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HomeMy WebLinkAbout20181251I PAGE OF DOCUMENT INCLUDED IN PAPER FILE RE AINDE.R RETAINED ELECTRONICALLY IN TYLER. organtc 5 16350 WCR 76, Eaton, Colorado (970) 4544492 GROUNDWATER MONITORING REPORT NOVEMBER 2017 EATON ORGANIC RECYCLING FACILITY 76350 WELD COUNTY ROAD 76 EATON, COLORADO FEBRUARY 5. 2018 2o/r / ?61 Ilh organics otordo's Leader in Organic /Recycling February 5, 2018 Mr. Ben Frissell. Weld County Department of Public Health and Environment 1555 N. 17th Avenue Greeley, Colorado 80631 NOTICE: Groundwater Monitoring Report - November 2017 Eaton Organic Recycling Facility 16350 WCR 76, Eaton, CO Dear Mr. Frissell: Al Organics is pleased to furnish this Groundwater Monitoring Report for sampling and analysis of wells/devices implemented at our Eaton Organic Recycling Facility located at 16350 WCR 76, Eaton, Weld County, Colorado (Site). Please call (970) 454-3492, if you have any questions or concerns. Chris Skelton, P.G. Al Organics Regulatory and EH&S Officer Al Organics Corporate Headquarters: 16350 WCR 76 • Eaton, Colorado 80616 Tel 970-454-3492 • 80th -776-1644 • Fax 97a-454-0202 Facilities: Eaton • Keenesburg • Stapleton Las Vegas, Nevada www,al organ ics.com US Composting Council Seal of Testing Assurance TABLE OF CONTENTS °I .X introduction +...}a.}***a.s*e■•..•*iqa* 1.1 Facility Summary 1.2 Facility Location •.. 41 Ornti**40.04f•4•f!•i**41.41VOiifailFMAa.ifiiiie*iiia■iiiiiiieie., non 604414 a 0•4 a le F . U} ,4 - 444441 4441 4 4 a 3 a F• 4 4 4 P 4 44 B' d 4 WV ■..... 114 1. 1.3 Site Assessment Background r } 4.. • h 2 2.0 Geology and Hydrogeology .r 2.1 P Y■. i J•.. a t.4 4 •4 4 2.2 Hydrogeology 1111 sr •.••***•••••* 41..■a**■a■■v••X1104•X9999140 Illifsi#ilettenalmiifaiiitini i■■iii. 4444/; *4f 944 a••.r I a i1n a.., / a. }, 3 i 14P14 44% 444444•F f 404404 ii 3.0 Monitoring Well System Summary�**•■■.•.•*.*. �r��fefs3ifff!��r�r�ifa9fffffaif aarriiiiai••wf�■•aa.i•iii�ifiiaiifiis 4.0 Groundwater Data Summar '**1000i••iiii+F4fiiiai.aiffaliiMfiiiifiiiiiiiiiaiiiiiiierii 4.1 Sources forConstituentsof Concern a*hPia..a4.n ./ 444•4011f94 it44 i•rieivneriet ** 4,2 rou n drate r Recharge Sources .a eriiiai . 4 �10 a aee..aa�44+.env reei..•rar.•a 11.4 ,4.4 -a.A 4.3 Ground ater Monitoring iaa a4..ea..rs....aaarP 10 4.4 Groundwater Elevations ..e......ra es.Y aaa.aa.aa, a:..6..a,a.aAt*P.444.4i meet 1 4.5 Groundwater ater Flow Direction •ass. }.4il1444414444 r$ i.6riiers1 Olt 1 1 4.6 Water Quality ••ft fa la a 4.7 Statistical Analysis 14 4* 5.0 Finding 4 a, S..... a 54' 4' 0 M a o ... ••••••• 4 4 e. a 4 ... * .. 1 a. a. a *4•1 P a 4 4 4: 1 4 4 y 4 4 e r 4 4 4 1 4 •} y 4140141444444.1. 4 ., aa.. .a,a..1 i041n*t•a*tfiainil a*i.i•a.iirfifafi■■■i.*..**f*a.0.sf•aaffa41iaii*.i41aaiffiaaIMO aiir*iai *.•****,111111.11**12 6.0 Limitations *i**••••**...,11041.1111.f*•••0i.•fi.*DO Oil .iriiell iiir■.••*****••aisf••a..S••fa*•fiat..tssai.r*4a.iieiti.■.1, Tables Table 1: Table 2: Table 3: Table 4: Figures Figure 1: Figure : Figure 3: Figure 4: Figure 5: Figure 6: Appendices Summary of Field Parameters Summary of Groundwater Elevations Summary of pH, Salinity, and Major Cations and Anions Summary of Metals Analytical Results Site Location Map Site and Vicinity ity Map Topographic Map Well Location Map Groundwater Recharge Map Groundwater Contour Map Appendix A: Groundwater Information and Site Hydrographs Appendix B: Laboratory Analytical Report Appendix C: SMA's Statistical Evaluation GROUNDWATER MONITORING REPORT Al ORGANICS EATON ORGANIC RECYCLING FACILITY 16350 WELD COUNTY ROAD 76 EATON, WELD COUNTY, COLORADO 1.0 Introduction Al Organics (A►l) has prepared this Groundwater Monitoring Report (Report) to describe for the record recent groundwater monitoring implemented at the Eaton Organic Recycling Compost Facility (Site) in Weld County, Colorado. The monitoring well system (system) is comprised of four monitoring wells and one piezometer installed by others and one new "leak -detection" device (MW -6) installed as directed at the Site. Generally, groundwater monitoring has been conducted for three of the four Site monitoring wells since as early as June 2011, and for one well: -1 since May 2004. Groundwater from MW -6 was sampled for the second time in November 2017. I A Facility Summary In 1974, Lambland Inc., doing business as Al Organics, began composting manure generated by the lamb feeding operation that existed at the Al Eaton, Colorado location. Over the next 20 years, Al's composting expanded to include operating other facilities and composting other organic materials such as paunch from foul meat packing plants, green waste, waste beer and brewers residuals, food waste, biosolids, water treatment plant residuals with Tier 1 designation, andvarious wood wastes The Eaton Organic Recycling Facility is defined in 6 CCR 1007-2, Part '1 (The Regulations) as a "compost facility" and is operating a Class 3 organic composting facility since 2015. An Engineering, Design and Operations Plan (EDGE') stamped May 6, 2014 was approved by the Director and Weld County. The compost facility is unrestricted and may produce any variety of compost throughout the facility boundary, but typically produces compost using yard waste, wood waste, and selected food - wastes. 1.2 Facility Location The Site is located in the eastern plains of the Front Range approximately one and a half miles west of Highway 85, and the town of Eaton, Colorado (Figures 1 and 2). The vicinity of the Site is predominately agriculture and scattered oil well sites (Figure 2). The Site slopes gently to the south and lies at an approximate elevation of 4,850 feet above mean sea level (Figure 3). Although not necessarily in a depression, properties to the north, east, west, and south are at greater elevation than the Site. Groundwater Monitoring Report Eaton Organic Recycling Facility Weld County, CO February 5, 2018 The Site lies within an historic agricultural area that has regional and proximate sources for agricultural/fertilizer constituents of concern that likely has significantly contributed to the overall degradation of water quality throughout the vicinity. The Site also appears to lie in an area designated as highly vulnerable to agricultural nitrate impacts as mapped by Ceplecha (Ceplecha, 2001). As reported by the Colorado Agricultural Chemicals and Groundwater Protection Program (Ag program), shallow groundwater in the Weld sub -region of the Lower South Platte River Basin is known to have elevated nitrate levels. Median nitrate results for the area are reported by the Ag program as 20 milligrams per liter (mg/L). 1.3 Site Assessment Background A limited site assessment was conducted by Terracon during May 2004. The assessment was limited to assessing the hydraulic conductivity of near surface soils in the production area and installation of monitoring well MW -II to assess groundwater quality. Based on Terracon's assessment, the shallow subsurface soils exhibited hydraulic conductivities of 51 x 10-6 and 2 10.7 centimeters per second (cm/s) and groundwater occurred at a depth of approximately 23 feet below ground surface (bgs) and exhibited elevated nitrate (26.9 mg/L), sulfate (1,985 mg/L), and total dissolved solids (3,428 mg/L) concentrations. Additional subsurface characterization was conducted in summer 2011 by R now known as Souder Miller & Associates (SMA). Shallow subsurface soils exhibited hydraulic conductivities ranging from 4.7 x 10-5 to 5.9 x 10-8 cm/s which are similar to data reported by Terracon. Subsurface soils were described by A as clays, silts, a n d sands with some water -bearing gravel occurring at variable depths. Bedrock was reportedly encountered at boring locations MW -2 (P1-2) and MW -5A at depths of 21 and 23 feet bgs, respectively. SMA installed two monitoring wells (MW -2 and MW -3) in June 2011 and two more monitoring wells (MW -4 and MW -5) in August 2012. A replacement well for MW -5 (MW -5A) was installed in June 2013. Additionally, several test pits were excavated and examined. Based on SMA's characterization, depth to groundwater varies across the Site, but shallow groundwater that suggests mounding1'2 was observed in the vicinity of neighboring unlined ponds and Graham Seep located near the southwest portion of the facility. SMA reports groundwater flowing to the southeast at gradients of approximately 0.011 ft/ft. SMA further reported3 elevated nitrate, sulfate, and specific conductivity concentrations that may be related to off -site proximate sources. "It should be noted that the relatively shallow depth to groundwater in Test Pit l suggests that there may be a groundwater mounding effect in the vicinity of the unlined ponds located along the west side of the property." EDOP, Hydrogeologic Report by KRW dated May 6, 2014, page 9. 2 "Also, it should be noted that localized groundwater recharge provided by the unlined ponds just west of MW -2 creates a mounding effect in the vicinity of the ponds during irrigation season." EDOP, Hydrogeologic Report by KRW dated May 6 2014, page 1 3 "The presence of elevated nitrate and TLS concentrations in the uppermost alluvial water bearing zone may be related to the agricultural operations on and adjacent to the property." EDOP, Hydrogeologic Report by KRW dated May 6, 2014, pg, 14 Groundwater Monitoring Report Eaton Organic Recycling Facility Weld County, CO February 5, 2018 2.0 Geology and Hydrogeology 2.1 Geology The Site lies on the northeastflank of the Denver Basin which extends from Greeley in the north to Colorado Springs in the South and from the Front Range in the west to Limon in the east. The greater Denver Basin is a north -south trending asymmetrical down -warp involving as much as 13,000 feet of Sedimentary rock. The Denver Basin consists of Precambrian crystalline basement rock overlain by a thick section of pre -Cretaceous and Cretaceous sedimentary units. The formations beneath the upper -Cretaceous Pierre Shale are likely thicker than the 3,135 feet observed on the western flank of the basin (Weimer, 1973). The Pierre Shale is approximately 8,000 feet thick and consists of fossiliferous marine shale, silt, and clayey sandstone, containing numerous calcareous concretions (McWhorter and Ortiz, 1978). The Pierre Shale is the lowest geologic unit of interest and considered the base of the water yielding units in the Denver Basin (Robson, 1987). The Fox Hills Sandstone lies above the Pierre Shale and is composed of calcareous marine sandstone interbedded with dark -gray to black sandy shale and some massive white sandstone (McWhorter and Ortiz, 1978). The thickness of the Fox Hills Sandstone likely ranges from 60 to 300 feet (Weimer, 1973). The Laramie Formation overlies the Fox Hills Sandstone and is the uppermost bedrock unit in the vicinity of theSite. The Laramie Formation consists of yellow -brown and gray to blue -gray soft carbonaceous shale and clay -shale interbedded with sand and shaley sand (McWhorter and Ortiz, 1978). The Laramie contains cross -bedded gray to buff sandstone, which is slightly to well -cemented, and contains coal in the lower portion. Overlying the Laramie Formation are recent deposits of alluvium and eolian sand. The alluvial materials consist of silty, clayey, fine to coarse grained sands with occasional gravel. The eolian sand is generally of uniform thickness. The bedrock formations described above dip gently to the southwest toward the center of the basin. The upper limit of the competent bedrock beneath the Site is an erosional surface controlled by, and generally reflecting the northeast dipping surface topography. 2.2 Hydrogeology The Denver Basin comprises a portion of the Colorado Piedmont Section of the Great Plains physiographic province. Surface drainage in the basin is divided into a portion that flows to the South Platte River and a portion that forms part of the Arkansas River watershed. The major streams in the portion within the South Platte catchment include Plum Creek, Bear Creek, Cherry Creek, Clear Creek, Box Elder Creek and Bijou Creek. The South Platte River enters the basin a few miles southwest of Denver and flows in a Groundwater Monitoring Report Eaton Organic Recycling Facility Weld County, CO 3 February 57 2018 general northerly direction to Greeley where it turns eastward toward the High Plains region (McWhorter, 1984). The significant bedrock aquifers of the Denver Basin are, in descending order; the Dawson, Denver, and Arapahoe formations of the Dawson Group; the Laramie -Fox Hills formations; and the Dakota, Lyons, and Fountain formations. The Dawson Arkose is the uppermost of the aquifers in the Upper Cretaceous Dawson Group. It consists of interbedded sandstone, conglomerate, shale, and clay comprising a total thickness of as much as 1 100 ft. According to the Colorado Division of Water Resources (1976), the lower 400-500 ft. consists mainly of coarse, arkosic and micaceous sandstone and is the principal water bearing zone within the Dawson aquifer. Immediately below the Dawson Arkose, the Denver formation consists of a series of sandstones that thin toward the east and become interbedded with clays and shales. The lowest member of the Dawson Group is the Arapahoe formation which ranges in thickness from 500 to 600 ft. The lithology is dominated by sandstone and conglomerate. Some 300 ft. or more of sandstone is locally present and provides a reliable source of water of good quality. The Laramie -Fox Hills aquifer is the next significant aquifer below the Arapahoe. This aquifer includes the Milliken sandstone of the Fox Hills formation and the A and B sandstones of the overlying Laramie. The portion of the Laramie formation extending between the top of the B sandstone and the base of the Arapahoe is thought to be the confining stratum for the Laramie -Fox Hills aquifer. The average thickness of the Laramie -Fox Hills aquifer is 200 ft. but ranges upward to about 400 ft. Individual sandstone strata form the water bearing intervals and are often separated by 5-20 ft. of shale. Locally, 100-250 ft. of net sandstone thickness is available for water production. The Dakota aquifer consists of the upper 100 ft. of the South Platte and Lytle formations of the Dakota Group. Ground waters of usable quality are found in the Dakota only near the west boundary of the basin where the Dakota outcrops. Like the Dakota aquifer, the Fountain formation and the Lyons sandstone are useful aquifers only near the outcrop on the western side of the basin. These aquifers are Permian in age and are separated from the Dakota by Lykins, Ralston Creek, and Morrison formations. Except near the outcrop areas, all of the above aquifers are artesian. Confining beds are clay and shale strata, but are not believed to preclude vertical communication between the Dawson Arkose, the Denver, the Arapahoe, and the Laramie -Fox Hills. The piezometric head is generally greatest in the uppermost aquifer (i.e. the Dawson Arkose) and decreases with depth to the Laramie -Fox Hills, at least in the undisturbed, pre -development state. This downward gradient is thought to result in some small Groundwater Monitoring Report Eaton Organic Recycling Facility Weld County, CO 4 February 5, 2018 downward movement of water from aquifer to aquifer. The hydraulic properties of the aquifers vary substantially, both within individual aquifers and from aquifer -to -aquifer. 3.0 Monitoring Well System Summary There are four monitoring wells and one piezorneter installed by others within the system and one new "leak detection" device excluded from the system. The Director's leak detection device is specifically excluded from the system due to the device being uncertified as required by the Regulations. Generally, groundwater monitoring has been conducted for three of the four Site monitoring wells since June 2011 and for one well: N7 --I since May 2004. The well spacing ranges from approximately 500 feet to 1000 feet. The certified well locations and MW-6MW-6 are shown on Figure 4. Monitoring well MIN -1 Monitoring well MW -1 was installed by Terracon as described in Te rraco n's Limited Site Assessment dated May 27, 2004. Although not explicitly stated or stamped within the report,MW--1 appears to be certified by Dean R. Pearson P.E., of Terracon. MW --I is located on the east side of the facility within 20 feet of the neighboring property and an unlined irrigation ditch. MW --1 is considered down gradient of properties to the northwest, the production area, the septic leach field, and the stormwater pond. The well construction diagram does not show the complete construction details. Based on Al's experience and an inspection of MW --1 , the well is likely constructed of 2 -inch schedule 40 PVC. The diagram shows the well screen length is 15 feet placed from 10 to 25 feet bgs and likely 0.01 slot. The filter pack is placed two feet above the top of the screen with a bentonite and/or cement seal to the surface. Groundwater generally occurs within the screened interval. Sources for constituents of concern are the septic leach field, the stormwater retention pond, the compost production area, and irrigation through canals/water supply wells and application to neighboring crops. Groundwater recharge sources include up gradient (north/northwest) groundwater flow, discharge from the unlined ponds north and west of the well, and likely discharge of applied irrigation at the property east of the facility. Groundwater elevation in this well is strongly influenced by the pumping of water supply wells east of the facility. This well is appropriate for assessing impacts to groundwater from the general vicinity of the site. Had the well been considered representative of Al's operational impact, the results would suggest that since 2004, Al's operations have generally reduced nitrate concentrations and remediated historic agricultural impacts. Groundwater Monitoring Report Eaton Organic Recycling Facility Weld County, CO February 5, 2018 Piezometer PZ-2 Piezometer PZ-2 was originally installed as Monitoring well MW -2 by in June 2011 as described in SMA's Hydrogeological Report dated October 10, 2012 and revised May 2014. PZ-2 appears to be stamped certified by ichael Pretti P, E., of SMA. PZ-2 is located on the west side of the facility within close proximity to the neighboring unlined ponds, unlined seep, and Al's storm water pond. PZ-2 is considered down gradient of the neighboring unlined ponds and seep and associated groundwater mounding. Piezometer PZ-2 is constructed of 2 -inch schedule 40 PVC. The diagram shows the well screen length is 15 feet placed from 5 to 20 feet bgs and 0.01 slot. The filter pack is placed one foot above the top of the screen with a bentonite and/or cement seal to the surface. Groundwater generally occurs within the screened interval. Due to elevated ( > 4 feet) seasonal groundwater mounding in the proximate vicinity, the source for constituents of concern are chiefly the unlined neighboring ponds and recharge from the unlined Graham Seep. Notwithstanding, the Director's4 opinion, piezometer PZ-2 is solely appropriate for assessing impacts to groundwater from the neighboring unlined ponds and flow associated with Graham Seep. Monitoring well MW -3 Monitoring well MW-3MW-3 was installed by MA in June 2011 as described in SMA's Hydrogeological Report dated October 10, 2012 and revised May 2014. Well -3 appears to be stamped certified by Michael Pretti P.E., of SMA. MW -3 is located at the northeast corner of the facility► within 20 feet of the neighboring crops and an unlined irrigation ditch. MW -3 is considered down gradient of property and farming operations to the north and northwest of the compost facility. Well MW -3 is constructed of 2 -inch schedule 40 PVC. The diagram shows the well screen length is 15 feet placed from 19 to 34 feet bgs and 0.01 slot. The filter pack is placed two feet above the top of the screen with a bentonite and/or cement seal to the surface, Groundwater generally occurs within the screened interval. Sources for constituents of concern are the neighboring crops to the north and likely crops to the east as well. Groundwater recharge sources include up gradient (north) groundwater flow►, discharge from the ponds north of MW -3, and likely discharge of applied irrigation at the property east of the facility. Groundwater elevation in this well is strongly influenced by the pumping of water supply wells east of the facility. This well is appropriate for assessing impacts to groundwater from the general vicinity north of the site. "the physical proximity of monitoring well MW -2 to the Facility's leachate field, storm water detention basins, and adjacent ponds makes this a good monitoring well for these impoundments." CDPHE letter dated December 17, 2015 Groundwater Monitoring Report Eaton Organic Recycling Facility Weld County, CO + February 5, 2018 Monitoring e l l MW -4 Monitoring well MW -4 was installed by SMA in August 2012 as described in S MA's Hydrogeological Report dated October 10, 2012 and revised May 2014. Well MW -4 appears to be stamped certified by Michael Pretti RE., of SMA. MW -4 is located on the east side of the facility within 20 feet of the neighboring crops and an unlined irrigation ditch. MW -4 is considered down gradient of the production area, the septic leach field, the stormwater pond, Graham Seep, and the unlined ponds to the west. Well MW -4 is constructed of 2 -inch schedule 40 PVC. The diagram shows the well screen length is 20 feet placed from 10 to 30 feet bgs and 0.01 slot. The filter pack is placed at the top of the screen with a bentonite seal to the surface. Upon initial inspection of the well in August 2016, the completion at the surface did not maintain a seal. Subsequently and at l's demand, SMA reset the surface seal to preclude short circuiting of the welt Groundwater generally occurs within the screened interval. The longer screen interval (20 -feet of screen) at MW -4 likely accounts for the lower nitrate concentrations observed at MW -4 as compared to concentrations observed at MW -I (15 -feet of screen). Generally, in agricultural settings, younger and shallower groundwater bearing zones are more nutrient -impacted than older and deeper groundwater bearing zones. Longer well screen intervals allows for the mixing of upper and lower water bearing zones. Sources for constituents of concern are the unlined ponds, the septic leach field, the stormwater retention pond, the compost production area, Graham Seep, and neighboring crops. Groundwater recharge sources include up gradient (north/northwest) groundwater flow, discharge from the unlined ponds north and west of the well, and likely discharge of applied irrigation at the property east of the facility. Groundwater elevation in this well is strongly influenced by the pumping of water supply wells east of the facility. This well is appropriate for assessing impacts to groundwater from the general vicinity of the Site. Had the well been considered representative of ►l's operational impact, the results would suggest that since 2004, l's operations have generally reduced nitrate concentrations and remediated historic agricultural impacts. Monitoring well MW -5A Monitoring well MW -5A was installed as a replacement well for MW -5 by SMA in June 2013 as described in SMA's Hydrogeological Report dated October 10, 2012 and revised May 2014. Well MW -5 has since been plugged and sealed. Well MW -5A appears to be stamped certified by Michael Pretti P.E., of SMA. MW -5A is located on the north side of the facility within 150 feet of the neighboring property and 225 feet from the north unlined irrigation ditch and unlined pond with associated settling basins. MW -SA is considered down gradient of the unlined irrigation ditch and unlined pond/settling basins. Groundwater Monitoring Report Eaton Organic Recycling Facility Weld County, CO February 5, 2018 Well - A is constructed of 2 -inch schedule 40 PVC, The diagram shows the well screen length is 20 feet placed from 4Y2 to 24% feet bgs and 0,02 slot. The filter pack is placed to the top of the screen with a thin 9 -inch bentonite seal above the screen and then sand packed to the surface. Groundwater generally occurs within the screened interval. Due to groundwater mounding in the proximate vicinity during irrigation season, the source for constituents of concern are chiefly the unlined ditch and unlined ponds and upgradient historic nutrient impacts. However, due the lack of a proper annular seal, the shallow screen interval, and nativesands from the screen interval to the surface, this well has potential to short circuit during flood/storm events. Director's device MW -6 Director's device: MW -6 was installed as a 'leak detection" device for the stormwater pond. The Director, having assumed responsible charge of the device, had ample opportunity to certify the device; however, the device has not been certified as required by Appendix B of the regulations and the approved Groundwater Monitoring Plans within the EDOP. As such, Al considers all analytical data collected from the device objectionable, since no one is willing or capable of verifying the Director's device is appropriate. The device is located south of the stormwater pond and within 525 feet of the neighboring unlined ponds and Graham Seep to the west. The device is considered down gradient of the unlined neighboring pond, the septic leach field, Graham Seep, and the stormwater pond. The device is constructed of 2 -inch schedule 40 PVC. The device screen length is 10 feet placed from 9 to 19 feet bgs and 0.02 slot. The filter pack is placed one foot above the screen with a bentonite seal above the filter pack to the surface. Groundwater generally occurs near the top of the screened interval. Due to groundwater mounding in the proximate vicinity, the multiple sources for nutrient constituents of concern, the inconsistent construction of the pond liner, and other technical reasons6, the device is incapablee of quantifying a volume/rate of seepage from the storm water pond with any degree of certainty. The device is inappropriate for 5 "Modifications to the plan will be made as appropriate and in compliance with CDPHE requirements based on these evaluations. The number, spacing, and depths of groundwater monitoring systems will be certified by a qualified groundwater scientist." EDOP, Appendix H, page 5 6 "The empirical data developed by CVDRMP P illustrate that monitoring wells are an unreliable tool for detecting impacts of lagoon seepage on groundwater even under relatively favorable hydrogeologic conditions. In most cases, seepage remains either not evident or inconclusive based on groundwater testing." Evaluation of Earthen Liquid Dairy Manure Lagoons, t ...; LSCE 2017 7 "More fundamentally, groundwater constituent concentrations do not yield information on the concentration of the lagoon seepage, the seepage rate, overall subsurface mass loading rate, or the duration of the loading. Although groundwater monitoring generates quantitative information, this information can only be used qualitatively with respect to lagoon seepage, i.e., supporting a statement such as, "groundwater chemistry is (or is not) indicative of lagoon seepage". Since guidelines, standards, and laws for the construction of existing earthen lagoons were intended to control seepage but not to stop it, seepage is to be expected and a data collection effort (e.g., groundwater sampling via monitoring wells or other means) that supports a qualitative statement of whether a lagoon seeps or not has limited utility for devising a path to subsurface N -emission reductions on a dairy farm scale." Evaluation of Earthen Liquid Dairy Manure Lagoons,.....; LSCE 2017 Groundwater Monitoring Report Eaton Organic Recycling Facility Weld County, CO February 5, 2018 assessing groundwater conditions with respect to the storm water pond liner performance. Monitoring Well System Summary There are effectively two monitored units at the Site: the compost production area and the storm water retention pond. Neither of which significantly contributes to groundwater recharge beneath the Site as compared to the orders of magnitude greater recharge volumes from proximate off -site seasonal sources comprised of similar constituents of concern. In the absence of a unique identifier (specific constituent linked to a specific on -site source), interpretation of groundwater quality data is most successful with consideration of the well's source area. Monitoring wells positioned down gradient of monitored units are typically intended to intercept groundwater which originates under the monitored unit only. However, it must be recognized that this is not possible when seepage from the storm water pond approaches zero and neighboring unlined pond's/ditch's seepage is significant, such as is the case here. As pond seepage decreases, the source area of a down gradient monitoring welt will extend beyond the footprint of the monitored unit (pond). Further, recharge or groundwater mounding associated with the proximate unlined ponds/ditches and Graham Seep during irrigation season already extends well beyond the storm water retention pond. Under these circumstances, groundwater chemical characteristics cannot be unambiguously attributed to the pond liner performance or site operations notwithstanding the statistical analysis. One of the most basis premises of groundwater monitoring is that the monitoring well must provide a representative hydraulic connection to the monitored unit. Without this representative hydraulic connection, the groundwater analytical data cannot be interpreted in relation to the flow system dynamics or the transport of constituents of concern in the monitored unit. Groundwater monitoring has limitations, particularly in agricultural settings where the flow of monitored constituents of concern are present at significantly greater volumes and mass in upgradient and proximate locations in comparison to Site sources. To put it simply, groundwater impacts from agricultural operations in the vicinity of the Site are more than likely masking impacts that may originate at the composting facility. 4.O Groundwater Data Summary 4.1 Sources for constituents of Concern There are significant historical sources for nutrients (constituents of concern) in the vicinity of the Site. Most notably are the surrounding adjacent parcels and the significant historical duration and mass of fertilizer/manure application to crops. Additionally, irrigation water flowing in the unlined ditches north and east of the Site may collect nutrients from crop application and tail water return. Locally, the septic leach Groundwater Monitoring Report Eaton Organic Recycling Facility Weld County, C February 5, 2018 field lies directly between the upgradient Graham Seep and the down gradient storm water retention pond. Cultivation of crops requires applied irrigation and nutrients to penetrate the soil surface and leach through to the root zone. It is likely that surrounding cultivated parcels have historically applied over 150 pounds (Ibs) of nitrogen per acre as fertilizer annually. Technical reports from exhaustive studies conducted in the Central Valley of California suggest a proportional relationship of 1000:18 between subsurface nitrogen -emissions from fertilized and irrigated cropland and from earthen -lined water retention features in similar agricultural land use settings. Estimates of annual applied irrigation and surrounding fertilizer application at neighboring agricultural facilities comprising approximately 150 acres are 100 million gallons of water and 15,000 lbs of nitrogen. Als estimate of annual precipitation over the production area is approximately 325,000 gallons. 4.2 Groundwater Recharge Sources There are several significant sources for groundwater recharge in the vicinity of the Site. Most notably are the surrounding adjacent parcels and the application of irrigation of unknown quality to crops. Locally, there are several unlined surface water retention features in close proximity to the Site.Other notable sources are the unlined irrigation ditch that borders the Site to the east, another unlined irrigation ditch on the north side of County Road 76, and the likely leaking drain that connects the irrigation ditch to the north and Graham Seep. Groundwater recharge features are shown on Figure 5. Based on previous assessments of surface and near surface soils within the production area of the Site, the Site soils are likely to preclude significant infiltration of precipitation that comes in contact with compost and feedstocks. Infiltration within the production area and discharge from the storm water pond are not significant sources of groundwater recharge when compared to the orders of magnitude significant irrigation - related recharge volumes of off -site proximate and upgradient sources for nutrient constituents of concern. 4.3 Ground ater Monitoring Groundwater from the wells and MW-6MW-6 was measured in the field during purging for specific conductance (EC), temperature, pH, oxidation-reduction potential or redox (ORP) and dissolved oxygen. Well and device locations are provided as Figure 4. Measured field water quality parameters are summarized in Table I . Groundwater from Site wells and MW-6MW-6 was collected on November 29, 2017 and submitted to Colorado Analytical Laboratory. The groundwater samples were analyzed for the constituents described in the approved EDOP with the exception of volatile organic compounds and semi -volatile organic compounds which will resume testing in May 2019. $ "This compares well to Addressing Nitrate in California's Drinking Water (Harter, Lund et al. 2012). On the scale of the Tulare Lake basin and the Salinas Valley, that report suggests a proportional relationship of l000:lbetween subsurface N -emissions from cropland and from lagoons." Evaluation of Earthen Liquid Dairy Manure Lagoons ... LSCE 2017 Groundwater Monitoring Report Eaton Organic Recycling Facility Weld County, CO 10 February 5, 2018 4.4 Groundwater Elevations Depth -to -groundwater and total well depth measurements were gauged in wells: MW -1, FEZ -2, MW -3, MW -it; MW -5A, and the Director's MW -6. Groundwater elevations are calculated by subtracting depth -to -groundwater measurements from surveyed top -of - casing elevation at each location. During the November 2017 groundwater monitoring event, depth -to -groundwater measurements ranged from approximately 5% to 9 feet bgs for wells on the west boundary and from approximately 15 to 18% feet bgs for wells on the east boundary. Table 2 summarizes depth to water measurements and groundwater elevations for Site wells and devices. Groundwater elevations across the site are significantly affected by major storm water events, seasonal irrigation, and the pumping of water supply wells during the growing season. Data from the Site hydrographs show declines in groundwater elevations for wells at the west property boundary of greater than four feet when irrigation is not flowing (September through March). During the same period, wells on the east boundary show rising groundwater elevations (well recovery) when water supply wells are shutdown. During the irrigation season, the opposite holds true. Groundwater elevations at wells along the west property boundary rise due to massive recharge/mounding and elevations at the wells along the east property boundary decline due to water supply well pumping east of the Site. During May 2017, the first major storm event showed an immediate rise of groundwater of about 2 feet for wells (MW -5A and F2-2) at the west property boundary. However, during subsequent large storm events, only PZ-2 showed groundwater elevation rises of greater than one foot (1.41', 1.0 1, and 1. 1'), while MWW- A showed groundwater elevation rises no greater than 0.19 feet from the same storm events. The data suggests significant groundwater mounding beneath the storm water pond during irrigation season from storm events and irrigation flow. Groundwater elevation summaries and hydrographs of groundwater elevations with time are provided in Appendix . 4.5 Groundwater Flow Direction The natural topography suggests that groundwater would chiefly flow from higher ground surface elevations at the northeast corner of the Site towards areas of lower elevation to the southwest. However; Site groundwater data supports groundwater flowing from northwest to southeast of the Site at a gentle gradient of 0.009 ft/ft. The shift from anticipated groundwater flow is attributed to the significant groundwater recharge along the west property boundary and the pumping of water supply wells east of the property boundary that directs Site groundwater eastward during the irrigation season, Figure 6 shows groundwater elevation contours for Site monitoring conducted on November 9, 2017. Groundwater Monitoring Report Eaton Organic Recycling Facility Weld County, Co 11 February 5, 2018 4.6 Water Quality The Site lies within an historic area where neighboring agricultural operations within the vicinity have contributed to the overall degradation of water quality. Shallow groundwater in the vicinity of the Site is known to be impaired with regards to nitrates. As reported by the Colorado Agricultural Chemicals and Groundwater Protection Program (Ag program), shallow groundwater in the Weld sub -region of the Lower South Platte River Basin is known to have elevated nitrate levels. Median nitrate as nitrogen results for the area are reported by the Ag program as 20 milligrams per liter (mg/L). Analysis of groundwater from site wells indicates nitrate and sulfate concentrations exceed standards. Tables 3 and 4 summarize the analytical results of groundwater samples collected from the on -site monitoring wells and MW -6. Table 3 summarizes results of pH, salinity, and the major cations and anions. Table 4 summarizes additional inorganic metals analyses. Laboratory reports with Chain -of -Custody documentation are provided in Appendix B. Since 2004, nitrates and other nutrient -constituents have generally decreased. Nitrate concentrations reported for Site wells in November 2017 show less variability than previous monitoring events. Particularly, nitrate concentrations across the Site narrowly range from 10.45 mg/L (MWa3) to 14.53 rng/L (MW -I). 4.7 Statistical Analysis Statistical evaluation of groundwater monitoring results is provided by Al's third party engineer. It should be noted that MA's statistical findings are solely under the responsible charge of A's qualified groundwater scientist. Al's findings for the groundwater monitoring program are separate and under the responsible charge of Al Organics' qualified groundwater professional. Essential excerpts from M.'s statistical evaluation are provided as Appendix C. SMA s complete statistical analysis is provided within the enclosed compact disc. 5.0 Findings Similar to the Central Valley of California, historic and current agricultural operations in the vicinity of the Site are most likely responsible for the nutrient (nitrate, sulfate, and total dissolved solids) concentrations observed in Site monitoring wells. During 2017, groundwater monitoring was conducted within two distinct and separate groundwater flow regimes. During the May 2017 groundwater monitoring event, groundwater was affected by a major storm event where a significant rise in groundwater elevations was exhibited across all wells in the system. Concentrations for constituents of concern were reported for the May 2017 event as significantly elevated in most wells, Groundwater Monitoring Report Eaton Organic Recycling Facility Weld County, CO 12 February 5, 2018 Curing the November 2017 groundwater monitoring event, groundwater elevations suggest that groundwater flow was equilibrating in the absence of seasonal significant recharge and adjacent water supply welt pumping. Under this groundwater flow regime, concentrations for constituents of concern were reported as significantly decreased in most wells as compared to the May 017 groundwater monitoring event. These results further suggest that seasonal upgrad lent agricultural nutrient applications, associated irrigation, and major storm water events are responsible for the elevated nutrient concentrations observed in Site monitoring wells. As a point of clarification regarding Al's May 2017 Groundwater Monitoring Report: all clay -lined water retention ponds leak to a certain degree. In Al's May 2017 Groundwater Report, the statement that "Al finds the storm water pond is definitely leaking" was intended to acknowledge that fact only. There is not currently, nor has there been presented any verifiable evidence demonstrating or supporting that a representative hydraulic connection9 with the uppermost aquifer beneath the facility exists as was inferred by the comment presented in the CDPHE correspondence dated September 20, 2017. 6.0 Limitations Al has prepared this Report based on available information consistent with the standards of care and skill ordinarily► exercised by members of the profession practicing under similar conditions in the geographic vicinity and at the time the monitoring was performed. No warranty or guarantee, expressed or implied, is a part of this Report. This Report is for the exclusive use of Al Organics. Use or reliance by others is prohibited without the express authorization of Al. Unauthorized use or reliance is at third party's sole risk. 9 "This statement demonstrates a hydraulic connection with the uppermost aquifer beneath the Facility." ." CDPHE correspondence to Al dated September 20, 2017. Groundwater Monitoring Report Eaton Organic Recycling Facility Weld County, CO 13 February 5, 2018 Tables TABLE 1 SUMMARY OF FIELD PARAMETERS Al EATON WELD COUNTY, COLORADO Well Identification No. Date Specific Conductivity pH (pmhoslcm) Temperature Purge Volume r C) (gallons) MW -1 PZ-2 MW -3 MW -4 6/11/2011 8128/2012 11/29/2012 6/28/2013 11/25/2013 2/26/2014 5/28/2014 8/5/2014 11/26/2014 2/12/2015 5/28/2015 8/19(2015 11/25/2015 5/18/2016 11/10/2016 5/30/2017 11/29/2017 2112/2018 8/19/2015 5/18/2016 11/10/2016 5/30/2017 11/29/2017 4/13/2012 7/23/2012 2/12/2015 8/19/2015 5/18/2016 11/10/2016 5/30/2017 11/29/2017 8/28/2012 11/29/2012 6/28/2013 11/25/2013 2/26/2014 NM 2360 3640 3500 3410 2870 3200 3400 3720 3690 3600 3710 3850 3450 3157 3094 3661 3290 2650 3010 2 841 2726 3757 2360 5260 3160 2980 2770 2585 2427 3247 7050 3340 3040 2460 2400 NM 7.46 7.42 6.93 7.33 7.35 7.17 7.02 6.86 6.90 7.21 6.82 7.08 6.52 7.24 6.93 7.09 4.45 7.37 6.55 7.29 6.78 7.17 7.40 6.34 7.08 6.93 6.48 7.27 6.93 7.20 7.63 7.44 7.09 7.55 7.60 NM NM 17.4 NM 12.1 NM 16.2 NM 12.2 NM 13.2 NM 15.0 NM 13.8 NM 10.6 NM 11.8 NM 13.1 NM 14.8 NM NM NM 14.3 NM 13.4 5.0 12.9 6,0 13,8 6.0 8.3 NM 14.5 NM 6.5 NM 14.3 8.0 10.0 8,0 13.5 8.0 13.1 NM 15.0 NM 10.1 NM 12.0 NM 7.8 NM 12.8 8.0 12.8 10.0 13.0 10.0 14.3 NM 11.2 NM 18,1 NM 1 1 A NM 9.5 NM TABLE SUMMARY F FIELD PARAMETERS Al EATON WELD COUNTY, COLORADO Well Specific Identification Date Conductivity pH No. (pmhoslcm) Temperature Purge Volume (°C) (gallons) MW -4 5/28/2014 2 520 7.23 14.7 NM 8/5/2014 3300 7.20 12.6 NM 11/26/2014 3240 7.09 9.4 NM 2/12/2015 3140 7.03 10.9 NM 5/28/2015 3600 7.41 13.1 NM 8/19/2015 3540 7.32 12.4 NM 11/25/2015 3350 7.06 NM NM 5/18/2016 3360 6.98 12.7 NM 11/10/2016 3171 7.31 12.3 9.0 5/30/2017 3152 6.96 12.6 10.0 11/29/2017 3807 7.13 12.4 10.0 MW -5A 8/28/2012 7680 8.01 17.8 NM 11/29/2012 3620 7.95 12.8 NM 6128/2013 3200 7.07 18.1 NM 11/25/2013 2360 4.48 13.4 NM 2/26/2014 2420 7.39 12.3 NM 5/28/2014 2000 7.00 15.9 NM 8/5/2014 2700 7.05 16.9 NM 11/26/2014 2670 7.04 9.0 NM 2/12/2015 2690 4.11 11.0 NM 5/28/2015 3400 7.34 12.1 NM 8/19/2015 3430 7.39 15.6 NM 11/25/2015 2780 7.17 NM NM 5/18/2016 3300 6.49 8.4 NM 11/10/2016 2508 7.31 14.6 8.0 5/30/2017 3005 6.63 12.2 8,0 11/29/2017 3174 6.65 14.2 8.0 MW -6 5/30/2017 3025 5.83 11.4 0.0 11/29/2017 3592 7.20 13.6 6.0 Notes: pmhos/cm - rnicromhos per centimeter °'C - degrees Celsius gpm - gallons per minute N/A - Non Assumpsit TABLE SUMMARY OF GROUNDWATER ELEVATIONS Al EATON WELD COUNTY, COLORADO Well ID No. Date Top of Casing S* Casing Elevation n height Elevation ft a�n 1 (ft) (ft amyl) Reported Top of Bottom Screen Interl Screen of Screen b Elevation Elevation (ft Depth to Water (ft below TOC) Total Depth (ft below TOC) Depth to Water Water Elevation (ft bgs) (ft amsi) MW -1 6/11/2011 8/28/2012 11/29/2012 6/28/2013 11/25/2013 2/26/2014 5/28/2014 8/5/2014 11/26/2014 2/12/2015 5/28/2015 8/19/2015 11/25/2015 5/18/2016 11/10/2016 5/30/2017 11/29/2017 P7-2 2/12/2015 8/19/2015 11/25/2015 5/18/2016 11/10/2016 5/30/2017 11/29/2017 4859.31 4854.82 3.10 4856.21 2.43 4852.39 10 - 25 4846.21 4831.21 5 - 20 4847.39 4832.39 NM NM NM 20.74 NM 17.64 21.53 NM 18.43 20.99 NM 17.89 21.09 NM 17.99 21.13 NM 18.03 20.80 NM 17.70 19.65 NM 16.55 18.98 NM 15.88 18.96 NM 15.86 18.64 NM 15.54 17.85 NM 14.75 18.21 NM 15.11 17.84 NM 14.74 18.77 28.2 15.67 17.69 28.2 14.59 18.25 NM 15.15 8.63 NM 6.20 5.25 NM 2.82 7.40 NM 4.97 8.21 NM 5.78 7.63 22.8 5.20 7.53 22.8 5.10 8.17 NM 5.74 NM 4838.57 4837.78 4838.32 4838.22 4838.18 4838.51 4839.66 4840.33 4840.35 4840.67 4841.46 4841.10 4841.47 4840.54 4841.62 4841.06 4846.19 4849.57 4847.42 4846.61 484719 4847.29 4846.65 TABLE SUMMARY OF GROUNDWATER ELEVATIONS Al EATON WELD COUNTY, COLORADO Well ID No. Date Top of Casing Elevation (ft amsl) Casing G.S. height Elevation (ft) (ft amyl) Reported Screen Interval (ft bgs) Top of Bottom Depth to Water Screen of Screen (ft below Elevation Elevation TOC) Total Depth (ft below TOC) Depth to Water Water Elevation (ft bgs) (ft amal) MW -3 4/13/2012 7/23/2012 2/12/2015 5/19/2015 11/25/2015 '5/18/2010 11/10/2016 5/30/2017 11/29/2017 MW -4 8/28/2012 11/29/2012 6/28/2013 11/25/2013 2/26/2014 '5/28/2014 8/5/2014 11/26/2014 2/1212015 5/28/2015 8/19/2015 1'1/25/2015 5/18/2016 11/10/2015 5/30/2017 11/29/2017 4867.14 4857.76 2.50 2.52 4854.54 19 - 34 4845.64 4830.64 4855.24 10 - 30 4845.24 4825.24 22.09 NM 19.59 24.32 NM 21.82 22.02 NM 19.52 19.62 NM 1712 21.15 NM 18.85 20.89 NM 18.39 21.97 37.0 19.47 20.84 37.0 18.34 21.18 NM 18.68 20.05 NM 17.53 20.84 NM 18.32 20,30 NM 17.78 2a40 Nm 17.88 20.43 NM 17.91 20.17 NM 17.65 19.11 NM 18.59 18.46 NM 15.94 18.45 NM 15.93 18.05 NM 15.53 17.34 NM 14.82 17.68 NM 15.15 17.26 NM 14.74 18.15 34.9 15.63 16.97 34.8 14.45 17.69 NM 15.17 4845.05 4842.82 4845.12 4847.52 4845.99 4846.25 484517 4846.30 4845.96 4837.71 4836.92 4837.46 4837.36 4837.33 4837.59 4838.65 4839.30 4839.31 4839.71 4840,42 4840.08 4840.50 4839.61 4840.79 4840.07 TABLE SUMMARY OF GROUNDWATER ELEVATIONS N Al EATON WELD COUNTY, COLORADO Well ID No. Date Top of Casing Elevation (ft amyl) Casing G. . Reported Top of Bottom Screen height Elevation Interval Screen of Screen (ft) (ft amyl) ft b Elevation Elevation Depth to Water (ft below TOC) Total Depth to Water Depth Water Elevation (ft below (ft bgs) (ft amsl) TOG) MW -5 MW -5A MW -6 Notes: 8/28/2012 11/29/2012 6/28/2013 11/25/2013 2/26/2014 5/28/2014 8/5/2014 11/26/2014 '2/12/2015 5/28/2015 8/19/2015 11/25/2015 5/18/2916 11/10/2016 5/30/2017 11/29/2017 4862.82 5/30/2017 4855.90 11/29/2017 2.45 4860.37 5► - 20 4855.37 4840.37 3.08 4852.82 ft amsl feet above mean sea level ft below TOC - feet below top of casing ft bgs - feet below ground surface NIA Non Assumpsit 9 19 4843.82 4833.82 10.29 NM 7.84 13.22 NM 10.77 12.09 NM 9.64 13.65 NM 11.28 14.86 NM 12.41 13.37 NM 10.92 9.44 NM 6.99 11.11 NM 8.66 12.24 NM 9.79 11.91 1 N M 9.46 6.90 NM 4415 10.78 NM 8.33 12.05 NM 9.60 11.40 26.5 8.95 11.15 26.5 8.7 11.52 NM 9.1 11.03 21.8 7.95 11.78 NM 8.70 4852.53 4849.60 4850.73 4849.17 4847S6 4849.45 4853.38 4851.71 4850.58 4850.91 4855.92 4852.04 4850.77 4851.42 4851.67 4851.30 4844.87 4844.12 TABLE SUMMARY OF pit SALINITY AND MAJOR CATIONS AND ANIONS Al EATON WELD COUNTY, COLORADO Well Identification Date No. Specific Total Organic Carbonate Bicarbonate Chloride Sulfate pH Conductivity Carbon (CO2-)H 0 '(Cl ) 2. Nitrate as N @mh ) ) Nitrite (NO2) MC USM CL* 6.518.x* 250* 250* 'I 0 I MW -1 5/1 /2004 6/11/2011 8/28/2012 11/29/2012 6/28/2013 11/25/2013 2/26/2014 5/28/2014 8/5/2014 11/26/2014 2/12/2015 5/28/2015 8/19/2015 11/25/2015 5/18/2016 11/10/2016 5/30/2017 11/29/2017 n/a 7.13 7.14 7.05 7.03 7.10 7.07 7.20 7.09 7.20 7.26 7.11 7.15 7.18 8.00 7.00 6.95 6.98 n/a 3100 3020 2790 3090 3130 3310 2790 2660 2860 2980 2700 2620 2570 2870 3060 3117 3127 n/a 5.6 5.5 5.7 5.8 5.7 5.3 5.1 5.5 5.1 4.9 5.0 5.1 5.2 <5 6.5 5.9 5.9 n/a n/a n/a nia n/a n/a n/a n/a n/a n/a n/a n/a nfa <2 n/a < 0.1 < 0.1 n/a rila 1985 26.9 500 156 1670 23.7 436 190 1600 24.1 406 199 1530 24.2 443 211 1400 22.2 451 166 1340 20.3 459 172 1410 21.2 521 179 1360 19.7 466 143 1390 21.4 598 127 1370 19.3 434 126 1430 19.1 409 107 1340 17.6 374 119 1290 17.7 398 118 1330 17.8 427 114 1350 17.0 417 144 1380 18.2 411 131 1433 19.4 427 108 1411 14.5 < 0.05 < 0.12 < 0.05 < 0.02 < 0.02 < 0.02 C 0.02 c 0.02 < 0.02 < 0.02 c 0.02 < 0.02 0.043 < 0.02 < 0.01 < 0.01 < 0.03 < 0.03 TABLE SUMMARY OF pH, SALINITY AND MAJOR CATIONS AND ANIONS Al EATON WELD COUNTY, COLORADO Well Identification Date No. Specific Total Organic Carbonate Bicarbonate Chloride Sulfate ph Conductivity Carbon (CO • HCO - I ' Nitrate a N (pmhos!cm) (m91) Nitrite (NO2) M LISMCL* 6,518.5* 250* 250* '10 'I PZ-2 6/7/2011 2/12/2015 8/19/2015 5/18/2016 11/10/2016 5130/2017 11/29/2017 MW -3 6/7/2011 1/17/2012 4/13/2012 7/23/2012 2/12/2015 8/19/2015 5/18/2016 11/10/2016 5/30/2017 11/29/2017 7.41 7.37 7.37 8.10 7.11 710 7.07 7.38 7.29 7.15 7.38 7.40 7.27 8.00 7.13 7.01 7.05 2220 2400 2310 2630 2730 2757 3195 1880 2230 2800 2090 2650 2320 2320 2540 2457 2773 5.8 6.1 7.5 8.6 7.6 1.2 7.9 5.8 10.5 7.2 5.3 6.0 7.6 9.0 6.7 8.6 6.3 n/a n/a n/a <2 n/a < 0.1 <0.1 n/a n/a n/a n/a n/a n/a < 0.1 < 0.1 570 420 370 470 431 431 451 960 495 453 372 461 436 452 429 401 415 42.4 44.1 49.0 48.5 50.2 56.4 54.2 30.2 43.3 42.4 34.7 33.6 34.0 42.9 44.2 47.1 49.3 1270 12.3 1240 11.3 1210 11.8 1130 8.3 1300 9.5 1284 11.5 1491 12.3 930 10.4 1280 7.6 1420 11.6 1150 9.2 1400 1210 8.3 947 11.0 1170 9.3 1095 14.4 1513 10.5 < 0.12 < 0.02 < 0.04 < 0.01 < 0.01 c0.03 < 0.03 < 0.12 < 0.31 <0.05 < 0.05 < 0.02 < 0.02 < 0.01 < 0.01 <0.03 < 0.04 TABLE 3 SUMMARY OF pH, SALINITY AND MAJOR CATIONS AND ANIONS Al EATON WELD COUNTY, COLORADO Well Identification Date No. SpecificTotal Organic Carbonate Bicarbonate Chloride Sulfate Nrite pH Conductivity Carbon (CO3 �- (HCO'(Cl 80 _ Nitrate as N o e) (pmhos!cm) (mglL) M LU M L* 6.518.5* 250* 250* 10 1 MW -4 8117/2012 11129/2012 6/28/2013 11/25/2013 2/26/2014 5/28/2014 815/2014 11/2612014 2/12/2015 5/28/2015 8/19/2015 11/25/2015 5/18/2016 /1110/2015 5/30/2017 11/29/2017 7.27 7,22 7.26 7.35 7.4 7.33 7.21 7.32 7.33 7.28 7.34 7.35 8.00 7.08 7.04 7.05 2720 2530 2710 2700 2840 2420 2190 2360 2650 2540 2520 2550 2840 3040 3182 3266 6.4 5.9 5.9 5,9 5.5 5.1 5.0 4.8 5:1 5.0 5.3 5.6 5.9 6.3 1.5 6.7 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 N/A N/A < 0.1 < 0.1 385 383 414 382 366 370 368 492 366 365 356 387 460 422 443 471 145 1240 133 1420 104 1220 71.9 1270 70.6 1360 63.6 1190 67.4 1270 70.9 1250 71.1 1300 81.8 1220 97.3 1310 161 1310 114 1360 122 1320 122 1465 117 1478 17.6 18.0 15.1 12.2 12.5 10.7 12.1 12.1 12.2 11.4 12.4 12.8 12.0 12.0 12.9 12.0 < 0.05 < 0.02 0.15 0.031 < 0.02 <0.0 1 0.03 0.026 0.029 0.02 0.039 0.07 0.07 0.073 < 0.03 < 0.03 TABLE SUMMARY OF pH, SALINITY AND MAJOR CATIONS AND ANIONS Al EATON WELD COUNTY, COLORADO Well Identification No. Date Specific Total Organic Carbonate Bicarbonate Chloride Sulfate pH Conductivity Carbon(CO3' 0' H ') (Cl) _ Nitrate as N (mhos/ern) OWL) Nitrite (NO2) MCLIMCL* 6.518.5* 250* 250* 10 1 MW -5 MW -5A MW -8 Notes: 8/17/2012 11/29/2012 6128/2013 11/2512013 2/26/2014 5/28/2014 8/5/2014 11/26/2014 2/12/2015 5/28/2015 8/19/2015 11/25/2015 5/18/2016 11/10/2016 5/30/2017 11/29/2017 7.35 7.65 7.23 7.33 7.22 7.31 7.20 7.34 7.33 7.26 7.33 7.38 8.00 7.23 6.92 7.04 5/30/2017 7.00 11/29/2017 7.01 2650 2430 2690 2300 2820 2180 1870 2040 2280 2360 2390 2040 2780 2480 3047 2710 3067 3072 mg/L - milligrams per liter µmhos/cm - micromohs per centimeter N/A - Non Assumpsit m psit 7.2 6.4 9.2 7.0 8.5 7.2 5.6 5.3 6.0 13.5 8.2 6.1 10.0 6.5 9.2 6.6 < 0.5 376 45.8 1410 12.1 < 0.5 349 50.8 1820 12.1 < 0.5 585 49.7 1480 11.4 < 0.5 400 39.6 1100 9.6 < 0.5 443 46.8 1330 10.4 < 0.5 446 38.6 1140 8.6 < 0.5 358 30.8 1010 7.6 < 0.5 557 29.7 979 6.3 < 0.5 467 32.1 1080 7.0 < 0.5 450 37.2 1240 6.2 < 0.5 392 36.2 1310 7.3 < 0.5 395 31.8 1080 6.9 N/A 496 41.9 1260 7.9 N/A 443 34.5 1090 8.5 < 0.1 460 55.1 1437 14.5 < 0.1 415 42.1 1471 11.4 2A < 0.1 448 107.8 1405 13.3 61 < 0.1 457 80.1 1360 11.7 0.46 0.21 < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 0.02 < 0.02 < 0.04 0.021 < 0.05 0.02 < 0.03 < 0.04 < 0.03 < 0.03 TABLE 4 SUMMARY OF METALS NALYT1 AL RESULTS Al EATON WELD COUNTY, COLORADO Well ID No. Date Calcium Magnesium Potassium Sodium Zinc Copper Arsenic Barium Cadmium Chromium (mg!L) (mglL) OA) (mglL) (mglL) (mg1) (mglL) Olga.) OWL) (mg/L) M L/ M L* 5* 1* 0.01 0.005 0.10 MW -1 8/11/2011 8/2812012 11/29/2012 6/28/2013 11/25/2013 2/26/2014 5/28/2014 8/5/2014 11/26/2014 2/12/2015 5/28/2015 8/19/2015 11/25/2015 5/18/2016 11/10/2016 5/30/2017 11/2912017 P7-2 6/7/2011 2/12/2015 8/19/2015 5/18/2016 11/10/2016 5/30/2017 11/29/2017 316 256 2.74 224 291 247 3.37 240 322 235 2.51 213 276 227 3.21 231 295 218 2.77 219 291 223 3.04 234 284 227 2.90 235 277 214 2.61 213 288 199 2.51 222 294 234 3.00 233 270 205 2.94 204 253 200 2/0 218 274 215 2.84 226 259 199 2.90 206 309 206 2/8 206 269 201 2.80 218 248 196 3.30 211 232 172 5.47 189 227 176 3.61 199 230 166 3.54 165 263 188 3.60 176 262 182 4.43 183 265 182 3.30 167 381 251 5.10 254 <0.05 < 0.05 0.073 0.11 0.0526 < 0.05 0.0532 0.0744 < 0.05 < 0.05 < 0.05 < 0.05 0.0775 < 0.05 < 0.02 < 0.001 0.014 0.079 0.226 0.0687 0.05 < 0.02 < .001 0.001 < 0.01 0.01 • 0.023 0.0154 < 0.01 0.0124 0.0202 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 0.0223 < 0.01 0.0078 0.0029 0.0033 0.03 0.0656 0.034 < 0.05 0.0069 0.0016 0, 0021 < 0.008 0.0023 0.0070 0.0093 0.0028 0.0014 0.0037 0.0063 0.0018 0.0018 0.0018 0.0011 0.0059 <0.002 0.0024 0.0007 0.0012 0.0110 0.0273 0.0081 0.0073 0.0028 0.0011 0.0011 0.0230 0.0490 0.1600 0.2800 0.0707 0.0219 0.1180 0.1550 0.0288 0.0370 0.0850 0.0186 0.2110 0.0330 0.0333 0.0127 0.0375 0.1200 0.5240 0.1880 0.1470 0.0263 0.0101 0.0135 < 0.0005 < 0.0005 0.0011 0.00076 C 0.0005 '< 0.0005 < 0.0005 0.00072 < 0.0005 < 0.0005 < 0.0005 C 0.001 0.00065 < 0.0002 0.00055 < 0.0001 < 0.0001 0.0036 0.0022 < 0.001 < 0.001 0.00041 < 0.0001 < 0.0001 < 0.02 0.015 0.028 0.025 < 0.01 < 0.01 0.0116 0.0162 < 0.01 < 0.01 < 0.01 < 0.01 0.0180 < 0.01 <0.004 < 0.0015 0.0034 < 0.02 0.0479 0.0199 < 0.05 <0.004 < 0.0015 < 0.0015 TABLE 4 SUMMARY OF METALS ANALYTICAL RESULTS Al EATON WELD COUNTY, COLORADO WeII ID No. Date Calcium Magnesium Potassium Sodium Zinc Copper Arsenic Barium Cadmium Chromium (rnglL) {mglL) (mglL) (mgrL) (mglL) (mglL) (mglL) (mglL) {mg/L} (mgJL) MCLI' M L* 0.01 2 0:055 0.10 A -3 6/7/2011 1/17/2011 4/13/2012 7/23/2012 2112/2015 8/19/2015 5/18/2016 11110/20/5 5/30/2017 11129/2017 MW -4 8/172012 11/29/2012 6/28/2013 11/25/2013 2/26/2014 5/28/2014 8/5/2014 11/26/2014 2/12/2015 5/28/2015 8/19/2015 11/25/2015 5/18/2016 11/10/2016 5130/2017 193 125 3.96 139 268 174 3.82 170 284 186 4.02 176 220 150 8.54 152 297 207 4.37 197 244 167 3.75 169 235 149 3.80 145 264 154 3.70 148 240 151 3.60 147 277 182 4.20 175 270 196 3.50 219 272 182 2.82 206 232 173 3.34 215 255 172 2.92 213 243 172 3.01 209 244 178 2.92 216 234 169 2/2 201 251 163 2.65 213 246 188 2.96 214 248 171 2.81 194 236 174 2.78 211 266 195 2.96 234 261 188 3.00 205 297 203 3.26 217 286 201 3.00 232 < 0.05 0.47 < 0.05 0.11 0.069 0.0056.E 0.06 < 0.02 < 0.001 < 0.001 0.072 0.070 0.27 0.0751 0.147 < 0.05 0.0654 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.01 <0.02 < 0.001 0.017 0.044 0.012 0.028 0.0192 0.0163 < a05 0.0069 0.0015 0.0017 0.017 0.019 0.059 0.207 0.0295 < 0.01 0.0117 < 0.01 < 0.01 < 0.01 < 0.01 0.0106 < 0.01 0.004 0.0015 0.0085 0.0190 0.0077 0.0190 0.0076 0.0073 0.0067 0.0043 0.001 0.0011 0.0077 0.0080 0.0330 0.0062 0.0148 0.0026 0.0055 0.0020 0.0013 0.0016 0.0015 0.0033 <0.002 0.001 0.0007 0.1700 0.6800 0.1400 0.4700 0.2420 0.2330 0.2260 0.0800 0.0119 0.0150 0.1400 0.1200 0.5700 0.1240 0.3110 0.4760 0.1120 0.0336 0.0212 0.0256 0.0248 0.1040 0.0210 0.0137 0.0123 0.0036 0.0028 0.0013 0.0022 < 0.0005 < 0.001 < 0.001 0.00042 < 0.0001 < 0.0001 0.00084 0.0013 0.0016 0.0005 0.00093 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.001 C 0.0005 < 0.0002 0.00023 < 0.0001 c 0.02 0.034 0.013 0.031 0.0161 0.0182 < 0.05 <0.004 < 0.0015 < 0.0015 0.016 0.017 0.051 0.0127 0.028 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.004 < 0.0015 TABLE 4 SUMMARY OF METALS N, LYTI AL RESULTS Al EATON WELD COUNTY, COLORADO Well ID No. Date Calcium Magnesium Potassium Sodium Zinc Copper Arsenic Barium Cadmium Chromium OWL) (ma) (mgt) (m L) (mglL) (mglL) (rnglL) (mg/L} (mg/L) (mg!L) .III L/SMCL* 0.0111 0.005 0.10 MW -4 MW -5 MW -5A MW -6 Notes: 11/29/2017 8/17/2012 11/29/2012 6/28/2013 11/25/2013 2/26/2014 5/28/2014 815/2014 11/26/2014 2/12/2015 5/28/2015 8/19/2015 11/25/2015 5/18/2016 11/10/2016 5/30/2017 11/29/2017 5/30/2017 11/29/2017 282 205 3A0 237 281 192 5.43 234 294 191 5.20 310 295 202 5.40 207 239 145 3.85 155 280 181 4.39 182 240 157 3.90 175 199 127 4.15 145 219 126 3.95 161 232 156 4.01 163 284 174 4.23 166 259 169 8.35 189 232 154 7.19 174 291 184 4.20 188 244 149 4.28 175 307 187 4.30 185 256 164 4A0 179 288 193 3.50 208 294 199 3.90 212 mg/L - milligrams per liter; pg/L - micrograms per liter 0.009 0.0032 0.0015 0.0279 < 0.05 < 0.05 0.21 0.225 0.12 0.159 <0.08 0.0716 0.0958 0.129 < 0.05 < 0.08 0.05 < 0.02 < 0.001 < 0.001 < 0.01 0.0013 0.0220 0.014 0.0053 0.0580 0.052 0.0360 0.5700 0.0619 0.0360 0.6470 0.03 0.0167 0.3610 0.036 0.0188 0.4270 < 0.01 0.0039 0.0667 0.0198 0.0097 0.1940 0.025 0.0131 0.2590 0.0293 0.0156 0.3190 0.0119 0.0047 0.1060 0.0124 0.0054 0.1190 < 0.08 0.0091 0.2070 0.0073 0.0040 0.0324 0.002 0.0011 0.0172 0.002 0.0011 0.0147 < 0.001 0.0017 0.0008 0.0128 < 0.001 0.0014 0.0009 0.0127 < 0.0001 < 0.0008 0.00065 0.0014 0.00052 0.00076 < 0.000► < 0.0008 0.00072 < 0.0008 < 0.0005 < 0.001 <0.0008 < 0.001 0.00039 < 0.0001 < 0.0001 < 0.0001 < 0.0001 0.0018 < 0.01 0.016 0.038 0.044 0.0245 0.0284 c 0.01 0.0156 0.0199 0.0232 0.0116 < 0.01 < 0.05 <0.004 < 0.0015 < 0.0018 < 0.0018 < 0.0015 TABLE 4 (continued) SUMMARY OF METALS ANALYTICAL RESULTS Al EATON WELD COUNTY, COLORADO WeII ID No. Date Cobalt Lead Nickel Selenium Silver Vanadium Beryllium Antimony Thallium (mg1L) (rnglL) (mgr .) (mg/L0 (mglL) (mq!L) (m l'L) (mg1L) (mglL) MCU CL* 04050 0,100* 01,34 0.006 04002 MW -1 6/11/2011 8/28/2012 11/29/2012 6/28/2013 11/25/2013 2/26/2014 5/28/2014 8/5/2014 11/26/2014 2/12/2015 5/28/2015 8/19/2015 11/25/2015 5/18/2016 PZ-2 < 0.002 < 0.001 0.0055 0.008 < 0.001 < 0.001 0.0016 0.0041 < 0.001 < 0.002 < 0.002 < 0.001 0.0059 < 0.01 11/1012016 < 0.0004 5/30/2017 0.0004 11/29/2017 0.0014 6/7/2011 0.007 2/12/2015 0.0524 8119/20/8 0.0123 5/18/2016 < 0.05 11/10/2016 < 0.0004 5/30/2017 < 0.0002 11/29/2017 0.0017 c 0.0025 0.0032 0.013 0.024 0.0057 < 0.0025 0.0073 0.012 < 0.0025 < 0.0025 0.0026 < 0.0025 0.016 0.0027 0.0065 0.0005 0.0022 0.013 0.0523 0.0147 0.0118 0.0021 c .0001 <.0001 0.02 0.019 0.061 0.026 0.0165 0.0139 0.0111 0.0212 0.0104 0.0164 0.0119 0.0100 0.0227 < 0.008 0.0124 0.0014 0.0034 0.052 0.0683 0.0166 < 0.04 0.0118 0.001 0.0015 0.013 0.012 0.018 0.011 0.0066 0.0073 0.0082 0.0091 0.0079 0.0087 0.0073 0.0081 0.0095 0.0077 0.0101 0.0092 0.0054 0.012 0.0079 0.0055 < 0.008 0.0042 0.0043 0.0032 < 0.0008 < 0.0005 < 0.0008 < 0.0008 < 0.0005 < 0.0008 < 0.0008 < 0.0008 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.01 < 0.0002 < 0.0001 < 0.0001 0.0056 0.0150 0.0340 0.0480 0.0156 0.0077 0.0222 0.0290 0.0084 0.0089 0.0086 < 0.008 0.0380 < 0.005 0.0087 0.003 0.007 c 0.0005 0.04 < 0.0005 0.1140 < 0.0005 0.0461 < 0.01 0.033 < 0.0002 0.0097 < 0.0001 0.004 < 0.0001 0.006 < 0.001 < 0.001 < 0.001 0.0021 < 0.001 < 0.001 < 0.001 0.0011 < 0.001 < 0.001 c 0.001 < 0.001 0.0015 < 040005 0.00062 < 0.0001 0.0002 0.0074 0.0042 0.0011 0.0011 < 0.0004 < 0.0001 < 0.0001 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 c 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.0008 < 0.0008 < 0.0012 < 0.0012 < 0.002 < 0.002 < 0.002 < 0.0008 < 0.0008 < 0.0012 < 0.0012 < 0.001 < 0.001 0.0012 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.0002 < 0.0004 < 0.0002 < 0.0002 < 0.001 0.001 < 0.001 < 0.001 < 0.0004 < 0.0002 < 0.0002 TABLE 4 (continued) SUMMARY OF METALS ANALYTICAL RESULTS Al EATON WELD COUNTY, COLORADO Well ID No. Date MCUSIVICLIc Labatt Lead Nickel Selenium Silver Vanadium Beryllium Antimony Thallium (mg1L) tmglLy (mg1Lj (mg/L) (mg/L) (mgfL) (mg1L) (mglL) {mg(L) 0.050 MOO* 0.004 0.006 0.002 MW -3 6/7/2011 1/17/2011 4/13/2012 7/23/2012 2/12/2015 8/19/2015 5/18/2016 11/10/2016 5/30/2017 11/29/2017 MW -4 8/1720/2 11/29/2012 6/28/2013 11/25/2013 2/26/2014 5/28/2014 8/512014 11/26/2014 2/12/2015 5/28/2015 8/19/2015 11/25/2015 5/18/2016 11/10/2016 5/30/2017 11/29/2017 0.0079 9 0.02 0.0049 0.013 0.0044 0.0048 < 0.01 0.0009 < 0.0002 < 0.0002 0.0053 0.0056 0.03 0.0037 0.014 < 0.001 0.0025 < 0.001 < 0.002 < 0.002 < 0.001 0.0016 <0.01 < 0.004 0.0004 0.0019 0.021 0.035 0.011 0.027 0.0134 0.0128 0.0109 0.0057 < 0.0001 < 0.0001 0.011 0.0089 0.054 0.0101 0.0252 0.0036 0.0076 < 0,0025 c 0.0025 < 0.0025 < 0.0025 0.0064 < 0.001 < 0.001 0.0002 0.0027 0.039 0.0086 0.05 0.0050 0.024 0.0071 0.032 0.008 0.0262 0.0072 0.021 0.0061 < 0.04 0.0052 0.0113 0.0065 0.0011 0.0059 0.0011 0.0071 0.016 0.0079 0.057 0.01 0.058 0.011 0.0201 0.0000 0.039 0.0118 < 0.01 0.0086 0.0178 0.0105 0.0101 0.0093 0.0132 0.0082 0.0113 0.0082 0.0104 0.009 0.0142 0.008 < 0.04 0.0056 0.0102 0.0042 0.0017 0.005 0.0038 0.0042 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.01 < 0.0002 < 0.0001 < 0.0001 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 <0.01 < 0.0002 < 0.0001 < 0.0001 0.0460 0.1000 0.0390 0.0740 0.0442 0.0460 0.037 0.0168 0.005 0.005 0.02 0.0290 0.0100 0.0254 0.0597 0.0104 0.0177 < 0.005 < 0.005 0.0063 0.0056 0.0115 <0.005 0.002 0,002 0.006 0.0036 0.0029 0.0013 0.0022 0.0013 < 0.001 0.0009 < 0.0004 < 0.0001 < 0.0001 < 0.001 < 0.001 0.004 < 0.001 0.0022 < 0.001 < 0.001 < 0.001 < 0.001 • 0.001 < 0.001 < 0.001 < 0.0001 < 0.0004 < 0.0001 0.0002 < 0.002 < 0.002 < 0.002 < 0.002 <0.002 < 0.002 < 0.0005 < 0.0005 < 0.0012 < 0.0012 <0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 <0.002 < 0.002 <0.002 < 0.0003 < 0.0005 < 0.0012 < 0.0012 < 0.001 0.002 < 0.001 0.0017 < 0.001 < 0.001 < 0.0002 < 0.0004 c 0.0002 < 0.0002 < 0.001 0.0026 < 0.001 < 0,001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.0002 < 0.0004 < 0.0002 < 0.0002 TABLE 4 (continued} SUMMARY OF METALS ANALYTICAL RESULTS Al EATON WELD CC3UNTY, COLORADt? Well ID No. Date Cobalt Lead Nickel Selenium Silver Vanadium Beryllium Antimony Thallium (maf L) (mg!L) (mg!L) (mglL) (mglL) (mg/L) (m L) (mg#L) (mglL) M LISMCL* 01 ll 004 0,006 0.002 MW -5 MW -5A MW -6 Notes: 8/17/2012 11/29/2012 6/28/2013 11/25/2013 2/26/2014 5/28/2014 8/5/2014 11/26/2014 2/12/2015 5/28/2015 8/19/2015 11/25/2015 5/18/2016 11/10/2016 5/30/2017 11/29/2017 5/30/2017 11/29/2017 < 0.001 0.0012 0.018 0.0227 0.009 0.012 < 0.001 0.0043 0.0059 0.007 < 0.001 0.0014 < 0.05 0.0006 0.0002 < 0.0025 0.0053 0.043 0.0485 0.0227 0.0277 0.0033 0.0132 0.0171 0.0217 0.0062 0.0068 0.0109 0.0055 < 0.0001 <0.01 0.063 0.044 0.0497 0.0319 0.0266 0.0101 0.0166 0.0256 0.0257 0.0153 0.0119 <0.04 0.0111 0.0014 < 0.0002 < 0.0001 0.0009 0.01 0.0075 0.0099 0.0086 0.01 0.0065 0.0071 0.0079 0.0097 0.0095 0.0057 0.0054 0.0053 0.0059 0.0067 0.0056 < 0.01 0.014 0.052 0.0619 0.03 0.036 < 0.01 0.0198 0.025 0.0293 0.0119 0.0124 < 0.05 < 0.0002 < 0.0001 < 0.005 0.0230 0.1200 0.1420 0.0780 0.0889 0.0140 0.0449 0.0604 0.0731 0.0240 0.0273 0.0410 0.0143 0.005 < 0.001 < 0.001 0.0039 0.0041 0.0028 0.003 < 0.001 0.0012 0.0015 0.0017 < 0.001 < 0.001 0.001 0.00053 < 0.0001 < 0.0001 0.005 < 0.0001 0.0002 < 0.0001 0.0018 0.0082 < 0.0001 0.003 < 0.0001 0.0002 < 0.0001 0.0014 0.0067 001001 0.003 < 0.0001 mg1L - milligrams per liter < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 c0.002 <0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.0008 0.0018 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.0002 < 0.0004 < 0.0002 < 0.0002 < 0.0002 < 0.0002 Figures R _ _,. th Severance n d o r I Hi • a Pierce An1 Organics Eaton �!. in 4 eta a Greeley , fic4) Garden ity Evans La Salle Approximate Scale 1 inch = 6 miles (14A:i Gale -tog Kersey 4 organics 16350 WCH 76Ji Eaton, CO 80615 (O) 970454-3492, (F) 9704544232 Site Location Map Al Organics - Eaton 16 350 Weld County Rd 76 Eaton, Weld County, Colorado FIGURE 1 Site and Vicinity Map 414 organics 16350 WCR 76, Eaton, CO 80615 (0) 970-454-3492 (F) 970454-3232 Al Organics - Eaton 16350 Weld County Rd 76 Eaton, Weld County, Colorado FIGURE 2 Approximate Scale 1 inch = 2,200 feet So organics 15350 WCR 76, Eaton, CO 80615 (0) 970-454-3492 (9 970-454-3232 Topographic Map Al Organics Eaton 16350 Weld County Rd 76 Eaton, Weld County, Colorado FIGURE 3 MW -3 -sip .+rs a 4 r 4 4 7 a II; I FZ-3 ximate Scale 1 inch = 175. feet organics Well Location Map Al Organics - Eaton 1 350 Weld County Rd 76 Eaton, Weld County, Colorado FIGURE 4 - Surface water body - Crop► Irrigation recharge organics Al Stouter Pond 16350 WCR 76, Eaton, CO 80615 (0) 970-454-3492 (F) 970-454-3232 Groundwater Recharge Map Eaton Organic Recycling Facility 1 350 WCR 76 Eaton, Colorado FIGURE 5 p li R IN M ■ !I 4,44 12. Approximate Scale I inch v 175 feet 'Contour Interval 1 loot Groundwater Contour Map November 29, 2017 Al Organics - Eaton 16350 Weld County Rd 76 Eaton, Weld County, Colorado FIGURE Appendix A Groundwater Information and Site Hydrographs Depth to Water (feet bgs) 0.00 JV 05/10/16 08/18/16 11/26/16 -5.00 -20.00 -25.00 03/06/17 06/14/17 09/22/17 12/31/17 04/10/18 Date —. MW -1 PZ-2 MW -3 M '-4 MW -5A M1 -6 TPZ-3 Al Organics - Eaton MW's Hydrograph 4856.00 4854.00 4852.00 4850.00 U IC g 4848.00 140 41 4846.00 C 0 '5 4844.00 4842.00 4840.00 4838.00 05/10/16 12/31/17 08/18/16 11/26/16 03/06/17 06/14/17 Date 09/22/17 04/10/18 —es M -1 -- —PZ-2 -4 —0—MW-5A TPZ-3 East MW's Hydrograph 4848.00 4847.10 4846.00 4845.00 2 cc g 4844.00 re 4843.00 3 C c 4842.00 4841.00 4840.00 4839.00 Same pattern as below MW natural WS well no Rum recovery in Stormwater and irrigation recharge MW ', ►ellrr�ire pumping IOW S well nat r 'Now _ w _ _ _f . 05/10/16 08/18/16 11/26/16 03/06/17 06/14/17 Date 09/22/17 12/31/17 c -a —MW -4 oral recovery no pumping 04/10/18 East MW's DTW 0100 05/1(/16 -5.00 -1100 42 .r. L IR 44 CL ,l -15.00 -20.00 -25.00 08/18/16 11/26/16 03/06/17 06/14/17 09/22/17 12/31/17 04/10/18 May event - NO3 MW -1 = 1964 MW -4 = 12r9 Nov event - NO3 '11u-1=14.5 MW -4=12.O Date --f- MW -1 men MW -3 i1�ItJ'k-4 Central MW's Hydrograph 4850.00 4849.00 4848.00 ire 2 4 ift c 4847.00 to a' W 0J 4.0 4846.00 wv ti to 4845.00 4844.00 Significant Stormwater recharge event Significant Storrnwaytor recharge event 4843,00 03/06/17 04/25/17 06/14/17 08/03/17 09/22/17 11/11/17 12/31/17 02/19/18 Date [fit '-► —TPZ-8 West MW's DTW 0.00 Groundwater depth below ground surface (t) 05/10/16 -2.00 -4.00 -6.00 -8.00 40.00 -12.00 08118/16 11/26/16 03/06/17 06/14/17 09/22/17 12/31/17 04/10/18 Date MW -SA Groundwater Mounding Beneath the Storm Water Pond 4855.00 4854.00 485100 485100 VI 2 4851.00 c tu it 4850.00 -t3 4849.+00 c Q, 4848.00 4847.00 4846.00 4845.00 t. Surveyed Storm Water Pond Surface Elevation - 4851.00 feet AIVISL Excessive -moisture August 2016 issues 18' Clay liner in the sump area Typical minimum separation distance 5 feet ii! 05/10/16 08/18/16 11/26/16 03/06/17 06/14/17 Date 09/22/17 12/31/17 04/10/18 -es PZ-2 Figure 4 Appendix A SUMMARY OF GROUNDWATER ELEVATIONS Al EATON WELD COUNTY, COLORADO Well ID No. Date Top of Casing Elevation* (ft amsl) Casing height (ft) Reported G.8,Screen Elevation Interval (ft amsl) (ft bgs) Top of Bottom Depth to Water Screen of Screen (ft below Elevation Elevation TOC) Total Depth (ft below TOC) Depth to Water Water Elevation (ft bya) (ft amsl) MW -1 5/18/2016 8/17/201 6 8/25/2016 8/31/2016 9/7/2016 9/12/2016 9/20/2016 9/26/2016 10/4/2016 10/10/2016 10/17/2016 10/26/2016 11/1/2016 11/10/2016 11/16/2016 11/23/2016 11/30/2016 12/6/2016 12/12/2016 12/20/2016 12/28/2016 1/6/2017 1/12/2017 1/18/2017 1/26/2017 1/31/2017 2/8/2017 2/15/2017 4859.31 3.10 4856.21 10 - 25 4846.21 4831.21 17.84 NM -14.74 18.17 28.2 -15.07 18.25 28.2 -15.15 18.29 NM -15.19 18.48 28.2 -15.38 18.63 NM -15.53 18.79 28.2 15.69 18.85 NM -15.75 18.85 28.2 -15.75 18.81 NM -15.71 18.79 28.2 4 5.69 18.81 NM -15.71 18.75 28.2 -15.65 18.77 28.2 -15.67 18.65 NM -15.55 18.70 NM -15.60 18.7'1 28.2 45.61 18.69 NM -15.59 18.65 28.2 -15.56 18.66 NM -15.56 18.64 NM -15.54 18.59 NM -15.49 18.61 NM -15.51 18.54 NM -15.44 18,54 NM -15.44 18.44 NM -15.34 18.52 NM -15.42 18.42 NM -15.32 4841.47 4841.14 4841.06 4841.02 4840.83 4840.68 4840.52 4840.46 4840.46 4840.50 4840.52 4840.50 4840.56 4840.54 4840.66 4840.61 4840.60 4840.62 4840.66 4840.65 4840.67 4840.72 4840.70 4840.77 4840.77 4840.87 4840/9 4840.89 Well ID No. Date Top of Casing Elevation* (ft amsl) Casing G.S. height Elevation (ft) (ft arnsl° Reported Screen Interval (ft bgs) Top of Bottom Water Screen of Screen ft below Elevation Elevation TOG) Depth to Total Depth (ft below TOG) Depth to Water (ft bgs) Water Elevation (ft am l) it -1 2/22/2017 3/1/2017 3/8/2017 3115/2017 3/22/2017 3/30/2017 4/5/2017 4/11/2017 4/19/2017 4/26/2017 5/312017 5/12/2017 5/16/2017 5/24/2017 5/30/2017 6/7/2017 6/19/2017 6/23/2017 6/27/2017 6/30/2017 7/5/2017 7/1112017 7/1412017 7/19/2017 7/26/2017 7131/2017 8/3/2017 8/7/2017 8/10/2017 8/11/2017 8115/2017 8/21/2017 8/24/2017 8/28/2017 911/2017 18.40 NM 18.45 NM 18.42 NM 18.40 NM 18.39 28.2 18.38 NM 18.44 NM 18.47 NM 18.39 NM 18.35 NM 18.35 NM 18.34 NM 18.33 NM 17.71 NM 17.69 NM 17.73 NM 17.73 NM 17.70 NM 17.58 NM 17.43 NM 17.78 NM 17.91 NM 18.00 NM 18.17 NM 18.38 NM 18.49 NM 18.59 NM 18.63 NM 18.65 NM 18.68 NM 18.71 NM 18.85 NM 18.89 NM 18.87 NM 18.87 NM -15.30 - 15.35 - 15.32 - 15.30 -15.29 -15.28 -15.34 -15.37 -15.29 -15.25 --15.25 -15.24 -15.23 - 14.61 -14.59 -14.63 -14.63 - 14.60 -14.48 -14.33 - 14.68 - 14.81 -14.90 `15.07 -15.28 - 15.39 -15.49 -15.53 -15.55 - 15.58 -15.61 -15.75 -15.79 -15/7 - 15.77 4840.91 4840.86 4840.89 4840.91 4840.92 4840.93 4840.87 4840.84 4840.92 4840.96 4840.96 4840.97 4840.98 4841.60 4841.62 4841.58 4841.58 4841.61 4841.73 4841.88 4841.53 4841.40 4841.31 484114 4840.93 4840.82 4840.72 4840.68 4840.66 4840.63 4840.60 4840.46 4840.42 4840.44 4840.44 Well ID No. Date Top of Casing Elevation* (ft amsi) Casing G.S. height Elevation (ft) (ft amyl) Reported Screen Interval (ft bgs) Top of Bottom Screen of Screen Elevation Elevation Depth to Water (ft below TOC) Total Depth to Water Depth p ft below Water Elevation (ft bgs) (ft amsl) TOC) MW -1 9/6/2017 9/11/2017 9/14/2017 9/1812017 9/21/2017 9/25/2017 9/28/2017 10/3/2017 10/12/2017 10/16/2017 10/20/2017 10/24/2017 10/30/2017 11/10/2017 11/13/2017 11/17/2017 11/27/2017 11/29/2017 12/5/2017 12/8/2017 12/12/2017 12/15/2017 12/19/2017 12/27/2017 PZ-2 5/18/2016 4854.82 8/12/2016 8/17/2016 8/25/2016 8/31/2016 91712016 9/12/2016 9/20/2016 9/26/2016 10/4/2016 2.43 4852.39 5 - 20 18.88 NM -15.78 18.87 NM -15.77 18.84 NM 15.74 18.75 NM -15.85 18.71 NM -15.61 18.78 NM 15.88 18.69 NM -15.59 18.08 NM -15.53 18.54 NM -15.44 18.50 NM -15.40 18.45 NM -15.35 18.47 NM -15.37 18.46 NM -15.36 18.34 NM -15.24 18.34 NM -15.24 18.28 NM -15.18 18.23 NM -15.13 18.25 NM -15.15 18.24 NM -15114 18.19 NM -15.09 18.18 NM -15.08 18.16 NM -15.06 18.20 NM -15.10 18.09 NM -14.99 4847.39 4832.39 8.21 NM -5.78 4.67 22.8 -2.24 4.62 22.9 -2.19 5.34 22.9 -2.91 5.70 NM -3.27 6.07 22,9 -3.64 6.31 NM -3.88 6.68 22.8 -4.25 6.93 NM -4.50 7.10 22.8 -4.67 4840.43 4840.44 4840.47 4840.56 4840.60 4840.58 4840.62 4840.68 4840.77 4840.81 4840.86 4840.84 4840.8 5 4840.97 4840.97 4841.03 4841.08 4841.00 4841.07 4841.12 4841.18 4841.15 4841.11 484t22 4846.61 4850.15 4850.20 4849.48 48491 2 4848.75 4848.51 4848.14 4847.89 4847.72 Well ID No. Date Top of Casing Elevation* (ft amsl) +basin� . . Reported Top of Bottom Screenhei height Elevation Interval Screen of Screen (ft) (ft amsl) ft Elevation Elevation P1-2 16/19/2016 10/17/2016 10/26/2016 11/1/2016 11/10/2016 11/16/2016 11/23/2016 11130/2016 12/6/2016 12/12/2016 12/20/2016 12/28/2016 1/6/2017 1/12/2017 1/18/2017 1/26/2017 1/31/2017 2/8/2017 2/15/2017 2/22/2017 3/1/2017 3/8/2017 3/15/2017 3122/2017 8/30/2017 4/5/2017 4/11/2017 4/19/2017 4/26/2017 5/3/2017 5/12/2017 5/16/2017 5/24/2017 5/30/2017 6/7/2017 Depth to Water (ft below TOC) 7.15 7.22 7.44 7.49 7.63 7.64 7.80 7.95 7.95 7.88 7.93 7.91 8.05 8.66 7.99 8.05 8.03 8.08 8.10 8.17 8.28 8.34 8.52 8.65 8.75 8.87 8.93 8.99 8.68 8.74 8.75 8.83 7.00 7.53 7.77 Total Depth (ft below TOC) NM 22.9 NM 22.9 22.8 NM NM 22.8 N M 22.8 NM NM NM NM NM NM NM NM NM NM NM NM NM 22.8 NM N M 22.8 NM NM NM NM NM NM NM NM Depth to Water Water Elevation (ft bgs) (ft amsl) -4.72 -4.79 -5.01 -5.06 -5.20 - 5.21 -5.37 -5.52 - 5.52 -5.45 - 5.50 -5.48 - 5.62 -5.62 -5.56 -5.62 - 5.61 - 5.65 -5.67 -5.74 -5.86 -5.91 -6.09 -6.22 -6.32 -6.44 - 6.50 -6.56 - 6.25 - 6.31 -6.32 -6A0 -4.57 -5.10 -5.34 4847667 4847.60 4847.38 4847.33 4847.19 4847.18 4847.02 4846.87 4846.87 4846.94 4846.89 4846.91 4846.77 4846.77 4846.83 4846.77 4846.79 4846.74 4846.72 4846.65 4846.54 4846.48 4846.30 4846.17 4846.07 4845.95 4845.89 4845.83 4846.14 4846.08 4846.07 4845.99 4847.82 4847.29 4847.05 Well ID No. Date Top of Casing Elevation* (ft amsl) Casing height (ft) Reported Screen Elevation Interval (ft amsl) (ft bgs) Top of Bottom Screen of Screen Elevation Elevation Depth to Water (ft below TOC) Total Depth to Water Depth ft below Water Elevation (ft bgs) (ft amsl) TOC) P7-2 6/19/2017 6/20/2017 6/23/2017 6/27/2017 6/30/2017 7/5/2017 7/11/2017 7/1412017 7/19/2017 7/26/2017 7/31/2017 8/3/2017 8/7/2017 8/10/2017 8/1112017 8115/2017 8/21/2017 8/24/2017 8/28/2017 9/112017 9/6/2017 9/11/2017 9/14/2017 9/18/2017 9/21/2017 9/25/2017 9/28/2017 10/3/2017 10/12/2017 10/16/2017 10/20/2017 10/24/2017 10/30/2017 11/10/2017 11/13/2017 7.13 NM -4.70 7.28 NM -4.85 636 NM -4.13 7.12 NM -4.69 6.65 NM -4.22 7.25 NM -4.82 5.84 NM -3.41 6.78 NM -4,35 7.12 NM -4.69 6.62 NM -4.19 7.07 NM -4.64 6.01 NM -3.58 5.84 NM -3.41 6.03 NM -3.60 5.69 NM -3.26 8.45 NM -4.02 6.94 NM -4.51 5.43 NM -3.00 4.97 NM -234 4.55 NM -2.12 6.27 NM -3.84 6.67 NM -4.24 6,83 NM -4.40 8.97 NM -4.54 7.09 NM -4.66 7.22 NM -4.79 7.27 NM -4.84 7.35 NM -4.92 7.42 NM -4.99 7.55 NM -5.12 7.58 NM -5.15 7.74 NM -5.31 7.85 NM -5.42 7.95 NM -5.52 8.01 NM -5.58 4847.69 4847.54 4848.26 4847.70 4848.17 4847.57 4848.98 4848.04 4847.70 4848.20 4847.75 4848.81 4848.98 4848.79 4849.13 4848.37 4847.88 4849.39 4849.85 4850,27 4848.55 4848.15 4847.99 4847.85 4847.73 4847.60 4847.55 4847.47 4847.40 4847.27 4847.24 4847.08 4846.97 4846.87 ✓484+6.81 Well ID No. Date Top of Casing Elevation* (ft amsi} Casing t Reporti Top of Bottom height Elevation Screen Interval Screen of Screen (ft) (ft amsl) ft b }Elevation Elevation PZ-2 11/1712017 11/27/2017 11/29/2017 12/5/2017 12/8/2017 12/12/2017 12/16/2017 12119/2017 12/27/2017 MW -3 5/18/2016 8/12/2016 8/17/2016 8/25/2016 8/31/2016 9/7/2016 9/112/2016 9/20/2016 9/26/2016 10/4/2016 10/10/2016 10/17/2016 10/26/2016 11/1/2016 11/10/2016 11116/2016 11/23/2016 11 /30/2016 12/6/2016 12112/2016 12/20/2016 12/28/2016 1/612017 1/1212017 1/18/2017 4867.14 2.50 4864.64 19 - 34 4845.64 4830.64 Depth to Water (ft below TOC) 8.02 8.11 8.17 8.27 8.28 8.29 8,30 8.39 8.43 20.89 21.40 21.43 21.58 21.74 22.01 22.21 22.18 22.25 22.24 22.20 22.12 22.09 22.01 21.97 21.87 21.88 21.85 21.84 21.80 21.78 21.75 21.72 21.71 21.66 Total Depth (ft below TOC) NM NM NM NM NM NM NM NM NM NM 37.1 37.1 37.1 NM 37.0 NM 37.0 NM 37.0 NM 37.0 NM 37.0 37.0 NM NM 37.0 NM 37.0 NM NM NM NM NM Depth to Water Water Elevation (t bgs) (ft smsl) -5.59 -5.68 -5/4 - 5.84 -5.85 -5.88 - 5.87 - 5.96 - 6.00 -18.39 -18.90 - 18.93 - 19.08 - 19.24 - 19.51 -19.71 -19.68 -19.75 -19.74 -19.70 - 19.62 - 19.59 -19.51 -19.47 -19.37 - 19.38 - 19.35 -19.34 -19.30 - 19.28 - 19.25 - 19.22 -19.21 -19.16 4846.80 4846.71 4846.65 4846.55 4846.54 4846.53 4846.52 4846.43 4846.39 4846.25 4845.74 4845.71 4845.56 4845.40 4845,13 4844.93 4844,96 4844.89 4844.90 4844.94 4845.02 4845.05 4845.13 4845.17 4845.27 4845.26 4848.29 4845.30 4848.34 4845.36 4845.39 4845.42 4845.43 4845.48 Well ID No. Date Top of Casing Elevation* (ft amsl) Casing G.S. Reported Top of Bottom a Screen height Elevation Interval Screen of Screen (ft) (ft amsl) bgsElevation Elevation (ft MW -3 1/26/2017 1131/2O17 2/8/2017 2/15/2017 2/22/2017 3/1/2017 3/8/2017 3/15/2017 3/22/2017 3/30/2017 4/5/2017 4/11/2017 4/19/2O17 4/26/2017 5/3/2017 5/12/2O17 5/16/2017 5/24/2017 5/30/2017 6J ■ /2017 6/19/2017 6/23/2017 6127/2017 6/30/2017 7/5/2O17 7/11/2017 7/14/2017 7/19/2017 7/26/2017 7/31/2017 8/312017 8/7/2017 8/1O/2O17 8111/2017 8/15/2017 Depth to Water (ft below TOC) 21.68 21.59 21.61 21.59 21.55 21.61 21.59 21.58 21.54 21.52 21.57 21.56 21.28 21.19 21.33 21.43 21.45 20.80 20.84 20.93 20.28 20.30 20.49 20.69 20/9 21.00 21.07 21.35 21.50 21.45 2+1.69 21.84 22.03 22.18 22.22 Total Depth (ft below TOC) NM NM NM NM NM NM NM NM 37.0 NM NM 37.0 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM Depth to Water (ft bgs) Water Elevation (ft amsl) -19.18 - 19.09 - 19.11 -19.09 -19.05 -19.11 -19.09 -19.08 - 19.04 - 19.O2 - 19.07 -19.06 -18.78 - 18.69 - 18.83 -18.98 -18.95 -18.30 - 18.34 18.48 -17.78 -17.80 -17.99 - 18.19 - 18.29 - 18.50 - 18.57 -18.85 -19.00 -18.95 -19.19 -19.34 -19.53 -19.68 -19.72 4845.46 4845.55 4845.53 484535 484539 4845.58 4845.55 4845.56 4845.60 4845.62 4845.57 4845.58 4845.86 4845.95 4845.81 4845.71 4845.69 4846.84 484630 4846.21 4846.86 4846.84 4846.65 4846.45 4846.35 484614 4846.07 4845.79 4845.64 4845.69 4845.45 4845.80 4845.11 4844.96 4844.92 Well ID Date Top of Casing Elevation* (ft a ms l) Casing +l. height Elevation (ft) (ft acrd) Reported Top of Screen Screen Interval Elevation (ft bgs) Bottom Water of Screen (ft below Elevation TOG) Depth to Total Depth (ft below TOC) Depth to Water (ft bgs) Water Elevation (ft amsl) MW -3 8/21/2017 8/24/2017 8/28/2017 9/112017 9/6/2017 9/11/2017 911412017 9/18/2017 9/21/2017 9/25/2017 9/28/2017 10/3/2017 10/12/2017 10/16/2017 10/20/2017 10124/2017 10/30/2017 11/10/2017 11/13/2017 11/17/2017 11/27/2017 11/29/2017 12/5/2017 12/8/2017 12/12/2017 12/15/2017 12/19/2017 12/27/2017 22.39 NM 22.40 NM 22.48 NM 22.34 NM 22.35 NM 21.99 NM 21.69 NM 21A4 NM 21A4 NM 21.62 NM 21.64 NM 21.65 NM 21.59 NM 21.58 NM 21.51 NM 21.53 NM 21.48 NM 21.32 NM 21.29 NM 21.28 NM 21.19 NM 21A8 NM 21.18 NM 21.14 NM 21.11 NM 21.11 NM 21.10 NM 21.03 NM -19.89 - 19.90 -19.98 -19.84 - 19.85 - 19.49 - 19.19 -18.94 -18.94 -19.12 -19.14 -19,15 -19.09 -19.08 -19.01 - 19.03 - 18.98 - 18.82 - 18.79 -18.78 - 1889 - 18.88 -18.68 - 18.64 - 18.61 - 18.61 - 18.60 - 18.58 4844.75 4844.74 4844.66 4844.86 4844.79 4845.5 4845.45 4845.70 4845.70 4845.52 4845.50 4845.49 4845.55 4845.56 4845.63 4845.61 4848.66 4845.82 4845.85 4845.86 4845.95 4845.96 4845.96 4846.00 4846.03 4846.03 4846.04 4846.11 Well ID Non Date Top of Casing Elevation* (ft amsl) Casing height (ft) Reported of Screen G.S.Top Elevation Screen Interval (ft amsl) (ft bgs) Elevation Bottom Depth to Water of Screen below Elevation (ft TOC) Total Depth (ft below TOC) Depth to Water Water Elevation (ft bgs) (ft amyl) MW -4 5/18/2016 8/12/2016 8/17/2016 8/25/2016 8/31/2016 917/2016 9/12/2016 9/20/2016 9/26/2016 10/4/2016 10/10/2016 10/17/2016 10/26/2016 11/1/2016 11/10/2016 11/16/2016 11/23/2016 11/30/2016 12/6/2016 12/12/2016 12/20/2016 12/28/2016 1/6/2017 1/12/2017 1/18/2017 1/26/2017 1/31/2017 2/8/2017 2/15/2017 2/22/2017 3/1/2017 3/8/2017 3/15/2017 3/22/2017 4857,76 2.52 4855.24 10 - 30 4845.24 4825.24 17.26 NM -14.74 17.45 35.0 -14.93 17.54 35.0 -15.02 17,53 35.1 -15.01 17.60 NM -15.08 17.78 34.9 -15.26 17.95 NM -15.43 18.14 34.7 -15.62 18.22 NM -15.70 18.21 34.8 -15.69 18.22 NM -15.70 18.21 34.8 -15.69 18.22 NM -15.70 18.17 34.8 -15.65 18.15 34.9 -15,63 18.09 NM -15.57 18.13 NM -15.61 18.13 34.8 -15.61 18,12 NM -15.60 18.08 34.8 -15.56 18.09 NM -15.57 18.05 NM -15.53 5 18.09 NM -15.57 18.03 NM -15.51 17.96 NM -15.44 17.95 NM -15.43 17.86 NM -15.34 17.93 NM -15.41 17.83 NM -15.31 17.79 NM -15.27 17.86 NM 15.34 17.83 NM -15.31 17.79 NM -15.27 17.82 34.7 15.30 4840.50 4840.31 4840.22 4840.23 4840.16 4839.98 4839.81 4839.62 4839.54 4839.55 4839.54 4839.55 4839.54 4839.59 4839.61 4839.67 4839.63 4839.63 4839.64 4839.68 4839.67 4839.71 4839.67 4839.73y 4839.80 4839.81 4839.90 4839.83 4839.93 4839.97 4839.90 4839.93 4839.97 4839.94 Well ID No. Date Top of Casing Elevation* (ft arnsl) Casing M.S. height Elevation (ft) (ft arms!) Reported Screen Interval (ft bgs) Top of Bottom Depth to Water Screen of Screen belowElevation Elevation TOC) Total Depth (ft below TOC) Depth to Water Water Elevation (ft bgs) (ft amsl) MW -4 3/3012017 4/5/2017 4/11/2017 4/19/2017 4/26/2017 5/3/2017 5/12/2017 5/16/2017 5/24/2017 5/30/2017 6/7/2017 6/19/2017 6/23/2017 6/27/2017 6/30/2017 7/512017 7/11/2017 7/14/2017 7/19/2017 7/26/2017 7/31/2017 8/3/2017 8/7/2017 8/10/2017 8/11/2017 8/15/2017 8/21/2017 8/24/2017 8/28/2017 9/1 /2017 9/8/2017 9/11/2017 9/14/2017 9/18/2017 9/21/2017 1719 NM -15.27 17.83 NM -15.31 17.88 34.8 -15.36 17.79 NM -15.27 17.73 NM -15,21 17.75 NM -15.23 17.75 NM -15.23 17.75 NM -15.23 16.75 NM -14.23 16.97 NM -14.45 17.06 NM -14.54 17.10 NM -14.58 17.06 NM -14i54 16.94 NM -14.42 1103 NM -14.51 17.08 NM -14.56 17.24 NM -14.72 17.33 NM 14.81 17.51 NM -14.99 17.68 NM -15.16 17.82 NM -15.30 17,88 NM -15.36 17.89 NM -15.37 17.92 NM 15.40 17.98 NM -15.44 17.92 NM -15.40 18.11 NM -15.59 18.15 NM -15.63 18.13 NM -15.61 18.08 NM -15.56 18.14 NM -15.62 18.20 NM -15.68 18.16 NM -15.64 18.15 NM -15.63 18.08 NM -15.56 4839.97 4839.93 4839.88 4839.97 4840.03 4840.01 4840.01 484001 4841.01 4840.79 4840.70 4840.66 4840.70 4840.82 484013 4640.68 4840.52 4840.43 4840.25 4840.08 4839.94 4839.88 4839.87 4839.84 4839.80 4839.84 4839.65 4839.61 4839.53 4839.68 4839.62 483+9.68 4839.60 4839.61 4839.68 Well ID No. Date Top of Casing G.S. Reported Top Bottom ottom Casing a Screen height Elevation Interval Screen of Screen Elevation* (ft) (ft a ms i) Elevation Elevation (ft aural) (ft bgs) MW -4 9/25/2017 9/28/2017 10/3/2017 10/12/2017 10/12/2017 10/20/2017 10/24/2017 10/30/2017 11/1012017 11/13/2017 11/17/2017 11/2712017 11/29/2017 12/5/2017 12/8/2017 12/12/2017 12/1512017 12/19/2017 12/27/2017 MW5A 5/18/2016 8/11/2016 8/17/2016 8/25/2016 8/31/2016 9/7/2016 9/12/2016 9/20/2016 9/26/2016 10/4/2016 10/10/2016 10/17/2016 10/26/2016 11/1/2016 11/10/2016 4862.82 2.45 4860.37 5 20 4855.37 4840.37 Depth to Total Water Depth (ft below (ft below TOC) TOC) 18.09 NM 18.09 NM 18.03 NM 17.96 NM 17.91 NM 17.85 NM 17.90 NM 17.85 NM 17.78 NM 17.74 NM 17/2 NM 17.69 NM 17,69 NM 17.68 NM 17.63 NM 17.63 NM 17.60 NM 17.63 NM 17.58 NM 12.05 NM 8.78 26.6 8.69 26.6 8.65 26.6 8.78 NM 9.25 26.6 9.19 NM 9.66 26.5 9.99 NM 10.37 26.5 10.63 NM 10.84 26.6 11.10 NM 11.19 26.5 11.40 26.5 Depth to Water (ft bgs) Water Elevation (ft amyl) -15.57 -15.57 -15.51 -15.44 -15.89 -15.33 -15.38 -15.88 -15.26 - 15.22 -15.20 - 15.17 -15.17 -15.16 - 15.11 -15.11 - 15.08 - 15.11 -15.06 -9.60 -6.33 -6.24 -6.20 -6.33 - 6.80 -6.74 -7.21 7.54 -7.92 - 8.18 - 8.39 -8.65 -8.74 -8.95 4839.67 4839.67 4839.73 4839.80 4839.85 4839.91 4839.86 4839.91 4839.98 4840.02 4840.04 4840.07 4840.07 4840.08 4840.18 4840.13 4840.16 4840.13 4840.18 4850.77 4854.04 4854.13 4854.17 4854.04 4853.57 4853.63 4853.16 4852.83 4852.45 4852.19 4851.98 4851.72 4851.63 ■ 851.42 Well ID No. Date Top of Casing Elevation* (ft arnsi) Casing height (ft) Reported Gas. Screen Elevation Interval (ft amsl ) (ft bs) Top of Bottom Water Screen of Screen (ft below Elevation Elevation TOC) Depth to Total Depth (ft below TOC) Depth to Water (ft bgs) Water Elevation (ft amsl) MW -5A 11/16/2016 11/23/2016 11/30/2016 12/6/2016 1211212018 12/20/2016 12/28/2016 1/6/2017 111212017 1/18/2017 1/26/2017 1/31/2017 2/8/2017 2/15/2017 2/22/2017 311120/7 3/8/2017 3/1512017 3/22/2017 3/30/2017 4/5/2017 4/1112017 4/19/2017 4/26/2017 5/3/2017 5/12/2017 5/16/2017 5/24/2017 5/30/2017 61712017 6/19/2017 6/20/2017 6/23/2017 6/27/2017 613012017 11.49 NM -9.04 11.64 NM -9.19 11.74 26.5 -9.29 11.84 NM -9.39 11.90 26.6 -9.45 12.01 NM -9.56 12.10 NM -9.65 12,09 NM -9.64 1 211 NM -9.76 1127 NM -9,82 12.35 NM -9.90 12,34 NM -9.89 12.44 NM -9.99 12.46 NM -10.01 12.50 NM -10.05 12.59 NM -10.14 12.64 NM -10.19 12.68 NM -10.23 12.76 26.6 -10.31 12.79 NM -10.34 12.86 NM -10.41 12.90 26.5 -10.45 12.72 NM -10.27 12.64 NM -10.19 12.72 NM -10.27 12.83 NM -10.38 12.87 NM 10.42 10.80 NM -8.35 11.15 NM -8.70 1 t43 NM -8.98 10.56 NM -8.11 10,48 NM 8.03 10a64 NM -8.19 10.40 NM -7.95 10.40 NM -7.95 4851.33 4851.18 4851.08 4850.98 4850.92 4850.81 4850.72 4850.73 4860.61 4850.66 4850.47 4850.48 4850.38 4850.36 4850.32 4850.23 4850.18 4850.14 4850.06 4850.03 4849.96 4849.92 4850.10 4850.18 4850.10 4849.99 4849.95 4852.02 4851.67 4851.39 4852.26 4852.34 4852.18 4852.42 4852.42 Well ID No. Date Top of Casing Elevation* (ft amsl) Casing G.S. height Elevation (ft) (ft amyl) Reported Screen Interval (ft bgs) Top of Bottom Depth to Water Screen of Screen (ft below Elevation Elevation TOC) Total Depth (ft below TOC) Depth to Water (ft bgs) Water Elevation (ft amsl) MW -5A 7/5/2017 7/11/2017 7/14/2017 7/19/2017 7/26/2017 7/31/2017 8/312017 8/7/2017 8110/2017 8/11/2017 8/15/2017 8/21/2017 8/24/2017 8/28/2017 9/1/2017 9/6/2017 9/11/2017 9/14/2017 9/18/2017 9/21/2017 9/25/2017 9/28/2017 10/3/2017 10/12/2017 10/16/2017 10/20/2017 10/24/2017 10/30/2017 11/10/2017 11/13/2017 11/17/2017 11/27/2017 11/29/2017 12/5/2017 12/8/2017 10.44 NM 10.25 NM 10.18 NM 10.49 NM 10.49 NM 9.69 NM 9.64 NM 9.69 NM 9.79 NM 9.76 NM 9.77 NM 10.15 NM 10.20 NM 10.14 NM 9.69 NM 9.54 NM 919 NM 9.11 NM 9.31 NM 9.50 NM 9.81 NM 9.98 NM 10.23 NM 10.53 NM 10.67 NM 1077 NM 10.89 NM 11.06 NM 11.25 NM 11.29 NM 11.38 NM 11.47 NM 11.52 NM 11.63 NM 11.65 5 NM - 7.99 -7.80 - 7.73 - 8.04 -8.04 - 7.24 -7.19 -7.24 - 7.34 - 7.31 -7.32 - 7.70 -7.75 -7.69 -7.24 -7.09 - 6.74 -6.66 -6.86 - 7.05 - 7.36 -7.53 - 7.78 - 8.08 ▪ 8,22 - 8.32 - 8.44 - 8.61 -8.80 -8.84 -8.93 - 9.02 -9.07 - 918 -9.20 4852.38 4852.57 4852.64 4852.33 4852.33 4853.13 4853.18 485318 4853.03 4853.06 4858.05 4852.67 4852.62 4852.68 4853.13 4853.28 4853.63 4853.71 4853.51 4853.32 4853.01 4852.84 4852.59 4852.29 4852.15 4852,05 4851.93 4851.76 4851.57 8 4851.53 4851.44 4851.35 4851.30 4851.19 4851.17 Well ID No. Date Top of Casing Elevation* (ft amsl) Casing G.S. height Elevation (ft) (ft amsl) Reported Screen Interval (ft bgs) Depth to Top of Bottom Water Screen of Screen ft below r Elevation Elevation TO C) Total Depth (ft below TOC) Depth to Water Water Elevation (ft bgs) (ft amsl) MW -5A 12112/2017 12/15/2017 12/19/2017 12127/2017 MW -6 3/22/2017 4855.90 3/24/2017 3/30/2017 4/5/2017 4/11/2017 4/19/2017 4/26/2017 5/3/2017 5/12/2017 5/16/2017 5/24/2017 5/30/2017 6/7/2017 6/19/2017 6/23/2017 6/2712017 6/30/2017 7/5/2017 7/11/2017 7/1412017 7/19/2017 7/26/2017 7/3112017 8/3/2017 8/7/2017 811012017 8/11/2017 8115/2017 8/21/2017 8/24/2017 3.08 4852.82 9 - 19 11.69 NM -9.24 11.78 NM -9.28 11.80 NM -9.35 11.85 NM -9.40 4843.82 4833.82 12.11 21.7 -9.03 12.15 21.7 -9.07 1214 21.6 -9.06 12.18 21.5 -9.10 12.26 21.8 -9.18 12.27 21.8 -9.19 12.17 21.8 -9.09 1215 21.8 -9.07 12.14 21.8 -9.06 12.19 21.8 -9.11 10/7 21.8 -7.69 1t03 21.8 -7.95 11.23 21.8 -8.15 1'1.40 21.8 -8.32 11.16 21.8 -8.08 11.04 21.8 -7.96 10.93 21.8 -7.85 11.00 218 -7.92 10/7 21.8 -7.69 10.84 NM -7.76 10.98 NM -7.90 10.97 NM -7.89 11.17 NM -8.09 11.01 NM -7.98 10.87 NM -7.79 10.77 NM -7.69 10.72 NM -7.64 10.76 NM -7.68 11.07 NM -7.99 10.89 NM -7.81 4851.13 4851.09 4851.02 4850.97 484179 4843.75 4843.76 4843.72 4843.64 4843.63 4843.73 4843.75 4843.76 4843.71 4845.13 4844.87 4844.67 4844.50 484414 4844.85 4844.97 4844.90 4845.13 4845.06 4844.92 4844.93 4844.73 4844.89 4845.03 4845.13 4845.18 4845.14 4844.83 4845.01 Well ID No. Date Top of Casing Elevation* (ft a ma l) Casing G.S.Reported Top of Screen height Elevation Screen Interval (ft) (ft ama l) Elevation (ft bgs) Bottom of of Screen Water Elevation TOC) eft below Total Depth (ft below TOC) Depth to Water Water Elevation (ft bgs) (ft amsl) MW -6 8/28/2017 9/1/2017 9/6/2017 9/11/2017 9114/2017 9118/2017 9/21/2017 9/25/2017 9/28/2017 10/3/2017 10/12/2017 10/16/2017 10/20/2017 10/2412017 10/30/2017 11/10/2017 11/13/2017 11/17/2017 11/27/2017 11/29/2017 1215/2017 12/8/2017 12/12/2017 12/15/2017 12/19/2017 12/27/2017 TPZ-3 3/22/2017 4859.69 3/24/2017 3/30/2017 4/5/2017 4/11/2017 4/19/2017 4/26/2017 5/3/2017 2.75 4856.94 10 - 15 4846.94 4841.94 10.66 NM -7.58 10.50 NM -7.42 10.75 NM -7.67 11.04 NM -7.96 11.13 NM -8.05 11.19 NM -8.11 11.23 NM -8.15 11.33 NM -8.25 11.34 NM -8.26 11.41 NM -8.33 11.41 NM -8.33 11.47 NM -8.39 11.47 NM -8.39 11.55 NM -8.47 11.66 NM -8.58 11.68 NM -8.60 11.70 NM -8.62 11.69 NM -8.81 11.74 NM -8.66 11.78 NM -8.70 11.84 NM -8.78 11.83 NM -8.75 11.79 NM -8.71 11.80 NM -8.72 11.87 NM -8.79 11.88 Nm -8.80 12.20 17.5 -9.45 12.21 17.5 -9.46 12.19 17.0 -9.44 12.26 18.4 -9.51 12.32 17.5 -9.57 12.25 17.5 -9.50 12.08 17.5 -9.33 12.13 17.5 -9.38 4845.24 4845.49 4845.18 4844.86 4844.77 4844.71 4844.87 4844.57 4844.88 4844.9 4844.49 4844.43 4844.43 4844.35 4844.24 4844.22 4844.20 4844.21 4844.16 4844.12 4844.06 4844.07 4844.11 4844.10 4844.03 4844.02 4847.49 4847.48 4847.50 4847.43 4847.37 4847.44 4847.61 4847.88 Well ID Noe Date Top of Casing Elevation* (ft amsl) Casing C.S. Reported Top of Bottom so Screen height Elevation Interval Screen of Screen (ft) (ft amsl) ft Elevation Elevation TPZ-3 5/12/2017 5/16/2017 5/24/2017 5/30/2017 6/7/2017 6/19/2017 6/20/2017 6/23/2017 6/27/2017 6130/2017 7/5/2017 7/11/2017 7/14/2017 7/19/2017 7/26/2017 7/31/2017 8/3/2017 8/7/2017 8/10/2017 8/11/2017 8/15/2017 8/21/2017 8/24/2017 8/28/2017 9/1/2017 9/6/2017 9/ 11 /2O17 9/14/2017 9/18/2017 9/21/2017 9/25/2017 9/28/2017 10/3/2017 10/12/2017 10/16/2017 Depth to Water (ft below TOC) 12.19 12.23 11.14 11.01 11.13 10.97 10.90 10.78 10.60 10.59 10.57 10.48 10.45 10.54 10.61 10.50 10.45 10.36 10.32 10.32 10.34 10.59 10.61 10.57 10.39 10.27 10.30 10.22 10.20 10.20 10.35 10.42 10.59 10.74 10.84 Total Depth (ft below TOC) 17.5 17.5 17.5 17.5 17.5 17.5 17.5 17.5 17.5 17.5 173 17.5 17.5 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM Depth to Water (ft bgs) Water Elevation (ft amyl) - 9.44 - 9.48 ▪ 8.39 - 8.26 - 8.38 - 8.22 - 8.15 -8.03 - 7.85 -7.84 4.82 - 7.73 - 7.70 -7.79 -7.86 -7.75 -7.70 - 7.61 -7.57 -7.57 -7.59 -7.84 -7.86 -7.82 -7 .64 - 7.5.E -7.55 - 7.47 -7.45 -7.45 -7.60 -7.67 -7.84 -7.99 -8.09 4847.50 4847.46 4848.55 4848.68 4848.56 4848.72 4848.79 4848.91 4849.09 4849.10 4849.12 4849.21 4849.24 4849.15 4849.08 4849.19 4849.24 4849.33 4849.37 4849.37 4849.35 4849.10 4849.08 4849.12 4849.30 4849.42 4849.39 4849.47 4849.49 4849.49 4849.34 4849.27 4849.10 4848.95 4848.85 Well ID NO. Date Top of Casing Elevation* (ft amsl) Casing G.S. Reported Top of Screen height Elevation Interval Screen (ft) (ft amsl) ft b s Elevation Bottom Depth to of Screen Water Elevation (ft below TOC) Total Depth (ft below TOC) Depth to Water Water Elevation (ft bgs) (ft arnsl) TPZ-3 10120120/7 1812412017 10/30/2017 11/10/2017 11/13/2017 11/17/2017 11/27/2017 11/29/2017 12/5/2017 12/8/2017 12/12/2017 12/15/2017 12/19/2017 12/27/2017 10,87 11.00 11.10 11.19 11.23 11,24 11.33 11.37 11.44 11.45 11.45 11.47 11.54 11.59 NM NM NM NM NM NM NM NM NM NM NM NM NM NM -812 -8.25 -8.35 -8.44 -8.48 - 8.49 - 8.58 -8.62 -8.69 -8.70 -8.70 -8.72 -8.79 -8.84 4€48.82 4848.69 4848.59 4848.50 4848.48 4848.4► 4848.36 4848,32 4848.25 4848.24 4848.24 4848.22 4848.15 4848.10 Appendix B Laboratory Analytical Report ^� Colorado Analytical LABORATORIES, [NC Report To: Chris Skelton Company:A-1 Organics 16350 WCR 76 Eaton CO 80615 Analytical Results TASK NO: 171130009 09 Bill To: Chris Skelton Company: A-1 Organics 16350 WCR 76 Eaton CO 80615 Task No.: 171130009 Client PO: Client Project: Eaton Date Received: 11130117 Date Reported: 12/6/17 Matrix: Water - Ground Customer Sample ID G -MW -5A Sample DatelTime: 11/29/17 11.05 AM Lab Number: 171130009-01 Test Result Method AAL. Date Analyzed Analyzed By Arrimonia Nitrogen Bicarbonate Carbonate Chloride Nitrate Nitrogen Nitrite Nitrogen pH Specific Conductance Sulfate Total Alkalinity Total Organic Carbon Total Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper < 0.03 cnglL 415.0 mg/L as CaCO3 < 0.1 mgiL as CaCO3 42.09 mg/L 11.43 mg/L < 0.03 mg/L 7.04 units 2710 umhos/cm 25c 1471.20 mg/L 415.0 mg/L as CaCO3 6.8 mg/L Abbreviations/ References: ML = Minimum Level = LRL = PL mot = Milligrams Per Liter or PPM ug/'L ; Micrograms Per Liter or PPB mpn/ O ads = Most Probable Number index, 100 mis Date Analyzed = Date Test Completed < 0.0012 mg/L 0.0011 mg/L 0.0147 mg/L < 0,0001 mg!L < 0.0001 mg/L 256.0 mglL < 0.0018 mg/L < 0.0002 mg/L 0,0020 mg/L SM 4500-NH3-G SM 2320-B SM 2320-B EPA 300.0 EPA 300.0 EPA 300.0 SM 4500 -H -B EPA 120.1 EPA 300.0 SM 2320-B SM 5310-C EPA 200.8 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200 7 EPA 200.8 EPA 200.8 EPA 200.8 0.03 mg/L 0.1 mg/L as CaCO3 0 1 mg/L as CaCO3 0.01 mgiL 0.05 mg/L 0.03 mg/L 0.01 units 5 umhos/cm @ 25c 0.01 mg/L 0.1 mg/L as CaCO3 0.5 mg/L 0.0012 rng/L 0.0006 mg/L 0.0007 mg/L 0.0001 mg/L 0.0001 mg/L 01 mg/L 0.001 mg/L 0 0002 mg/L 0.0008 mg/L 12/5/17 12/4/17 12/4/17 11/30/17 11/30/17 11/30/17 11/30/17 11/30/17 11/30117 12/4/17 12/1117 1211/17 12/1/17 12/1117 12/1/17 12/1/17 12/4/17 12/1/17 12/1/17 12/1/17 MBN VDB VDB SEA SEA SEA MBN MBN SEA VDB ISG DBM DBM DBM DBM DBM MBN DBM DBM DBM DATA APPROVED FOR RELEASE BY 240 South Main Street ye Brighton, CO 80601-0507 / 303-659-2313 Mailing Address: P.O. Box 507 / Brighton, CO 80601-0507 / Fax: 303-659-2315 Page 1 of 9 171i30009 1/8 iltS1/4) Colorado ' � Analytical LABORATORIES, INC Report To: Chris Skelton Company: A-1 Organics 16350 WCR 76 Eaton CO 80615 Analytical Results TASK NO: 171130009 Bill To:Chris Skelton Company: A-1 Organics 16350 WCR 76 Eaton CO 80615 Task Now: 1711300 09 Client PO: Client Project: Eaton Date Received: 11/30/17 Date Reported: 1216/17 Matrix: Water - Ground Customer Sample ID GW-Mk/V-5A Sample DatelTime: 11129/17 11:05 AM Lab Number: 171130009-01 Test Result I ML Date Analyzed Analyzed By Method Total Lead Magnesium Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Abbreviations/ References: ML Mintrnum Level = LRL = RL mg/L = Milligrams Per Liter or PPM ug/L = Micrograms Per Liter or PPB mpn/100 rigs = Most Prababte Number Index/ 100 rills Date Analyzed = Date Test Completed < 0.0001 mg!L 164.20 mg/L 0.0009 mg/L 4.+4 mg/L 0.0056 mglL < 0.0001 mg/L 178.8 mg/L < 0.0002 mg/L 0.005 mg/L c 0.001 mg/L EPA 200.8 EPA 200.7 EPA 200.8 EPA 200.7 EPA 200,8 EPA 200.8 EPA 200/ EPA 200.8 EPA 200.8 EPA 200.8 0.0001 mg/L 0.02 mg/L 0.0009 mg1L 0.1 mg/L 0.0008 mg/L 0 0001 mg&L 01 mg/L 0.0002 mg/L 0.001 mg/L 0.001 mg/L 12/1117 12/4/17 12/1/17 12/4/17 12/1/17 12/1117 12/4/17 12/1/17 12/1/17 12/1/17 DBM MBN DBM MBN DBM DBM MBN DBM DBM DBM DATA APPROVED FOR RELEASE BY 240 South Main Street ! Brighton, CO 80601-0507 / 303-659-2313 Mailing Address: P.O. Box 507 l Brighton, CO 80601-0507 / Fax: 303-659-2315 Page 2 of 9 171130009 2/8 ^� Colorado Analytical S LABORATORIES, INC Report To: Chris Skelton Company:A-1 Organics 16350 WCR 76 Eaton CO 80615 Analytical Results TASK NO: 171130009 Bill To: Chris Skelton Company: A-1 Organics 16350 WCR 76 Eaton CO 80615 Task No.: 171130009 Client PO: Client Project: Eaton Date Received: 11/30/17 Date Reported: 12/6/17 Matrix: Water - Ground Customer Sample ID G -MW -3 Sample Date/Time: 11/29/17 12:45 PM Lab Number: 171130009-02 Result Method j ML Data Analyzed Analyzed By Ammonia Nitrogen Bicarbonate Carbonate Chloride Nitrate Nitrogen Nitrite Nitrogen pH Specific Conductance Sulfate Total Alkalinity Total Organic Carbon Total Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper < 0.03 mg/L 414.0 mg/L. as CaCO3 < 0.1 mg/L as CaCO3 49.29 mglL 10.45 mglL < 0.03 mg1L 7.05 units 2773 urn hoslcm @ 25c 1513.09 mg/L 41449 mglL as CaCO3 6.3 mg/L Abbreviations/ References: ML = Minimum Level = LRL = R'L n1Z = Milligrams Per Liter or PPM (A i1L = Micrograms Per Liter or PPB mpryl 00 mis = Most Probable Number Index/ WO oils Date Analyzed = Date Test Completed < 0.0012 mg/L 0,0O11 mg/L O.0r150 mg/L < 0.0001 mg/L < 0,0001 mglL 276.9 mg/L < 0.0015 mglL c 0.0002 mg/L 0.0017 mg/L SM 4500-N H3 -G SM 2320-B SM 2320-B EPA 300.0 EPA 300.0 EPA 3000 SM 4500 -H -B EPA 120.1 EPA 300.0 SM 2320-B SM 5310-C EPA 200.6 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200 7 EPA 200.8 EPA 200.8 EPA 200.8 0.03 mg/L 0,1 mg/L as CaCO3 0.1 mg/L as CaCO3 0.01 rng/L 0,05 mg/L 0,03 mg/L 0.01 units 5 umhos/cm cp 25c 0,01 mg/L 0.1 mg/L as CaCO3 0.5 mg/L 0,0012 mg/L 0.0000 mg/L 0.0007 mg/L. 0 0001 mg/L 0.0001 mg/L 0,1 mg/L 0,0015 mg/1 0.0002 mg/ 0_0008 mg/L 12/5/17 12/4/17 12/4/17 11130/17 11/30/17 11/30/17 11/30117 11/30/17 11/30/17 12/4/17 12/1/17 12/1/17 12/1/17 12/1/17 12/1/17 12/1/17 12/4/17 12/1/17 12/1/17 12/1/17 DATA APPROVED FOR RELEASE BY MBN VDB VDB SEA SEA SEA MBN MBN SEA VDB ISG DBM DBM DBI` DBM DBM MBN DBM DBM DBM s r 240 South Maui Street / Brighton, CO 80601-0507 / 303-659-2313 Mailing Address: P.O. Box 507 / Brighton, CO 80601-0507 / Fax: 303-6594315 Page 3 of 9 171130009 3/8 Irpto) Colorado • ace, Analytical LABORATORIES, INC Report To: Chris Skelton Company:A-1 Organics 16 350 WCR 76 Eaton CO 80615 Analytical Results TASK NO: 171130009 Bill To:Chris Skelton Company: A-1 Organics 16350 WCR 76 Eaton CO 80615 Task No.: 171130009 Client PO: Client Project: Eaton Date Received: 11/30/17 Date Reported: 12/6/17 Matrix: Water - Ground Customer Sample ID OW -MW -S Sample Date/Time: 11/291171 12:48 PM Lab Number 171130009-02 [rest - - -1 moult Method I ML Date Analyzed Analyzed By Total Lead Magnesium Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Abbreviations/ References: ML = Minimum Level = LRL = RL trign_ Milligrams Per Lifer or PPM ugiL = Micrograms Per Liter or PPB mpn/1 00 mis = Most Probable Number index' 100 mis Date Analyzed = Date Test Completed < 0.0001 182.20 0.0011 4.2 0,0071 < 0.0001 174.8 C 0.0002 0,+008 < 0.001 mg1L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg1L EPA 200,8 EPA 200.7 EPA 200.8 EPA 200.7 EPA 200.8 EPA 200.8 EPA 200.7 EPA 200.8 EPA 200.8 EPA 200.8 0.0001 mg/L 0.02 mg/L 0.0009 mglL 0.1 mg/L 0.0008 mg/L 0.0001 mglL 0.1 mg/L 0.0002 mg/L 0.001 mg/L 0.001 mg/L 12/1/17 12/4/17 12/1/17 1214/17 12/1/17 12/1/17 12/4117 12/1/17 12/1/17 12/1/17 DBM MBN DBM MON DBM DBM MBN DBM DBM DBM Gill DATA APPROVED FOR RELEASE BY 240 South Main Street / Brighton, CO 80601-0507 / 303-659-2313 Mailing Address: P.O. Box 507 / Brighton, CO80601-0507 / Fax: 303-659-2315 Page 4 of 9 171130009 4/8 Colorado • 1.*7\- Analytical LABORATORIES, INC. Report To: Chris Skelton Company:A-1 Organics 16350 WCR 76 Eaton CO 80615 Analytical Results TASK NO: 171130009 Bill To: Chris Skelton Company: A 1 Organics 16350 WCR 76 Eaton CO 80615 Task No.: 171130009 Client PO: Client Project: Eaton Date Received: 11/30/17 Date Reported: 12/6/17 Matrix: Water - Ground Customer Sample ID GW-MW-1 Sample Date/Time: 11/29117 1:08 PM Lab Number: 171130009-03 set Ammonia Nitrogen Bicarbonate Carbonate Chloride Nitrate Nitrogen Nitrite Nitrogen pH Specific Conductance Sulfate Total Alkalinity Total Organic Carbon Total Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper i Result < 0.03 mg/L. 427.2 mg/L as CaCO3 c 0.1 mg/L as CaCO3 108.06 mg/L 14.53 mg/L < 0.03 mg/L 5.58 milts 3127 umhoslcm 25c 1410.51 mglL 42782 mglL as CaCO3 5.9 mglL Abbreviation References: ML = Minimum Level = LRL = 'L mg/L = 44Iffigrams Per Liter or PPM tugiL = Micrograms Per Liter or PPB mpni100 nis = Most Probable Number Index/ 100 mIs Date Analyzed = Date Test Completed c 0.0012 mg/L 0.0012 mg/L 0.0375 mg/L 0.0002 mg/L < 0.0001 mg/L 248.3 mg/L 0.0734 mg/L 0.0014 mg&L 0,0033 mg/L i Method SM 4500-N H3 -G SM 2320-B SM 2320-B EPA 300.0 EPA 300.0 EPA 300.0 SM 4500 -H -B EPA 1201 EPA 300,0 SM 2320-B SM 5310-C EPA 200.8 EPA 200:8 EPA 200 8 EPA 200.8 EPA 200.8 EPA 200.7 EPA 200.8 EPA 200 8 EPA 200.0 ML 0 03 mg/L 0.1 mg/L as CaCO3 1 mglL as CaCO3 0.01 mg/L 0.05 mg/L 0 03 mg/L 0.01 units 5 umhos/cm 25c 0 01 rng/L 0.1 mg/L as CaCO3 0.5 mg/L 0 0012 mg/L 0 0008 mg/L 0.0007 mg/L 0.0001 mg/L 0.0001 mg/L 01 mg/L 0,0015 mg/L 0.0002 mg/L 0 0008 mg/L DEM Analyzed Analyzed By DATA APPROVED FOR RELEASE BY r 12/5/17 12/4/17 1214117 11/30/17 11/30/17 11/30117 11/30/17 11130/17 11/30/17 12/4/17 12/1/17 12/1/17 12/1/17 12/1/17 12/1117 12/1117 12/4/17 12/1/17 12/1/17 12/1/17 T 240 South Main Street / Brighton, CO 80601-0507 / 303-659-2313 Mailing Address: P.O. Box 507 1 Brighton, CO 80601-0507 / Fax: 303-659-2315 Page 5 of 9 MBN VDB VDB SEA SEA SEA MBN MBN SEA VDB I B DBM DBM DBM DBM DBM MBN DBM DBM DBM 171130009 5/8 rips,$) Colorado Analytical LABORATORIES, INC Report To: Chris Skelton Company:A-1 Organics 16350 WCR 76 Eaton CO 60615 Analytical Results ■ A K NO: 171130009 Bill To: Chris Skelton Company: A-1 Organics 16 350 WCR 76 Eaton CO 60615 Customer Sample ID G -MW -1 Sample Date/Time: 11/29/17 1:08 PM Lab Number: 171130009-03 Tit Result Method ML 1 Date Analyzed 1 ,Aunalyzet) By Total Lead Magnesium Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Abbreviation References: ML = Minimum Level = LRL rier AL rng = Milligrams Per Liter or PPM wilt. = Micrograms Per Liter or PPB mpn/100 mis = Most Probable Number index' 100 mils Date Analyzed = Date Test Completed 0.0022 mg&L 196.20 mg/L 0.0034 mg/L 3.3 mg/L 0.0054 mg/L < 0.0001 mg/L 211.3 mglL < 0.0002 mg/L. 0.007 mg/L 0.014 mg/L EPA 200.8 EPA 200,7 EPA 200 8 EPA 200.7 EPA 200.8 EPA 200.8 EPA 200.7 EPA 200.8 EPA 200.8 EPA 200.8 0.0001 mg/L 0.02 rng/L 0.0009 mg/L 0.1 mg/L 0.0008 mg/L 0 9001 mg/L 01 mg/L 0.0002 m g/L 0.001 mg/L 0.001 mg/L 1211/17 12/4117 12/1/17 12/4/17 1211/17 12/1/17 1214/17 12/1/17 1211/17 12/1/17 DATA APPROVED FOR RELEASE BY 240 South Main Street / Brighton, CO 80601-0507 / 303-659-2313 Mailing Address: F.O. Box 507 / Brighton, CO 80601-0507 / Fax: 303-659-2315 Page 6 of 9 DBM MBN DBM MBN DBM DBM MBN DBM DBM DBM 171/30009 6/8 It\ Colorado Analytical LABORATORIES INC. Report To: Chris Skelton Company:A-1 Organics 16350 WCR 76 Eaton CO 80615 Analytical Results TASK NO: 171130009 Bill To: Chris Skelton Company:41 Organics 16350 WCR 76 Eaton CO 80615 Task No.: 171130009 Client FAO: Client Project: Eaton Date Received: 11/30/17 Date Reported: 12/6/17 Matrix: Water - Ground Customer Sample ID GW-MW-4 Sample Date/Time: 11/29117 1:37 PM Lab Number: 171130009-04 _ Result [ Method ML Date Arialyzed ! Analyzed By test Ammonia Nitrogen Bicarbonate Carbonate Chloride Nitrate Nitrogen Nitrite Nitrogen pH Specific Cond uctance Sulfate Total Alkalinity Total Organic Carbon Total Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper 0.03 mg/L 471.3 mg1L as CaCO3 < 0.1 mg/L as CaCO3 117.15 mg!L 11.97 mg/L 0.29 mg/L 7.06 units 3266 urnhos/cm a 26c 1477.62 mg/L 471.3 mg/L as CaCO3 6.7 mg/L Abbreviations/ References: ML = Minimum Level = LRL = P'L mg/L = Milligrams Per Liter or PPM t,agiL = Micrograms Per Liter or P'P'S mpn/100 ruts t Most P'ri:tarb/a Number index/ 100 m!s Date Analyzed = Date Test Completed < 0.0012 mg/L 040015 mg/L 0.0279 cmgIL 0.0002 mglL < 0.0001 mg/L 2822 mg!L 0.0018 mg/L 0.00'19 mg/L 0.0032 mg/L SM 4500 -NI -13-G SM 2320-B SM 2320-B EPA 300.0 EPA 300.0 EPA 300 SM 4500 -H -B EPA 120.1 EPA 300.0 SM 2320-B SM 5310-C EPA 200.8 EPA 200.3 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200.7 EPA 2008 EPA 200 3 EPA 200.B 0.03 rngf L 0.1 mg/L as CaCO3 0.1 mg/L as CaCO3 0.01 mg/L 0.05 mg/L 0.03 mg/L 0.01 units 5 um hos/cm @ 25c 0.01 mg/L 0 1 mg/L as CaCO3 0.5 mg/L 0.0012 mg/L 0 0006 mg/L 0.0007 mg/L 0.0001 mg/L 0.0001 mg/L 01 mg/L 0,0015 mg/L 0.0002 m g/L 0.0008 mg/L 12/5/17 12/4/17 12/4117 11/30/17 11130/17 11/30/17 11/30/17 11 /30/17 11/30/17 12/4/17 12/1/17 12/1117 12/1/17 12/1/17 12/1/17 12/1/17 12/4/17 12/1/17 12/1 /17 12/1/17 MBN VDB VDB SEA SEA SEA MBN MBN SEA VDB ISG DBM DBM DBM DBM DBM MBN DBM DBM DBM DATA APPROVED FOR RELEASE BY 240 South Main Street / Brighton, CO 80601-0507 / 303-659-2313 Mailing Address: P.O. Box 507 / Brighton, CO80601-0507 / Fax: 303-659-2315 Page 7of9 171130009 7/8 iri)dps., Colorado • Analytical LABORATORIES, INC Report To:Chris Skelton Company:A-1 Organics 16350 WCR 76 Eaton CO 80615 Analytical Results TASK NO: 17113000 Bill To: Chris Skelton Company:A-1 Organics 16350 WCR 76 Eaton CO 80615 Task No.: 171130009 Client P0: Client Project: Eaton Date Received: 11/30/17 Date Reported: 12/6/17 Matrix: Water - Ground Customer Sample ID GW-MW-4 Sample Date/Time: 11/29117 1:37 PM Lab Number: 171130000-04 I Result Method J ML Date Analyzed Analyzed By Test Total Lead Magnesium Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Abbreviation References: Mi. = Minimum Level = LRL = RL mg'L = Milligrams Per Liter or PPM ugit = Micrograms Per Liter or PPS mpnr+l oO ml. = Most Probable Number index/ 100 miss Date Analyzed = Date Test Completed 0.0027 mglL. 204.60 mg!L 00038 mglL 3.4 mglL 0.0042 mglL < 0.0001 mglL 236.5 mg/L < 0.0002 mglL 0.006 mg/L 0.009 mg/L EPA 200.8 EPA 200 7 EPA 200.8 EPA 200.7 EPA 2018 EPA 200.8 EPA 200.7 EPA 200 , 8 EPA 200.8 EPA 200.8 0.0001 mg/ 0.02 mg/L 0.0009 m9/L 0.1 mg/L 0,0008 rng/L a 0001 mg/L © 1 mg/L 0.0002 m g&L 0.+001 mg/L 0.001 mg/L 12/1/17 12/4/17 12/1/17 12/4117 12/1/17 12/1/17 12/4/17 12/1/17 1211117 12/1/17 DATA APPROVED FOR RELEASE BY DBM MBN DBM MBN DBM DBM MBN DBM DBM DBM 240 South Main Street / Brighton, CO 80601-0507 / 303-4659-2313 Mailing Address: P.O. Box 507 / Brighton, CO 80601-0507 / Fax: 303-659-2315 Page 8 of 9 171130009 8/B 6 6 abed Chain of Custody Form Is w +L 11 cc 1.= cot Ein 2 mg op 4 8 4 sr e thi z E Task Numb(Cam. Task No_ r Ihuit 1■"' Phone: 303-659-2313 Fax: 303-659-2315 2 ww w.. cola ratio la b. eo m ate(Lab Use 0 ■A Bill To information Of different from report ci CC a I.� S O it < ... •t u E 4.► tu l� - 7 ii I Q fa ar tot 4 0 Pt U 4fC - C Phone:970-454-3492 r C Ois S�•y I.Y @,1/2,m 0 IM..A tat EA 1.6 LLJ iQ z P C 4.41 C U +C li.► at 6 4: Ii!�M 9-4• w■ Ill 14 et4 < ..C i4 an U C ix e .it— Z CI - Pi, 7 0 = "-a °" CA 1 06 • ' i iz In 0 4 az Cg U U < _4 State CO Zi p8061S rat cn Lrt Is I I �•t �o C U a It Lei I L) II I I El ei E II II II Nit i 4 IL ill O at ■ TJ 1 LiEJu■i■ ■ 11. ■ ■ ■ ■ ■ ■ ■ ■ ■ ■lie Received By: I 5., D]DEflDU_lid uzA±V `S ■■ ■■■ � •.I M� DA iii lissegd 4nj 4°3 4.O i6.. Li ri `P3 'ait'il i`s Y `ciS , Dfri M' 0 ■ 0 O Q o -1 is u �p Relinquished 7Date/Time: I DOI`D3 ,'i Di■ ■ ■ ■ ■ ■ 04 D rid `VOS `ID `EO H ' DA■ ■ ■ ■ Q goo t3° Lt.ti` (I FA LI !r OA ■ ■ ■ ■ ■ gDvaIu Sr v e flits ' Wa if i N a - (Awn auo gaup) JoIspr quip I S s'.Iaursiuop jo ' ON. b' mot'i •".I R iii • l/.us . Gi3f MW -SR PI Q 4 tiii co At Instr'uetions:P/ease entail results to chrisskelon@a#organics.com. ' , t Tissue l IBC II 11 r y`coiIt Vii, C a• 1 -CI ( a t, '' 1�411.4 4,q LIB 1. y a -° ." r ., .v, V 111 f I eIt } R11 1 ❑ ❑ O I., 1 aril Iu+d ge om post ..4 rah Pile:. ID • �••.. 4 a SO E lieftr •: rasa a ap r ,, , N N Pk pit Ilji N 00 *I Waste Water Ground Water Surface ater 0 Ip.. I WI r- z ..1 r- ,..., ..., ,_.. r-. rte` ea a t� at ti Colorado Analytical LABORATORIES, INC Report To: Chris Skelton Company:A-1 A► -1 Organics 16350 WCR 76 Eaton CO 80615 Analytical Results TASK NO: 171130022 Bill To: Chris Skelton Company: A-1 Organics 16350 WCR 76 Eaton CO 80615 Task No.: 171130022 Client PO: Client Project: Eaton Date Received: 11/30/17 Date Reported: 12/6/17 Matrix: Water - Ground Customer Sample ID GW-MW-0 Sample Date Time: 11/29/17 2:00 PM Lab Number 171130022-01 treat Result i Method I ML Date Analyzed ! Analyzed By Ammonia Nitrogen Bicarbonate Carbonate Chloride Nitrate Nitrogen Nitrite Nitrogen pH Specific Conductance Sulfate Total Alkalinity Total Organic Carbon Total Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper < 0.03 mg/L 456.9 mglL as CaCO3 < 0.1 mgJL as CaCO3 80.95 mg/L 11.68 mg/L < 0.03 mglL 7.01 units 3072 umhas/cm c 25c 1359.91 mg/L 456.9 mg/L as CaCO3 6.7 mgfL Abbreviation References: ML = Miriimurn Level = LPL = RL mg4- = Milligrams Per Liter or PPM ugiL = Micrograms Per Liter or PPB mprn/100 mis = Most Probable Number !ride*' 100 !Pis Date Analyzed = Date Test Completed ( 0.0012 0.0009 0.0127 < 0.0001 C 0.0001 293.9 < 0.0015 0.0002 0.0014 mg/L mgJL mgJL mg/L mgJL mg/L mgJL mglL mg/L SM 4500-NH3-G SM 2320-B SM 2320-B EPA 300 0 EPA 300 0 EPA 300.0 SM 4500 -H -B EPA 120.1 EPA 300 0 SM 2320-B SM 5310-C EPA 200 3 EPA 200 8 EPA 200.3 EPA 200.8 EPA 200.8 EPA 200/ EPA 200.3 EPA 200.8 EPA 200 8 0 03 mg/L 0 1 mg/L as CaCO3 0 1 mg/L as CaCO3 0 01 mg/L 0 05 mg/L 0.03 mglL 0.01 units 5 umhaslcm 25c 0.01 mg/L 0 1 mglL as CaCO3 0 5 mg/L 0.0012 mg/L 0.0006 mg/L 0.0007 mg/L 0 0001 mg/L 0 0001 mg/L 0.1 mg/L 0.0015 mg/L 0.0002 mg/L 0 0008 mg/L 12/5/17 12/4/17 12/4/17 11130/17 11/30/17 11/30/17 11/30/17 11/30/17 11130/17 1214/17 12/1117 12/1/17 1211117 1211117 1211/17 12/1/17 1214/17 12/1/17 12/1/17 12/1/17 MBN VDB VDB SEA SEA SEA MBN MBN SEA VDB ISG DBM DBM DBM DBM DBM MBN DBM DBM DBM DATA APPROVED FOR RELEASE BY 240 South Main Street / Brighton, CO 80601-0507 / 303-659-2313 Mailing Address: P.O. Box 507 / Brighton, CO 80601-0507 / Fax: 303-659-2315 Page lof3 171130022 1/2 illtS) Colorado • SA Analytical LABORATORIES, INC Report To: Chris Skelton Company:A-1 Organics 16350 WCR 76 Eaton CO 80615 Analytical Results TASK NO: 171130022 Bill To: Chris Skelton Company: A-1 Organics 16350 WCR 76 Eaton CO 80615 Task No.: 171130022 Client PO: Client Project: Eaton Date Received: 11/30/17 Date Reported: 1216117 Matrix: Water - Ground Customer Sample ID GW-MW-6 Sample Date/Time: 11/29117 2:00 PM Lab Number: 171130022-01 IratResult Method ML Date Analyzed j Analyzed By Total Lead Magnesium Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Abbreviations/ References: ML = Minimum Level =LRL = RL mgriL = Milligrams Per Liter or PPM ugtl = Micrograms Per Liter or PPB mpn1100 rats = Most Probable Number Index,' 100 mis Date Analyzed = Date Test Completed < 0.0001 mg/L 198.50 mg/L 0.0014 mg/L 3.9 mg/L 0.0067 mg/L 0.0001 mg/L 211,6 mg/L c 0.0002 mg/L 0.003 rng1L < 0.001 mg/L EPA 200.8 EPA 200.7 EPA 200,8 EPA 2007 EPA 200.8 EPA 200,8 EPA 200.7 EPA 200.8 EPA 200.8 EPA 200.8 0.0001 mg/L 0.02 mg/L 0.0009 mg/L 0.1 mg/L 0.0008 mg/L 0.0001 mg/'L 0.1 mg/L 0.0002 mg/L 0.001 mg/L 0.001 mg/L 12/1117 12/4/17 12/1/17 12/4/17 12/1/17 12/1/17 12/4/17 12/1/17 12/1/17 12/1/17 DATA APPROVED FOR RELEASE BY 240 South Main Street 1 Brighton, CO 80601-0507 / 303-659-2313 Mailing Address: P*O. Box 507 / Brighton, CO 80601-0507 / Fax: 303-659-2315 Page 2 of 3 0B1'1 MBN DBM MBN DBM DBM MBN DBM DBM DB1"1 171130022 2/2 06ed Io ,u Ti <� 1-1-4 tri Chain of Custody Form ca .s li c ` con g act ea O en u gl is fes• w? © n.. r co 1:12 esi CCpa Phone: 303-659-2313 Fax: 303-659-2315 www.coloradolab.com 311181 Disposal Date(Lab Use Only) r'0 W OS 4 may, V 1 i i C Chi G 43/41 03 is ry° en � t rVT}• •i al W. -DM O E9 E :ssaippv bris Skelton, J P P es wo ni ai Cr Itt In I 0 N cn iii C a ch l organics.com Sample Collector: Chris Skelton, PG - Al Organics Address: 16350 Wer 76 Lion Organics O S II Cd c, AO Ill ll 5 DDDQII t Mil i DD■DD'QDDD� UZ 'A 'II IV `aS Apia 0 ti est ili a CFA I rqd crib cop ,10, ■ I ■ ■ ■ ■ ■ III EI `Pp` s`EI`v`cis iliv.4 ■ ■ ■ ■ ■ ■ ■ ■ ■ de 410 1433 ■ ■ ■ L. r ❑ c.„) 5 [1 *Os 'EDin ■ ■ il ■, ■ ■ ■ ti IOD tr.) 51 tistrgiAl IralOf_iD 4aiI1v 3 u 1i IMF i1 `aTeip ° lost _ 0!S0dW03 (tCluin u0 13214D) 10 quip I • fl a 0 D il tians:Pteosse email results to chrisskeitor ' lorganics cam. 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C. y -e d 1 0 N.I f re}t_9 o ' 1 ;te Water I find Water race Water I _ r� r� a 4-4 7�e 1 etis1/4) Colorado aNA Analytical S LABORATORIES, INC Report To: Chris Skelton A-1 Organics Project Name: Eaton Total Alkalinity Ammonia Nitrogen Chloride Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Calcium Magnesium Potassium Sodium Nitrate Nitrogen Nitrite Nitrogen Sulfate Total Organic Carbon Blank Method Blank Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Blank Blank Blank Blank QC3O511 QC30515 QC30491 QC30481 QQ3O481 QC3O481 QC3O481 0C3O481 QC3O481 QQ3O481 QC30481 OC3O481 QC3O481 QC3O481 QC3O481 QC3O481 QC3O481 QC30481 QC3O5O2 QC3O5O2 QC3O5O2 QC3O5O2 QC3048O QC30490 OC3O493 QC3O461 Detailed Analytical QC Summary TASK NO: 171130022 Receive Date: 11 /30/2017 Collector: Chris Skelton <0.1 mg/L as CaCO3 <0.03 mg/L <0.01 mg/L <0.0O12 r'rrg/L <0.00O8 mg/L <0,0007 mg/L <0.0001 mg/L <o.0001 mg/L <0.OO15 mg/L <0.0OO2 mg/L <0.0008 mg/ <0,0001 mg/L <0,0009 mg/L <0.0008 mg/L <0.0001 mg/L <0.0002 rng/L <0.001 mg/L <0.001 mg/l. <0,1 mg/L <0.02 mg/L <0.1 mg/L <0.1 rng/L <0.05 rng/L <0,03 mg/L <0 .01 mg/L <0.5 mg/L SM 2320-B SM 4500-NH3-G EPA 3O0-0 EPA 200.8 EPA 200-8 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200-8 EPA 200.8 EPA 200.B EPA 200.8 EPA 200.8 EPA 200.8 EPA 200,8 EPA 200.7 EPA 200.7 EPA 200.7 EPA 200,7 EPA 300.0 EPA 300.0 EPA 300,0 SM 5310-C rest Total Alkalinity QC Type Duplicate LCS QC Batch QC30511 LCL UCL I �/0 Roc 0 20 90 110 104.1 RPD Method 1.5 SM 2320-B (d) PPG acceptable due to low duplicate and sample concenlrations (s) Spike amount low relative to the sample amount 1 /4 Pagel of6 tS Colorado as\s„ Analytical • LABORATORIES, INC detailed Analytical QC Summary TASK NO: 171130022 Report To: Chris Skelton Receive Date: 11/30/2017 A► -1 Organics Collector: Chris Skelton Project Name: Eaton Ammonia Nitrogen Chloride Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Duplicate QC30515 0 20 LCS 90 110 101.5 MS 75 125 100.7 Duplicate 0030401 0 20 LCS 90 110 98.7 MS 75 125 102.1 Duplicate 0030481 0 10 LCS 90 110 955 MS 70 130 95.8 Duplicate OC30481 0 10 LCS 90 110 98.1 MS 70 130 95.4 Duplicate QC30481 0 10 LCS 90 110 94,7 MS 70 130 87.6 Duplicate 0C30481 0 10 LCS 90 110 96.8 MS 70 130 97.2 Duplicate QC30481 0 10 LCS 90 110 93,9 MS 70 130 91.1 Duplicate QC30481 0 10 LCS 90 110 98.7 MS 70 130 93.8 Duplicate QC30481 0 10 LCS 90 110 103.6 MS 70 130 91.8 Duplicate 0030481 0 10 LCS 90 110 99 2 MS 70 130 82.9 8.5 SM 4500 -NI -3-C 0.5 EPA 300.0 7.7 EPA 200.8 7.7 EPA 200.8 9,2 EPA 200.8 0.8 EPA 200.8 3.1 EPA 200.8 4.5 EPA 200.8 3.4 EPA 200.6 4.7 EPA 200.8 (d) RPD acceptable due to low duplicate and sample concentrations (s) Spike amount low relative to the sample amount 2/4 Page 2 of 5 irmb;,\ Colorado ' : AnaLytical LABORATORIES, INC. Detailed Analytical QC Summary TASK NO: 171130022 Report To: Chris Skelton Receive Date: 11/30/2017 A-1 Organics Collector: Chris Skelton Project Name: Eaton Lead Nickel Selenium Silver Thallium Vanadium Zinc Calcium magnesium Potassium Duplicate QO30481 0 10 LCS 90 110 1023 MS 70 130 96.1 Duplicate QC30481 0 10 LOS 90 110 98 ,6 MS 70 130 89.4 Duplicate QC30481 0 10 LCS 90 110 99.1 MS 70 130 105.8 Duplicate QC30481 0 10 LOS 90 110 105.0 MS 70 130 88.9 Duplicate OC30481 0 10 LOS 90 110 103.6 MS 70 130 97.3 Duplicate QC30481 0 10 LCS 90 110 98 1 MS 70 130 9112.4 Duplicate OC30481 0 10 LCS 90 110 101.2 MS 70 130 48.4 s Duplicate QC30502 0 20 LCS 90 110 106.9 MS 75 125 89.5 Duplicate OC30502 0 20 LCS 90 110 107 5 MS 75 125 88.4 Duplicate QC30502 0 20 LCS 90 110 107.0 MS 75 125 96.2 4.9 EPA 200.8 1.8 EPA 200.8 0.0 EPA 200.8 0.0 EPA 200.8 5.0 EPA 280.8 9,91 EPA 200.8 5.0 EPA 200.8 2.6 EPA 200.7 1.7 EPA 200.7 2.6 EPA 200 7 (d) RFD acceptable due to low duplicate and sample concentrations (s) Spike amount low relative to the sample amount 3/4 Page 3 of 6 Colorado ' � Analytical LABORATORIES, INC Detailed Analytical QC urnmary TASK NO: 171130022 Report To: Chris Skelton Receive Date: 1//3012017 A-1 Organics Project, Name: Eaton Collector: Chris Skelton Sodium Nitrate Nitrogen Nitrite Nitrogen Sulfate Total Organic Carbon Duplicate OO30502 0 20 LOS 90 110 104.1 MS 75 125 96.7 Duplicate QC30439 0 20 LOS 90 110 90.8 MS 76 125 99.7 Duplicate QC30490 0 20 LCS 90 110 92.8 MS 75 125 96.0 Duplicate QC30493 0 20 LCS 90 110 98.3 MS 75 125 94.6 Duplicate QC30461 0 LCS 90 MS 85 10 110 102.0 115 35 3 1 8 EPA 200.7 2.0 EPA 300.0 0.0 EPA 300.0 1.6 EPA 300.0 0.5 SM 5310-C Approved: (d) RPD acceptable due to low duplicate and sample concentrations (s) Spike amount low relative to the sample amount Date: 12/612017 Page 4 of 6 .11X\ Colorado Analytical LABORATORIES; I N C Report To: Chris Skelton A-1 Organics Project Name: Eaton Detailed Analytical QC Summary TASK NO: 171130023 Receive Date: 11/30/201 7 Collector: Chris Skelton Test QC Type QC Batch Result Method Total Alkalinity Ammonia Nitrogen Chloride Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Calcium Magnesium Potassium Sodium Nitrate Nitrogen Nitrite Nitrogen Sulfate Total Organic Carbon Test Blank Method Blank Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Method Blank Blank Blank Blank Blank QQ30511 QC30515 QC30491 QC30481 OC30481 QC30481 QC30481 0030481 QC30481 OC30481 OC30481 QC30481 QC30481 QC30481 QC30481 QC30481 QC30481 QC30481 QC30502 QC30502 QC30502 QC30502 QC 30489 OC30490 QC30493 QC30481 QC Type QC Batch LCL <0.1 mg/L as CaCO3 <0.03 mg/L <0.01 mg/L <0,0012 mg/L <0.0006 mg/L <0.0007 mg/L <0.0001 mg/L <0.0001 mg/L <0 0015 mg/L <0.0002 mg/L <0_00084 mg/L <0.0001 mg/L <0 0009 mg/L <0.0008 mg/L <0.0001 mg/L <0.0002 mg/L <0,001 mg/L <0,001 mg/L <0.1 mg/L <0.02 mg/L <0.1 mg/L <0.1 mg/L <0.05 mg/L <1.03 mg/L <0,01 mg/L <0.5 mg/L JCL % Roc SM 2320-B SM 4500-NH3-G EPA 300.0 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200 8 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200.6 EPA 200 8 EPA 200.8 EPA 200.8 EPA 2008 EPA 200.7 EPA 200.7 EPA 200.7 EPA 2007 EPA 300.0 EPA 300.0 EPA 300.0 SM 5310-C RPD Method Total Alkalinity Duplicate LCS QC30511 0 90 20 110 104.1 t5 SM 2320-B (d) RPD acceptable due to low duplicate and sample concentrations (5) Spike amount low relative to the sample amount 1/4 Page 1 of 5 Colorado • AnaLytical LABORATORIES( 1NC. Detailed Analytical QC Summary TASK NO: 171130023 Report To: Chris Skelton Receive Date: 11/30/2017 A-1 Organics Collector: Chris Skelton Project Name: Eaton Ammonia Nitrogen Chloride Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Duplicate QC30515 0 20 LCS 90 110 101.6 MS 75 125 100.7 Duplicate OC30491 0 20 LCS 90 110 98.7 MS 75 125 102.1 Duplicate QC30481 O 1O LCS 9O 11O 95.5 MS 70 130 98.8 Duplicate QC30481 O 10 LOS 90 110 98.1 MS 70 13O 95.4 Duplicate QO30481 0 1O LCS 90 110 94.7 MS 7O 13O 87.6 Duplicate QC30481 O 10 LCS 90 110 96.8 MS 70 130 97.2 Duplicate QC30481 0 10 LCS 90 110 93.9 MS 70 130 97.1 Duplicate QC30481 O 1O LOS 9O 110 98.7 MS 70 130 98.8 Duplicate QC30481 0 10 LDS 90 110 103.6 MS 70 130 91.8 Duplicate QD80481 0 10 LCS 9O 110 99.2 MS 70 130 82.9 8.5 SM 4500 -NHS -G 0.5 EPA 300.0 7.7 EPA 200.8 7.7 EPA 200.8 9.2 EPA 209.8 8,8 EPA ,200.8 3.1 EPA 200.8 4.5 EPA 200.8 3.4 EPA 200.8 4.7 EPA 200.8 (d) RPD 000eptable dce to low duplicate end sample concentrations (s) Spike amount low relative to the sample amount 214 Page 2of5 repo) Colorado aca, Analytical LABORATORIES, INC. Detailed Analytical QC Summary TASK NO: 171130023 Report To: Chris Skelton Receive Date: 11/30/2017 A-1 Organics Collector: Chris Skelton Project Name: Eaton Lead Nickel Selenium Silver Thallium Vanadium Zinc Calcium Magnesium Potassium Duplicate QC30481 0 10 LOS 90 110 102.3 MS 70 130 96.1 Duplicate 0030481 0 10 LCS 90 110 98.6 MS 70 130 89.4 Duplicate QC30481 0 10 LCS 90 110 99.1 MS 70 130 105.8 Duplicate QC30481 0 10 LOS 90 110 105.0 MS 70 130 88.9 Duplicate QC30481 0 10 LCS 90 110 103.6 MS 70 130 97.3 Duplicate QC30481 0 10 LOS 90 110 98.1 MS 70 130 92.4 Duplicate OC30481 0 10 LOS 90 110 101.2 MS 70 130 40,4 a Duplicate O030502 0 20 LCS 90 110 106.9 MS 75 125 89.5 Duplicate QQ30502 0 20 LOS 90 110 1075 MS 75 125 88.4 Duplicate OC30502 0 20 LOS 90 110 107 0 MS 75 125 962 4a9 EPA 7 200.8 1.8 EPA 200.8 0,0 EPA 200 8 0.0 EPA 200.8 5.0 EPA 200.8 9.9 EPA 200.8 5.0 EPA 200,8 2 6 EPA 200.7 1.7 EPA 200 7 2.6 EPA 200.7 (d) RPD acceptable due to low duplicate and sample concentrations (a) Spike amount low relative to the sample amount 3/4 Page 3 of 5 lit's) Colorado %, Analytical LABORATORIES, INC Detailed Analytical QC Summary TASK NO: 171130023 Report To: Chris Skelton Receive Date: 11/3012017 A-1 Organics Collector: Chris Skelton Project Name: Eaton Sodium Nitrate Nitrogen Nitrite Nitrogen Sulfate Total Organic Carbon Duplicate OC30502 0 20 LCS 90 110 104.1 MS 75 125 06.7 Duplicate QC30489 0 20 LCS 90 110 90.8 MS 75 125 99.7 Duplicate QC3O490 0 20 LCS 90 110 92.8 MS 75 125 96.0 Duplicate QC30493 0 20 LCS 90 110 98 3 MS 75 125 94 6 Duplicate 0C30461 0 10 LCS 90 110 102.0 MS 85 115 85.3 1.8 EPA 200.7 2.0 EPA 300.0 0.0 EPA 300.0 1.6 EPA 300.0 0.5 SM 5310-C Approved: (d) RPD acceptable due to low duplicate and sample concentrations, (s) Spike amount low relative to the sample amount Date: 12/6/2017 414 Page 4 of 6 Appendix C SMA's Statistical Evaluation Results of Statistical Analysis All statistical tests were performed using the most current version of Sanitasw, which is based on the methods described by Gibbons (Gibbons, 1994), Gilbert (Gilbert, 1987), Hollander (Hollander and Wolfe, 1973) and Environmental Protection Agency (EPA,1989; EPA,1992). Additional information associated with the following statistical evaluations and related discussions are supported by the Unified Guidance (EPA, 2009). Non-VOC constituent concentrations and, when applicable, SanitasT , statistical analysis results for wells MW -1, MW -3, MW -4, MW -5A, and Mw -6 may be found in Appendix C. Background ranges are included in Appendix C. All statistical analyses were performed in accordance to the approved Engineering Design and Operations Plan (Pretti, 2016). Laboratory analyses for VOCs and SVOCs were not conducted during the November 2017 monitoring event for any samples collected at any wells in the monitoring well network. VOCs and SVOCs will be monitored beginning in May 2019. MW -1 (Down -Gradient) No constituent concentrations exceeded the Shewhart-CUSUM Control Chart/Prediction Limit during the November 2017 monitoring event at well MW -1. The Mann -Kendall trend analysis indicated no statistically significant increasing trends during the most recent monitoring event. Arsenic, calcium, chloride, chromium, magnesium, nickel, and nitrate concentrations exhibited statistically significant decreasing trends during the November 2017 monitoring event. The detected concentrations of nitrate and sulfate at MW -1 were 14.53 mg/I and 1411 mg,fl, respectively, during the November 2017 monitoring event, which exceed the Basic Standards for Groundwater (BSGW) of 10 mg/l and 250 mg/I, respectively. No other constituent concentrations exceeded the BSGW at well MW -1. MW -3 (Side -Gradient) No constituent concentrations exceeded the Shewhart-CUSUM Control Chart/Prediction Limit during the November 2017 monitoring event at well Mw -3. The Mann -Kendall trend analysis indicated no statistically significant increasing trends during the most recent monitoring event. Arsenic, beryllium, cadmium/ cobalt, lead, nickel, vanadium concentrations exhibited statistically significant decreasing trends during the November 2017 monitoring event. The detected concentrations of nitrate and sulfate at MW -3 were 10.45 and 1513 mg/I, respectively, during the November 2017 monitoring event, which exceed the BSGW of 10 mg/1 and 250 mg/1, respectively. No other constituent concentrations exceeded the BSGW at well MW -3. MW -4 (Down Gradient) No constituent concentrations exceeded the 5hewhart-CU LM Control Chart/Prediction Limit during the November 2017 monitoring event at well MW -4, with the exception of nitrite. The non -parametric prediction limit for nitrite concentrations at well MW -4 is 0.15 mg/1, and during the November 2017 sampling event, nitrite was detected at a concentration of 0.29 mg/I. November 2017 was the first nitrate concentration prediction limit exceedance at well Mw -4. It should be noted, the CUSUM for calcium, magnesium, sodium, and sulfate exhibited control chart limit a .ceedances, while detected concentrations were less than control chart limits, The Mann -Kendall trend analysis indicated no statistically significant increasing trends during the most recent monitoring event. Arsenic, barium, cadmium, chromium, cobalt, copper, lead, nickel, selenium, vanadium, and zinc concentrations exhibited statistically significant decreasing trends during the November 2017 monitoring event. The detected concentrations of nitrate and sulfate at MW -4 were 11,97 and 1478 mg 'I, respectively, during the November 2017 monitoring event, which exceed the BSGW of 10 mg/I and 250 mg/I. No other constituent concentrations exceeded the BSGW at well W-4. MW -SA (Up -Gradient) No constituent concentrations exceeded the Shewhart-CUSUM US U M Control Chart/Prediction limit during the November 2017 monitoring event at well MW -SA. The Mann -Kendall trend analysis indicated no statistically significant increasing trends during the most recent monitoring event. Beryllium, nickel, selenium, and zinc concentrations exhibited statistically significant decreasing trends during the November 2017 monitoring event. The detected concentrations of nitrate and sulfate at MW -SA were 11,43 and 1471 mg'"i, respectively, during the November 2017 monitoring event, which exceed the SS W of 10 mei and 250 mg, 1. No other constituent concentrations exceeded the BSGW at wellMW-5A. MW -6 (Down -Gradient) Monitoring well MW -6 was sampled for the second time during the November 2017 sampling event. Statistical analysis for constituent concentrations will begin once an adequate number of sampling events have occurred to populate the background set. The detected concentrations of nitrate and sulfate at MW -6 were 11.68 and 1360 mg `I, respectively, during the November 2017 monitoring event, which exceed the BSGW of 10 mill and 250 mg,'1. No other constituent concentrations exceeded the BSGW at well MW -6. BIBLIOGRAPHY EPA, 1989, Statistical Analysis of Ground -Water Monitoring Data at RCRA Facilities: Office of Solid Waste Management Division, U.S. Environmental Protection Agency EPA/530-SW-89-026, April 19189, EPA, 1992, Statistical Analysis of Ground -Water Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance: U S. Environmental Protection Agency, July 1992. EPA, 2009, Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance, EPA 530/R-09-007, March 2009 Gibbons, R.D., 1994, Statistical Methods for Groundwater Monitoring: Chicago, John Wiley & Sons, Inc., 286 p. Gilbert, R.0.,1987, Statistical Methods for Environmental Pollution Monitoring, New York, Van Nostrand Reinhold, 320 p. Hollander, M. and Wolfe, DA., 1973, Nonparametric Statistical Methods: New York, John Wiley & Sons, Inc., 503 p. Prett i, M., 2016, Engineering Design and Operations Plan, Souder, r, Miller & Associates, February 2012. Revised: May 2014, December 2016. Al Organics: Non-VOC Constituents for MW -I Al Organic0 Client Eaton Organic Recycling Data: Al Organics PONS 12121/2017, 12:30 PM 10411 1 y ti e Cisc %-:' ktoo. 041 ys0 �� 7+' ,4010 er „„anweiO 1 O0IC. 0F� 'M" fl a Tom'" CP 61712011 $12612012 11/2912012 6128/2013 1112512013 2/28/2014 5)20/2014 815)2014 11/2512014 2112/2015 512513015 811912015 11/25/2015 5/18/2016 1111 b/2016 5/30/2017 11/29/2017 438 406 443 461 469 521 466 434 409 374 395 427 417 411.4 427.2 <0.002 <0 002 <0.002 c0,002 <0.002 <0.002 <0,002 <0,002 40,002 40,002 <0,002 00.002 <0.00a 0.0023 0.007 0 0083 0.0028 00014 0.0037 0.4063 0,0018 O,d01a 0,0018 0.0011 0,023 0049 0.16 0,26 0.0707 0.0219 0 118 0.155 0.0280 0.037 0.035 0.0165 <0.002 0.0059 0.211 .00,0008 <0.002 (0)0.033 <0,0008 0 0024 0.0333 <0.0012 040007 0.0127 <0,0012 0.0012 0,037'5 311/2011 0/2612012 1112912012 8/28(2012 11/25/2013 2/2612014 Si20/2014 91512014 11/2612014 211212015 512812015 8/19/2015 11/25/2[115 5110/2016 11/1012016 6/30/2017 11/29/2017 <0.02 0.015 0,023 0025 <0.01 cD 01 0.0115 0,0162 <O.01 <0.01 <0.01 40.01 0,018U <0,01 <0,004 .00,01115 0.003+1 <0.002 <t1.OG1 0.0055 0.009 <0.001 <0,001 0.0016 0,0041 <13,001 <0.002 #0.002 <0.001 0.0059 <0.01 <0,0004 0.0004 0.0014 .00.01 0.01 0,023 0,03 00154 <0.01 0,0124 0.0202 <0,01 <0,01 <0,01 0.0223 41.01 0.0078 0.0028 0,0033 <0,001 504 <0.001 436 <$001 406 0 0021 443 <0.001 451 <0.001 459 <O,001 521 0,0011 466 <0,001 595 <0,001 434 <0.001 400 <0.001 374 0.0015 398 0,0005 (.1427 0,00052 417 <0.0001 4114 0.0002 427.2 <00005 316 <0.0005 291 0.0011 322 0.00076 276 <Q.000►5 295 <0.0005 291 <0.0005 284 0,00072 277 <0.0006 289 <0,0005 294 <O.O305 270 <0,001 253 0.00065 274 <Q.0002 259 0.00056 309 <0,0001 289,1 <0,0001 246.3 <0,0025 256 0.0032 247 0.013 235 00424 227 0.0057 218 .00,00251 223 04073 227 0.012 214 <0 0025 199 <0.0025 234 0.0026 205 <0.0025 200 0,010 215 1474 <2 <0,02 0.0027 0,0065 0.0005 0.0022 199 206 200i 196.2 <a 156 <5 190 <5 190 <5 211 c5 i 60 172 <5 179 <5 143 <5 127 <5 126 45 107 <5 119 <5 116 <2 4B 114 144 <0.1 130 78 <0.1 105000 0.02 23.7 0.019 241 0:061 24,2 0.026 22,2 0,0165 20.3 0.0139 2"1,2 0,0111 19.7 0.0212 21,4 0.0104 19.3 0.9164 19.1 0.0118 17,13 0.0106 17',7 0.0227 17$ <0.005 <0,008 17 0.0124 18.2 0,0014 16,35 0.0034 14.53 16.7 Al Organics: Non-VOC Constituents for MW -1 Al Organica Ghent: Eaton Organic Recycling Data; Al Organics Printed 12/21/2017, 12:30 PM Rage 2 sots' �i� 4�a14 ' ,, �+ n 4{" 15°6tea+ er.,1y `t oth atio ,04 taws - so,A 5•9700. 6/7/2011 <0.12 7.13 8128/2012 40,05 7.14 7,46 1112912012 40 02 7.05 7.42 812812013 <0,02 7,03 6.03 1i/25/2013 40,02 71 7,33 2/2812014 40,02 7,07 7,35 512812014 40.02 7.2 7.17 0/6/2014 40,02 7,09 7,02 11112012014 40,02 7.2 8.88 2112/2015 40,02 7,28 6,9 512812015 40,02 7.11 7,21 6/19/2015 0,043 7.15 0.82 i1/25/201.5 <0,02 7,18 7,08 5/4012015 40,01 8 8.52 11/10/2016 <0.4 7 7.24 5/3012017 <0.03 8.85 6.93 11/2912017 <0;D$ 8.88 7.09 2474 3,37 2,51 3.21 2,77 3.04 2,8 2,01 2451 3 2,94 2.7 2:84 2.0 2.76 2.8 3.3 Q,013 0.012 D.013 0.011 0.0066 0.0073 0,0082 0.0091 0,0079 0,0097 0.0073 0.0081 0.0095 0.0077 4.0101 0.0092 11.0054 <0,0005 404005 40 0005 40.00055 <0,0005 40;0005 40,0005 <0,0005 <0,0005 < 0,0005 44,0005 4000005 < 0,0005 < O 01 < 010002 <0.0001 40.0'001 224 3310 3100 16M 240 3020 2.3$ 16[30 213 2790 3.84 1530 231 3190 3.6 1400 215 3134 3.41 1340 234 3310 2,87 1410 2.36 2790 3.2 1350 215 2660 3.4 1390 222 2860 3.72 1374 233 2080 3.69 1430 204 2700 3.6 1340 218 2020 3,71 1290 226 2670 3,65 1330 206 2470 2870 3.45 1350 41 206 3060 3AS 1380 217 6 3117 3094 1433.44 211.3 3127 3661 1410451 pot Ok 6/7/2011 8/28/2012 1112912012 612812013 11(2512013 2126/2014 5128/2014 8/512014 11/2612414 2(12/2015 611228/2015 800121015 11/25121315 5118(2018 11/10/2016 5/3012017 11129/2017 ,1, oM"Mtidiek oar -4004,00--# 4pt woo a(St 14 a Orl SNaltillitairitroca knyeefl 17.4 12.1 16.2 12,2 13.2 15 13.0 10.8 119 13.1 14.8 38 1,05 1+4.3 13.4 120 13.55 40,001 40.0101 0.0012 40.041 40.401 401,401 40,001 40,401 <04001 <0,1301 40,001 <0,001 <0.001 <0.0002 <0.0004 40.0002 40.0002 5,6 5.5 5,7 5.8 5,7 53 5.1 5,5 5,1 49 5 5.1 5.2 <5 (J) 8.5 5,9 5,9 0.0058 0.015 0,034 0,048 0,0155 0,0077 00.222 0,028 0.0084 D.0089 0.0088 40,005 0.018 404005 0.003 0.007 40.05 207'4 <0,05 21.53 0.073 20,9 0,11 21.09 0.0526 21.13 40,05 20.8 0.0532 19.65 0.0744 18.98 40,106 18,96 <0.05 18.84 40.05 17.85 40,08 1021 0.0775 17.84 <0,01 40,02 17.69 <DM01 0,014 Al Organics. Non-VOC Constituents for MW -3 Al Organics Client: Eaton Organic Recycling Dais: Ai Organics Printed 12)21/2O17, 12:37 PM 617/2O11 111712012 411312012 7123/2012 2/1212015 811812O/5 1112512O16 5/1812018 11110/2016 513O/2O17 11/29/2017 495 4613 312 481 436 452 429 400,7 414.9 ,c0.002 <0,002 <0.002 <0,002 <0.002 <0,002 O1085 6.019 0.0077 0 019 0.00711 0.0073 00.0008 O40087 <0,11008 11,0043 <0,0012 0.001 <0.0012 0,0011 0.17 0.00 0.14 0.47 3.242 0.233 4.2281 0,09 0,0119 0.015 O.O038 9t}IJ 0.0029 495 0,0413 453 0.0022 372 0.0013 481 <0,001 438 0,0009 452 <0t0004 429 {0,0001 400.7 cO.OOO1 414.9 0.0£35 0,0028 0.0013 0.0022 <0.00055 <0,001 113 28$ 284 220 297 244 <0,001 (J) 235 0.00042 284 <0,0d01 240,3 <0.0001 278.9 <2 <061 .(041 I5 c5 red c5 c5 -1.9 81712011 1117/2012 4/13/2O12 7123/2O12 2/1212O15 811912O15 11125/2015 5(1812016 11/1O/2O18 513012017 11/29/2O17 kungfri OA Opt V psettutilA Loa 0191 * 1014 30 2 <0,02 0,0070 0,017 43 3 15.034 0,02 0,044 42 4 0,013 0,0049 O.Of 2 34 7 0.031 0,013 0,029 33 6 0.0101 0.0044 O4192 34 0.0182 0,0049 0.0193 42 9 44 2 471 4229 <0,O8 (i) <0401 <0,004 0.00087 0.4415 c0.0002 4.4.41! 15 0.0002 c0.O5 (,I) 1200 0.4498 0.4015 0.001? 0.021 125 4.035 174 0,011 188 0.027 150 O,O13# 207 0.0129 167 1104.5 0,039 0.05 0.024 4.032 O.}282 0.021 C2 <0,02 O,O1O9 149 {4.005 <0,04 (J) 0.41157 154 00113 c0.0001 150.9 0,0011 <0.0001 182.2 0.0011 Al Organics: Non-VOC Constituents for MW -3 Al Organics Client: Eaton Organic Recycling Data: Al Organics Printed 12121/201?, 12:3? IPM Page 2 0001040 -befits crif.lotist salve d °Atte .14:15A or it It kite mum Asolorui 1/4twiLue, 01,14 tioa ww- Ito it, tatrits seiroto scietio.1 617/2011 10,4 <0.12 7.38 3.96 1(1712012 74 <0.31 7.29 3.82 4113/2012 11.6 <0.05 7.15 7.4 4.02 7/23/2012 92 <0.05 7.38 8.34 3.54 2(12/2016 8,7 <0.02 7 4 7108 4.37 6(1912315 8,3 <0.04 7.27 CO 3,75 11125/2015 5(1912'418 11 11.4 <0.01 a $.40 3.6 1111012016 9.3 <0,02 7.13 7.27 33,7 8(30/2017 1443 <0 03 7.01 6.93 3.6 11/29/2017 10 45 <0.03 7iO5 7,2 4.2 0,0086 <0,0005 139 1820 1880 0,0089 40.0005 170 2234 0.0071 <0.0008 176 2600 0,008 {0,0045 152 2090 0.4072 <0.0005 197 2850 0.0061 40.0006 169 2320 0,0052 <0.01 145 1850 2320 00065 40k0002 148 2540 0.0059 <0.0001 146,5 2457 0.0071 <0.0001 174.8 2773 6/7/2011 1/17(2412 4/1312012 7/2312012 2112/2015 8/1012015 11)2 015 5/1812016 11/10/2016 5/30(2017 11129/2017 Ilagt° 11 ti wkal % 441 calcw" ,PILI ,094 _tr- y ci „�1/4,0001 ' .9064011/41" p, `,d 3 ona s�1++�! °1 r� `�� �+1 i 5 '�' � 1/4100444"'4100,241410,1400 ``i, <0.001 5.8 0,046 <0.05 0,402 i0,5 0,1 0,17 131 <0.001 7.2 0.039 22,09 <0,05 16 0,0017 5.3 0.074 24.32 Oi 101 <0,001 6 0.0442 22.02 0,089 12 <0.001 7 6 0.046 19.52 0,0858 21.15 31 3Q 1.45 7.8 <0.Q0O2 9 0.037 20,38 0.06 12,64 it 0.0004 6.7 0,©188 44,02 12,8 <0,0002 8,6 9 005 20.64 <0,001 13 <0,0002 8,3 0.006 +0001 Al Organics: Non-VOC Constituents for MW -4 Al Organics Client Eaton Organic Recycling Data: At Organics Printed 12121/2017, 12;51 PM 8/17/2012 &/2$/2012 1119/20412 6/28/2013 11/25/2013 210/2014 5/28/2014 8/5/2014 11/26/2014 2/121015 5/28/2015 8/19/2016 11/25/2015 5/18/2016 11/10/2018 5130/2017 11/29/2017 I cpaotts toot vir r1/40 _sits* _asps .,,dthsekr4 naratiota 3855 <0.002 343 414 382 358 370 368 360 365 358 387 460 422 443,1 471.3 <0,002 <0,002 40.002 <0.002 40,002 'c0,002 <0,002 40.002 40.002 40,002 <0.002 400.0009 400008 40,002 <0,0012 0,1077 0,14 €.008 M2 0.033 0.67 0,0062 0.124 /0.0148 X07, 311 0.002 0,478 0,0055 0.112 0,002 0,0336 0,0013 0,0212 0,0010 0.0258 0,0018 0,0248 0.0033 0,104 40.002 (,JJ 0,021 0,001 4,0137 0.0007 001.23 040015 0.0279 <0.001 365 +0,001 0,004 <0,001 0,0022 <0,001 40.001 c0,0D1 <0.001 t0.001 -40,001 <0,0001 <040004 40.0001 0,0002 383 414 382 365 370 368 492 358 365 356 387 460 422 443.1 471,3 t es X03rfikicpano,J"11 Nee Wei O4 to A Gs 0,4 0S0084 270 <5 0.0013 0.0016 0 0005 0.00093 <0.0005 <0,0005 +0,0005 <0,0005 <0.i0005 <04001 <0.0005 <0_0002 0.00023 <0,0001 40.2001 272 232 256 243 244 234 251 246 246 236 265 281 297 285.5 282,2 <2 <5 <0,1 <0,1 <5 <5 45 45 <5 <5 <5 c5 <S <5 •c5 -5 8117/2012 912812012 11129(2012 6i28/2013 11125/2013 2128/2014 5128/2014 915!2014 11/26/2014 2(12/2015 5/2612015 1'1912015 11/25/2015 5/101201B 11110/2013 6/30/2017 11129)2017 a WAYSilitelltitilt"ekszereStirtmis.01 ssiitrasitiCa3-JAPLCAP°1 -El %kVA" Or -Cs offA - repfAvr- • 01A mar A Pori— - °sea yr" necticrie _awe v tismikelitoom 0111 Do A War OA 1 r 145 0.018 0,0053 0.017 0.011 196 0016 133 104 71,9 70,6 83,8 07.4 70,9 71.1 81,8 97.3 181 114 122 122,1 117.15 0,017 0,051 0.0127 0.028 <0401 40.01 40.01 ct.Q1 <0,01 <0,01 <0t}1 4341 40}004 <0.0015 0 0018 0.0056 0'Vv♦ 0.0031 0,014 <0.001 0,0025 <0.001 <0,002 <0,002 <0.0131 0,0018 <0,01 <0,0004 0,0004 00019 0.019 0,050 0.0207 0+0205 40 01 0,0117 <0.0t <0.01 <0.01 <0.01 0.0106 40.1/1 1430 <2 0,004 0.0015 0.0032 40.02 0.0069 0.054 0.0101 0.0252 M036 0.0076 <0.0025 <0,0025 40,0025 c0,0025 0.0064 102 173 172 172. 173 169 163 158 171 174 195 <GF001 (J) 186 40,.001 203 0.0002 200.7 0.0027 204,6 0.057 0.056 00201 0,039 <0.01 040178 0.0101 0.0132 0,0113 0.0104 00142 <0,03 (J) 40,04 /) 0,0102 0.0017 0,0138 Al {organics: Non-VOC Constituents for MW -4 Al Organics Client: Eaton Organic Recycling Data: Al Organics Printed 12121/2017, 12:51 PM Page 2 8(17(2012 812012012 11/29/2012 6/26/2013 11/25/2013 2/2612014 5/23/2014 815120 14 11/26/2014 2/1212015 5/2812015 8/1912015 11/25/201$ 5/19/2015 11114/2010 5/3012017 11/26/2017 tostssv 1? 0 16 15 1 12.2 125 107 121 12.1 122 11.4 1204 128 12 12 12.84 11'97 4' 40.05 <0,02 0.15 0,031 10.02 04081 003 0.028 0,029 0.026 0.039 0.07 11.5 0.07 O,O73 .40.03 0.29 Wfoly iiips mom 11640 otk�,n„1 ci 7,27 3.5 0.0079 40006 218 2720 7563 7,22 744 2,82 0,01 <.f0.0005 206 7.26 7.09 3.34 D,O1j 1 <O.0005 215 7,38 7.56 2,82 0.0090 <0.0005 213 ?.35 7.0 6.01 0 0118 #1.4005 209 7.33 7,23 2.1112 0.0088 <0,0005 21e 7.21 7.2 172 0,0105 '0.0045 201, 7.32 7,09 2,85 0,0003 '0,4005 213 7.33 7 03 2406 0,,0082 <0.0006 214 7,28 7.41 2.81 0*0082 <0,0005 194 7.34 7.32 .2,7'0 0.000 <0.04Q5 211 7.35 7,06 2,96 0.00$ '40.0005 234 8 8,00 3 0.0055 <0.01 205 2460 7.08 7,31 3,28 D„0353 '0,0002 217 7.O4 8,96 3 0,005 40,0001 231.5 7.05 7.13 3.4 00042 c0,0001 236 5 2530 2710 2700 2840 2420 2190 2200 2650 2540 2520 2650 2440 3040 3182 3260 Tao 051'4 rim'' ,dilh+�a�' . 0,40 SerAfroat A 501.012.---A 54"11104417.6TivsestorrAiwirrarallossir %pm' rivAlortitH6P#40„:400.0u1Thwur tinvtiosieg21; 811712012 8f2W2012 7205 111241'(2012 3,34 1420 8126/2013 3,04 1220 11126/2013 248 127t1 212612014 2.4 1380 512@/2014 2,52 1190 81612014 363 1270 11/26/2014 324 1250 2/1212015 3.14 1300 5/28/2015 3.8 1220 8/1612015 3,54 1310 11)25/2015 3.35 1310 5/19/2016 3.36 1360 11110/2018 3.17 1320 5/3012017 3152 1465.38 11129)21117 3807 1477.52 4 y.4 A 1240 {0,001 6.,4 4102 0,072 143 20.05 11.2 010026 5.9 O,029 20,84 0.074 15,1 <0.001 6.9 On 24.3 O 27 11,4 <0,001 5,9 0.0284 20.4 0.0751 9.5 <0,001 5.5 0.0597 20.43 0.147 14.7 <0.001 5.1 0.0104 2017 '40.05 12 6 {0,001 5 0,0177 18.11 0,0654 9.4 '0.1101 4.8 <O,Q05 18.46 <0.05 10,9 <0.001 5.1 <0,005 18.45 <0.05 13,1 <0,001 6 0.0063 18.05 <0,05 12,E <0.001 5.3 0,0056 1724 '0,05 c0.001 5.6 0 0115 17.88 <0,05 42 311 1.04 12,7 <0,0002 6.9 <0.005 17.26 <0 01 12.25 <0,0004 8.3 0 002 <0.02 12,6 <0.0002 1.5 0 002 16.97 <0,001 12.4 {4.0002 O,408 0.009 Al Organics: Non-VOC Constituents for MW -5A Al 0rganica Cosa!: Eaton Organic Recycling Data: Al Organics Printed 12/2112017, 12:59 PM 911712012 012812012 11'12812012 349 0/2812013 585 11125/201S 400 2/2612014 443 5/26/2014 446 $/512014 35$ 11/26/2014 2/1212015 467 5/2612015 450 8/1912015 392 11/2512015 395 5/18/2510 498 11110/2018 443 51.30/2017 459 6 11129/2017 415 1 sea an WAI VOGS !MOP "Ail Cr tiosil too .5r% MBA' y," 'uui!r' i, erPr !.' 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Ai Organics printed 111112018,11:34 AM 5/30(2017 1112012017 4 is* 011.1:41v, PA16414 wetS itrom liffterP thooda CA 10 04 0046 too ofrefripo csodalliftill4401040,41. 'Mu"' 1041 imes) 4041 440,2 0,0012 0,0008 0,0126 #0,0001 440.2 c0.0O01 2881 .401 456.9 <0.00i2 0.0009 3.0127 0.14+01 +1•5&G <0.000i 293.9 <0,1 O003 "raj Cri:kr7CODOWYn le° 107.0 <0.0015 80495 4.0015 03012017 1109/2017 ttj i'�'n4t') c,00:00.6too�' L��y ,1��` wart'u� � aideA�l1, X4'1kgti 0,0002 0,00117 ca.0001 193 0,001$ 0,0002 0.4014 10.0001 198.5 0.0014 3,,32 c0.03 11.88 CID 7 CI 6,83 3,5 013082 7.2 3.9 01)087 513012017 11/280017 <Q,0001 208,2 0,0001 211.6 „an:A sag OOP 3067 30025 140446 11.4 <0.0002 2.4 0.4©3 11.03 40.0101 3072 3592 1359.91 13.6 4010002 6.7 0,003 11.79 .40.001 Hello