limit : Variable Upper explosive limit : Variable Suitable extinguishing media : SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2, water spray, fire fighting foam, or Halon. LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for fighting the fire, but may be used to cool fire-exposed containers., Water may be ineffective for fighting the fire, but may be used to cool fire-exposed containers. Specific hazards during fire : Vapors are heavier than air and may travel long distances to a point of ignition and fighting flash back. Do not allow liquid runoff to enter sewers or public waters. Gas may form explosive mixture with air. Special protective equipment : Use NIOSH/MSHA approved positive pressure self-contained breathing apparatus for fire-fighters and fully protective clothing such as bunker gear if needed to prevent exposure. Further information : Isolate area, particularly around ends of storage vessels. Cool tanks, shells, and containers exposed to fire and excessive heat with water. For massive fires the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Major fires may require withdrawal, allowing the tank to burn. Large storage tank fires typically require specially trained personnel and equipment to extinguish the fire, often including the need for properly applied fire fighting foam. SECTION 6. ACCIDENTAL RELEASE MEASURES 3/ 12 MATERIAL SAFETY DATA SHEET Crude Oil Page 4of 12 Personal precautions : Evacuate nonessential personnel and remove or secure all ignition sources. Consider wind direction; stay upwind and uphill, if possible. Evaluate the direction of product travel, diking, sewers, etc. to contain spill areas. Environmental precautions : Carefully contain and stop the source of the spill, if safe to do so. Protect bodies of water by diking, absorbents, or absorbent boom, if possible. Do not flush down sewer or drainage systems, unless system is designed and permitted to handle such material. The use of fire fighting foam may be useful in certain situations to reduce vapors. Methods for cleaning up : Take up with sand or oil absorbing materials. Carefully shovel, scoop or sweep up into a waste container for reclamation or disposal -caution, flammable vapors may accumulate in closed containers. Response and clean-up crews must be properly trained and must utilize proper protective equipment (see Section 8). SECTION 7. HANDLING AND STORAGE Handling : Handle as a combustible liquid. Keep product and empty containers away from fire, sparks and heated surfaces. Electrical equipment should be approved for classified area. Bond and ground containers during product transfer to reduce the possibility of static-initiated fire or explosion. Requirements for storage . Keep away from flame, sparks, excessive temperatures and open flame. Use areas and containers approved vented containers. Keep containers closed and clearly labeled. Empty product containers or vessels may contain explosive vapors. Do not pressurize, cut, heat, weld or expose containers to sources of ignition. Store in a well- ventilated area. This storage area should comply with NFPA 30 "Flammable and Combustible Liquid Code". Avoid storage near incompatible materials. The cleaning of tanks previously containing this product should follow API Recommended Practice (RP)2013 "Cleaning Mobile Tanks In Flammable and Combustible Liquid Service" and API RP 2015 "Cleaning Petroleum Storage Tanks". SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines List Components CAS-No. Type: Value OSHA Benzene 71-43-2 TWA 1 ppm 71-43-2 STEL 5 ppm 71-43-2 OSHA AL 0.5 ppm N-hexane 110-54-3 PEL 500 ppm 1,800 mg/m3 Hydrogen sulfide 7783-06-4 STEL 20 ppm Cumene 98-82-8 TWA 50 ppm Ethylbenzene 100-4-4 TWA 100 ppm Naphthalene 91-20-3 TWA 10 ppm Toluene 108-88-3 TWA 200 ppm Xylenes 1330-20-7 TWA 100 ppm Ceiling 300 ppm Polycyclic Aromatic Compound TWA 0.2 mg/m3 4/ 12 MATERIAL SAFETY DATA SHEET Crude Oil Page 5of 12 (Benzene Soluble) ACGIH N-hexane 110-54-3 TWA 50 ppm Hydrogen Sulfide 7783-06-4 TWA 1 ppm 7783-06-4 STEL 5 ppm Benzene 71-43-2 TWA 0.5 ppm 71-43-2 STEL 2.5 ppm Cumene 98-82-8 TWA 50 ppm Ethylbenzene 100-4-4 TWA 50 ppm 100-4-4 STEL 125 ppm Naphthalene 91-20-3 TWA 10 ppm 91-20-3 STEL 15 ppm Toluene 108-88-3 TWA 20 ppm Xylenes 1330-20-7 TWA 100 ppm 1330-20-7 STEL 150 ppm Polycyclic Aromatic Compound TWA 0.2 mg/m3 (Benzene Soluble) Engineering measures . Use adequate ventilation to keep gas and vapor concentrations of this product below occupational exposure and flammability limits, particularly in confined spaces. Eye protection : Ensure that eyewash stations and safety showers are close to the workstation location. Goggles, and face shield or full facepiece pressure-demand supplied air respirator as needed to prevent eye and face contact. Hand protection : Gloves constructed of nitrile, neoprene, or PVC are recommended. The resistance of specific material may vary from product to product as well as with degree of exposure. Skin and body protection : Chemical protective clothing such as DuPont TyChem ®, Barricade or equivalent, recommended based on degree of exposure. Respiratory protection : A NIOSH/ MSHA-approved air-purifying respirator with organic vapor cartridges or canister may be permissible under certain circumstances where airborne concentrations are or may be expected to exceed exposure limits or for odor or irritation. Protection provided by air-purifying respirators is limited. Refer to OSHA 29 CFR 1910.134, ANSI Z88.2-1992, NIOSH Respirator Decision Logic, and the manufacturer for additional guidance on respiratory protection selection. Use a NIOSH/ MSHA-approved positive-pressure supplied-air respirator if there is a potential for uncontrolled release, exposure levels are not known, in oxygen- deficient atmospheres, or any other circumstance where an air-purifying respirator may not provide adequate protection. 5/ 12 MATERIAL SAFETY DATA SHEET Crude Oil Page 6of 12 Hygiene measures : Avoid repeated and/or prolonged skin exposure. Wash hands before eating, drinking, smoking, or using toilet facilities. DO NOT use gasoline, kerosene, solvents, or harsh abrasive skin cleaners to clean skin. Waterless hand cleaners are effective. Promptly remove contaminated clothing and launder before reuse. Consider the need to discard contaminated leather shoes and gloves. Use good personal hygiene practices. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form : Liquid Appearance : Variable depending on its source; typical is a thick, dark yellow to brown or greenish black liquid Odor : Petroleum asphalt odor. Hydrogen sulfide (H2S) has a characteristic rotten egg odor with an odor threshold as low as 10 parts per billion or even less. However, this odor should not be used as a warning property because H2S can deaden the sense of smell. H2S concentrations can be measured with an H2S meter orcolorimetric indicating tubes. Flash point -typical : < 100°F (38°) Lower explosive limit : Variable Upper explosive limit : Variable pH : Not applicable Percent Volatiles : 100 % Specific Gravity < 1 SECTION 10. STABILITY AND REACTIVITY Materials to avoid : Strong Oxidizers Hazardous decomposition : Carbon monoxide, carbon dioxide and noncombusted hydrocarbons (smoke). products I SECTION 11. TOXICOLOGICAL INFORMATION Carcinogenicity NTP : Benzene (CAS-No.: 71-43-2) Naphthalene (CAS-No: 91-20-3) IARC : Benzene (CAS-No.: 71-43-2) Naphthalene (CAS-No: 91-20-3) Ethylbenzene (CAS-No: 100-41-4) OSHA : Benzene (CAS-No.: 71-43-2) CA Prop 65 : WARNING! This product contains a chemical known to the State of California to cause cancer. Benzene (CAS-No.: 71-43-2) Toluene (CAS-No: 108-88-3) : WARNING! This product contains a chemical known to the State of California to 6/ 12 MATERIAL SAFETY DATA SHEET Crude Oil Page 7of 12 cause birth defects or other reproductive harm. Benzene (CAS-No.: 71-43-2) Component: Petroleum; Crude oil 8002-05-9 Acute oral toxicity LD50 rat Dose: 5,001 mg/kg Acute dermal toxicity LD50 rabbit Dose: 2,001 mg/kg Skin irritation Result:Mild skin irritation Eye irritation Result: Mild eye irritation Carcinogenicity: N11.00418605 N-hexane 110-54-3 Acute oral toxicity LD50 rat Dose: 25,000 mg/kg Acute dermal toxicity LD50 rabbit Dose: 2,001 mg/kg Acute inhalation toxicity LC50 rat Dose 171.6 mg/I Exposure time:4 h Skin irritation Classification: Irritating to skin. Result:Skin irritation Eye irritation Classification: Irritating to eyes. Result: Mild eye irritation Teratogenicity: N11.00418960 Sulfur 7704-34-9 Acute oral toxicity LD50 rat Dose: 5,001 mg/kg Acute dermal toxicity LD50 rabbit Dose: 2,001 mg/kg Acute inhalation toxicity LC50 rat Dose 9.24 mg/I Exposure time:4 h Eye irritation Classification: Irritating to eyes. Result: Mild eye irritation Benzene 71-43-2 Acute oral toxicity LD50 rat Dose: 930 mg/kg Acute inhalation toxicity LC50 rat Dose 44 mg/I Exposure time:4 h Skin irritation Classification: Irritating to skin. Result: Mild skin irritation Repeated or prolonged exposure may cause skin irritation and dermatitis,due to degreasing properties of the product. Eye irritation Classification: Irritating to eyes. Result: Risk of serious damage to eyes. Toluene 108-88-3 Acute oral toxicity LD50 rat Dose: 636 mg/kg Acute dermal toxicity LD50 rabbit Dose: 12,124 mg/kg Acute inhalation toxicity LC50 rat 7/ 12 MATERIAL SAFETY DATA SHEET Crude Oil Page 8of 12 Dose 49 mg/I Exposure time:4 h Skin irritation Classification: Irritating to skin. Result: Mild skin irritation Prolonged skin contact may defat the skin and produce dermatitis. Eye irritation Classification: Irritating to eyes. Result: Mild eye irritation Xylene 1330-20-7 Acute oral toxicity LD50 rat Dose: 2,840 mg/kg Acute dermal toxicity LD50 rabbit Dose:ca.4,500 mg/kg Acute inhalation toxicity LC50 rat Dose 6,350 mg/I Exposure time:4 h Skin irritation Classification: Irritating to skin. Result: Mild skin irritation Repeated or prolonged exposure may cause skin irritation and dermatitis,due to degreasing properties of the product. Eye irritation Classification: Irritating to eyes. Result: Mild eye irritation Naphthalene 91-20-3 Acute oral toxicity LD50 rat Dose: 2,001 mg/kg Acute dermal toxicity LD50 rat Dose: 2,501 mg/kg Acute inhalation toxicity LC50 rat Dose 101 mg/I Exposure time:4 h Skin irritation Classification: Irritating to skin. Result: Mild skin irritation Eye irritation Classification: Irritating to eyes. Result: Mild eye irritation Carcinogenicity: N11.00422130 Ethylbenzene 100-41-4 Acute oral toxicity LD50 rat Dose: 3,500 mg/kg Acute dermal toxicity LD50 rabbit Dose: 15,500 mg/kg Acute inhalation toxicity LC50 rat Dose 18 mg/I Exposure time:4 h Skin irritation Classification: Irritating to skin. Result: Mild skin irritation Eye irritation Classification: Irritating to eyes. Result: Risk of serious damage to eyes. SECTION 12. ECOLOGICAL INFORMATION Additional ecological : Keep out of sewers, drainage areas, and waterways. Report spills and releases, as information applicable, under Federal and State regulations. Component: N-hexane 110-54-3 Toxicity to fish 8/ 12 MATERIAL SAFETY DATA SHEET Crude Oil Page 9of 12 LC50 Species Pimephales promelas(fathead minnow) Dose: 2.5 mg/I Exposure time:96 h Acute and prolonged toxicity for aquatic invertebrates: EC50 Species Daphnia magna(Water flea) Dose: 2.1 mg/I Exposure time:48 h Sulfur 7704-34-9 Acute and prolonged toxicity for aquatic invertebrates: ECU Species Daphnia magna(Water flea) Dose: > 10,000 mg/I Exposure time:24 h SECTION 13. DISPOSAL CONSIDERATIONS Disposal : Consult federal, state and local waste regulations to determine appropriate waste characterization of material and allowable disposal methods. I SECTION 14. TRANSPORT INFORMATION CFR Proper shipping name : PETROLEUM CRUDE OIL UN-No. : 1267 Class : 3 Packing group : II TDG Proper shipping name : PETROLEUM CRUDE OIL UN-No. : UN1267 Class : 3 Packing group : II IATA Cargo Transport UN UN-No. : UN1267 Description of the goods . PETROLEUM CRUDE OIL Class : 3 Packaging group : II ICAO-Labels : 3 Packing instruction (cargo : 364 aircraft) Packing instruction (cargo : Y341 aircraft) IATA Passenger Transport UN UN-No. : UN1267 Description of the goods : PETROLEUM CRUDE OIL Class : 3 Packaging group : II ICAO-Labels : 3 Packing instruction : 353 (passenger aircraft) Packing instruction : Y341 9/ 12 MATERIAL SAFETY DATA SHEET Crude Oil Page10of12 (passenger aircraft) IMDG-Code UN-No. : UN 1267 Description of the goods : PETROLEUM CRUDE OIL Class : 3 Packaging group : II IMDG-Labels : 3 EmS Number : F-E S-E Marine pollutant : No SECTION 15. REGULATORY INFORMATION OSHA Hazards : Flammable liquid Toxic by inhalation. Moderate skin irritant Moderate eye irritant Carcinogen Teratogen TSCA Status : On TSCA Inventory DSL Status : All components of this product are on the Canadian DSL list. SARA 311/312 Hazards : Fire Hazard Acute Health Hazard Chronic Health Hazard CERCLA SECTION 103 and SARA SECTION 304(RELEASE TO THE ENVI ROM ENTI The CERCLA definition of hazardous substances contains a"petrol eum exd udon"d arse whi ch exempts crude of I.Fractions of crude of I,and products(both fi ni shed and i ntermedi ate)from the crude oil ref ni ng process and any indigenous components of such from the CERCLA Section 103 reporting requirements. However,other federal reporting requirements, including SARA Section 304,aswdl as the Clean Water Act may still apply. MASS RTK US. Massachusetts Commonwealth's Right-to-Know Law(Appendix A to 105 Code of Massachusetts Regulations Section 670.000) Components CAS-No. Benzene 71-43-2 Hydrogen Sulfide 7783-06-4 Sulfur 7704-34-9 N-hexane 110-54-3 Petroleum; Crude oil 8002-05-9 Toluene 108-88-3 Xylene 1330-20-7 Components CAS-No. hydrogen sulfide 7783-06-4 PENN RTK US.Pennsylvania Worker and Community Right-to-Know Law(34 Pa. Code Chap.301-323) 10/ 12 MATERIAL SAFETY DATA SHEET Crude Oil Page 11 of 12 Components CAS-No. Benzene 71-43-2 Hydrogen Sulfide 7783-06-4 Sulfur 7704-34-9 N-hexane 110-54-3 Petroleum; Crude oil 8002-05-9 Toluene 108-88-3 Xylene 1330-20-7 NJ RTK US. New Jersey Worker and Community Right-to-Know Act(New Jersey Statute Annotated Section 34:5A-5) Components CAS-No. Benzene 71-43-2 Hydrogen Sulfide 7783-06-4 Sulfur 7704-34-9 N-hexane 110-54-3 Petroleum; Crude oil 8002-05-9 Toluene Xylene California Prop. 65 : WARNING! This product contains a chemical known to the State of California to cause cancer. Benzene 71-43-2 WARNING! This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Benzene 71-43-2 Toluene 108-88-3 SECTION 16. OTHER INFORMATION Further information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Template GWU mbH Prepared by: Birlenbacher Str. 18 D-57078 Siegen Germany 11 / 12 MATERIAL SAFETY DATA SHEET Crude Oil Page12of12 Telephone: +49-(0)271-88072-0 Revision Date 02/01/2011 12/ 12 mu ti-chem Material Safety Data Sheet NFPA HMIS HEALTH FLAMMABILITY El REACTIVITY o , Issuing Date 26-Jul-2006 Revision Date 10-Aug-2011 Revision Number 2 1 . PRODUCT AND COMPANY IDENTIFICATION Product Name MC EB-1595 Product Code MC EB-1595 UN-No 2924 Recommended Use Emulsion Breaker. Manufactured by: Multi-Chem Group LLC 2905 Southwest Blvd San Angelo, TX 76904 Phone: 1 325 223 6200 Emergency Telephone Number 1 800 535 5053 +1 352 323 3500 (Outside United States) 613 996 6666 or*666 on a cell phone(Inside Canada Only) 2. HAZARDS IDENTIFICATION Emergency Overview Flammable Corrosive The product causes burns of eyes, skin and mucous membranes Harmful by inhalation, in contact with skin and if swallowed Contains known or suspected carcinogens Contains known or suspected reproductive toxins Appearance Clear to Slightly Physical State Liquid Odor Pungent Hazy, Light Amber to Dark Amber Potential Health Effects Principle Routes of Exposure Eye contact, Skin contact, Inhalation, Ingestion. Acute Toxicity 1 / 10 MC EB-1595-MC EB-1595 Revision Date 10-Aug-2011 Eyes Causes burns. Risk of serious damage to eyes. Skin Contact causes severe skin irritation and possible burns. Inhalation Irritating to respiratory system. May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. Exposure to mists may cause severe irritation or burns to the upper respiratory tract. Ingestion Harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Ingestion causes burns of the upper digestive and respiratory tract. May cause additional affects as listed under"Inhalation". Potential for aspiration if swallowed. Chronic Effects Possible risks of irreversible effects Prolonged exposure may cause chronic effects Contains known or suspected carcinogens Contains known or suspected reproductive toxins Aggravated Medical Conditions Preexisting eye disorders. Skin disorders. Respiratory disorders. Liver disorders. Kidney disorders. Neurological disorders. Environmental Hazard See Section 12 for additional Ecological Information 3. COMPOSITION/INFORMATION ON INGREDIENTS Formula Mixture Chemical Name CAS-No Weight% Benzenesulfonic acid, C10-16-alkyl derivatives 68584-22-5 15-40 Xylene 1330-20-7 10-30 Solvent naphtha (petroleum), light aliphatic 64742-89-8 10-30 Toluene 108-88-3 5-10 Ethyl benzene 100-41-4 3-7 Isopropyl alcohol 67-63-0 1-5 Sulfuric acid 7664-93-9 0.1-1 4. FIRST AID MEASURES General Advice Get medical attention immediately if symptoms occur. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek immediate medical attention/advice. Skin Contact Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Seek immediate medical attention/advice. Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Seek immediate medical attention/advice. Ingestion Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Rinse mouth. Get medical attention. Notes to Physician If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Asphyxia from glottal edema may occur. Marked decrease in blood pressure may occur. 5. FIRE-FIGHTING MEASURES Flammable Properties Flammable. Flash Point 18.9 °C/66 °F 2/ 10 MC EB-1595-MC EB-1595 Revision Date 10-Aug-2011 Suitable Extinguishing Media Foam. Dry chemical. Carbon dioxide (CO2). Water spray. Water fog. Hazardous Combustion Products Carbon oxides, Sulfur oxides, Sulfuric acid. Explosion Data Sensitivity to Mechanical Impact Not sensitive Sensitivity to Static Discharge May be ignited by friction, heat, sparks or flames. Specific Hazards Arising from the Chemical Most vapors are heavier than air. They will spread along ground and collect in low or confined areas(sewers, basements,tanks). Vapors may travel to source of ignition and flash back. Protective Equipment and Precautions for Firefighters As in any fire,wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent)and full protective gear NFPA Health Hazard 3 Flammability 3 Stability 0 Physical and - Chemical Hazards 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Only trained and properly protected personnel must be involved in clean-up operations. Use personal protective equipment. Avoid contact with the skin and the eyes. Ensure adequate ventilation. Remove all sources of ignition. Take precautionary measures against static discharges. Methods for Containment Dike far ahead of liquid spill for later disposal. Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Neutralise with soda ash or other non-reactive alkaline. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Ground and bond containers when transferring material. 7. HANDLING AND STORAGE Handling Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove all sources of ignition. Take precautionary measures against static discharges. Storage Keep containers tightly closed in a cool,well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Benzenesulfonic acid, C10-16-alkyl derivatives 68584-22-5 Xylene =150 ppm STEL TWA:435 mg/m3 1330-20-7 TWA: 100 ppm TWA: 100 ppm Solvent naphtha(petroleum), light aliphatic 64742-89-8 3/ 10 MC EB-1595-MC EB-1595 Revision Date 10-Aug-2011 Toluene TWA:20 ppm TWA:200 ppm IDLH:500 ppm 108-88-3 TWA: 100 ppm TWA:375 mg/m3 STEL: 150 ppm STEL:560 mg/m3 Ethyl benzene =125 ppm STEL TWA: 100 ppm IDLH:800 ppm 100-41-4 TWA: 100 ppm TWA:435 mg/m3 TWA:435 mg/m3 (vacated)TWA: 100 ppm TWA: 100 ppm (vacated)TWA:435 mg/m3 STEL: 125 ppm (vacated)STEL: 125 ppm STEL:545 mg/m3 (vacated)STEL:545 mg/m3 Isopropyl alcohol =400 ppm STEL TWA:400 ppm IDLH:2000 ppm 67-63-0 TWA:200 ppm TWA:980 mg/m3 TWA:400 ppm (vacated)TWA:400 ppm TWA:980 mg/m3 (vacated)TWA:980 mg/m3 STEL: 1225 mg/m3 (vacated)STEL: 1225 mg/m3 STEL: 500 ppm (vacated)STEL:500 ppm Sulfuric acid TWA:0.2 mg/m3 TWA: 1 mg/m3 IDLH: 15 mg/m3 7664-93-9 TWA: 1 mg/m3 Chemical Name Alberta British Columbia Saskatchewan Benzenesulfonic acid, C10-16-alkyl derivatives 68584-22-5 Xylene STEL:651 mg/m3 STEL: 150 ppm TWA:434 mg/m3 1330-20-7 STEL: 150 ppm TWA: 100 ppm TWA: 100 ppm TWA:434 mg/m3 STEL:651 mg/m3 TWA: 100 ppm STEL: 150 ppm Solvent naphtha(petroleum),light aliphatic 64742-89-8 Toluene TWA:50 ppm TWA:20 ppm TWA:50 ppm 108-88-3 TWA: 188 mg/m3 STEL:60 ppm Ethyl benzene STEL: 125 ppm STEL: 125 ppm TWA: 100 ppm 100-41-4 STEL:543 mg/m3 TWA: 100 ppm TWA:435 mg/m3 TWA:434 mg/m3 STEL:543 mg/m3 TWA: 100 ppm STEL: 125 ppm Isopropyl alcohol STEL: 1230 mg/m3 STEL:400 ppm TWA:400 ppm 67-63-0 STEL:500 ppm TWA:200 ppm TWA:983 mg/m3 TWA:400 ppm STEL: 1230 mg/m3 TWA:983 mg/m3 STEL:500 ppm Sulfuric acid STEL:3 mg/m3 TWA:0.2 mg/m3 TWA:0.2 mg/m3 7664-93-9 TWA: 1 mg/m3 STEL:0.6 mg/m3 Engineering Measures Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. If splashes are likely to occur,wear:. Goggles. Face-shield. Skin and Body Protection Wear protective gloves/clothing. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations Hygiene Measures Remove and wash contaminated clothing before re-use. Wash hands before breaks and immediately after handling the product. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Clear to Slightly Hazy Light Odor Pungent Amber to Dark Amber Physical State Liquid pH 1.65-2.65 Flash Point 18.9 °C/66 °F Autoignition Temperature No data available Boiling Point/Range No data available 4/ 10 MC EB-1595-MC EB-1595 Revision Date 10-Aug-2011 Flammability Limits in Air No data available Explosion Limits No data available Specific Gravity 0.8589-0.8989 Solubility Oil soluble Evaporation Rate No data available Vapor Pressure No data available Vapor Density No data available Density 7.16-7.49 lbs/gal 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions Incompatible Products Strong oxidizing agents. Strong bases. Conditions to Avoid Heat,flames and sparks. Hazardous Decomposition Products Carbon oxides. Sulfur oxides. Sulfuric acid. Hazardous Polymerization Hazardous polymerization does not occur 11 . TOXICOLOGICAL INFORMATION Acute Toxicity Product Information The product itself has not been tested. Irritation Causes severe irritation and or burns. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Benzenesulfonic acid, C10-16-alkyl 530 mg/kg(Rat) 530 mg/kg(Rat) derivatives Xylene 4300 mg/kg(Rat) 1700 mg/kg(Rabbit) 5000 ppm(Rat)4 h Solvent naphtha(petroleum),light 5000 mg/kg(Rat) 3000 mg/kg(Rabbit) aliphatic Toluene 636 mg/kg(Rat) 12124 mg/kg(Rat) 12.5 mg/L(Rat)4 h 8390 mg/kg(Rabbit) 26700 ppm(Rat)1 h Ethyl benzene 3500 mg/kg(Rat) 15354 mg/kg(Rabbit) 17.2 mg/L(Rat)4 h Isopropyl alcohol 4396 mg/kg(Rat) 12800 mg/kg(Rabbit) 72.6 mg/L(Rat)4 h 12800 mg/kg(Rat) Sulfuric acid 2140 mg/kg(Rat) 347 ppm(Rat)1 h 510 mg/m3(Rat)2 h Chronic Toxicity Chronic Toxicity Possible risks of irreversible effects. Prolonged exposure may cause chronic effects. Contains known or suspected carcinogens. Contains known or suspected reproductive toxins. Carcinogenicity This product contains one or more substances which are classified by IARC as carcinogenic to humans(Group I), probably carcinogenic to humans(Group 2A)or possibly carcinogenic to humans(Group 2B). Isopropanol is only a Group 1 IARC carcinogen as a strong acid process.The classification does not apply to the finished solvent product. Exposure to strong inorganic mists containing sulfuric acid may cause cancer by inhalation. Chemical Name ACGIH IARC NTP OSHA Ethyl benzene A3 Group 2B X Isopropyl alcohol Group 1 Sulfuric acid A2 Group 1 Known X 5/ 10 MC EB-1595-MC EB-1595 Revision Date 10-Aug-2011 Reproductive Toxicity Contains a known or suspected reproductive toxin. Teratogenic Effects May cause harm to the unborn child Target Organ Effects Eyes, Skin, Liver, Kidney, Respiratory system, Central nervous system (CNS). Other Adverse Effects Chronic inhalation exposure to xylene causes midfrequency hearing loss in laboratory animals. Xylene reacts synergistically with n-hexane to enhance hearing loss. Long term exposure of xylene may cause nervous system effects with symptoms such as headaches, irritability,depression, insomnia, agitation, extreme tiredness,tremors, impaired concentration and short term memory.The blood platelet count may be reduced on exposure to xylene which is reversible when exposure is stopped. 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated Chemical Name Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna(Water Flea) Benzenesulfonic acid, LC50=3 mg/L EC50=5 mg/L 6 h EC50=2.9 mg/L 48 h C10-16-alkyl derivatives Oncorhynchus mykiss 96 h Xylene LC50= 13.4 mg/L EC50=0.0084 mg/L 24 h Pimephales promelas 96 h LC50= 16.1 mg/L Lepomis macrochirus 96 h LC50=26.7 mg/L Pimephales promelas 96 h LC50=8.05 mg/L Oncorhynchus mykiss 96 h Solvent naphtha EC50=4700 mg/L 72 h (petroleum), light aliphatic Toluene EC50= 12.5 mg/L 72 h LC50 11.0-15.0 mg/L EC50= 19.7 mg/L 30 min EC50= 11.3 mg/L 48 h EC50>433 mg/L 96 h Lepomis macrochirus 96 h EC50=310 mg/L 48 h LC50 14.1-17.16 mg/L Oncorhynchus mykiss 96 h LC50 15.22-19.05 mg/L Pimephales promelas 96 h LC50 5.89-7.81 mg/L Oncorhynchus mykiss 96 h LC50 50.87-70.34 mg/L Poecilia reticulata 96 h LC50= 12.6 mg/L Pimephales promelas 96 h LC50=28.2 mg/L Poecilia reticulate 96 h LC50=5.8 mg/L Oncorhynchus mykiss 96 h LC50=54 mg/L Oryzias latipes 96 h Ethyl benzene EC50=4.6 mg/L 72 h LC50= 14.0 mg/L EC50=9.68 mg/L 30 min EC50 1.8-2.4 mg/L 48 h EC50>438 mg/L 96 h Oncorhynchus mykiss 96 h EC50=96 mg/L 24 h LC50= 150.0 mg/L Lepomis macrochirus 96 h LC50=32 mg/L Lepomis macrochirus 96 h LC50=4.2 mg/L Oncorhynchus mykiss 96 h LC50=48.5 mg/L Pimephales promelas 96 h LC50=9.09 mg/L Pimephales promelas 96 h LC50=9.6 mg/L Poecilia reticulate 96 h 6/ 10 MC EB-1595-MC EB-1595 Revision Date 10-Aug-2011 Isopropyl alcohol EC50> 1000 mg/L 72 h LC50=61200 mg/L EC50=35390 mg/L 5 min EC50= 13299 mg/L 48 h EC50> 1000 mg/L 96 h Pimephales promelas 96 h LC50=94900 mg/L Pimephales promelas 96 h LC50=9640 mg/L Pimephales promelas 96 h _ Sulfuric acid LC50>500 mg/L EC50=29 mg/L 24 h Brachydanio rerio 96 h Chemical Name Log Pow Benzenesulfonic acid,C10-16-alkyl derivatives =2 23°C Toluene =2.65 Ethyl benzene =3.118 Isopropyl alcohol =0.05 25°C 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of in accordance with local regulations. Contaminated Packaging Dispose of in accordance with local regulations Chemical Name RCRA-Halogenated RCRA-P Series Wastes RCRA-F Series Wastes RCRA-K Series Wastes Organic Compounds Toluene- 108-88-3 Toxic waste waste number F025 Waste description: Condensed light ends,spent filters and filter aids,and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons,by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from one to and including five,with varying amounts and positions of chlorine substitution. This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status Toluene Toxic; Ignitable Ethyl benzene Toxic; Ignitable Isopropyl alcohol Toxic, Ignitable Sulfuric acid Toxic;Corrosive 14. TRANSPORT INFORMATION DOT Proper Shipping Name Flammable Liquid, Corrosive, N.O.S(Xylene and Toluene) Hazard Class 3 Subsidiary Class 8 UN-No 2924 Packing Group II ERG Code 132 IATA UN-No 2924 7/ 10 MC EB-1595-MC EB-1595 Revision Date 10-Aug-2011 Proper Shipping Name Flammable Liquid, Corrosive, N.O.S(Xylene and Benzenesulfonic acid, C10-16-alkyl derivatives) Hazard Class 3 Subsidiary Class 8 Packing Group II IMDG/IMO Proper Shipping Name Flammable Liquid, Corrosive, N.O.S(Xylene and Benzenesulfonic acid, C10-16-alkyl derivatives) Hazard Class 3 Subsidiary Class 8 UN-No 2924 Packing Group II TDG Proper Shipping Name Flammable Liquid, Corrosive, N.O.S(Xylene) Hazard Class 3 Subsidiary Class 8 UN-No 2924 Packing Group II 15. REGULATORY INFORMATION International Inventories Component TSCA DSL EINECS/ELIN ENCS IECSC KECL PICCS AICS CS Benzenesulfonic acid, Present X X - X KE-02595 X X C10-16-alkyl derivatives 68584-22-5( 15-40) Xylene Present X X 3-3;3-60 X KE-35427 X X 1330-20-7( 10-30) Solvent naphtha Present X X - X KE-31661 X X (petroleum), light aliphatic 64742-89-8( 10-30) Toluene Present X X 3-2 X KE-33936 X X 108-88-3(5-10) Ethyl benzene T X X 3-28;3-60 X KE-13532 X X 100-41-4(3-7) Isopropyl alcohol Present X X 2-207 X KE-29363 X X 67-63-0( 1-5) Sulfuric acid Present X X (1)-724 X - X X 7664-93-9(0.1-1 ) (1)-430 U.S. Federal Regulations SARA 313 Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. Chemical Name CAS-No Weight% SARA 313-Threshold Values% Toluene 108-88-3 5-10 1.0 Ethyl benzene 100-41-4 3-7 0.1 Isopropyl alcohol 67-63-0 1-5 1.0 Sulfuric acid 7664-93-9 0.1-1 1.0 SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard No 8/ 10 MC EB-1595-MC EB-1595 Revision Date 10-Aug-2011 Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act(40 CFR 122.21 and 40 CFR 122.42). Component CWA-Reportable CWA-Toxic Pollutants CWA-Priority Pollutants CWA-Hazardous Quantities Substances Toluene 1000 lb X X X 108-88-3(5-10) Ethyl benzene 10001b X X X 100-41-4(3-7) Isopropyl alcohol x 67-63-0( 1-5) Sulfuric acid 1000 lb X 7664-93-9(0.1-1 ) Clean Air Act, Section 112 Hazardous Air Pollutants(HAPs)(see 40 CFR 61) This product contains the following substances which are listed hazardous air pollutants(HAPS)under Section 112 of the Clean Air Act:. Chemical Name CAS-No Weight% HAPS data VOC Chemicals Class 1 Ozone Class 2 Ozone Depletors Depletors Xylene 1330-20-7 10-30 Group I Toluene 108-88-3 5-10 Present Group I Ethyl benzene 100-41-4 3-7 Present Group I CERCLA Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs Xylene 100 lb Toluene 1000 lb Ethyl benzene 1000 lb Sulfuric acid 1000 lb 1000 lb U.S. State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name CAS-No California Prop.65 Toluene 108-88-3 Developmental Female Reproductive Ethyl benzene 100-41-4 Carcinogen Sulfuric acid 7664-93-9 Carcinogen Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island Xylene X X X X Toluene X X X X X Ethyl benzene X X X X X Isopropyl alcohol X X X X Sulfuric acid X X X X X International Regulations Mexico-Grade No information available. Chemical Name Carcinogen Status Exposure Limits Xylene Mexico:TWA=435 mg/m3 Mexico:TWA= 100 ppm Toluene Mexico:TWA 50 ppm Mexico:TWA 188 mg/m3 Ethyl benzene Mexico:TWA= 100 ppm Mexico:TWA=435 mg/m3 Isopropyl alcohol Mexico:TWA=980 mg/m3 Mexico:TWA=400 ppm Sulfuric acid A2 Mexico:TWA 1 mg/m3 9/ 10 MC EB-1595-MC EB-1595 Revision Date 10-Aug-2011 Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class B2 Flammable liquid D2A Very toxic materials E Corrosive material • Chemical Name NPRI Toluene X Ethyl benzene X Isopropyl alcohol X Sulfuric acid X 16. OTHER INFORMATION Prepared By Amanda Burwell Issuing Date 7/26/06 Revision Date 10-Aug-2011 Reason for Revision New Format. Disclaimer The information provided on this MSDS is correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use,processing,storage,transportation,disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process,unless specified in the text. End of MSDS 10/ 10 MATERIAL SAFETY DATA SHEET ProTreat Technology Corporation P.O. Box 16640 WT-990 Golden, Colorado 80402 (303) 463-1984 Date Prepared: February 1, 1994 SECTION 1 - PRODUCT IDENTIFICATION TRADE NAME: WT-990 Generic Name: Corrosion Inhibitor DOT Proper Shipping Name: Cleaning Compound NOS Class 55 UN/NA Number: None DOT Hazard Class: None NFPA 704M Rating: 1 Health 2 Flammability 0 Reactivity 0 Other 0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme SECTION 2 - HAZARDOUS INGREDIENTS The composition of this mixture may be proprietary information. In the event of a medical emergency, compositional information will be provided to a physician or nurse. This product is hazardous as defined in 29 CFR1910.1200, based on the following compositional information. INGREDIENT(S) CAS # OSHA HAZARD Methanol 67-56-1 Flammable Ethyl Alcohol 64-17-5 Inhalation irritant, flammable SECTION 3 - PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: greater than 200° F Specific Gravity: .92 Vapor Density: NA Percent Volatiles by Volume: appreciable Appearance and Odor: Pale Yellow Liquid; slight alcohol odor Freezing Point: -40° F Vapor Pressure at 20° C: NA Solubility in Water: soluble Evaporation Rate: NA Stability: Stable Incompatibility: Strong oxidizing agents 1 WT-990 Hazardous Polymerization: Will not occur Conditions to Avoid: Avoid heat, sparks and open flames. Avoid contact with strong oxidizing agents. Hazardous Combustion Carbon monoxide, ammonia, carbon or Decomposition Products: dioxide, nitrogen oxides, and unidentified organic compounds may be formed during combustion. NOTE: These physical properties are typical values for this product. • • SECTION 4 - HEALTH EFFECTS INFORMATION EYE CONTACT: Can cause severe irritation. SKIN CONTACT: Repeated or prolonged contact causes drying, brittleness, cracking and irritation. Prolonged and repeated skin contact with methanol-soaked material has produced toxic effects including vision effects and death. Low toxicity to animals by skin contact (minimum lethal dose, monkeys: 1.6 g/kg). INHALATION: High vapor/aerosol concentrations (greater than approximately 1000 ppm) are irritating to the eyes and the respiratory tract, may cause headaches, dizziness, anesthesia, drowsiness, nausea, unconsciousness, and other central nervous system effects. May cause narcosis. INGESTION: Can cause blindness from methanol. Can cause central nervous system depression, nausea, dizziness, vomiting or unconsciousness depending on the length of exposure and on the first aid action given. Can cause liver, kidney damage. Can be fatal. Ingestion may cause irritation to the membranes of the mouth, throat and gastrointestinal tract, cramps and diarrhea may occur. SYMPTOMS OF EXPOSURE: ACUTE: Exposure to 4,000 - 13,000 ppm of methanol was fatal to humans. CHRONIC: Exposure of 1,200 - 8,000 ppm of methanol for four years caused chronic poisoning and dimming of vision. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Because of its defatting properties, prolonged and repeated skin contact may aggravate an existing dermatitis (skin condition). SECTION 5 - FIRST AID INFORMATION EYE CONTACT: Immediately flush with water for at least 15 minutes while holding eyelids open. Call a physician at once. 2 WT-990 SKIN CONTACT: Flush with large amounts of water; use soap if available. Remove grossly contaminated clothing, including shoes, and launder before reuse. If irritation occurs, get medical attention. INHALATION: Using proper respiratory protection, immediately remove the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest. Call for prompt medical attention. INGESTION: If patient is conscious and can swallow, give two glasses of water (16 oz.). Induce vomiting as directed by medical personnel. Never give anything by mouth to an unconscious or convulsing person. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be needed. SECTION 6 - OCCUPATIONAL EXPOSURE LIMITS Methanol = TWA 200 ppm, STEL 250 ppm (skin) ACGIH/TLV 260 mg/m3, 310 mg/m3 ACGIH/TLV Ethyl Alcohol =TWA 800 ppm, STEL 1000 ppm ACGIH/TLV 985 mg/m3 1230 mg/m3 ACGIH/TLV ACUTE ORAL TOXICITY (ALBINO RATS): Methanol LD50 = 9,100 mg/kg ACUTE DERMAL TOXICITY (ALBINO RABBITS): Methanol LD50 = 15,800 mg/kg ACUTE INHALATION TOXICITY (ALBINO RATS): Methanol LD50 = 14,500 ppm (1-hour exposure) PRIMARY SKIN IRRITATION TEST (ALBINO RABBITS): COMMENTS: Methanol, at the product concentration, may cause skin irritation. PRIMARY EYE IRRITATION TEST (ALBINO RABBITS): COMMENTS: Methanol, at the product concentration, may cause eye irritation. 3 WT-990 SECTION 7- PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Airborne concentrations should be kept to lowest levels possible. If vapor, mist or dust is generated, use respirator approved by MSHA or NIOSH as appropriate. Supplied air respiratory protection should be used for cleaning large spills or upon entry into tanks, vessels, or other confined spaces. VENTILATION: General ventilation is recommended. Additionally, local exhaust ventilation is recommended where vapors, mists or aerosols may be released. PROTECTIVE EQUIPMENT: Use impermeable gloves and chemical splash goggles when attaching feeing equipment, doing maintenance or handling product. Examples of impermeable gloves available on the market are neoprene, nitrile, PVC, natural rubber, viton and butyl (compatibility studies have not been performed). Skin Protection: Workers should wash exposed skin several times daily with soap and water. Soiled work clothing should be laundered or dry-cleaned. SECTION 8 - FIRE AND EXPLOSION INFORMATION FLASHPOINT: 105 Deg F. METHOD: TCC NOTE: Minimum FLAMMABLE LIMITS IN AIR, % by volume (methanol): Upper: 36.5 Lower: 5.5 GENERAL HAZARD: Combustible Liquid, can form combustible mixtures at temperatures at or above the flashpoint. Static Discharge, material can accumulate static charges which can cause an incendiary electrical discharge. "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner, or properly disposed of. FIRE FIGHTING: Use water spray to cool fire exposed surfaces and to protect personnel. Isolate "fuel" supply from fire. According to NFPA Guide, use foam, dry chemical, or water spray to extinguish fire. Avoid spraying water directly into storage containers due to danger of boilover. 4 WT-990 This liquid is volatile and gives off invisible vapors. Either the liquid or vapor may settle in low areas or travel some distance along the ground or surface to ignition sources where they may ignite or explode. Firefighters must be equipped to prevent breathing of vapors or products of combustion. Wear an approved self-contained breathing apparatus and protective clothing. HAZARDOUS COMBUSTION PRODUCTS: May evolve NOx under fire conditions. Containers exposed in a fire should be cooled with water to prevent vapor pressure buildup leading to a rupture. SECTION 9 - REACTIVITY INFORMATION STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Heat, sparks, flame. HAZARDOUS DECOMPOSITION PRODUCTS: None INCOMPATIBILITY: Avoid contact with sulfuric acid or strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, NOx, CO2 may be formed. Heating in air may produce irritating aldehydes, acids, and ketones. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 - PRECAUTIONARY LABEL INFORMATION WARNING: Harmful or fatal if swallowed. Contains methanol. May cause blindness if swallowed. Causes irritation to skin and eyes. Combustible. Prolonged inhalation of vapor may be harmful. Do not get in eyes, on skin or on clothing. Wear goggles and face shield when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Do not use, store, spill or pour near heat, sparks or open flame. Wash thoroughly with soap and water after handling. Wash contaminated clothing thoroughly before re-use. Discard contaminated leather clothing. KEEP OUT OF REACH OF CHILDREN. Keep container closed when not in use. Ground all equipment to prevent accumulation of static charge. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. 5 WT-990 SECTION 11 - SPILL AND DISPOSAL INFORMATION SPILL CONTROL AND RECOVERY: Those responsible for control and recovery should wear protective equipment. If it is possible to generate vapors or mists, a NIOSH approved respirator is recommended. Eliminate sources of ignition. Prevent additional discharge of material. Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Prevent liquid from entering sewers, watercourses, or low areas. Contain spilled liquid with sand or earth. Do not use combustible materials such as sawdust. Recover by pumping (use an explosion proof or hand pump) or with a suitable absorbent. Dispose in accordance with local, state and federal regulations. Use qualified disposal company to incinerate, or otherwise discard, at an approved facility. DISPOSAL: If this product becomes a waste, it meets the criteria of a hazardous waste as defined under the Resources Conservation and Recovery Act (RCRA) 40 CFR 261. Hazardous Waste D001. As a hazardous liquid waste, it must be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal facility). A hazardous liquid waste can also be deep-well injected in accordance with local, state, and federal regulations. SECTION 12 - REGULATORY INFORMATION The following regulations apply to this product: TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List(40 CFR 710). CERCLA/SUPERFUND, 40 CFR 117, 302: This product contains methanol, a Reportable Quantity (RQ) substance and if 24,000 pounds of product are released, it requires notification to the NATIONAL RESPONSE CENTER, WASHINGTON, D.C. (1-800-424-8802). 6 WT-990 SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTION 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: X Immediate (acute) health hazard _ Delayed (chronic) health hazard X Fire hazard _ Sudden release of pressure hazard Reactive hazard SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product contains the following ingredient(s), (with CAS if and % range) which appear(s) on the List of Toxic Chemicals. Component CAS NO. MAXIMUM % Methanol 67-56-1 30.0 California Proposition 65: This product contains no known chemicals known to the State of California to cause cancer or reproductive toxicity. SECTION 13 - USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 14 - DISCLAIMERS Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself. 7 WT-990 The information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. This MSDS has been prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200). Date Prepared: February 1, 1994 8 WT-990 Material Safety Data Sheet DIESEL FUEL PETROCANADA 1 . Product and company identification Product name : DIESEL FUEL Synonym : Seasonal Diesel, #1 Diesel, #2 Heating Oil, #1 Heating Oil, D50, D60, P40, P50, Arctic Diesel, Farm Diesel, Marine Diesel, Low Sulphur Diesel, LSD, Ultra Low Sulphur Diesel, ULSD, Mining Diesel, Naval Distillate, Dyed Diesel, Marked Diesel, Coloured Diesel, Furnace special, Biodiesel blend, B1, B2, B5, Diesel Low Cloud (LC). Code : W104, W293 Material uses : Diesel fuels are distillate fuels suitable for use in high and medium speed internal combustion engines of the compression ignition type. Mining diesels, marine diesels, MDO and naval distillates may have a higher flash point requirement. Manufacturer : PETRO-CANADA P.O. Box 2844 150—6th Avenue South-West Calgary, Alberta T2P 3E3 In case of emergency : Petro-Canada: 403-296-3000 Canutec Transportation: 613-996-6666 Poison Control Centre: Consult local telephone directory for emergency number(s). 2 . Hazards identification Physical state : Bright oily liquid. Odor : Mild petroleum oil like. WHMIS (Canada) : •O Class B-3: Combustible liquid with a flash point between 37.8°C (100°F)and 93.3°C (200°F). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). OSHAIHCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Emergency overview : WARNING! COMBUSTIBLE LIQUID AND VAPOR. CAUSES EYE AND SKIN IRRITATION. Combustible liquid. Severely irritating to the skin. Irritating to eyes. Keep away from heat, sparks and flame. Do not get in eyes. Avoid breathing vapor or mist. Avoid contact with skin and clothing. Use only with adequate ventilation. Wash thoroughly after handling. Routes of entry : Dermal contact. Eye contact. Inhalation. Ingestion. Potential acute health effects Inhalation : Inhalation of this product may cause respiratory tract irritation and Central Nervous System (CNS) Depression, symptoms of which may include; weakness, dizziness, slurred speech, drowsiness, unconsciousness and in cases of severe overexposure; coma and death. Ingestion : Ingestion of this product may cause gastro-intestinal irritation. Aspiration of this product may result in severe irritation or burns to the respiratory tract. Skin : Severely irritating to the skin. Eyes : Irritating to eyes. Potential chronic health effects Chronic effects : No known significant effects or critical hazards. Carcinogenicity : Diesel engine exhaust particulate is probably carcinogenic to humans (IARC Group 2A). Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Date of issue : 6/28/2013. Internet www.petro-canada.calmsds Page: 1/8 Petro-Canada is a Suncor Energy business TM Trademark of Suncor Energy Inc.Used under licence. DIESEL FUEL Page Number 2 2 . Hazards identification Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Medical conditions : Avoid prolonged or repeated skin contact to diesel fuels which can lead to dermal aggravated by over- irritation and may be associated with an increased risk of skin cancer. exposure See toxicological information (Section 11) 3 . Composition/information on ingredients Name CAS number %o Hydrotreated Renewable Diesel/ Fuels, diesel/ Fuel Oil No. 1/ Fuel Oil No. 2 64742-81-0/ 95 - 100 68334-30-5/ 8008-20-6/ 68476-30-2 Alkanes, O10-20 Branched and Linear(R100) 928771-01-1 10 - 20 Fatty acids methyl esters 61788-61-2/ 0 - 5 67784-80-9/ 73891-99-3 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 4 . First aid measures Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Ingestion : Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. 5 . Fire-fighting measures Flammability of the product : Combustible liquid Extinguishing media Suitable : Use dry chemical, OO2, water spray(fog)or foam. Not suitable : Do not use water jet. Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Products of combustion : Carbon oxides (CO, CO2), nitrogen oxides (NOx), sulphur oxides (SOx), sulphur compounds (H2S), smoke and irritating vapours as products of incomplete combustion. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA)with a full face-piece operated in positive pressure mode. Date of issue : 6/28/2013. Internet: www.petro-canada.calmsds Page: 2/8 Petro-Canada is a Suncor Energy business TM Trademark of Suncor Energy Inc.Used under licence. DIESEL FUEL Page Number 3 5 . Fire-fighting measures Special remarks on fire : Flammable in presence of open flames, sparks and heat. Vapours are heavier than air hazards and may travel considerable distance to sources of ignition and flash back. This product can accumulate static charge and ignite. Special remarks on : Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or explosion hazards sources of ignition. Runoff to sewer may create fire or explosion hazard. 6 . Accidental release measures Personal precautions : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods for cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion- proof equipment. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. 7 . Handling and storage Handling : Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling)equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. Storage : Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10)and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Ensure the storage containers are grounded/bonded. Date of issue : 6/28/2013. Internet: www.petro-canada.calmsds Page:3/8 Petro-Canada is a Suncor Energy business TM Trademark of Suncor Energy Inc.Used under licence. DIESEL FUEL Page Number 4 8 . Exposure controls/personal protection Ingredient Exposure limits Fuels, diesel ACGIH TLV(United States). Absorbed through skin. TWA: 100 mg/m3, (Inhalable fraction and vapour) 8 hour(s). Fuel oil No. 2 ACGIH TLV(United States). Absorbed through skin. TWA: 100 mg/m3, (Inhalable fraction and vapour) 8 hour(s). Hydrotreated Renewable Diesel ACGIH TLV(United States). Absorbed through skin. TWA: 200 mg/m3 8 hour(s). Fuel oil No. 1 ACGIH TLV(United States). Absorbed through skin. TWA: 200 mg/m3 8 hour(s). Consult local authorities for acceptable exposure limits. Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace atmosphere procedures or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Personal protection Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: organic vapour cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air-supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstances where air-purifying respirators may not provide adequate protection. Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Recommended: nitrile, neoprene, polyvinyl alcohol (PVA), Viton®. Consult your PPE provider for breakthrough times and the specific glove that is best for you based on your use patterns. It should be realized that eventually any material regardless of their imperviousness, will get permeated by chemicals. Therefore, protective gloves should be regularly checked for wear and tear. At the first signs of hardening and cracks, they should be changed. Eyes : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Skin : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure they controls comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Date of issue : 6/28/2013. Internet: www.petro-canada.calmsds Page:4/8 Petro-Canada is a Suncor Energy business TM Trademark of Suncor Energy Inc.Used under licence. DIESEL FUEL Page Number 5 9 . Physical and chemical properties Physical state : Bright oily liquid. Flash point : Diesel fuel and other distillate fuels: Closed cup:>40°C (>104°F) Marine Diesel/MDO/Naval Distillate: Closed Cup: >60°C (>140°F) Mining Diesel: Closed Cup: >52°C (>126°F) Auto-ignition temperature : 225°C (437°F) Flammable limits : Lower: 0.7% Upper: 6% Color : Clear to yellow(This product may be dyed red for taxation purposes). Odor : Mild petroleum oil like. Odor threshold : Not available. pH : Not available. Boiling/condensation point : 150 to 371°C (302 to 699.8°F) Melting/freezing point : Not available. Relative density : 0.80 to 0.88 kg/L @ 15°C (59°F) Vapor pressure : 1 kPa (7.5 mm Hg) @ 20°C (68°F). Vapor density : 4.5 [Air= 1] Volatility : Not available. Evaporation rate : Not available. Viscosity : Diesel fuel: 1.3 -4.1 cSt @ 40°C (104°F) Marine Diesel Fuel: 1.3-4.4 cSt @ 40°C (104°F) Pour point : Not available. Solubility : Insoluble in cold water, soluble in non-polar hydrocarbon solvents. 10 . Stability and reactivity Chemical stability : The product is stable. Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur. Materials to avoid : Reactive with oxidizing agents and acids. Hazardous decomposition : May release COx, NOx, SOx, H2S, smoke and irritating vapours when heated to products decomposition. 11 . Toxicological information Acute toxicity Product/ingredient name Result Species Dose Exposure Fuels, diesel LD50 Dermal Mouse 24500 mg/kg - LD50 Oral Rat 7500 mg/kg - Fuel oil No. 2 LD50 Oral Rat 12000 mg/kg - Fuel oil No. 1 LD50 Dermal Rabbit >2000 mg/kg - LD50 Oral Rat >5000 mg/kg - LC50 Inhalation Rat >5000 mg/m3 4 hours Vapor Hydrotreated Renewable Diesel LD50 Dermal Rabbit >2000 mg/kg - LD50 Oral Rat >5000 mg/kg - LC50 Inhalation Rat >5200 mg/m3 4 hours Vapor Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available. Irritation/Corrosion Conclusion/Summary : Not available. Sensitizer Date of issue : 6/28/2013. Internet: www.petro-canada.calmsds Page: 5/8 Petro-Canada is a Suncor Energy business TM Trademark of Suncor Energy Inc.Used under licence. DIESEL FUEL Page Number 6 11 . Toxicological information Conclusion/Summary : Not available. Carcinogenicity Conclusion/Summary : Diesel engine exhaust particulate is probably carcinogenic to humans (IARC Group 2A). Classification Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHA Fuels, diesel A3 3 - - - - Fuel oil No. 1 A3 3 - - - - Fuel oil No. 2 A3 3 - - - - Hydrotreated Renewable Diesel A3 3 - - - - Mutagenicity Conclusion/Summary : Not available. Teratogenicity Conclusion/Summary : Not available. Reproductive toxicity Conclusion/Summary : Not available. 12 . Ecological information Environmental effects : No known significant effects or critical hazards. Aquatic ecotoxicity Conclusion/Summary : Not available. Biodegradability Conclusion/Summary : Not available. 13 . Disposal considerations Waste disposal : The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. 14 . Transport information Regulatory UN number Proper shipping Classes PG* Label Additional information name information TDG Classification UN1202 DIESEL FUEL 3 III - DOT Classification Not available. Not available. Not available. - - Date of issue : 6/28/2013. Internet: www.petro-canada.calmsds Page: 6/8 Petro-Canada is a Suncor Energy business TM Trademark of Suncor Energy Inc.Used under licence. DIESEL FUEL Page Number 7 14 . Transport information PG* : Packing group 15 . Regulatory information United States HCS Classification : Combustible liquid Irritating material Canada WHMIS (Canada) : Class B-3: Combustible liquid with a flash point between 37.8°C (100°F)and 93.3°C (200°F). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. International regulations Canada inventory : All components are listed or exempted. United States inventory : All components are listed or exempted. (TSCA 8b) Europe inventory : All components are listed or exempted. 16 . Other information Label requirements : COMBUSTIBLE LIQUID AND VAPOR. CAUSES EYE AND SKIN IRRITATION. Hazardous Material 2 Information System (U.S.A.) 2 FI mm .ility 0 Personal protection H National Fire Protection Association (U.S.A.) Flammability Health 2 0 Instability Special References : Available upon request. TM Trademark of Suncor Energy Inc. Used under licence. Date of printing : 6/28/2013. Date of issue : 28 June 2013 Date of previous issue : 6/28/2013. Responsible name : Securite de produit - KKB Indicates information that has changed from previously issued version. For Copy of(M)SDS : Internet: www.petro-canada.ca/msds Canada-wide: telephone: 1-800-668-0220; fax: 1-800-837-1228 For Product Safety Information: (905) 804-4752 Notice to reader Date of issue : 6/28/2013. Internet www.petro-canada.ca/msds Page: 7/8 Petro-Canada is a Suncor Energy business TM Trademark of Suncor Energy Inc.Used under licence. DIESEL FUEL Page Number 8 16 . Other information To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue : 6/28/2013. Internet: www.petro-canada.calmsds Page: 8/8 Petro-Canada is a Suncor Energy business TM Trademark of Suncor Energy Inc.Used under licence. THATCHER COMPANY MATERIAL SAFETY DATA SHEET PRODUCT: HYDROCHLORIC ACID (22 BAUME) , Page 1 of 4 MSDS Date: October 28, 2010 Emergency Contact: 1-800-424-9300 SECTION I PRODUCT NAME: Hydrochloric Acid(22°Baumd) CHEMICAL NAME: Hydrochloric Acid CHEMICAL FAMILY: Inorganic Acid FORMULA: HCI DOT SHIPPING INFORMATION: Hydrochloric Acid Solution 8,UN 1789,PG II SECTION II-HAZARDOUS INGREDIENTS This material contains no ingredients which are known by Thatcher Company to be hazardous unless listed below, HAZARDOUS MATERIAL CAS NUMBER w/w% EXPOSURE LIMITS IN AIR Hydrochloric Acid 7647-01-0 35.2 ACGIH TLV=5 ppm(7 mg/m3) The specific identity of some ingredients may be withheld for confidential business purposes. However,all known potential health effects from exposure to these ingredients are being addressed. This product is subject to the reporting requirement of EPCRA Section 313 (40 CFT Part 372) SECTION III-HEALTH HAZARD DATA NEPA HAZARD RATING Health= 3 Flammability= 0 Reactivity= I Carcinogenic Listing: NTP: No ingredients listed in this section. IARC MONOGRAPHS: No ingredients listed in this section. OSHA 29 CFR 1910: No ingredients listed in this section. ENTRY ROUTES& EFFECTS OF OVEREXPOSURE: Contact Can cause severe burns to eyes,skin and mucous membranes. Inhalation Vapor can causes severe irritation or bums to respiratory tract. Ingestion Can causes severe burns to the gastrointestinal system,which could result in death. Thatcher Company, P.O. Box 27407, Salt Lake City, Utah 84127 THATCHER COMPANY MATERIAL SAFETY DATA SHEET PRODUCT: HYDROCHLORIC ACID (22 BAUME) r Page 2 of 4 STATEMENT OF PRACTICAL TREATMENT: Contact Immediately flush exposed area thoroughly with water for at least 15 minutes while removing contaminated clothing and shoes. Consult a physician. For eyes,flush with large amounts of cool water for at least 15 minutes. Get medical attention immediately. Inhalation Remove to fresh air. If not breathing,begin artificial respiration. If breathing is difficult.give oxygen. Get medical attention immediately. Ingestion If swallowed,do not induce vomiting. Give several glasses of water or milk.If vomiting occurs spontaneously,keep airway clear.Get medical attention immediately. SECTION IV- FIRE AND EXPLOSION DATA. FLASH POINT: Nonflammable. FLAMMABLE LIMITS: UEL: N/A LEL: N/A EXTINGUISHING MEDIA: Water spray,dry chemicals,foam or carbon dioxide. SPECIAL FIRE-FIGHTING PROCEDURES: When heated,hydrochloric acid releases hydrogen chloride gas. Use a self-contained respirator if heating occurs. Hydrochloric acid reacts with steel and many common metals to produce hydrogen gas,which is highly flammable and a fire and explosion hazard. SECTION V-SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: Self-contained organic respirator should be available. VENTILATION: Use ventilation to maintain TLV below 5 ppm. EYE PROTECTION: Full face shield, chemical goggles. SKIN PROTECTION: Acid suit,rubber boots, impervious gloves. OTHER PROTECTIVE EQUIPMENT: As needed to avoid all bodily contact and breathing of vapor. Thatcher Company, P.O. Box 27407, Salt Lake City, Utah 84127 THATCHER COMPANY MATERIAL SAFETY DATA SHEET PRODUCT: HYDROCHLORIC ACID (22 BAUME) Page 3 of 4 SECTION VI-SPECIAL PRECAUTIONS HANDLING AND STORAGE PRECAUTIONS: Keep container tightly closed. Store in a cool,dry area protected from corrosion. Store away from other chemicals such as oxidizing agents,bases or metals. SECTION VII- PHYSICAL DATA MELTING POINT C(F): -34 C(-29F) BOILING POINT C (F): 61 C (142 F) DENSITY: 1.18 VAPOR PRESSURE(mmHg): 80 at 20 C pH: <1 EVAPORATION RATE: Similar to water APPEARANCE AND ODOR: Clear,colorless to slightly yellow liquid with pungent odor. SECTION VIII-REACTIVITY DATA STABILITY: Stable. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS OR MATERIALS TO AVOID: Avoid contact with metals and sulfides. Contact with metals produces flammable or explosive hydrogen. Contact with sulfides releases poisonous hydrogen sulfide gas. Avoid contact with bases or any other chemicals. HAZARDOUS DECOMPOSITION PRODUCTS: Hydrochloric acid is stable; however,highly corrosive hydrogen chloride gas and hydrochloric acid vapor is released at above boiling temperatures. SECTION IX-SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL SPILLS OR LEAKS: Evacuate area. Wear proper safety gear. For small spills,neutralize with soda ash and, if permitted, flush to sewer with large amounts of water. For larger spills, dike the liquid and recover as much as possible into polyethylene drums. Neutralize residue with soda ash and flush to sewer with large amounts of water,if permitted.Comply with applicable government regulations. WASTE DISPOSAL METHOD: Hydrochloric acid is an EPA hazardous waste due to corrosivity and must be disposed of by an EPA approved hazardous waste facility. Comply with all local, state and federal regulations. Thatcher Company, P.O. Box 27407, Salt Lake City, Utah 84127 THATCHER COMPANY MATERIAL SAFETY DATA SHEET PRODUCT: HYDROCHLORIC ACID (22 BAUME) (14) Page 4 of 4 Cl. to SECTION X-REGULATORY INFORMATION CHEMICAL INVENTORY STATUS: Ingredient TSCA EC Japan Australia Korea Canada Phil DSL NDSL drochloric Acid 7647-01-0 Water 7732-18-5 Y Y Y Y Y Y N Y ACGIH=American Conference of Governmental Industrial Hygienists CL =Ceiling Level IARC —International Agency for Research on Cancer: Monographs OSHA =Occupational Safety and Health Administration N/D =Not Determined N/A =Not Applicable NTP =National Toxicology Program:Annual Report on Carcinogens PEL =Permissible Exposure Level(OSHA) TLV =Threshold Limit Value(ACGIH) • TWA =Time Weighted Average over 8 Hours This information is,to the best of our knowledge,accurate but may not be complete.THATCHER COMPANY furnishes this information in good faith,but without warranty,representation or guarantee of its accuracy, completeness,or reliability. Thatcher Company, P.O. Box 27407, Salt Lake City, Utah 84127 MATERIAL SAFETY DATA SHEET VALERO 1. Product and Company Identification Material name UNLEADED GASOLINE Version# 03 Issue date 07-28-2011 Revision date 11-13-2012 Supersedes date 09-28-2012 MSDS Number 002 Product use Motor fuels. Synonym(s) Regular/Premium/Midgrade- Unleaded Gasoline, RFG-Reformulated Unleaded Gasoline, Conventional Unleaded Gasoline, Oxygenated Unleaded Gasoline, Non-Oxygenated Unleaded Gasoline, CARB(California Air Resource Board) Unleaded Gasoline, RBOB- Reformulated Blendstock for Oxygenate Blending, CBOB-Conventional Blendstock for Oxygenate Blending, Petrol, Motor Fuel. See section 16 for complete information. Manufacturer/Supplier Valero Marketing &Supply Company and Affiliates P.O. Box 696000 San Antonio, TX 78269-6000 General Assistance 210-345-4593 Emergency 24 Hour Emergency 866-565-5220 1-800-424-9300(CHEMTREC USA) 2. Hazards Identification Physical state Liquid. Appearance Light straw to red clear liquid with characteristic strong odor of gasoline. Emergency overview DANGER! Extremely flammable liquid and vapor-vapor may cause flash fire.Will be easily ignited by heat, spark or flames. Heat may cause the containers to explode. Harmful if inhaled, absorbed through skin,or swallowed.Aspiration may cause lung damage. Irritating to eyes, respiratory system and skin. In high concentrations, vapors and spray mists are narcotic and may cause headache,fatigue, dizziness and nausea. Contains benzene. Cancer hazard-can cause cancer. Mutagen. May cause heritable genetic damage. May cause adverse reproductive effects-such as birth defects, miscarriages, or infertility.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Static accumulating flammable materials can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite material and vapor may cause flash fire(or explosion). OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication). Potential health effects Routes of exposure Inhalation. Ingestion. Skin contact. Eye contact. Eyes Contact may irritate or burn eyes. Eye contact may result in corneal injury. Skin Harmful if absorbed through skin. Irritating to skin. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Inhalation Harmful if inhaled. Irritating to respiratory system. In high concentrations, vapors and spray mists are narcotic and may cause headache,fatigue,dizziness and nausea. May cause breathing disorders and lung damage. May cause cancer by inhalation. Prolonged inhalation may be harmful. Ingestion Harmful if swallowed. Ingestion may result in vomiting; aspiration (breathing)of vomitus into lungs must be avoided as even small quantities may result in aspiration pneumonitis. Irritating to mouth, throat, and stomach. Target organs Blood. Eyes. Liver. Respiratory system. Skin. Kidneys. Central nervous system. UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 1 /17 Prepared by 3E Company Chronic effects Cancer hazard. Contains material which may have reproductive toxicity, teratogenetic or mutagenic effects. Liver injury may occur. Kidney injury may occur. May cause central nervous system disorder(e.g., narcosis involving a loss of coordination,weakness,fatigue, mental confusion and blurred vision)and/or damage. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Signs and symptoms Irritation of nose and throat. Irritation of eyes and mucous membranes. Skin irritation. Unconsciousness. Corneal damage. Narcosis. Cyanosis(blue tissue condition, nails, lips, and/or skin). Decrease in motor functions. Behavioral changes. Edema. Liver enlargement. Jaundice. Conjunctivitis. Proteinuria. Defatting of the skin. Rash. Potential environmental effects Toxic to aquatic organisms. Harmful to aquatic life with long lasting effects. 3. Composition / Information on Ingredients Components CAS# Percent Gasoline 86290-81-5 0-100 Toluene 108-88-3 0-30 Hexane(Other Isomers) 96-14-0 5-25 Xylene (o, m, p isomers) 1330-20-7 0-25 Octane(All isomers) 111-65-9 0-18.5 Ethanol 64-17-5 0-10 1,2,4, Trimethylbenzene 95-63-6 0-6 n-Heptane 142-82-5 1-5 Pentane 109-66-0 1-5 Cumene 98-82-8 0-5 Ethylbenzene 100-41-4 0-5 Benzene 71-43-2 0-4.9 n-Hexane 110-54-3 0-3 Cyclohexane 110-82-7 0-3 4. First Aid Measures First aid procedures Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. Skin contact Remove contaminated clothing and shoes. Wash off immediately with soap and plenty of water. Get medical attention if irritation develops or persists.Wash clothing separately before reuse. Destroy or thoroughly clean contaminated shoes. If high pressure injection under the skin occurs, always seek medical attention. Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. Ingestion Rinse mouth thoroughly. Do not induce vomiting without advice from poison control center. Do not give mouth-to-mouth resuscitation. If vomiting occurs, keep head low so that stomach content does not get into the lungs. Get medical attention immediately. Notes to physician In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. General advice If exposed or concerned: get medical attention/advice. Ensure that medical personnel are aware of the material(s)involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.Wash contaminated clothing before re-use. 5. Fire Fighting Measures Flammable properties Flammable by OSHA criteria. Containers may explode when heated. Extinguishing media Suitable extinguishing Water spray. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). media Unsuitable extinguishing Do not use a solid water stream as it may scatter and spread fire. media UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 2/17 Prepared by 3E Company Protection of firefighters Specific hazards arising Vapor may cause flash fire.Vapors can flow along surfaces to distant ignition source and flash from the chemical back. Sensitive to static discharge. Protective equipment and Wear full protective clothing, including helmet, self-contained positive pressure or pressure precautions for firefighters demand breathing apparatus, protective clothing and face mask. Fire fighting Wear full protective clothing, including helmet, self-contained positive pressure or pressure equipment/instructions demand breathing apparatus, protective clothing and face mask. Withdraw immediately in case of rising sound from venting safety devices or any discoloration of tanks due to fire. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Move containers from fire area if you can do it without risk. In the event of fire, cool tanks with water spray. Cool containers exposed to flames with water until well after the fire is out. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Vapors may form explosive air mixtures even at room temperature. Prevent buildup of vapors or gases to explosive concentrations. Some of these materials, if spilled, may evaporate leaving a flammable residue.Water runoff can cause environmental damage. Use compatible foam to minimize vapor generation as needed. Specific methods In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened containers. Hazardous combustion Carbon monoxide. Carbon Dioxide. Sulfur oxides. Nitrogen oxides(NOx). Hydrocarbons. products 6. Accidental Release Measures Personal precautions Keep unnecessary personnel away. Local authorities should be advised if significant spills cannot be contained. Keep upwind. Keep out of low areas. Ventilate closed spaces before entering. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. See Section 8 of the MSDS for Personal Protective Equipment. Environmental precautions Gasoline may contain oxygenated blend products (Ethanol, etc.)that are soluble in water and therefore precautions should be taken to protect surface and groundwater sources from contamination. If facility or operation has an"oil or hazardous substance contingency plan", activate its procedures. Stay upwind and away from spill.Wear appropriate protective equipment including respiratory protection as conditions warrant. Do not enter or stay in area unless monitoring indicates that it is safe to do so. Isolate hazard area and restrict entry to emergency crew. Extremely flammable. Review Firefighting Measures, Section 5, before proceeding with clean up. Keep all sources of ignition (flames, smoking,flares, etc.)and hot surfaces away from release. Contain spill in smallest possible area. Recover as much product as possible (e.g. by vacuuming). Stop leak if it can be done without risk. Use water spray to disperse vapors. Use compatible foam to minimize vapor generation as needed. Spilled material may be absorbed by an appropriate absorbent, and then handled in accordance with environmental regulations. Prevent spilled material from entering sewers, storm drains, other unauthorized treatment or drainage systems and natural waterways. Contact fire authorities and appropriate federal, state and local agencies. If spill of any amount is made into or upon navigable waters,the contiguous zone, or adjoining shorelines, contact the National Response Center at 1-800-424-8802. For highway or railways spills, contact Chemtrec at 1-800-424-9300. Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. This material is a water pollutant and should be prevented from contaminating soil or from entering sewage and drainage systems and bodies of water. Dike the spilled material, where this is possible. Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up Use non-sparking tools and explosion-proof equipment. Small Spills:Absorb spill with vermiculite or other inert material, then place in a container for chemical waste. Clean surface thoroughly to remove residual contamination.This material and its container must be disposed of as hazardous waste. Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent product from entering drains. Do not allow material to contaminate ground water system. Should not be released into the environment. Other information Clean up in accordance with all applicable regulations. UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 3/17 Prepared by 3E Company 7. Handling and Storage Handling Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Wear personal protective equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Do not taste or swallow.Avoid prolonged exposure. Use only with adequate ventilation.Wash thoroughly after handling.The product is extremely flammable, and explosive vapor/air mixtures may be formed even at normal room temperatures. DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight.Take precautionary measures against static discharges.All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. When using, do not eat, drink or smoke. Avoid release to the environment. Storage Flammable liquid storage. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. The pressure in sealed containers can increase under the influence of heat. Keep container tightly closed in a cool,well-ventilated place. Keep away from food, drink and animal feedingstuffs. Keep out of the reach of children. 8. Exposure Controls / Personal Protection Occupational exposure limits US.ACGIH Threshold Limit Values Components Type Value 1,2,4, Trimethylbenzene TWA 25 ppm (CAS 95-63-6) Benzene(CAS 71-43-2) STEL 2.5 ppm TWA 0.5 ppm Cumene (CAS 98-82-8) TWA 50 ppm Cyclohexane(CAS TWA 100 ppm 110-82-7) Ethanol (CAS 64-17-5) STEL 1000 ppm Ethylbenzene (CAS TWA 20 ppm 100-41-4) Gasoline(CAS 86290-81-5) STEL 500 ppm TWA 300 ppm Hexane(Other Isomers) STEL 1000 ppm (CAS 96-14-0) TWA 500 ppm n-Heptane(CAS 142-82-5) STEL 500 ppm TWA 400 ppm n-Hexane (CAS 110-54-3) TWA 50 ppm Octane(All isomers)(CAS TWA 300 ppm 111-65-9) Pentane (CAS 109-66-0) TWA 600 ppm Toluene (CAS 108-88-3) TWA 20 ppm Xylene (o, m, p isomers) STEL 150 ppm (CAS 1330-20-7) TWA 100 ppm US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Components Type Value Benzene(CAS 71-43-2) STEL 5 ppm TWA 1 ppm US. OSHA Table Z-1 Limits for Air Contaminants(29 CFR 1910.1000) Components Type Value Cumene (CAS 98-82-8) PEL 245 mg/m3 50 ppm Cyclohexane(CAS PEL 1050 mg/m3 110-82-7) 300 ppm Ethanol (CAS 64-17-5) PEL 1900 mg/m3 UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 4/17 Prepared by 3E Company US. OSHA Table Z-1 Limits for Air Contaminants(29 CFR 1910.1000) Components Type Value 1000 ppm Ethylbenzene(CAS PEL 435 mg/m3 100-41-4) 100 ppm n-Heptane(CAS 142-82-5) PEL 2000 mg/m3 500 ppm n-Hexane (CAS 110-54-3) PEL 1800 mg/m3 500 ppm Octane(All isomers)(CAS PEL 2350 mg/m3 111-65-9) 500 ppm Pentane (CAS 109-66-0) PEL 2950 mg/m3 1000 ppm Xylene (o, m, p isomers) PEL 435 mg/m3 (CAS 1330-20-7) 100 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) Components Type Value Benzene(CAS 71-43-2) Ceiling 25 ppm TWA 10 ppm Toluene (CAS 108-88-3) Ceiling 300 ppm TWA 200 ppm Canada.Alberta OELs (Occupational Health &Safety Code, Schedule 1,Table 2) Components Type Value 1,2,4, Trimethylbenzene TWA 123 mg/m3 (CAS 95-63-6) 25 ppm Benzene(CAS 71-43-2) STEL 8 mg/m3 2.5 ppm TWA 1.6 mg/m3 0.5 ppm Cumene (CAS 98-82-8) TWA 246 mg/m3 50 ppm Cyclohexane(CAS TWA 344 mg/m3 110-82-7) 100 ppm Ethanol (CAS 64-17-5) TWA 1880 mg/m3 1000 ppm Ethylbenzene (CAS STEL 543 mg/m3 100-41-4) 125 ppm TWA 434 mg/m3 100 ppm Gasoline(CAS 86290-81-5) STEL 500 ppm TWA 300 ppm Hexane(Other Isomers) STEL 3500 mg/m3 (CAS 96-14-0) 1000 ppm TWA 1760 mg/m3 500 ppm n-Heptane(CAS 142-82-5) STEL 2050 mg/m3 500 ppm TWA 1640 mg/m3 400 ppm n-Hexane (CAS 110-54-3) TWA 176 mg/m3 50 ppm UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 5/17 Prepared by 3E Company Canada.Alberta OELs (Occupational Health &Safety Code, Schedule 1,Table 2) Components Type Value Octane(All isomers)(CAS TWA 1400 mg/m3 111-65-9) 300 ppm Pentane (CAS 109-66-0) TWA 1770 mg/m3 600 ppm Toluene (CAS 108-88-3) TWA 188 mg/m3 50 ppm Xylene (o, m, p isomers) STEL 651 mg/m3 (CAS 1330-20-7) 150 ppm TWA 434 mg/m3 100 ppm Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97,as amended) Components Type Value 1,2,4, Trimethylbenzene TWA 25 ppm (CAS 95-63-6) Benzene(CAS 71-43-2) STEL 2.5 ppm TWA 0.5 ppm Cumene (CAS 98-82-8) STEL 75 ppm TWA 25 ppm Cyclohexane(CAS TWA 100 ppm 110-82-7) Ethanol (CAS 64-17-5) STEL 1000 ppm Ethylbenzene (CAS TWA 20 ppm 100-41-4) Gasoline(CAS 86290-81-5) STEL 500 ppm TWA 300 ppm Hexane(Other Isomers) TWA 200 ppm (CAS 96-14-0) n-Heptane(CAS 142-82-5) STEL 500 ppm TWA 400 ppm n-Hexane (CAS 110-54-3) TWA 20 ppm Octane(All isomers)(CAS TWA 300 ppm 111-65-9) Pentane (CAS 109-66-0) TWA 600 ppm Toluene (CAS 108-88-3) TWA 20 ppm Xylene (o, m, p isomers) STEL 150 ppm (CAS 1330-20-7) TWA 100 ppm Canada.Ontario OELs.(Control of Exposure to Biological or Chemical Agents) Components Type Value 1,2,4, Trimethylbenzene TWA 25 ppm (CAS 95-63-6) Benzene(CAS 71-43-2) STEL 2.5 ppm TWA 0.5 ppm Cumene (CAS 98-82-8) TWA 50 ppm Cyclohexane(CAS TWA 100 ppm 110-82-7) Ethanol (CAS 64-17-5) STEL 1000 ppm Ethylbenzene(CAS STEL 125 ppm 100-41-4) TWA 100 ppm Gasoline(CAS 86290-81-5) STEL 500 ppm TWA 300 ppm Hexane (Other Isomers) STEL 1000 ppm (CAS 96-14-0) TWA 500 ppm UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 6/17 Prepared by 3E Company Canada.Ontario OELs.(Control of Exposure to Biological or Chemical Agents) Components Type Value n-Heptane(CAS 142-82-5) STEL 500 ppm TWA 400 ppm n-Hexane (CAS 110-54-3) TWA 50 ppm Octane(All isomers)(CAS TWA 300 ppm 111-65-9) Pentane (CAS 109-66-0) STEL 2210 mg/m3 750 ppm TWA 1770 mg/m3 600 ppm Toluene (CAS 108-88-3) TWA 20 ppm Xylene (o, m, p isomers) STEL 150 ppm (CAS 1330-20-7) TWA 100 ppm Canada.Quebec OELs. (Ministry of Labor-Regulation Respecting the Quality of the Work Environment) Components Type Value 1,2,4, Trimethylbenzene TWA 123 mg/m3 (CAS 95-63-6) 25 ppm Benzene(CAS 71-43-2) STEL 15.5 mg/m3 5 ppm TWA 3 mg/m3 1 ppm Cumene (CAS 98-82-8) TWA 246 mg/m3 50 ppm Cyclohexane(CAS TWA 1030 mg/m3 110-82-7) 300 ppm Ethanol (CAS 64-17-5) TWA 1880 mg/m3 1000 ppm Ethylbenzene(CAS STEL 543 mg/m3 100-41-4) 125 ppm TWA 434 mg/m3 100 ppm Hexane(Other Isomers) STEL 3500 mg/m3 (CAS 96-14-0) 1000 ppm TWA 1760 mg/m3 500 ppm n-Heptane(CAS 142-82-5) STEL 2050 mg/m3 500 ppm TWA 1640 mg/m3 400 ppm n-Hexane (CAS 110-54-3) TWA 176 mg/m3 50 ppm Octane (All isomers) (CAS STEL 1750 mg/m3 111-65-9) 375 ppm TWA 1400 mg/m3 300 ppm Pentane (CAS 109-66-0) TWA 350 mg/m3 120 ppm Toluene (CAS 108-88-3) TWA 188 mg/m3 50 ppm Xylene (o, m, p isomers) STEL 651 mg/m3 (CAS 1330-20-7) 150 ppm TWA 434 mg/m3 UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 7/17 Prepared by 3E Company Canada.Quebec OELs. (Ministry of Labor-Regulation Respecting the Quality of the Work Environment) Components Type Value 100 ppm Mexico. Occupational Exposure Limit Values Components Type Value 1,2,4, Trimethylbenzene STEL 170 mg/m3 (CAS 95-63-6) 35 ppm TWA 125 mg/m3 25 ppm Benzene(CAS 71-43-2) STEL 16 mg/m3 5 ppm TWA 3.2 mg/m3 1 ppm Cumene (CAS 98-82-8) STEL 365 mg/m3 75 ppm TWA 245 mg/m3 50 ppm Cyclohexane(CAS STEL 1300 mg/m3 110-82-7) 375 ppm TWA 1050 mg/m3 300 ppm Ethanol (CAS 64-17-5) TWA 1900 mg/m3 1000 ppm Ethylbenzene(CAS STEL 545 mg/m3 100-41-4) 125 ppm TWA 435 mg/m3 100 ppm Hexane (Other Isomers) STEL 3500 mg/m3 (CAS 96-14-0) 1000 ppm TWA 1760 mg/m3 500 ppm n-Heptane(CAS 142-82-5) STEL 2000 mg/m3 500 ppm TWA 1600 mg/m3 400 ppm n-Hexane (CAS 110-54-3) TWA 176 mg/m3 50 ppm Octane(All isomers)(CAS STEL 1800 mg/m3 111-65-9) 375 ppm TWA 1450 mg/m3 300 ppm Pentane (CAS 109-66-0) STEL 2250 mg/m3 760 ppm TWA 1800 mg/m3 600 ppm Toluene (CAS 108-88-3) TWA 188 mg/m3 50 ppm Xylene (o, m, p isomers) STEL 655 mg/m3 (CAS 1330-20-7) 150 ppm TWA 435 mg/m3 100 ppm UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 8/17 Prepared by 3E Company Engineering controls Provide adequate general and local exhaust ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof equipment. Personal protective equipment Eye/face protection Wear safety glasses. If splash potential exists, wear full face shield or chemical goggles. Skin protection Wear chemical-resistant, impervious gloves. Full body suit and boots are recommended when handling large volumes or in emergency situations. Flame retardant protective clothing is recommended. Respiratory protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workplace exposure limits for product or components are exceeded, NIOSH approved equipment should be worn. Proper respirator selection should be determined by adequately trained personnel, based on the contaminants, the degree of potential exposure and published respiratory protection factors.This equipment should be available for nonroutine and emergency use. General hygiene Consult supervisor for special handling instructions. Avoid contact with eyes.Avoid contact with considerations skin. Keep away from food and drink. Wash hands before breaks and immediately after handling the product. Provide eyewash station and safety shower. Handle in accordance with good industrial hygiene and safety practice. 9. Physical & Chemical Properties Appearance Light straw to red clear liquid with characteristic strong odor of gasoline. Physical state Liquid. Form Liquid. Color Light straw to red clear. Odor Characteristic Gasoline Odor(Strong). Odor threshold Not available. pH Not available. Vapor pressure 60.8- 101.3 kPa (20°C) Vapor density 3-4(Air=1) Boiling point 80.1 -440.1 °F(26.7-226.7 °C) Melting point/Freezing point 44°F(6.67 °C) May start to solidify at this temperature. This is based on data for the following ingredient: Cyclohexane. Weighted average: -91.9 deg C (-133.4 deg F) Solubility(water) Very slightly soluble. Specific gravity 0.66-0.75(Water=1) (60°F) Flash point -40 °F (-40°C)(closed cup) Flammability limits in air, 7.1 % upper,% by volume Flammability limits in air, 1.3% lower, % by volume Auto-ignition temperature > 500 °F (>260 °C) VOC 100% Evaporation rate 10- 11 BuAc Other data Flash point class Flammable IA 10. Chemical Stability & Reactivity Information Chemical stability Stable under normal temperature conditions and recommended use. Conditions to avoid Heat,flames and sparks. Ignition sources. Contact with incompatible materials. Do not pressurize, cut, weld, braze, solder, drill,grind or expose empty containers to heat,flame, sparks, static electricity, or other sources of ignition;they may explode and cause injury or death. Incompatible materials Strong oxidizing agents. Hazardous decomposition Carbon oxides. Sulfur oxides. Nitrogen oxides(NOx). Hydrocarbons. products Possibility of hazardous Hazardous polymerization does not occur. reactions UNLEADED GASOLINE 3536 Version/1:03 Revison date: 11-13-2012 Print date: 11-13-2012 9/17 Prepared by 3E Company 11. Toxicological Information Toxicological data Components Species Test Results 1,2,4, Trimethylbenzene (CAS 95-63-6) Acute Dermal LD50 Rabbit > 3160 mg/kg Inhalation LC50 Rat >2000 mg/I,48 Hours Oral LD50 Rat 6 g/kg Benzene(CAS 71-43-2) Acute Oral LD50 Rat 3306 mg/kg Cumene (CAS 98-82-8) Acute Inhalation LC50 Mouse 2000 mg/I, 7 Hours Rat 8000 mg/I,4 Hours Oral LD50 Rat 1400 mg/kg 2.91 g/kg Cyclohexane(CAS 110-82-7) Acute Oral LD50 Rat 12705 mg/kg Ethanol (CAS 64-17-5) Acute Inhalation LC50 Rat 30000 mg/m3 Oral LD50 Rat 11.5 g/kg Ethylbenzene (CAS 100-41-4) Acute Dermal LD50 Rabbit > 5000 mg/kg Oral LD50 Rat 5.46 g/kg n-Heptane(CAS 142-82-5) Acute Inhalation LC50 Rat 103 mg/I,4 Hours Octane(All isomers)(CAS 111-65-9) Acute Inhalation LC50 Rat 118 mg/I,4 Hours Pentane (CAS 109-66-0) Acute Inhalation LC50 Rat 364 mg/I,4 Hours UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 10/17 Prepared by 3E Company Components Species Test Results Toluene (CAS 108-88-3) Acute Dermal LD50 Rabbit 14.1 ml/kg Inhalation LC50 Rat 49000 mg/m',4 Hours Oral LD50 Rat 636 mg/kg Xylene (o, m, p isomers)(CAS 1330-20-7) Acute Oral LD50 Rat 4300 mg/kg Sensitization This substance may have a potential for sensitization which may provoke an allergic reaction among sensitive individuals. Acute effects Harmful if inhaled, absorbed through skin,or swallowed. Harmful: may cause lung damage if swallowed. Irritating to eyes, respiratory system and skin. In high concentrations, vapors and spray mists are narcotic and may cause headache,fatigue, dizziness and nausea. Local effects US.ACGIH Threshold Limit Values Benzene(CAS 71-43-2) Can be absorbed through the skin. n-Hexane (CAS 110-54-3) Can be absorbed through the skin. Chronic effects Repeated exposure of laboratory animals to high concentrations of gasoline vapors has caused kidney damage and cancer in rats and cancer in mice. Gasoline was evaluated for genetic activity in assays using microbial cells, cultured mammalian cells and rat bone marrow cells. The results were all negative so gasoline was considered nonmutagenic under these conditions. Overexposure to this product or its components has been suggested as a cause of liver abnormalities in laboratory animals and humans. Lifetime studies by the American Petroleum Institute have shown that kidney damage and kidney cancer can occur in male rats after prolonged inhalation exposures at elevated concentrations of total gasoline. Kidneys of mice and female rats were unaffected. The U.S. EPA Risk Assessment Forum has concluded that the male rat kidney tumor results are not relevant for humans. Total gasoline exposure also produced liver tumors in female mice only. The implication of these data for humans has not been determined. Subchronic effects Subchronic inhalation of benzene by rats produced decreased white blood cell counts, decreased bone marrow cell activity, increased red blood cell activity and cataracts. Blood disorders may occur after prolonged inhalation, prolonged skin contact and/or ingestion. Liver and kidney damage may occur after prolonged and repeated exposure. Carcinogenicity ACGIH Carcinogens Benzene(CAS 71-43-2) Al Confirmed human carcinogen. Ethanol (CAS 64-17-5) A3 Confirmed animal carcinogen with unknown relevance to humans. Ethylbenzene (CAS 100-41-4) A3 Confirmed animal carcinogen with unknown relevance to humans. Gasoline(CAS 86290-81-5) A3 Confirmed animal carcinogen with unknown relevance to humans. Toluene (CAS 108-88-3) A4 Not classifiable as a human carcinogen. Xylene (o, m, p isomers)(CAS 1330-20-7) A4 Not classifiable as a human carcinogen. IARC Monographs. Overall Evaluation of Carcinogenicity Benzene(CAS 71-43-2) 1 Carcinogenic to humans. Cumene (CAS 98-82-8) 2B Possibly carcinogenic to humans. Ethylbenzene (CAS 100-41-4) 2B Possibly carcinogenic to humans. Gasoline(CAS 86290-81-5) 2B Possibly carcinogenic to humans. Toluene (CAS 108-88-3) 3 Not classifiable as to carcinogenicity to humans. Xylene (o, m, p isomers)(CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans. US NTP Report on Carcinogens: Known carcinogen Benzene(CAS 71-43-2) Known To Be Human Carcinogen. UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 11 /17 Prepared by 3E Company US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Benzene(CAS 71-43-2) Cancer hazard. Epidemiology Contains benzene. Human epidemiology studies indicate that prolonged and/or repeated overexposure to benzene may cause damage to the blood-producing system and serious blood disorders, including leukemia. Animal tests suggest that prolonged and/or repeated overexposure to benzene may damage the embryo/fetus. The relevance of these animal studies to humans has not been fully established. Studies have shown a risk of spontaneous abortions in women exposed to high concentrations of organic solvents during pregnancy. Mutagenicity In in-vitro experiments, neither benzene,toluene nor xylene changed the number of sister-chromatid exchanges(SCEs)or the number of chromosomal aberrations in human lymphocytes. However, toluene and xylene caused a significant cell growth inhibition which was not observed with benzene in the same concentrations. In in-vivo experiments, toluene changed the number of sister-chromatid exchanges(SCEs)in human lymphocytes.Toluene may cause heritable genetic damage. Neurological effects Chronic exposure to high concentrations of various hydrocarbon blends may lead to polyneuropathy(peripheral nerve damage), characterized by progressive weakness and numbness in the extremities, loss of deep tendon reflexes and reduction of motor nerve conduction velocity. Numerous cases of polyneuritis have been reported following prolonged exposures to a petroleum fraction containing various isomers of heptane as major ingredients. May cause central nervous system disorder(e.g., narcosis involving a loss of coordination, weakness,fatigue)and/or damage. Reproductive effects Benzene, xylene and toluene have demonstrated animal effects of reproductive toxicity. Animal studies of benzene have shown testicular effects, alterations in reproductive cycles, chromosomal aberrations and embryo/fetotoxicity. Ethanol has demonstrated human effects of reproductive toxicity. May damage fertility or the unborn child. Can cause adverse reproductive effects-such as birth defects, miscarriages, or infertility.Avoid exposure to women during early pregnancy. Avoid contact during pregnancy/while nursing. Teratogenicity Abusive inhalation of toluene("glue sniffing")has been reported to be associated with birth defects in the offspring of abusers. Rats exposed to benzene and xylene vapor during pregnancy showed embryo/fetotoxic effects. Ethanol has demonstrated human effects of teratogenicity. Further information Symptoms may be delayed. 12. Ecological Information Ecotoxicological data Components Species Test Results 1,2,4, Trimethylbenzene (CAS 95-63-6) Aquatic Fish LC50 Fathead minnow(Pimephales promelas) 7.19-8.28 mg/I, 96 hours Benzene(CAS 71-43-2) Aquatic Crustacea EC50 Water flea (Daphnia magna) 8.76- 15.6 mg/I,48 hours Fish LC50 Rainbow trout,donaldson trout 5.3 mg/I, 96 hours (Oncorhynchus mykiss) Cumene (CAS 98-82-8) Aquatic Crustacea EC50 Brine shrimp(Artemia sp.) 3.55- 11.29 mg/I,48 hours Fish LC50 Rainbow trout,donaldson trout 2.7 mg/I, 96 hours (Oncorhynchus mykiss) Cyclohexane(CAS 110-82-7) Aquatic Fish LC50 Fathead minnow(Pimephales promelas) 3.961 -5.181 mg/I, 96 hours Ethanol (CAS 64-17-5) Aquatic Algae EC50 Freshwater algae 275 mg/I, 72 Hours Marine water algae 1970 mg/I Fish LC50 Fathead minnow(Pimephales promelas) > 100 mg/I, 96 hours Freshwater fish 11200 mg/I, 96 Hours UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 12/17 Prepared by 3E Company Components Species Test Results Invertebrate EC50 Freshwater invertebrate 5012 mg/I,48 Hours Marine water invertebrate 857 mg/I,48 Hours Ethylbenzene (CAS 100-41-4) Aquatic Crustacea EC50 Water flea (Daphnia magna) 1 -4 mg/I, 48 hours Fish LC50 Rainbow trout,donaldson trout 4 mg/I, 96 hours (Oncorhynchus mykiss) n-Hexane (CAS 110-54-3) Aquatic Fish LC50 Fathead minnow(Pimephales promelas) 2.101 -2.981 mg/I, 96 hours Toluene (CAS 108-88-3) Aquatic Crustacea EC50 Water flea (Daphnia magna) 5.46-9.83 mg/I,48 hours Fish LC50 Coho salmon,silver salmon 5.5 mg/I, 96 hours (Oncorhynchus kisutch) Xylene (o, m, p isomers)(CAS 1330-20-7) Aquatic Fish LC50 Rainbow trout,donaldson trout 8 mg/I, 96 Hours (Oncorhynchus mykiss) Ecotoxicity Contains a substance which causes risk of hazardous effects to the environment. Environmental effects The product contains a substance which is toxic to aquatic organisms and which may cause long-term adverse effects in the aquatic environment. Aquatic toxicity Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Persistence and degradability Not available. Bioaccumulation/ Not available. Accumulation Partition coefficient Ethanol -0.31 Benzene 2.13 Toluene 2.73 Ethylbenzene 3.15 Xylene (o, m, p isomers) 3.2 Pentane 3.39 Cyclohexane 3.44 Hexane (Other Isomers) 3.6 Cumene 3.66 n-Hexane 3.9 n-Heptane 4.66 Octane(All isomers) 5.18 13. Disposal Considerations Waste codes D001:Waste Flammable material with a flash point<140 °F D018:Waste Benzene Disposal instructions Dispose in accordance with all applicable regulations. Dispose of this material and its container to hazardous or special waste collection point. Incinerate the material under controlled conditions in an approved incinerator. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds,waterways or ditches with chemical or used container. 14. Transport Information DOT Basic shipping requirements: UN number UN1203 Proper shipping name Gasoline UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 13/17 Prepared by 3E Company Hazard class 3 Packing group II Additional information: Special provisions 139, B33, B101, T8 Packaging exceptions 150 Packaging non bulk 202 Packaging bulk 242 IATA UN number UN1203 UN proper shipping name Gasoline Transport hazard class(es) 3 Packing group II ERG code 3H IMDG UN number UN1203 UN proper shipping name Gasoline Transport hazard class(es) 3 Packing group II EmS F-E, S-E TDG Proper shipping name GASOLINE; MOTOR SPIRIT; or PETROL, MARINE POLLUTANT Hazard class 3 UN number UN1203 Packing group II Marine pollutant Yes Special provisions 17 15. Regulatory Information US federal regulations This product is a"Hazardous Chemical"as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. Clean Air Act(CAA) Section 112 Hazardous Air Pollutants(HAPs) List Benzene(CAS 71-43-2) Cumene (CAS 98-82-8) Ethylbenzene (CAS 100-41-4) n-Hexane (CAS 110-54-3) Toluene (CAS 108-88-3) Xylene (o, m, p isomers)(CAS 1330-20-7) US EPCRA(SARA Title Ill)Section 313-Toxic Chemical: De minimis concentration 1,2,4, Trimethylbenzene (CAS 95-63-6) 1.0% Benzene(CAS 71-43-2) 0.1 % Cumene (CAS 98-82-8) 1.0% Cyclohexane(CAS 110-82-7) 1.0% Ethylbenzene (CAS 100-41-4) 0.1 % n-Hexane (CAS 110-54-3) 1.0% Toluene (CAS 108-88-3) 1.0 Xylene (o, m, p isomers)(CAS 1330-20-7) 1.0% US EPCRA(SARA Title Ill)Section 313-Toxic Chemical: Listed substance 1,2,4, Trimethylbenzene (CAS 95-63-6) Listed. Benzene(CAS 71-43-2) Listed. Cumene (CAS 98-82-8) Listed. Cyclohexane(CAS 110-82-7) Listed. Ethylbenzene (CAS 100-41-4) Listed. n-Hexane (CAS 110-54-3) Listed. Toluene (CAS 108-88-3) Listed. Xylene (o, m, p isomers)(CAS 1330-20-7) Listed. UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 14/17 Prepared by 3E Company CERCLA(Superfund)reportable quantity(Ibs)(40 CFR 302.4) Gasoline: 100 Toluene: 1000 Hexane (Other Isomers): 100 Xylene (o, m, p isomers): 100 Octane(All isomers): 100 Pentane: 100 Cumene: 5000 Ethylbenzene: 1000 Benzene: 10 n-Hexane: 5000 Cyclohexane: 1000 Superfund Amendments and Reauthorization Act of 1986(SARA) Hazard categories Immediate Hazard -Yes Delayed Hazard -Yes Fire Hazard-Yes Pressure Hazard- No Reactivity Hazard -No Section 302 extremely No hazardous substance(40 CFR 355,Appendix A) Section 311/312 (40 CFR No 370) Drug Enforcement Not controlled Administration (DEA)(21 CFR 1308.11-15) Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS status Controlled WHMIS classification B2- Flammable Liquids D1A- Immediate/Serious-VERY TOXIC D2A-Other Toxic Effects-VERY TOXIC D2B-Other Toxic Effects-TOXIC WHMIS labeling 010 Inventory status Country(s)or region Inventory name On inventory(yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List(DSL) Yes Canada Non-Domestic Substances List(NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical Yes Substances(EINECS) Europe European List of Notified Chemical Substances(ELINCS) No Japan Inventory of Existing and New Chemical Substances(ENCS) Yes Korea Existing Chemicals List(ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) United States&Puerto Rico Toxic Substances Control Act(TSCA) Inventory No *A"Yes"indicates this product complies with the inventory requirements administered by the governing country(s) State regulations WARNING:This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US-California Hazardous Substances(Director's): Listed substance 1,2,4, Trimethylbenzene (CAS 95-63-6) Listed. Benzene(CAS 71-43-2) Listed. UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 15/17 Prepared by 3E Company Cumene (CAS 98-82-8) Listed. Cyclohexane(CAS 110-82-7) Listed. Ethanol (CAS 64-17-5) Listed. Ethylbenzene (CAS 100-41-4) Listed. Hexane (Other Isomers) (CAS 96-14-0) Listed. n-Heptane(CAS 142-82-5) Listed. n-Hexane (CAS 110-54-3) Listed. Octane(All isomers)(CAS 111-65-9) Listed. Pentane (CAS 109-66-0) Listed. Toluene (CAS 108-88-3) Listed. Xylene (o, m, p isomers)(CAS 1330-20-7) Listed. US-California Proposition 65-Carcinogens &Reproductive Toxicity(CRT): Listed substance Benzene(CAS 71-43-2) Listed. Cumene (CAS 98-82-8) Listed. Ethylbenzene (CAS 100-41-4) Listed. Toluene (CAS 108-88-3) Listed. US-California Proposition 65-CRT: Listed date/Carcinogenic substance Benzene(CAS 71-43-2) Listed: February 27, 1987 Carcinogenic. Cumene (CAS 98-82-8) Listed: April 6, 2010 Carcinogenic. Ethylbenzene (CAS 100-41-4) Listed: June 11, 2004 Carcinogenic. US-California Proposition 65-CRT: Listed date/Developmental toxin Benzene(CAS 71-43-2) Listed: December 26, 1997 Developmental toxin. Toluene (CAS 108-88-3) Listed: January 1, 1991 Developmental toxin. US-California Proposition 65-CRT: Listed date/Female reproductive toxin Toluene (CAS 108-88-3) Listed: August 7, 2009 Female reproductive toxin. US-California Proposition 65-CRT: Listed date/Male reproductive toxin Benzene(CAS 71-43-2) Listed: December 26, 1997 Male reproductive toxin. US-New Jersey RTK-Substances: Listed substance 1,2,4, Trimethylbenzene (CAS 95-63-6) Listed. Benzene(CAS 71-43-2) Listed. Cumene (CAS 98-82-8) Listed. Cyclohexane(CAS 110-82-7) Listed. Ethanol (CAS 64-17-5) Listed. Ethylbenzene (CAS 100-41-4) Listed. n-Heptane(CAS 142-82-5) Listed. n-Hexane (CAS 110-54-3) Listed. Octane(All isomers)(CAS 111-65-9) Listed. Pentane (CAS 109-66-0) Listed. Toluene (CAS 108-88-3) Listed. Xylene (o, m, p isomers)(CAS 1330-20-7) Listed. US-Pennsylvania RTK-Hazardous Substances: Special hazard Benzene(CAS 71-43-2) Special hazard. US. Massachusetts RTK-Substance List 1,2,4, Trimethylbenzene (CAS 95-63-6) Listed. Benzene(CAS 71-43-2) Listed. Cumene (CAS 98-82-8) Listed. Cyclohexane(CAS 110-82-7) Listed. Ethanol (CAS 64-17-5) Listed. Ethylbenzene (CAS 100-41-4) Listed. Hexane (Other Isomers) (CAS 96-14-0) Listed. n-Heptane(CAS 142-82-5) Listed. n-Hexane (CAS 110-54-3) Listed. Octane(All isomers)(CAS 111-65-9) Listed. Pentane (CAS 109-66-0) Listed. Toluene (CAS 108-88-3) Listed. Xylene (o, m, p isomers)(CAS 1330-20-7) Listed. US. New Jersey Worker and Community Right-to-Know Act 1,2,4, Trimethylbenzene (CAS 95-63-6) 500 LBS Benzene(CAS 71-43-2) 500 LBS Cumene (CAS 98-82-8) 500 LBS Cyclohexane(CAS 110-82-7) 500 LBS Ethylbenzene (CAS 100-41-4) 500 LBS n-Hexane (CAS 110-54-3) 500 LBS UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 16/17 Prepared by 3E Company Pentane (CAS 109-66-0) 500 LBS Toluene (CAS 108-88-3) 500 LBS Xylene (o, m, p isomers)(CAS 1330-20-7) 500 LBS US. Pennsylvania RTK-Hazardous Substances 1,2,4, Trimethylbenzene (CAS 95-63-6) Listed. Benzene(CAS 71-43-2) Listed. Cumene (CAS 98-82-8) Listed. Cyclohexane(CAS 110-82-7) Listed. Ethanol (CAS 64-17-5) Listed. Ethylbenzene (CAS 100-41-4) Listed. Gasoline(CAS 86290-81-5) Listed. Hexane (Other Isomers) (CAS 96-14-0) Listed. n-Heptane(CAS 142-82-5) Listed. n-Hexane (CAS 110-54-3) Listed. Octane(All isomers)(CAS 111-65-9) Listed. Pentane (CAS 109-66-0) Listed. Toluene (CAS 108-88-3) Listed. Xylene (o, m, p isomers)(CAS 1330-20-7) Listed. 16. Other Information Further information HMIS®is a registered trade and service mark of the NPCA. Other information Note:This Material Safety Data Sheet applies to the listed products and synonym descriptions for Hazard Communication purposes only.Technical Specifications vary greatly depending on the products and are not reflected in this document. Consult specification sheets for technical information. HMIS®ratings Health: 2* Flammability: 3 Physical hazard: 0 NFPA ratings Health: 1 Flammability: 3 Instability: 0 Disclaimer This Material Safety Data Sheet(MSDS)was prepared in accordance with 29 CFR 1910.1200 by Valero Marketing &Supply Co., ("VALERO"). VALERO does not assume any liability arising out of product use by others. The information, recommendations, and suggestions presented in this MSDS are based upon test results and data believed to be reliable. The end user of the product has the responsibility for evaluating the adequacy of the data under the conditions of use, determining the safety,toxicity and suitability of the product under these conditions, and obtaining additional or clarifying information where uncertainty exists. No guarantee expressed or implied is made as to the effects of such use ,the results to be obtained, or the safety and toxicity of the product in any specific application. Furthermore,the information herein is not represented as absolutely complete, since it is not practicable to provide all the scientific and study information in the format of this document, plus additional information may be necessary under exceptional conditions of use, or because of applicable laws or government regulations. UNLEADED GASOLINE 3536 Version#:03 Revison date: 11-13-2012 Print date: 11-13-2012 17/17 Prepared by 3E Company Hello