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Home My WebLink About20252973.tiffNEIGHBORHOOD MEETING NOTICE Dear neighbor, Biochar Now is in process of permitting a conversion facility on the subject property, shown below, located south of and adjacent to CR 6 and approximately 0.25 miles west of CR 31. As part of this process, we want to reach out to the nearby property owners to explain the proposed operation and answer any questions you may have. It is our desire to respectfully integrate into your community and to mitigate impacts of our operation. Please consider attending an informal neighborhood meeting, to be held at the: Fort Lupton Public and School Library Fort Lupton Community Room 2 370 S Rollie Ave, Fort Lupton, CO 80621 10:00 Aid, SATURDAY, OCTOBER 12, 2024 The goals of this meeting are to: ■ Explain biochar and the proposed on -site operations. ■ Provide you with details about the project, including the permitting processes. ■ Address concerns and answer questions that you may have about the project. We hope to see you there! NEIGHBORHOOD MEETING DETAILS On September 24, 2024, the applicant team mailed notice to the surrounding property owners identified on the Weld County Property Portal 500 -foot buffer report, listed below. BROWN RACHEL E LIVING TRUST 4510 COUNTY ROAD 6 FORT LUPTON. CO 806218216 HALE TONY LYNN 4760 Cc: U NTY ROAD I F=)RT LI_!PT 'N.'.1O 80621821b NGL WATER SOLUTIONS DJ LLC 865 ALBION ST STE 400 DENVER, CO 802204809 FAUDOA FERNANDO •ii 45/12 C O l_1 N TY ROAD 6 FORT LUPTON: C€=> >801;.2'182.' 6 YARBROUGH JERI E 451, t r=:, U N TY ROAD 6 FORT LUPTON_, CO 806218216 SACK GEORGE A. 4323 cod._l NT's' ROAD 6 FORT LUPTON. CC) 8062/82/5 This meeting was intended to provide the community with accurate information and to assist in addressing any concerns in a positive manner. Included in this document is a copy of the mailed letter and the attendance sheet. MEETING MINUTES The following topics were discussed: ■ What is Biochar, what will occur on this property, our desire to integrate into the area ■ Co -permitting efforts with NGL & OGED for injection wells; USR & WOGLA timeline • Mitigation efforts and options to reduce perceived land use conflicts ■ Irrigation practices and business impacts • Air emissions & pollution questions ■ Decrease in property values and quality of life ■ Site selection & compatibility complaints • General environmental health and contamination concerns • Stockpile heights and on -site equipment types ■ Kiln operated process and temperature ■ History of traffic incidents on CR 6 and possibility of increase NEIGHBORHOOD MEETING ATTENDANCE SHEET 10:00 AM, SATURDAY, OCTOBER 12, 2024 Name EmaRR SheJdie to\ettn 01 1\161 bOtioey000vieji(possi I Q)\iefl 5 \atr✓icc7hti1e9ryia.-il .C° SAG fee ,,u-dsM SUeQSreLAOLCW\ if Litt /Qc 'gall Y114le IYd le COril Alla tat K(c 't'v&c�7 Y/€ ( al 2MY-CA sk- c -a0 Qra-avvicaLs62-1-- foN/<.. 9 auk I. C W CV\CknC4 cz Yit eacut± V p%Ka( ouGHs'•cr&-SeP lei fr. �e "ilk 0 I ell i 1r 2arbeirh 0 36DallYYLou /57n%y�v611Z di � �v+-rso J to en Nnegi beer � a3 BIOCHAR PROCESSING CR 6, LLC USE BY SPECIAL REVIEW (USR) BIOCHAR INFORMATION JULY 1, 2024 Biochar Processing CR 6, LLC is pursuing a Use by Special. Review permit for a wood conversion facility, using kilns. Specifically, waste wood streams will be delivered to the site for conversion into biochar via pyrolysis. Biochar is a stable solid, rich in carbon that is made from organic waste material or biomass that is partially combusted in the presence of limited oxygen; essentially a form of charcoal. The qualities that make up biochar vary depending upon the material that it comes from. Biochar can then be used for a variety of agricultural, industrial and reclamation purposes. The pyrolysis process designed by Biochar Now utilizes a sealed emissions flaring system (kiln). The propane fired emissions stack maintains a constant temperature with minimal air emission and no visible emissions. The pyrolysis equipment remains sealed during the process. Upon completion of the pyrolysis process, the kilns cool to the required temperature, at which point the kilns that are filled with inactive biochar are then emptied into a closed containers, to then be removed from the property and delivered to off -site processing facilities. Proper operation of the equipment developed by Biochar Now and proper dust abatement ensures that any particulate emission (including odor) from the site should be minimal and not extend beyond the boundaries of the site property. Other site operations in support of this process will occur such as incoming and outgoing trucks, employee traffic, yard operations, storage, stockpiling, sorting, shredding and screening. Biochar Now currently operates a full processing facility within the municipal limits of the Town of Berthoud, on County Road 7. This facility includes the above conversion (pyrolysis) process and also includes processing and packaging of the final biochar products. This subject site will only include the conversion. Biochar Now maintains an active website, which details the products, applications, science and other questions about biochar. Provided below are several screenshots of the website: About Biochar Now WHO WE ARE ochar Now Is a pioneer in die biochar industry with strong engineering, manufacturing. sates and administrative personnel focused' on making and selling quality biochar on a very large scale. HISTORY Biochar Now IIILU! FU.; dtt_d November 2011 with three primary goals in mind; 1. Understand biochar's beneficial properties and potential markets 2. Understand how to consistently make high -quality biochar at very large scale 3. Meet the EPA's emissions standards To accomplish these goals. the company turned to existing research. consultants, science and engineering. However, because the industry was quite young. there were many questions that could only be answered by Biochar Now's own research and development. Biochar Now has been awarded eleven patents to date on both our technology and applications of biochar. The company has now successfully proven itself and is undergoing significant expansion throughout North America. MISSION STATEMENT To restore the Earth for Humanity Page 1 of 4 What is Biochar? Highly Adsorbent, Specially -Produced Ciiwcoal with Unique Properties "Biochar is a highly adsorbent, specially -produced charcoal with unique properties originally used as a soil amendment" Simply put, biochar is a highly adsorbent, specially -produced charcoal originally used as a soil amendment. Scientists theorize biochar was first used in the Amazon Basin thousands of years ago where extensive regions of dark, highly fertile soil known as terra preta were discovered, revealing high concentrations of biochar and organic matter. Similar to charcoal, biochar is produced using the ancient practice of heating wood or other plant material (biomass) with little to no oxygen. However, unlike charcoal, which is often used for cooking, biochar is made under specific conditions with the intent to be applied to soil as a means to increase soil fertility and agricultural yields, and sequester carbon to reverse global warming. Other market uses of biochar are being discovered regularly as universities and large industrial partners conduct extensive research into this versatile material and it~ cation exchange properties. Biochar is thought to be the key component in a carbon -negative strategy to resolve several critical current ecological challenges. Slow Pyrolysis Highest Carbon Sequestration Potential "Pyrolysis, a process in which biomass is heated in an oxygen -deprived environment to break down into simpler substances." Biochar is produced by pyrolysis, a process in which biomass is heated in an oxygen -deprived environment to break down into simpler substances. There are two types of pyrolysis: fast and slow. Fast pyrolysis uses moderate to high temperatures and rapid heating of wood chips while slow pyrolysis is characterized by gradual heating over a wide range of temperatures to produces its biochar. Biochar Now uses slow pyrolysis to permit various wood sizes, moistures and nature's anomalies to be slowly processed into consistent, high quality biochar. Climate Change Sequestering Atmospheric Carbon Ila "Biochar in soils create a long-term carbon -negative cycle by sequestering atmospheric carbon over long periods of time?' In addition to sustainably producing food, biochar is now seen as a simple, relatively low-cost tool for mitigating climate change. The production and use of biochar in soils create a long- term carbon -negative cycle by sequestering atmospheric carbon over long periods of time and reducing nitrous oxide and methane emissions from soil. Carbon Sequestration Biochar is referred to as "carbon -negative" because it sequesters more carbon than is produced when it is created. During pyrolysis, approximately 50% of the biomass' carbon content is held by the biochar, compared to 10-20% that remains in biomass after 5-10 years of natural decomposition. When biochar is added to soil, the carbon is sequestered for centuries, thereby reducing atmospheric carbon dioxide. Biochar also Improves soil fertility, thereby enhancing plant growth which absorbs more carbon dioxide from the atmosphere. Reduction in Greenhouse Gas Emissions Biochar also retains nitrogen, thereby reducing emissions of another alarming greenhouse gas, nitrous oxide. Research indicates that biochar-amended soils can provide anywhere from 50-80% reduction in nitrous oxide emissions, which is significant considering that the nitrous oxide released from certain fertilizers is 310 times more potent than an equal amount of carbon dioxide. Turning agricultural and forestry waste into biochar also reduces methane generated by natural decomposition. Page 2 of 4 PREMIUM QUALITY BIOCHAR CHIP SMALL BIOCHAR SIZE SELECTION INFORMATION MEDIUM POWDER When the biochar conversion process is finished, the raw biochar pieces are too large for practical use so they are resize-d at a crushing and screening workstation. The output produces four sizes - Chip. Medium, Small and Powder. Each size has its own uses as seen •i the table below. BIOCHAR SIZE SELECTION TABLE Chip Medium Small Powder Particle sizes (based on screen sizes) 1" to 3rnm 3mm to mesh 26 26 mesh to 50 mesh 50 mesh and under Applications Direct placement into soil X X X x Top -dressed on soil or grass X X Air seeder insertion into soil X Suspended in water spray x: Ag irrigation systems X. X Suspended in water for soil injection X Biofitter for air or water X X X A Biofiller for plastic, concrete or asphalt X X X Microbe carriers X X X X BAG SELECTION INFORMATION CHIP BIOCHAR NOW CRUSHING AND SCREENING WORKSTATION RAW, DRY BIOCHAR I CRUSHED BIOCHAR 4 OUTPUT SCREENER POWDER �;. SMALL MEDIUM After sizing, the biochar is packaged in either one cubic foot plastic bags or one cubic yard super sacks (FYI there are 27 cubic feet in one cubic yard). CUBIC FOOT BAGS SHIPPING INFORMATION CUBIC YARD SUPER SACKS Biochar Now has negotiated national discount rates with major carriers to handie the company's shipments. Our freight rates flow through to the buyer. Page 3 of 4 Specialty Agriculture lig]] Value Crop Production Specialty Agriculture Clients report yield increase of 100% or more with only 2% Biochar in the root zone. Research confirms biochar-enriched soils grow larger, healthier plants with greater yields, particularly in degraded or highly -weathered soils. In fact, Biochar Now users typically report their costs of biochar are paid off during the first year by increased yield revenues. Increases in soil fertility are attributable to biochar's unique properties of adsorption and stability. Compared to other organic soil amendments, biochar is much more effective at retaining nutrients and keeping them available to plants. it maintains a porous structure, which attracts beneficial microbes, holds onto nutrients, retains moisture - qualities that increase fertilizer efficiency and enhance crop yield, while reducing the need to irrigate. And biochar is much more stable in the environment than any other form of organic matter. Reclamation Soil Amendment and Sequestration "Once sterile soil can now support plant growth." Blochar offers an extremely cost-effective solution to bind toxins and prevent their leaching into surface and ground water. And, as a bonus, the once sterile soil can now support plant growth. By sequestering the heavy metals in the soil surrounding abandoned mines, biochar prevents these contaminants from leaching into local water supplies. Secondarily, biochar quickly facilitates the reestablishment of vegetation on this typically sterile ground with improved soil fertility and reduced erosion. Moreover, biochar can accomplish mine reclamation quickly and at a mere fraction of the cost of removing tailings to hazardous waste landfills. Proof of biochar's mine reclamation capabilities can be found within many biochar experiments at abandoned mine sites throughout Colorado and other western states. In less than a year, the projects revegetated the area and drastically reducing the risk of the heavy metals leaching into water supplies. Oil and Gas Filtration and Cleanup `Hydrocarbons and VOCs are captured and sequestered in the biochar." Biochar from Biochar Now is being used by the oil and natural gas industries as an economical method of complying with the U.S. Environmental Protection Agency's (EPA) air and water quality regulations. To comply during drilling operations, Biochar Now biochar is applied to the soil in oil and gas production areas to decontaminate the soil. In so doing, hydrocarbons and VOCs are captured and sequestered in our biochar and broke down to nontoxic levels by embedded microbes. This process has been approved for many projects across the U.S. including in Texas by the Texas Railroad Commission. Biochar Now biochar filtration process is used to purify producer water from wells. Our biochar removes pollutants allowing for the discharge of clean water. Page 4 of 4 In response to completeness review question #9: Provide the details about the injection wells. And the process to get the injection wells approved. Note that the approval of the injection wells is required prior to approval of this USR The applicable wells are identified as follows: Well Name Roy SWD #1 Roy SWD #4 Roy SWD #5 API Number 05-123-49505 05-123-49502 05-123-49501 From the standpoint of the State of Colorado, the injection permits have been approved and issued. The attached permit approval provides substantial detail about the injection wells. Based on our 5-24-24 telephone conference with Jason Maxey, the Weld County approval process for Class II injection permits will be overseen by the Oil and Gas Energy Department (OGED). As you know, this represents a change from past protocol when Class II injection permits were administered by the Planning Department. At the time of our call, Jason indicated the effective date of the change from Planning to OGED would likely be 7-5-24. The process will involve filing of a Pre -Application Meeting Request. That would be followed by a meeting among all applicable parties. The next step in the process would be notification of applicable landowners, which would then be followed by formal application for Class II injection well approval. Ultimately, the final approval decision will be made via the OGED hearing process by the designated hearing officer. FOR COMMERCIAL OR INDUSTRIAL BUILDINGS, PLEASE COMPLETE THE FOLLOWING INFORMATION: Business Name: Address: BIOCHAR NOW, LLC Phone: OFFICE NUMBER TBD TBD CR 6 City, state, zip: FORT LUPTON, CO 80621 Business Owner: SAME Phone: Home Address: City, state, zip: List up to three persons in the order to be called in the event of an emergency: Name Title TBD - SITE OPERATIONS MANAGER Phone Address TBD - ASSISTANT SITE OPERATIONS MANAGER TBD - OFFICE PHONE Business Hours: 24 HOURS PER DAY Utility Shut Off Locations: Main Electrical: TBD Gas Shut Off: Days: 7 DAYS PER WEEK TBD Exterior Water Shutoff: TBD Interior Water Shutoff: TBD 01/24 13 1111111 ilia 1111111 uii liii! lii 11111111 III 11111 liii ini 2803263 10/3012000 12:05P JA Suki Tsukamoto 1 of 2 R 10.00 D 0.00 Weld County Co a Co 3 NOTICE OF RIGHT TO USE SURFACE OF LANDS THE UNDERSIGNED, James P. Wason, as Denver Basin Land Supervisor, of HS RESOURCES, INC., a Delaware corporation ("HSR"), whose address is 1999 Broadway, Suite 3600, Denver, Colorado 80202, on behalf of HSR, states as follows: HSR. is the owner of or has the right to an undivided interest in and to those certain Oil and Gas Leases set forth on Exhibit "A" attached hereto and by this reference made a part hereof, as same may be amended (hereinafter referred to as the "Oil and Gas Leases"). The undersigned is familiar with the terms and conditions of the Oil and Gas Leases and hereby confirms such as valid and subsisting Oil and Gas Leases which are within or have been extended beyond their primary terms by the actual drilling and production from a well or wells capable of producing oil and/or natural gas on lands covered by the Oil and Gas Leases or lands which have been pooled or unitized therewith. HSR, its agents, employees, designees, co -owners, successors and assigns hold certain rights to use and access the surface of the lands described below for the purpose of, among other things, DRILLING OR COMPLETION OPERATIONS OR CONTINUING ACTIVITIES FOR THE PRODUCTION OR TRANSPORTATION OF OIL, GAS, OR OTHER HYDROCARBONS OR PRODUCTS ASSOCIATED WITH THE FOREGOING INCLUDING, BUT NOT LIMITED TO, SURFACE USE, INGRESS TO, EGRESS FROM, AND CONSTRUCTION, MAINTENANCE, REPAIR, REPLACEMENT, AND MONITORING OF WELLS, LOCATIONS, EQUIPMENT, MUD AND RESERVE PITS, WELLHEAD EQUIPMENT, SEPARATORS, TANK BATTERIES, PIPELINES, GATHERING LINES, FLOWLINES, PIPELINE INTERCONNECTIONS, AND ANY AND ALL OTHER REASONABLE OR CUSTOMARY USES OF LAND RELATED TO SAID OPERATIONS OR ACTIVITIES. ALL OF SUCH SURFACE USES ARE SUBJECT TO THE TERMS SET FORTH IN THE OIL AND GAS LEASES, AT LOCATIONS WITHIN THE FOLLOWING DESCRIBED LANDS: Township 1 North 2 Range 66 West, 6th P.M. Section 8: N/2 NOTICE is hereby provided to all interested parties, including any surface owners, their heirs, assigns and successors -in -interest that HSR has an ongoing right to use the surface of the lands described above for any use as allowed by the Oil and Gas Leases now or at some future date. Certain Oil and Gas Leases may contain specific provisions restricting HSR's surface uses and occupancy. This Notice shall not apply to those Oil and Gas Leases containing such provisions. The provisions of each Oil and Gas Lease may be determined by examining the document as recorded on the Weld County records at the book and reception number provided on the attached Exhibit "A". This notice is intended to remain in force for as long as the Oil and Gas Leases, or any extensions or renewals thereof remain in effect as to the above -described lands or any portion thereof. However, nothing herein contained shall be construed to limit the rights or enlarge the obligations of HSR or any other party owning an interest in said lands or Oil and Gas Leases. Further, this notice shall not be construed to modify or disclaim any interest HSR or any other party may have in any other valid lease or leases which along with the Oil and Gas Leases may form a part of a pooled or unitized area for an existing well or which may become part of a future spacing unit or pooled area or may actually cover an interest in the specific lands herein described. r HS RESO rte* INC. By: `tip . , - 4. T r , 4 . STATE P (QUI.ADO ) w. w. O r,. ! Tit' OF F DENVER. chi 44; a SS ftrealta,sr j •' •r - yc �f fffa Mre oin� instrument was acknowledged before me this 29th day of September, 2000, by James P. /fill gg p Wason, as Denver Basin Land Supervisor of HS Resources, Inc., a Delaware corporation. WITNESS my hand and official seal. sin Supervisor My Commission expires: WGroup/Land1Wason/Eorros/Notice of Surface Use Aslnt(Multi).doc- a\t,),o) EXHIBIT "A" ATTACHED TO AND MADE A PART OF NOTICE OF RIGHT TO USE SURFACE LANDS TIN-R66W SEC. 28: N/2 WELD COUNTY, COLORADO LEASE NO. LESSOR . LESSEE LEASE DATE BOOK RE NO. `fWN P RANGE SECTION DESCRIPTION CO --004119-000 RITCHEY, CLARA M HANES M. DAWSON CO -004260-000 HEITMAN I TITAN ET AL, Ft K. HANES M. DAWSON CO -004123-000 BETTS ET UX, MAR' IN C. HANES M. DAWSON CO -004171-000 MCCRERY ET WK., JACK C. HANES M. DAWSON 1111111 11111 1111111 IIII111II1111l1IIlli II11111t ll111111 2803263 1013012U00 12:05P JA Suki Tsukamoto 2 of 2 R 10.00 0x.00 Weld County CO 2/21/70 2/21/70 2/21/70 3/1/70 Page 1 of 1 623 634 622 624 1544541 1556338 1544374 1545859 IN IN IN IN 66W 66W 66W 66W 28 28 28 28 EI2 N E/4 Wf2N E/4 N/2NW/4 S/2NW/4 1111111 uiu iiii1i iiui iiiiii nui 1iui III 11111 iii iui 3525268 12/2112007 01:50P Weld County, CO 1 of 14 R 71.00 D 0.00 Steve Moreno Clerk & Recorder REQUEST FOR NOTIFICATION (Mineral Estate Owner) Pursuant to C.R.S. Section 24-65.5-101, et seq., as amended, (hereinafter referred to as the "Statute") this Request for Notification shall serve to identify the undersigned, Kerr-McGee Oil & Gas Onshore LP, its successors and assigns, (hereinafter referred to as "Kerr-McGee") as a Mineral Estate Owner, underlying the lands(Surface Estate) described can the attached Exhibit A. Pursuant to the provisions of the Statute, an Applicant who submits an Application for Development to a local government shall send notice thereof to the Mineral Estate Owner. Such notice must comply with and be sent in accordance with the provisions of the Statute. All notices shall be sent to: Kerr-McGee Oil & Gas Onshore LP 1099 18th Street, #1500 Denver, CO 80202 Attn: Land M a n ag a rat t o nberg or such other address as Kerr-McGee may indicate by filing of record with the clerk a notification of change of address form or an amendment to the request for notification. Failure by the Applicant to comply with the Statute shall entitle the Mineral Estate Owner to the damages and remedies, both legal and equitable, as provided for in the Statute, or otherwise permitted by the law, including an award of reasonable attorney fees. All terms used herein, including hut not limited to Mineral Estate Owner, Applicant, and Application for Development shall have the meaning provided for in the statute. Kerr-McGee Pr Gas Onshore LP By: Joseph H. L CPC STATE OF COLORADO ) CITY AND COUNTY OF DENVER ) ttomey-act The foregoing instrument was acknowledged before me this _al day of _ , . l� V 2007, by Joseph H. Lorenzo, attorney -in -fact of Kerr-McGee Oil & Gas Onshore LP, a Delaware limited partnership, on behalf of the partnership. Witness my hand and official seat. Signature Name(Print) My commission expires My Commission Expires 01/19/2011 l 111111 11111 111111 Illll IIIMII hID 11111 111O11t 1111 I!!l 3525268 1212112007 01:50P Weld County, CO 2 of 14 R 71.00 D 0.00 Steve Moreno clerk & Recorder Attached to and made a part of that certain REQUEST FOR NOTIFICATION (Mineral Estate Owner) EXHIBIT A COUNTY WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD TOWNSHIP RANGE 1N 1N 1N 1N 1N 1N 1N 1N IN IN 1N 1N 1N 1N 1N 1N 1N IN 1N 1N 1N 1N IN IN 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N IN 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 63W 63W 63W 63W 63W 63W 63W 64W 64W 64W 64W 64W 65W 65W 65W 65W 65W 65W 65W 65W 65W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66V 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 67W 67W 67W 67W 67W 67W SECTION DESCRIPTION 5 11 12 13 23 24 31 24 29 30 33 35 3 5 6 7 18 20 24 29 35 1 2 3 4 5 6 7 8 10 11 13 15 16 17 18 19 20 21 22 28 29 33 35 36 1 2 3 4 5 7 W/2 SE ALL ALL NW, S12 ALL NW, SE SE SE ALL W/2 S/2 NE ALL ALL W/2 ALL W/2 NE N/2 S/2 SW2 ALL ALL ALL ALL ALL N/2 ALL ALL S/2, NW W/2 N12 ALL ALL ALL ALL E12, NW N/2 ALL W12, NE ALL N/2 ALL SW ALL ALL W/2 ALL ALL ALL 111111111111 11111 uui iuiii 1111111111 III 11111 iii 3525268 12/21/2007 01:50P Weld County, CO 3 of 14 R 71.00 13 0.00 Steve Moreno Clerk & Recorder Attached to and made a part of that certain REQUEST FOR NOTIFICATION (Mineral Estate Owner) EXHIBIT A i _ COUNTY WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD TOWNSHIP RANGE SECTION DESCRIPTION 1N 1N 1N 1N IN 1N 111 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 1N 'IN 1N 1N IN IN IN 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 2 of 13 8 9 10 11 12 13 14 15 17 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 25 27 31 ALL ALL ALL ALL ALL ALL ALL W/2 ALL ALL ALL ALL ALL ALL ALL S/2 ALL ALL ALL S/2, NW ALL ALL N12 ALL ALL ALL NE,S111J ALL ALL ALL W12 S/2 E12 6/2 E/2, NW W/2, NE ALL ALL ALL ALL ALL ALL ALL ALL ALL N/2 N/2, SW ALL \N12 ALL ALL S/2, NW S/2 * 1 Mill 11111 111111 11111 111111 11111 11111 ill 1111111111111 GO 3525268 12/21/2007 01:50P Weld County, 4 of 14 R 71.00 0 4.00 Steve Moreno Clerk & Recorder Attached to and made a part of that certain REQUEST FOR NOTIFICATION (Mineral Estate Owner) EXHIBIT A COUNTY WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELL) WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD TOWNSHIP 1N 1N 1N 1N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N1 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N RANGE 68W 68W 68W 68W 63W 63W 63W 63W 63W 63W 63W 63W 64W 64W 64W 64W 64W 64W 64W 64W 64W 64W 64W 64W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65K 65W 65W 65W 65W 65W 3 of 13 SECTION 33 34 35 36 5 6 7 8 18 19 20 30 1 4 6 7 18 19 21 24 26 27 29 31 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 DESCRIPTION E/2 NE ALL ALL S12, NW W/2 ALL 5/2 W/2 5/2 W/2 N/2 ALL N/2, SW W/2 ALL W/2 ALL W/2 NE SE 8/2 8/2 SE 8/2 ALL ALL ALL ALL E/2 SW ALL ALL ALL ALL ALL 812 ALL ALL ALL NW ALL S/2 ALL W/2 ALL ALL ALL S/2 W/2 , S E SW ALL rniu 1111 I III11I IIIII 11111111111 lull III 1Illl 1111 Ill1 3525268 12!2112047 01:50P Weld County, CO 5 of 14 fi 71.00 D 0.00 Steve Moreno Clerk & Recorder Attached to and made a part of that certain REQUEST FOR NOTIFICATION (Mineral Estate Owner) EXHIBIT A COUNTY WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD TOWNSHIP 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N 2N RANGE 65W 65W 65W 65W 65W 65W 65W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66 66W 66W 66W 66W 66W 66W 66W 66W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 4of13 SECTION 29 30 31 32 33 34 35 1 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 20 21 22 23 25 26 27 28 30 31 32 33 35 1 2 3 4 5 6 8 9 10 11 12 13 14 15 16 DESCRIPTION SW NE ALL ALL N/2, SW ALL ALL ALL ALL N/2 NE, SW ALL ALL W/2 Sf2 W/2 ALL ALL N/2 ALL W/2, SE ALL S/2, NE ALL N/2 ALL ALL 512 SW E/2 ALL E12 S12 Sf2 E/2 NE,W/2 S/2 A L L E12 ALL N/2 ALL ALL N/2, SW E12 ALL ALL ALL ALL ALL ALL E/2 111111 11111 111111 liii 11111111111 11111 ilL 11111 1111 IIII 3525268 1212112007 01:50P Weld County, CO 6 of 14 R 71.00 D 0.00 Steve Moreno Clerk & Recorder Attached to and made a part of that certain REQUEST FOR NOTIFICATION (Mineral Estate Owner) EXHIBIT A COUNTY TOWNSHIP RANGE SECTION DESCRIPTION WELD 2N 67W 17 S12 WELD 2N 67W 18 S/2 WELD 2N 67W 19 ALL WELD 2N 671! 20 ALL WELD 2N 6711 21 N/2 WELD 2N 67W 22 ALL WELD 2N 67W 23 ALL WELD 2N 67W 24 ALL WELD 2N 67W 25 A L L WELD 2N 67W 26 ALL WELD 2N 67W 27 ALL WELD 2N 67W 28 ALL WELD 2N 67W 29 W12 WELD 2N 67W 30 ALL WELD 2N 67W 31 ALL WELD 2N 67W 32 E12 WELD 2N 67W 33 ALL WELD 2N 67W 34 ALL WELD 2N 67W 35 ALL WELD 2N 67W 36 ALL WELD 2N 68W 1 ALL WELD 2N 68W 2 ALL WELD 2N 68W 3 ALL WELD 2N 68W 4 N/2 WELD 2N 68W 9 SW WELD 2N 68W 10 ALL WELD 2N 68W 13 E/2 WELD 2N 68W 14 W/2 WELD 2N 68W 15 ALL WELD 2N 68W 16 W12, SE 1111ELD 2N 68W 17 NE WELD 2N eaW 19 E12 WELD 2N 68W 20 ALL WELD 2N 68W 21 W/2, NE WELD 2N 68W 22 W/2, SE WELD 2N 68W 23 E/2 WELD 2N 68W 24 N/2 WELD 2N 68W 25 ALL WELD 2N 68W 26 ALL WELD 2N 68W 27 S/2 WELD 2N 68W 28 N/2, SE WELD 2N 68W 29 ALL WELD 2N 68W 30 ALL WELD 2N 58W 31 A L L WELD 2N 68W 32 N/2 WELD 2N 68W 33 N/2, SE WELD 2N 68W 34 ALL WELD 2N 68W 35 ALL WELD 2N 68W 36 ALL WELD 3N 62W 18 ALL WELD 3N 62W 1.9 ALL 5 of 13 111111 nui lUll 11111 111111 1111111111111111111111 1111 3525268 12121/2007 01:50P Weld Count, CO 7 of 14 R 71.00 D 0.00 Steve Moreno Clerk & Recorder Attached to and made a part of that certain REQUEST FOR NOTIFICATION (Mineral Estate Owner} EXHIBIT A COUNTY TOWNSHIP RANGE SECTION DESCRIPTION WELD 3N 62W WELD 3N 62W WELD 3N 63W WELD 3N 63W WELD 3N 63W WELD 3N 63W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64111,E WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64111. WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 64W WELD 3N 65W WELD 3N 65W WELD 3N 65W WELD 3N 65W WELD 3N 65W WELD 3N 65W WELD 3N 65W WELD 3N 65W WELD 3N 65W WELD 3N 65W WELD 3N 65W WELD 3N 65. WELD 3N 65W WELD 3N 65W WELD 3N 65W WELD 3N 65W WELD 3N 65W WELD 6N 65W WELD 3N 65W WELD 3N 65W 6 of 13 20 29 19 21 29 31 1 2 7 8 9 10 11 13 14 15 17 18 19 20 21 22 23 24 25 26 27 28 29 30 33 34 1 2 3 5 6 7 9 10 11 13 14 15 17 18 19 20 21 22 23 24 S/2 ALL W/2 W/2, SE W/2 W/2 W/2, SE NE NW ALL NW NW ALL SW N/2 NW NW,SE W/2 NW E/2, SW NW W/2 SW E/2 NE 5/2, NW S/2 E/2 SE S/2 Sf2, NW ALL S/2t NW ALL NE ALL ALL N/2, SW E/2 S/2 W/2, SE NE N/2 ALL ALL W/2 E/2 W/21 SE N/2 ALL ALL ALL 1111$!! 11111 lliil! IIIII I1fl1 1111! IIII UI I1I!11111f11 3525268 12/21/2007 01:50P Weld Cou ry, 8 of 14 R 71.00 D 0.00 Steve Moreno Clerk & Recorder Attached to and made a part of that certain REQUEST FOR NOTIFICATION (Mineral Estate Owner) EXHIBIT A COUNTY TOWNSHIP WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELL} WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD RANGE SECTION DESCRIPTION 3N 65W 25 N/2 3N 65W 26 N/2 3N 65W 27 ALL 3N 65W 28 ALL 3N 65W 29 ALL 3N 65W 30 ALL 3N 65W 31 ALL 3N 65W 32 E/2 3N 65W 33 ALL 3N 65W 34 ALL 3N 65W 35 N/2 3N 65W 36 E/2 3N 66W 1 ALL 3N 66W 2 ALL 3N 66W 3 E/Z SW 3N 66W 4 ALL 3N 66W 5 ALL 3N 66W 6 ALL 3N 66W 7 ALL 3N 66W 8 ALL 3N 66W 9 ALL 3N 66W 10 ALL 3N 66W 11 S/2, NE 3N 66W 13 ALL 3N 66W 14 ALL 3N 66W 15 ALL 3N 66W 16 ALL 3N 66W 17 A L L 3N 66W 18 ALL 3N 66W 19 ALL 3N 66W 20 N/2 3N 66W 21 A L L 3N 66W 22 ALL 3N 66W 23 ALL 3N 66W 24 N/2 3N 66W 25 N/2 3N 66W 26 ALL 3N 66W 27 ALL 3N 66W 28 ALL 3N 66W 29 N/2, SW 3N 66W 30 E/2, SW 3N 66W 31 ALL 3N 66W 32 E/2 3N 66W 33 ALL 3N 66W 34 W/2 3N 66W 35 ALL 3N 66W 36 A L L 3N 67W 1 ALL 3N 67W 2 ALL 3N 67W 3 ALL 3N 67W 4 ALL 3N 67W 5 W/2 7of13 . 1111111 111 MIME IMO 11111 11111111 11111 1111 1111 3525268 12/21/2007 01:50P Weld County, CO 9 of 14 R 71.00 D 0.00 Steve Moreno Clerk & Recorder Attached to and made a part of that certain REQUEST FOR NOTIFICATION (Mineral Estate Owner) EXHIBIT A COUNTY WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD' WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD TOWNSHIP RANGE SECTION DESCRIPTION 3N 3N 3N 3N 3N 3N 3N 3N 3N1 3N 3N 3N 3N 3N 3N 3N 3N 3N 3N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 67W 67W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 65W 68W 68W 68W 61W 62W 62W 62W 62W 62W 62W 63W 63W 63W 63W 63W 63W s. 64W 64W 64W 64W 64W 64W 64W 64W 64W 64W 64W 64W 64W 64W 64W 65W 65W 65W 65W 8 of 13 7 8 1 7 12 13 14 21 22 23 24 25 26 27 28 33 34 35 36 31 27 28 30 32 33 35 6 7 8 9 16 29 1 2 3 7 9 11 14 17 19 20 25 29 30 32 35 2 3 4 5 ALL ALL ALL NW SE ALL W/2 NE ALL ALL ALL ALL ALL ALL SW ALL ALL ALL ALL SW SW ALL ALL ALL S/2, NW ALL NW 8/2, NE ALL SW ALL NW NE NE NE SE W12 W/2 SW 812 ALL SW 8/2 W/2, SE SW ALL 8/2 ALL ALL SW E/2 I iuiii 11111 IIIII liii 111111 uiii 11111 lU 111111 iii iui 3525268 1212112007 01:50P Weld County, CO 10 of 14 R 71.00 D 0100 Steve Moreno Clerk & Recorder Attached to and made a part of that certain REQUEST FOR NOTIFICATION (Mineral Estate Owner) EXHIBIT A COUNTY WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD TOWNSHIP RANGE SECTION DESCRIPTION 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N1 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 66W 66W 66W 65W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 7 9 10 12 13 14 15 16 17 18 19 20 21 22 23 24 25 27 28 29 30 31 32 33 34 35 2 3 4 5 6 7 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 NW, 512 E/2, SW N/2, SW NE, SW 512 N12, SW ALL NE, SW NW, S/2 ALL ALL ALL W/2, SE S/2 N1/2, SE SW NW, SE N/2, SW N/2, SW ALL ALL ALL ALL S/2 ALL NW, S/2 SE S12 NW N/2 E/2, SW N/2 NW, Sf2 NWT 5/2 ALL ALL ALL ALL E/2 E/2 SE N/2, SW W/2, NE S/2 N/2, SW N/2 ALL SE ALL ALL ALL 9 of 13 111111111111 flU li 352526& 12/21/2007 01:50P Weld County, CO 11 of 14 A 71.00 Q 0.00 Steve Moreno Clerk & Recorder Attached to and made a part of that certain REQUEST FOR NOTIFICATION {Mineral Estate Owner) EXHIBIT A COUNTY TOWNSHIP RANGE SECTION DESCRIPTION WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 4N 66W 66W 66W 66W 66W 66W 66W 66W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 671,E 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 68W 28 30 31 32 33 34 35 36 1 3 4 5 6 7 8 9 1D 11 12 13 14 15 16 17 18 19 21 22 23 24 25 26 28 31 33 34 35 36 1 8 10 11 12 12 13 14 15 22 23 24 30 21 10of 13 S/2 NW, SE N/2, SW N/2, SW ALL ALL ALL ALL N/2 E/2 SE S12 ALL N E , SW W/2 SE Ell SW N/2, SE ALL NW NE, S/2 N/2 E/2 W/2 N/2, SW NE NE N/2, SE N E, S12 ALL ALL SE N E, St2 S/2 ALL ALL ALL E/2 NW S/2 ALL NW, S}2 N/2, SE N/2, SE W/2 S12 E12 W/2 NW, SE Ell NE IIIII111111111111111111111111111111111111111111111Ill 3525268 12/21/2007 01:50P Weld County, CO 12 of 14 R 71.00 D 9.00 Steve Moreno Clerk & Recorder Attached to and made a part of that certain REQUEST FOR NOTIFICATION (Mineral Estate Owner) EXHIBIT A COUNTY WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD TOWNSHIP RANGE SECTION DESCRIPTION 5N SN 5N SN SN 5N 5N 5N 5N 5N SN 5N 5N 5N 5N 5N SN 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N SN 5N 5N 5N 5N 5N 5N 5N SN 5N 5N 5N 5N 5N 5N 61W 62W 62W 63W 63 63W 63W 63W 63W 63 64W 64W 64W 64W 64W 64W 64W 64W 64W 64W 64W 64W 64W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 65W 66W 66W 66W 66W 66W 66W 66W 11fiat 13 2 18 20 13 14 18 19 24 29 31 3 7 9 14 15 21 22 23 24 29 31 32 35 1 2 3 4 11 12 13 14 15 21 22 23 24 25 26 27 29 30 32 33 34 35 1 3 5 6 7 9 17 SE NE E/2 SW N/2 S E NE E/2 NW NE N/2 NW SW N E N/2 N/2 SE NW, 5/2 NW, S/2 SE SE NW, Sf2 SW S12, NE E/2 W/2 N E ALL W12 S12, NW ALL NW, 3/2 N/2, SE VV/2 ALL N/2, SW ALL NE, SW N/2, SE SW W/2 SW NE N/2 ALL NE, SW NW, S12 W/2, SE NE W/2 SE NW 1111111111111111111111 IIILII 11111111111111111111111111 3525268 12/21/2007 01:50P Weld County, CO 13 of 14 R 71.00 D 0.00 Steve Moreno Clerk & Recorder Attached to and made a part of that certain REQUEST FOR NOTIFICATION (Mineral Estate Owner) EXHIBIT A COUNTY WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD' WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD TOWNSHIP 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 5N 6N 6N 6N 6N 6N 6N 6N 6N 6N 6N 6N am RANGE 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 66W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 67W 57W 67W 67W 67W 67W 67W 67W 67W 67W 61W 61W 64W 64W 64W 64W 64W 64W sitie4W 64W 64W 12 of 13 SECTION 19 20 21 23 24 25 27 28 29 30 31 32 33 34 35 36 1 2 3 5 6 7 8 11 12 13 15 20 21 23 25 26 27 28 29 31 32 33 34 35 36 24 25 16 18 19 20 28 29 30 32 33 DESCRIPTION E/2 ALL 5/2 N12 N/2, SW ALL W12, SE NEr SW E/2 NE W/2, NE ALL S/2 ALL N/2, SE ALL NE, SW W12 NW, 5/2 W/2, SE SE SE SW W12, SE E/2 SE S/2 ALL NE NW NW, S/2 S/2 N E , W/2 E/2 SE W/2, SE E12, NW NW, S/2 NE N12, SE ALL SE N/2 SW N/2, SW ALL SE E/2 S/2 E12, SW S/2 S/2 11111111111 111111 IIM11lI1III1111I III huLl I11Iill 3525268 12!2112007 01:50P Weld County, CO 14 of 14 R 71.00 D 0.00 Steve Moreno Clerk & Recorder Attached to and made a part of that certain REQUEST FOR NOTIFICATION (Mineral Estate Owner) EXHIBIT A COUNTY WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD WELD TOWNSHIP RANGE SECTION DESCRIPTION 6N 65W 14 SVV 6N 65W 15 S/2, NW 6N 65W 17 E12, SW 6N 65W 18 SW 6N 65W 22 SW 6N 65W 28 SE 6N 65W 31 W12 6N 65W 32 ALL 6N 65W 33 ALL 6N 65W 34 SW 6N 66W 14 SW ON 66W 28 SE 6N 66W 33 NE 6N 66W 35 SE 6N 66W 36 SE 6N 67W 14 NW 6N 67W 15 8/2 6N 67W 20 SE ON 67W 35 SE 7N 60W 14 SW 7N 60W 16 ALL 7N 66W 19 SW 9N 58W 3 W/2 9N 58W 4 E/2 9N 58W 5 SE 9N 58W 9 ALL 9N 58W 10 NW ION 58W 32 5/2, NE ION 58W 33 W/2, SE 13 of 13 LAND SERVICES OIL AND GAS TITLE P.O. Box 336337 Phone (970) 351-0733 Greeley, CO 80633 Fax (970) 351-0867 LIST OF MINERAL OWNERS AND MINERAL LESSEES for NOTIFICATION (NGL Water Solutions DJ LLC Property) Subject Property: Township 1 North, Range 66 West of the 6th P.M. Weld Count CO Section 28: Lot A and B of Recorded Exemption No. 1471-28-01 RECX17-O182, according to that certain map or plat thereof, record April 11, 2018 under Reception No. 4390255 and Surveyor's Affidavit of Correction recorded September 4, 2018 under Reception No. 4428199, being a part of the N% Zeren Land Services, an oil and gas title research company, states that to the best of its knowledge the following is a true and accurate list of the names and addresses of the mineral owners and mineral leasehold owners entitled to notice under the Surface Development Notification Act, Colorado Revised Statutes §24-65.5-101, et seq. in the Subject Property based upon the records of the Weld County Assessor and Clerk Recorder as of April 5, 2024 at 7:45 a.m.: Mineral Owners: None (entitled to notice) Dated this 11th of April, 2024 Mineral Leasehold Owners: Kerr-McGee Oil & Gas Onshore LP Attn: Land Manager/Wattenberg 1099 18th Street, Suite 700 Denver, CO 80202 ZEREN LAND SERVICES a6 By: Cynthia A. E. Zeren, C P Certified Professional Landman #4044 Page 1 of 2 At the request of KW Commercial ("Client"), Zeren Land Services, an independent land consulting firm, has prepared the foregoing list of mineral estate owners entitled to notice under the Surface Development Notification Act, Colorado Revised Statutes §24-65.5-101, et seq. Zeren Land Services, searched (I) the records of the Weld County Assessor relating to the Subject Property for persons identified therein as mineral estate owners, and (ii) the records of the Weld County Clerk and Recorder relating to the Subject Property for recorded requests for notification in the form specified in the Surface Development Notification Act. The results of these searches are set forth above in this List of Mineral Owners Entitled to Notice. At the date of the search, the records of the Assessor and the Clerk and Recorder were posted through April 5, 2024 at 7:45 A.M. Zeren Land Services, agreed to prepare this listing for the Client only if the Client agreed that the liability of Zeren Land Services, would be strictly limited to the amount paid by the Client for such services. Zeren Land Services, makes no warranty, express, implied or statutory, in connection with the accuracy, completeness or sufficiency of such listing of mineral estate owners. In the event the listing proves to be inaccurate, incomplete, insufficient or otherwise defective in any way whatsoever or for any reason whatsoever, the liability of Zeren Land Services, shall never exceed the actual amount paid by Client to Zeren Land Services, for the listing. In order to induce Zeren Land Services, to provide such services, Client further agreed to indemnify and hold Zeren Land Services, its managers, members and employees, harmless from and against all claims by all persons (including, but not limited to Client) of whatever kind or character arising out of the preparation and use of each such listing of mineral estate owners, to the extent that such claims exceed the actual amount paid to Client by Zeren Land Services, for such listing. Client specifically intends that both the foregoing limitation on liability and foregoing indemnification shall be binding and effective without regard to the cause of the claim, inaccuracy or defect, including, but not limited to, breach of representation, warranty or duty, any theory of tort or of breach of contract, or the fault or negligence of any party (including Zeren Land Services) of any kind or character (regardless of whether the fault or negligence is sole, joint, concurrent, simple or gross). Client's use of this listing evidences Client's acceptance of, and agreement with, this limitation on liability and the indemnification. ZEREN LAND SERVICES Date: April 11, 2024 Cynthia Zeren, as Presx ent Page 2 of 2 The names and addresses of any owner, operator of any oil and gas facilities, irrigation ditches/laterals, pipelines, overhead lines, railroad, etc. on the property, if applicable. NGL Water Solutions DJ, LLC 3773 Cherry Creek North Drive, Suite 1000, Denver, CO 80209 Union Rural Electric Association, Inc. now United Power 500 Cooperative Way, Brighton, CO, 80603 Brighton Lateral Ditch Company 500 S 4th Avenue, Utilities Brighton, CO 80601 Fulton Irrigating Ditch Company 25 S 4th Avenue, Brighton, CO 80601 Rmit _ re REPUBLIC 414 'SERVICES April 22, 2024 Dylan Van Demark Operations Manager Biochar Now Mr. Van Demark, I work with large manufacturers across the Front Range of Colorado. Many of my customers have large volumes of wood waste; pallets, crating dunnage etc. I am often asked to find a recycle option for these materials. With the current trend of many companies taking sustainability driven steps to divert more waste from landfills we need wood recycle options, in particular plywood, treated and painted wood. Since 2022, Republic Services had used Biochar Now in Berthoud as a wood recycling resource for our customers. We are excited about this new location and the expanded feed stock that your new locations will be able to receive. Republic Services strongly supports your plans for a new wood recycling location in Brighton. Brighton is much closer than Berthoud to many of the Denver manufacturers who wish to divert large volumes of wood waste from the landfill. This location will increase the value proposition for companies wanting to recycle wood waste in the Denver area, and we look forward to providing this cost- effective wood recycle option to our values customers. Neil Noble , Ers Manufacturing and Environmental Services Executive Republic Services 5075 E 74th Ave Denver CO 80022 SOURCE TEST REPORT 2021 EMISSIONS TESTING BIOCHAR NOW KILNS 56, 65 and 74 BERTHOUD, COLORADO Prepared For: Biochar Now P .O. Box 1832 Loveland, Colorado 80513 For Submittal To: Colorado Department of Public Health and Environment Air Pollution Control Division 4300 Cherry Creek Drive South Denver, CO 80246 P repared By: Montrose Air Quality Services, LLC 990 West 43rd Avenue Denver, Colorado 80211 Document Number: Test Dates: S ubmittal Date: LAcCREIDITIE-011 TO AIM a UV *Mit G P043AS -007255-RT-644 April 13th through 15th, 2021 May 13th, 2021 M MONTROSE AIR QUALITY SHRVICES Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report REVIEW AND CERTIFICATION All work, calculations, and other activities and tasks performed and presented in this document were carried out by me or under my direction and supervision. I hereby certify that, to the best of my knowledge, Montrose operated in conformance with the requirements of the Montrose Quality Management System and ASTM D7036-04 during this test project. S ignature: Name: Jeff Goldfine Date: Title: May 13, 2021 Client Project Manager I have reviewed, technically and editorially, details, calculations, results, conclusions, and other appropriate written materials contained herein. I hereby certify that, to the best of my knowledge, the presented material is authentic, accurate, and conforms to the requirements of the Montrose Quality Management System and ASTM D7036-04. S ignature: Name: Timothy Wojtach Date: Title' May 13, 2021 Account Manager FACILITY CERTIFICATION I have reviewed this document and agree that the information contained herein is true, accurate, and complete, to the best of my knowledge. S ignature: Name: Date: Title' G P043AS-007255-RT-644 2 of 381 I 4/\, MONTROSE AIR QUALIFY NI-RI:RA S Biochar Now — Berthoud, Colorado 2021 Emissions Source Test Report TABLE OF CONTENTS SECTION PAGE 1.0 INTRODUCTION 5 1.1 SUMMARY OF TEST PROGRAM 5 1.2 KEY PERSONNEL 11 2.0 PLANT AND SAMPLING LOCATION DESCRIPTIONS 13 2.1 PROCESS DESCRIPTION, OPERATION, AND CONTROL EQUIPMENT 13 2.2 FLUE GAS SAMPLING LOCATIONS 13 2.3 OPERATING CONDITIONS AND PROCESS DATA 13 3.0 SAMPLING AND ANALYTICAL PROCEDURES 14 3.1 TEST METHODS 14 3.1 TEST METHODS 14 3.1.1 EPA Method 1 14 3.1.2 EPA Method 2 14 3.1.3 EPA Methods 3A, 7E, and 10 14 3.1.4 EPA Method 4 16 3.1.5 EPA Methods 5 and 202 17 3.1.6 EPA Method 9 18 3.1.7 EPA Method 25A 18 3.1.8 EPA Method 308 19 4.0 TEST DISCUSSION AND RESULTS 21 4.1 FIELD TEST DEVIATIONS AND EXCEPTIONS 21 4.2 PRESENTATION OF RESULTS 21 5.0 INTERNAL QA/QC ACTIVITIES 28 5.1 QA/QC AUDITS 28 5.2 QA/QC DISCUSSION 28 5.3 QUALITY STATEMENT 29 LIST OF APPENDICES A FIELD DATA AND CALCULATIONS 30 A.1 Sampling Locations 31 A.2 Kiln 56 (Kiln 2) Field Data Sheets 33 A.3 Kiln 65 (Kiln 1) Field Data Sheets 44 A.4 Kiln 74 (Kiln 3) Field Data Sheets 55 A.5 Kiln 56 (Kiln 2) Instrumental Test Method Data 66 A.6 Kiln 65 (Kiln 1) Instrumental Test Method Data 73 A.7 Kiln 74 (Kiln 3) Instrumental Test Method Data 80 A.8 Kiln 56 (Kiln 2) Calculations/Results 87 A.9 Kiln 65 (Kiln 1) Calculations/Results 91 G P043AS-007255-RT-644 3 of 381 MONTROSE 4s", AIR (tth%I I IY SERVICES Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report A.10 Kiln 74 (Kiln 3) Calculations/Results 95 A.11 Example Calculations 99 B FACILITY PROCESS DATA 111 C LABORATORY ANALYSIS DATA 113 C.1 Particulate Matter Analyses 114 C.2 Methanol Analyses 124 D QUALITY ASSURANCE/QUALITY CONTROL 327 D.1 Units and Abbreviations 328 D.2 Manual Test Method QA/QC Data 336 D.3 Instrumental Test Method QA/QC Data 348 D.4 Accreditation Information/Certifications 370 D.5 Quality Assurance Program Summary and Equipment Calibration Schedule 376 LIST OF TABLES 1-1 SUMMARY OF TEST PROGRAM 6 1-2 SUMMARY OF AVERAGE EMISSIONS RESULTS - KILN 56 (KILN 2) 8 1-3 SUMMARY OF AVERAGE EMISSIONS RESULTS - KILN 65 (KILN 1) 9 1-4 SUMMARY OF AVERAGE EMISSIONS RESULTS - KILN 74 (KILN 3) 10 1-5 TEST PERSONNEL AND OBSERVERS 12 2-1 SAMPLING LOCATIONS 13 4-1 PM EMISSIONS and OPACITY OF EMISIONS RESULTS - KILN 56 (KILN 2) 22 4-2 NOx, CO, VOC and McOH EMISSIONS RESULTS - KILN 56 (KILN 2) 23 4-3 PM EMISSIONS and OPACITY OF EMISIONS RESULTS - KILN 65 (KILN 1) 24 4-4 NOx, CO, VOC and McOH EMISSIONS RESULTS - KILN 65 (KILN 1) 25 4-5 PM EMISSIONS and OPACITY OF EMISIONS RESULTS - KILN 74 (KILN 3) 26 4-6 NOx, CO, VOC and McOH EMISSIONS RESULTS - KILN 74 (KILN 3) 27 LIST OF FIGURES 3-1 US EPA METHODS 3A, 7E, 10, 25A - O2, CO2, NOx, CO and VOC SAMPLING TRAIN 16 3-2 US EPA METHOD 5/202 - PM/PM10/PM2.5 SAMPLING TRAIN 18 3-3 US EPA METHOD 308 - METHANOL SAMPLING TRAIN 20 G P043AS-007255-RT-644 4 of 381 4/\, MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report 1.0 INTRODUCTION 1.1 SUMMARY OF TEST PROGRAM 5280 Recycling Solutions has permission from the Colorado Department of Public Health and Environment, Air Pollution Control Division, to perform an emission test program on kilns using treated wood and contracted Montrose Air Quality Services, LLC to perform the emissions testing. The purpose of the test program is not to demonstrate compliance with any existing permits, including those at the test site. Instead, the test results will inform potential permitting to prepare biochar using treated wood as feedstock. The specific objectives were to: • Measure emissions of PM/PM,o/PM2.5from the outlet of three (3) kilns • Determine the opacity of emissions from the outlet of three (3) kilns • Measure emissions of NOx, CO and VOC from the outlet of three (3) kilns • Measure emissions of methanol McOH from the outlet of three (3) kilns • Conduct the test program with a focus on safety Montrose performed the tests to measure the emission parameters listed in Table 1-1. G P043AS-007255-RT-644 5 of 381 I1 MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report TABLE 1-1 SUMMARY OF TEST PROGRAM Source Test Dates Name Activity/ Parameters Test Methods Duration No. of Runs (Minutes) Kiln 65 April 13, 2021 p (Kiln 1) Perform emissions testing for PM/PM1o/PM2.5 Perform opacity observations Perform emissions testing for NOx, CO and VOC1 Perform emissions testing for methanol1 EPA 1, 2, 3 120 3A, 4, 5/202 EPA 9 3 62 EPA 3A, 7E, 3 120 10, 18, 25A EPA 308 3 120 Kiln 56 April 14, 2021 (Kiln 2) Perform emissions testing for PM/PM1o/PM2.5 Perform opacity observations Perform emissions testing for NOx, CO and VOC1 Perform emissions testing for methanol EPA 1, 2, 3 120 3A, 4, 5/202 EPA 9 3 62 EPA 3A, 7E, 3 120 10, 18, 25A EPA 308 3 120 Kiln 74 April 15, 2021 (Kiln 3) Perform emissions testing for PM/PM1o/PM2.5 Perform opacity observations Perform emissions testing for NOx, CO and VOC1 Perform emissions testing for methanol1 EPA 1, 2, 3 120 3A, 4, 5/202 EPA 9 3 62 EPA 3A, 7E, 3 120 10, 18, 25A EPA 308 3 120 I The gas volumetric flow rate, determined during the EPA Methods 5/202 testing, are used to calculate the emission rates of NOx, CO, VOC and Me0H. 2 The opacity of emissions are composed of 24, 15 -second averages, per run, and are reported as the highest six - minute average observed. G P043AS-007255-RT-644 6 of 381 I 4A, MONTROSE AIR QUALIFY %LKVR AS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report To simplify this report, a list of Units and Abbreviations is included in Appendix D.1. Throughout this report, chemical nomenclature, acronyms, and reporting units are not defined. Please refer to the list for specific details. This report presents the test results and supporting data, descriptions of the testing procedures, descriptions of the facility and sampling locations, and a summary of the quality assurance procedures used by Montrose. The average emission test results are summarized and compared to their respective permit limits in Table 1-2. Detailed results for individual test runs can be found in Section 4.0. All supporting data can be found in the appendices. The testing was conducted by the Montrose personnel listed in Table 1-3. The tests were conducted according to the test protocol no. GPo43AS-007255-PP-299, dated March 10th, 2021. G P043AS-007255-RT-644 7 of 381 I 4/\, MONTROSE AIR QUALIFY NI-RI:RA S Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report TABLE 1-2 SUMMARY OF AVERAGE EMISSIONS RESULTS - KILN 56 (KILN 2) APRIL 13th, 2021 Parameter/Units Average Results Filterable Particulate Matter (PM) lb/hr lb/ton Particulate Matter (PM1o) lb/hr lb/ton Particulate Matter (PM2.5) lb/hr lb/ton Total Particulate Matter (PM/PMIo/PM2.5) lb/hr lb/ton Opacity3 Nitrogen Oxides (NOX) lb/hr lb/ton Carbon Monoxide (CO) lb/hr lb/ton Total Hydrocarbons, as Propane (VOC) lb/hr lb/ton Methanol (MeOH) lb/hr lb/ton 3 Opacity results are calculated as the highest six -minute average observed. 0.00677 0.0562 0.00816 0.0677 0.00687 0.0570 0.0104 0.0862 0.0 0.425 3.53 0.179 1.49 <0.00497 <0.0412 <8.99 x 10-4 <7.47 x 10-3 G P043AS-007255-RT-644 8 of 381 I 4A, MONTROSE AIR QUALIFY NI-RI:RA S Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report TABLE 1-3 SUMMARY OF AVERAGE EMISSIONS RESULTS - KILN 65 (KILN 1) APRIL 14th, 2021 Parameter/Units Average Results Filterable Particulate Matter (PM) lb/hr lb/ton Particulate Matter (PM1o) lb/hr lb/ton Particulate Matter (PM2.5) lb/hr lb/ton Total Particulate Matter (PM/PMIo/PM2.5) lb/hr lb/ton Opacity'. Nitrogen Oxides (NOX) lb/hr lb/ton Carbon Monoxide (CO) lb/hr lb/ton Total Hydrocarbons, as Propane (VOC) lb/hr lb/ton Methanol (MeOH) lb/hr lb/ton 4 Opacity results are calculated as the highest six -minute average observed. 0.0109 0.102 0.0121 0.113 0.0100 0.0941 0.0157 0.147 0.0 0.417 3.91 0.0598 0.561 <0.00426 <0.0400 <4.36 x 10-4 <4.09 x 10-3 G P043AS-007255-RT-644 9 of 381 I 4A, MONTROSE AIR QUALIFY NI-RI:RA S Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report TABLE 1-4 SUMMARY OF AVERAGE EMISSIONS RESULTS - KILN 74 (KILN 3) APRIL 15th, 2021 Parameter/Units Average Results Total Particulate Matter (PM) lb/hr lb/ton Particulate Matter (PM1o) lb/hr lb/ton Particulate Matter (PM2.5) lb/hr lb/ton Total Particulate Matter (PM/PMIo/PM2.5) lb/hr lb/ton Opacity5 Nitrogen Oxides (NOX) lb/hr lb/ton Carbon Monoxide (CO) lb/hr lb/ton Total Hydrocarbons, as Propane (VOC) lb/hr lb/ton Methanol (MeOH) lb/hr lb/ton 5 Opacity results are calculated as the highest six -minute average observed. 0.00691 0.0604 0.0108 0.0942 0.00948 0.0828 0.0131 0.114 0.0 0.363 3.17 0.219 1.91 <0.00617 <0.0538 <0.00124 <0.0106 G P043AS-007255-RT-644 10 of 381 I 4/\, MONTROSE AIR QUALIFY NI-RI:RA S Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report 1.2 KEY PERSONNEL A list of project participants is included below: Facility Information Source Location: Biochar Now, LLC Berthoud Plant 19500 Weld County Road 7 Berthoud, Colorado 80513 Project Contact: Jordan Wieda Role: Managing Director Telephone: 970-443-4896 Email: Jordan.wieda@biocharnow.com Agency Information Regulatory Agency: Colorado Department of Public Health and Environment, Air Pollution Control Division Agency Contact: Jeffry Bishop Telephone: 303-692-3106 Email: Jeffrey.Bishop@state.co.us Testing Company Information Testing Firm: Montrose Air Quality Services, LLC (Montrose) Contact: Jeff Goldfine Title: Client Project Manager Telephone: 312-919-2609 Email: JGoldfine@montrose-env.com Laboratory Information, EPA Methods 5/202 Laboratory: Montrose Air Quality Services, LLC City, State: Denver, Colorado Laboratory Information, EPA Method 308 Laboratory: Enthalpy Analytical, LLC City, State: Durham, North Carolina G P043AS-007255-RT-644 11 of 381 4/\, MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Test personnel and observers are summarized in Table 1-5. TABLE 1-5 TEST PERSONNEL AND OBSERVERS Name Affiliation Role/Responsibility Jeff Goldfine David Smith Tyler Conway Timothy Wojtach Jordan Wieda Jon Haugen Montrose Montrose Montrose Montrose Biochar Now Biochar Now Project Manager/Field Team Leader/Qualified Individual (Q0/Trailer operator/Sample recovery/Sample train operator Sample recovery/Sample train operator Sample recovery/Sample train operator/Certified VE reader Calculations and report preparation Observer/Client Liaison/Test Coordinator Observer/Client Liaison/Test Coordinator G P043AS-007255-RT-644 12 of 381 4/\, MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report 2.0 PLANT AND SAMPLING LOCATION DESCRIPTIONS 2.1 PROCESS DESCRIPTION, OPERATION, AND CONTROL EQUIPMENT Biochar Now, LLC operates a biochar production facility and has offered the use of three kilns to be used for the treated wood data collection. The pilot batch test results will be used to prepare a permit application for the processing of feedstock described as treated wood/painted wood. The permit application will be based on similar equipment and operating conditions used for the pilot batch test. Each operating kiln is equipped with an afterburner stack for emission control. Treated wood will be processed under low oxygen conditions to convert the wood to biochar, a charcoal- like material. Off gasses generated during the process pass through an afterburner for emission control before being emitted to the atmosphere. Prior to the commencement of testing, three kilns are loaded with treated wood. The wood mass loaded into each kiln is recorded in order to calculate emission factors in units of "lb pollutant/ton wood". The three kilns are transported to available locations on the firing line and each is fitted with a stack. Connections are made from the kiln/stack to the process control system and to utilities. The kilns will thus be ready for the stack emission. The kilns are identical in mechanical and electric design, as are the stacks. While kilns and stacks include identifying marks, these are for maintenance purposes only. The placement of a kiln on the firing line is based on availability of space. Thus kilns, stack, and firing line location are interchangeable factors that have no effect on the emissions during processing. 2.2 FLUE GAS SAMPLING LOCATIONS Information regarding the sampling locations is presented in Table 2-1. TABLE 2-1 SAMPLING LOCATIONS Stack Distance from Nearest Disturbance Inside Sampling Diameter Downstream Upstream Number of Traverse Location (in.) EPA "B" (in./dia.) EPA "A" (in./dia.) Points Kilns 56, 65 and 74 (Identical) 24.0 ≥48.0 / ≥2.0 >12.0 / ≥0.5 Isoki netic: 24 (12/port) 2.3 OPERATING CONDITIONS AND PROCESS DATA Emission tests are performed while the sources and air pollution control devices are operating. Plant personnel are responsible for establishing the test conditions and collecting all applicable unit -operating data. Data collected includes the following parameters: • Initial load, lbs G P043AS-007255-RT-644 13 of 381 I 4/\, MONTROSE AIR QUALIFY NI-RI:RA S Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report 3.0 SAMPLING AND ANALYTICAL PROCEDURES 3.1 TEST METHODS The test methods for this test program were presented previously in Table 1-1. Additional information regarding specific applications or modifications to standard procedures is presented below. 3.1 TEST METHODS The test methods for this test program were presented previously in Table 1-1. Additional information regarding specific applications or modifications to standard procedures is presented below. 3.1.1 EPA Method 1, Sample and Velocity Traverses for Stationary Sources EPA Method 1 is used to assure that representative measurements of volumetric flow rate are obtained by dividing the cross-section of the stack or duct into equal areas, and then locating a traverse point within each of the equal areas. Acceptable sample locations must be located at least two stack or duct equivalent diameters downstream from a flow disturbance and one-half equivalent diameter upstream from a flow disturbance. 3.1.2 EPA Method 2, Determination of Stack Gas Velocity and Volumetric Flow Rate (Type S Pitot Tube) EPA Method 2 is used to measure the gas velocity using an S -type pitot tube connected to a pressure measurement device, and to measure the gas temperature using a calibrated thermocouple connected to a thermocouple indicator. Typically, Type S (Stausscheibe) pitot tubes conforming to the geometric specifications in the test method are used, along with an inclined manometer. The measurements are made at traverse points specified by EPA Method 1. The molecular weight of the gas stream is determined from independent measurements of O2, CO2, and moisture. The stack gas volumetric flow rate is calculated using the measured average velocity head, the area of the duct at the measurement plane, the measured average temperature, the measured duct static pressure, the molecular weight of the gas stream, and the measured moisture. Pertinent information regarding the performance of the method is presented below: o S -type pitot tube coefficient is 0.84 o Shortridge multimeter was used to measure velocity The sampling apparatus is detailed in Figure 3-2, as part of the EPA Methods 5/202 sampling train. 3.1.3 EPA Methods 3A, 7E, and 10, Determination of Oxygen, Carbon Dioxide, Nitrogen Oxides, and Carbon Monoxide Concentrations in Emissions from Stationary Sources (Instrumental Analyzer Procedures) Concentrations of O2, CO2, NOx, and CO are measured simultaneously using EPA Methods 3A, 7E, and 10, which are instrumental test methods. Conditioned gas is sent to a series of analyzers G P043AS-007255-RT-644 14 of 381 4/\, MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report to measure the gaseous emission concentrations. The performance requirements of the method must be met to validate the data. Pertinent information regarding the performance of the method is presented below: o A dry extractive sampling system is used to report emissions on a dry basis o A paramagnetic analyzer is used to measure O2 o A nondispersive infrared analyzer is used to measure CO2 o A chemiluminescent analyzer is used to measure NOR o A gas filter correlation nondispersive infrared analyzer is used to measure CO o Calibration span values were 0-21.73% O2, 0-17.48% CO2, 0-246.7 ppmv NOR, and 0-2,490 ppmv CO (Kiln 74) and 0-4,536 ppmv CO (Kilns 56 and 65) o Target Sample Duration: 120 minutes The typical sampling system is detailed in Figure 3-1. G P043AS-007255-RT-644 15 of 381 I 4/\, MONTROSE AIR QUALIFY NI-RI:RA S Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report FIGURE 3-1 US EPA METHODS 3A, 7E, 10, 25A - O2, CO2, NOx, CO and VOC SAMPLING TRAIN STACK GAS STACK WALL DATA OUTPUT SIGNAL r 1 SIGNAL SIGNAL I DAS SAMPLE PROBE HEATED FILTER HEATED SAMPLE LINE 1 SIGNAL SIGNAL VOC Analyzer with Pump Oz ANALYZER OO2 ANALYZER NO( ANALYZER CO ANALYZER EPA Protocol Calibration Gases Exhaust Sample / Calibration Gas low- Exhaust Sample / Calibration Gas pr- Exhaust Sample / Calibration Gas Exhaust Sample / Calibration Gas Exhaust Sample / Calibration Gas "ANALYZER` ROTAMETERS WITH FLOW CONTROL VALVES "BIAS" ROTAMETER WITH FLOW CONTROL VALVE CALIBRATION GAS LINE MASS FLOW CONTROLLER I CALIBRATION GAS MANIFOLD THREE WAY VALVE 0 BY-PASS HEATED SAMPLE LINE "SAMPLE AND "BY-PASS" ROTAMETERS WITH FLOW CONTROL VALVES SAMPLE CONDITIONING SYSTEM WITH PUMP 3.1.4 EPA Method 4, Determination of Moisture Content in Stack Gas EPA Method 4 is a manual, non-isokinetic method used to measure the moisture content of gas streams. Gas is sampled at a constant sampling rate through a probe and impinger train. Moisture is removed using a series of pre -weighed impingers containing methodology -specific liquids and silica gel immersed in an ice water bath. The impingers are weighed after each run to determine the percent moisture. Pertinent information regarding the performance of the method is presented below: 0 0 0 0 Condensed water is measured gravimetrically Moisture sampling is performed as part of the pollutant sample trains Target Sample Duration: 120 minutes Minimum Required Sample Volume: 21 scf The sampling apparatus is detailed in Figure 3-2, as part of the EPA Methods 5/202 sampling train. G P043AS-007255-RT-644 16 of 381 4/\, MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report 3.1.5 EPA Methods 5 and 202, Determination of Particulate Matter from Stationary Sources and Dry Impinger Method for Determining Condensable Particulate Emissions from Stationary Sources EPA Methods 5 and 202 are manual, isokinetic methods used to measure FPM and CPM (PM/PM10/PM2.$) emissions. The methods are performed in conjunction with EPA Methods 1, 2, 3A and 4. The stack gas is sampled through a nozzle, probe, heated filter, unheated CPM filter, condenser, and impinger train. FPM is collected from the probe and heater filter. CPM is collected from the unheated CPM filter and the impinger train. The samples are analyzed gravimetrically. The sum of FPM and CPM represents TPM. The FPM, CPM, and TPM results are reported in emission concentration and emission rate units. Pertinent information regarding the performance of the method is presented below: o Due to high stack temperatures, EPA Method 201A can not be used to directly determine PM10 and PM2.5 results. The PN/lio and PM2.5 emissions are calculated based on the ton/yr emission limits presented in Construction Permit No. 15WE1395, Issuance 5, Condition 2, Annual Limits. A PM10 e mission factor of 67% of total filterable PM, and PM2.5 emission factor of 48% of total filterable PM are used to calculate filterable PM10 and PM2.5 e missions. Condensable particulate matter (CPM) results are included in the calculation of PM10 and PM2.5 total emissions. o Quartz -glass sample nozzles and probe liners are used o Condensed water is measured gravimetrically o Target Sample Duration: 120 minutes o Target Sample Volume: 60 dscf o Analytical Laboratory: Montrose Air Quality Services, LLC, Denver, Colorado The typical sampling system is detailed in Figure 3-2. G P043AS-007255-RT-644 17 of 381 I 4/\, MONTROSE AIR QUALIFY NI-RI:RA S Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report FIGURE 3-2 US EPA METHOD 5/202 - PM/PM1o/PM2.5SAMPLING TRAIN ThERMCCCURJES THERMCCCUFLE HEATED FRCBE NOZZLE c � TYFE "S" ATOT MANOME I ER r i I r FILTER I -OLDER V r CCNCENSER HEATED AREA TI-ERIVCCCUPLE FILTER I-(CLDER- THERMOCCUPLE r MANOMETER 1 > o h PATS' IN Empty i WATER BATH Errpty (modified / no tip) (modified / no tip) C) THERMCCCUFLE 0 ❑Ril O ❑ El ❑ ❑ n ❑ LSO _A_— ICE _ D 0 n BATH 0000 1C0 rri I -t20 (r►cdfied/notip) 2CG3COg Silica CeI (modified / no tip) BY-PASS VALVE (fine adjust) VPCULN1 GAUGE TIWLES <1- CRI A CE r }I I� (4 j CAS EXIT CRY GAS f1 \ AIRTIGHT NETER 1 MAI N VALVE (coarse adjust) V\ VPCUUVI LI ICE ADA TCR VACUUM LINE 3.1.6 EPA Method 9, Visual Determination of the Opacity of Emissions EPA Method 9 is used to observe the visual opacity of emissions (opacity). The observer stands at a distance sufficient to provide a clear view of the emissions with the sun oriented in the 140° sector to their back. The line of vision is perpendicular to the plume direction and does not include more than one plume diameter. Observations are recorded at 15 -second intervals and are made to the nearest 5% opacity. The qualified observer is certified according to the requirements of EPA Method 9, section 3.1. o Each Method 9 observation period was six minutes in duration, composed of 24, 15 -second averages. 3.1.7 EPA Method 25A, Determination of Total Gaseous Organic Concentration Using a Flame Ionization Analyzer and EPA Method 18, Measurement of Gaseous Organic Compound Emissions by Gas Chromatography EPA Method 25A is an instrumental test method used to measure the concentration of THC in stack gas. A gas sample is extracted from the source through a heated sample line and glass G P043AS-007255-RT-644 18 of 381 4/\, MONTROSE I AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report fiber filter to an FIA. Results are reported as volume concentration equivalents of the calibration gas or as carbon equivalents. Pertinent information regarding the performance of the method is presented below: o Results are reported in terms of propane o Span value for THC is 100 ppmvw o Since THC emissions demonstrated results near the detection limit, analysis of IGS bags for methane and ethane was not performed o Target Analytes: Total hydrocarbons (VOC) o Target Sample Duration: 120 minutes The typical sampling system is detailed in Figure 3-1. 31.8 EPA Method 308, Procedure for Determination of Methanol Emission from Stationary Sources EPA Method 308 is a manual method used to measure methanol emissions. A gas sample is extracted from the sampling point in the stack. The methanol is collected in deionized distilled water and adsorbed on silica gel. The sample is returned to the laboratory where the methanol in the water fraction is separated from other organic compounds with a gas chromatograph (GC) and is then measured by a flame ionization detector (FID). The fraction adsorbed on silica gel is extracted with deionized distilled water and is then separated and measured by GC/FID. Pertinent information regarding the performance of the method is presented below: o Target Sample Duration: 120 minutes o Analytical Laboratory: Enthalpy Analytical, LLC, Durham, North Carolina The typical sampling system is detailed in Figure 3-3. G P043AS-007255-RT-644 19 of 381 4/\, MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report FIGURE 3-3 US EPA METHOD 308 - METHANOL SAMPLING TRAIN ‘4 Sitrc C,erTube 1r UAA31Br _ T it I 1►I d Fyn t dhl eb.c. " I - Jr__ I -'-t ftt "Li �lA�3lti• n:1 Errseb YuIuiun1 Ssisterig Tern tature. ; ti.. , / c O Drys Flow; et r Gmi Merry Methanol EPA Method Sarnptinq I Train MONTROSE I All flV111l1 s17'iI '1 G P043AS-007255-RT-644 20 of 381 4,\I MONTROSE AIR QUALIFY NI -c VICI: Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report 4.0 TEST DISCUSSION AND RESULTS 4.1 FIELD TEST DEVIATIONS AND EXCEPTIONS Due to high stack temperatures, EPA Method 201A can not be used to directly determine PM10 and PM2.5 results. The PM10 and PM2.5 emissions are calculated based on the ton/yr emission limits presented in Construction Permit No. 15WE1395, Issuance 5, Condition 2, Annual Limits. A PM10 emission factor of 67% of filterable PM, and PM2.5 emission factor of 48% of filterable PM are to be used to calculate filterable PM10 and PM2.5 emissions. Condensable particulate matter (CPM) results are included in the calculation of PM10 and PM2.5 total emissions. Methanol results are calculated using the concentration corrected for spike recovery. No other field deviations or exceptions from the test plan or test methods were reported by the test crew during this test program. 4.2 PRESENTATION OF RESULTS The average results are compared to the permit limits in Tables 1-2 through 1-4. The results of individual compliance test runs performed are presented in Tables 4-1 through 4-6. Emissions are reported in units consistent with those in the applicable regulations or requirements. Additional information is included in the appendices as presented in the Table of Contents. G P043AS-007255-RT-644 21 of 381 I 4/\, MONTROSE AIR QUALIFY NI-RI:RA S Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report TABLE 4-1 PM EMISSIONS and OPACITY OF EMISIONS RESULTS - KILN 56 (KILN 2) Run Number 1 2 3 Average Date Time P rocess Data Initial Load, lb Test duration, hr Sampling & Flue Gas Parameters O2, % volume dry CO2, % volume dry flue gas temperature, °F moisture content, % volume volumetric flow rate, dscfm Filterable PM Results gr/dscf lb/hr lb/ton raw feed Condensable PM Results gr/dscf lb/hr lb/ton raw feed P M10 Results lb/hr lb/ton raw feed P M2.5 Results lb/hr lb/ton raw feed Total PM/PM1o/PM2.5 Results gr/dscf lb/hr lb/ton raw feed Opacity Results Opacity 4/14/2021 8:28-10:40 EMIEME 9.54 9.87 1,189 13.6 422 0.00245 0.00885 0.0735 0.000776 0.00280 0.0233 0.00873 0.0725 0.00705 0.0585 0.00322 0.0117 0.0967 0 4/14/2021 11:47-13:58 11.2 8.91 1,276 13.2 469 0.00128 0.00516 0.0429 0.00134 0.00539 0.0448 0.00885 0.0735 0.00787 0.0653 0.00263 0.0106 0.0876 0 4/14/2021 15:00-17:16 8.99 9.64 891 8.27 556 0.00132 0.00628 0.0522 0.000561 0.00268 0.0222 0.00689 0.0572 0.00569 0.0473 0.00188 0.00896 0.0744 0 MOM 2,120 8.80 9.91 9.47 1,118 11.7 482 0.00188 0.00677 0.0562 0.000892 0.00362 0.0301 0.00816 0.0677 0.00687 0.0570 0.00258 0.0104 0.0862 0 G P043AS-007255-RT-644 22 of 381 4/\, MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report TABLE 4-2 NOx, CO, VOC and McOH EMISSIONS RESULTS - KILN 56 (KILN 2) Run Number 1 2 3 Average Date Time Process Data Initial Load, lb Test duration, hr Sampling & Flue Gas Parameters O2, % volume dry CO2, % volume dry flue gas temperature, °F moisture content, % volume volumetric flow rate, dscfm Nitrogen Oxides (NOx) ppmvd lb/hr lb/ton raw feed Carbon Monoxide (CO) ppmvd lb/hr lb/ton raw feed 4/14/2021 8:28-10:40 EMIEME 9.54 9.87 1,189 13.6 422 96.4 0.291 2.42 220 0.405 3.36 Total Hydrocarbons, as Propane (VOC) ppmvd 2.43 lb/hr 0.00703 lb/ton raw feed 0.0584 Methanol (MeOH) ppmvd lb/hr lb/ton raw feed 0.617 0.00130 0.0108 4/14/2021 11:47-13:58 11.2 8.91 1,276 13.2 469 144 0.482 4.01 50.9 0.104 0.864 <1.2 <0.00371 <0.0308 <0.276 <6.47 x 10-4 <5.37 x 10-3 4/14/2021 15:00-17:16 8.99 9.64 891 8.27 556 126 0.500 4.15 12.1 0.0293 0.243 <1.1 <0.00416 <0.0346 <0.271 <7.52 x 10-4 <6.25 x 10-3 MOM 2,120 8.80 9.91 9.47 1,118 11.7 482 122 0.425 3.53 94.3 0.179 1.49 <1.56 <0.00497 <0.0412 <0.388 <8.99 x 10-4 <7.47 x 10-3 G P043AS-007255-RT-644 23 of 381 4/\, MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report TABLE 4-3 PM EMISSIONS and OPACITY OF EMISIONS RESULTS - KILN 65 (KILN 1) Run Number 1 2 3 Average Date Time P rocess Data Initial Load, lb Test duration, hr Sampling & Flue Gas Parameters O2, % volume dry CO2, % volume dry flue gas temperature, °F moisture content, % volume volumetric flow rate, dscfm Filterable PM Results gr/dscf lb/hr lb/ton raw feed Condensable PM Results gr/dscf lb/hr lb/ton raw feed P Mlo Results lb/hr lb/hr P M2.5 Results lb/hr lb/hr Total PM/PMlo/PM2.5 Results gr/dscf lb/hr lb/ton raw feed Opacity Results Opacity 4/13/2021 8:11-10:34 MINIM 10.1 8.77 1,068 12.3 496 0.00413 0.0175 0.165 0.000753 0.00320 0.0300 0.0149 0.140 0.0116 0.109 0.00488 0.0207 0.195 0 4/13/2021 11:57-14:09 11.0 8.68 1,226 12.5 624 0.00152 0.00815 0.0765 0.00127 0.00681 0.0639 0.0123 0.115 0.0107 0.101 0.00280 0.0150 0.140 0 4/13/2021 15:25-17:45 11.4 7.68 1,162 10.5 522 0.00155 0.00692 0.0650 0.000989 0.00692 0.0415 0.00906 0.0850 0.00775 0.0727 0.00254 0.0113 0.106 0 MOM 2,040 9.57 10.8 8.38 1,152 11.8 547 0.00240 0.0109 0.102 0.00101 0.00481 0.0451 0.0121 0.113 0.0100 0.0941 0.00341 0.0157 0.147 0 G P043AS-007255-RT-644 24 of 381 4/\, MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report TABLE 4-4 NOx, CO, VOC and McOH EMISSIONS RESULTS - KILN 65 (KILN 1) Run Number 1 2 3 Average Date Time Process Data Initial Load, lb Test duration, hr Sampling & Flue Gas Parameters O2, % volume dry CO2, % volume dry flue gas temperature, °F moisture content, % volume volumetric flow rate, dscfm Nitrogen Oxides (NOx) ppmvd lb/hr lb/ton raw feed Carbon Monoxide (CO) ppmvd lb/hr lb/ton raw feed 4/13/2021 8:11-10:34 MINIM 10.1 8.77 1,068 12.3 496 72.7 0.258 2.42 52.8 0.114 1.07 Total Hydrocarbons, as Propane (VOC) ppmvd <1.1 lb/hr <0.00388 lb/ton raw feed <0.0364 Methanol (MeOH) ppmvd lb/hr lb/ton raw feed <0.183 <4.21 x 10-4 <3.95 x 10-3 4/13/2021 11:57-14:09 11.0 8.68 1,226 12.5 624 116 0.519 4.87 11.9 0.0324 0.304 <1.1 <0.00490 <0.0459 <0.186 <4.61 x 10-4 <4.32 x 10-3 4/13/2021 15:25-17:45 11.4 7.68 1,162 10.5 522 127 0.474 4.44 14.4 0.0327 0.307 <1.1 <0.00400 <0.0376 <0.173 <4.27 x 10-4 <4.01 x 10-3 MOM 2,040 9.57 10.8 8.38 1,152 11.8 547 105 0.417 3.91 26.4 0.0598 0.561 <1.1 <0.00426 <0.0400 <0.181 <4.36 x 10-4 <4.09 x 10-3 G P043AS-007255-RT-644 25 of 381 4/\, MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report TABLE 4-5 PM EMISSIONS and OPACITY OF EMISIONS RESULTS - KILN 74 (KILN 3) Run Number 1 2 3 Average Date Time P rocess Data Initial Load, lb Test duration, hr Sampling & Flue Gas Parameters O2, % volume dry CO2, % volume dry flue gas temperature, °F moisture content, % volume volumetric flow rate, dscfm Filterable PM Results gr/dscf lb/hr lb/ton raw feed Condensable PM Results gr/dscf lb/hr lb/ton raw feed P M10 Results lb/hr lb/ton raw feed P M2.5 Results lb/hr lb/ton raw feed Total PM/PM1o/PM2.5 Results gr/dscf lb/hr lb/ton raw feed Opacity Results Opacity 4/15/2021 10:20-12:44 MIME 11.5 8.09 1,233 14.9 460 0.00263 0.0104 0.0906 0.00112 0.00440 0.0384 0.0113 0.0991 0.00938 0.0819 0.00375 0.0148 0.129 0 4/15/2021 13:50-15:58 11.7 8.22 1,273 13.4 496 0.00152 0.00646 0.0565 0.00237 0.0101 0.0879 0.0144 0.126 0.0132 0.115 0.00389 0.0165 0.144 0 4/15/2021 16:58-19:04 11.0 7.52 1,019 10.0 494 0.000922 0.00390 0.0341 0.000948 0.00401 0.0350 0.00663 0.0579 0.00589 0.0514 0.00187 0.00792 0.0691 0 MOM 2,000 8.73 11.4 7.98 1,175 12.8 483 0.00169 0.00691 0.0604 0.00148 0.00616 0.0538 0.0108 0.0942 0.00948 0.0828 0.00317 0.0131 0.114 0 G P043AS-007255-RT-644 26 of 381 4/\, MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report TABLE 4-6 NOx, CO, VOC and McOH EMISSIONS RESULTS - KILN 74 (KILN 3) Run Number 1 2 3 Average Date Time Process Data Initial Load, lb Test duration, hr Sampling & Flue Gas Parameters O2, % volume dry CO2, % volume dry flue gas temperature, °F moisture content, % volume volumetric flow rate, dscfm Nitrogen Oxides (NOx) ppmvd lb/hr lb/ton raw feed Carbon Monoxide (CO) ppmvd lb/hr lb/ton raw feed 4/15/2021 10:20-12:44 MIME 11.5 8.09 1,233 14.9 460 104 0.342 2.98 192 0.385 3.36 Total Hydrocarbons, as Propane (VOC) ppmvd 3.10 lb/hr 0.00979 lb/ton raw feed 0.0855 Methanol (MeOH) ppmvd lb/hr lb/ton raw feed 1.40 0.00321 0.0280 4/15/2021 13:50-15:58 11.7 8.22 1,273 13.4 496 125 0.444 3.88 109 0.235 2.05 <1.2 <0.00394 <0.0344 <0.151 <3.74 x 10-4 <3.26 x 10-3 4/15/2021 16:58-19:04 11.0 7.52 1,019 10.0 494 85.2 0.302 2.63 16.8 0.0361 0.315 1.41 0.00477 0.0417 <0.0572 <1.41 x 10-4 <1.23 x 10-3 MOM 2,000 8.73 11.4 7.98 1,175 12.8 483 105 0.363 3.17 106 0.219 1.91 <1.89 <0.00617 <0.0538 <0.536 <0.00124 <0.0108 G P043AS-007255-RT-644 27 of 381 4/\, MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report 5.0 INTERNAL QA/QC ACTIVITIES 5.1 QA/QC AUDITS The meter boxes and sampling trains used during sampling performed within the requirements of their respective methods. All applicable post-test leak checks, minimum metered volumes, minimum sample durations, and percent isokinetics met the applicable QA/QC criteria. EPA Method 3A, 7E, and 10 calibration audits were all within the measurement system performance specifications for the calibration drift checks, system calibration bias checks, and calibration error checks. EPA Method 25A FIA calibration audits were within the measurement system performance specifications for the calibration drift checks and calibration error checks. The NO2 to NO converter efficiency check of the analyzer was conducted per the procedures in EPA Method 7E, Section 8.2.4. The conversion efficiency met the criteria. EPA Method 9 was performed by a certified Visible Emissions Evaluator. For quality assurance, the observer obtained a view of the emissions with the best available contrasting background and with the sun oriented in the 140° sector to their back. Readings were taken every 15 seconds and made to the nearest 5% opacity. EPA Method 5 analytical QA/QC results are included in the laboratory report. The method QA/QC criteria were met, except if noted in Section 5.2. An EPA Method 5 reagent blank was analyzed. The maximum allowable amount that can be subtracted is 0.001 % of the weight of the acetone blank. The blank did not exceed the maximum residue allowed. EPA Method 202 analytical QA/QC results are included in the laboratory report. The method QA/QC criteria were met. An EPA Method 202 Field Train Recovery Blank (FTRB) was performed for each source category. The maximum allowable amount that can be subtracted is 0.002 g (2.0 mg). For this project, the FTRB had a mass of 1.9 mg, and 1.9 mg was subtracted. EPA Method 308 analytical QA/QC results are included in the laboratory report. The method QA/QC criteria were met, except where noted in Section 5.2. 5.2 QA/QC DISCUSSION The EPA Method 308 methanol spikes fell below the criteria outlined in 40 CFR Part 63, Appendix A, Method 30, §13.0.b.i. The concentrations reported in the results are corrected for the actual spike recovery. All other QA/QC criteria were met during this test program. G P043AS-007255-RT-644 28 of 381 4/\, MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report 5.3 QUALITY STATEMENT Montrose is qualified to conduct this test program and has established a quality management system that led to accreditation with ASTM Standard D7036-04 (Standard Practice for Competence of Air Emission Testing Bodies). Montrose participates in annual functional assessments for conformance with D7036-04 which are conducted by the American Association for Laboratory Accreditation (A2LA). All testing performed by Montrose is supervised on site by at least one Qualified Individual (QI) as defined in D7036-04 Section 8.3.2. Data quality objectives for estimating measurement uncertainty within the documented limits in the test methods are met by using approved test protocols for each project as defined in D7036-04 Sections 7.2.1 and 12.10. Additional quality assurance information is included in the report appendices. The content of this report is modeled after the EPA Emission Measurement Center Guideline Document (GD- 043). G P043AS-007255-RT-644 29 of 381 4/\, MONTROSE AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report APPENDIX A FIELD DATA AND CALCULATIONS G P043AS-007255-RT-644 30 of 381 MONTROSE E AIR QUALIFY tiERvIEFS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix Al Sampling Locations G P043AS-007255-RT-644 31 of 381 ti\ MONTROSE I AIR QUALIFY NI-RI:RAS Port 1 i 12 Disturbance • t i / j f • • i" • • • h A r'I Measurement I • • • • • • • • • • • • Port Site H 1 12 H 2 1 \ • • • • // N. \ • Disturbance Diameter (in.) 24.0 A (Duct Diameters) ≥0.5 Distance Distance B (Duct Diameters) ≥2.0 Distance Wall (in.) Point From 1 23.0 2 22.4 3 21.2 4 19.8 5 18.0 6 15.5 8.5 7 8 6.0 9 4.2 10 2.8 11 1.6 12 1.0 Cross Section of the Kiln Locations Test with Points Traverse Biochar Now Berthoud, Colorado MONTROSE AIR lltiaAt l i' '. i :111r' i_ EN G P043AS-007255-RT-644 32 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix A.2 Kiln 56 (Kiln 2) Field Data Sheets G P043AS-007255-RT-644 33 of 381 4A, MONTROSE I AIR QUALIFY tiERvIEFS MONTROSE O E ili.�. MR QUALITY SERVICES Metro Field Datashset (Is°kinetic) Page of ALT 011 IC ID: Ambient °F Ref. ° F 'Project Information Sa..mptin.g Conditions I Stack 01/3, - - Date ' ) . ' , , protect# P - 00 2 Static l resaure„ lip. H2O . + ' /' AmbientTempF35]ff2q ; Probe i custorneriFacilil Or _,i!' ; - no Barometric Pressure. In. Hg if a Ref" Barometer ID . A ip.. . 4 Filter Box 11,13. a 1 Unit ID/Sample Location Wind Speed !'fire tIon Precipitation, V fitfrityThe% Filter Exit Roils operator J'S Probe I Filter Term Range °F alai S 25 - ' Sampling Equipment IDa Calibration Equipment Checks Pre E Post Meter outlet � k . 4 , _ , - trnpinger exit '� 99 pilot � pass in. H20 le� f x � � eCer' r ,, . Other Umbilical ID le,90. 4.r Meterbax Alliai in, H2O 1" 79 Pilot (4 pass ,F. , in.1120 [i"' f, " No ID Nozzle diameter, Dry, in. Pltot visual inspection pass jalass JirPar, Ref, Thermometer ID - Continuity' Check 0 Continuity wl Proper Polarity Pilot / Probe ID 693,11Vbere5ff -445 Pilot coefficient, Cp O. 8 Nozzle visual rospection pass sErePass 2'ipass Notes: Manometer SID ALI2 172 soli ic Manometer zero and level g Meter, cfrn © in. Hg Lot@ kerb at ato © ' e — K -Fa Intermediate leak check volume), ft3 / Traverse I # Elapsed Time Clock l^�r Time 0GM' Reading, gym, in Heed, H OfifiCO Pressure Stack Tampa F �y Pro''be Temp, a F Filter Temp, if Impinger Tamp, Exit F Dry Gas Meter ,, Temperature, F a "'acuumPaint Pump In, HI 9 Target kctuai # ox Extt moat Outlet , aWilaalaINFAIIKEIMI 5 . ' / ' tip' ' CA' 41 4 I ' ,� I Pat"linallafralliallall 0 61 0 ell lierialnnt illinn I- PERM rte, c �'" 7_ 2 CP ,fir ! O L �.++R' r i �,rr r - ME r 0ci, 0 05 et or6 in s ' 1. to . O 0 Cir O _ SG% 1 i . O l I Orr 7csi 7 1 • " 12.45,3 s OP 7 . 4 if Z 26 e ' I d 0023 owl' ..r I 9 lei (to . tilst / 2, 83 12 1 / 3 2 1 2 . cro qi ar 77 6 ff.- o C /O 1- 2 2 Tit _3_ Oi ,s! iCo 41 Ca Or, clie, Of 99 INIFIrilarell / i MI 1,iiiiirana, • 9 i or -0 0 Hz ram C nilintriEi IOWA 25/ ow co a Cor c - 0 ItiraWhalill •5 slat ler / 2., e 1 S'Si . in. Oro or. -70; Inns WM Wifiiiiiiin SIM ring NM I 101 or . 4so Id V" i a 2 30 Ma nillIMIll En Lir 4 0 ino if 5 1 CJI °I 1 Or 'ea I ° fl5fett ' t 1 MEI C• ze,orb' - StiliErralfri t/2. ra Wariliiini49 NainsSi 4/ a, irkinni Wira /MU (... Windiffili Pr -t1 Winnarnan • acira SIMMEWsii 1 1 3 I 0 ti MO niPlingnillnal rIli i 1 to Nall Inaltras lin ore6g co . ._ to ' I 115 '2H 4& 0,r° m" cr. it i 0 re i i 7 5 2 H 1 See gr * _ice 5.__ k I 1 z6ezit 0_4_ iiiEN .* 1 al 1 6, _ 71 F • blot I tired '44. / , A ci 0 5fr vet 45 an P %Id Lef 9440 a_aiIIC:97%;.1*.: : f . Averages gireir.€ ati" AC. " '' 11 se . 0A/QC Cheer Completeness Legibility. curacy' Specifications Checked !Sy' Team Leader v*5 001 AS-Q!MS-FM 225 G P043AS-007255-RT-644 34 of 381 Pi ft:75 ern VIMO MONTROSE E AIR QUALITY SERVICES EPA MethodSels4CLI Field Datast eet (Isokinetic) Rage Project information Sampling Conditions ALT 011 TC ID: Ambient tiF Ref. F Date aoill . Off ' » ilik Project* pi,Q)j - 007 f 5 Static Pressure, 11 in. as , .r O/ Ambient Terre, 6F ' Stack CustomeriFacility r /?bwt"J9e/t1,cL4dBarometric Pressure, in. Hg I , Ret Barometer ID ; Probe I Unit ID/Sample Location S K Wind S I Direction IF Sec ' ' Precipitation,' pa Flirter Box iit 42. Operator Probe 1Farr Temp Range, CF Parre a Fitter Exit .Plum Sampling Equipment ID; Calibration ;Equipment Checks Pre Mid Post ' Meter outlet - /,Walvfeterbox .sr ' imin,H2O el@ Meterbox in .9t ,Pitati+)apass @ Impirtgar Exit Umbilical ID /Co-fh Melerbox MV, in. H2O ' tat (3 pass @ in. H2O 0 a ai Other /' 7 w Nozzle ID c Nozzle diameter. On, in, 0. 7 .q 3 intim visual inspection 7 pass pass Ref. Thermometer ICS f Y 'itat I Probe I' r6 'et P'itot coefficient, 'p Nozzle visual inspection pn P asp .�" P ass I, contirmUit Check a' .coamt rwi i Proper Pctiark Manometer ID , ' al SIR Manometer zero and level yes ;Meter, c in- Hg ° ' / Pre of L° 0 "S Notes: anafil,q0 EensilMty 0 . Oct if I K-Fa.ator 7. j "s' co ;Intermediate leak check volume, ft3 / / ' o Traverse e Point* Elected Elad Time Clock 24hr Time 0GM Reading, Vm, lta VelocityHead, i,P in H, Orifice Differential,. Pressure :�IHTemperature, Stack Temp, aF Probe Temp, °F I Filler Tempo, dF impinger Temp, 12F Exit Dr r Meter ,,. "F Vacuum, Ir Pump . Hg Ta et Actual Box Exit. Inlet Outlet be": li 'Li 729 . q 1ICt770.o)3ci Ro4 PC> iIci � , ' ' ' _ . 73 . _ a I.'' .. , 2 / , 13o9 . . tit 3 41 / 2 a 5 3 / 0 730t0 I ) 5 IL 'O cl l c 2 'i ,e ,�, jorc' 141/ • imj — 7 3 cl . ' _\ CPN f' ' O 2 f _ / t) , --- - 4/ i2 — - ei 2 • 792 � ° ' l a r got . W c r #74/12. ' ) '--,�' ' ' � ' 3 4 a 5 f at i r ' . 'o : 1 ,: '! I s _ I 7 90 7 Iii , teed' '/ r 4 I _Ss "' 2452 ' Li 412 i0 1' 5 4, 441 f Coign & c, / ' Li'' 7 _ 0 I/ 4, do 4 to 5° 41 42 c> 110 7'jt//ic.oi - ' r 2 K 0 495 71ff go, 00 its 3 7j1► I / Z / 3 ii Q - - - 2 .y 1 1 50 75 u a Ci 67? 0 70 Cr rz. /5' ....s. 4 C, I 2. 9 / .. St '7 Geri r L 1 4 W.30 2. f 2 l Sn cd a cr5 _ 76441•i no l It �r' 71 cl f -Fool ZSCI1/2" 3 7 c. 7 ; z T1 3 a gq O &I 2.115 _ 6 oil rOP 1q 6 I fit s I Geo ) ci.iat) 4./' _ 8, col or c) 0 i n ce I i 1 on core a ZOI 5 14_,+_ 25/ / rei , kat' 5 Z s O � J il JiG e by ' ■ moo 6 ice. 0 n3/4 IL O ein Ii/'ae ° I I _ 41 42 , # 1. VC/_. 3 I ,, ' ,� 4 it Il i 7 7 f i71-1 75'' .6 I a I 45 00 * r r 40 ;401'5 r - r Averages l � (n I&2, �f � I e e 1p. low OAIOC Check: Completeness Legibility Specifications Checked By _ Team Leader co $-0MS-FM.225 1342 G P043AS-007255-RT-644 35 of 381 (y4s TI3 .4,141AUTY siZv;cts /4/ / Project 0 (TA ' r Sampling Equips Ios Meterbax ID Umbilical ID Traverse Point Avenges Method Field D.ataslheet tIsoklr +tic) Sampling Conditions Static Pressure, In. ' "" . tif Arnbir Temp, °F Barometric Pressure, Ira Hg . • 4,02 Rai ilarocneter10 Wind Speed / Direction All Precipitation? . V Probe d Filter Tem. Range, °F Calibration bleterbox ar 9 el ) ,. Itieterboxa,H©,, I11. H2O Azle diameter, On, in, Piot coefficient Cp Mincrneter zero and level Clock Time 241r DGM Reeding, yr Velocfty Head,. AP In H2O Equipment Checks PE ktet' ID pass :r• i in. H2O Pitt a- , pass 4n. H2O Pitot visual Inspec on Tonle visual inspection Meter, dm 4, in. Hg Orifice Pressure D fter entice:, as H Target 4- _ _____ 1pass piss pass Pass V Pas pas Frcta Temp, °'F aAiAOC Care.: Completeness : Legibility ``-- P',; �* _ S fi Checked By Team Leader G P043AS-007255-RT-644 36 of 381 ALT011 TC I ; Slack ot,�,�' , Probe Fitter Baic H tt3 Filter Exit Meter oft 7C - a irinpinger &t Other Rat Thermometer ICI irmpinger Exit Temp, "F of Pump VEcuun u in. Hg 7 6 Dry Gas Meter Temper-. r, W inlet Outlet 4ze) Page CC�1 AS -Q V) AIR CUM Lire SWIM MONTROSE Project information Date j/1.4 / Customer! Facility Sample Recovery & Caret= Check Datutheel Project - °la Unlit ID 1 Sample Location 0-346 _ 'Run# f —_z ---- Operator Balance Audit (Field balance must be within g.5g of check weight mass) Date /1 Standard mass, gmay-00y CD Field balance mass, g Lint ilk Equipment identification Ret 'Thermometer Hygrometer Field Balance G t Check Weights Ctiv Calipers Ambient Conditions Mobile tab) Rekilive tidityk 1% temp, eF 7C/ Mobile tab # Moisture Detemrilnation Contents P Knockout IIrnpinger 1 Irnpktger 2 lrnpinger 3 impinge( 4 Impinger 5 ilmpinger 6 lmpinger 7 Irminger 8 Silica Gel Line Rinse Train Net Gain(Vic) Runt" Initial Initial Page Run 2 Run 3 Net I initial S. _ Picnic Measurements piterence between any two measurements must not be more than 0.004 in (01 mm)) Nozzle ll diameters Nrzle 2 diameters Nozzle 3 diameters Nozzle Material Probe Type Probe Liner Q quartz heated quartz Li Dl D1 glass O unheated glass steel D air-cooled O2 D2 D2 titanium O D3 D3 D3 Incronei O water-cooled steel LI Talton ® other C other other Average Average Average Filter Information Front Halt 11 quartz fiber glass fiber i7 Teflon El Teflon/quartz �Ilte Number: Runt : P� 'Back Hal El quariz Mier n glass fiber Q Teflon 1 Teflon/quart Rung 03 Run 3: other i0 rS Cl other Run Reagent Type Information Lot Number Sample Observations OA/QC Check: Completeness Legibility Accuracy Specifications Checked by: Team Leader 00IAS-QMS-FM-226 G P043AS-007255-RT-644 37 of 381 vs,„ MONTROSE • r Al V. 1) !,_1 %Ai rr ant:: EPA Method 9 Opacity Datasheet Sty Time 00 Project No_— tart lime GlienvFaolifty • r� I. 1� rill.tf Source/Location a IIY �/�J ra=y �yy y(r ate 11.24P SJ d '1 'f 1 _ $ of L k'n North Arrow ��eeer/� tt y[`�J/-'� Emisstor (kr Point 1 loYhib > sir Sun Shadow Line Process junit ii 56 �I Control Equipment _a_. -- Describe Emission Point cako( fl.�— ‘10n Height of Emission Point (fl) Start � �� Stogy � r 'Height of Em. Pt Rel. to Observer (ft) Start- ' FT sty a) Distance, to Erniss. Pt. (ft) I Direction to Emits. Pt. (Degrees) start ► itr ?Is- slap j (1 Start A sty ascot' Vertical ml Start q)e to Obs. Pt. Oi rsflon Point Sto901 Start Stop ILALM Emission Color Start 1 Point in plume at which observations were made 119 oist3 fro f Describe Plume Bao ground Start' Stop ineh Background Color Start + . Ste Ambient Temperature Sind a if st l� Wet Huib c2 Observers Name l oew CC%oOJ Observers Signature Additional Comments:r- o pfbitinf Sec 5 30 45 Min a 4 6 7 8 9 10 11 13 14 16 16 m 24 25 26 27 28 29 46 0 c GP043AS-007255-RT-64438isffo0fL-38° 1 S b 0 31 32 33 34 35 36 37 38 39 40 41 42 46 47 48 55 56 67 58 59 0 15 30 45 54 Reviewed: PPM CPtvl gesiso MONTROSE low I ma QUA ry St.r.Ve_.. t' EPA Method 9 Opacity Datasheet Start Time 41110 — ProJed No. � — top Tlmv 0 MISM (Theil0Fa014 1 %! iffilin Stitatztkocation Date Sketch of man ell North Arrow Emission Point cOn 0 Sun Shadow Line Process Unit Contra ' i' ettt /' Describe Emission Potrit e07p, re,,\ Jr\ Height of E Staff i f sion Point (ft) Stop Height of Em. Pt lit to Obse (ft) Start Glid F Stop awl [Distance to rjp•iss Pt. (ft) Start Stop 4 3 ri Directiogjo � Miss. Pt.' 9r' s 0 Start Stop 7 Vertical Ante to Obs. Pt. Direction to Obervation Point Start t2p 30 Start E Stop C - Describe Erplssions. Start GE it Emission Color Start CI t tiny Stop (Ic � Water Plutne Attached Dd Wane Point In plume at which observations were made nick. duo IO4T19 °cis Describe Plume Background Start brt Stu Background Color Sky Condit ons Start r9 Stop -4 Start C IQ u.4\ -- stogy C/tOusVi Ind Speed Start stop t1tt, Wind Direction start Nam 5 Stop 11/4) Ambient Te m .erature 1 Start - Stop 34 Wet Bulb Observers Name laSyl ler Co Observers Signature RH Percent IR '61 [Certified B' JDate of Certi#i an tr $ Additional Cornmen ha) no ulSait� PritlYiNc GP043AS-007255-RT-644 39 of 381 Sec 0 75 30 4b 0 15 30 45 Min ! a ry V 0 30 0 � 31 �32 2 o O 0 b O '0 D 1 g � 38 ■ ��.■ 9 39 40_■■ 10 ■ 41 11 42 ■ 12 13 1 43 � ■ 44 .■ 14 ■■■ 75 � 16 ■■ 46 17 ■ ■ 47 18 ■ 48 19 49 20 ■ 5Q � 51 ■ 52 22 23 53 24 54 �■ 55 ■ 26 57 59 PM CPM gyn MONTROSE Ant iiwittci!c. EPA Method 9 Opacity Datasheet 'Sac Stem ( coo Project No. CilentlFacillty 4 1. p Time 1 0 SouroeiLocationDate y ". Sketch of Lrrtion North Anew Emission Point 5 (Anap Sun Shadow Lone Process 1`-c 1 rsi Unit , +L Control Equipment el. , .Describe Emission Pointic)9 � y •� I r Sk `` Q Height of Ereinion Point (IL. `Start r Stop Ire Distance o has. Pt. (ft) Start 6 St V Height of Ent. Rot. to Start k S VertEcal Antis to Obe. Pt Oireagon to t}benretion Pokifi Start d otssrt. 1� stop r Describe Start Coe Of Emission Color Start a Q. Stop Wind Speed Start s 1 Stop G{ � "Y Wind Direction Start 4 hl Ambleril re nature Wet Bulb Start 10 St c Observers Name ,► . Observers Signature Certified Date of Certification G P043AS-007255-RT-644 umQ (Zo(I'r�0 of 81 I1��i Revi€wed: FPt t_ _ EPA Method atirsaaDatasheet 3o7 Project ODdo Operator: Cent: _ Barometric Pressure a lg): ael' re . DatRe; Date; � � r fROSt RO ft a AIRUt; ' ERVlC F' Nritlarl W a a Post w Trap ID: Run g 1 g ? en over .Meter tO: Start Thne: 'Stop Time: coa Whit Weight: Trap 101 $ :Plot Welillt IritiTast Lea.kCheck NA Post -Tao Leak Clhecit nip ' ew: 1 .C-0 Meter ID: Start VIM _ Yd; 02 (%): Col PO: Pre Test Leakcheck ma • task PotTast "H . S" I&1: _. Sample Time Sample Rpm).' Rate Sample : Volume IL) DGM Temp Imp, Outlet Vacuum Sample Sample Rate Sample Volume IN Dahl Temp Mips Outlet Vacuum —� Stack Tern;. 'F) Temp tin inNg)Time 1Pm) rn TAR I r ) CF) sil coP 2 i erAne / : 1 it ' 4 M* '' 5 I 1 , a ,- ism- ' I c Baer R ) icor 8 .1 i I 3 3 - 1 1 eta RATA Ruti Start Time: Stop Tlr.L Sample Time Total Total Orifice Pressure Volume MI) aH ('20.1 Total Average Average Meter Box ID: 'Maximum ( Maxi DGM Temp CF Inlet Outlet Average Imp. Outlet Temp rFJ Total Madmurn cJIum Avenge Total Average Maximum Impinge, Weights. _ Ianrpkger 1 _ Impinges 2; Impinger 3 _ Impinges 4 O _ Total htl,al Etna Total Maximum G P043AS-007255-RT-644 41 of 381 Reviewed; FPM ,CPM EPA Method 4 and 305 Datasheet 3os %project Code ChM sour= /2d - co 7 . Operator: J3 , c j C 11e1 Weight Trap .Its: j SiG ( 5)9I '1 no orn Run bIMeItEID: 3C, ;Start Time: Stop 'glee; Sample Time Yd: / P 4 ter 7 1 b 5$ Sample Rate Sample Volume ft) BarootetrIc Pressure ("Hs): Notes: Post Weight: Notes: 02 MO Initial Weight: (fpm) Ofe' o "'_ 4/ lc/ i A PreNTest Leak Check (n H2O @ tHel: Post -Test LeakCheck ( i120 @ °f7); DGM Temp CT) L�r rnip Outlet Temp ('F) Trap ID: Runt I�{ z9c► 0127 Metes lily 'Start lime: Vacuum Hg) I Stop -Timer Total 5g Average Maximum 1 I, Sample Time 91 (iN IROSIZ Mr M 1.1 iA L i V 'I ti E VICF\ Post Weight: "Notes: col N r _ Pre -Test Leak Check MO @ 91gJ; Post -Test Leak check ("Hz° ogi "FHB): Sample Sample Rate Vokeme (L) DGM Temp (lpm) leer O' `+* ' I ('nn 42-c- 0 1-/ I ye co Run # RATA Run JI► Meter Box ID: 1 trisi Start Time: Stop Time: Sam* Time Orifice Pressure �! ("i420) Sample Volume (ft 3) Pre -Test Leak Check ir'ico O "lie: 1'a -Tnt Leak Check ("820 Si "Hg): Defill Temp ('Fj Inlet : Outlet Imp. Outlet: Temp ('F) Vacuum HO Total Average Total Average Maximum Maximum �3 Imp. Outlet Temp rn Coo 012 Vacuum ells) i Stack Temp (7) P57 erage Tottar-- Average Imp IngerWeights Impinger I. Impinger 2 I rrtp I nger 3 imply ,.ar 4 (SG) Total) S I Maximum Iyaae um InttlsI Final Total G P043AS-007255-RT-644 42 of 381 Reviewed: PP. CP M EPA Method 3 Datasheet Sea Project Coyle .- . - - Operator: PROS' rt-cs7 Client: � Barometric Pressure ("Hg)745a II /2 Source: Notes Date: 201,1I . / lit A I R ON r .4 irRo 1' 1. Inttlal Weight Post Weight: NOS WIfght: Post Weight: , Trap Mt iii VC 00 int _ Notes: Run Rim #Oita JO 'id: . O/O ' r ;- ( ae�ter Via: Meter ID: ', `r'i : Start Time: Pre-Tea't Leek Citedt riii20 EP NO 15 te art `T me; ■ ■ ��:if Post -Teed Liikamkrif213, EP 'HA: � P t�T L C i C �" H rStep Time: Sample The Sample Rate Simple Volume CO 0GIVI Temp Imp. -outlet Vaituum Simple I Sample Rate Sample VoPt nee IL) DGM Temp Imp. Outlet Vacuum Steck Tern (Ipm) rri Temp r'J n"ig) Time (rpm) CO Temp (7) ("HR) V O4 11O 16 .7 G a , , ...zeo: " %. riec. zo en! cop / 83 : L.& 31 • co MEIM. 2 ,1 1 +r` el hl 1 I� MEM]7/4,,i wb'f Thal --- verage Total Average Maximum Maximum Total Average Total. Ave raee lvfaximum Maximum Run Meter Box In: RATA Run # Yd: AN : Pr Test Leak Ch c i?"KK1C1 @li Start Time: Stop Time: Post -Test Leek Check ("Hz(' @1 "HA: Sample Time i Orifice Pressure Sample Volume (ft3) 0GM Temp (''F) imp. Owlet Temp N Vacuum I"18) ISH (112O) i Inlet Outlet I I - I � Total Average Total Average Maximum Maximum ImpingerWeighti INtlal Final I,rnpinger I Imp Inger 2 Impinger 3 Impinge 4 (SG) TataG r - Tctall G P043AS-007255-RT-644 43 of 381 Reviewed: FPM CP M Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix A.3 Kiln 65 (Kiln 1) Field Data Sheets G P043AS-007255-RT-644 44 of 381 ti\ MONTROSE I AIR QUALIFY tiERvIEFS AAaMONTROSE E MR QUALITY SERVICES EPA Method Field Datasheet (Isokinetic) IC0Rhati/Pe , 0z Writ Page of ' Project Information Sampling Conditions ALT Oil TC ID: Ambient aF Ref. =F — °'F Hate lodall kcal, Project # .Pmcy — 00-7255 Static Pressure,, in. H2O O , O I Ambient Ternp, 20.14 'Stack. , 3 w..., .,,,5 Customer/Facility ' jl�wt"Berfjicx.,c/ Baromekiric Pressure, hochei in. Hg 7i5 * r Barometer ID 4 Probe 4;Ref. Unit tD/Sample Location +an it & 5 Wind Speed P Direction Precipitation &f P4, type iiVc.'v Filter Sox (3 2 , Run # Operator5. i. Probe ! Filler Temp Rar )e, `F 2 'Filter Exit Sampling Equipment IDs Calibration Equipment Checks Pre Mid p5-2 Post 'Meter outlet + C7 9 la Pilot (+), in. 'H20 [@ Meterbox ID A Meted:my y pass @ 7, • ! @ - - . ,0Irripfirager Exit LIItIb�11ica1 ID Z 1 5 Pilot �Y� In, H Q U L Li. O 0 I'�+eterbax r�H.�. Iri . H20 • , Pa 0 � � '�-� +�. ''` Other t 'Nozzle ID Nozzle diameter, Dn. 'rrr. Pilot visual inspection p` pass �i�ef. pass paw Thermometer ID ,� Pilot I Prate ID 0 list. - a Pilot coefficient Cp Nozzle visual inspection Ca s VA l pass E 02 ss ,tp Continuity Check In Continuity wP Proper Polarit `'r IMaaonneter ID " ' Manometer zero and level K. yes Meter, cfrn @ in. Hg i O @ / a ; '' ett5@5 e @■■��, 1 t . sensitivity . era K-Faclor 7 .. f '"7 7P Intermediate leak check volurme, ft ,r 2 35 i 1,1 , 01 100041/ Traverse Point # Elapsed Time Clock Time '4h,r DGM Reading, 'rn. Ilia I Velocity Head. �P in : H20 r Orifice Pressure Differential, ,�H Stack Temp. aF Probe Temp, °F filter Ten�rp, _F Impinger T+erIap„ °'I` Exit' Dry Gas Temperature, Meter cif Pump Vacuum. in. Hg l Jf Target actual g� ExEt inlet Outlet � 1 Oa. i i g rP L/53 ., 0%6; 6 ." , !i : xi 156 . 3 ) 1In 0,62. 3 0 3 / 3 /T 7IG i 3 / 0_ L i G 1! OO 2-7 cr - ice "Ina 7 7 3 2s tit a ' G5 y / 9 .1 5 co a9 O Lit 2r Ced nr ti 7 o cii 'o or, -5- LI 6 2. di . • or cor " a ' e C ,/ 0 66 31/ 3 1 1 • , 5 ..2.0 2. 5 Li GI-) „ q I . or ° r &tic 01,00 / .!. / 2. erg 2 9 3 5- 0 O I 7 r J r 1' r 3 I c e i-3 O r 3 1-5 , 3 2 9 3" 7 15. 02 7 30 2.. '4.f Li 3i Li 601,, 3 1 a c,,, .5-c Or En c) a IP i 2, til .2„ e2 . 0 93 2 9 3 g R. 9 '' ct i C Q.C1' in ) a 3 . o e, g? 4.{ Obi a '/ 9 3 4b .,J tri tri, to -oilissro.ses-cmi Lee ova ci mie/ Lii 3 c, 3 3 3 Z - csol Li 76: ci 1 . i i 70 e5/ '1 2 -59 rar it3 0 „HO 0 G 0.50I I or OO 4.7) Lig2_, c orec) a 6) 0 , • J.,'�.•.w��1�f/ g 9.52..Ign II er)F 3 '1.f ! Do �••+' o0:01 or GI/ or _ f' 3 ' fi 7• .''o' r Li ".►rli 410 7 ce O1 c. els. So '5 2., 0 3 ...., li 2,.. k)i? 5 1 : to 4/ 9z. co , O1 2, Oe- °I Z 11 I 6i. G 2..% cd) Bliell 3 , 4 5 3 '.. 6, Ir L i5 2 50 z o k 5 5 1 67 z... 0 . ce 5 ci . EMPEEME 2 .. 7 1 ).. 30 cl i 3 " , nt z_ 1 5 ,/' 0 1: 3 5' P-50.1. 32 .O if f at ICes9/ _ 253 76/ e2-Gy • '`r+' 7 hi / igt a ,90 5 a i I f1ei !. G r• fug ii ` Li / Cor ►r' o i `• ie .' ' 1-,i+' h' i , , 6 7 2 e 5 5 'it' cat 1 ` el . 1 . ,1 I i 1 -,' O 509.. _ENV . J / a I its 41 0So Zr ! D i : 7 fal �I " 35 •1 r / 4) ms's I1 i •1' J f �y + 4`l 777"'• 7 �� J. - -- _ _ II�� r - i y3j z•fieciou lual ° oni 14 i �3rO tr,.I't i • J09 Y �V.f � � el f•r�p � Averages ��° F �1�a+T 'IiJ p7d' � ,rr � t� QNOC Check; Comp;eteness Legibility % Bracy v3 Specifications Checked By Team Leader 001 A M Mi-225 4"? G P043AS-007255-RT-644 45 of 381 T (-Cr, — ✓ Y� yMO NT O E AlAra QUA.LZTY SERYlC.1S PA Method 202,3Field Datasheet I(Ist kinetic) Page of Project Information Sampling Conditions ALT CM TC ID: Ambient °F Ref. -F ! Date i' Project -� `-097� "' Static Pressure, In. r Ambient Temp, 'IF lSlack i ,I a , 1 �C , , ,� , �;' • 3.," ��,3�: -.'.,�" ` 4 y ( ter' " � Y I v \ O ',.``) / ustomeraFaciiii l' r, ,�o e'. :l ,��V Lam•- U/ait4ocaarometc Pressure.. In. Hg . ,� g Ref. Barometer ID Probe ill Unit lCi(Sarriple Location1 0.5. '"' Wind Speed I Direction 4 L'4/ Precipitation, rrc'type F,:Itte.r Box ,„o ,5 ,. r+ f . Run # Operator rl J 5 !Probe it Filter Temp Fi I' e r Exit Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter oat A 1 c_2 ' iV1.--a.Meterbox 4 M-eterbox ID Y rl ) 2 P.itot (+)A pass ln. 11-1.0 g ling --J ', Ycn pirnger Exit 1 Umbilical ID ,� 4- hileterbox 1 Pilot H2O V jot' &h1©, tin. H2O . (-H, pass @, in. ( ---olet—,. °' g Other . O. 7 41 5` visual Inspector, ? Nozzle ID N le & aler, On., In. p pass pass pass .Pitet , Peet Thermometer ID Pita/ Probe ICS 0113014-0,55"� aO IPA ccet dent, Cp 8 x Nozzle visual Ins.pecition v pass q pass. ° pass J r� r e Continuity �u Proper F aro ,�: Manometer IL M1217: iviano�rneter zero and level `143ter, cfr . in,. Hg .C^ ?el '1 ''- - i„_.. y _ �,"I? Notes: 44y , . kit, 9/. 7, 1 ,'` 7I Sensitivi . O -- K -Factor ,� Intermediate leak check volume, r�.e, i•#:f p 6- 7rifi e Pressure C Probe Tempi o -F Filter Temp, F Impingar Temp, if Exit Ci ry" Gas Meter T rasp rst�ur .; F i Pump Vacuum, Traverse Elapsed Clock Time ' DG Reading, Velocity Head, Differentia', Stack Temp, Point Time Vihr Vms s tP in Hn *F Box . Ntet Ouget in Fig ,_,,. c.) '` Target . ctusExit o -' �' 77, c"..-5-3 J�r1 or i ��1 4 / 00:00 r'� 7 3 O ( 2 )06c 7 F5 C Of . '�..J' -�° k , 2 O° 4. ID,. —7 i 7 15 7) g g 7 ci O 2,5 6,-- 24 0 25 ) o 2 5-‘7 C2) oeir a 2/5-3 2/ 5- 5 4Ill "17 2 4 0 O cm) rol 00 2/0 6/0 i , 1 r.:" r y si, ..,, (..", 24 ? �. _7 - 1 I Id ,�� "'�,:, fir-, °� j� r +'} -cn, i- &Go 5- _ -Tr --, ' " 19 5 J . ..-, ■ :4/ cie7,2" r 7! - 5 �.r, •' S.F ,r J',/ ,1 _ _ _ _ . .. • Xid 0 . E0 4 e---) 2-/ I 3 05. . .. I idf' a q. " �" I — - - - r.siof - ?II y 'Lr• J, Or r 1 5 i3. g (-1 . _ z Do I a 4,...., , , • . l 1 ," \ 537 'e.�,ll 11 a "� Re.}yp ILe � ' M ^�f'►y pfI{,Jl P"� LV' i ;' Ct.�ICla Yii 1 5 a .. ;// L_ _ �. ) �•G„..., i --a lie ' 1 73 r ed.) �_) i I 1 5 1 I 0 0 H •-3 . - �+" Jir 4 3:2-2 0 , 6....,s ) ii ...L...----;c_i 4:-,,4, .,, 5:5 i cp 5 a , 1 M CI 0 r / L {"' I / �"L. ) 3 L �• ,..+` a r _ff 3 ir u i 3 3) 2 t ti7 .Ir 21 :zi ) 2- ii I er--- o 5 agit 47 i 60 /5I I Z a e it 5.- a 5 0 ' di -2D I I 17,0 7 I, V it' ..) { r 0-1 'n 41 1/5 7 7 ? to 0 0 ) 3 O �. _ o-. +� _� fr er r p t 5 7'in* 111 3.82 _ '.�'' '�'. ifre- a. I,17. 0 j r �" IJffo P "' lam' 1iz.a ',,' ' � ' - 'yam.' I ,r* J'� _ 1 1 Ail- 1- 6 I 50 i al r r ./ I (, ItrN 1 2 'cam °' '.!r' J/ Z117 L4 ° ls.r" I a al 1 9 e P 17) g ------ 4.' V d 1 IN i MOE 2. it fa _ racy G P043AS-007255-RT-644 Specilcatlons Checked By - Team. Leader 46 of 381 m -MO T O E AIR QUALITY S Elx,S EPA Method F leki Datasheet (IsckIn'ettc) Hs 7 Oreet 7, Page 4 614, 1613 liallItilliMUIREI Project informationSampling COridlticne ALT I 1 'l IC ID: Ambient 'F Ref. 'F �� Cate ' H f / Project* J F T 007 Sta5c P '% Inv Hap —Or r ofitiatibient Temp, itis Customenfaciaty Ci _ r 0 _ Barometric PreaureDiii. Ha 2 , Jo :III. Barometer ID Probe 1 Unit IIO/Sample Location Wired Speed /' Direodon Pre ipa ator N, type Filter Box „ 3 Run # Operator ) i 5 PT `- , PrObe I Fitter Teem • Range q Filter Exit : Sampling Equipment IDa Calibration Equipment Checks Pre Mid port Meter_c' let -i,. - - ' 99di Pitt l- In, He20 G..._se.......„/4 � ivce erd c Y , p' C l gec Impinge( p.'. "M _ ,. � - _mil, AI Umbilical 10 o 'Meterbox .Aid k,, In H �' Pmt (-�I, p►as In:, H2O �. Other -7 Pftol ER.spe f-�Ara Nozzle ID Nye dame Qln, tn. 0' vfsuel p pass �f pas ,L , Ref 1'1 earianaier ID PItoti' Probe lD � rS -9-. Fill ic,er Cpl f Ntcnie dual nsp ion peg pass -C pass ■ „ T.g. . . _ . contnuity check Conlinuity wl proper I 'lancmeter ID �, '� 'Manometer zero and navel Meter, cfm in. � '. '' ' �� ' ,I Notes: ., 'K`F ' -R7 Se M �M� r OI • e t, , • 276 276. ti.d' FF tenTledlate teak Med( volumes � i I - "Y"r�rrse Iel ire R� Fir Tempt T irn ger Dry Gas M Pump ,� Vacuum, Elapsedt+cirrrl e DGM Readings ge Head, Stack Temp, Probe Temp., Tempe i . 1 Differential, Ail Temp1 �'� Point* Time 4hr % ! In I -1 X _ F rF . I, Target I Inlet O Exit; f �, in. Hg IRIgn nillakillinall a sm..- I ) i ling' 28t9 * - -Ticalo CM MEM WM . i P . e 79 �M # atm L6 iq. NM /ti, mair ma dm Iffinigaga 1 p 0 / Zi s7 Li bi-' A 0 i O g cf / , get, 2, 6-7 3 . 5 . 2 t 0 EMI 6,6r .3 5-- 'DS 6 43. 0 ) 4;75 z frallgSZNPAIIIM ' 3 c? z i ; 7 Y WIN lenliMilnairdra 3 5MI O 0cdi 0.0 re (2 a 6' ' Ell G 3 i • dr 0 ed 1 Ce ,Q45*-- ••• 2r o7 6 Eartara igninglilli ic) 0 O 'St 0 t - 7 0 a I a o 50 G3G. 641 , o 0 ci 0 oa .75 a -- liazig 6 3 ern 7O O. e 0,6o Wilialirrallicitill 51 NMI ez 0 , & 5 9 do 4_ Of. 1 Wia a w , • , - - - Tom! 0 Z. _ orp 2 Inilr 4 .4 a 6 Milli : Man o & 0 ralefda it/ 1 0 -, a aglia ' ,o Jfl EMI lir ! 5/ 0 ME . , 4 Zit, , NMI 50 1 , zet5 6 I I f iI" Al CI 1I 0 WariaillnilINIZIEL4 2 _, 'a UM ill 7 X1 / 4 Rain ):301 •' 14 i 77 4 01 10 cote M rinlirklaiMil 1 . PIT 1 7 0JI f o,PI / OO 1� 4,1 ; IIIMAINIIIIMI I � OIe if I V t ) ic///L/ �, Phi Jp?7 _, r." I Cl 2 r MIENS7 - .F' .: 2. - I y del+ � y i � „ 00 oil' 3 U. SD '' Cis 9 I ,END De° • -702---. itafrel:: O i C) 11 le& assol-..., si.ava,.... ---.--•••—a. 1 -"m•--. Mr Averages �'#70 Li2A1/4. r' r 6 ` 4. L-70/1 p > f ,. V w t ci ' 1 ., ,f UQCCIPCheck: Completeness Legibility Accuracy G P043AS-007255-RT-644 Specifications Checked Eity Team Leader 47 of 381 Nozzle 1 diameters Nuzzle 2 diameters Norris 3 diameters MONTUOSE AIR gyAu Y SERVIC14 Sample Recovery & Calibration Check Datasheet Page Project Intontion ra PR61 , Equipment Identification Date � i j j I Priad s Lr,` 4� �' �'sr Ref. Thermometer Customer / Faciliy in ley 1 I eftslifo Hygrometer Unit ID I Sample Location ' I Field Balance S i Runt 1 Opkr'fr Check Weights CLAJ I O Calipers Balance Audit (Field balance must be within 0.50 of check weight mass) Ambient Conditions (Mobile Lab) "--' Date e i _ 1 Relative humidity, % r" , Standard mass, g 5c) ) c' , ca - Temperature, "F Field balance mass, g --1 etc Mode tab # _ - - Moisture e Determination Runt k, Run 2 Run 3 Contents_ 1 -- initial Final Net Initial Final - Net Initial Final Net Knockout tin 1- - 771 O ilirl ci ' i 4C _- ' -1 ,a7SS .�. ac— Impirige l * 4 e 71r� . ��4JT., +i 4 ,`}ter+ 6 Pt �.' Irnpinge(2 1 0, C 30- 0 ►--7 O 7 5 / f Impinges 3 o I tel M r Irminger 4 H Crnpinger 5 impinger 5 - Impinr 7 Irnpin.r 8 Silica Gel Cr IPO1 10 _JI a/ /7J el ) )- FyC ; I (XS& I . N I I Line Rinse Train Net Gain(Vic) itSS j Cj f- 4 j 3 3 co lz, cis Nozzle Measurements (Difference between any two measurements must not be more than 01104 in (0.1 mm)) 02 0 k 7 D3 Orb 74 Average D3 - Average D1 D2 D3 Average D1 D2 Nom Material, quartz Yee -glass steel titanium iii inconel lI other I Probe Type heated unheated ® air-cooled O water -pled other Probe Liner 0 quartz glass Q steel E Teflon 0 other Filter Information Front. Halt ® quartz fiber 4i glass fiber Q Teflon l] Teflon/quartz Filter Nor, Run 1: I IID-._ Run 2: r j / Run 3: C] other 8=10 -let quartz flbec CI glass fiber Oe Teflon Teflon/quart2 O ether r a Reagent information Typo Lot Number Semple Observations QAICIC Check: Completeness Legibility Accuracy Specifications Checked by: Team leader, - 001 AS-QMS--FIVC-225 G P043AS-007255-RT-644 48 of 381 EPA Method 9 Opacity Datasheet ted) MONTROSE 4 c U F it Ayr: -1-.s rz �� Start Time 9/6 Project No. QrU3' s_ 601‘;2.54 Client/Facility 010 c IV0 tial PIO? Stop Time Cf r" Source/Location i I Li {` A t Date - i , 3 -� i Sketch ofLibation North Arrow Emission Point41) Sun Shadow Line Process R T I nI Unit egifi ir$ Control Equipment - Describe Emission Point kusu +oc h r\ kiijS5�_ Height of Eiglssian Point fit} Start l F 1 Stop J'FT Height of Ern. Pt. Refit tp Observer Start? ITT Stop; Distance to ,miss. Pt Oft) r Start 4 >r sto O f Direction to Briss. Pt. (Degrees) Start 1 Stop Vertical Anle to Ohs. Pt. Start 36 stop 3t6 Direction to Obennation Point Start YStop avisie Describe issions Start t' Stop Ch°K-- Emission Color Water Plume Start ct ' r Stop c . Attached detached None Point in plume at which observations were made Li.) Pi Describe Plume Background Start r '- -, Background Color Start (.7 Sto (r t Sky Conditions Start tea dem ciL Wet Bul PH Percent %.3. cc%) Ambient Start7 Temp ature Stop 9) ir.' Observers Name Observers Stgnatur = — - 71 a tcertified sii4erkt 1'Yi t loatcertnication 4 Additional Comments: orl6i9, o 45 15 30 45 30 rio (../ 31 tl 2 0 Lai 33 0 34 5 t,t 35 .r� 36 I I 37 40 41 12 42 13 43 14 44 15 45 46 47 17 18 48 19 49 20 50 1 5`1 22 ' 52 23 i' 2'4 25 I5 2 56 27 57 28I 58 29, � 5'g \ Y GP043AS-007255-RT-644 49 LOA GPM EPA Method 9 Opacity Dalai heat MONTROSE A13 cr4itillY II PA' t tz, f/ DO I start Time Project No. V a Client/Facility ) 0 c ha JIt iv/ "P s ,Stop Time Date Source/Location r n .Sitetch of Location North Arrow Emission Point ,', Sun Shadow Line Unit i la Process ic i ) Csit - Control P.ui•ment y cribs Emission Point I' tri n 54ct' 1,2 4I V Height of Emission Point (ft) Start r ,rat` Stops CT Vertical An e to Obs. PL Start Sic Height of Em. Pt. Rel. to Observer (ft Start , Stop t\ p Describe Emissions Start C 1 Q Emission Color Start C Ic Sto stagy _ ("f Pt{" Water Plume Attached _ Detached None Point in plume at which observations were made 11/4)\- • no El • u� Describe Plume Background /' L: C Stop Start � _ Background Color Gn _ Start r t�. Stop Sky Conditions Start C11) lit Stop WO ut Wind Speed Start 4 , , i/I Sta0S Wind Direction Start Stop N Ambient Temperature Start 4 F Stop 'Wet Buli_b \1 RH Percent a Observers Name L (riI iev -4 Observers_rt t -- Certified B / Date of Certification 2, j Additional Comments: 574cf c 0 .ice.. 15 30 45 0 15 30 45 in I.T1 0O 0 oil 1 � 0 0 iUfl M f Ili I ( - lJ ID II 6 �' r� V . �J' 36 yl � `,i :,,, O 37 8 D 0 CT) ,- � U D l' i 10 ,:,,, u ster, i ) 40 0 11 C) 0I L 41 ri 12 I 0 ., ,: ._ 42 IMI 13 0', 43 14 e 44 - e 15 C2 ' 0 Cr 46 Q), 16 . 17 47 18 48 19 49 20 50 21 51- 22 52 23 53 54 25 55 56 26 27 57 28 58 29 , I 59 SoS-0y2Rnrv64 ' J -5oi 381 '1('k' 06 76 0 PM CPM EPA Method 9 Opacity Datasheet 41YI MONTROSIE IV r! IIVIC ASS CS 2-`1` Pro ect No. Qrq3—O6j Stop Time 104 3 ' Client/Facility 13 I 0 Or,ow ptit Date - i 31 Sou rc L Lion t l I titifittsfr_ Sketch of Location North Arrow M Emission Point _..----- .....4 i 41 C). Sun Shadow Line h _ Process ' I _ tunit 11 6,..5 Control Equipment Describe Emission Pain ,rI n 1/7N Height of Emission Point (ft) < Height of Em. Pt. Rel. to Observer (ftl t jr: StarSto jStart - l Pt Stop )--1 RI Distance to Ems, P1 (ft) Direction amiss. t. (Degrees) 0 StartOStopStart _ ;1 Stop' Fethcat Angle to Obs. Pt, Start 90 4 Stop 0 Direction to Point �p E Describe pnissions Start el R Emission oior Start Stop Sto� ` €akar r Water Plume Attached - flostached Ji Nana Point in plume at which observations were made Describe Plume Background Start i ft,1 Stop G r a y Background Color Start C- I) Sky Conditions tart CIO Stop do LkcA1 Wind Speed Start d to ('1' _,�` Stoi.2n1 Wind Direction Start 1147;r' - Stop AI 4-)15 Ambient Teomrperature del Start fal r Stop °r Wet Bulb 0 .7 a RH Percent ir Observers Name Observers Signatn, r Cam, Liu ct Certified By + ° alt. joateofcertification = i Additional Camments+ � { �� crfOL,G� his no v}�Ph,( Sec o 15 = 30 45 0 15 30 :_ 45 Min 030 31 1 U C) 32 1 6 33 0 34 I -D i 3 (7) L., 0 0 1 36 3? 5 39 il 10 , 40 11 41 12 42 1 3 ' 43. 14' 144 i ; 45 15 46 16 17 47 18 48 49 19 50 s 20 51 21 22 52 23 53 24 54 55 25 26 56 27 57 58 28 29 59 G P043AS-007255-RT-644 Reviewed: FPM CPM ERA Me ad #arrd 30B Dafiasheet 3O Operator: '1 [Projea code ' — Cic/7 2 . I Client � �' ray Barometric Prissure nHg): ` ,� � Source: 5 Notes: loads: ZI• o 1 - Initial W&ght; at) 111F.37 Total Total "Jaximuni Maximum Sample Total PURIa Metes Box ID: RATA Run $ Yd: � l LAM Start Time: Pre -Test Leak Check nip II •K&: 1 Stop Time; Post-test Leak Check (""HZO • *H : Sample Orifice Pressure Volume MI] 0�GM T� ► �p, �� VacuumT1i Time AM rtH 2�') _ Inlet 1 T Temp (V) Total Average Total Average Maximum Pats mean Average .:q MON Alit QJLIALifi .1:1,1/4/17 F Vacuum rift) Ave rage Total Maxim urn I! rtpanger'Wefights.[ Initial Impinge, I ImpIrger 2 Impinger 3 Irni:Inger 4,(56) Tag Final Ted Maximum Stack Te G P043AS-007255-RT-644 52 of 381 Reviewed: FPM 2PM EPA Method illitindlen Datashest 3age Operator: i 047 .. � ll Project Code PROS— co 7 2 Beat: , .+0 Barometric Pressure. el NO: r- SOMME 1 Notes: Date: l' . Oil / 5 4040 MONTROSE AIR CIJAWIII EVIN: r In l' Weight Post Weight: InItrai WeightPost 'eight; Trap Mr 5) (lit/ 07 Notes: Trap ID:: �{ i q 0 '- 3'' Notes: taint 0 2 0 (SiRun e — ' --) 0100: Meter ID: Yd: I 0 ci CO3 (%): Meter ID: Yid, Or a COI Start Time: ;" � 7 Pre -Test Leak -t etk ("H7D_ ' 'Hs): Q, 0 0 I rt Time: ' dr " P Test� leak rat f'H3O di 94g): '�.�i ';5 _ RH��H _ "' 'Kg): Stop Thine: ;",�w ►_r � Post -Test teak Check ��'►H2O actor�'` Stop Time; /� LI Ten Leak Check ("H20 ( '.f-. — - - Sample Sample - Sample Sample Rate Volume (L} ISM, Term Imp, Cutlet Vacuum Sample Staple Ruts Volume (Li DGM Temp I Imp. Outlet VaCal rn Stack Tem 44 Time UipmI I, - re F) _ Temp rp) eine Time Om) +f CF) Temp ("'F) rI1g) rF) hi -ago ' al i pin „.. 1 / 20 0, I / li r' h �a5 ..--.-- in 7 C CI FF � ., O ' 1 ..-- I1 ___? . catei(e.,e7 ----,) ,_ i yet_ ..---"-- t (� Y� r y.+ i �� ;-577ivt'� 'wr/ - .. ,: -- � r j, 'I I r zee r F,� �' IMPArill illMaINEAMI II - T,o i.== Ave -ge Total Average Maximum I' ax'y Um c T. .. Average Total Average IVIaxirri um Mom PKura # - Meter Box 1D RATA R un # Yd a I laini : Start Time: Pre-Tet Leak Check r li20 @ "Hs): Time; Post -Test Leak Check r,H30 co "Hg)/ Sample Time ISample Orifice Pressure aHI (ElH20)inlet. Volume eft') DGM Temp leFJ Outlet Imps.. Ootjet Temp 09 Il Vacuum ("Ho - - r Total Average Total Average Maximum Maximum ImpingerWeights fn fhl Final Imp Inger 1. Impir. ger 2 !mpinger 3 Irnpinges•4(S Total Total G P043AS-007255-RT-644 53 of 381 Reviewed; FPM CP PSI EPA Method frandlOB Da sheet 3O S# I nta I Weight: Trap Ili: Mir ID: Start TIME: Stop Time: Sample Time 0 to 2 to Total Run # WA Run# Start Time: Stop Time: Sample Time orifice Pressure ("H10) Total Average Volume (fta) Tota I' Operator: Barometric Pressure trHgj; Past Weight: Average lmp. Outl t Term ( F). Vacuum Sample ' Ig) Time Imp. Outlet Vacuum Temp ('F) (WH'g) Maximum. Maximum Sample' Sarnpre Rate Volume (L) (Ipm) Notes! Impinger Weights' initial Impinger �. In',pnnger i,mpinger S` Impinger 4 (SG) Total SY) MONITROS AIR CW A. LVor Imp. Outlet. Temp ('F' Final Total Vacuum Stack Tern ('F) G P043AS-007255-RT-644 54 of 381 pawls:AL:04 rPMA rt3IAA Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix A.4 Kiln 74 (Kiln 3) Field Data Sheets G P043AS-007255-RT-644 55 of 381 4A, MONTROSE I AIR QUALIFY tiERvIEFS MONTROSE SE A4 la COMt TV $FR.VICFS 085% Methodan--Field Datasteet (Isokin a c.) Page fr. z z ./4 Project Information Sampling Conditions ALT 011 TAG ID: Ambient"F Ref. . 'F I '' � _ '' I °'F3 Date . at, p5 Project # Static Pressure, in. H2O ,. 0 Ambient Temp, Stack. Custorner/Facility %c4r" , Barometric Pressure,. in. Hg tj, 9.2 Ref. Barometer ID Probe ,1.� Unit IID/Samp4'e Location 74,r Wind Speed / Direction Precipitation, Y" 'ps Filter Brox Run 4 / Operator /275 Probe / Filter Temp Rance, aF29 23012 iiii Fitter Exit Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter outlet +leterbox ID Ada ! 2. Meterbox Y i Pilot (+), pass a In. H2O @ B r irnpInger Exit i Umbilical ID Jj! JCL Meteitiox Aliffil. in. H20 9 idee; Pit0L_ (-), pass @ in'' N2C @ err @ Other , 4 !No ID Cc Nye diameter, Dn, in, a 7 4? Pltot visual inspection pass ' ,pass WI pass a , V Ref, Thermometer to , Ai IPitct I Probe ID0100012145as Pilot coefficient, Cp CP, S Nome visual inspection pass i puss pi Pass Continuity Check 0 Corttinuity awl P roper Polarity 7 Manometer ID Manometer zero and level es Meter, cfrn ,@ in. Hg 4•40.2'I, j _ , -v, '� Notes: -721* _ .S 34 a' 7' Intermediate leak i t3 Sensitivity �+t;�"�' if I�-Pacts. -; check volume, �' -- .� Traverse Point* Elapsed Clara Time 24hr DGM Reading, I �'rta, li �' Velma Head, in � �} fii Orifice Pressure aStack Temp,. Differential, AIRTemperature , Probe T � F - - - Dry Gas Meter Pump Vacuum, in. Fim� g Rater Temp, °F Irnpinger Term, sF Exit. '�F fime Target � Actual Sox Exit InletOutlet C4:411"" PP : a 2767.615-/ a oas i 30,7 I a his Lira 2 5-1/ C2 2 0 , 9 , I 0.0001 '+ ii Aso a S o , i " 6%40 O claps/ li63 &ease t4tz 01,7ro. 3iis La75 9 15 • w 73 cc 7 / z1 -3leo_y► 2 r 31 -'ii, 5 2sor o 9 Lam' 8 als 0, CG _ 3.7 "II 9 ‘,r Ci f o F-77 7 r 1 7, Or 749 a 7 a 75 3-7c5, GC a .,�'' ' .. , — '_7�/'a "w7, / e- jZ&'/25'ia 1 • � 382 J ^ !kcc %I . 5 I r °i e 8 Cy•67 , ■ . -7O O'Estro 12.7/ 4I 3 9 411 t g iref ice 5,36, 9 Lit G ot 1 !L,oilQ-/:Y/ao7&o Bali i2s, 31-1^/�J .Pti,i 7 2 . 0 1710 to L/2 ier tic 3e3c) . 671 o tic mon- oicio 2 a 0 Lira 5-ei L/2 it ileac,/ 254/ i/ 0 M0 iff 0 I• LI 2. ) - tic i L3 I 2 . , 6e 5ca-99•24.ill it t5 kip/ 0 le i - 2f ao )294- 2 �) . _ 139-5 igc / w' ' � /may . ar �� r lita , 110 1ti a i 133o. ! / r rY 2 .08 I 21 O 74a 0 .�t, ) 2 45 CO if O 3 i 1 0 1 Citil 2 O aiSCA7 i 13 ) 20 la 5 2--5-4/ I , e." og - 5 1O1 � I ,, .767 i i 1.O tic / . 0 co. i cl3 i 39 2. its is 7/ 6 2rIs 1 11 isci 17 , iv 25 / 2 -7 15-/ . i . �h 1 II ,-..5 3 224 2-D 0_ ' -) r 3t icerBe/ 1 z ff. 7 2'55' 4/7 I Lf 77-71/_ -I o gl 7 7 ;5 9419 02-. citoornaT 0.66 a C5 II L 73 z 4 0 J 2.055 g p Lig 9 1/ 1 cgliital 412.. 0 ra 5 Cif65 I O 73 2,. : 0085 1 qt.ai it 9 I T hi6" 012,,,,t1 30 peso & o c X41' r Co tei Li 9 74/ I r - // 70 IS2 I I tit Y.i. f 1 M.+' 7 11'6 i Q CO _// 7/ , 5. ) . 255 So • , d+' .20. i 14?2," e2,42,, 9 z_a / 5-"5° i 455 7 Lel 2_ c . 0'071,a. 461 i5-5 ,5-•• Foatil 0 /Z. LH - 1 + ■ ; 0 , o i of , se 2 ■' Cf ,D . ap '�R 60 I Averages )24,04 IG9-4 CI b a —ICI' 1 Zder52. ii _ ,,,,i4C.11 Jo) yr; .9-- 5C-41 es 0 . CaPigf Q QC Check.. Corn cleteness Legibility Accuracy YRS Specifications Checked By Team Leader 001 - M S-Fi1425 CelOQ cei G P043AS-007255-RT-644 56 of 381 MONTROSE Metrodrld Datasheet (Isokinetic) Page Af L QUALITY SERVICES Project rnformartion Sampling Conditions ALT 011 TG [0: Ambient CF Ref, °F i re C#71 ciF Date 20. /� Project # pricey J55 Static Pressure, in, H2O --- Ambient Temp, X1)Stack Customer/Facility cihirri Ate treeBarometric Pressure,1n- Hg 2 4/ , gat Ref. Barometer ID Probe Filter Box Unit IDitGam+ �e Location' p '�" Wind Speed f Direction Prectp�i�ti�ar' X11, type ��,,� j '` Filter ra RW•ri # 2 Operator Probe f FilterTemp Range, °F 29. 95 Meter outlet Sampling Equipment IDs Calibration 'Equipment Checks -$ Pre Mid Post JMet&boxlD ' V if O 9 'i 1 2 Pitot (+)•, in, H2O r - frn i ger licit u2, Meterbox pass - ' Other Urrubilicat ID Meterbox r H in. H/7 5P Pitot - pass @ in, G O © , d 'Nozzle ID 1Nonle diameter, On, in. a 7 11 5 Prtot visual inspection r, '' pass a pass piss Ref Thermometer ID ., , Continuity Check O Continuity wit Proper Polarity Pilot/ Probe VD'��'' ' Not coefficient, Cp •' , L"�p Nozzle visual inspectionpasspass , , pass . Meter, elm @ in. Fig O, t@. @ Notes: Manometer ID Manometer zero and level yes I K tnte mediate leak check volume, ft3 1 Sensitivity r.t,Occr I -Factor x Traverse # Elapsed t Time Clock 24hr Time Orifice Pressure Dry Gas Meter Ttjet ,�Vacuumn1 Pump iPodnt in. Vacuum, DGM Reading, g'n� 'rh, Velocity 'r' Head, Stack Temp, a Probe Temp, Filter Temp. 'F Impinge( Exit Term, °f '��' Target ctuat Box Exit ,�3,--ad, ) . r + " �' O1 050 1 3 ;t z- -7 14 6 4 r L.) �/ are i ii le/ i C r 0 {. '53 II .-1 1 • 4 I ice '933 • GI ri oxii ig 101 , IMMinti Ii f 3 / Le. I 7 J3eAtli , ir 5-1 4p, 'Lc 0111'5 3 e a i enrol z S' 2-51 0 i "' f 2,r ie .5 ci 70 L a a. 2611L9 o J .3 7 el,c) 9.6 i il •71e7 ". `* 7( fa - se 5..... g 35 °L•45 3 0 Cl/ O .01 I i Coe Got Ct 70 'ear Da' 2113 2 52. _ „o: 5 cr 7 50 e2 com1 ter tFl°6 r Sed II ZO i 15c 450 5 5 5 e I6, Pio P H ! CI Ci 75 ea r 5 1O "nazi 5o r 5 GrDW - 7 a • at -.r 75 2-a a - 9 74o f ,'K.r- Z , 1 I c,-3-3 Corgo --vo ec c'ecadia '507 72 iza 2 1 7 al", w2 rf r r 0 or 7_ Cr 4 O 4C5 IllieRatal 'Y or i 3 / 1 a art 6r 4) 4 r r sac , Agzeir9 o F 1' 95-1 it ffi or ,r '4J' .. ' I 4 I C , (3_ 0 Ms/ .2-5- a 71- cry zit i . rill 'CAW.. 0 2 / .1," I Cov 62) 2..5— i il tor I . ily7 - color/ --77 7 i to)/ —55 , .. _I. it 1 t )05-- 7 3 , 6, 4/ O. 04075 rkin of ill- .7 Ka° cer 4115 [ 2773 4 q 5 a ,z/7 I I . -45. 1 ( O it 1 Cr 4#' Erakili ' 8 O. ---I 2:55 42 ,06 •s a;(w,11.zoo O7 � 1 r , r f '5..f 1 1 t3 St, ran O 0 C IP- a Q11 67. GC/ / 25 12-c caY nriaramorim I EiIIIIIIM�iF .r t ' _ ' girn"CI 7 ci irMili -D.9. MitiZaRtnitill, ): iditeoso 02_ IMIEll ors 76 tz2,6 INISrazartatn, ' to iin .„ 4 ce. ced 2._ , MEI eta i / 0,0 coi.EINSINEaralli Mirrial IESIIMILIKI it 55 9 ii. 6 .., 6G Inn IMP211 rani Wia i - nilinge relitimal i Is)at fr ti �a IoND r Average 700; 11700;41 / o 4i 7 , -+' • z CPO agilialialarrialfit QA/QC Check; Completeness Legibility Accuracy Specifications Checked By _ Team Leader 4-rraos 001 AS-iQPA S -P1-225 G P043AS-007255-RT-644 57 of 381 3 r c400t -O r ,�d IC/ 7 3o g 35 lot 46 M MONTROSE L AIR QUALM SERVICES Project Information Date 02) • Ott 15 Customerifacility Unit ID""Sara pie Location Run 'Sampling Equipment las Meterbox ID limbilkal ID 'letho _ Field Datasheet (tsakinetic) Project* ,,, 'dry /C5I_ neeMme/off 0 Operator D3 Naezile ID Picot "r Probe I 1 441 5-- 3 Manomreter ID 2/2 .02 Sensitivity .fir'. X00.0/ r r-- Traverse Ela.psled CNctk Time Point* Time 24hr Sarnpiing Conditions Sialic Pressure, in_ H2O -` K Of Barometric Pressure, in. Hg 2 I-i ,. r _ Wind Speed a Direction Prate I Filter Temp Range, 0c 22 9 Calibration Mete tor Y 0 71 hie&erbux aHr,@, on. H2O ". S Nozzle diameter, C►n, in. 49. 7 3 Pito coefficient, Cp. 0. 211 O Manometer zero and level ''K -Factor 0 GM Reading. Vm,, 113. Yes Velocity Head., SP in H2O Ambient Temp, tF Ref. Barometer JD Precipitant Mid Page ar ALT Oil Slack 'Probe N. type 5,72„:07744, Equipment Checks Pilot IN ] pass @ in, FH20 Pilot (-). pass @ in. H2O Pito+i visual inspection Nozzle visual inspection Meter, arm in_ Hg Pre TC ID: Ambient 'IF Ref, °F ''Filter Box Filer Exit L Pass i _ pass Post Lkv j21ars pass airegass pass Intermediate leak check volume„ n3 Orifice ,Pressure D ff�erenliaf, ttH 3 a 9 Ave ra ges Y r cr5 1O I 2511 cd _ 35 115 C, I tcir j73 52-11 176, X100 3471 I ikyrip g I la. . 33 JO, 4. S C 2.t . re r Target 1 Actual Stack Temp, p et. 77 �i Go 4-1O 00 f tiro Cr. PI O r1- I C, ., G' 1 O 07 re2-4Ldi 610 3 r . Lt o. Lai JI 15 FO "Co. ' 717. 2 OO cdf.coC L , 0 II co , A 6r ti993 QAVC Check: Completeness 0r O O jr" = Otto ca. i O L -70 ire" 9 7 -2 ~7� ,12 I ell 04 GI° ce 62 I. Q911 - 0• 4), es r O 7-1 J J 610 2.4 f Probe Temp, °F [rcK-0r .1 } Meter outlet Im pAnger Exit Other Ref, Thermometer ID Continuity Check ❑ Continuity nuity+ w? Proper Polarity Notes: , 6 /` ° 2't Filter Temp, cF Irnpinger Exit Temp, T Dry Gas Meter Temperature, °F I 3 9 I se-joite3 2,57 car Lot' Pi ci O Si 0. 9! tit! i - clot cedor 4 Checked By q al 3 I 7 �1 Team Leander Iii 2.4 63 2/5 2501 2 L.;:-.5 sr 2 . 27-5 aft 25 2±1 LAI H-1 Inlet Outlet 3 Li Li 2 113 ti Legibility Accuracy. Specifications AT & 3 3 it CIP le 0 1 tel Sr E1 � eoct 172 5-3 a r fir'? 45-el Pump 'Vacuum in. Hg 2 2 if2 2 2 2 yerel n 1-) 001 AS -d", pi -2.i5 G P043AS-007255-RT-644 58 of 381 Nozzle 1 diameters Nozzle 2 diameters Nozzle 3 diameters ;Writ ID it Sample Location Run. / a 3 �MONTROSE IS Sample Recovery & Calibration Check Datasheet Project Information Dale Li nist_ Customer 1 Facility (13, i e„{— Operator tCv Project Page Of Equipment Identification Ref. Thermometer Hygrometer Field Balance 5 / 0 Check Weights CUL/ Calipers Balance Audit (old balance must be within 0059 of check weight mass) Date 4i/is/awl Standard mass, fj TOO- Ci- - Field balance mass, g Ambient Conditions (Mobile Lab) Relators humidity, Temper ar Temperature. Mobile Moisture Determination Contents Knockout ' --r- Impinger 1 Y\ Impinger 2 J/air 0 impinger 3 impinger 4 Impinger 5 impinger 6 Impinger 7 Impinger S Silica Gel Line Rinse Kuril Initial Final Net &tI bro-- Rim2 Run lnlflal Final Soo .o s� 4 Net Initial Final 7-01‘.9 _ __L`c, Net Di33i 3 Train Net Gain (Vic) '-� CI fi- Frazzle Measurements (Difference between any two measurements must not be more than 0.004 in (0.1 mm)) Di _ , D2 D3 Average Di 02 D3 Average Average dg .3 Di 02 03 Nozzle Material 0 quartz D glass 0 steel ° titanium 0 innonel El other Probe Type 0 heated 0 unheated El air-cooled 0 water-cooled 0 other Probe Liner Li quartz Cl glass Cl steel 0 Teflon Q other G1 /42a Filter Information Front Halt © quartz fiber fl glass fiber 0 Teflon E:1 Telionlquartz 0 other Filter Nwnber. Run 1: (05,& Run 2: tote/ RIM 3: Back Half. qua tiler 0 glass fiber O Teflon a Telioniquartz 171 other • Run Reagent Type Information Lot Dumber Sample Observations CIA/QC Check: Completeness Legibility Accuracy Specifications Checked by: Team Leader - - 001AS-QM -, 6 G P043AS-007255-RT-644 59 of 381 41%1 MON TROS E EPA Method 9 Opacity Datasheet Sec 15 45 15 30 1 45 Project NO. Pi`ic 0 01- Start Time 0:40 np. ClierittFac lity ;0 pier 0: fi Stcp Time Date 4 1- If isour `t, tion AWL( 0 _._ Sketch cif L Pin North Arrow 3altis Emission Paull • Ofrk Sun Shadow Line Process /CIO, ' Unit ''' Control Equipment _ mak Describe Emission Point 7Of o F k:�, 5rOwiek Height of Emission Point (ft) Start i Height of Em. Pt. Rel. to Observer (ft) Start A ( StoplT Distance to Emiss, Pt, (ft) Start 63 FT- Sto 3 Pt Direction to Emiss. Pt. (Degrees) Start Stop Vertical Angle to Obs. Pt. Start 40" tot's" I Direction to Oberva,tlon Point Start tiiV Stop Describe Emiss ons Start Ceo Emission Color Start Cip tor Stop fr Stop Cr Water Plume Attached Detached None Point in plume at Which observations were made 110 Liwgioi P�umf Describe Plume Background Start ' r ' 1 scup 6r till BaU�gro na Color Skye Start fPI Slop �f tart Backgro nd Color Sky Con . itr ' ns art i� Step �`' Mart ' p U 1 Stop C/Okt•Stv Y Wind Speed Start 0 .1 Mil Stop 01 . l i+ o Wind Direction Start N S Ambient Temperature Start 3is3 ' F Sto Wet Bull RHIzccgjit E}'I Observers Name eryir Observers Signature Certified B / from Date of Certification Additional Comments: ht) u tor Mien C O r 30 C) D 6 31 D 0 i 32 33 0 V 34 itj -0 35 36 37 38 39 40 11 41 42 43 44 15 45 16 46 17 47 59 Reviewed; FPM CPIM GP043AS-007255-RT-644 P01/04W 431 'il EPA Method 9 Opacity Datasheet (16 MONTROSE I 1'♦ I. Y I }�1 I Stert Time 14°' 40 Proled No. Prer _ 0b bel- lif Client/Facility Z , (, ° ni tAi Stop Time Date 4 4 - Source/Location ' tr4ko ok 4 CA sketch oLoOttion North Arrow Emission Point epee '.tilri Sun Shadow Line 0 r44 Process i 1 t\ IUflLL Control Equipment Describe Emission Point + I540A Qiece Height of Emission Point (ft) Height of Em. Pt. Rel. to Observer ft Start i Stop Start s_ [ 1e Stop 2 \ c Distan Start to Emiss. Pt. (ft) Tsto 3 FT Direction to imiss. Pt. (Degreesi Start Stop 0 Vertical Angie to Obs. Pt. Start 3o stop )0 a Direction t; Obervation Point Start Stop C.' Describe Start C fissions Emission Color Start CelQW Stop ce/ Stop CI g � 'Water Plume Attached I Detached II None Point in plume at which observations were made hilts, no v:+51bli r Diescr1b Plume Background Start , chit Sto Background Color Start (` Wind Speed Start l Stop jWirid [iirectio P�N$₹aIf N '� � stop f V 35 Ambient Start Temperature 70 Stop 6s F 'Wet Bulb 0 RFl Percent en Date oif Certification . q Certified Additional Comments: n et f?ikire Sec { 15 30 45 15 30 45 Min 0 0% 30 0 i0 0 31 V 3 0 —6c 0 4 —0 0 ,I 34 I ' e 0 0 1 35 D 0 36 7 37 8 38 9 39 10 i 40 41 11 12 42 13 43 44 14 15 16 46 47 17 18 I 48 19 49 20 50 21 51 22 52 23 ' 53 24 54 25 55 26 56 27 57 ,' 28 58 59 24 0 G P043AS-007255-RT-644 34/8 Reviewed: FPM CPM EPA Method 9 Opacity Datasheet (vs, MONTROSE ry L a 3 :tart Time 110404) Project No_ r 0 Client/Facility 0 Ch Pr NerbdStop Time d Source#Location , 'a/CO Date C--(74-1 Sketch of Location. North Arrow Emission Point S n Shadow Line I A Unit Process1:41/ Control Equipment _ be Emission Point 7679 orf- is -1h 5'1041 Height oloEptission Point (f) f Start i Stop Height opiEm.reyel. to Ob e ( ) Start r Stop 'Distance to Fa Start 63 tr- F't. (ft) Stop 03 Direction to En ss. Pt. (Degree94 Start Stop O Vertical AnWe ie to Obs_ Pt. Start 3Stop �0 I (/ Directioto Obervation Point Start Stop Cr :Describtenissions Start t f IV' Emissiort Col 4 Start Sty P aw stop Cl P - r Water Plume Attached [lOetactied Noner Point in plume at which observations were made PA pi itilannif vriedie Describe Plume Background Start i C Stop a•� Background Color Start 6 c t ` Stop 7 RI Sky Con . film Start Q0 idi Al Stop 1,/ Wind S eed Wind Direct too Start /1 Stop 9 mph Start N 7 -2 Ambler Start rperature Stop Wet Bulb t Date of Certification Additional Comments: ,, r plikne ild 02,01/,• G P043AS-007255-RT-644 Stop 1RHE;r5nt See 15 45 0 15 30 45 30 ' Main 0 6 10 ,„ey 0 i 0 I a r 6 6 31 2 ,i 0 di 6 No 32 3 O o 0 a 4 0 0 0 b 34 5 0 0 , 0 36 fo 0 6 ' (3 0 36. 7 ' V? I 8 38 9 39 10 - 40 11 -- - 41 13 _ 14 15 18 46 47 17 18 4 48 19 49 i I 20 50 i 21 ; 51 22 52 '23 53 24 25_ 55 26 5 21 57 58 - 29 59 4 4> j Reviewed: FPM CPM EPA Method 4-and40B Datasheet 3os Project Code Operator ?JO" 5 firirC 1/4 r.s. CPC 7 3-57 diet,. � Barometric Eresiure I'lgf, VII - 9 Source: , Notes: 741 7• 04/ A Run y - _ Meter y� DI, Start Ttnne: Stop Time: Total Average Total Avenge Maximum M1.a.xt"m um Totai RATA stun # Meter Box ID; Yd: Start lime: i Pre -Test Leak Check MO @ Stop Time: Sample Time Orifice Pressure rH2O j Sample Volume (ft3 Post -Test Leak Check (°M,O "Hg): DC M Temp ('7) Inlet Outlet imp, Outlet Temp �'F) Vacuum ("fig) a, 1 Total Average Total Average Maximum Maximum. Average Run 0 Impthger Weights UNTIROSE i 1 LIIli A C L. V "a' I :: _ F �. cO2 Pr&Test Leak Check ("H,0 if 'Ng): ,Past -Test Leak Chick ("M,o @ 11 Kgj: imply r.1 ImPhille 2 implInger 3 _ mpin ' 4 (SG) _ Total i Final Total it G P043AS-007255-RT-644 63 of 381 :Picri i cruaciri r P ?IA r -P rot EPA Method 4 and 308 E7atasheet ar Prooact Code P .3 •- (Jo 7 2. S' Operator: Clenta A/� j Barometric Pressure 1°H j: if - ' Source: I; - I Let -girl - Notes: I Date: 1 r lifiCi Z- l r� i L)NdlkO5f '- _" •'�r f Start Time: cc SO Stop Time: ,Post Weight: pi : 02001 CO21%):: Initial Weight: Trap ID: Run 0. �fl ID: Pre -Test Leak Check (H1O @ 'Kg): 's AV 5 Post -Test Leak Check ("Hi° @ 'K rt e� - _ 11 Sta TISK Ycl Post Weight: Notes: 02 00: Pre —Test Leak Check (11• eil : Past -Test Leak Check ' 1 '1 : Sample Time Sample Vlpm)Cr- Rate Sample Vohume (L) i0GM Temp I Imp. Cutlet Temp (*F) _ - Vacuum Ills4) Sample Tim. 'IPi Sample apni)rF) Rate ;Sample Volume (L) DGM Temp Imp. Outlet Temp P) Vacuum ("Hed Stack ( Tem e (`F) Ice Cele 11 et Lilt G % " M ✓'� I I� a _ Total Ave Total Average Maximum Maximum Total Run # Meter Box PD: I RATA Run # Yoh Affti Start Time: J Pre -Test Leak Check ("1120 @ ' Iig): Stop TImet Post -Test Leak Check (%H%0 @'Hg): Sample Time Orifice Pressure hH ("t 1 O), Volume Sample (fti Inlet DGM Temp rF) Cutlet Unpin Oudot Temp rni Vacuum nig) Total Average Total Average Maximum Maxim urn Avenge Total Average Maximum Impinger Weights Inatfaa Final Impinger I _ Impinger 2 lrtnptnger 3 _ limpinger i (SG) Total Total Maxirraim G P043AS-007255-RT-644 64 of 381 Reviewed: FP '9 CP14M coriti Operator:. Barometric Pressure CHg): Notes: EPA Method dinand-30B Datasheet 368 Project Code Client urte t 295 7W Time: p "Arne; Sample Time Average DGM Temp rF)) Inlet Outlet Total Average Total 414 942 Maximum Maximum MONTROSE le A_,' Ba lots ED Al 11 .t r J \ 1• a m pinger Weights uiItGat AsI ImpTrger I. _ Irn:pinger 2 Impinger 31 IrrpIager 4 (SG) total! To ta 1 t Ilk' G P043AS-007255-RT-644 65 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix A.5 Kiln 56 (Kiln 2) Instrumental Test Method Data G P043AS-007255-RT-644 66 of 381 4A, MONTROSE I AIR QUALIFY tiERvIEFS PROJ-007255 Biochar Now Kiln #56 4/14/2021 Test Run #1 Start Time 8:28 Run Length 120 Stop Time 10:40 Uncorrected Analyzer Data O2 CO2 NO„ CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 1 8:28 9.8 7.4 46.9 0.1 1.67 2 8:29 9.6 7.6 44.6 0.5 1.57 3 8:30 9.6 7.6 42.4 1.0 1.46 4 8:31 9.8 7.4 41.3 0.3 1.38 5 8:32 9.9 7.4 39.3 0.2 1.13 6 8:33 10.0 7.3 39.2 0.5 1.17 7 8:34 9.7 7.5 38.9 0.8 1.12 8 8:35 8.7 8.8 41.5 0.1 0.98 9 8:36 7.3 10.5 72.3 -0.1 0.93 10 8:37 7.0 11.2 86.2 -0.3 0.88 11 8:38 7.5 11.1 88.5 0.3 0.87 12 8:39 9.2 10.0 75.4 27.2 3.84 13 8:40 9.8 9.8 66.7 1074.7 27.02 14 8:41 8.5 11.4 101.3 762.7 2.22 15 8:42 8.5 11.5 95.9 316.3 1.95 16 8:43 8.2 11.8 102.1 285.2 1.77 17 8:44 8.2 11.8 105.3 264.2 1.57 18 8:45 7.8 12.2 125.5 162.5 0.90 19 8:46 8.1 12.1 133.7 105.2 0.89 20 8:47 8.2 12.0 143.7 127.7 0.91 21 8:48 8.4 11.8 151.7 153.4 0.91 22 8:49 8.2 11.9 162.7 136.9 0.87 23 8:50 8.1 12.1 176.7 96.5 0.83 24 8:51 8.2 12.0 185.5 72.3 0.80 25 8:52 6.9 13.3 234.3 52.8 0.75 26 8:53 8.1 12.1 206.8 65.7 0.81 27 8:54 8.3 12.0 208.5 61.9 0.73 28 8:55 8.5 11.8 195.6 69.0 0.76 29 8:56 8.7 11.6 174.6 83.9 0.73 30 8:57 8.4 11.8 166.5 119.5 0.74 31 8:58 7.9 12.2 203.8 70.6 0.66 32 8:59 7.7 12.3 211.0 24.0 0.67 33 9:00 9.0 11.2 174.8 68.7 1.13 34 9:01 10.3 9.8 118.1 505.7 11.78 35 9:02 10.4 9.6 108.9 1147.8 18.36 36 9:03 10.4 9.6 105.2 1139.4 17.06 37 9:04 10.4 9.6 101.7 1139.2 17.76 38 9:05 10.3 9.8 103.6 990.6 10.54 39 9:06 10.2 9.8 104.7 664.0 6.76 40 9:07 10.2 9.8 104.1 699.9 8.28 41 9:08 10.0 10.1 107.8 592.3 3.07 42 9:09 10.1 10.0 105.3 492.9 3.27 43 9:10 10.1 10.0 108.9 459.5 2.19 44 9:11 10.0 10.1 111.2 409.9 2.88 45 9:12 10.6 9.4 96.9 623.4 9.54 46 9:13 10.5 9.4 98.4 807.2 7.97 47 9:14 10.7 9.3 98.1 811.2 7.49 48 9:15 10.3 9.7 109.2 641.7 2.86 49 9:16 10.3 9.8 113.2 480.0 2.46 50 9:17 10.0 10.0 121.2 418.4 1.67 51 9:18 10.3 9.8 119.1 310.9 1.54 52 9:19 10.3 9.7 116.0 437.4 1.63 53 9:20 10.4 9.7 115.8 405.1 2.32 54 9:21 10.6 9.4 109.7 498.3 3.98 55 9:22 10.7 9.3 106.2 515.0 4.01 56 9:23 10.9 9.1 102.6 566.0 5.40 57 9:24 10.7 9.3 102.4 586.3 3.77 58 9:25 10.8 9.1 97.0 541.5 5.53 59 9:26 10.9 9.0 93.9 669.7 7.37 60 9:27 10.4 9.5 104.4 515.2 2.57 61 9:40 10.8 8.8 82.5 203.4 0.94 62 9:41 10.8 8.8 82.5 260.9 1.00 63 9:42 10.6 9.0 86.5 262.7 0.67 64 9:43 10.7 9.0 82.9 256.1 1.00 65 9:44 10.5 9.2 85.0 277.4 1.11 66 9:45 10.6 9.2 82.1 321.6 1.12 67 9:46 10.7 9.0 79.5 300.6 0.78 68 9:47 10.8 8.8 71.2 288.2 1.30 69 9:48 10.8 8.8 71.2 332.1 1.26 70 9:49 10.3 9.4 73.1 209.3 0.37 G P043AS-007255-RT-644 67 of 381 PROJ-007255 Biochar Now Kiln #56 4/14/2021 Test Run #1 Start Time 8:28 Run Length 120 Stop Time 10:40 Uncorrected Analyzer Data O2 CO2 NO„ CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 71 9:50 10.3 9.4 73.1 141.2 0.36 72 9:51 10.2 9.5 72.2 169.1 0.36 73 9:52 10.1 9.5 70.7 112.9 0.38 74 9:53 9.9 9.8 73.7 134.0 0.40 75 9:54 9.9 9.7 73.4 160.4 0.41 76 9:55 9.8 9.8 76.3 114.8 0.31 77 9:56 9.9 9.7 72.9 121.6 0.25 78 9:57 9.9 9.7 72.9 94.6 0.20 79 9:58 9.7 9.9 76.9 56.9 0.21 80 9:59 9.7 9.9 76.9 103.1 0.33 81 10:00 9.8 9.8 76.1 62.4 0.22 82 10:01 9.4 10.1 81.8 55.3 0.20 83 10:02 9.5 10.0 82.0 37.9 0.16 84 10:03 8.9 10.6 92.3 21.3 0.08 85 10:04 8.9 10.6 91.8 63.6 0.17 86 10:05 9.9 9.7 78.5 109.9 0.26 87 10:06 9.9 9.7 78.5 86.7 0.14 88 10:07 9.8 9.7 78.2 76.4 0.16 89 10:08 9.8 9.7 78.2 104.3 0.16 90 10:09 9.9 9.7 76.8 71.6 0.16 91 10:10 9.7 9.9 79.1 63.1 0.19 92 10:11 9.7 9.9 79.5 67.7 0.18 93 10:12 9.6 10.0 80.3 62.4 0.17 94 10:13 9.6 9.9 78.6 78.0 0.18 95 10:14 9.3 10.1 76.8 74.1 0.22 96 10:15 9.3 10.1 76.8 67.0 0.15 97 10:16 9.4 10.0 68.9 76.6 0.12 98 10:17 9.4 10.0 68.9 53.1 0.06 99 10:18 9.3 10.1 67.8 58.1 0.18 100 10:19 9.3 10.1 66.4 47.1 0.07 101 10:20 9.4 10.0 64.7 84.2 -0.02 102 10:21 9.7 9.7 61.3 69.2 -0.16 103 10:22 9.5 9.9 61.7 92.0 -0.12 104 10:23 8.1 11.2 80.6 74.1 -0.17 105 10:24 8.1 11.2 80.6 9.1 -0.10 106 10:25 8.3 11.3 83.3 5.9 -0.09 107 10:26 8.3 11.3 83.3 11.0 -0.14 108 10:27 8.5 11.2 84.8 12.9 -0.08 109 10:28 9.1 10.7 82.2 12.3 -0.09 110 10:29 9.4 10.4 81.2 9.5 -0.03 111 10:30 9.4 10.5 82.9 14.5 0.01 112 10:31 9.5 10.5 83.5 20.0 -0.01 113 10:32 9.4 10.5 85.6 29.3 -0.04 114 10:33 9.4 10.5 85.6 16.7 0.03 115 10:34 9.3 10.5 86.3 25.4 0.01 116 10:35 9.3 10.5 86.3 14.3 -0.03 117 10:36 9.2 10.6 88.1 14.1 -0.03 118 10:37 9.3 10.6 87.9 15.2 -0.01 119 10:38 9.2 10.7 90.1 16.1 0.02 120 10:39 9.2 10.7 91.4 16.2 0.09 Average Co Cm Cma Corrected Average: 9.50 0.0 10.47 10.52 10.1 0.1 8.14 7.937 96.6 0.2 145.0 144.9 225.8 1.0 2545 2490 9.54 I 9.87 96.4 I 220 2.10 G P043AS-007255-RT-644 68 of 381 PROJ-007255 Biochar Now Kiln #56 4/14/2021 Test Run #2 Start Time 11:47 Run Length 120 Stop Time 13:58 Uncorrected Analyzer Data O2 CO2 NO„ CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 1 11:47 10.1 10.0 138.4 4.3 1.9 2 11:48 10.4 9.7 132.7 3.4 1.5 3 11:49 10.4 9.7 132.7 5.0 1.3 4 11:50 9.9 10.2 137.6 3.7 1.2 5 11:51 9.9 10.2 137.6 2.5 1.2 6 11:52 9.8 10.3 140.0 2.6 1.1 7 11:53 9.9 10.1 138.1 2.4 1.0 8 11:54 10.0 9.9 135.8 2.5 0.9 9 11:55 10.2 9.7 133.2 3.4 0.9 10 11:56 10.4 9.5 129.1 3.6 1.0 11 11:57 10.3 9.6 131.6 3.8 1.1 12 11:58 10.3 9.6 131.6 3.9 1.0 13 11:59 10.4 9.6 130.0 5.7 0.9 14 12:00 10.4 9.6 130.0 3.7 0.9 15 12:01 10.6 9.4 124.1 5.1 0.8 16 12:02 10.8 9.2 120.9 5.1 0.8 17 12:03 10.8 9.2 120.8 6.3 0.6 18 12:04 10.7 9.3 122.7 7.1 0.7 19 12:05 10.6 9.3 123.0 8.8 0.8 20 12:06 10.5 9.5 126.6 5.5 0.8 21 12:07 10.5 9.5 126.6 5.5 0.8 22 12:08 10.5 9.5 125.7 5.4 0.8 23 12:09 10.5 9.5 125.7 5.9 0.8 24 12:10 10.6 9.6 127.8 4.9 0.7 25 12:11 10.5 9.6 126.4 4.8 0.7 26 12:12 10.3 9.7 131.5 3.9 0.7 27 12:13 10.6 9.5 129.3 3.7 0.6 28 12:14 10.5 9.6 130.0 4.6 0.5 29 12:15 10.6 9.6 128.2 5.3 0.6 30 12:16 10.6 9.6 128.2 3.8 0.6 31 12:17 10.4 9.8 133.2 3.8 0.6 32 12:18 10.4 9.8 133.2 2.9 0.6 33 12:19 10.7 9.5 129.5 3.0 0.6 34 12:20 10.7 9.4 126.9 4.6 0.5 35 12:21 10.4 9.8 133.1 3.9 0.5 36 12:22 10.3 9.8 133.2 3.6 0.5 37 12:23 10.6 9.6 126.5 3.4 0.5 38 12:24 10.5 9.6 128.7 3.5 0.5 39 12:25 10.5 9.6 128.7 3.6 0.5 40 12:26 11.1 9.1 121.9 4.4 0.5 41 12:27 11.1 9.1 121.9 5.3 0.4 42 12:28 11.3 9.0 120.5 5.6 0.4 43 12:29 11.5 8.7 116.7 6.9 0.3 44 12:30 11.7 8.5 114.6 6.7 0.3 45 12:31 11.2 8.9 120.3 6.9 0.2 46 12:32 10.8 9.4 126.4 4.9 0.2 47 12:33 11.0 9.1 121.2 4.9 0.3 48 12:34 11.0 9.1 121.2 5.6 0.3 49 12:35 10.8 9.3 122.2 7.6 0.4 50 12:36 10.8 9.3 122.2 7.3 0.4 51 12:37 11.2 8.9 118.8 5.7 0.4 52 12:38 11.2 9.0 120.6 5.5 0.4 53 12:39 11.0 9.2 123.5 5.0 0.5 54 12:40 11.0 9.2 125.2 6.3 0.4 55 12:41 11.3 8.9 122.3 7.3 0.4 56 12:42 11.7 8.5 120.0 8.1 0.3 57 12:43 11.7 8.5 120.0 7.5 0.2 58 12:44 11.5 8.7 123.6 7.8 0.2 59 12:45 11.5 8.7 123.6 6.7 0.2 60 12:46 10.5 9.8 144.7 5.3 0.2 61 12:58 11.9 8.7 143.5 79.5 0.3 62 12:59 11.9 8.7 143.5 116.6 0.4 63 13:00 12.0 8.6 139.7 96.3 0.3 64 13:01 11.9 8.6 142.9 64.4 0.4 65 13:02 12.0 8.6 142.5 95.0 0.5 66 13:03 12.0 8.5 141.4 65.3 0.5 67 13:04 11.9 8.7 147.2 53.2 0.6 68 13:05 11.9 8.6 144.2 100.1 0.6 69 13:06 11.9 8.6 144.2 117.0 0.8 70 13:07 12.1 8.4 138.7 155.6 0.8 G P043AS-007255-RT-644 69 of 381 PROJ-007255 Biochar Now Kiln #56 4/14/2021 Test Run #2 Start Time 11:47 Run Length 120 Stop Time 13:58 Uncorrected Analyzer Data O2 CO2 NOx CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 71 13:08 12.1 8.4 138.7 189.7 1.0 72 13:09 12.2 8.3 136.2 124.0 0.6 73 13:10 11.4 9.3 156.0 43.9 0.6 74 13:11 11.1 9.4 162.1 49.3 0.7 75 13:12 11.2 9.3 162.7 49.3 0.7 76 13:13 11.1 9.4 170.4 23.0 0.7 77 13:14 11.6 9.0 175.2 22.3 0.6 78 13:15 11.6 9.0 175.2 12.3 0.5 79 13:16 11.1 9.6 192.8 6.9 0.4 80 13:17 11.1 9.6 192.8 16.0 0.5 81 13:18 11.6 9.0 178.5 19.8 0.6 82 13:19 11.4 9.2 183.1 26.2 0.7 83 13:20 11.6 9.0 178.7 38.3 0.7 84 13:21 11.9 8.6 167.5 38.4 0.5 85 13:22 11.2 9.3 180.3 23.5 0.5 86 13:23 10.7 9.8 192.4 18.5 0.4 87 13:24 10.7 9.8 192.4 16.7 0.5 88 13:25 11.0 9.4 170.0 37.8 0.5 89 13:26 11.0 9.4 170.0 79.6 0.6 90 13:27 11.7 8.7 158.2 67.8 0.7 91 13:28 11.8 8.5 154.5 107.9 0.7 92 13:29 11.7 8.6 153.8 77.6 0.6 93 13:30 11.6 8.7 150.7 118.7 0.5 94 13:31 11.8 8.5 140.2 218.5 0.7 95 13:32 11.2 9.0 147.2 217.3 0.3 96 13:33 11.2 9.0 147.2 145.5 0.2 97 13:34 10.6 9.5 159.8 107.0 0.3 98 13:35 10.6 9.5 159.8 92.6 0.2 99 13:36 10.9 9.3 156.9 66.9 0.2 100 13:37 10.5 9.7 158.9 65.5 0.3 101 13:38 10.3 9.8 158.0 125.0 0.9 102 13:39 10.7 9.4 147.8 138.6 0.4 103 13:40 10.6 9.4 154.2 109.1 0.3 104 13:41 10.7 9.4 171.0 63.2 0.3 105 13:42 10.7 9.4 171.0 54.5 0.2 106 13:43 11.2 8.9 170.9 55.6 0.2 107 13:44 11.2 8.9 170.9 55.3 0.2 108 13:45 11.4 8.7 169.0 77.1 0.2 109 13:46 11.5 8.6 168.8 71.0 0.2 110 13:47 11.8 8.3 164.8 96.2 0.3 111 13:48 11.8 8.2 162.9 103.3 0.5 112 13:49 12.0 8.0 159.7 159.7 0.5 113 13:50 11.8 8.1 161.8 160.6 0.5 114 13:51 11.8 8.1 161.8 161.1 0.6 115 13:52 11.8 8.0 163.6 169.7 0.5 116 13:53 11.8 8.0 163.6 136.1 0.5 117 13:54 12.0 7.9 165.4 163.9 0.7 118 13:55 12.4 7.5 158.7 239.2 1.2 119 13:56 12.5 7.3 155.6 300.7 1.7 120 13:57 12.6 7.2 149.4 332.1 2.2 Average Co Cm Cma Corrected Average: 11.1 0.0 10.4 10.5 9.1 0.1 8.1 7.9 144.0 0.5 145.3 144.9 51.1 -0.2 2510.1 2490.0 11.2 8.91 144 50.9 0.59 G P043AS-007255-RT-644 70 of 381 PROJ-007255 Biochar Now Kiln #56 4/14/2021 Test Run #3 Start Time 15:00 Run Length 120 Stop Time 17:16 Uncorrected Analyzer Data O2 CO2 NO„ CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 1 15:00 11.1 8.0 151.8 18.6 0.5 2 15:01 11.9 7.3 134.5 17.9 0.6 3 15:02 10.2 8.6 157.4 18.0 0.5 4 15:03 10.1 8.7 156.7 16.5 0.5 5 15:04 11.8 7.3 129.3 74.2 0.7 6 15:05 10.1 8.7 156.4 109.7 0.5 7 15:06 9.6 9.2 166.1 57.5 0.7 8 15:07 9.4 9.3 168.3 33.6 1.3 9 15:08 9.3 9.5 163.7 19.2 2.0 10 15:09 9.1 9.5 159.8 15.2 2.9 11 15:10 9.3 9.4 152.8 21.7 2.7 12 15:11 9.1 9.6 158.3 30.7 2.4 13 15:12 9.3 9.5 153.6 18.8 2.5 14 15:13 10.4 8.5 138.2 18.8 3.1 15 15:14 9.9 9.0 146.8 20.4 3.0 16 15:15 10.2 8.6 141.6 16.1 2.8 17 15:16 9.4 9.4 153.6 15.7 2.5 18 15:17 9.2 9.5 152.0 20.2 2.2 19 15:18 9.0 9.7 153.2 28.6 2.0 20 15:19 10.3 8.6 137.8 17.9 1.9 21 15:20 10.6 8.4 132.2 18.8 1.7 22 15:21 10.1 8.8 140.0 14.2 1.6 23 15:22 10.4 8.5 135.6 17.6 1.5 24 15:23 10.5 8.5 135.3 17.6 1.3 25 15:24 9.9 9.1 144.5 12.1 1.2 26 15:25 9.0 9.7 152.5 6.0 1.0 27 15:26 9.0 9.7 150.0 6.4 0.9 28 15:27 9.5 9.3 142.2 5.7 0.8 29 15:28 8.8 9.8 151.1 6.3 0.7 30 15:29 9.0 9.7 149.0 6.0 0.7 31 15:30 9.1 9.6 146.9 6.1 0.7 32 15:31 9.6 9.2 140.4 4.8 0.7 33 15:32 9.4 9.4 141.5 5.1 0.7 34 15:33 8.8 9.8 146.0 5.0 0.6 35 15:34 8.3 10.2 148.6 3.6 0.5 36 15:35 8.3 10.3 146.1 3.6 0.5 37 15:36 8.2 10.3 144.0 3.7 0.5 38 15:37 8.5 10.1 141.3 4.0 0.5 39 15:38 8.2 10.4 143.6 4.1 0.4 40 15:39 8.6 10.1 140.4 3.9 0.4 41 15:40 8.1 10.4 143.9 3.8 0.4 42 15:41 8.3 10.3 142.5 3.5 0.4 43 15:42 9.7 9.1 126.3 2.4 0.3 44 15:43 9.5 9.3 129.3 3.5 0.3 45 15:44 8.4 10.2 139.0 4.4 0.3 46 15:45 9.0 9.7 132.2 5.8 0.4 47 15:46 9.6 9.3 127.1 8.1 0.4 48 15:47 9.8 9.1 126.5 10.8 0.4 49 15:48 11.1 7.9 111.2 18.7 0.5 50 15:49 11.5 7.6 109.4 28.2 0.5 51 15:50 11.2 7.9 114.2 24.2 0.5 52 15:51 9.3 9.4 135.0 15.1 0.4 53 15:52 9.2 9.6 134.7 6.5 0.4 54 15:53 9.5 9.3 128.4 6.9 0.4 55 15:54 9.8 9.1 125.4 8.0 0.5 56 15:55 8.8 9.9 135.0 6.0 0.4 57 15:56 8.1 10.4 141.4 3.8 0.4 58 15:57 8.0 10.6 143.2 3.9 0.4 59 15:58 9.2 9.6 130.3 4.8 0.4 60 15:59 8.8 9.9 136.8 6.1 0.4 61 16:16 7.7 10.9 135.1 7.0 0.2 62 16:17 7.7 10.9 135.1 8.4 0.3 63 16:18 8.4 10.3 126.5 12.2 0.2 64 16:19 8.5 10.2 125.8 11.2 0.2 65 16:20 8.8 10.0 124.3 8.7 0.2 66 16:21 8.3 10.4 131.6 7.5 0.2 67 16:22 8.4 10.3 128.9 7.3 0.2 68 16:23 8.0 10.6 130.2 6.4 0.2 69 16:24 8.0 10.6 130.2 6.7 0.2 70 16:25 8.2 10.4 128.2 7.7 0.2 G P043AS-007255-RT-644 71 of 381 PROJ-007255 Biochar Now Kiln #56 4/14/2021 Test Run #3 Start Time 15:00 Run Length 120 Stop Time 17:16 Uncorrected Analyzer Data O2 CO2 NO„ CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 71 16:26 8.2 10.4 128.2 7.6 0.2 72 16:27 8.2 10.5 127.5 7.8 0.1 73 16:28 8.2 10.5 126.9 7.5 0.1 74 16:29 8.1 10.6 129.9 7.2 0.1 75 16:30 8.4 10.3 128.1 7.6 0.1 76 16:31 8.7 10.0 124.4 11.5 0.1 77 16:32 8.5 10.1 122.7 9.1 0.1 78 16:33 8.5 10.1 122.7 7.8 0.1 79 16:34 9.0 9.8 111.2 7.5 0.1 80 16:35 9.0 9.8 111.2 11.4 0.1 81 16:36 8.7 10.0 112.2 10.2 0.1 82 16:37 8.4 10.2 113.4 11.0 0.1 83 16:38 8.5 10.2 110.9 10.8 0.1 84 16:39 8.2 10.4 111.1 10.5 0.1 85 16:40 8.2 10.4 109.7 13.2 0.1 86 16:41 8.1 10.4 106.8 9.4 0.1 87 16:42 8.1 10.4 106.8 8.2 0.1 88 16:43 8.1 10.5 104.7 10.5 0.1 89 16:44 8.1 10.5 104.7 11.8 0.1 90 16:45 8.3 10.3 101.7 11.3 0.1 91 16:46 8.4 10.2 101.7 13.2 0.1 92 16:47 8.5 10.1 100.4 10.0 0.0 93 16:48 8.2 10.4 102.6 13.9 0.1 94 16:49 8.5 10.2 99.3 14.8 0.0 95 16:50 8.6 10.1 97.1 15.3 0.0 96 16:51 8.6 10.1 97.1 10.0 0.0 97 16:52 8.3 10.3 98.1 11.2 0.0 98 16:53 8.3 10.3 98.1 11.6 0.0 99 16:54 8.3 10.3 98.1 11.0 -0.1 100 16:55 8.2 10.4 99.7 11.2 0.0 101 16:56 8.4 10.3 98.0 11.8 0.0 102 16:57 8.1 10.5 99.7 11.4 0.0 103 16:58 8.2 10.3 98.7 10.6 0.0 104 16:59 8.1 10.5 100.1 9.5 0.0 105 17:00 8.1 10.5 100.1 10.9 0.1 106 17:01 8.1 10.5 100.2 11.7 0.2 107 17:02 8.1 10.5 100.2 12.0 0.3 108 17:03 8.7 10.1 95.9 19.5 0.4 109 17:04 9.6 9.4 87.8 19.1 0.5 110 17:05 8.8 10.0 93.6 11.1 0.6 111 17:06 8.1 10.4 99.1 6.1 0.6 112 17:07 8.0 10.5 99.3 5.7 0.6 113 17:08 8.1 10.5 99.5 4.9 0.6 114 17:09 8.1 10.5 99.5 8.5 0.6 115 17:10 8.0 10.5 99.6 5.5 0.6 116 17:11 8.0 10.5 99.6 6.7 0.6 117 17:12 8.1 10.4 98.4 6.8 0.7 118 17:13 8.0 10.6 99.4 5.6 0.7 119 17:14 8.1 10.5 98.6 5.1 0.6 120 17:15 8.1 10.4 97.5 7.1 0.5 Average Co Cm Cma Corrected Average: 8.89 0.0 10.4 10.5 9.80 0.1 8.1 7.9 125.7 0.5 145.0 144.9 12.5 0.3 2523.5 2490.0 8.99 I 9.64 126 12.1 0.60 G P043AS-007255-RT-644 72 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix A.6 Kiln 65 (Kiln 1) Instrumental Test Method Data G P043AS-007255-RT-644 73 of 381 ti\ MONTROSE I AIR QUALIFY tiERvIEFS PROJ-007255 Biochar Now Kiln #65 4/13/2021 Test Run #1 Start Time 8:11 Run Length 120 Stop Time 10:34 Uncorrected Analyzer Data O2 CO2 NO„ CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 1 8:11 10.0 7.0 65.1 2.0 0.61 2 8:12 9.5 7.3 67.5 1.7 0.56 3 8:13 12.4 5.3 49.3 2.1 0.56 4 8:14 12.6 5.1 45.6 16.8 0.32 5 8:15 12.5 5.2 45.5 5.0 0.22 6 8:16 12.5 5.2 45.0 2.7 0.17 7 8:17 12.2 5.3 45.9 1.7 0.06 8 8:18 11.6 5.9 44.2 1.6 0.09 9 8:19 11.7 6.0 38.7 2.6 0.84 10 8:20 12.0 5.8 33.8 3.9 0.83 11 8:21 11.5 6.6 38.7 6.5 0.51 12 8:22 10.0 8.3 56.6 18.9 0.82 13 8:23 7.0 11.3 86.5 3.6 0.81 14 8:24 7.7 11.2 90.8 3.2 0.97 15 8:25 7.8 11.1 90.1 2.6 0.88 16 8:26 8.1 10.8 89.9 4.6 0.75 17 8:27 8.7 10.3 88.8 11.3 0.80 18 8:28 8.6 10.6 101.8 11.3 0.72 19 8:29 8.4 10.8 111.6 8.6 0.74 20 8:30 8.3 10.9 122.7 7.3 0.69 21 8:31 8.3 10.9 127.3 6.0 0.72 22 8:32 8.5 10.8 129.0 6.7 0.75 23 8:33 8.5 10.8 134.2 6.2 0.86 24 8:34 8.4 10.8 143.4 6.3 0.90 25 8:35 8.4 10.9 155.1 5.9 0.88 26 8:36 8.9 10.5 153.4 13.9 0.97 27 8:37 9.1 10.3 156.1 66.7 0.97 28 8:38 9.0 10.4 169.2 50.4 0.87 29 8:39 8.9 10.5 179.9 26.5 0.82 30 8:40 8.7 10.7 185.1 18.2 0.73 31 8:41 8.7 10.8 187.5 10.1 0.66 32 8:42 8.6 10.8 187.1 7.2 0.63 33 8:43 9.1 10.5 168.8 24.5 0.77 34 8:44 9.1 10.4 162.0 19.2 0.75 35 8:45 9.2 10.4 155.9 27.6 0.78 36 8:46 9.2 10.5 152.4 46.7 0.88 37 8:47 9.2 10.4 149.6 39.5 0.86 38 8:48 9.3 10.4 145.0 30.7 0.94 39 8:49 9.2 10.4 140.4 26.6 0.99 40 8:50 9.3 10.3 132.1 28.6 1.06 41 8:51 9.2 10.3 127.6 30.7 1.06 42 8:52 9.3 10.3 124.7 32.4 0.91 43 8:53 9.4 10.2 119.4 41.0 0.90 44 8:54 9.4 10.1 111.6 75.2 1.01 45 8:55 9.5 10.0 101.8 151.9 1.39 46 8:56 9.3 10.1 97.5 84.3 1.21 47 8:57 9.5 9.9 88.3 98.1 1.36 48 8:58 9.8 9.6 80.5 206.7 1.82 49 8:59 10.0 9.4 75.5 242.2 2.02 50 9:00 10.2 9.2 71.8 301.3 1.90 51 9:01 9.6 9.6 77.2 208.7 0.64 52 9:02 9.6 9.5 74.5 36.9 0.71 53 9:03 9.7 9.4 71.4 41.1 0.81 54 9:04 9.8 9.3 69.1 43.1 0.92 55 9:05 10.0 9.1 65.1 60.4 0.81 56 9:06 9.9 9.2 64.8 73.0 0.83 57 9:07 9.9 9.2 63.8 66.9 0.71 58 9:08 9.8 9.2 63.8 56.4 0.53 59 9:09 9.9 9.1 62.1 45.2 0.44 60 9:10 9.9 9.1 60.8 30.4 0.52 61 9:34 10.8 7.9 36.6 151.5 -0.01 62 9:35 10.8 7.8 36.3 161.8 0.04 63 9:36 10.8 7.8 36.3 154.2 0.01 64 9:37 10.5 8.0 36.6 143.5 0.05 65 9:38 10.5 8.0 36.6 142.3 0.21 66 9:39 10.5 8.0 36.5 121.2 0.39 67 9:40 10.5 8.0 36.5 110.9 0.54 68 9:41 10.6 7.9 35.6 120.9 0.69 69 9:42 10.6 8.0 36.6 105.4 0.62 70 9:43 10.5 8.0 36.4 86.6 0.67 G P043AS-007255-RT-644 74 of 381 PROJ-007255 Biochar Now Kiln #65 4/13/2021 Test Run #1 Start Time 8:11 Run Length 120 Stop Time 10:34 Uncorrected Analyzer Data O2 CO2 NO„ CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 71 9:44 10.4 8.1 37.0 100.3 0.94 72 9:45 10.4 8.1 37.0 67.0 0.80 73 9:46 10.5 8.0 36.7 84.2 0.87 74 9:47 10.5 8.0 36.7 78.1 0.98 75 9:48 10.5 8.0 37.4 70.7 0.86 76 9:49 10.5 8.0 37.4 70.9 0.67 77 9:50 10.6 8.1 37.5 57.4 0.64 78 9:51 10.5 8.2 38.2 48.6 0.69 79 9:52 10.5 8.1 37.4 56.9 0.71 80 9:53 10.8 7.9 36.4 74.0 0.51 81 9:54 10.8 7.9 36.4 78.6 0.28 82 9:55 10.8 7.9 36.4 58.3 0.24 83 9:56 10.8 7.9 36.4 47.1 0.25 84 9:57 10.6 8.2 36.9 65.3 0.39 85 9:58 10.6 8.2 36.9 55.6 0.52 86 9:59 10.3 8.4 38.5 53.0 0.63 87 10:00 10.2 8.5 39.4 51.2 0.91 88 10:01 10.3 8.4 39.3 47.5 0.96 89 10:02 10.4 8.3 39.6 44.2 1.05 90 10:03 10.4 8.3 39.6 36.0 1.20 91 10:04 10.3 8.4 41.9 41.3 1.10 92 10:05 10.3 8.4 41.9 41.7 1.07 93 10:06 10.3 8.5 44.0 44.6 1.08 94 10:07 10.3 8.5 44.0 33.3 1.09 95 10:08 10.6 8.3 45.1 30.5 1.01 96 10:09 10.4 8.5 45.3 31.2 0.99 97 10:10 10.8 8.1 41.8 40.3 1.04 98 10:11 10.9 8.1 41.4 46.2 0.87 99 10:12 10.9 8.1 41.4 50.3 0.73 100 10:13 10.6 8.3 44.4 48.1 0.64 101 10:14 10.6 8.3 44.4 38.6 0.82 102 10:15 10.4 8.5 44.8 36.3 1.00 103 10:16 10.4 8.5 44.8 34.1 1.23 104 10:17 10.7 8.2 42.4 48.6 1.26 105 10:18 10.7 8.1 41.4 43.9 1.24 106 10:19 10.9 8.0 40.3 51.6 1.09 107 10:20 10.7 8.2 41.7 48.4 0.91 108 10:21 10.7 8.2 41.7 53.4 0.90 109 10:22 10.4 8.4 43.4 50.5 0.97 110 10:23 10.4 8.4 43.4 51.4 0.96 111 10:24 10.5 8.4 44.6 43.7 1.05 112 10:25 10.5 8.4 44.6 42.6 1.13 113 10:26 10.3 8.6 48.3 48.1 1.24 114 10:27 10.2 8.7 50.7 43.3 1.27 115 10:28 10.5 8.5 51.6 49.9 1.18 116 10:29 10.4 8.6 54.6 46.3 1.09 117 10:30 10.4 8.6 54.6 33.5 0.95 118 10:31 10.5 8.5 61.1 32.4 0.89 119 10:32 10.5 8.5 61.1 22.2 0.96 120 10:33 10.4 8.7 67.2 25.4 1.05 Average Co Cm Cma Corrected Average: 10.0 0.0 10.5 10.52 8.80 0.0 7.97 7.937 72.1 0.1 144 144.9 52.5 0.6 2446 2490 10.1 I 8.77 72.7 I 52.8 0.81 G P043AS-007255-RT-644 75 of 381 PROJ-007255 Biochar Now Kiln #65 4/13/2021 Test Run #2 Start Time 11:57 Run Length 120 Stop Time 14:09 Uncorrected Analyzer Data O2 CO2 NO„ CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 1 11:57 10.3 9.3 115.1 11.3 -0.2 2 11:58 10.3 9.3 115.1 11.5 -0.1 3 11:59 10.4 9.3 113.6 11.2 -0.1 4 12:00 10.6 9.0 109.6 17.1 0.2 5 12:01 10.7 8.8 106.1 23.7 0.3 6 12:02 10.8 8.7 103.4 27.5 0.5 7 12:03 11.1 8.5 98.8 24.8 0.7 8 12:04 10.9 8.7 100.3 25.7 0.8 9 12:05 10.6 9.0 102.6 24.4 0.7 10 12:06 10.5 8.9 103.4 20.4 0.5 11 12:07 10.5 8.9 103.4 22.0 0.5 12 12:08 10.6 8.9 102.2 19.5 0.4 13 12:09 10.4 9.0 105.9 15.9 0.2 14 12:10 10.4 9.1 107.5 13.8 0.2 15 12:11 10.3 9.2 109.4 13.9 0.1 16 12:12 10.3 9.2 110.8 12.6 0.3 17 12:13 10.3 9.2 112.3 11.5 0.4 18 12:14 10.2 9.3 115.8 10.4 0.1 19 12:15 10.3 9.3 120.8 11.9 0.0 20 12:16 10.3 9.3 120.8 8.7 -0.1 21 12:17 10.2 9.3 125.8 8.1 -0.1 22 12:18 10.3 9.3 126.8 9.5 -0.2 23 12:19 10.2 9.3 131.2 7.6 -0.3 24 12:20 10.2 9.4 136.3 7.2 -0.4 25 12:21 10.2 9.4 136.6 8.3 -0.4 26 12:22 10.4 9.3 136.0 7.4 -0.4 27 12:23 10.2 9.4 140.4 9.4 -0.4 28 12:24 10.3 9.5 138.6 8.2 -0.5 29 12:25 10.3 9.5 138.6 10.1 -0.5 30 12:26 10.4 9.3 137.2 14.3 -0.5 31 12:27 10.5 9.2 133.0 12.0 -0.6 32 12:28 10.4 9.3 134.4 11.5 -0.5 33 12:29 10.5 9.2 130.5 15.6 -0.5 34 12:30 10.7 9.1 125.2 22.0 -0.5 35 12:31 10.8 9.0 121.6 23.1 -0.5 36 12:32 10.7 9.0 121.0 14.0 -0.4 37 12:33 10.3 9.4 124.3 12.2 -0.5 38 12:34 10.3 9.4 124.3 14.6 -0.5 39 12:35 10.4 9.3 119.9 13.8 -0.5 40 12:36 10.6 9.1 114.6 16.2 -0.5 41 12:37 10.6 9.1 111.8 21.7 -0.6 42 12:38 10.7 9.0 108.2 23.7 -0.6 43 12:39 10.6 9.0 106.4 19.0 -0.5 44 12:40 10.6 9.0 104.2 24.9 -0.5 45 12:41 10.8 8.8 99.4 26.2 -0.4 46 12:42 10.8 8.8 96.5 36.6 -0.4 47 12:43 10.8 8.8 96.5 26.4 -0.2 48 12:44 10.6 8.9 98.9 38.8 0.0 49 12:45 10.8 8.8 96.1 44.6 0.2 50 12:46 10.8 8.8 96.6 41.8 0.0 51 12:47 10.7 8.8 97.0 49.6 -0.1 52 12:48 10.7 8.8 97.3 46.0 0.0 53 12:49 10.7 8.9 98.7 33.3 0.0 54 12:50 10.7 8.8 101.0 38.8 -0.2 55 12:51 10.6 9.0 105.0 32.6 -0.3 56 12:52 10.6 9.0 105.0 29.9 -0.2 57 12:53 10.6 9.0 104.9 34.3 0.0 58 12:54 10.6 9.0 106.1 27.7 0.1 59 12:55 10.6 9.0 109.5 24.3 0.0 60 12:56 10.6 9.0 109.9 27.6 0.1 61 13:08 11.6 8.3 103.0 6.4 -0.3 62 13:09 11.4 8.5 107.2 4.3 -0.3 63 13:10 11.4 8.5 107.2 3.4 -0.3 64 13:11 11.3 8.6 110.8 3.6 -0.3 65 13:12 11.3 8.6 110.8 3.4 -0.3 66 13:13 11.8 8.2 104.9 2.7 -0.3 67 13:14 11.8 8.2 104.9 3.4 -0.3 68 13:15 11.8 8.3 106.8 2.4 -0.3 69 13:16 11.8 8.3 106.8 2.4 -0.4 70 13:17 11.7 8.4 108.1 3.0 -0.4 G P043AS-007255-RT-644 76 of 381 PROJ-007255 Biochar Now Kiln #65 4/13/2021 Test Run #2 Start Time 11:57 Run Length 120 Stop Time 14:09 Uncorrected Analyzer Data O2 CO2 NOx CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 71 13:18 11.5 8.6 111.6 2.6 -0.4 72 13:19 11.5 8.6 111.6 3.0 -0.4 73 13:20 11.3 8.7 115.5 1.6 -0.5 74 13:21 11.3 8.7 115.5 1.8 -0.4 75 13:22 11.3 8.7 113.4 2.3 -0.4 76 13:23 11.3 8.7 113.4 2.1 -0.4 77 13:24 11.6 8.5 112.5 1.8 -0.4 78 13:25 11.6 8.5 112.5 2.2 -0.4 79 13:26 11.5 8.5 115.5 3.0 -0.4 80 13:27 11.1 8.8 120.4 2.5 -0.5 81 13:28 11.1 8.8 120.4 1.8 -0.5 82 13:29 11.2 8.7 119.5 1.7 -0.5 83 13:30 11.2 8.7 119.5 2.2 -0.6 84 13:31 11.6 8.5 116.9 2.4 -0.5 85 13:32 11.6 8.5 116.9 1.6 -0.5 86 13:33 11.7 8.3 116.4 1.9 -0.3 87 13:34 11.7 8.3 116.4 2.8 0.0 88 13:35 12.0 8.0 113.2 2.6 0.2 89 13:36 12.0 8.1 114.9 2.9 0.4 90 13:37 12.0 8.1 114.9 2.2 0.5 91 13:38 12.3 7.7 110.3 2.6 0.3 92 13:39 12.3 7.7 110.3 3.5 0.1 93 13:40 12.2 7.9 113.0 2.7 0.0 94 13:41 12.2 7.9 113.0 2.4 -0.1 95 13:42 12.2 7.9 113.5 2.4 -0.1 96 13:43 12.2 7.9 113.5 2.9 -0.2 97 13:44 12.1 8.0 115.0 2.5 -0.2 98 13:45 11.5 8.5 121.6 2.7 -0.2 99 13:46 11.5 8.5 121.6 1.6 -0.3 100 13:47 11.1 8.9 127.0 0.9 -0.3 101 13:48 11.1 8.9 127.0 2.6 -0.3 102 13:49 11.7 8.3 118.2 2.8 -0.3 103 13:50 11.7 8.3 118.2 2.6 -0.3 104 13:51 11.5 8.5 118.8 2.7 -0.3 105 13:52 11.5 8.5 118.8 2.8 -0.3 106 13:53 11.6 8.3 116.5 2.3 -0.3 107 13:54 11.7 8.3 116.3 2.1 -0.3 108 13:55 11.7 8.3 116.3 2.3 -0.2 109 13:56 11.4 8.5 120.7 2.4 -0.2 110 13:57 11.4 8.5 120.7 2.6 -0.2 111 13:58 11.7 8.3 117.6 2.0 -0.2 112 13:59 11.7 8.3 117.6 0.7 -0.2 113 14:00 11.3 8.6 123.5 1.2 -0.2 114 14:01 11.3 8.6 123.5 1.1 -0.2 115 14:02 11.3 8.6 126.2 2.2 -0.2 116 14:03 11.5 8.5 124.5 2.0 -0.2 117 14:04 11.5 8.5 124.5 2.2 -0.2 118 14:05 11.7 8.3 124.6 1.1 -0.2 119 14:06 11.7 8.3 124.6 1.0 -0.2 120 14:07 11.5 8.4 126.4 2.0 -0.2 Average Co Cm Cma Corrected Average: 11.1 0.0 10.6 10.52 8.73 0.0 7.99 7.937 114.9 0.2 143 144.9 11.5 -0.1 2418 2490 11.0 8.68 116.1 11.9 -0.18 G P043AS-007255-RT-644 77 of 381 PROJ-007255 Biochar Now Kiln #65 4/13/2021 Test Run #3 Start Time 15:25 Run Length 120 Stop Time 17:45 Uncorrected Analyzer Data O2 CO2 NO„ CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 1 15:25 10.9 8.9 120.0 2.5 2.4 2 15:26 11.1 8.7 118.2 1.4 2.4 3 15:27 11.1 8.7 118.2 1.5 2.3 4 15:28 11.2 8.6 113.6 2.1 2.2 5 15:29 11.2 8.6 113.6 1.8 2.1 6 15:30 11.1 8.7 110.1 2.3 2.4 7 15:31 11.1 8.7 110.1 3.4 2.3 8 15:32 11.1 8.6 108.9 3.0 2.2 9 15:33 11.1 8.6 108.7 2.3 2.0 10 15:34 10.9 8.7 110.4 1.6 1.9 11 15:35 11.0 8.7 110.6 1.9 1.8 12 15:36 11.0 8.7 110.6 1.9 1.8 13 15:37 11.3 8.3 106.3 1.8 1.8 14 15:38 11.3 8.3 106.3 1.6 1.3 15 15:39 11.0 8.6 107.2 2.7 1.1 16 15:40 11.0 8.6 107.2 2.5 1.4 17 15:41 11.4 8.2 102.0 2.2 1.1 18 15:42 11.4 8.3 102.5 2.8 1.0 19 15:43 11.6 8.0 99.1 3.0 1.1 20 15:44 11.3 8.3 103.8 2.4 0.9 21 15:45 11.3 8.3 103.8 2.6 1.0 22 15:46 11.2 8.3 109.4 2.6 0.9 23 15:47 11.2 8.3 109.4 2.5 0.8 24 15:48 11.4 8.2 110.0 2.4 0.7 25 15:49 11.4 8.2 110.0 2.5 0.6 26 15:50 11.5 8.0 108.4 2.5 0.6 27 15:51 11.7 7.9 107.9 2.5 0.7 28 15:52 11.9 7.7 105.5 2.5 0.6 29 15:53 11.8 7.7 108.2 4.1 0.8 30 15:54 11.8 7.7 108.2 3.9 0.8 31 15:55 11.7 7.8 111.5 4.4 0.8 32 15:56 11.7 7.8 111.5 3.4 0.9 33 15:57 11.7 7.7 113.3 4.0 0.9 34 15:58 11.7 7.7 113.3 2.3 0.9 35 15:59 11.7 7.7 114.4 3.0 1.0 36 16:00 11.9 7.5 115.0 2.8 1.0 37 16:01 11.8 7.6 117.2 2.8 1.0 38 16:02 11.4 8.0 123.1 2.3 0.7 39 16:03 11.4 8.0 123.1 2.6 0.7 40 16:04 11.5 7.8 123.6 3.1 0.7 41 16:05 11.5 7.8 123.6 2.3 0.7 42 16:06 11.5 7.8 124.5 2.3 0.7 43 16:07 11.5 7.8 124.5 3.0 0.7 44 16:08 11.4 7.9 128.8 3.7 0.7 45 16:09 11.8 7.5 127.6 2.9 0.8 46 16:10 11.6 7.7 131.9 2.6 1.0 47 16:11 11.1 8.1 139.8 2.3 1.2 48 16:12 11.1 8.1 139.8 3.1 1.4 49 16:13 11.7 7.6 137.9 2.5 1.4 50 16:14 11.7 7.6 137.9 2.3 1.6 51 16:15 11.6 7.6 143.6 3.0 1.5 52 16:16 11.6 7.6 143.6 2.8 1.4 53 16:17 11.6 7.6 151.6 2.9 1.3 54 16:18 11.6 7.5 153.7 2.3 1.2 55 16:19 11.6 7.6 154.9 2.5 1.1 56 16:20 11.3 7.8 162.1 2.9 1.1 57 16:21 11.3 7.8 162.1 3.1 1.0 58 16:22 12.1 7.0 149.5 4.6 0.9 59 16:23 12.1 7.0 149.5 5.3 0.9 60 16:24 12.3 6.7 136.1 13.9 0.9 61 16:37 10.4 8.4 130.9 81.7 0.1 62 16:38 10.4 8.5 141.3 9.6 0.1 63 16:39 10.4 8.5 141.3 9.3 0.1 64 16:40 11.0 8.0 147.2 8.7 0.1 65 16:41 11.0 8.0 147.2 8.3 0.1 66 16:42 10.9 8.1 156.7 7.9 0.1 67 16:43 10.9 8.1 156.7 6.5 0.1 68 16:44 11.1 7.9 155.9 6.6 0.1 69 16:45 10.9 8.1 161.0 6.0 0.1 70 16:46 11.3 7.7 159.1 6.5 0.1 G P043AS-007255-RT-644 78 of 381 PROJ-007255 Biochar Now Kiln #65 4/13/2021 Test Run #3 Start Time 15:25 Run Length 120 Stop Time 17:45 Uncorrected Analyzer Data O2 CO2 NOx CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 71 16:47 11.3 7.7 160.5 7.2 0.1 72 16:48 11.3 7.7 160.5 7.4 0.1 73 16:49 11.5 7.5 154.8 8.7 0.1 74 16:50 11.5 7.5 154.8 7.3 0.1 75 16:51 11.3 7.6 154.0 8.4 0.2 76 16:52 11.3 7.6 154.0 8.9 0.3 77 16:53 11.3 7.6 155.6 9.2 0.5 78 16:54 11.5 7.5 149.3 9.6 0.7 79 16:55 11.4 7.6 148.0 10.5 0.8 80 16:56 11.4 7.6 146.2 11.4 0.9 81 16:57 11.4 7.6 146.2 10.2 1.0 82 16:58 11.4 7.5 141.8 11.3 1.0 83 16:59 11.4 7.5 141.8 11.5 1.1 84 17:00 11.3 7.6 142.8 13.1 1.1 85 17:01 11.3 7.6 142.8 13.2 1.1 86 17:02 11.6 7.4 138.0 12.8 1.1 87 17:03 11.8 7.2 134.6 14.9 1.1 88 17:04 11.6 7.3 137.0 16.0 1.1 89 17:05 11.7 7.2 132.8 17.0 1.1 90 17:06 11.7 7.2 132.8 17.4 1.0 91 17:07 12.1 6.8 125.4 20.3 0.8 92 17:08 12.1 6.8 125.4 21.1 0.6 93 17:09 12.0 6.9 124.8 21.8 0.5 94 17:10 12.0 6.9 124.8 24.3 0.4 95 17:11 12.1 6.8 116.9 26.9 0.4 96 17:12 12.0 6.8 116.6 29.8 0.3 97 17:13 12.0 6.8 116.2 28.2 0.3 98 17:14 12.1 6.7 113.6 31.9 0.2 99 17:15 12.1 6.7 113.6 33.7 0.2 100 17:16 12.1 6.7 111.5 35.6 0.1 101 17:17 12.1 6.7 111.5 39.7 0.1 102 17:18 12.3 6.5 106.1 42.9 0.1 103 17:19 12.3 6.5 106.1 47.2 0.1 104 17:20 12.3 6.5 103.0 56.1 0.0 105 17:21 12.3 6.5 100.3 65.6 0.1 106 17:22 12.5 6.4 97.4 79.8 0.0 107 17:23 12.5 6.3 94.3 94.4 0.1 108 17:24 12.5 6.3 94.3 111.4 0.0 109 17:25 12.3 6.5 95.9 99.7 0.0 110 17:26 12.3 6.5 95.9 40.6 -0.1 111 17:27 12.0 6.7 96.3 40.7 0.0 112 17:28 12.0 6.7 96.3 46.6 -0.1 113 17:29 11.5 7.3 106.3 21.0 -0.1 114 17:30 11.3 7.4 108.2 20.3 -0.1 115 17:31 10.7 8.0 117.9 13.8 -0.1 116 17:32 9.7 9.0 134.3 6.7 -0.1 117 17:33 9.7 9.0 134.3 3.4 -0.1 118 17:34 9.6 9.1 131.1 3.6 -0.1 119 17:35 9.6 9.1 131.1 5.1 -0.2 120 17:36 8.0 10.5 149.7 3.6 -0.2 Average Co Cm Cma Corrected Average: 11.4 0.0 10.6 10.52 7.72 0.0 7.98 7.937 125.7 0.3 144 144.9 13.9 -0.1 2417 2490 11.4 I 7.68 126.7 14.4 0.75 G P043AS-007255-RT-644 79 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix Al Kiln 74 (Kiln 3) Instrumental Test Method Data G P043AS-007255-RT-644 80 of 381 I1 MONTROSE AIR QUALIFY NI-RI:RAS PROJ-007255 Biochar Now Kiln #74 4/15/2021 Test Run #1 Start Time 10:20 Run Length 120 Stop Time 12:44 Uncorrected Analyzer Data O2 CO2 NO„ CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 1 10:20 7.4 9.0 60.9 4.4 0.36 2 10:21 8.3 8.4 60.9 3.8 0.34 3 10:22 9.0 7.8 59.7 1.8 0.29 4 10:23 8.5 8.1 58.9 1.3 0.21 5 10:24 10.0 7.2 49.8 1.3 0.21 6 10:25 9.5 7.9 42.4 1.2 0.14 7 10:26 9.5 8.3 43.5 1.5 -0.01 8 10:27 7.5 10.5 50.1 2.1 -0.09 9 10:39 7.3 11.4 104.1 32.5 2.68 10 10:40 7.6 11.3 108.6 22.4 2.46 11 10:41 7.5 11.3 113.8 16.3 2.55 12 10:42 7.5 11.3 115.9 11.5 2.40 13 10:43 7.3 11.9 125.8 9.2 2.66 14 10:44 7.6 12.2 158.5 16.3 2.89 15 10:45 12.1 8.6 119.2 9.4 3.25 16 10:46 15.9 4.6 67.5 5.2 3.71 17 10:47 17.0 3.7 53.9 4.3 4.22 18 10:48 17.2 3.7 52.0 3.4 4.41 19 10:49 18.1 2.9 38.2 3.9 4.49 20 10:50 18.3 2.7 34.4 3.5 4.17 21 10:51 18.5 2.5 31.0 3.4 4.10 22 10:52 18.8 2.3 27.5 2.7 3.96 23 10:53 16.9 3.8 55.9 3.8 3.59 24 10:54 17.0 3.8 53.0 2.9 3.68 25 10:55 17.8 3.2 42.7 2.5 3.59 26 10:56 17.2 3.5 53.7 2.7 2.81 27 10:57 18.9 2.2 29.0 2.7 3.05 28 10:58 18.8 2.3 31.8 2.7 3.08 29 10:59 18.8 2.2 33.7 2.4 3.29 30 11:00 19.0 2.0 29.7 2.3 3.29 31 11:01 18.4 2.6 41.0 2.5 2.96 32 11:02 11.8 8.5 160.9 2.6 2.85 33 11:03 7.6 12.7 230.9 3.9 2.78 34 11:04 7.6 12.7 229.6 21.9 2.37 35 11:05 8.9 11.6 194.5 68.0 2.60 36 11:06 8.9 11.3 189.0 117.9 2.51 37 11:07 9.2 11.1 188.3 101.5 2.58 38 11:08 8.9 11.3 200.3 141.9 2.41 39 11:09 8.9 11.3 204.5 101.3 2.32 40 11:10 9.0 11.3 210.1 77.4 2.34 41 11:11 8.6 11.6 218.8 89.2 2.26 42 11:12 8.8 11.5 214.1 51.8 2.30 43 11:13 9.0 11.2 205.7 82.1 2.29 44 11:14 9.0 11.2 208.5 120.1 2.34 45 11:15 9.0 11.2 211.9 106.2 2.39 46 11:16 9.0 11.1 211.0 126.1 2.38 47 11:17 9.1 11.1 211.3 109.2 2.36 48 11:18 9.1 11.2 210.9 114.2 2.33 49 11:19 9.1 11.2 207.8 144.2 2.51 50 11:20 9.2 10.8 206.6 192.8 2.48 51 11:21 9.3 10.7 205.7 166.6 2.34 52 11:22 9.4 10.6 201.2 184.0 2.32 53 11:23 9.5 10.5 192.8 233.3 2.54 54 11:24 9.6 10.4 185.2 243.1 2.69 55 11:25 9.6 10.3 179.6 262.8 2.72 56 11:26 9.9 9.9 166.3 324.2 3.41 57 11:27 10.0 9.9 164.8 404.8 4.10 58 11:28 9.9 10.0 166.3 415.4 3.68 59 11:29 9.8 10.1 167.6 382.3 2.94 60 11:30 9.7 10.2 166.5 273.9 2.56 61 11:44 12.1 7.7 108.2 375.8 3.67 62 11:45 12.1 7.7 108.2 429.4 5.81 63 11:46 12.5 7.3 99.7 444.4 3.94 64 11:47 12.5 7.3 96.7 464.5 5.48 65 11:48 12.4 7.4 93.9 477.6 5.05 66 11:49 12.6 7.1 89.4 403.7 4.03 67 11:50 12.5 7.2 87.7 453.0 5.60 68 11:51 12.7 7.0 81.7 420.0 4.21 69 11:52 12.8 6.8 78.4 429.5 4.88 70 11:53 12.3 7.4 81.4 412.5 5.09 G P043AS-007255-RT-644 81 of 381 PROJ-007255 Biochar Now Kiln #74 4/15/2021 Test Run #1 Start Time 10:20 Run Length 120 Stop Time 12:44 Uncorrected Analyzer Data O2 CO2 NO„ CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 71 11:54 12.3 7.4 81.4 405.5 2.75 72 11:55 12.5 7.1 79.7 320.4 2.58 73 11:56 11.9 7.7 88.1 261.9 1.91 74 11:57 12.0 7.7 89.7 139.0 1.93 75 11:58 11.6 8.1 93.7 93.7 1.70 76 11:59 11.7 8.0 92.8 55.7 1.71 77 12:00 11.8 7.8 91.1 32.3 1.70 78 12:01 11.4 8.3 100.0 21.9 1.76 79 12:02 11.1 8.7 109.9 16.1 1.86 80 12:03 11.1 8.7 109.9 15.4 1.83 81 12:04 11.1 8.6 109.5 15.6 1.83 82 12:05 10.9 8.9 112.0 20.2 1.81 83 12:06 11.1 8.5 107.0 29.4 1.78 84 12:07 10.9 8.7 104.9 55.2 1.76 85 12:08 11.1 8.6 96.7 137.0 2.24 86 12:09 11.4 8.2 86.9 227.1 1.91 87 12:10 11.8 7.9 81.9 185.1 2.02 88 12:11 11.9 7.6 75.9 250.1 2.48 89 12:12 11.9 7.6 75.9 248.5 2.21 90 12:13 11.9 7.6 76.9 193.9 2.17 91 12:14 11.9 7.8 75.2 218.8 2.22 92 12:15 12.1 7.5 71.6 192.8 2.29 93 12:16 12.2 7.4 68.9 260.8 2.90 94 12:17 12.2 7.4 65.0 305.0 2.84 95 12:18 12.5 7.1 60.8 325.6 2.93 96 12:19 12.2 7.3 61.3 347.6 3.48 97 12:20 11.4 8.1 64.7 480.6 4.59 98 12:21 11.4 8.1 64.7 517.4 4.84 99 12:22 10.7 8.8 77.1 398.9 3.56 100 12:23 11.6 7.9 63.5 465.0 6.24 101 12:24 12.6 6.8 52.2 559.0 7.18 102 12:25 13.1 6.3 47.9 589.9 5.45 103 12:26 12.9 6.4 50.1 424.4 4.08 104 12:27 11.9 7.3 57.0 424.2 2.37 105 12:28 11.3 8.0 61.9 409.6 2.13 106 12:29 11.1 8.2 63.0 422.0 2.76 107 12:30 11.1 8.2 63.0 439.1 1.70 108 12:31 11.1 8.2 64.4 371.6 1.13 109 12:32 11.0 8.3 66.0 341.7 0.63 110 12:33 10.9 8.5 68.2 342.9 1.34 111 12:34 11.4 8.1 64.8 367.6 1.36 112 12:35 11.5 8.0 66.1 374.2 1.58 113 12:36 11.4 8.1 67.4 373.9 1.16 114 12:37 11.4 8.1 69.4 368.8 1.73 115 12:38 11.1 8.4 74.5 392.6 1.38 116 12:39 11.1 8.4 74.5 356.9 1.05 117 12:40 10.9 8.7 79.0 360.5 0.64 118 12:41 10.7 8.9 82.7 355.6 1.06 119 12:42 10.7 8.9 85.3 271.0 0.00 120 12:43 10.3 9.2 92.6 213.0 0.09 Average Co Cm Cma Corrected Average: 11.5 0.0 10.5 10.5 8.2 0.0 8.0 7.9 103.9 0.3 144.9 144.9 192.9 0.3 1401.8 1399.0 11.5 I 8.1 103.8 I 192.3 2.6 G P043AS-007255-RT-644 82 of 381 PROJ-007255 Biochar Now Kiln #74 4/15/2021 Test Run #2 Start Time 13:50 Run Length 120 Stop Time 15:58 Uncorrected Analyzer Data O2 CO2 NO„ CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 1 13:50 12.2 8.0 129.4 23.6 -0.1 2 13:51 12.2 8.0 129.4 49.5 0.0 3 13:52 12.3 7.8 126.9 58.5 0.0 4 13:53 12.2 7.9 129.2 44.9 0.0 5 13:54 12.2 7.9 128.7 50.6 0.0 6 13:55 12.4 7.7 124.8 42.7 0.0 7 13:56 12.2 8.0 127.0 28.0 0.0 8 13:57 12.3 7.9 125.6 25.3 0.0 9 13:58 12.2 8.0 124.5 21.3 0.0 10 13:59 12.0 8.1 121.4 25.7 0.0 11 14:00 12.0 8.1 121.4 26.1 -0.2 12 14:01 11.2 8.9 129.5 21.5 -0.3 13 14:02 11.1 9.0 127.7 28.2 -0.4 14 14:03 11.1 8.9 126.2 30.1 -0.5 15 14:04 11.0 9.0 125.5 33.8 -0.6 16 14:05 11.0 9.0 122.4 47.6 -0.6 17 14:06 11.2 8.8 117.4 42.9 -0.6 18 14:07 11.0 9.0 118.8 52.5 -0.6 19 14:08 11.3 8.7 111.3 96.2 -0.4 20 14:09 11.3 8.7 111.3 214.6 0.1 21 14:10 11.9 8.2 103.2 230.7 -0.1 22 14:11 12.2 7.8 99.6 203.8 -0.3 23 14:12 11.6 8.4 104.9 170.5 -0.3 24 14:13 11.6 8.4 102.9 215.7 -0.1 25 14:14 11.9 8.1 98.8 230.1 -0.2 26 14:15 11.6 8.4 101.8 218.0 -0.2 27 14:16 11.5 8.5 103.2 208.9 -0.3 28 14:17 12.0 8.1 97.6 237.9 -0.2 29 14:18 12.0 8.1 97.6 227.2 -0.3 30 14:19 11.3 8.7 105.8 217.6 0.0 31 14:20 11.3 8.8 106.6 157.0 0.4 32 14:21 11.3 8.7 106.3 164.7 1.6 33 14:22 11.5 8.5 103.4 199.3 1.9 34 14:23 11.8 8.3 101.1 174.8 1.6 35 14:24 11.8 8.3 103.4 161.0 1.6 36 14:25 11.6 8.4 107.3 182.6 1.3 37 14:26 12.3 7.8 105.6 148.2 1.1 38 14:27 12.3 7.8 105.6 169.2 1.0 39 14:28 11.6 8.5 117.1 116.4 1.8 40 14:29 11.5 8.7 124.5 83.0 1.4 41 14:30 11.9 8.3 123.8 63.8 1.1 42 14:31 11.3 8.9 135.1 42.9 1.0 43 14:32 11.2 9.0 139.5 41.6 0.8 44 14:33 11.1 9.0 142.5 35.9 0.6 45 14:34 11.4 8.9 140.8 31.6 0.5 46 14:35 11.5 8.7 138.4 40.0 0.6 47 14:36 11.5 8.7 138.4 54.7 0.5 48 14:37 11.8 8.5 135.4 83.2 0.6 49 14:38 12.1 8.1 128.8 97.7 0.4 50 14:39 12.0 8.3 130.9 94.3 0.4 51 14:40 11.9 8.3 131.4 120.1 0.3 52 14:41 12.0 8.2 128.7 137.7 0.5 53 14:42 12.0 8.1 127.4 195.9 0.5 54 14:43 12.0 8.1 126.9 202.3 0.3 55 14:44 11.9 8.2 130.6 160.8 0.3 56 14:45 11.9 8.2 130.6 192.7 0.4 57 14:46 12.3 7.9 124.6 207.1 0.2 58 14:47 12.2 7.9 127.5 140.0 -0.1 59 14:48 11.7 8.4 135.3 147.4 0.1 60 14:49 11.8 8.3 134.7 148.6 -0.2 61 14:57 11.6 8.6 150.2 83.4 -0.4 62 14:58 11.6 8.6 150.2 108.2 -0.3 63 14:59 11.4 8.8 153.2 102.2 -0.5 64 15:00 11.4 8.8 154.3 58.5 -0.6 65 15:01 11.3 8.8 155.4 73.3 -0.5 66 15:02 11.3 8.8 154.1 119.2 -0.4 67 15:03 11.3 8.8 154.1 96.7 -0.5 68 15:04 11.3 8.8 152.7 77.9 -0.6 69 15:05 11.3 8.8 152.7 73.4 -0.5 70 15:06 11.6 8.6 146.5 77.7 -0.5 G P043AS-007255-RT-644 83 of 381 PROJ-007255 Biochar Now Kiln #74 4/15/2021 Test Run #2 Start Time 13:50 Run Length 120 Stop Time 15:58 Uncorrected Analyzer Data O2 CO2 NOx CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 71 15:07 11.6 8.6 146.5 94.1 -0.4 72 15:08 11.3 8.8 150.1 57.4 -0.6 73 15:09 11.2 8.9 151.6 59.8 -0.6 74 15:10 11.3 8.7 147.4 71.5 -0.6 75 15:11 11.3 8.7 147.6 71.4 -0.5 76 15:12 11.3 8.7 147.6 71.5 -0.6 77 15:13 11.6 8.5 140.5 92.1 -0.6 78 15:14 11.6 8.5 140.5 73.5 -0.6 79 15:15 11.6 8.5 139.7 76.7 -0.6 80 15:16 11.6 8.5 139.7 63.9 -0.6 81 15:17 11.6 8.4 137.1 80.4 -0.7 82 15:18 11.5 8.6 136.8 73.3 -0.6 83 15:19 11.3 8.7 134.4 75.2 -0.6 84 15:20 11.5 8.4 124.5 75.0 -0.6 85 15:21 11.5 8.4 124.5 89.8 -0.7 86 15:22 11.5 8.5 123.5 92.7 -0.6 87 15:23 11.5 8.5 123.5 119.1 -0.6 88 15:24 11.6 8.3 120.4 113.0 -0.6 89 15:25 11.6 8.3 120.4 144.2 -0.4 90 15:26 11.9 8.1 116.1 140.7 -0.5 91 15:27 12.0 8.0 114.1 144.3 -0.2 92 15:28 12.2 7.7 109.9 201.1 -0.2 93 15:29 12.1 7.9 107.9 191.5 -0.3 94 15:30 12.1 7.9 107.9 166.1 -0.5 95 15:31 12.5 7.5 102.3 183.4 -0.1 96 15:32 12.5 7.5 102.3 222.7 0.2 97 15:33 12.6 7.4 101.6 260.2 0.5 98 15:34 12.6 7.4 101.6 276.6 0.2 99 15:35 12.0 7.9 108.1 219.5 -0.4 100 15:36 11.8 8.1 113.3 197.5 -0.1 101 15:37 12.0 7.8 112.4 129.7 -0.5 102 15:38 11.2 8.6 124.4 96.8 -0.5 103 15:39 11.2 8.6 124.4 147.0 -0.5 104 15:40 11.8 8.1 119.5 102.5 -0.5 105 15:41 11.8 8.1 119.5 102.0 -0.6 106 15:42 11.6 8.2 124.4 85.1 -0.6 107 15:43 11.6 8.2 124.4 65.4 -0.6 108 15:44 11.8 8.0 123.4 68.4 -0.6 109 15:45 11.9 7.9 122.0 50.8 -0.6 110 15:46 11.9 7.8 124.5 38.0 -0.6 111 15:47 11.5 8.2 128.8 38.0 -0.7 112 15:48 11.5 8.2 128.8 38.5 -0.6 113 15:49 11.7 8.0 125.9 45.3 -0.6 114 15:50 11.7 8.0 125.9 60.8 -0.5 115 15:51 12.4 7.3 115.0 73.3 -0.4 116 15:52 12.4 7.3 115.0 59.3 -0.6 117 15:53 11.6 7.9 126.5 44.5 -0.6 118 15:54 11.5 8.1 127.9 51.8 -0.6 119 15:55 11.6 8.0 127.0 51.4 -0.5 120 15:56 12.2 7.4 120.2 62.5 -0.6 Average Co Cm Cma Corrected Average: 11.7 0.0 10.5 10.5 8.3 0.0 8.0 7.9 124.9 0.4 144.8 144.9 108.3 -0.2 1397.0 1399.0 11.7 8.2 124.9 108.6 -0.1 G P043AS-007255-RT-644 84 of 381 PROJ-007255 Biochar Now Kiln #74 4/15/2021 Test Run #3 Start Time 16:58 Run Length 120 Stop Time 19:04 Uncorrected Analyzer Data O2 CO2 NO„ CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 1 16:58 14.0 5.3 74.1 345.1 4.4 2 16:59 13.6 5.6 77.6 287.6 3.6 3 17:00 13.6 5.6 77.6 190.2 3.9 4 17:01 13.6 5.6 75.4 158.5 3.9 5 17:02 13.6 5.6 75.4 130.1 3.8 6 17:03 13.6 5.6 73.9 102.1 4.0 7 17:07 13.2 5.9 73.6 55.5 4.5 8 17:08 13.1 6.0 73.6 53.7 4.6 9 17:09 12.6 6.5 79.0 38.3 4.4 10 17:10 12.5 6.5 80.3 28.7 4.0 11 17:11 12.6 6.5 78.2 27.5 3.9 12 17:12 12.2 6.7 82.3 21.3 3.7 13 17:13 12.2 6.9 82.6 21.2 3.6 14 17:14 11.8 7.2 86.4 18.4 3.3 15 17:15 12.0 7.0 85.3 17.6 3.2 16 17:16 13.0 6.0 77.4 24.2 3.2 17 17:17 12.5 6.5 83.0 23.0 3.1 18 17:18 13.0 6.0 77.7 23.5 3.2 19 17:19 12.7 6.3 80.2 19.6 3.2 20 17:20 12.2 6.7 82.5 19.1 3.1 21 17:21 12.9 6.1 75.6 17.9 3.2 22 17:22 12.0 6.9 85.4 13.3 3.2 23 17:23 11.8 7.1 86.7 7.3 3.4 24 17:24 11.6 7.4 87.7 8.1 3.5 25 17:25 12.0 7.0 81.2 10.5 3.5 26 17:26 12.1 6.8 79.6 12.1 3.3 27 17:27 11.8 7.1 83.1 6.9 3.2 28 17:28 11.8 7.1 81.5 9.9 2.8 29 17:29 11.9 7.0 80.4 11.3 2.6 30 17:30 11.7 7.1 81.1 10.5 2.3 31 17:31 12.0 6.9 78.9 11.3 2.0 32 17:32 12.1 6.8 76.9 13.4 1.9 33 17:33 12.2 6.6 76.0 17.7 1.7 34 17:34 12.1 6.7 77.1 17.7 1.5 35 17:35 11.8 7.0 81.0 9.3 1.3 36 17:36 11.8 7.0 80.3 10.7 1.2 37 17:37 11.6 7.2 83.7 9.2 1.1 38 17:38 11.2 7.6 86.9 10.0 1.0 39 17:39 11.7 7.2 82.1 10.2 1.0 40 17:40 12.0 6.9 81.5 9.9 1.0 41 17:41 11.6 7.2 85.7 12.6 0.9 42 17:42 11.9 6.9 82.9 10.9 0.8 43 17:43 12.0 6.9 82.2 9.9 0.7 44 17:44 12.0 6.8 82.9 9.1 0.7 45 17:45 11.5 7.3 87.3 8.4 0.7 46 17:46 11.6 7.2 84.3 10.2 0.7 47 17:47 11.7 7.1 81.0 12.0 0.6 48 17:48 11.9 6.9 79.8 10.0 0.6 49 17:49 11.5 7.3 84.2 8.1 0.5 50 17:50 11.9 7.0 81.2 9.0 0.5 51 17:51 11.2 7.7 88.0 5.8 0.4 52 17:52 11.3 7.6 86.3 4.7 0.4 53 17:53 10.6 8.0 89.5 4.7 0.3 54 17:54 9.8 8.6 93.0 1.4 0.2 55 17:55 10.2 8.1 86.7 1.4 0.2 56 17:56 10.2 8.2 85.8 1.4 0.2 57 17:57 10.2 8.3 86.8 1.4 0.2 58 17:58 10.0 8.4 86.4 1.4 0.2 59 17:59 10.2 8.2 82.8 1.6 0.2 60 18:00 10.3 8.1 81.4 1.4 0.2 61 18:04 10.5 7.9 78.7 1.2 0.2 62 18:05 10.5 7.9 78.7 1.2 0.2 63 18:06 10.5 8.0 78.5 1.5 0.2 64 18:07 11.2 7.4 72.1 0.7 0.2 65 18:08 10.9 7.6 76.6 1.6 0.2 66 18:09 10.4 8.1 80.0 1.4 0.2 67 18:10 10.6 7.9 79.0 1.0 0.2 68 18:11 10.5 8.0 81.7 1.3 0.2 69 18:12 10.5 8.0 81.7 0.9 0.2 70 18:13 10.4 8.1 84.6 0.7 0.2 G P043AS-007255-RT-644 85 of 381 PROJ-007255 Biochar Now Kiln #74 4/15/2021 Test Run #3 Start Time 16:58 Run Length 120 Stop Time 19:04 Uncorrected Analyzer Data O2 CO2 NO„ CO TVOC Minute Time %vd %vd ppmvd ppmvd ppmvw 71 18:14 10.4 8.1 84.6 0.8 0.2 72 18:15 10.4 8.0 81.6 1.0 0.2 73 18:16 10.4 8.1 80.8 1.5 0.2 74 18:17 10.4 8.1 80.4 1.1 0.2 75 18:18 10.5 8.1 78.8 1.3 0.2 76 18:19 10.0 8.5 82.8 1.2 0.3 77 18:20 9.8 8.8 89.2 1.3 0.3 78 18:21 9.8 8.8 89.2 1.3 0.3 79 18:22 9.5 9.1 90.0 0.9 0.4 80 18:23 9.5 9.1 90.0 1.2 0.4 81 18:24 9.8 9.0 89.2 1.4 0.4 82 18:25 9.7 8.9 89.5 1.1 0.4 83 18:26 9.9 8.7 88.9 0.9 0.4 84 18:27 9.8 8.8 92.1 1.1 0.4 85 18:28 9.7 9.0 93.2 1.0 0.5 86 18:29 9.7 8.9 92.3 1.4 0.5 87 18:30 9.7 8.9 92.3 1.3 0.5 88 18:31 10.4 8.3 84.2 1.3 0.5 89 18:32 10.4 8.3 84.2 1.4 0.5 90 18:33 9.8 8.8 90.8 1.5 0.5 91 18:34 10.0 8.8 91.4 1.5 0.5 92 18:35 9.9 8.7 94.0 0.8 0.5 93 18:36 9.4 9.2 99.1 1.0 0.5 94 18:37 9.6 9.0 97.9 1.0 0.6 95 18:38 9.9 8.7 94.7 1.4 0.6 96 18:39 9.9 8.7 94.7 0.8 0.7 97 18:40 9.7 8.8 93.7 1.3 0.7 98 18:41 9.7 8.8 93.7 0.9 0.6 99 18:42 9.0 9.4 98.6 1.3 0.5 100 18:43 8.9 9.5 100.2 0.9 0.5 101 18:44 9.3 9.2 95.3 1.1 0.5 102 18:45 10.1 8.6 88.3 1.3 0.4 103 18:46 9.4 9.1 94.2 1.1 0.4 104 18:47 9.1 9.5 103.6 1.1 0.3 105 18:48 9.1 9.5 103.6 0.7 0.2 106 18:49 10.0 8.8 99.4 0.8 0.3 107 18:50 10.0 8.8 99.4 1.5 0.3 108 18:51 9.9 8.7 99.7 1.5 0.3 109 18:52 10.2 8.6 96.8 1.1 0.3 110 18:53 10.1 8.6 95.2 1.1 0.3 111 18:54 10.1 8.6 93.6 1.1 0.2 112 18:55 10.3 8.5 89.2 1.3 0.2 113 18:56 10.2 8.5 87.6 1.2 0.2 114 18:57 10.2 8.5 87.6 1.2 0.1 115 18:58 9.9 8.8 87.7 1.2 0.2 116 18:59 9.9 8.8 87.7 1.0 0.2 117 19:00 10.1 8.7 85.4 1.5 0.2 118 19:01 10.0 8.8 84.4 1.8 0.6 119 19:02 10.4 8.4 80.2 1.5 1.4 120 19:03 10.6 8.3 79.5 1.4 2.2 Average Co Cm Cma Corrected Average: 11.0 0.0 10.5 10.5 7.8 0.0 8.1 7.9 85.3 0.2 144.9 144.9 16.9 0.3 1387.2 1399.0 11.0 I 7.6 85.2 16.8 1.3 G P043AS-007255-RT-644 86 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix A.8 Kiln 56 (Kiln 2) Calculations/Results G P043AS-007255-RT-644 87 of 381 ti\ MONTROSE I AIR QUALIFY tiERvIEFS PROJ-007255 Biochar Now Kiln #56 4/14/2021 EPA Method 2 Data Run # 1 Start Time 8:28 Stop Time 10:40 2 11:47 13:58 1 2 3 15:00 17:16 3 Average DS Pbar Pg Cp VA Pavg TS A Pg Md MS PS Ts(abs)VS Q Q Inputs Stack Diameter (inches) Barometric Pressure ("Hg) Stack Static Pressure ("H2O) Pitot Tube Coefficient (unitless) Avg. Velocity Head of Stack Gas V("H2O) Stack Gas Temperature (°F) Calculations Stack Area (ft2) Stack Static Pressure ("Hg) Stack Gas Molecular Weight, dry basis (lb/lb-mole) Stack Gas Molecular Weight, wet basis (lb/lb-mole) Absolute Stack Pressure ("Hg) Absolute Stack Gas Temperature (°R ) Stack Gas Velocity (ft/sec) Stack Gas Dry Volumetric Flow Rate (dscf/hr) Stack Gas Dry Volumetric Flow Rate (dscf/min) EPA Method 4 Data 24.0 25.12 -0.01 0.84 0.0881 1189 3.14 0.00 29.96 28.34 25.12 1649 9.63 25,307 422 1 24.0 24.0 25.12 25.12 -0.01 -0.01 0.84 0.84 0.1000 0.1001 1276 891 1118 3.14 3.14 0.00 0.00 29.87 29.90 28.31 28.92 25.12 25.12 1736 1351 1578 11.2 9.80 10.22 28,134 33,373 28,938 469 556 482 2 3 Average Vic Vm Y AH Tm Pm Tm Vwc(std) Vm(std) Bws Inputs Volume of Water Condensed (mL) Volume of Stack Gas Collected (dcf) Meter Calibration Factor (unitless) Pressure Differential Across Orifice ("H2O) Temperature at Gas Meter (°F) Calculations Absolute Pressure at Gas Meter ("Hg) Absolute Temperature at Gas Meter i°R) Volume of Water Condensed (scf) Sample Gas Volume (dscf) Stack Gas Moisture Content (%/100) 166.0 55.770 0.9912 0.64 33.0 25.17 493 7.81 49.78 0.136 EPA Method 3A, 7E, 10 and 25A Data 1 174.3 62.608 0.9912 0.76 50.0 25.18 510 8.20 54.04 0.132 121.1 74.913 0.9912 1.09 62.1 25.20 522.1 5.70 63.22 0.0827 2 3 153.8 64.430 0.9912 0.83 48.4 25.18 508 7.24 55.68 0.117 Average O2 (%vd) CO2 (%vd) NOx (ppmvd) CO (ppmvd) TVOC (ppmvw as C3H8) TVOC (ppmvd as C3H8) 9.54 9.87 96.4 220 2.10 2.43 Mass Emission Calculations (Using EPA Methods 1-4) 1 11.2 8.91 144 50.9 <1.0 <1.2 8.99 9.64 126 12.1 <1.0 <1.1 2 3 9.91 9.47 122 94.3 1.37 1.56 Average NO), (lb/hr) NO), (lb/ton raw feed) CO (lb/hr) CO (lb/ton raw feed) TVOC (lb/hr as C3H8) TVOC (lb/ton raw feed as C3H8) *Kiln processed 2,120 lb of raw feed in 8.80 hours 0.291 2.42 0.405 3.36 0.00703 0.0584 0.482 4.01 0.104 0.864 <0.00371 <0.0308 0.500 4.15 0.0293 0.243 <0.00416 <0.0346 0.425 3.53 0.179 1.49 0.00497 0.0412 G P043AS-007255-RT-644 88 of 381 Kiln # 56 Test Performed For: Source(s) Tested: Test Condition: Test(s) Performed: Run Number Biochar Now, LLC Testing Performed By: Berthoud Plant / Colorado Montrose Air Quality Services Kiln # 56 Pilot Batch Process of Treated Wood 5/202 Run 1 Run 2 Project Manager: Jeff Goldfine Run 3 Average Date of Run 4/14/21 4/14/21 4/14/21 Emission Test Run Time Began - Ended Oxygen Concentration Carbon Dioxide Concentration Isokinetic Sampling Rate Stack Temperature Stack Temperature Moisture Content Stack Gas Velocity Stack Gas Flow @ Actual Conditions Stack Gas Flow @ Standard Conditions Stack Gas Flow @ Dry Standard Conditions Batch Time Raw feed processed %(dry) %(dry) % °F °C % volume f/s acfm scfm dscfm hr lb 0828-1040 1147-1358 9.54 11.2 9.9 8.91 102.6 100.2 1189 1276 643 691 13.6 13.2 9.63 11.2 1,816 2,115 488 540 422 469 1500-1716 8.99 9.64 98.8 891 477 8.27 9.80 1,849 607 556 9.91 9.47 1118 604 11.7 10.22 1,927 545 482 8.80 2,120 Visible Emissions, Highest Six Minute Average 0.0 0.0 0.0 0.0 Particulate Concentration, Filterable Particulate Emissions, Filterable Particulate Emissions, Filterable gr/dscf lb/hr lb/ton 0.00245 0.00128 0.00132 0.00168 0.00885 0.00516 0.00628 0.00677 0.0735 0.0429 0.0522 0.0562 Particulate Concentration, Condensable Particulate Emissions, Condensable Particulate Emissions, Condensable gr/dscf lb/hr lb/ton 0.000775 0.00134 0.000561 0.000892 0.00280 0.00539 0.00268 0.00362 0.0233 0.0448 0.0222 0.0301 PKa Emissions, Total PM1a Emissions, Total lb/hr 0.00873 0.00885 0.00689 0.00816 lb/ton 0.0725 0.0735 0.0572 0.0677 PM2.5 Emissions, Total PM2.5 Emissions, Total lb/hr lb/ton 0.00705 0.00787 0.0585 0.0653 0.00569 0.00687 0.0473 0.0570 Particulate Concentration, Total Particulate Emissions, Total Particulate Emissions, Total gr/dscf lb/hr lb/ton 0.00322 0.00263 0.00188 0.00258 0.0117 0.0106 0.00896 0.0104 0.0967 0.0876 0.0744 0.0862 G P043AS-007255-RT-644 89 of 381 Biochar Now Kiln 56 EPA Method 308 Parameters Project No. PROJ-007255 Parameters Run 1 Run 2 Run 3 Average Date Start Time Stop Time Un-Spiked Barometric Pressure, Pb (Inches Hg) Volume Metered, Vm (L) Meter Temperature, Tm (°F) Gas Meter Correction Factor, ' Run Time, 0 (minutes) Spiked Volume Metered, Vm (L) Meter Temperature, Tm (°F) Gas Meter Correction Factor, )6 Run Time, 0 (minutes) Total Methanol Collected Un-Spiked, m (ug) Total Methanol Collected Spiked, m (ug) Mass of Methanol Injected in Spiked Train, S (ug) RESULTS 4/14/21 8:28 10:40 25.12 48.11 33.7 1.010 120 8.51 4/14/21 11:47 13:58 25.12 48.52 54.2 1.010 120 48.52 55.0 0.998 120 <3.69 76.7 308 4/14/21 15:00 17:16 25.12 48.71 58.8 1.010 105 <3.60 Volume Metered Un-Spiked, \A(std) (L) Volume Metered Spiked, \m(std) (L) METHANOL RESULTS Mass per Volume Spike, rr3 (ug/L) Spike Recovery, R Methanol Concentration, C (ppmv) Recovery Corrected Methanol Concentration, C (ppmv) Gas volumetric flow rate (dscfm) Methanol Emission Rate (lb/hr) Methanol Emission Rate (lb/ton)* *2,120 lb were processed in 8.80 hours 43.67 NA NA 0.146 0.617 422 0.00130 0.0108 42.3 417 1.75 0.24 <0.0655 <0.276 469 <6.47E-04 <5.37E-03 42.1 NA NA <0.0642 <0.271 556 <7.52E-04 <6.25E-03 <0.0920 <0.388 482 <8.99E-04 <7.47E-03 G P043AS-007255-RT-644 90 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix A.9 Kiln 65 (Kiln 1) Calculations/Results G P043AS-007255-RT-644 91 of 381 ti\ MONTROSE I AIR QUALIFY tiERvIEFS PROJ-007255 Biochar Now Kiln #65 4/13/2021 EPA Method 2 Data Run # 1 Start Time 8:11 Stop Time 10:34 2 11:57 14:09 1 2 3 15:25 17:45 3 Average DS Pbar Pg Cp VA Pavg TS A Pg Md MS PS Ts(abs)VS Q Q Inputs Stack Diameter (inches) Barometric Pressure ("Hg) Stack Static Pressure ("H2O) Pitot Tube Coefficient (unitless) Avg. Velocity Head of Stack Gas V("H2O) Stack Gas Temperature (°F) Calculations Stack Area (ft2) Stack Static Pressure ("Hg) Stack Gas Molecular Weight, dry basis (lb/lb-mole) Stack Gas Molecular Weight, wet basis (lb/lb-mole) Absolute Stack Pressure ("Hg) Absolute Stack Gas Temperature (°R ) Stack Gas Velocity (ft/sec) Stack Gas Dry Volumetric Flow Rate (dscf/hr) Stack Gas Dry Volumetric Flow Rate (dscf/min) EPA Method 4 Data 24.0 24.0 24.0 25.16 25.16 25.16 -0.01 -0.01 -0.01 0.84 0.84 0.84 0.0982 0.1301 0.1045 1068 1226 1162 1152 3.14 3.14 3.14 0.00 0.00 0.00 29.81 29.83 29.68 28.35 28.35 28.46 25.16 25.16 25.16 1528 1686 1622 1612 10.3 14.4 11.3 12.0 29,733 37,436 31,309 32,826 496 624 522 547 1 2 3 Average Vic Vm Y off Tm Pm Tm Vwc(std) Vm(std) Bws Inputs Volume of Water Condensed (mL) Volume of Stack Gas Collected (dcf) Meter Calibration Factor (unitless) Pressure Differential Across Orifice ("H2O) Temperature at Gas Meter (°F) Calculations Absolute Pressure at Gas Meter ("Hg) Absolute Temperature at Gas Meter i°R) Volume of Water Condensed (scf) Sample Gas Volume (dscf) Stack Gas Moisture Content (%/100) 165.5 62.464 0.9912 0.79 38.1 25.22 498.1 7.79 55.29 0.123 EPA Method 3A, 7E, 10 and 25A Data 1 223.6 85.899 0.9912 1.02 54.0 25.24 514 10.52 73.74 0.125 151.1 70.482 0.9912 1.06 51.5 25.24 511.5 7.11 60.81 0.105 2 3 25.23 508 8.47 63.28 0.118 Average O2 (%vd) CO2 (%vd) NOx (ppmvd) CO (ppmvd) TVOC (ppmvw as C3H8) TVOC (ppmvd as C3H8) 10.1 8.77 72.7 52.8 <1.0 <1.1 Mass Emission Calculations (Using EPA Methods 1-4) 1 11.0 8.68 116 11.9 <1.0 <1.1 11.4 7.68 127 14.4 <1.0 <1.1 2 3 10.8 8.38 105 26.4 <1.0 <1.1 Average NO), (lb/hr) NO), (lb/ton raw feed) CO (lb/hr) CO (lb/ton raw feed) TVOC (lb/hr as C3H8) TVOC (lb/ton raw feed as C3H8) *Kiln processed 2,040 lb of raw feed in 9.57 hours 0.258 2.42 0.114 1.07 <0.00388 <0.0364 0.519 4.87 0.0324 0.304 <0.00490 <0.0459 0.474 4.44 0.0327 0.307 <0.00400 <0.0376 0.417 3.91 0.0598 0.561 <0.00426 <0.0400 G P043AS-007255-RT-644 92 of 381 Kiln # 65 Test Performed For: Source(s) Tested: Test Condition: Test(s) Performed: Run Number Biochar Now, LLC Testing Performed By: Berthoud Plant / Colorado Montrose Air Quality Services Kiln # 65 Pilot Batch Process of Treated Wood 5/202 Run 1 Run 2 Project Manager: Jeff Goldfine Run 3 Average Date of Run 4/13/21 4/13/21 4/13/21 Emission Test Run Time Began - Ended Oxygen Concentration Carbon Dioxide Concentration Isokinetic Sampling Rate Stack Temperature Stack Temperature Moisture Content Stack Gas Velocity Stack Gas Flow @ Actual Conditions Stack Gas Flow @ Standard Conditions Stack Gas Flow @ Dry Standard Conditions Batch Time Raw feed processed %(dry) %(dry) % °F °C % volume f/s acfm scfm dscfm hr lb 0811-1034 1157-1409 1525-1745 10.1 11.0 11.4 10.8 8.77 8.68 7.68 8.38 97.0 103.0 101.3 100.4 1068 1226 1162 1152 576 663 628 622 12.3 12.5 10.5 11.8 10.3 14.4 11.3 12.0 1,946 2,707 2,130 2,261 566 713 583 621 496 624 522 547 - 9.57 2,040 Visible Emissions, Highest Six Minute Average OA 0.0 0.0 0.0 0.0 Particulate Concentration, Filterable Particulate Emissions, Filterable Particulate Emissions, Filterable gr/dscf lb/hr lb/ton 0.00413 0.00152 0.00155 0.00240 0.0175 0.00815 0.00692 0.0109 0.165 0.0765 0.0650 0.102 Particulate Concentration, Condensable Particulate Emissions, Condensable Particulate Emissions, Condensable gr/dscf lb/hr lb/ton 0.000753 0.00127 0.000989 0.00101 0.00320 0.00681 0.00443 0.00481 0.0300 0.0639 0.0415 0.0451 PKo Emissions, Total PM1a Emissions, Total lb/hr 0.0149 0.0123 0.00906 0.0121 lb/ton 0.140 0.115 0.0850 0.113 PM2 5 Emissions, Total PM25 Emissions, Total lb/hr lb/ton 0.0116 0.0107 0.109 0.101 0.00775 0.0100 0.0727 0.0941 Particulate Concentration, Total Particulate Emissions, Total Particulate Emissions, Total gr/dscf lb/hr lb/ton 0.00488 0.00280 0.00254 0.00341 0.0207 0.0150 0.0113 0.0157 0.195 0.140 0.106 0.147 G P043AS-007255-RT-644 93 of 381 Biochar Now Kiln 65 EPA Method 308 Parameters Project No. PROJ-007255 Parameters Run 1 Run 2 Run 3 Average Date Start Time Stop Time Un-Spiked Barometric Pressure, Pb (Inches Hg) Volume Metered, Vm (L) Meter Temperature, Tm (°F) Gas Meter Correction Factor, ' Run Time, 0 (minutes) Spiked Volume Metered, Vm (L) Meter Temperature, Tm (°F) Gas Meter Correction Factor, )6 Run Time, 0 (minutes) Total Methanol Collected Un-Spiked, m (ug) Total Methanol Collected Spiked, m (ug) Mass of Methanol Injected in Spiked Train, S (ug) RESULTS 4/13/21 8:11 8:34 25.16 48.37 36.8 1.010 120 <3.86 4/13/21 11:57 14"08 25.16 48.57 56.7 1.010 120 48.59 57.8 0.998 120 <3.78 115 308 4/13/21 15:25 17:37 25.16 43.50 47.7 1.010 105 <3.21 Volume Metered Un-Spiked, \A(std) (L) Volume Metered Spiked, \m(std) (L) METHANOL RESULTS Mass per Volume Spike, rr3 (ug/L) Spike Recovery, R Methanol Concentration, C (ppmv) Recovery Corrected Methanol Concentration, C (ppmv) Gas volumetric flow rate (dscfm) Methanol Emission Rate (lb/hr) Methanol Emission Rate (lb/ton)* *2,040 lb were processed in 9.57 hours 43.7 NA NA <0.0663 <0.183 460 <4.21 E-04 <3.95E-03 42.2 41.6 2.68 0.36 <0.0672 <0.186 496 <4.61 E-04 <4.32E-03 38.5 NA NA <0.0626 <0.173 494 <4.27E-04 <4.01 E-03 <0.0654 <0.181 484 <4.36E-04 <4.09E-03 G P043AS-007255-RT-644 94 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix A.10 Kiln 74 (Kiln 3) Calculations/Results G P043AS-007255-RT-644 95 of 381 4A, MONTROSE I AIR QUALIFY tiERvIEFS PROJ-007255 Biochar Now Kiln #74 4/15/2021 EPA Method 2 Data Run # 1 Start Time 10:20 Stop Time 12:44 2 13:50 15:58 1 2 3 16:58 19:04 3 Average DS Pbar Pg Cp VA Pavg TS A Pg Md MS PS Ts(abs)VS Q Q Inputs Stack Diameter (inches) Barometric Pressure ("Hg) Stack Static Pressure ("H2O) Pitot Tube Coefficient (unitless) Avg. Velocity Head of Stack Gas V("H2O) Stack Gas Temperature (°F) Calculations Stack Area (ft2) Stack Static Pressure ("Hg) Stack Gas Molecular Weight, dry basis (lb/lb-mole) Stack Gas Molecular Weight, wet basis (lb/lb-mole) Absolute Stack Pressure ("Hg) Absolute Stack Gas Temperature (°R ) Stack Gas Velocity (ft/sec) Stack Gas Dry Volumetric Flow Rate (dscf/hr) Stack Gas Dry Volumetric Flow Rate (dscf/min) EPA Method 4 Data 24.0 24.0 24.0 24.92 24.92 24.92 -0.01 -0.01 -0.01 0.84 0.84 0.84 0.0986 0.1063 0.0945 1233 1273 1019 1175 3.14 3.14 3.14 0.00 0.00 0.00 29.76 29.78 29.66 28.00 28.20 28.49 24.92 24.92 24.92 1693 1733 1479 1635 11.0 12.0 9.79 10.94 27,576 29,787 29,650 29,004 460 496 494 483 1 2 3 Average Vic Vm Y off Tm Pm Tm Vwc(std) Vm(std) Bws Inputs Volume of Water Condensed (mL) Volume of Stack Gas Collected (dcf) Meter Calibration Factor (unitless) Pressure Differential Across Orifice ("H2O) Temperature at Gas Meter (°F) Calculations Absolute Pressure at Gas Meter ("Hg) Absolute Temperature at Gas Meter i°R) Volume of Water Condensed (scf) Sample Gas Volume (dscf) Stack Gas Moisture Content (%/100) 200.3 62.438 0.9912 0.79 46.2 24.98 506 9.43 53.87 0.149 EPA Method 3A, 7E, 10 and 25A Data 1 173.6 61.457 0.9912 0.74 48.4 24.97 508 8.17 52.79 0.134 142.0 68.993 1.0071 0.91 48.5 24.99 509 6.68 60.23 0.100 2 3 0.128 Average O2 (%vd) CO2 (%vd) NOx (ppmvd) CO (ppmvd) TVOC (ppmvw as C3H8) TVOC (ppmvd as C3H8) 11.5 8.09 104 192 2.64 3.10 Mass Emission Calculations (Using EPA Methods 1-4) 1 11.7 8.22 125 109 <1.0 <1.2 11.0 7.62 85.2 16.8 1.27 1.41 2 3 11.4 7.98 105 106 <1.64 <1.89 Average NO), (lb/hr) NO), (lb/ton raw feed)) CO (lb/ton raw feed) CO (lb/hr) TVOC (lb/hr as C3H8) TVOC (lb/ton raw feed as C3H8) *Kiln processed 2,000 lb of raw feed in 8.73 hours 0.342 2.98 0.385 3.36 0.00979 0.0855 0.444 3.88 0.235 2.05 <0.00394 <0.0344 0.302 2.63 0.0361 0.315 0.00477 0.0417 0.363 3.17 0.219 1.91 <0.00617 <0.0538 G P043AS-007255-RT-644 96 of 381 Kiln #74 Test Performed For: Source(s) Tested: Test Condition: Test(s) Performed: Run Number Biochar Now, LLC Berthoud Plant / Colorado Kiln #74 Pilot Batch Process of Treated Wood 5/202 Run 1 Run 2 Testing Performed By: Montrose Air Quality Services Project Manager: Jeff Goldfine Run 3 Average Date of Run Emission Test Run Time Began - Ended Oxygen Concentration Carbon Dioxide Concentration Isokinetic Sampling Rate Stack Temperature Stack Temperature Moisture Content Stack Gas Velocity Stack Gas Flow @ Actual Conditions Stack Gas Flow @ Standard Conditions Stack Gas Flow @ Dry Standard Conditions Batch Time Raw feed processed %(dry) %(dry) °F °C % volume f/s acfm scfm dscfm hr lb 4/15/21 1020-1244 11.5 8.09 102.0 1233 667 14.9 11.0 2,078 540 460 4/15/21 1350-1558 11.7 8.22 92.5 1273 690 13.4 12.0 2,260 573 496 4/15/21 1658-1904 11.0 7.62 106.0 1019 548 10.0 9.79 1,846 549 494 11.4 7.98 1175 635 12.8 10.9 2,061 554 484 8.73 2,000 Visible Emissions, Highest Six Minute Average °I0 0.0 0.0 0.0 0.0 Particulate Concentration, Filterable Particulate Emissions, Filterable Particulate Emissions, Filterable gr/dscf lb/hr lb/ton 0.00263 0.0104 0.0906 0.00152 0.00646 0.0565 0.000922 0.00390 0.0341 0.00169 0.00691 0.0604 Particulate Concentration, Condensable Particulate Emissions, Condensable Particulate Emissions, Condensable gr/dscf lb/hr lb/ton 0.00112 0.00440 0.0384 0.00237 0.01007 0.0879 0.000948 0.00401 0.0350 0.00148 0.00616 0.0538 PM1a Emissions, Total PM1a Emissions, Total lb/hr lb/ton 0.0113 0.0991 0.0144 0.126 0.00663 0.0579 0.0108 0.0942 PM2.5 Emissions, Total PM25 Emissions, Total lb/hr lb/ton 0.00938 0.0819 0.0132 0.115 0.00589 0.0514 0.00948 0.0828 Particulate Concentration, Total Particulate Emissions, Total Particulate Emissions, Total gr/dscf lb/hr lb/ton 0.00375 0.0148 0.129 0.00389 0.0165 0.144 0.00187 0.00792 0.0691 0.00317 0.0131 0.114 G P043AS-007255-RT-644 97 of 381 Biochar Now Kiln 74 EPA Method 308 Parameters Project No. PROJ-007255 Parameters Run 1 Run 2 Run 3 Average Date Start Time Stop Time Un-Spiked Barometric Pressure, Pb (Inches Hg) Volume Metered, Vm (L) Meter Temperature, Tm (°F) Gas Meter Correction Factor, ' Run Time, 0 (minutes) Spiked Volume Metered, Vm (L) Meter Temperature, Tm (°F) Gas Meter Correction Factor, )6 Run Time, 0 (minutes) Total Methanol Collected Un-Spiked, m (ug) Total Methanol Collected Spiked, m (ug) Mass of Methanol Injected in Spiked Train, S (ug) RESULTS 4/15/21 10:20 12:44 24.92 49.61 45.5 1.010 120 51.23 46.7 0.998 120 35.8 172 308 4/15/21 13:50 13:58 24.92 48.38 43.8 1.010 120 <3.78 4/15/21 16:58 19:04 24.92 48.55 39.7 1.010 105 <1.45 Volume Metered Un-Spiked, \A(std) (L) Volume Metered Spiked, \m(std) (L) METHANOL RESULTS Mass per Volume Spike, rr3 (ug/L) Spike Recovery, R Methanol Concentration, C (ppmv) Recovery Corrected Methanol Concentration, C (ppmv) Gas volumetric flow rate (dscfm) Methanol Emission Rate (lb/hr) Methanol Emission Rate (Ib/ton)* *2,000 lb were processed in 8.73 hours 43.6 44.4 3.05 0.44 0.616 1.40 460 0.00321 0.0280 42.7 NA NA <0.0664 <0.151 496 <3.74E-04 <3.26E-03 43.2 NA NA <0.0252 <0.0572 494 <1.41E-04 <1.23E-03 <0.236 <0.536 484 <0.00124 <0.0108 G P043AS-007255-RT-644 98 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix A.11 Example Calculations G P043AS-007255-RT-644 99 of 381 I1 MONTROSE AIR QUALIFY NI-RI:RAS Sample Calculations for Kiln 56 Run Area of Sample Location 7r X d 2x12) ( 24.0 )2 As=Tzxl L2x12) Ay = 3.14/12 where: As = area of sample location (ft2) d = stack diameter (in) 2 = conversion factor (radius/diameter) 12 = conversion factor (in/ft) Stack Pressure Absolute Pa = Pb + P 13.6 0.01 Pa = 25.12+ 13.6 P = 25.12in.Hg where: Pa = stack pressure absolute (in. Hg) Pb = barometric pressure (in. Hg) PS = static pressure (in. H2O) 13.6 = conversion factor (in. H2O/in Hg) G P043AS-007255-RT-644 100 of 381 Volume of Dry Gas Collected Corrected to Standard Temperature and Pressure Vm(std) Vm(std) H 17.64(Vm)(Ya)Pv+ � 6� (T+ 460 17.64(55.770)(0.9912) 25.12+ � 66 2 (33.0+ 460 V m(std) = 49.78scf where: Vm(std) Vm Yd Pb OH Tm 13.6 17.64 460 volume of gas collected at standard temperature and pressure (scf) volume of gas sampled at meter conditions (ft3) gas meter correction factor (dimensionless) barometric pressure (in. Hg) average sample pressure (in. H2O) average gas meter temperature (°F) conversion factor (in. H2O/in Hg) ratio of standard temperature over standard pressure (°R/in.Hg) conversion (°F to °R) Volume of Water Vapor Collected Corrected to Standard Temperature and Pressure Vw(std) Vw(std) Vw(std) 0.04715 Vwc +Vwsb 0.04715(150.9+15.1) 7.8 lscf where: Vw(std) vwc Vwsg 0.04715 volume of water vapor at standard conditions (scf) weight gain of liquid collected (g) weight gain of silica gel (g) volume occupied by one gram of water at standard temperature and pressure (ft3/g) G P043AS-007255-RT-644 101 of 381 Percent Moisture BwS =100x BwS =100x B,,s =13.6% where: BwS Vm(std) Vw(std) 100 Vw(std) Vm(std) + Vw(std) J 7.81 1 7.81) J moisture content of the gas stream C/0) volume of gas collected at standard temperature and pressure (scf) volume of water vapor at standard conditions (scf) conversion factor Molecular Weight of Dry Gas Stream1 %CO., %O(%co+%N2)L2 M = 44x + 32x + 28x 100 100 100 9.87 I 9.54(80.6)) 44x + 32x + 28x 100 100 100 29.961b llb — mole d Md Md where: Md %CO2 44 %02 32 %CO 0/01\12 28 100 molecular weight of the dry gas stream (lb/lb-mole) carbon dioxide content of the dry gas stream r/o) molecular weight of carbon dioxide (lb/lb-mole) oxygen content of the dry gas stream C/0) molecular weight of oxygen (lb/lb-mole) carbon monoxide content of the dry gas stream (`)/0) nitrogen content of the dry gas stream (%) molecular weight of nitrogen (lb/lb-mole) conversion factor 1 The remainder of the gas stream after subtracting carbon dioxide and oxygen is assumed to be nitrogen. G P043AS-007255-RT-644 102 of 381 Molecular Weight of Wet Gas Stream M�=IM�x�1 l�+�l8x I 100)) 100) 13.61'\_( 13.61sM=129.96x1111118x 1oo)j 100 1 Ms = 2834/b / !h mole where: MS Ma EL 18 100 molecular weight of the wet gas stream (lb/lb-mole) molecular weight of the dry gas stream (lb/lb-mole) moisture content of the gas stream (%) molecular weight of water (lb/lb-mole) conversion factor Velocity of Gas Stream V V V 85.49 Cp)( JAP) 1\ (1" � (T�i46o) / p s Pb +13s.6 85.49(0.84)(0.0881) 9.63./i /s where: VS Cp JAP Ts Ms Pb Ps 85.49 460 13.6 (1,189_i 460 /0.Ol \ (28.34)25.12+ 13.6 , average velocity of the gas stream (ft/sec) pitot tube coefficient (dimensionless) average square root of velocity pressures (in. H2O)112 average stack temperature (°F) molecular weight of the wet gas stream (lb/lb-mole) barometric pressure (in. Hg) static pressure of gas stream (in. H2O) pitot tube constant (ft/sec)([(lb/lb-mole)(in. Hg)]/[(°R)(in. H2O)])'/z conversion (°F to °R) conversion factor (in. H2O/in Hg) G P043AS-007255-RT-644 103 of 381 Volumetric Flow of Gas Stream - Actual Conditions Q, Q� Q, 60(US)(AS) 60(9.63)(3.14) 1, 816acfin where: Qa vs A 60 volumetric flow rate of the gas stream at actual conditions (acfm) average velocity of the gas stream (ft/sec) area of duct or stack (ft2) conversion factor (sec/min) Volumetric Flow of Gas Stream - Standard Conditions Qstd Qstd Qstd 17.64(Q ) � a13.6) (T+ 460 17.64(1I816) 25.12+ -0.011 L 13.6 ) 488scfin where: Qstd Qa Ts Pb PS 13.6 17.64 460 (1,189 + 460 volumetric flow rate of the gas stream at standard conditions (scfm) volumetric flow rate of the gas stream at actual conditions (acfm) average stack temperature (°F) barometric pressure (in. Hg) static pressure of gas stream (in. H2O) conversion factor (in. H2O/in Hg) ratio of standard temperature over standard pressure (°Rlin.Hg) conversion (°F to °R) G P043AS-007255-RT-644 104 of 381 Volumetric Flow of Gas Stream - Standard Conditions - Dry Basis Qdstd Qdstd Qdstd where: Qdstd Qstd Bws 100 Qstd ( B��s 1 100 , 488(1 13.6 100 J 422dscf n volumetric flow rate of the gas stream at standard conditions, on a dry basis (dscfm) volumetric flow rate of the gas stream at standard conditions (scfm) moisture content of the gas stream (°/0) conversion factor Area of Nozzle An All An 1Z X I do l2 2x12) (0.7431 ;TXc2x12 0.00301/12 where: An d n 12 2 area of nozzle (ft2) diameter of nozzle (in) conversion factor (in/ft) conversion factor (radius/diameter) G P043AS-007255-RT-644 105 of 381 Percent Isokinetic 0.0945(T5 + 460)( V,,,(Gtd) I I Pb-�- PS �(v5)(A)(Q)Iii1—B'vs 13.6 L 100) 0.0945(1,189+460)(49.78) I ( -0.011 ( 13.6 � 25.12+ 13.6 )�9.63�(0.00301�(120�L1- 100 ) I =102.5% where: I Ts Vm(std) Pb PS VS An 0 Bws 0.0945 13.6 100 percent isokinetic C/0) average stack temperature (°F) volume of gas collected at standard temperature and pressure (scf) barometric pressure (in. Hg) static pressure of gas stream (in. H2O) average velocity of the gas stream (ft/sec) cross sectional area of nozzle (ft2) sample time (min) moisture content of the gas stream (°/0) conversion (°F to °R) conversion factor (in. H20/in Hg) conversion factor G P043AS-007255-RT-644 106 of 381 NOx Concentration, Corrected for Analyzer Drift2 Cgas C (lea where: Cgas Cavg Co Cma Cm (Caiig Co (Cii,a) )(cm m co) (144.9) (96.6—0.2) (145.0-0.2) 96.4 ppmvd average gas concentration, adjusted for drift (ppm or %) average unadjusted gas concentration (ppm or %) average of initial and final calibration value for the zero gas (ppm or %) actual value for the upscale calibration gas (ppm or %) average of initial and final calibration value for the upscale gas (ppm or %) NOx Emission Rate (lb/hr)3 ((Igo, )(MW )(.(2d„d )(60) (385.3)(106) (96.4)(46.01)(422)(60) (385.3)(106) 0.291/b / hr 1 -'lb l hr Elb/hr where: Elb/hr Cgas MW Qdstd 60 385.3 106 NO emission rate (lb/hr) concentration of NOR, corrected for analyzer drift (ppm) molecular weight (lb/lb-mole) volumetric flow rate of the gas stream at standard conditions, on a dry basis (dscfm) conversion factor (min/hr) molar volume of 1 lb -mole of gas at standard conditions (dscf/lb-mole) conversion factor (ppm) 2 Similar calculations are performed for O2, 0O2, and CO. 3 Similar calculations are performed for CO, VOC and MeOH, using the appropriate molecular weights. G P043AS-007255-RT-644 107 of 381 NOx Emission Rate (lb/ton raw feed) 4 (h/h/Il,. )( r)(2,000) (P) (o.291)(8.80)(2, 000) (2,120) 2.42/b / ton Elb /ton i'lb lton 'lb lton where: EIb/ton Elb/hr QT 2,000 P NOx emission rate (lb/ton of raw feed) NOX emission rate (lb/hr) total test batch time (hr) conversion factor (lb/ton) raw feed (Ib) Filterable PM Concentration (grldscf)5 (in, )05.43) ) ) (0.0079)(15.43) (49.78) 0.00245/b / chic/ C„, C n1 Ci where: Cm me 15.43 Vm(std) PM concentration (gr/dscf) mass of PM collected in sample (g) conversion factor (gr/g) volume of gas collected at standard temperature and pressure (dscf) 4 Similar calculations are performed for all PM fractions, CO, VOC and MeOH. 5 Similar calculations are performed for CPM and total PM. G P043AS-007255-RT-644 108 of 381 Filterable PM Emission Rate (lb/hr)6 (c,)(Qasta)(60) (7,000) (o.00245)(422)(60) (7,000) 0.00885/b /hr P' ]b / hr 'lb l hr where: Elb/hr Cm Qdstd 60 7,000 filterable PM emission rate (lblhr) filterable PM concentration (griciscf) volumetric flow rate of the gas stream at standard conditions, on a dry basis (dscfm) conversion factor (min/hr) conversion factor (grllb) Mho Emission Rate (lb/hr)7 where: EPM10 0.67= Elb/hr ECPM 0.67(''lb/hr )+ kCPM 0.67 (0.00885) + 0.00280 0.00873/b /hr = PKo emission rate (lb/hr) ratio of PM10 to filterable PM based on the ton/yr emission limits presented in Construction Permit No. 15WE1395, Issuance 5, Condition 2, Annual Limits. = filterable PM emission rate (lb/hr) = condensable PM emission rate (lb/hr) 6 Similar calculations are performed for CPM and total PM. 7 Similar calculations are performed for PM2.5, using a PM2.5:PM ratio of 0.48. G P043AS-007255-RT-644 109 of 381 Methanol Concentration (ppmv) (n'\IOH )(28.31)(385.3)(106) (i/flStd )(106 )(45359)(jpyr (8.50(28.30(385.3)001 (43.67)(106)(453.59)(32.04) 0.146 ppmv /A eOH CAleOH CHeOH where: CMeOH m McOH 28.31 385.3 106 Vm(std) 106 453.59 MW methanol concentration (ppmv) mass of methanol collected or detection limit (µg) conversion factor (l/dscf) molar volume of 1 lb -mole of gas at standard conditions (dscf/lb-mole) conversion factor (ppmv) volume of gas collected at standard temperature and pressure (I) conversion factor (µg/g) conversion factor (glIb) molecular weight (lb/lb-mole) Methanol Concentration, Corrected for Spike Recovery (ppmv) CCOI'1' L Ale OH R 0.146 0.24 CCO1.,. = 0.617 pp 1v where: Ccorr CMeOH R methanol concentration, corrected for spike recovery (ppmv) methanol concentration (ppmv) spike recovery G P043AS-007255-RT-644 110 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report APPENDIX B FACILITY PROCESS DATA G P043AS-007255-RT-644 111 of 381 4,/\, ONTRO E wI AIR QUALIFY tiERvIEFS -tc5C, (jJc:0 'i- L. 5 Turas 47,4 v vin, • 1:.-. -* ZPIO LO 31.000 G P043AS-007255-RT-644 112 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report APPENDIX C LABORATORY ANALYSIS DATA G P043AS-007255-RT-644 113 of 381 4,/\, ONTRO E wI AIR QUALIFY tiERvIEFS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix C.1 Particulate Matter Analyses G P043AS-007255-RT-644 114 of 381 ti\ MONTROSE I AIR QUALIFY tiERvIEFS 6 M.ONTROSE EPA Method 5/202 Gravimetric Analysis Report MR ccUIai,1iv srivicrc Project Code: Date Finalized: Analyst: PROJ-007255 4/28/2021 T. Wojtach/J. Kinney Laboratory Results Summary Sample ID Filterable Particulate Matter (mg) Kiln 2 (Kiln 56), Run #1 7.9 Kiln 2 (Kiln 56), Run #2 4.5 Kiln 2 (Kiln 56), Run #3 5.4 Sample ID Condensable Particulate Matter (mg) Kiln 2 (Kiln 56), Run #1 2.5 Kiln 2 (Kiln 56), Run #2 4.7 Kiln 2 (Kiln 56), Run #3 2.3 *Blank corrections were performed in accordance with EPA Method 5. CPM value includes a field blank correction. Analytical Narrative Quartz fiber filters were dessicated and tared to a constant weight in the MAQS laboratory prior to sampling. Following testing, the filters were dessicated for at least 24 hours, then weighed to a constant weight (±0.5 mg). The acetone rinses were measured to the nearest milliliter, transferred to tared aluminum weighing dishes, taken to dryness under a fume hood, dessicated for at least 24 hours, then weighed to a constant weight (±0.5 mg). Each result above represents total filterable particulate matter for each test run (acetone rinse + filter catch), with no blank correction performed unless otherwise indicated. Teflon CPM filters were extracted in a sonicator three times with water and three times with hexane. The extraction water was added to the back -half impinger contents and extracted with hexane three times in a separatory funnel. The inorganic fraction was transferred to a tared Teflon baggie, baked at 105C until 10 mL remained, taken to dryness under a fume hood, dessicated for at least 24 hours, then weighed to a constant weight (±0.5 mg). The organic fraction was combined with the acetone and hexane field rinses, measured to the nearest milliliter, transferred to a tared aluminum weighing dish, taken to dryness under a fume hood, dessicated for at -- •_. Instrumentation All measurements were taken using a Torbal Model AGCN2OO Analytical Balance under laboratory conditions. The instrument is auto -calibrated and challanged with three NIST-traceable reference weights daily. Detection Limit / Sensitivity All measurements are recorded to 0.0001g (0.1mg). Notes No deviations from the analytical procedures from EPA Method 5 were noted. All samples were received in good condition. After analysis, all samples are archived for a period of one year. Attachments Gravimetric Analysis Logs Sample Chain of Custody G P043AS-007255-RT-644 115 of 381 MONTItOSE ' TALI i Y $' tvlc ' r Project Code: PROJ-007255 Unit ID: EPA Method 5 Gravimetric Analysis Log Kiln 2 (Kiln 56) Front -Half Particulate Matter Filter Catch Filter # Final Filter Weight #1 (g) Final Filter Weight #2 (g) Filter Tare Weight #1 (g) Filter Tare Weight #2 (g) Filter Catch (g) Run #1 Run #2 Run #3 Blank 1099 1103 1055 1056 Date Weight (g) Date Weight (g) Date Weight (g) Date Weight (g) 4/22/21 0.3405 4/22/21 0.3336 4/22/21 0.3392 4/22/21 0.3332 4/23/21 0.3400 4/23/21 0.3338 4/23/21 0.3394 4/23/21 0.3329 12/29/20 0.3348 12/29/20 0.3302 12/22/20 0.3349 12/22/20 0.3330 12/30/20 0.3348 12/30/20 0.3300 12/29/20 0.3349 12/29/20 0.3330 0.0055 0.0036 0.0044 0.0001 Front -Half Particulate Matter Acetone Rinse Catch Rinse Volume (ml) Rinse Mass (g) Tin # Final Dish Weight #1 (g) Final Dish Weight #2 (g) Dish Tare Weight (g) Dish Tare Weight (g) Total Rinse Catch (g) Acetone Blank Correction Run #1 59.4 Run #2 68.7 Run #3 64.2 Blank 73.1 46.6 6833 53.9 6832 50.4 6831 57.4 6834 Date Weight (g) Date Weight (g) Date Weight (g) Date Weight (g) 4/22/21 6.0173 4/22/21 6.0044 4/22/21 5.9587 4/22/21 6.0397 4/23/21 6.0175 4/23/21 6.0043 4/23/21 5.9586 4/23/21 6.0399 10/27/20 6.0149 10/27/20 6.0036 10/27/20 5.9576 10/27/20 6.0396 11/5/20 6.0149 11/5/20 6.0031 11/5/20 5.9575 11/5/20 6.0397 0.0025 0.0010 0.0011 0.0001 EPA Method 5 §12.6: Acetone Blank Concentration Ca= ma VaPa (Eq. 5-4) Ca = 0.1 Where: Ca = Acetone blank residue concentration (mg/mg) m a = Mass of residue of acetone after evaporation (mg) V a = Volume of acetone blank (mL) p a = Density of acetone (785 mg/mL) EPA Method 5 §12.7: Acetone Wash Blank Wa= CaVawPa (Eq. 5-5) Where: W a = Weight of residue in acetone wash (mg) Ca = Acetone blank residue concentration (mg/mg) Vow = Volume of acetone wash (mL) p a = Density of acetone (785 mg/mL) Run #1: Run #2: Run #3: (1.74E-06)(59.4)(785) (1.74E-06)(68.7)(785) (1.74E-06)(64.2)(785) Total Particulate Catch (73)(785) = 0.1 mg = 0.1 mg = 0.1 mg = 1.74E-06 mg/mg Maximum Allowable Blank (ma) 0.5 0.5 0.5 Filter Catch (g) + Rinse Catch (g) - Acetone Blank (g) Run #1 0.0055 0.0025 0.0001 Run #2 0.0036 0.0010 0.0001 Run #3 0.0044 0.0011 0.0001 Total PM (g) 0.0079 0.0045 0.0054 G P043AS-007255-RT-644 116 of 381 EPA Method 202 Gravimetric Analysis Lo I MONTROSE AIRQUALITY SERVi,CF; Y Log Project Code: PROJ-007255 Unit ID: Kiln 2 (Kiln 56) Back -Half Organic Particulate Matter Catch Tin # Final Weight #1 (g) Final Weight #2 (g) Tare Weight #1 (g) Tare Weight #2 (g) Organic CPM Catch (g) Run #1 Run #2 Run #3 Blank 6824 6823 6822 6821 Date Weight (g) Date Weight (g) Date Weight (g) Date Weight (g) 4/26/21 5.9357 4/26/21 5.9530 4/26/21 6.0180 4/27/21 6.0463 4/27/21 5.9356 4/27/21 5.9530 4/27/21 6.0181 4/27/21 6.0460 10/27/20 5.9332 10/27/20 5.9493 10/27/20 6.0163 10/27/20 6.0451 11/5/20 5.9327 11/5/20 5.9488 11/5/20 6.0158 11/5/20 6.0448 0.0027 0.0039 0.0020 0.0012 Back -Half Inorganic Particulate Matter Catch Teflon Baggie # Final Weight #1 (g) Final Weight #2 (g) Tare Weight #1 (g) Tare Weight #2 (g) Inorganic CPM Catch (g) Condensable Particulate Catch Run #1 Run #2 Run #3 Blank 1389 1392 1393 1398 Date Weight (g) Date Weight (g) Date Weight (g) Date Weight (g) 4/26/21 3.1738 4/26/21 3.2937 4/27/21 3.3838 4/26/21 3.2614 4/28/21 3.1742 4/27/21 3.2942 4/28/21 3.3840 4/27/21 3.2616 4/14/21 3.1723 4/14/21 3.2913 4/14/21 3.3815 4/14/21 3.2610 4/16/21 3.1722 4/16/21 3.2913 4/16/21 3.3819 4/16/21 3.2606 0.0017 0.0027 0.0022 0.0007 Organic CPM Catch (g) + Inorganic CPM Catch (g) - CPM Blank (g) Run #1 0.0027 0.0017 0.0019 Run #2 0.0039 0.0027 0.0019 Run #3 0.0020 0.0022 0.0019 Total CPM (g) 0.0025 0.0047 0.0023 G P043AS-007255-RT-644 117 of 381 6 M.ONTROSE EPA Method 5/202 Gravimetric Analysis Report MR ccUIai,1iv srivicrc Project Code: Date Finalized: Analyst: PROJ-007255 5/3/2021 T. Wojtach/ J. Kinney Laboratory Results Summary Sample ID Filterable Particulate Matter (mg) Kiln 1 (Kiln 65), Run #1 14.8 Kiln 1 (Kiln 65), Run #2 7.3 Kiln 1 (Kiln 65), Run #3 6.1 Sample ID Condensable Particulate Matter (mg) Kiln 1 (Kiln 65), Run #1 2.7 Kiln 1 (Kiln 65), Run #2 6.1 Kiln 1 (Kiln 65), Run #3 3.9 *Blank corrections were performed in accordance with EPA Method 5. CPM value includes a field blank correction. Analytical Narrative Quartz fiber filters were dessicated and tared to a constant weight in the MAQS laboratory prior to sampling. Following testing, the filters were dessicated for at least 24 hours, then weighed to a constant weight (±0.5 mg). The acetone rinses were measured to the nearest milliliter, transferred to tared aluminum weighing dishes, taken to dryness under a fume hood, dessicated for at least 24 hours, then weighed to a constant weight (±0.5 mg). Each result above represents total filterable particulate matter for each test run (acetone rinse + filter catch), with no blank correction performed unless otherwise indicated. Teflon CPM filters were extracted in a sonicator three times with water and three times with hexane. The extraction water was added to the back -half impinger contents and extracted with hexane three times in a separatory funnel. The inorganic fraction was transferred to a tared Teflon baggie, baked at 105C until 10 mL remained, taken to dryness under a fume hood, dessicated for at least 24 hours, then weighed to a constant weight (±0.5 mg). The organic fraction was combined with the acetone and hexane field rinses, measured to the nearest milliliter, transferred to a tared aluminum weighing dish, taken to dryness under a fume hood, dessicated for at -- •_. Instrumentation All measurements were taken using a Torbal Model AGCN2OO Analytical Balance under laboratory conditions. The instrument is auto -calibrated and challanged with three NIST-traceable reference weights daily. Detection Limit / Sensitivity All measurements are recorded to 0.0001g (0.1mg). Notes No deviations from the analytical procedures from EPA Method 5 were noted. All samples were received in good condition. After analysis, all samples are archived for a period of one year. Attachments Gravimetric Analysis Logs Sample Chain of Custody G P043AS-007255-RT-644 118 of 381 MONTItOSE ' TALI i Y $' tvlc ' r Project Code: PROJ-007255 Unit ID: EPA Method 5 Gravimetric Analysis Log Kiln 1 (Kiln 65) Front -Half Particulate Matter Filter Catch Filter # Final Filter Weight #1 (g) Final Filter Weight #2 (g) Filter Tare Weight #1 (g) Filter Tare Weight #2 (g) Filter Catch (g) Run #1 Run #2 Run #3 Blank 1155 1091 1101 1056 Date Weight (g) Date Weight (g) Date Weight (g) Date Weight (g) 4/22/21 0.3755 4/22/21 0.3402 4/22/21 0.3368 4/22/21 0.3332 4/23/21 0.3752 4/23/21 0.3400 4/23/21 0.3364 4/23/21 0.3329 1/4/21 0.3657 12/29/20 0.3373 12/29/20 0.3335 12/22/20 0.3330 1/5/21 0.3660 12/30/20 0.3375 12/30/20 0.3336 12/29/20 0.3330 0.0095 0.0027 0.0030 0.0001 Front -Half Particulate Matter Acetone Rinse Catch Rinse Volume (ml) Rinse Mass (g) Tin # Final Dish Weight #1 (g) Final Dish Weight #2 (g) Dish Tare Weight (g) Dish Tare Weight (g) Total Rinse Catch (g) Acetone Blank Correction Run #1 64.2 Run #2 61.7 Run #3 79.5 Blank 73.1 50.4 6830 48.4 6829 62.4 6828 57.4 6834 Date Weight (g) Date Weight (g) Date Weight (g) Date Weight (g) 4/22/21 5.9832 4/22/21 6.0321 4/22/21 6.0438 4/22/21 6.0397 4/23/21 5.9835 4/23/21 6.0323 4/23/21 6.0441 4/23/21 6.0399 10/27/20 5.9780 10/27/20 6.0276 10/27/20 6.0409 10/27/20 6.0396 11/5/20 5.9779 11/5/20 6.0273 11/5/20 6.0406 11/5/20 6.0397 0.0054 0.0047 0.0032 0.0001 EPA Method 5 §12.6: Acetone Blank Concentration ma Ca = Ca = VaPa (Eq. 5-4) 0.1 Where: Ca = Acetone blank residue concentration (mg/mg) m a = Mass of residue of acetone after evaporation (mg) V a = Volume of acetone blank (mL) p a = Density of acetone (785 mg/mL) EPA Method 5 §12.7: Acetone Wash Blank Wa = CaVawPa (Eq. 5-5) Where: W a = Weight of residue in acetone wash (mg) Ca = Acetone blank residue concentration (mg/mg) Vow = Volume of acetone wash (mL) p a = Density of acetone (785 mg/mL) Run #1: Run #2: Run #3: (1.74E-06)(64.2)(785) (1.74E-06)(61.7)(785) (1.74E-06)(79.5)(785) Total Particulate Catch (73)(785) = 0.1 mg = 0.1 mg = 0.1 mg = 1.74E-06 mg/mg Maximum Allowable Blank (ma) 0.5 0.5 0.6 Filter Catch (g) + Rinse Catch (g) - Acetone Blank (g) Run #1 0.0095 0.0054 0.0001 Run #2 0.0027 0.0047 0.0001 Run #3 0.0030 0.0032 0.0001 Total PM (g) 0.0148 0.0073 0.0061 G P043AS-007255-RT-644 119 of 381 EPA Method 202 Gravimetric Analysis Lo I MONTROSE AIRQUALITY SERVi,CF; Y Log Project Code: PROJ-007255 Unit ID: Kiln 1 (Kiln 65) Back -Half Organic Particulate Matter Catch Tin # Final Weight #1 (g) Final Weight #2 (g) Tare Weight #1 (g) Tare Weight #2 (g) Organic CPM Catch (g) Run #1 Run #2 Run #3 Blank 6820 6819 6818 6821 Date Weight (g) Date Weight (g) Date Weight (g) Date Weight (g) 4/26/21 6.0203 4/26/21 6.0159 4/26/21 6.0550 4/27/21 6.0463 4/27/21 6.0206 4/27/21 6.0161 4/27/21 6.0552 4/27/21 6.0460 10/27/20 6.0193 10/27/20 6.0129 10/27/20 6.0529 10/27/20 6.0451 11/5/20 6.0188 11/5/20 6.0124 11/5/20 6.0525 11/5/20 6.0448 0.0014 0.0033 0.0024 0.0012 Back -Half Inorganic Particulate Matter Catch Teflon Baggie # Final Weight #1 (g) Final Weight #2 (g) Tare Weight #1 (g) Tare Weight #2 (g) Inorganic CPM Catch (g) Condensable Particulate Catch Run #1 Run #2 Run #3 Blank 1395 1403 1401 1398 Date Weight (g) Date Weight (g) Date Weight (g) Date Weight (g) 4/26/21 3.2737 4/26/21 3.2877 4/29/21 3.4575 4/26/21 3.2614 4/27/21 3.2741 4/27/21 3.2880 4/29/21 3.4571 4/27/21 3.2616 4/14/21 3.2708 4/14/21 3.2834 4/14/21 3.4539 4/14/21 3.2610 4/16/21 3.2706 4/16/21 3.2830 4/16/21 3.4538 4/16/21 3.2606 0.0032 0.0047 0.0034 0.0007 Organic CPM Catch (g) + Inorganic CPM Catch (g) - CPM Blank (g) Run #1 0.0014 0.0032 0.0019 Run #2 0.0033 0.0047 0.0019 Run #3 0.0024 0.0034 0.0019 Total CPM (g) 0.0027 0.0061 0.0039 G P043AS-007255-RT-644 120 of 381 6 M.ONTROSE EPA Method 5/202 Gravimetric Analysis Report MR ccUIai,1iv srivicrc Project Code: Date Finalized: Analyst: PROJ-007255 5/3/2021 T. Wojtach/J. Kinney Laboratory Results Summary Sample ID Filterable Particulate Matter (mg) Kiln 3 (Kiln 74), Run #1 9.2 Kiln3(Kiln74),Run#2 5.2 Kiln 3 (Kiln 74), Run #3 3.6 Sample ID Condensable Particulate Matter (mg) Kiln 3 (Kiln 74), Run #1 3.9 Kiln 3 (Kiln 74), Run #2 8.1 Kiln 3 (Kiln 74), Run #3 3.7 *Blank corrections were performed in accordance with EPA Method 5. CPM value includes a field blank correction. Analytical Narrative Quartz fiber filters were dessicated and tared to a constant weight in the MAQS laboratory prior to sampling. Following testing, the filters were dessicated for at least 24 hours, then weighed to a constant weight (±0.5 mg). The acetone rinses were measured to the nearest milliliter, transferred to tared aluminum weighing dishes, taken to dryness under a fume hood, dessicated for at least 24 hours, then weighed to a constant weight (±0.5 mg). Each result above represents total filterable particulate matter for each test run (acetone rinse + filter catch), with no blank correction performed unless otherwise indicated. Teflon CPM filters were extracted in a sonicator three times with water and three times with hexane. The extraction water was added to the back -half impinger contents and extracted with hexane three times in a separatory funnel. The inorganic fraction was transferred to a tared Teflon baggie, baked at 105C until 10 mL remained, taken to dryness under a fume hood, dessicated for at least 24 hours, then weighed to a constant weight (±0.5 mg). The organic fraction was combined with the acetone and hexane field rinses, measured to the nearest milliliter, transferred to a tared aluminum weighing dish, taken to dryness under a fume hood, dessicated for at -- •_. Instrumentation All measurements were taken using a Torbal Model AGCN2OO Analytical Balance under laboratory conditions. The instrument is auto -calibrated and challanged with three NIST-traceable reference weights daily. Detection Limit / Sensitivity All measurements are recorded to 0.0001g (0.1mg). Notes No deviations from the analytical procedures from EPA Method 5 were noted. All samples were received in good condition. After analysis, all samples are archived for a period of one year. Attachments Gravimetric Analysis Logs Sample Chain of Custody G P043AS-007255-RT-644 121 of 381 MONTItOSE ' TALI i Y $' tvlc ' r Project Code: PROJ-007255 Unit ID: EPA Method 5 Gravimetric Analysis Log Kiln 3 (Kiln 74) Front -Half Particulate Matter Filter Catch Filter # Final Filter Weight #1 (g) Final Filter Weight #2 (g) Filter Tare Weight #1 (g) Filter Tare Weight #2 (g) Filter Catch (g) Run #1 Run #2 Run #3 Blank 1058 1045 1059 1056 Date Weight (g) Date Weight (g) Date Weight (g) Date Weight (g) 4/22/21 0.3399 4/22/21 0.3356 4/22/21 0.3358 4/22/21 0.3332 4/23/21 0.3395 4/23/21 0.3356 4/23/21 0.3353 4/23/21 0.3329 12/22/20 0.3319 12/22/20 0.3332 12/22/20 0.3324 12/22/20 0.3330 12/29/20 0.3317 12/29/20 0.3332 12/29/20 0.3322 12/29/20 0.3330 0.0079 0.0024 0.0033 0.0001 Front -Half Particulate Matter Acetone Rinse Catch Rinse Volume (ml) Rinse Mass (g) Tin # Final Dish Weight #1 (g) Final Dish Weight #2 (g) Dish Tare Weight (g) Dish Tare Weight (g) Total Rinse Catch (g) Acetone Blank Correction Run #1 58.7 Run #2 62.5 Run #3 61.5 Blank 73.1 46.1 6827 49.1 6826 48.3 6825 57.4 6834 Date Weight (g) Date Weight (g) Date Weight (g) Date Weight (g) 4/22/21 5.9414 4/22/21 5.9354 4/22/21 5.8924 4/22/21 6.0397 4/23/21 5.9414 4/23/21 5.9358 4/23/21 5.8924 4/23/21 6.0399 10/27/20 5.9402 10/27/20 5.9328 10/27/20 5.8920 10/27/20 6.0396 11/5/20 5.9398 11/5/20 5.9326 11/5/20 5.8920 11/5/20 6.0397 0.0014 0.0029 0.0004 0.0001 EPA Method 5 §12.6: Acetone Blank Concentration ma Ca = Ca = VaPa (Eq. 5-4) 0.1 Where: Ca = Acetone blank residue concentration (mg/mg) m a = Mass of residue of acetone after evaporation (mg) V a = Volume of acetone blank (mL) p a = Density of acetone (785 mg/mL) EPA Method 5 §12.7: Acetone Wash Blank Wa = CaVawPa (Eq. 5-5) Where: W a = Weight of residue in acetone wash (mg) Ca = Acetone blank residue concentration (mg/mg) Vow = Volume of acetone wash (mL) p a = Density of acetone (785 mg/mL) Run #1: Run #2: Run #3: (1.74E-06)(58.7)(785) (1.74E-06)(62.5)(785) (1.74E-06)(61.5)(785) Total Particulate Catch (73)(785) = 0.1 mg = 0.1 mg = 0.1 mg = 1.74E-06 mg/mg Maximum Allowable Blank (ma) 0.5 0.5 0.5 Filter Catch (g) + Rinse Catch (g) - Acetone Blank (g) Run #1 0.0079 0.0014 0.0001 Run #2 0.0024 0.0029 0.0001 Run #3 0.0033 0.0004 0.0001 Total PM (g) 0.0092 0.0052 0.0036 G P043AS-007255-RT-644 122 of 381 EPA Method 202 Gravimetric Analysis Lo I MONTROSE AIRQUALITY SERVi,CF; Y Log Project Code: PROJ-007255 Unit ID: Kiln 3 (Kiln 74) Back -Half Organic Particulate Matter Catch Tin # Final Weight #1 (g) Final Weight #2 (g) Tare Weight #1 (g) Tare Weight #2 (g) Organic CPM Catch (g) Run #1 Run #2 Run #3 Blank 6817 6816 6815 6821 Date Weight (g) Date Weight (g) Date Weight (g) Date Weight (g) 4/26/21 6.0618 4/26/21 6.0436 4/26/21 5.9532 4/27/21 6.0463 4/27/21 6.0618 4/27/21 6.0350 4/27/21 5.9531 4/27/21 6.0460 10/27/20 6.0598 10/27/20 6.0327 10/27/20 5.9504 10/27/20 6.0451 11/5/20 6.0593 11/5/20 6.0322 11/5/20 5.9502 11/5/20 6.0448 0.0022 0.0068 0.0029 0.0012 Back -Half Inorganic Particulate Matter Catch Teflon Baggie # Final Weight #1 (g) Final Weight #2 (g) Tare Weight #1 (g) Tare Weight #2 (g) Inorganic CPM Catch (g) Condensable Particulate Catch Run #1 Run #2 Run #3 Blank 1394 1387 1391 1398 Date Weight (g) Date Weight (g) Date Weight (g) Date Weight (g) 4/28/21 3.3218 4/29/21 3.2440 4/28/21 3.3267 4/26/21 3.2614 4/29/21 3.3220 4/29/21 3.2443 4/29/21 3.3262 4/27/21 3.2616 4/14/21 3.3183 4/14/21 3.2409 4/14/21 3.3238 4/14/21 3.2610 4/16/21 3.3183 4/16/21 3.2410 4/16/21 3.3237 4/16/21 3.2606 0.0036 0.0032 0.0027 0.0007 Organic CPM Catch (g) + Inorganic CPM Catch (g) - CPM Blank (g) Run #1 0.0022 0.0036 0.0019 Run #2 0.0068 0.0032 0.0019 Run #3 0.0029 0.0027 0.0019 Total CPM (g) 0.0039 0.0081 0.0037 G P043AS-007255-RT-644 123 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix C.2 Methanol Analyses G P043AS-007255-RT-644 124 of 381 ti\ MONTROSE I AIR QUALIFY tiERvIEFS Montrose Air Quality Services, LLC — Denver 990 West 43rd Avenue Denver, CO 80211 Biochar Now, LLC Client Project # PROJ-007255 Analytical Report (0421-011) EPA Method 308 Methanol rri ENTHALPY Enthalpy Analytical, LLC Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com 800-1 Capitola Drive Durham, NC 27713-4385 G P043AS-007255-RT-644 125 of 381 I certify that to the best of my knowledge all analytical data presented in this report: • Have been checked for completeness • Are accurate, error -free, and legible • Have been conducted in accordance with approved protocol, and that all deviations and analytical problems are summarized in the appropriate narratives) This analytical report was prepared in Portable Document Format (.PDF) and contains ??? pages. Report Issued: xx/xx/xxxx IhAlinile F NTHALPY ANALYTICAL G P043AS-007255-RT-644 126 of 381 Summary of Results rroilipoppr9 F NTHALPY G P043AS-007255-RT-644 127 of 381 Enthalpy Analytical Company: Montrose Air Quality Services, LLC - Denver Job No.: 0421-011 - EPA Method 308 Client No.: PROJ-007255 Site: Biochar Now, LLC Summary Table Compound / Catch Weight (ug) Sample Train Name Methanol Kiln 65 Run 1 3.86 ND Kiln 65 Run 2 3.78 3.21 ND ND Kiln 65 Run 3 Kiln 56 Run 1 8.51 3.69 3.60 ND ND Kiln 56 Run 2 Kiln 56 Run 3 35.8 J Kiln 74 Run 1 Kiln 74 Run 2 3.78 1.45 ND ND Kiln 74 Run 3 0421-011 EPA Method 308 Results G P043AS-007255-RT-644 128 of 381 Results F NTHALPY G P043AS-007255-RT-644 129 of 381 Enthalpy Analytical Company: Montrose Air Quality Services, LLC - Denver Job No.: 0421-011 - EPA Method 308 Client No.: PROJ-007255 Site: Biochar Now, LLC Methanol Client's Sample Name Filename #1 Filename #2 MDL Curve Min Curve Max Time (min) Ret Time (min) Ret %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) %dif Conc Avg Conc (ug/mL) DF Liquid Vol (mL) Catch Weight (ug) Flag Kiln 65 Run 1.Cond 080B0401.D 080B0402.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 44.0 3.86 ND Kiln 65 Run 1.CTFH-B 013F0501.D 013F0502.D 0.158 1.58 144 NA NA NA 0.158 0.158 0.0 0.158 1 5.00 0.790 ND Kiln 65 Run 1.CTBH-B 021F1401.D 021F1402.D 0.158 1.58 144 NA NA NA 0.158 0.158 0.0 0.158 1 5.00 0.790 ND 3.86 ND Kiln 65 Run 2.Cond 081B0501.D 081B0502.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 43.0 3.78 ND Kiln 65 Run 2.CTFH-B 015F0701.D 015F0702.D 0.158 1.58 144 NA NA NA 0.158 0.158 0.0 0.158 1 5.00 0.790 ND Kiln 65 Run 2.CTBH-B 022F1501.D 022F1502.D 0.158 1.58 144 NA NA NA 0.158 0.158 0.0 0.158 1 5.00 0.790 ND 3.78 ND Kiln 65 Run 2 SPK.Cond 082B0601.D 082B0602.D 0.0878 1.05 1,582 3.29 3.28 0.1 2.68 2.71 0.5 2.69 1 42.5 115 Kiln 65 Run 2 SPK.SGFH 013B1601.D 013B1602.D 0.0878 1.05 1,582 NA NA NA 0.0878 . 0.0878 0.0 0.0878 1 5.00 0.439 ND Kiln 65 Run 2 SPK.SGBH 014B1701.D 014B1702.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 5.00 0.439 ND 115 Kiln 65 Run 3.Cond 083B0701.D 083B0702.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 36.5 3.21 ND Kiln 65 Run 3.CTFH-B 016F0801.D 016F0802.D 0.158 1.58 144 NA NA NA 0.158 0.158 0.0 0.158 1 5.00 0.790 ND Kiln 65 Run 3.CTBH-B 023F1601.D 023F1602.D 0.158 1.58 144 NA NA NA 0.158 0.158 0.0 0.158 1 5.00 0.790 ND 3.21 ND Kiln 56 Run 1.Cond 084B0801.D 084B0802.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 44.0 3.86 ND Kiln 56 Run 1.CTFH-B 017F0901.D 017F0902.D 0.158 1.58 144 NA NA NA 0.158 0.158 0.0 0.158 1 5.0 0.790 ND Kiln 56 Run 1.CTBH-T 041F1201.D 041 F1202.D 0.158 1.58 144 3.16 3.16 0.1 1.65 1.75 3.1 1.70 1 5.0 8.51 Kiln 56 Run 1.CTBH-B 024F1701.D 024F1702.D 0.158 1.58 144 NA NA NA 0.158 0.158 0.0 0.158 1 5.0 0.790 ND 8.51 0421-011 EPA Method 308 Results G P043AS-007255-RT-644 130 of 381 Enthalpy Analytical Company: Montrose Air Quality Services, LLC - Denver Job No.: 0421-011 - EPA Method 308 Client No.: PROJ-007255 Site: Biochar Now, LLC Methanol Client's Sample Name Filename #1 Filename #2 MDL Curve Min Curve Max Time (min) Ret Time (min) Ret %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) %dif Conc Avg Conc (ug/mL) DF Liquid Vol (mL) Catch Weight (ug) Flag Kiln 56 Run 2.Cond 085B0901.D 085B0902.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 42.0 3.69 ND Kiln 56 Run 2.CTFH-B 018F1001.D 018F1002.D 0.158 1.58 144 NA NA NA 0.158 0.158 0.0 0.158 1 5.00 0.790 ND Kiln 56 Run 2.CTBH-B 025F1801.D 025F1802.D 0.158 1.58 144 NA NA NA 0.158 0.158 0.0 0.158 1 5.00 0.790 ND 3.69 ND Kiln 56 Run 2 SPK.Cond 086B1001.D 086B1002.D 0.0878 1.05 1,582 3.28 3.29 0.0 1.76 1.73 0.7 1.74 1 44.0 76.7 Kiln 56 Run 2 SPK.SGFH 015B1801.D 015B1802.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 5.00 0.439 ND Kiln 56 Run 2 SPK.SGBH 016B1901.D 016B1902.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 5.00 0.439 ND 76.7 Kiln 56 Run 3.Cond 087B1101.D 087B1102.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 41.0 3.60 ND Kiln 56 Run 3.CTFH-B 019F1101.D 019F1102.D 0.158 1.58 144 NA NA NA 0.158 . 0.158 0.0 0.158 1 5.00 0.790 ND Kiln 56 Run 3.CTBH-B 026F1901.D 026F1902.D 0.158 1.58 144 NA NA NA 0.158 0.158 0.0 0.158 1 5.00 0.790 ND 3.60 ND Kiln 74 Run 1.Cond 088B1301.D 088B1302.D 0.0878 1.05 1,582 3.28 3.28 0.1 0.845 0.784 3.7 0.814 1 44.0 35.8 J Kiln 74 Run 1.SGFH 004B0601.D 004B0602.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 5.00 0.439 ND Kiln 74 Run 1.SGBH 005B0701.D 005B0702.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 5.00 0.439 ND 35.8 J Kiln 74 Run 1 SPK.Cond 089B1401.D 089B1402.D 0.0878 1.05 1,582 3.28 3.28 0.0 3.80 4.01 2.6 3.90 1 44.0 172 Kiln 74 Run 1 SPK.SGFH 010B1201.D 010B1202.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 5.00 0.439 ND Kiln 74 Run 1 SPK.SGBH 012B1501.D 012B1502.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 5.00 0.439 ND 172 0421-011 EPA Method 308 Results G P043AS-007255-RT-644 131 of 381 Enthalpy Analytical Company: Montrose Air Quality Services, LLC - Denver Job No.: 0421-011 - EPA Method 308 Client No.: PROJ-007255 Site: Biochar Now, LLC Methanol Client's Sample Name Filename #1 Filename #2 MDL Curve Min Curve Max Time (min) Ret Time (min) Ret %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) %dif Conc Avg Conc (ug/mL) DF Liquid Vol (mL) Catch Weight (ug) Flag Kiln 74 Run 2.Cond 091B1601.D 1601. D 091B1602.D 1602. D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 43.0 3.78 ND Kiln 74 Run 2.SGFH 006B0801.D 006B0802.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 5.00 0.439 ND Kiln 74 Run 2.SGBH 007B0901.D 007B0902.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 5.00 0.439 ND 3.78 ND Kiln 74 Run 3.Cond 092B1701.D 092B1702.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 16.5 1.45 ND Kiln 74 Run 3.SGFH 008B1001.D 008B1002.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 5.00 0.439 ND Kiln 74 Run 3.SGBH 009B1101.D 009B1102.D 0.0878 1.05 1,582 NA NA NA 0.0878 0.0878 0.0 0.0878 1 5.00 0.439 ND 1.45 ND 0421-011 EPA Method 308 Results G P043AS-007255-RT-644 132 of 381 Enthalpy Analytical Company: Montrose Air Quality Services, LLC - Denver Job No.: 0421-011 - EPA Method 308 Client No.: PROJ-007255 Site: Biochar Now, LLC QC Samples QC Type QC Sample Name Methanol Spiked Blank Solvent gcprep4043 #LCS-AQ spiked: spikeprep1422.SP * 250uL catch (ug) spike (ug) recovery 272 257 106% Spiked Blank Tube gcprep4043 #LCS-CT spiked: gcstds1449.SP * 25uL catch (ug) spike (ug) recovery 39.8 39.6 101% Spiked Blank Tube gcprep4043 #LCS-SG spiked: spikeprep1422.SP * 50uL catch (ug) spike (ug) recovery 52.4 51.4 102% Lab Dup LD / Kiln 65 Run 1.CTFH-B Kiln 65 Run 1.CTFH-B ug/mL ug/mL RD N D N D NA Lab Dup LD / Kiln 74 Run 1 SPK.Cond Kiln 74 Run 1 SPK.Cond ug/mL ug/mL RD 3.74 3.90 4.4% Lab Dup LD / Kiln 74 Run 1 SPK.SGFH Kiln 74 Run 1 SPK.SGFH ug/mL ug/mL RD N D N D NA Blank Solvent gcprep4043 #MB-AQ ug/mL N D Blank Media Blank Media gcprep4043 #MB -CT gcprep4043 #MB -SG ug/mL ug/mL N D 0.422 0421-011 EPA Method 308 Results G P043AS-007255-RT-644 133 of 381 Enthalpy Analytical Company: Montrose Air Quality Services, LLC - Denver Job No.: 0421-011 - EPA Method 308 Client No.: PROJ-007255 Site: Biochar Now, LLC Analyte Methanol Sample ID Kiln 65 Run 2 Type Sample Catch Weight (ug) 0.00 Kiln 65 Run 2 Spike Spike 115 Spike AMT (ug) 308 Sample Vol 48.570 Rec. (%) 48.592 I _ Sample ID Kiln 56 Run 2 Type Sample Catch Weight I Spike (ug) I AMT (ug) 0.00 Kiln 56 Run 2 Spike Spike 76.7 308 Sample Vol 48.578 37.1 Rec. (%) 48.592 Sample ID Kiln 74 Run 1 Type Sample Catch Weight (ug) 35.8 Kiln 74 Run 1 Spike Spike 172 Spike AMT (ug) 308 Sample Vol 49.606 24.9 Rec. (%) 51.228 43.7 0421-011 EPA Method 308 Results G P043AS-007255-RT-644 134 of 381 Narrative Summary rroilipoppr9 F NTHALPY G P043AS-007255-RT-644 135 of 381 Enthalpy Analytical Narrative Summary Montrose Air Quality Services, LLC - Denver Company Job # 0421-011 - EPA Method 308 (3 -fractions) Client # PROJ-007255 Site: Biochar Now, LLC Custody Alyssa Miller received the samples on 4/20/21 at 3.5 °C after being relinquished by Montrose Air Quality Services, LLC of Denver, CO. The samples were received in good condition. However, it was noted by the sample custodian, the client used charcoal tube media (rather than method recommended silica gel tube media) for some of the unspiked runs. It could not be determined during the sample login process which samples were affected, as the Sample ID labels were covering the tubes. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, LLC. Analysis The samples were analyzed for methanol using the analytical procedures in EPA Method 308, Procedure for Determination of Methanol Emission from Stationary Sources (40 CFR Part 63, Appendix A). The samples were analyzed following the procedures in Section 11.0 Analytical Procedures. For the Kiln 65 spiked runs, Kiln 56 spiked runs, and all Kiln 74 samples, each sample train consisted of an impinger followed by an SKC silica gel (Cat# 226-22) sample tube. For the Kiln 65 and Kiln 56 unspiked samples, each sample train consisted of an impinger followed by a SKC charcoal (Cat# 226-16) sample tube. All sample tubes were desorbed in two fractions: the front half (FH) and the back half (BH). All tube fractions were desorbed using 5 mL of deionized water, with the silica gel tubes being shaken twice at 450 rev/min for 60 minutes, and the charcoal tubes being shaken at 450 rev/min for 30 minutes. The tubes were desorbed on 4/22/21. The Gas Chromatographs ("Disco Stu" and "Mufasa") were used in these analyses, was equipped with a Flame Ionization Detector. Calibration The calibration curve is located in the Raw Data section of this report. F N 1 HALPY aN 'r'TICAI G P043AS-007255-RT-644 136 of 381 Enthalpy Analytical Narrative Summary (continued) Calibration (Continued) Chromatographic Conditions QC Notes r iop °A I ENTHALPY The first page of the calibration curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) used to quantify the samples. The calibration curve section also includes a table with the Retention Time (RetTime), Level (Lvl), Amount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Name. The calibration table is used to identify (by retention time) and quantify each target compound. A copy of the acquisition methods (DISCO_STU_P407.M AND MCTFASA016.M) may be available upon request. The analyses of the laboratory reagent blank (water) and charcoal tuve media blank did not contain methanol at concentrations greater than the MDL. Methanol was identified in the analysis of the silica gel tube blank at a concentration greater than the MDL, but below the LOQ. Laboratory Duplicate (LD) analyses were performed using samples Kiln65 Run 1. CTFH-B, Kiln 74 Run 1 Spike. Cond, and Kiln 74 Run 1 Spike.SGFH. The difference values were below 5%, when both the original and duplicate analyses were above the LOQ. Prior to sample collection, the laboratory prepared six aqueous spikes containing 257 µg of methanol, and six silica gel tube spikes containing 51.4µg of methanol. Four of each of the spikes were provided to the client. Two of each type of spike were retained by the lab to be used as Laboratory Control Samples (LCSs). The client provided air sampling volumes, which were used to determine the spike recovery value. These are based on the client having used one of the aqueous spikes and one of the tube spikes prepared for their specific location. None of the spiked trains met the Method's 70- 130% recovery criterion. EPA Method 308 results are not adjusted using the recovery values. One aqueous and one silica gel tube Laboratory Control Samples (LCS) were prepared and analyzed with the samples and exhibited recovery values of 106% and 102%, respectively. G P043AS-007255-RT-644 137 of 381 Enthalpy Analytical Narrative Summary (continued) QC Notes The laboratory also prepared one charcoal tube Laboratory Control Sample and analyzed it with the samples, exhibiting a recovery value of 101%. Reporting Notes These analyses met the requirements of the TNI Standard. Any deviations from the requirements of the reference method or TNI Standard have been previously noted in the report narrative. The results presented in this report are representative of the samples as provided to the laboratory. prispne is a 4,, ! ENTHALPY ANALYTICAL G P043AS-007255-RT-644 138 of 381 General Reporting Notes The following are general reporting notes that are applicable to all Enthalpy Analytical, LLC data reports, unless specifically noted otherwise. • Any analysis which refers to the method as "Type" represents a planned deviation from the reference method. For instance a Hydrogen Sulfide assay from a Tedlar bag would be labeled as "EPA Method 16 -Type" because Tedlar bags are not mentioned as one of the collection options in EPA Method 16. • The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot determine the presence of the analyte of interest reliably. • The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot quantitate the analyte of interest within the criteria of the method. • The acronym ND following a value indicates a non -detect or analytical result below the MDL. • The letter J in the Qualifier or Flag column in the results indicates that the value is between the MDL and the LOQ. The laboratory can positively identify the analyte of interest as present, but the value should be considered an estimate. • The letter E in the Qualifier or Flag column indicates an analytical result exceeding 100% of the highest calibration point. The associated value should be considered as an estimate. • Sample results are presented 'as measured' for single injection methodologies, or an average value if multiple injections are made. If all injections are below the MDL, the sample is considered non -detect and the ND value is presented. If one, but not all, are below the MDL, the MDL value is used for any injections that are below the MDL. For example, if the MDL is 0.500 and LOQ is 1.00, and the instrument measures 0.355, 0.620, and 0.442 - the result reported is the average of 0.500, 0.620, and 0.500 - - - i.e. 0.540 with a J flag. • When a spike recovery (Bag Spike, Collocated Spike Train, or liquid matrix spike) is being calculated, the native (unspiked) sample result is used in the calculations, as long as the value is above the MDL. If a sample is ND, then 0 is used as the native amount (not the MDL value). • The acronym DF represents Dilution Factor. This number represents dilution of the sample during the preparation and/or analysis process. The analytical result taken from a laboratory instrument is multiplied by the DF to determine the final undiluted sample results. • The addition of MS to the Sample ID represents a Matrix Spike. An aliquot of an actual sample is spiked with a known amount of analyte so that a percent recovery value can be determined. The MS analysis indicates what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample matrix interferes with the analysis of the analyte(s). r... e inst ea ENTHALPY A tV A LYT l C A L G P043AS-007255-RT-644 139 of 381 General Reporting Notes (continued) • The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same manner as a MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times. • The addition of LD to the Sample ID represents a Laboratory Duplicate. The analyst prepares an additional aliquot of sample for testing and the results of the duplicate analysis are compared to the initial result. The result should have a difference value of within 10% of the initial result (if the results of the original analysis are greater than the LOQ). • The addition of AD to the Sample ID represents an Alternate Dilution. The analyst prepares an additional aliquot at a different dilution factor (usually double the initial factor). This analysis helps confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of interest, as they would have a different response/absorbance than the analyte of interest. • The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample matrix, prepared and analyzed by the laboratory using the same reagents, spiking standards and procedures used for the client samples. The LCS is used to assess the control of the laboratory's analytical system. Whenever spikes are prepared for our client projects, two spikes are retained as LCSs. The LCSs are labeled with the associated project number and kept in-house at the appropriate temperature conditions. When the project samples are received for analysis, the LCSs are analyzed to confirm that the analyte could be recovered from the media, separate from the samples which were used on the project and which may have been affected by source matrix, sample collection, and/or sample transport. • Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed, the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits displayed, but no confidence should be placed on more than two significant digits. In the case of small numbers, generally 3 significant figures are presented, but still only 2 should be used with confidence. Many neat materials are only certified to 3 digits, and as the mathematically correct final result is always 1 digit less than all its pre -cursors - 2 significant figures are what are most defensible. • Manual Integration: The data systems used for processing will flag manually integrated peaks with an "M". There are several reasons a peak may be manually integrated. These reasons will be identified by the following two letter designations on sample chromatograms, if provided in the report. The peak was not integrated by the software "NI", the peak was integrated incorrectly by the software "H" or the wrong peak was integrated by the software "WP". These codes will accompany the analyst's manual integration stamp placed next to the compound name on the chromatogram. ENTHALPY A tV A LYT l C A L G P043AS-007255-RT-644 140 of 381 Sample Custody F NTHALPY G P043AS-007255-RT-644 141 of 381 Raw Data rroilipoppr9 F NTHALPY G P043AS-007255-RT-644 148 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0934 ver.4 001 B0101. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 11:21 AM 4/27/2021 8:21 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a, tt 50 40 30 20 10 0 O C 03 1 i 1 2 i 3 4 Time (min) 5 6 7 i 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol VV 3.28 43.9940 6.83359 42.6964 1 42.6964 pg/mL G P043AS-007255-RT-644 149 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0934 ver.4 001 B0102.D GC/2021 /Disco Stu/Quarter 2 4/23/2021 11:34 AM 4/27/2021 8:21 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 i i 1 2 i 3 4 Time (min) 5 6 I 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol VV 3.28 40.8768 6.44221 39.6375 1 39.6375 pg/mL G P043AS-007255-RT-644 150 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep4043 #MB-AQ DISCOSTU0934 ver.4 078B0201. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 11:47 AM 4/27/2021 8:21 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 78 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 I i I 1 2 7 3 4 Time (min) 5 6 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 151 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep4043 #MB-AQ DISCOSTU0934 ver.4 078 B0202. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 11:59 AM 4/27/2021 8:21 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 78 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 1 2 7 3 4 Time (min) 5 6 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 152 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep4043 #LCS-AQ DISCOSTU0934 ver.4 079B0301. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 12:25 PM 4/27/2021 8:22 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 79 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a, tt 50 40 30 20 10 0 O C ct a) 2 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol VB 3.28 28.0805 4.41682 27.0805 1 27.0805 pg/mL G P043AS-007255-RT-644 153 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep4043 #LCS-AQ DISCOSTU0934 ver.4 079 B0302. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 12:38 PM 4/27/2021 8:22 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 79 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a) 0 60 a a, 50 40 30 20 10 0 O C a) 2 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol VB 3.28 28.3107 4.40223 27.3065 1 27.3065 pg/mL G P043AS-007255-RT-644 154 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R1.COND DISCOSTU0934 ver.4 080B0401.D GC/2021 /Disco Stu/Quarter 2 4/23/2021 12:51 PM 4/27/2021 8:22 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 80 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 C Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 155 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R1.COND DISCOSTU0934 ver.4 080B0402.D GC/2021 /Disco Stu/Quarter 2 4/23/2021 1:03 PM 4/27/2021 8:22 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 80 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 I i I 1 2 7 3 4 Time (min) 5 6 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 156 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2.COND DISCOSTU0934 ver.4 081 B0501. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 1:16 PM 4/27/2021 8:22 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 81 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 I i I 1 2 7 3 4 Time (min) 5 6 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 157 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2.COND DISCOSTU0934 ver.4 081 B0502. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 1:29 PM 4/27/2021 8:23 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 81 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 I i I 1 2 7 3 4 Time (min) 5 6 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 158 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2-SPK. CON D DISCOSTU0934 ver.4 082B0601. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 1:42 PM 4/27/2021 8:23 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 82 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a, tt 50 40 30 20 10 0 O C CU C) 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol VB 3.29 3.21715 0.53851 2.68229 1 2.68229 pg/mL G P043AS-007255-RT-644 159 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2-SPK. CON D DISCOSTU0934 ver.4 082 B0602. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 1:55 PM 4/27/2021 8:23 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 82 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a, tt 50 40 30 20 10 O C CO a) 0 I 2 7 i 3 4 Time (min) I 5 6 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol VB 3.28 3.24289 0.53118 2.70754 1 2.70754 pg/mL G P043AS-007255-RT-644 160 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R3.COND DISCOSTU0934 ver.4 083B0701. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 2:07 PM 4/27/2021 8:23 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 83 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 161 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R3.COND DISCOSTU0934 ver.4 083 B0702. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 2:20 PM 4/27/2021 8:23 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 83 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 162 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R1.COND DISCOSTU0934 ver.4 084B0801.D GC/2021 /Disco Stu/Quarter 2 4/23/2021 2:33 PM 4/27/2021 8:24 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 84 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 163 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R1.COND DISCOSTU0934 ver.4 084B0802.D GC/2021 /Disco Stu/Quarter 2 4/23/2021 2:46 PM 4/27/2021 8:24 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 84 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 164 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2. CO N D DISCOSTU0934 ver.4 085B0901. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 2:59 PM 4/27/2021 8:24 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 85 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 1 2 7 3 4 Time (min) 5 6 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 165 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2. CO N D DISCOSTU0934 ver.4 085 B0902. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 3:11 PM 4/27/2021 8:24 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 85 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 - 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 166 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2-SPK. CON D DISCOSTU0934 ver.4 086B1001. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 3:24 PM 4/27/2021 8:25 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 86 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a, tt 50 40 30 20 10 0 O C co m 2 2 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol VB 3.28 2.27256 0.35912 1.75537 1 1.75537 pg/mL G P043AS-007255-RT-644 167 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2-SPK. CON D DISCOSTU0934 ver.4 086B1002.D 1002. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 3:37 PM 4/27/2021 8:25 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 86 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a, tt 50 40 30 20 10 0 2 O c co n a) 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol VB 3.29 2.24596 0.35626 1.72927 1 1.72927 pg/mL G P043AS-007255-RT-644 168 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R3. CO N D DISCOSTU0934 ver.4 087B1101.D GC/2021 /Disco Stu/Quarter 2 4/23/2021 3:50 PM 4/27/2021 8:25 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 87 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 169 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R3. CO N D DISCOSTU0934 ver.4 087B1102.D 1102. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 4:03 PM 4/27/2021 8:25 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 87 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 1 2 7 3 4 Time (min) 5 6 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 170 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0934 ver.4 001 B1201.D GC/2021 /Disco Stu/Quarter 2 4/23/2021 4:15 PM 4/27/2021 8:25 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 1 2 O CD r 0 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol VV 3.28 43.6858 6.71432 42.3939 1 42.3939 pg/mL G P043AS-007255-RT-644 171 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0934 ver.4 001B1202.D GC/2021 /Disco Stu/Quarter 2 4/23/2021 4:28 PM 4/27/2021 8:26 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 0 C c0 0 1 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol VV 3.28 43.8400 6.72052 42.5452 1 42.5452 pg/mL G P043AS-007255-RT-644 172 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R 1. CO N D DISCOSTU0934 ver.4 088B1301. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 4:41 PM 4/27/2021 8:26 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 88 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a) 0 60 a a, 50 40 30 20 10 0 O ct v 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol VB 3.28 1.24826 0.20256 0.84452 1 0.84452 pg/mL G P043AS-007255-RT-644 173 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R 1. CO N D DISCOSTU0934 ver.4 088B1302. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 4:54 PM 4/27/2021 8:26 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 88 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 O co I f-/ 10 n 0 2 3 4 Time (min) 5 6 7 8 C Compound Type RT Area Height Amount DF SampAmt Unit Methanol VB 3.28 1.15902 0.21685 0.78414 1 0.78414 pg/mL G P043AS-007255-RT-644 174 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R1-SPK.COND DISCOSTU0934 ver.4 089B1401. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 5:06 PM 4/27/2021 8:26 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 89 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a) 0 60 a a, 50 40 30 20 10 0 O C CO a) 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol VB 3.28 4.35590 0.74922 3.79974 1 3.79974 pg/mL G P043AS-007255-RT-644 175 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R1-SPK.COND DISCOSTU0934 ver.4 089B1402.D 1402. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 5:19 PM 4/27/2021 8:27 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 89 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a, tt 50 40 30 20 10 0 O c a, 4- aD 2 2 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol VB 3.28 4.56601 0.76903 4.00592 1 4.00592 pg/mL G P043AS-007255-RT-644 176 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R1-SPK-LD.COND DISCOSTU0934 ver.4 090B1501. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 5:32 PM 4/27/2021 8:27 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 90 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a) 0 60 a as 50 40 30 20 10 0 O C co a) 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol VB 3.29 4.29443 0.77638 3.73941 1 3.73941 pg/mL G P043AS-007255-RT-644 177 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R1-SPK-LD.COND DISCOSTU0934 ver.4 090B1502. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 5:45 PM 4/27/2021 8:27 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 90 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a, tt 50 40 30 20 10 0 O C co Z 2 2 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.28 4.28835 0.77562 3.73345 1 3.73345 pg/mL G P043AS-007255-RT-644 178 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R2 . CO N D DISCOSTU0934 ver.4 091 B1601.D GC/2021 /Disco Stu/Quarter 2 4/23/2021 5:58 PM 4/27/2021 8:27 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 91 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 179 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R2 . CO N D DISCOSTU0934 ver.4 091B1602.D GC/2021 /Disco Stu/Quarter 2 4/23/2021 6:10 PM 4/27/2021 8:28 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 91 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 180 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R3 . CO N D DISCOSTU0934 ver.4 092B1701.D 1701. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 6:23 PM 4/27/2021 8:28 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 92 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 C Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 181 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R3 . CO N D DISCOSTU0934 ver.4 092 B1702. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 6:36 PM 4/27/2021 8:28 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 92 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 C Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 182 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0934 ver.4 001B1801.D GC/2021 /Disco Stu/Quarter 2 4/23/2021 6:49 PM 4/27/2021 8:28 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a) tt 50 40 30 20 10 0 i 1 O C ca as 1\\J 2 i 3 4 Time (min) I 5 6 7 i 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol VV 3.28 43.3929 6.96154 42.1065 1 42.1065 pg/mL G P043AS-007255-RT-644 183 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0934 ver.4 001 B 1802. D GC/2021 /Disco Stu/Quarter 2 4/23/2021 7:01 PM 4/27/2021 8:28 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a) 0 60 a a, 50 40 30 20 10 0 O C c0 a) 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol VV 3.28 43.8227 6.99029 42.5282 1 42.5282 pg/mL G P043AS-007255-RT-644 184 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0934A ver.2 001 B0301. D GC/2021 /Disco Stu/Quarter 2 4/26/2021 2:41 PM 4/27/2021 8:05 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a, tt 50 40 30 20 10 0 O C c13 ct 2 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol VV 3.27 39.3656 6.49049 38.1545 1 38.1545 pg/mL L G P043AS-007255-RT-644 185 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0934A ver.2 001 B0302. D GC/2021 /Disco Stu/Quarter 2 4/26/2021 2:53 PM 4/27/2021 8:05 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a) 0 60 a a) 50 40 30 20 10 0 1 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol VV 3.28 41.2907 6.64643 40.0436 1 40.0436 pg/mL G P043AS-007255-RT-644 186 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep4043 #MB -SG DISCOSTU0934A ver.2 002B0401.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 3:06 PM 4/27/2021 8:06 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 2 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a) tt 50 40 30 20 10 0 O ccl as 2 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol BV 3.29 0.62796 0.12204 0.42485 1 0.42485 pg/mL G P043AS-007255-RT-644 187 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep4043 #MB -SG DISCOSTU0934A ver.2 002B0402.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 3:19 PM 4/27/2021 8:06 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 2 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a, tt 50 40 30 20 10 0 O C cu a) 2 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol BV 3.30 0.61978 0.12621 0.41932 1 0.41932 pg/mL G P043AS-007255-RT-644 188 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep4043 #LCS-SG DISCOSTU0934A ver.2 003B0501. D GC/2021 /Disco Stu/Quarter 2 4/26/2021 3:32 PM 4/27/2021 8:06 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 3 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a, tt 50 40 30 20 10 0 2 O 0 a) i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol VV 3.28 10.8599 1.84085 10.1820 1 10.1820 pg/mL G P043AS-007255-RT-644 189 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep4043 #LCS-SG DISCOSTU0934A ver.2 003 B0502. D GC/2021 /Disco Stu/Quarter 2 4/26/2021 3:45 PM 4/27/2021 8:06 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 3 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a, tt 50 40 30 20 10 0 O 0 a.) 2 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol BV 3.28 11.4744 1.94892 10.7851 1 10.7851 pg/mL G P043AS-007255-RT-644 190 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R1.SGFH DISCOSTU0934A ver.2 004B0601.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 3:57 PM 4/27/2021 8:07 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 4 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 191 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R1.SGFH DISCOSTU0934A ver.2 004 B0602 . D GC/2021 /Disco Stu/Quarter 2 4/26/2021 4:10 PM 4/27/2021 8:07 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 4 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 1 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 192 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R1.SGBH DISCOSTU0934A ver.2 005B0701. D GC/2021 /Disco Stu/Quarter 2 4/26/2021 4:23 PM 4/27/2021 8:07 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 5 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 193 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R1.SGBH DISCOSTU0934A ver.2 005 B0702. D GC/2021 /Disco Stu/Quarter 2 4/26/2021 4:36 PM 4/27/2021 8:07 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 5 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r—. 70 a) 0 60 a a, 50 40 30 20 10 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 194 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R2.SGFH DISCOSTU0934A ver.2 006B0801.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 4:49 PM 4/27/2021 8:07 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 6 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 195 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R2.SGFH DISCOSTU0934A ver.2 006B0802.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 5:01 PM 4/27/2021 8:08 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 6 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 196 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R2.SGBH DISCOSTU0934A ver.2 007B0901. D GC/2021 /Disco Stu/Quarter 2 4/26/2021 5:14 PM 4/27/2021 8:08 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 7 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 197 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R2.SGBH DISCOSTU0934A ver.2 007 B0902. D GC/2021 /Disco Stu/Quarter 2 4/26/2021 5:27 PM 4/27/2021 8:08 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 7 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 198 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R3.SGFH DISCOSTU0934A ver.2 008B1001. D GC/2021 /Disco Stu/Quarter 2 4/26/2021 5:40 PM 4/27/2021 8:08 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 8 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 I L I 1 I I 2 I 3 4 Time (min) I I 5 6 7 I 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 199 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R3.SGFH DISCOSTU0934A ver.2 008B1002.D 1002. D GC/2021 /Disco Stu/Quarter 2 4/26/2021 5:53 PM 4/27/2021 8:09 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 8 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 200 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R3.SGBH DISCOSTU0934A ver.2 009B1101.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 6:05 PM 4/27/2021 8:09 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 9 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 C Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 201 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R3.SGBH DISCOSTU0934A ver.2 009B1102.D 1102. D GC/2021 /Disco Stu/Quarter 2 4/26/2021 6:18 PM 4/27/2021 8:09 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 9 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 202 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R1-SPK.SGFH DISCOSTU0934A ver.2 010B1201.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 6:31 PM 4/27/2021 8:09 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 10 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 I i I 1 2 7 3 4 Time (min) 5 6 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 203 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R1-SPK.SGFH DISCOSTU0934A ver.2 010B1202.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 6:44 PM 4/27/2021 8:10 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 10 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 204 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R1-SPK-LD.SGFH DISCOSTU0934A ver.2 011B1301.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 6:57 PM 4/27/2021 8:10 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 11 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 205 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R1-SPK-LD.SGFH DISCOSTU0934A ver.2 011B1302.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 7:09 PM 4/27/2021 8:10 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 11 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 206 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0934A ver.2 001 B1402.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 7:35 PM 4/27/2021 8:10 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 2 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a) tt 50 40 30 20 10 0 1 2 J\ i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol BV 3.28 42.6820 6.88233 41.4089 1 41.4089 pg/mL G P043AS-007255-RT-644 207 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0934A ver.2 001 B1403.D D GC/2021 /Disco Stu/Quarter 2 4/26/2021 7:48 PM 4/27/2021 8:11 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 3 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 0_ a) C O a a, 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 0 C co r 0 2 Ij\N 1 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BV 3.28 41.5092 6.74753 40.2580 1 40.2580 pg/mL G P043AS-007255-RT-644 208 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R1-SPK.SGBH DISCOSTU0934A ver.2 012B1501.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 8:01 PM 4/27/2021 8:11 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 12 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 209 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.74-R1-SPK.SGBH DISCOSTU0934A ver.2 012B1502.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 8:14 PM 4/27/2021 8:11 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 12 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 C Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 210 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2-SPK.SGFH DISCOSTU0934A ver.2 013B1601.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 8:26 PM 4/27/2021 8:11 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 13 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 211 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2-SPK.SGFH DISCOSTU0934A ver.2 013B1602.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 8:39 PM 4/27/2021 8:12 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 13 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a) 0 60 a a, 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 212 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2-SPK.SGBH DISCOSTU0934A ver.2 014B1701.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 8:52 PM 4/27/2021 8:12 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 14 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 213 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2-SPK.SGBH DISCOSTU0934A ver.2 014B1702.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 9:05 PM 4/27/2021 8:12 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 14 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 214 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2-SPK.SGFH DISCOSTU0934A ver.2 015B1801.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 9:18 PM 4/27/2021 8:12 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 15 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 215 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2-SPK.SGFH DISCOSTU0934A ver.2 015B1802.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 9:30 PM 4/27/2021 8:13 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 15 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 216 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2-SPK.SGBH DISCOSTU0934A ver.2 016B1901.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 9:43 PM 4/27/2021 8:13 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 16 1 1 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 217 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2-SPK.SGBH DISCOSTU0934A ver.2 016B1902.D GC/2021 /Disco Stu/Quarter 2 4/26/2021 9:56 PM 4/27/2021 8:13 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 16 1 2 of 2 DISCO_STU_P407.M D I S C O STU 0889_RM 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 a° 0 60 a a, tt 50 40 30 20 10 0 2 i 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.26) 1 pg/mL G P043AS-007255-RT-644 218 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0934A ver.2 001 B2002. D GC/2021 /Disco Stu/Quarter 2 4/26/2021 10:22 PM 4/27/2021 8:13 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 2 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a, tt 50 40 30 20 10 0 i 1 2 O c 2 r C) i 3 4 Time (min) 5 6 7 i 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol BV 3.28 39.6239 6.51806 38.4080 1 38.4080 pg/mL G P043AS-007255-RT-644 219 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0934A ver.2 001 B2003. D GC/2021 /Disco Stu/Quarter 2 4/26/2021 10:34 PM 4/27/2021 8:14 AM DiscoStu Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 3 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 4/27/2021 7:42 AM 4/29/2021 7:20 AM 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 O C ct a) 2 1 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol VV 3.28 42.9011 6.66676 41.6239 1 41.6239 pg/mL G P043AS-007255-RT-644 220 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #3 M U FASA019A ver.3 010 F0102. D GC/2021/Mufasa/Quarter 2 4/26/2021 10:15 AM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 10 1 2 of 3 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a o c O a o Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 O Co Z.) 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 9.52375 5.63334 37.0702 1 37.0702 ug/mL L G P043AS-007255-RT-644 221 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #3 M U FASA019A ver.3 010 F0103. D GC/2021/Mufasa/Quarter 2 4/26/2021 10:28 AM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 10 1 3 of 3 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 120 110 100 90 80 70 60 50 40 30 20 10 0 FID1A O v 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 9.20048 5.52224 35.8040 1 35.8040 ug/mL L G P043AS-007255-RT-644 222 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep4043 #LCS-CT M U FASA019A ver.3 012F0401. D GC/2021/Mufasa/Quarter 2 4/26/2021 2:02 PM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 12 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 O c CO a) 2 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.17 2.11242 0.97945 8.04101 1 8.04101 ug/mL G P043AS-007255-RT-644 223 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep4043 #LCS-CT M U FASA019A ver.3 012F0402.D GC/2021/Mufasa/Quarter 2 4/26/2021 2:14 PM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 12 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 120 110 100 90 80 70 60 50 40 30 20 10 0 FID1A a C a) 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.17 2.07530 1.00102 7.89563 1 7.89563 ug/mL G P043AS-007255-RT-644 224 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R1.CTFH-B M U FASA019A ver.3 013F0501.D GC/2021/Mufasa/Quarter 2 4/26/2021 2:26 PM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 13 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 225 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R1.CTFH-B M U FASA019A ver.3 013F0502.D GC/2021/Mufasa/Quarter 2 4/26/2021 2:39 PM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 13 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 226 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R1-LD.CTFH-B M U FASA019A ver.3 014F0601.D GC/2021/Mufasa/Quarter 2 4/26/2021 2:51 PM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 14 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 i 3 4 Time (min) I 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 227 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R1-LD.CTFH-B M U FASA019A ver.3 014F0602.D GC/2021/Mufasa/Quarter 2 4/26/2021 3:04 PM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 14 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 120 110 100 90 80 70 60 50 40 30 20 10 0 FID1A 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 228 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2.CTFH-B M U FASA019A ver.3 015F0701. D GC/2021/Mufasa/Quarter 2 4/26/2021 3:16 PM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 15 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 229 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2.CTFH-B M U FASA019A ver.3 015F0702.D GC/2021/Mufasa/Quarter 2 4/26/2021 3:28 PM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 15 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 230 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R3.CTFH-B M U FASA019A ver.3 016F0801.D GC/2021/Mufasa/Quarter 2 4/26/2021 3:41 PM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 16 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 231 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R3.CTFH-B M U FASA019A ver.3 016F0802.D GC/2021/Mufasa/Quarter 2 4/26/2021 3:53 PM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 16 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 232 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R1.CTFH-B M U FASA019A ver.3 017F0901.D GC/2021/Mufasa/Quarter 2 4/26/2021 4:06 PM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 17 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 233 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R1.CTFH-B M U FASA019A ver.3 017F0902.D GC/2021/Mufasa/Quarter 2 4/26/2021 4:18 PM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 17 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 I i 3 4 Time (min) I 5 6 I 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 234 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2.CTFH-B M U FASA019A ver.3 018F1001.D GC/2021/Mufasa/Quarter 2 4/26/2021 4:30 PM 4/28/2021 9:32 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 18 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 235 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2.CTFH-B M U FASA019A ver.3 018F1002.D GC/2021/Mufasa/Quarter 2 4/26/2021 4:43 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 18 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 120 110 100 90 80 70 60 50 40 30 20 10 0 FID1A 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 236 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R3.CTFH-B M U FASA019A ver.3 019F1101.D GC/2021/Mufasa/Quarter 2 4/26/2021 4:55 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 19 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 120 110 100 90 80 70 60 50 40 30 20 10 0 FID1A 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 237 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R3.CTFH-B M U FASA019A ver.3 019F1102.D GC/2021/Mufasa/Quarter 2 4/26/2021 5:07 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 19 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 238 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep4043 #MB -CT M U FASA019A ver.3 011F1201.D GC/2021/Mufasa/Quarter 2 4/26/2021 5:20 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 11 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 L\UL _ 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 239 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep4043 #MB -CT M U FASA019A ver.3 011F1202.D GC/2021/Mufasa/Quarter 2 4/26/2021 5:32 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 11 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 jt. 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 240 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #3 M U FASA019A ver.3 020F1301. D GC/2021/Mufasa/Quarter 2 4/26/2021 5:45 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 20 1 1 of 3 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 120 110 100 90 80 70 60 50 40 30 20 10 0 FID1A O co a6 Pi 7 2 3 4 Time (min) 5 6 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 9.14903 5.39986 35.6025 1 35.6025 ug/mL L G P043AS-007255-RT-644 241 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #3 M U FASA019A ver.3 020F1302.D 1302. D GC/2021/Mufasa/Quarter 2 4/26/2021 5:57 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 20 1 2 of 3 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 O Ct -Cr) 2 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 9.04992 5.33795 35.2143 1 35.2143 ug/mL L G P043AS-007255-RT-644 242 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R1.CTBH-B M U FASA019A ver.3 021 F 1401. D GC/2021/Mufasa/Quarter 2 4/26/2021 6:22 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 21 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 243 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R1.CTBH-B M U FASA019A ver.3 021 F1402.D D GC/2021/Mufasa/Quarter 2 4/26/2021 6:34 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 21 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 244 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2.CTBH-B M U FASA019A ver.3 022F1501. D GC/2021/Mufasa/Quarter 2 4/26/2021 6:47 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 22 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 l. 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 245 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2.CTBH-B M U FASA019A ver.3 022F1502.D 1502. D GC/2021/Mufasa/Quarter 2 4/26/2021 6:59 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 22 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 A 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 246 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R3.CTBH-B M U FASA019A ver.3 023F1601.D GC/2021/Mufasa/Quarter 2 4/26/2021 7:12 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 23 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 247 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R3.CTBH-B M U FASA019A ver.3 023F1602.D GC/2021/Mufasa/Quarter 2 4/26/2021 7:24 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 23 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 248 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R1.CTBH-B M U FASA019A ver.3 024F1701.D 1701. D GC/2021/Mufasa/Quarter 2 4/26/2021 7:36 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 24 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 249 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R1.CTBH-B M U FASA019A ver.3 024 F1702. D GC/2021/Mufasa/Quarter 2 4/26/2021 7:49 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 24 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 120 110 100 90 80 70 60 50 40 30 20 10 0 FID1A 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 250 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2.CTBH-B M U FASA019A ver.3 025F1801. D GC/2021/Mufasa/Quarter 2 4/26/2021 8:01 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 25 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 251 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2.CTBH-B M U FASA019A ver.3 025F1802.D 1802. D GC/2021/Mufasa/Quarter 2 4/26/2021 8:14 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 25 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 I'1 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 252 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R3.CTBH-B M U FASA019A ver.3 026F1901. D GC/2021/Mufasa/Quarter 2 4/26/2021 8:26 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 26 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 h 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 253 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R3.CTBH-B M U FASA019A ver.3 026F1902.D 1902. D GC/2021/Mufasa/Quarter 2 4/26/2021 8:38 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 26 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 G P043AS-007255-RT-644 254 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #2 M U FASA019A ver.3 028F2201. D GC/2021/Mufasa/Quarter 2 4/26/2021 9:53 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 28 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a o c O a a, Et 130 120 110 100 90 80 70 60 50 40 30 20 10 0 FID1A O c co I. au 2 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 1.14709 0.66119 4.25997 1 4.25997 ug/mL G P043AS-007255-RT-644 255 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #2 M U FASA019A ver.3 028 F2202. D GC/2021/Mufasa/Quarter 2 4/26/2021 10:05 PM 4/28/2021 9:33 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 28 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/27/2021 11:18 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 O c co a) 2 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 1.15362 0.63869 4.28552 1 4.28552 ug/mL G P043AS-007255-RT-644 256 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #2 MUFASA019B ver.3 031 F0102.D GC/2021/Mufasa/Quarter 2 4/27/2021 12:01 PM 4/28/2021 10:11 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 31 1 2 of 3 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 120 110 100 90 80 70 60 50 40 30 20 10 0 FID1A O c 03 a) 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 1.16490 0.67281 4.32970 1 4.32970 ug/mL G P043AS-007255-RT-644 257 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #2 MUFASA019B ver.3 031 F0103.D GC/2021/Mufasa/Quarter 2 4/27/2021 12:14 PM 4/28/2021 10:11 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 31 1 3 of 3 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 O c co a6 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol MM 3.16 1.16337 0.64046 4.32374 1 4.32374 ug/mL G P043AS-007255-RT-644 258 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2.CTFH-T MUFASA019B ver.3 033F0401. D GC/2021/Mufasa/Quarter 2 4/27/2021 2:02 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 33 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 120 110 100 90 80 70 60 50 40 30 20 10 0 FID1A c. 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 259 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2.CTFH-T MUFASA019B ver.3 033 F0402. D GC/2021/Mufasa/Quarter 2 4/27/2021 2:14 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 33 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 260 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R3.CTFH-T MUFASA019B ver.3 034F0501. D GC/2021/Mufasa/Quarter 2 4/27/2021 2:27 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 34 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 261 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R3.CTFH-T MUFASA019B ver.3 034 F0502. D GC/2021/Mufasa/Quarter 2 4/27/2021 2:39 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 34 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 262 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2.CTFH-T MUFASA019B ver.3 036F0701. D GC/2021/Mufasa/Quarter 2 4/27/2021 3:17 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 36 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 263 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2.CTFH-T MUFASA019B ver.3 036 F0702. D GC/2021/Mufasa/Quarter 2 4/27/2021 3:29 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 36 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 264 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R3.CTFH-T MUFASA019B ver.3 037F0801. D GC/2021/Mufasa/Quarter 2 4/27/2021 3:41 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 37 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 120 110 100 90 80 70 60 50 40 30 20 10 0 FID1A I 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 265 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R3.CTFH-T MUFASA019B ver.3 037 F0802. D GC/2021/Mufasa/Quarter 2 4/27/2021 3:54 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 37 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 120 110 100 90 80 70 60 50 40 30 20 10 0 FID1A 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 266 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R1.CTBH-T MUFASA019B ver.3 038F0901.D GC/2021/Mufasa/Quarter 2 4/27/2021 4:06 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 38 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 I ITV 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 267 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R1.CTBH-T MUFASA019B ver.3 038F0902.D GC/2021/Mufasa/Quarter 2 4/27/2021 4:19 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 38 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 120 110 100 90 80 70 60 50 40 30 20 10 0 FID1A 7 2 3 4 Time (min) 5 6 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 268 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2.CTBH-T MUFASA019B ver.3 039F1001.D GC/2021/Mufasa/Quarter 2 4/27/2021 4:31 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 39 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 269 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R2.CTBH-T MUFASA019B ver.3 039F1002.D GC/2021/Mufasa/Quarter 2 4/27/2021 4:44 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 39 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 270 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R3.CTBH-T MUFASA019B ver.3 040F1101.D GC/2021/Mufasa/Quarter 2 4/27/2021 4:56 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 40 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 f 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 271 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R3.CTBH-T MUFASA019B ver.3 040F1102.D GC/2021/Mufasa/Quarter 2 4/27/2021 5:08 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 40 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 272 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R1.CTBH-T MUFASA019B ver.3 041 F1201.D GC/2021/Mufasa/Quarter 2 4/27/2021 5:21 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 41 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM a o c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 O c co a) 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 0.48056 0.20497 1.64925 1 1.64925 ug/mL G P043AS-007255-RT-644 273 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R1.CTBH-T MUFASA019B ver.3 041 F1202.D D GC/2021/Mufasa/Quarter 2 4/27/2021 5:33 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 41 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 0.50732 0.22105 1.75407 1 1.75407 ug/mL G P043AS-007255-RT-644 274 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #2 MUFASA019B ver.3 042F1302.D 1302. D GC/2021/Mufasa/Quarter 2 4/27/2021 5:58 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 42 1 2 of 3 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM a o c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 O C co 15 2 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.15 1.23861 0.68339 4.61843 1 4.61843 ug/mL G P043AS-007255-RT-644 275 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #2 MUFASA019B ver.3 042F1303.D 1303. D GC/2021/Mufasa/Quarter 2 4/27/2021 6:11 PM 4/28/2021 10:12 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 42 1 3 of 3 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 O C Cu a) 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.15 1.19450 0.63180 4.44566 1 4.44566 ug/mL G P043AS-007255-RT-644 276 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2.CTBH-T MUFASA019B ver.3 043F1401.D 1401. D GC/2021/Mufasa/Quarter 2 4/27/2021 6:23 PM 4/28/2021 10:13 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 43 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 277 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R2.CTBH-T MUFASA019B ver.3 043F1402.D 1402. D GC/2021/Mufasa/Quarter 2 4/27/2021 6:35 PM 4/28/2021 10:13 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 43 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 J 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 278 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R3.CTBH-T MUFASA019B ver.3 044F1501.D GC/2021/Mufasa/Quarter 2 4/27/2021 6:48 PM 4/28/2021 10:13 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 44 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 279 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R3.CTBH-T MUFASA019B ver.3 044F1502.D 1502. D GC/2021/Mufasa/Quarter 2 4/27/2021 7:00 PM 4/28/2021 10:13 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 44 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 III 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 280 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R1.CTFH-T MUFASA019B ver.3 032F1601. D GC/2021/Mufasa/Quarter 2 4/27/2021 7:13 PM 4/28/2021 10:13 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 32 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 281 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.65-R1.CTFH-T MUFASA019B ver.3 032F1602.D 1602. D GC/2021/Mufasa/Quarter 2 4/27/2021 7:25 PM 4/28/2021 10:13 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 32 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol (3.17) 1 ug/mL G P043AS-007255-RT-644 282 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R1.CTFH-T MUFASA019B ver.3 035F1701. D GC/2021/Mufasa/Quarter 2 4/27/2021 7:38 PM 4/28/2021 10:13 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 35 1 1 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 O c co r 111 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 1.18791 0.37516 4.41986 1 4.41986 ug/mL G P043AS-007255-RT-644 283 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0421-011.56-R1.CTFH-T MUFASA019B ver.3 035F1702.D 1702. D GC/2021/Mufasa/Quarter 2 4/27/2021 7:50 PM 4/28/2021 10:13 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample 35 1 2 of 2 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 O C ca 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 1.22301 0.38602 4.55734 1 4.55734 ug/mL G P043AS-007255-RT-644 284 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #2 MUFASA019B ver.3 042F1802.D 1802. D GC/2021/Mufasa/Quarter 2 4/27/2021 8:15 PM 4/28/2021 10:13 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 42 1 2 of 3 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM a a) c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 O E CO s II) 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.15 1.26796 0.75504 4.73341 1 4.73341 ug/mL G P043AS-007255-RT-644 285 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #2 MUFASA019B ver.3 042F1803.D 1803. D GC/2021/Mufasa/Quarter 2 4/27/2021 8:27 PM 4/28/2021 10:13 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 42 1 3 of 3 M U FASA016 . M MUFASA019_F.M 4/28/2021 7:59 AM 4/29/2021 7:20 AM a o c O a a, Et 130 FID1A 120 110 100 90 80 70 60 50 40 30 20 10 0 0 c ct 0 2 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.15 1.25722 0.70747 4.69132 1 4.69132 ug/mL G P043AS-007255-RT-644 286 of 381 Method C:\GC\2021\DISCOSTU\METHODS\DISCOSTU0889 R M308.M Calibration Table Calib. Data Modified : Rel. Reference Window Abs. Reference Window Rel. Non -ref. Window Abs. Non -ref. Window Uncalibrated Peaks Partial Calibration Correct All Ret. Times: Curve Type Origin Weight • . • . • . • . • . • . • . • . • • Recalibration Settings: Average Response Average Retention Time: • . Friday, February 05, 2021 9:08:39 AM 2.000 % 0.050 min 2.000 % 0.050 min not reported Yes, identified peaks are recalibrated No, only for identified peaks Linear Connected Quadratic (Amnt) Average all calibrations Floating Average New 75% Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket) Signal 1: FID1 A, Signal 2: FID2 B, RetTime Lvl Amount [rain] 3.264 3.551 Sig [pg/mL] 2 2 1.05386 3 4.73133 4 38.58151 5 263.64030 6 451.95480 7 1581.84180 2 2 1.05025 3 4.71512 4 38.44932 5 262.73700 6 450.40629 7 1576.42200 I ***No Entries in table*** Area 1.57259 5.00628 39.44340 279.13210 463.85904 1634.98885 1.48277 7.02488 55.21298 392.95119 652.34867 I Amt/Area Ref Grp Name 6.70141e-1 9.45079e-1 9.78149e-1 9.44500e-1 9.74337e-1 9.67494e-1 7.08302e-1 6.71203e-1 6.96382e-1 6.68625e-1 6.90438e-1 2321.82690 6.78958e-1 Peak Sum Table I ---I --I Methanol Ethanol DiscoStu 2/5P2R943A5-4Q7L2'�o' Boyer 287 of 381 Page 1 of 2 Method C:\GC\2021\DISCOSTU\METHODS\DISCOSTU0889 R M308.M Calibration Curves Area = 1600 - 1400 - 1200 - 1000 - 800 - 600 - 400 - 200 - 0- i I z 7 1000 Amount[µg/mL] Area — 2000 - 1500 - _ - j 1000- 6/ 500 - 0J� 0 5 7 7 i 1000 Amount[µg/mL] Methanol at exp. RT: 3.264 FID2 B, Correlation: 0.99936 Residual Std. Dev.: 12.39313 Formula: y = mx + b m: 1.01906 b: 4.83728e-1 x: Amount y: Area Calibration Level Weights: L evel 2 •1 L evel 3 •0.049613 L evel 4 •0.000746 L evel 5 •0.000016 L evel 6 : 5.43719e-006 L evel 7 : 4.43852e-007 Ethanol at exp. RT: 3.551 FID2 B, Correlation: 0.99983 Residual Std. Dev.: 6.37309 Formula: y = mx + b m: 1.46997 b: -5.45787e-2 x: Amount y: Area Calibration Level Weights: L evel 2 •1 L evel 3 : 0.049613 L evel 4 : 0.000746 L evel 5 : 0.000016 L evel 6 : 5.43719e-006 L evel 7 : 4.43852e-007 DiscoStu 2/5P2R943A5-4Q7L2'Eco-' Boyer 288 of 381 Page 2 of 2 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #7 DISCOSTU0889 ver.4 026B0101.D GC/2021 /Disco Stu/Quarter 1 2/3/2021 1:59 PM 2/5/2021 9:32 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 26 1 1 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 O C Ct 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.25 3.54 1686.24 2404.24 321.727 489.233 1654.22 1635.61 1 1654.22 pg/mL 1 1635.61 pg/mL G P043AS-007255-RT-644 289 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #7 DISCOSTU0889 ver.4 026 B0102 . D GC/2021 /Disco Stu/Quarter 1 2/3/2021 2:12 PM 2/5/2021 9:32 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 26 1 2 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM a a) c O a a) Et 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 O C g III 2 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.25 3.54 1589.62 2255.02 316.717 470.307 1559.41 1534.10 1 1559.41 pg/mL L 1 1534.10 pg/mL G P043AS-007255-RT-644 290 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #7 DISCOSTU0889 ver.4 026 B0103. D GC/2021 /Disco Stu/Quarter 1 2/3/2021 2:25 PM 2/5/2021 9:33 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 26 1 3 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 8 2 3 4 Time (min) 5 6 7 Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.25 3.54 1629.11 2306.23 328.411 483.127 1598.16 1568.93 1 1598.16 pg/mL 1 1568.93 pg/mL G P043AS-007255-RT-644 291 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #6 DISCOSTU0889 ver.4 027B0201. D GC/2021 /Disco Stu/Quarter 1 2/3/2021 2:38 PM 2/5/2021 9:33 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 27 1 1 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM a o c O a a, Et 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 O c co v 2 2 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.25 3.54 457.021 641.849 94.1373 135.540 447.997 436.678 1 447.997 pg/mL 1 436.678 pg/mL G P043AS-007255-RT-644 292 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #6 DISCOSTU0889 ver.4 027 B0202. D GC/2021 /Disco Stu/Quarter 1 2/3/2021 2:51 PM 2/5/2021 9:33 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 27 1 2 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 ti 0 Ct 0 2 8 2 3 4 Time (min) 5 6 7 Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.26 476.998 3.55 671.592 92.2973 137.186 467.600 456.912 1 467.600 pg/mL 1 456.912 pg/mL L G P043AS-007255-RT-644 293 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #6 DISCOSTU0889 ver.4 027 B0203. D GC/2021 /Disco Stu/Quarter 1 2/3/2021 3:04 PM 2/5/2021 9:33 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 27 1 3 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 O c0 445 N 8 1 2 3 4 Time (min) 5 6 7 Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.25 3.54 457.558 643.605 90.4473 133.930 448.524 437.873 1 448.524 pg/mL 1 437.873 pg/mL G P043AS-007255-RT-644 294 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #5 DISCOSTU0889 ver.4 028B0301. D GC/2021 /Disco Stu/Quarter 1 2/3/2021 3:17 PM 2/5/2021 9:33 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 28 1 1 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 O c co 0 O C co U I 8 2 3 4 Time (min) 5 6 7 Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.26 291.098 3.54 410.120 58.0962 84.8244 285.178 279.036 1 285.178 pg/mL 1 279.036 pg/mL G P043AS-007255-RT-644 295 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #5 DISCOSTU0889 ver.4 028 B0302. D GC/2021 /Disco Stu/Quarter 1 2/3/2021 3:31 PM 2/5/2021 9:33 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 28 1 2 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 0 c (CC a) J 1 2 O c CZ w 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.25 3.54 272.019 382.705 55.9425 81.1699 266.456 260.386 1 266.456 pg/mL 1 260.386 pg/mL G P043AS-007255-RT-644 296 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #5 DISCOSTU0889 ver.4 028 B0303. D GC/2021 /Disco Stu/Quarter 1 2/3/2021 3:44 PM 2/5/2021 9:34 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 28 1 3 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM a a) C O a a, 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 0 C cU 4J U 0 C a) 2 1 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.25 3.54 274.279 386.028 56.1102 81.5459 268.674 262.647 1 268.674 pg/mL 1 262.647 pg/mL G P043AS-007255-RT-644 297 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0889 ver.4 029B0401. D GC/2021 /Disco Stu/Quarter 1 2/3/2021 3:57 PM 2/5/2021 9:34 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 29 1 1 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 O O C co co _ _C w 1 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.26 3.55 39.6977 55.5926 8.23483 11.6535 38.4804 37.8560 1 38.4804 pg/mL 1 37.8560 pg/mL G P043AS-007255-RT-644 298 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0889 ver.4 029 B0402. D GC/2021 /Disco Stu/Quarter 1 2/3/2021 4:10 PM 2/5/2021 9:34 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 29 1 2 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM 130 FID2B 120 110 100 90 80 r—. 70 a) 0 60 a a) 50 40 30 20 10 0 0 C c0 r a) 1 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.26 3.55 38.6105 53.9878 7.58350 11.2256 37.4135 36.7643 1 37.4135 pg/mL 1 36.7643 pg/mL G P043AS-007255-RT-644 299 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #4 DISCOSTU0889 ver.4 029 B0403. D GC/2021 /Disco Stu/Quarter 1 2/3/2021 4:23 PM 2/5/2021 9:34 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 29 1 3 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a) tt 50 40 30 20 10 0 C co I. C) 2 0 C Co 4-0 I\ 0 i 1 2 i 3 4 Time (min) 5 6 7 i 8 C Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.26 40.0220 3.55 56.0586 7.86269 11.5768 38.7986 38.1730 1 38.7986 pg/mL 1 38.1730 pg/mL G P043AS-007255-RT-644 300 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #3 DISCOSTU0889 ver.4 030B1301.D 1301. D GC/2021 /Disco Stu/Quarter 1 2/4/2021 2:41 PM 2/5/2021 9:38 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 30 1 1 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a) tt 50 40 30 20 10 0 O C O CO C _C co a31 2 w i 1 2 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BB BB 3.26 3.55 5.03186 6.97063 0.99951 1.46290 4.46305 4.77915 1 4.46305 pg/mL 1 4.77915 pg/mL G P043AS-007255-RT-644 301 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #3 DISCOSTU0889 ver.4 030B1302.D 1302. D GC/2021 /Disco Stu/Quarter 1 2/4/2021 2:54 PM 2/5/2021 9:38 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 30 1 2 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a) tt 50 40 30 20 10 0 O C O co c r (6 135 2 w i 1 2 I 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BB BB 3.26 4.91056 3.55 7.01339 0.97798 1.46741 4.34402 4.80824 1 4.34402 pg/mL 1 4.80824 pg/mL G P043AS-007255-RT-644 302 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #3 DISCOSTU0889 ver.4 030B1303.D 1303. D GC/2021 /Disco Stu/Quarter 1 2/4/2021 3:07 PM 2/5/2021 9:39 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 30 1 3 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM 130 FID2B 120 110 100 90 80 r-. 70 0° 0 60 a a, tt 50 40 30 20 10 0 O C co 6 O C Co n i 1 2 i 3 4 Time (min) 5 6 7 i 8 C Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BB BB 3.26 3.55 5.07643 7.09063 0.99178 1.46728 4.50679 4.86079 1 4.50679 pg/mL 1 4.86079 pg/mL G P043AS-007255-RT-644 303 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #2 DISCOSTU0889 ver.4 031 B1002.D D GC/2021 /Disco Stu/Quarter 1 2/4/2021 10:40 AM 2/5/2021 9:37 AM DiscoStu Brooke Boyer Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 31 1 2 of 4 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM a a) c O a a, Et 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 0 c 0 co c - co 2 n w 2 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BB BB 3.26 3.55 1.53080 1.45554 0.32877 0.30881 1.03568 1.02647 1 1.03568 pg/mL 1 1.02647 pg/mL G P043AS-007255-RT-644 304 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #2 DISCOSTU0889 ver.4 031 B1003.D D GC/2021 /Disco Stu/Quarter 1 2/4/2021 10:54 AM 2/5/2021 9:37 AM DiscoStu Brooke Boyer Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 31 1 3 of 4 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM a a) c O a o Et 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 O c o co c - ca 46 -c 2 w 2 3 4 Time (min) 5 6 7 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol MM 3.26 BB 3.55 1.59288 1.49406 0.34604 0.32287 1.08840 1.05352 1 1.08840 pg/mL 1 1.05352 pg/mL G P043AS-007255-RT-644 305 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #2 DISCOSTU0889 ver.4 031 B1004.D GC/2021 /Disco Stu/Quarter 1 2/4/2021 11:07 AM 2/5/2021 9:37 AM DiscoStu Brooke Boyer Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 31 1 4 of DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM a a) c O a a, Et 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 O C O alc co I)) -c 2 w 2 3 4 Time (min) 5 6 7 8 C Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BB BB 3.27 3.55 1.59409 1.49871 0.33340 0.29759 1.08959 1.05668 1 1.08959 pg/mL 1 1.05668 pg/mL G P043AS-007255-RT-644 306 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #3ss DISCOSTU0889 ver.4 032B0701. D GC/2021 /Disco Stu/Quarter 1 2/3/2021 5:54 PM 2/5/2021 9:35 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Control 32 1 1 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 1 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.26 3.55 76.1142 108.471 14.6408 21.9206 74.2157 73.8283 1 74.2157 pg/mL 1 73.8283 pg/mL G P043AS-007255-RT-644 307 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #3ss DISCOSTU0889 ver.4 032 B0702. D GC/2021 /Disco Stu/Quarter 1 2/3/2021 6:07 PM 2/5/2021 9:36 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Control 32 1 2 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM a a) c O a a, Et 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 i 1 2 0 C al w 1 i 3 4 Time (min) 5 6 I 7 i 8 c Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.26 3.55 78.4281 111.076 15.6651 23.2116 76.4863 75.6007 1 76.4863 pg/mL 1 75.6007 pg/mL G P043AS-007255-RT-644 308 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1333 #3ss DISCOSTU0889 ver.4 032 B0703. D GC/2021 /Disco Stu/Quarter 1 2/3/2021 6:20 PM 2/5/2021 9:36 AM DiscoStu Tara Hostetler Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Control 32 1 3 of 3 DISCO_STU_P407.M D I S C O STU 0889_R_M 308. M 2/5/2021 9:14 AM 2/5/2021 10:04 AM 0_ a) c O a a, 130 FID2B 120 110 100 90 80 70 60 50 40 30 20 10 0 0 c w 1 1 2 3 4 Time (min) 5 6 7 8 Compound Type RT Area Height Amount DF SampAmt Unit Methanol Ethanol BV VB 3.26 3.55 78.4828 111.528 15.0999 22.6334 76.5400 75.9079 1 76.5400 pg/mL 1 75.9079 pg/mL G P043AS-007255-RT-644 309 of 381 Method C:\GC\2021\MUFASA\METHODS\MUFASA019 F.M Calibration Table Calib. Data Modified : Rel. Reference Window : Abs. Reference Window : Rel. Non -ref. Window : Abs. Non -ref. Window : Uncalibrated Peaks : Partial Calibration : Correct All Ret. Times: Curve Type O rigin W eight • . • . • • Recalibration Settings: Average Response : Average Retention Time: Thursday, April 22, 2021 2:38:01 PM 1.000 0.100 min 0.500 0.100 min not reported Yes, identified peaks are recalibrated No, only for identified peaks Linear Connected Quadratic (Amnt ) Average all calibrations Floating Average New 75% Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket) Signal 1: FID1 A, Front Signal RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ ug/mL ] I I 3.168 1 1 1.58042 4.59630e-1 3.43846 2 4.73181 1.29506 3.65374 3 38.58500 10.19840 3.78344 4 143.81800 35.17355 4.08881 * -kN o Entries in table*** Peak Sum Table Calibration Curves Area 35 30 25 20 15 10 5 0 2 1, 0 50 100 Amount[ug/mL] 150 Methanol Methanol at exp. RT: 3.168 FID1 A, Front Signal Correlation: 0.99926 Residual Std. Dev.: 1.15218 Formula: y = mx + b m: 2.55306e-1 b: 5.94971e-2 x: Amount y: Area Calibration Level Weichts: J L evel 1 : 1 L evel 2 : 0.111556 L evel 3 : 0.001678 L evel 4 : 0.000121 Mufasa 4/23/ Q4aM7N7 *5R13 1 a4c4i r o 310 of 381 Page 1 of 1 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #4 M U FASA016 ver.3 004F0201.D GC/2021/Mufasa/Quarter 2 4/22/2021 12:08 PM 4/23/2021 9:25 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 4 1 1 of 3 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 22 20 18 16 14 12 10 8 6 FID1A 4a-, i��1.U..w1hm.V'�•�Y11�-wah..a-'l4l^^'V'w•Yla...y�nn-Mw/-..4e+J�._ +iJ.y.�u�...s-� ,"��F•�d�r�.a-•-.-.w+l✓�wM1+-n.v-Sa+,.^.rv�.^uwa..M�...r...M.Ky�...�..��_ x...n.+--w.J^rr.w..✓`^-••..�..•..—.-.v _ 2 3 Time (min) Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 35.2768 21.7585 137.941 1 137.941 ug/mL G P043AS-007255-RT-644 311 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #4 M U FASA016 ver.3 004F0202.D GC/2021/Mufasa/Quarter 2 4/22/2021 12:20 PM 4/23/2021 9:25 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 4 1 2 of 3 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 22 20 18 16 14 12 10 8 6 FID1A 1 4 `\Ai`""-`r--1-..n.,t-....n-rL..U..-.1�.M•....•,./.�M.,..n..s.....-_-._.,....-.,�.....•J— 3 Time (min) Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 35.1369 21.7276 137.394 1 137.394 ug/mL L G P043AS-007255-RT-644 312 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #4 M U FASA016 ver.3 004F0203.D GC/2021/Mufasa/Quarter 2 4/22/2021 12:33 PM 4/23/2021 9:25 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 4 1 3 of 3 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 22 20 18 16 14 12 10 8 6 FID1A 2 3 Time (min) Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 35.1070 21.3747 137.276 1 137.276 ug/mL G P043AS-007255-RT-644 313 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #3 M U FASA016 ver.3 003F0301.D GC/2021/Mufasa/Quarter 2 4/22/2021 12:45 PM 4/23/2021 9:25 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 3 1 1 of 3 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 22 20 18 16 14 12 10 8 6 FID1A O C co U) 2 , 3 Time (min) Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 10.3145 6.26943 40.1676 1 40.1676 ug/mL G P043AS-007255-RT-644 314 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #3 M U FASA016 ver.3 003F0302.D GC/2021/Mufasa/Quarter 2 4/22/2021 12:57 PM 4/23/2021 9:25 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 3 1 2 of 3 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 22 20 18 16 14 12 10 8 6 FID1A 45L�w..._-{.U�,�vw•..41+n-q..��N-.w..�..•tw��.•-..+A....M. �M� O C co n) 2 3 Time (min) Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 10.0775 6.12186 39.2393 1 39.2393 ug/mL G P043AS-007255-RT-644 315 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #3 M U FASA016 ver.3 003F0303.D GC/2021/Mufasa/Quarter 2 4/22/2021 1:10 PM 4/23/2021 9:25 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 3 1 3 of 3 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 22 20 18 16 14 12 10 8 6 FID1A 2 O C Co a) i N 3 Time (min) Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 10.2032 6.14334 39.7314 1 39.7314 ug/mL G P043AS-007255-RT-644 316 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #2 M U FASA016 ver.3 002F0401.D GC/2021/Mufasa/Quarter 2 4/22/2021 1:22 PM 4/23/2021 9:25 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 2 1 1 of 3 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 22 20 18 16 14 12 10 8 6 FID1A 71 2 O C CD aD 7 �,,.. .�'-�...v.�J�w,/��.\^.IJ�M��v'J`^-V-.J..�....1�....N.��.�`-I�r^^•4`ry�yµ� i�+.+4.�r�M`.YV�. '� F"M✓.'nNr_.S'.`AfN../�/ti^/'^./✓�Ir- % r+�-� 3 Time (min) 4 5 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 1.28576 0.73923 4.80310 1 4.80310 ug/mL G P043AS-007255-RT-644 317 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #2 M U FASA016 ver.3 002F0402.D GC/2021/Mufasa/Quarter 2 4/22/2021 1:35 PM 4/23/2021 9:25 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 2 1 2 of 3 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 22 20 18 16 14 12 10 8 6 FID1A 2 0 C Ct 0 3 Time (min) Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 1.32380 0.78412 4.95212 1 4.95212 ug/mL G P043AS-007255-RT-644 318 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #2 M U FASA016 ver.3 002F0403.D GC/2021/Mufasa/Quarter 2 4/22/2021 1:47 PM 4/23/2021 9:25 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 2 1 3 of 3 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 22 20 18 16 14 12 10 8 6 FID1A O C Ct a) 2 'yWvr�,.,�rV•..wvnil�w^-- ��_....v.�..�, = L -I.... �....�--1��`_,.-.-.-✓...-.J.w-.��.-ir.�v.•.�.+.w..._.��..��^'�`�v.i--..V- �r�-.ice..,.,_ wy...��.w�- rvd.i.��.Ati... 3 Time (min) Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 1.27561 0.71834 4.76336 1 4.76336 ug/mL G P043AS-007255-RT-644 319 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #1 M U FASA016 ver.3 001 F0501. D GC/2021/Mufasa/Quarter 2 4/22/2021 1:59 PM 4/23/2021 9:25 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 1 of 8 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 0_ a) c O a o 22 20 18 16 14 12 10 8 6 FID1A O C co a) elm"ul�^'....Zvi.-i�,..`.r`a.....✓.—...ti.,n� ,.t,..,.r.. _r -.:..r'.:..-.,+...v+�t.r�...�-i.-_1.....`n+....i �1wnM+a..`.'..q--.-.hM^r•.A-.r4+^,!-v-`J•.-"'•"•"'^ i..n.v...w�.-.wl/�.�'4�Nv`^'�'Yrti"^ 3 Time (min) Compound Type RT Area Height Amount DF SampAmt Unit Methanol MM 3.16 0.45890 0.28461 1.56646 1 1.56646 ug/mL G P043AS-007255-RT-644 320 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #1 M U FASA016 ver.3 001 F0502. D GC/2021/Mufasa/Quarter 2 4/22/2021 2:12 PM 4/23/2021 9:25 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 2 of 8 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 22 20 18 16 14 12 10 8 6 FID1A O C cU a) 2 2 3 Time (min) Compound Type RT Area Height Amount DF SampAmt Unit Methanol MM 3.16 0.45647 0.25459 1.55817 1 1.55817 ug/mL G P043AS-007255-RT-644 321 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #1 M U FASA016 ver.3 001 F0503. D GC/2021/Mufasa/Quarter 2 4/22/2021 2:24 PM 4/23/2021 9:25 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration 1 1 3 of 8 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 22 20 18 16 14 12 10 8 6 FID1A -.•r'r..�.. t-^.�.✓'tip^.+-•Jt..-..-v..��.�.��.Jnh�iV'r-�.N�-w�-�Nv�.--\_�^•-at��_-J O c 4- a) 2 'Vv��y�h'hi^��e-�M1nw-W-✓+4+'V4...h-.W-in��.�..M...n��iw�.�vw�.4/.`t�!/J+w-�J4ir.+•+�'"...I`� 4 - ��w. .v/-.......•�.-.�J�y,..w�.—`= J'----'`.�-.-^�'M.-.ef...^vv.•-„' r'•...�^/+�Mti�--err-.h..-.�. ... 2 3 Time (min) Compound Type RT Area Height Amount DF SampAmt Unit Methanol MM 3.17 0.46352 0.26612 1.58252 1 1.58252 ug/mL G P043AS-007255-RT-644 322 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #3ss M U FASA016 ver.3 006F0601.D GC/2021/Mufasa/Quarter 2 4/22/2021 4:00 PM 4/23/2021 9:26 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Control 6 1 1 of 3 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 22 20 18 16 14 12 10 8 6 FID1A tiq =—Methano � . { • , y^.M�.� o-u..-Nl..ah/.its-/..n-J:--..�h'w.•�-L..�w�. Lv+.-{..nw+�wir.1✓.._..-�i......-..�w—vYw.-.-.,y�...'n+.wl�.Y-+vl��.ly-iw•.+1.1 2 3 Time (min) Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 5.13001 2.95606 19.8605 1 19.8605 ug/mL L G P043AS-007255-RT-644 323 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #3ss M U FASA016 ver.3 006F0602.D GC/2021/Mufasa/Quarter 2 4/22/2021 4:13 PM 4/23/2021 9:26 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Control 6 1 2 of 3 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 22 20 18 16 14 12 10 8 6 FID1A 14 hnontml.-Vbilvv•IP,rt or. Mi tioi al I,. Methano .1.•.r,_.^'AINf✓iNN,,J,A, (- 1••�1�(',f•.i�(}4;n,ttA-::iiJ;a,1.w;.:;k.�...:.t^tr(i{1,:'lri!•.t�,/.a.....i`F:..1.Y�-nrwt.�J'It''Wf1F"1n..w.•..A•✓•(.vM^�M/Ilvl•Yf-�,IUItW.N��,isdL'i,^.,.^LnL../J.1.1:(.hl.)1N'r4AYV(Yiy..1M�1/1�GJ�'l+1'FIiY�M/"�M1'h��,n. 1 2 3 Time (min) 5 Compound Type RT Area Height Amount DF SampAmt Unit Methanol BV 3.16 5.33743 3.07689 20.6730 1 20.6730 ug/mL L G P043AS-007255-RT-644 324 of 381 Chromatogram Report Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds 1449 #3ss M U FASA016 ver.3 006F0603.D GC/2021/Mufasa/Quarter 2 4/22/2021 4:25 PM 4/23/2021 9:26 AM Mufasa Kim Maturo Enthalpy Analytical Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Control 6 1 3 of 3 M U FASA016 . M MUFASA019_F.M 4/23/2021 9:19 AM 4/23/2021 10:12 AM 22 20 18 16 14 12 10 8 6 FID1A ^1TD'U�t'1}r5 i "w%}, ✓1:1j�...:Aeb.1 :.if "YyLsv�}LaIrL.1r �qhJ: AM.K/:Jyly; \,47i_r+.,.;!�•r„,.f O C CO s 4- ry +fY\•°161kAA.IJIS(' 1 J r' /•.! 41/... Y}G 1.: Li'•,`n,4r�•1 ,\ ., MJ�r.in..A..y..I _r. 4... r r..Jlt,: 1 tTJ Jr .rL n / r�tJ.l.�-.v/4YV�w . Nnr•'iJ�J"1rw•.�INI. 1 �' T ` l�' l 1 1 1 r } r r'r� (rr�l•d.t.1� } �e,.,nw� xtn vr4k�llw.vn� J .--t-•.�+'y�✓'n^'qtr-rl�.e.�...,.•w��•✓�w'.�.N .A^r+y^+�Jdn...-• :4rn^�a+r- n-1�'N 1 / •�v".+{ 2 3 Time (min) Compound Type RT Area Height Amount DF SampAmt Unit Methanol BB 3.16 5.11520 2.99624 19.8025 1 19.8025 ug/mL L G P043AS-007255-RT-644 325 of 381 This Is The Last Page Of This Report. F NTHALPY G P043AS-007255-RT-644 326 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report APPENDIX D QUALITY ASSURANCE/QUALITY CONTROL G P043AS-007255-RT-644 327 of 381 4,/\, ONTRO E wI AIR QUALIFY tiERvIEFS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix D.1 Units and Abbreviations G P043AS-007255-RT-644 328 of 381 1 MONTROSE I AIR QUALIFY tiERvIEFS roMONTROSE AIR QUALITY SERVICES UNITS AND ABBREVIATIONS @X%O2 ICC' Idl °C °F °R „ H2O 13.6 AH AP e p9 Pa Pw acfm An As Btu Bws Ca CAvg CDir cf or ft3 cfm CGas CM cm or m3 CMA Co Cp Cs CS Cs Cv D dcf dcm Dn Ds dscf dscfm dscm Fd fpm fps ft ft2 g gal gr corrected to X% oxygen (corrected for dilution air) absolute value of the confidence coefficient absolute value of the mean differences degrees Celsius (centrigade) degrees Fahrenheit degrees Rankine inches of water column specific gravity of mercury pressure drop across orifice meter, inches H2O velocity head of stack gas, inches H2O total sampling time, minutes microgram density of acetone, mg/ml density of water, 0.9982 g/ml or 0.002201 lb/ml actual cubic feet of gas per minute at stack conditions cross-sectional area of nozzle, ft2 cross-sectional area of stack, square feet (ft2) British thermal unit proportion by volume of water vapor in gas stream particulate matter concentration in stack gas, gr/acf average unadjusted gas concentration, ppmv measured concentration of calibration gas, ppmv cubic feet cubic feet per minute average gas concentration adjusted for bias, ppmv average of initial and final system bias check responses from upscale calibration gas, cubic meters actual concentration of the upscale calibration gas, ppmv average of initial and final system bias check responses from low-level calibration gas, ppmv pitot tube coefficient particulate matter concentration in stack gas, gr/dscf calibration span, % or ppmv measured concentration of calibration gas, ppmv manufactured certified concentration of calibration gas, ppmv drift assessment, % of span dry cubic feet dry cubic meters diameter of nozzle, inches diameter of stack, inches dry standard cubic feet dry standard cubic feet per minute dry standard cubic meters F -factor, dscf/MMBtu of heat input feet per minute feet per second feet square feet gram gallons grains (7000 grains per pound) ppmv G P043AS-007255-RT-644 329 of 381 MONTROSE AIR QUALITY SERVICES UNITS AND ABBREVIATIONS gr/dscf hr I in k K K3 K4 kg Kp kwscfh I lb/hr lb/MMBtu 'pm m M m3 ma Md meq mg Mg min ml or mL mm MM MMBtu/hr mn moI mol. wt. or MW MS MW n ng nm Pbar Pg Pg Pm ppb ppbv ppbvd ppm ppmv ppmvd PS psi psia psig Pstd Qa grains per dry standard cubic feet hour percent of isokinetic sampling inch kilo or thousand (metric units, multiply by 103) kelvin (temperature) conversion factor 0.0154 gr/mg conversion factor 0.002669 ((in. Hg)(ft3))/((ml)(°R)) kilogram pitot tube constant (85.49 ft/sec) thousand wet standard cubic feet per hour liters pounds per hour pounds per million Btu liters per minute meter or milli thousand (English units) or mega (million, metric units) cubic meters mass of residue of acetone after evaporation, mg molecular weight of stack gas; dry basis, lb/lb-mole milliequivalent milligram megagram (106 grams) minute milliliter millimeter million (English units) million Btu per hour total amount of particulate matter collected, mg mole molecular weight molecular weight of stack gas; wet basis, lb/lb-mole molecular weight or megawatt number of data points nanogram nanometer barometric pressure, inches Hg picogram stack static pressure, inches H2O barometric pressure of dry gas meter, inches Hg parts per billion parts per billion, by volume parts per billion by volume, dry basis parts per million parts per million, by volume parts per million by volume, dry basis absolute stack gas pressure, inches Hg pounds per square inch pounds per square inch absolute pounds per square inch gauge standard absolute pressure, 29.92 inches Hg volumetric flow rate, actual conditions, acfm G P043AS-007255-RT-644 330 of 381 MONTROSE AIR QUALITY SERVICES UNITS AND ABBREVIATIONS Qs Qstd R SBfinal SBi scf scfh scfm scm scmh sec sf, sq. ft., or ft2 std t T 0.975 Ta Tm ton or tph or tons/hr tpy or tons/yr TS Tstd V Va Vaw Vic Vm Vm(std) Vma vn vs Vwc(std) Vwi(std) Vwsg(std) w Wa Wimp Wsg Y volumetric flow rate, standard conditions, scfm volumetric flow rate, dry standard conditions, dscfm ideal gas constant 21.85 ((in. Hg) (ft3))/((°R) (Ibmole)) post -run system bias check, % of span pre -run system bias check, % of span standard cubic feet standard cubic feet per hour standard cubic feet per minute standard cubic meters standard cubic meters per hour second square feet standard metric ton (1000 kg) t -value absolute average ambient temperature, °R (+460 for English) absolute average dry gas meter temperature, °R (+460 for English) ton = 2000 pounds tons per hour tons per year absolute average stack gas meter temperature, °R (+460 for English) absolute temperature at standard conditions volt volume of acetone blank, ml volume of acetone used in wash, ml total volume H2O collected in impingers and silica gel, grams volume of gas sampled through dry gas meter, ft3 volume of gas measured by the dry gas meter, corrected to standard conditions, dscf stack gas volume sampled, acf volume collected at stack conditions through nozzle, acf average stack gas velocity, feet per second volume of water vapor condensed, corrected to standard conditions, scf volume of water vapor in gas sampled from impingers, scf volume of water vapor in gas sampled from silica gel, scf watt weight of residue in acetone wash, mg total weight of impingers, grams total weight of silica gel, grams dry gas meter calibration factor, dimensionless G P043AS-007255-RT-644 331 of 381 MONTROSE AIR QUALITY SERVICES ACRONYMS AAS ACDP ACE AD ADL AETB AS ASTM BACT BDL BHP BIF BLS CC CD CE CEM CEMS CERMS CET CFR CGA CHNOS CNCG CO COC COMS CPM CPMS CT CTM CTO CVAAS De DE Dioxins DLL DNCG ECD EIT ELCD EMPC EPA EPRI ES ESP EU FCCU FGD Fl FIA FID FPD FPM atomic absorption spectroscopy air contaminant discharge permit analyzer calibration error, percent of span absolute difference above detection limit Air Emissions Testing Body applicable standard (emission limit) American Society For Testing And Materials best achievable control technology below detection limit brake horsepower boiler and industrial furnace black liquor solids confidence coefficient calibration drift calibration error continuous emissions monitor continuous emissions monitoring system continuous emissions rate monitoring system calibration error test Code of Federal Regulations cylinder gas audit elemental analysis for determination of C, H, N, O, and S content in fuels concentrated non -condensable gas catalytic oxidizer chain of custody continuous opacity monitoring system condensible particulate matter continuous parameter monitoring system combustion turbine conditional test method catalytic thermal oxidizer cold vapor atomic absorption spectroscopy equivalent diameter destruction efficiency polychlorinated dibenzo-p-dioxins (pcdd's) detection level limited dilute non -condensable gas electron capture detector Engineer In Training electoconductivity detector (hall detector) estimated maximum possible concentration US Environmental Protection Agency Electric Power Research Institute emission standard (applicable limit) electrostatic precipitator emission unit fluid catalytic cracking unit flue gas desulfurization flame ionization flame ionization analyzer flame ionization detector flame photometric detector filterable particulate matter G P043AS-007255-RT-644 332 of 381 MONTRO S E n AIR QUALITY SERVICES ACRONYMS FTIR FTPB FTRB Furans GC GC/MS GFAAS GFC GHG HAP HC HHV HPLC HRGC/HRMS HRSG IC ICAP ICPCR IR ISO kW LFG LHV LPG MACT MDI MDL MNOC MRL MS NA NCASI I NCG N DIR N ESHAP N G N IOSH N IST N MC N MOC N MVOC N PD NSPS OSHA PAH PCB PCW P PE P FAS P I P ID PM PM10 PM2.5 Fourier -transform infrared spectroscopy field train proof blank field train recovery blank polychlorinated dibenzofurans (pcdfs) gas chromatography gas chromatography/mass spectroscopy graphite furnace atomic absorption spectroscopy gas filter correlation greenhouse gas hazardous air pollutant hydrocarbons higher heating value high performance liquid chromatography high -resolution gas chromatography/high-resolution mass spectroscopy heat recovery steam generator ion chromatography inductively -coupled argon plasmography ion chromatography with a post -column reactor infrared radiation International Standards Organization kilowatts landfill gas lower heating value liquified petroleum gas maximum achievable control technology methylene diphyenyl diisocyanate method detection limit maximum normal operating conditions method reporting limit mass spectrometry not applicable or not available N ational Council For Air And Steam Improvement non -condensable gases non -dispersive infrared N ational Emissions Standards For Hazardous Air Pollutants natural gas N ational Institute For Occupational Safety And Health N ational Institute Of Standards And Technology non -methane cutter non -methane organic compounds non -methane volatile organic compounds nitrogen phosphorus detector N ew Source Performance Standards Occupational Safety And Health Administration polycyclic aromatic hydrocarbons polychlorinated biphenyl compounds plywood and composite wood products N rofessional Engineer per- and polyfluoroalkyl substances (PFAS) photoionization photoionization detector particulate matter particulate matter less than 10 microns in aerodynamic diameter particulate matter less than 2.5 microns in aerodynamic diameter G P043AS-007255-RT-644 333 of 381 MONTRO S E n AIR QUALITY SERVICES ACRONYMS POM PS PSD PSEL PST PTE PTM QA/QC QI QSTI RA RAA RACT RATA RCTO RICE RM RTO SAM SCD SCR SD Semi-VOST SRM TAP TBD TCA TCD TGNENMOC TGNMOC TGOC THC TIC TO TO TPM TSP TTE ULSD UV VE VOC VOST WC WWTP polycyclic organic matter performance specification particle size distribution plant site emission limits performance specification test permanent total enclosure performance test method quality assurance and quality control Qualified Individual Qualified Source Testing Individual relative accuracy relative accuracy audit reasonably available control technology relative accuracy test audit rotary concentrator thermal oxidizer stationary reciprocating internal combustion engine reference method regenerative thermal oxidizer sulfuric acid mist sulfur chemiluminescent detector selective catalytic reduction system standard deviation semivolatile organic compounds sample train standard reference material toxic air pollutant to be determined thermal conductivity analyzer thermal conductivity detector total gaseous non -ethane non -methane organic compounds total gaseous non -methane organic compounds total gaseous organic compounds total hydrocarbons tentatively identified compound thermal oxidizer toxic organic (as in EPA Method TO -15) total particulate matter total suspended particulate matter temporary total enclosure ultra -low sulfur diesel ultraviolet radiation range visible emissions volatile organic compounds volatile organic sample train water column waste water treatment plant G P043AS-007255-RT-644 334 of 381 40 MONTROSE AIR QUALITY SERVICES CHEMICAL NOMENCLATURE Ag As Ba Be C Cd CdS CH2O CH3CHO CH3OH CH4 C2H40 02H6 03H40 C3H60 03H8 C6H5OH 012 002 CO Co CO2 Cr Cu EtO Et0H H2 H2O H202 H2S H2SO4 HCI Hg IPA MDI MEK Me0H Mn N2 N H3 N i N O N O2 N O), 02 P Pb PCDD PCDF Sb Se silver arsenic barium beryllium carbon cadmium cadmium sulfide formaldehyde acetaldehyde methanol methane ethylene oxide ethane acrolein propionaldehyde propane phenol chlorine chlorine dioxide carbon monoxide cobalt carbon dioxide chromium copper ethylene oxide ethyl alcohol (ethanol) hydrogen water hydrogen peroxide hydrogen sulfide sulfuric acid hydrogen chloride mercury isopropyl alcohol methylene diphyenyl diisocyanate methyl ethyl ketone methanol manganese nitrogen ammonia nickel nitric oxide nitrogen dioxide nitrogen oxides oxygen phosphorus lead polychlorinated dibenzo-p-dioxins polychlorinated dibenzofurans antimony selenium SO2 SO3 SOX TODD TCDF TGOC THC TI TRS Zn sulfur dioxide sulfur trioxide sulfur oxides tetrachlorodibenzodioxin benzodioxi n tetrachlorodibenzofuran total gaseous organic concentration total hydrocarbons thallium total reduced sulfur compounds zinc G P043AS-007255-RT-644 335 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix D.2 Manual Test Method QA/QC Data G P043AS-007255-RT-644 336 of 381 1 MONTROSE yr I AIR QUALIFY tiERvIEFS ML %. Calibration (ilit ' k I 1: I_ r T i�► , Date: E Pitot 1: 1 October 28, 2020 Performed Tube Calibration by: Data Sheet David Smith Expiration Date: April 28, 2021 ID No.: No obstructions: No Calibrated Pitot Tube: S -type Probe/Pitot ID No: 043MAQS5-4-1 3 No damage: No Probe Description: Self Supporting Probe (SP) Effective Length (ft): 4 Level and Perpendicular: Yes Thermocouple calibration performed? Yes Thermocouple passed calibration? Yes Protractor or Digital Angle Finder ID: 043AS-REF-PRO-3 Calibration performed using the procedures of EPA Method 2, Section 10.1 Measuring Tape ID: 043AS-REF-RUL-3 Caliper ID: 043AS-REF-CPR-3 Alignment and Tubing Dimensions y a, (-10°<a1< +10°) 2.0 al 4+!It C.C77 a, (-10°<a-< +10°) 1.0 :') , I+ 1 2.0 [3, (-5°<[3,<+5°) (32 (-5° <(32_<+5°) 2.0 y 0.5 Degree indicating level position for determining a, and a,. I 0 0.5 _ P' '`'` A 0.7320 LA z= A tan 0.125") 0.0064 Pass y (± R A tan 0 0.03125") 0.0064 Pass w= (± Dt < Dt < 0.375") (0.1875" 0.2540 Pass _ _-_ =- -�"0 ____" - PA (1.05Dt < PA < 1.5D3 0.3800 Pass I PB (1.05Dt < PB < 1.5Dt) 0.3520 Pass Degree indicating level position for determining 0. I PA - PB I c 0.0625 0.0280 Pass [V I , , A PA A -- A B B 1 PB , , Degree indicating level position for determining y then calculating Assembly Inter -Component W≥ 3.0 in. Z. Spacing Requirements t W (≥ 3.0") NA Offset TC only Z ≥0.75 in. AA 2.0") 2.000 Setback TC -or- (≥ only tS i D X 0.449 A x D„ 0.251 - Y i - D X / Dn (≥ 1.5) 1.791 Pass Y n LL___u Y (≥ 3.0") 4.250 Pass Z ≥ 0.75" NA Pass Offset TC only AA≥ 2.0 in. { S otA CD S o; CD I x 0 IDn Y≥3.0in. , w` Performed By: David Smith Signature: Date: 10.28.2020 Approved By: Signature: Date: Pitot Tube Measurement Calibration Sheet Revision: 2 Created: 3/16/15 by IE Last revised: 5/17/17 by IE G P043AS-007255-RT-644 337 of 381 Pressure Standard: Heise #05-R Pressure Standard: Heise #06-L Pressure Standard: Heise #07-L Pressure Standard: Heise #07-R Pressure Standard: Heise #08-L Pressure Standard: Heise #09-L Pressure Standard: Heise #09-R Pressure Standard: Heise #10-L Customer ID: t AIRDATA MULTIMETER CERTIFICATE OF RECALIBRATION aZ.y Customer: mow - 5E Al42 i I1.4-,-__,� Vire SIN: / . �,�..,� City: �� State: CO�. As -Received Model #: Converted to Model #: PO #: Customer #• ��01-ig/ Eqpt ID#: Calibration Due Date: This instrument has been calibrated using Calibration Standards which are traceable to NISI (National institute of Standards and Technology). is 4:1 for pressures and temperature. Quality Assurance Program and calibration procedures meet the requirements for ANSI/NCS 40-1,IOT17025, accuracyMIL ratio 45662A and manufacturer's specifications. Calibration accuracy is certified when meters areL 2540-1, ISO MIL -STD expressed in expanded terms (twice the calculated uncertainty). This report shall not be reseoduced properly functioning accessories only. All Uncertainties are Instruments, Inc. Results relate only to the item calibrated. For limitations reproduced, except in full, without the written approval of Shortridge tons on use, see Shortridge Instruments, Inc. Instruction Manual far the use of AirData Multimeters. Procedure used: Procedure for Differential Pressure, Absolute Pressure and Temperature Recalibration of Revision: 30 Dated: 04/04/16 AirData Multimeters SIP-CPOZ Calibration Technician(s): -1/14 1-41134)-4 Calibration Approved by: AS -Received By ?'ti - hip cb.knei Date d W44 .pY t Rh 31 % Ambient Temperature —7 3 °F Barometric Pressure --d.k g _ 5a in Hg All within spec ES) NO NA TEST METER TOLERANCE = ± 2.0 % ± .1 in Hg AS-RECE Pressure Standard: Heise #02-R S/N: 41741/424 est z I est Pressure Standard: Heise #04-R SIN: 41743/42453 As -Revd Test 2 Test 3 Pressure Standard: Heise #06-R S/N: 41742/42452-1 As -Revd ai Test 3 Pressure Standard: Heise #08-R S/N: 42186/43328 As-Rcvd Test 2 Test 3 Pressure Standard: Heise #10-R S/N: 42203/43352 As -Revd Test 2 Test 3 Approx Set Pt Standard Test Meter 14.0 28.4 40.0 a , Lf- D. r % Diff 50 TEST METER TOLERANCE = ± 2.0 % ± 0 001 Pressure Standard: Heise #01-L S/N: 41739/42449 Pressure Standard: Heise #01-R S/N: 41739/42446 Pressure Standard: Heise #02-L S/N: 41741/42454 Pressure Standard: Heise #03A -L S/N: 45570/48461 Pressure Standard: Heise #03A -R S/N: 45570/48460 Pressure Standard: Heise #04-L S/N: 41743/42456 Pressure Standard: Heise #05-L S/N: 41740/42450 S/N: 41740/42447 S/N: 41742/42455 S/N: 42185/42186 S/N: 42185/43326 S/N: 42186/43329 S/N: 42202/43351 S/N: 42202/43350 SIN: 42203/43353 Approx Set Pt Standard Test Meter . 0500 . 1250 .2250 1.000 2.000 3.600 4.400 27.00 50.00 Overange ias� 3a5c1 I oc�I 0ILE- CiL, 3oS • l�T:3R -ed.,0 tf-23- NA �r ¶5 0 ia�a :953 ..� f' L o 00 5 .,c goo _ - OS Standard Title: Mat_ Test By : G . . Dateo,7a1/4,Qr2.1 Rh 2 % Ambient Temperature °F Barometric Pressure g.-7404 in Hg All within spec NO ABSOLUTE PRESSURE TEST (in Hg) IVED TEST WITHIN SPEC � Et--) NO N/A See Notes Pressure Standard: Heise #12A -R S/N: 45605/48491 6 --Revd,) Test 2 Test 3 Pressure Standard: Heise #14-R _ S/N: 43412/45043 2 As-Rcvd Test 2 Test 3 Pressure Standard: Heise #16-R S/N: 43413/45044 As -Revd Test 2 Test 3 Pressure Standard: Heise #18-R S/N: 44581/46845 As -Revd Test 2 Test 3 Pressure Standard: Heise #20-R S/N: 44582/46847 As -Revd Test 2 Test 3 Calibration Date: 3/0/ a42/ et E Date: oil o f z a Z/ Test By Da WA Rh Ambient Temp ratu e Barometric Pressure in Hg All within spec YES NO °F Test Meter % Diff fl/ 00 /3 "77/ 228 7O fie), 00 37J23 T35 DIFFERENTIAL PRESSURE TEST (in we) in we AS -RECEIVED TEST WITHIN SPEC As -Revd Test 2 Test 3 As-Rcvd Test 2 Test 3 As -Revd Test 2 Test 3 As -Revd Test 2 Test 3 As-Rcvd Test 2 Test 3 As-Rcvd Test 2 Test 3 As-RevdcresTDTest 3 As -Revd est crest 3 As -Revd est Test 3 As-Rcvd Test 2 Test 3 As -Revd Test 2 Test 3 As -Revd Test 2 Test 3 As-Rcvd Test 2 Test 3 As-Rcvd Test 2 Test 3 As -Revd Test 2 Test 3 750 Standard Test Meter % Diff IsJA %Diff 0 c:5 1+% eX-7 4-O Pressure Standard: Heise #11-L Pressure Standard: Heise #11-R Pressure Standard: Heise #12A -L Pressure Standard: Heise #13-L Pressure Standard: Heise #13-R Pressure Standard: Heise #14-L Pressure Standard: Heise #15-L Pressure Standard: Heise #15-R Pressure Standard: Heise #16-L Pressure Standard: Heise #17-L Pressure Standard: Heise #17-R Pressure Standard: Heise #18-L Pressure Standard: Heise #19-L Pressure Standard: Heise #19-R Pressure Standard: Heise #20-L Standard _ Test Meter % Diff er I 'asp z912- /-007 Zzeoc? , 1+ 3;6/3 30 /714 NA 2574' ~f 02-7/4 oso9 NA £2V b997 3, 605- 1741 P7o9 4� 9- 9 -73/ 730 �3c -736 t oc _2 7 f NA Shortridge Instruments, Inc. 7855 East Redfield -Road Scottsdale, Arizona 85260 (480) 991-6744 • Fax (480) 443-1267 • www.shortridge.com NO N/A See Notes S/N: 43165/44551-1 mss- cv' Test 2 Test 3 S/N: 43165/44730 s=Rcv Test 2 Test 3 S/N: 45605/48490-1 A RZO Test 2 Test 3 S/N: 43415/45041 As -Revd Test 2 Test 3 S/N: 43415/45039 As-Rcvd Test 2 Test 3 S/N: 43412/45045 As -Revd Test 2 Test 3 S/N: 43416/45042 As -Revd Test 2 Test 3 S/N: 43416/45040 As-Rcvd Test 2 Test 3 S/N: 43413/45046 As -Revd Test 2 Test 3 S/N: 44579/46842 As -Revd Test 2 Test 3 S/N: 44579/46841 As-Rcvd Test 2 Test 3 S/N: 44581/46846 As-Rcvd Test 2 Test 3 S/N: 44580/46844 As -Revd Test 2 Test 3 S/N: 44580/46843 As-Rcvd Test 2 Test 3 S/N: 44582/46848 As -Revd Test 2 Test 3 Standard Test Meter % Diff MEI NAIt. NA 'I ADM Recalibration Rev49/08/24/20 G P043AS-007255-RT-644 1 of 2 338 of 381 08/24/20 AIRDATA MULTIMETER CERTIFICATE OF RECALIBRATION SIN: (.2,j _ Vet Eqv Trans Std: S/N: M02009 Vel Eqv Trans Std: S/N: M02903 Vel Eqv Trans Std: S/N: M10839 Vel Eqv Trans Std: S/N: M10840 Approx Set Point 100 500 Order #: �1 d Ll 81 LOW VELOCITY CONFIRMATION (FPM) TEST METER TOLERANCE = ± 3.0% ± 7 FPM AS -RECEIVED TEST WITHIN SPEC aec-S NO N/A See Notes Test 2 Test 2 Test 2 Test 2 As-Rcvd Test 2 As-Rcvd Test 2 As-Rcvd As-Rcvd Standard Test Meter Test 2 Diff Test 3 Test 3 Test 3 Test 3 Standard /1/ 527 Vel Eqv Trans Std: S/N: M10897 As -R Vel Eqv Trans Std: S/N: M10901 Vel Eqv Trans Std: S/N: M13492 Vel Eqv Trans Std: S/N: M19325 Test Meter Diff As-Rcvd As-Rcvd As-Rcvd Standard Test 3 Test 3 Test 3 Test 3 Test Meter Diff ADM -880C, ADM -870/870C and ADM -860/860C models are read in AirFoil Mode. ADM -850/850L models are read in Pitot Tube Mode. TEMPERATURE TEST - AIRDATA MULTIMETER (° F) TEST METER TOLERANCE = ± 0.2° F AS -RECEIVED TEST WITHIN SPEC RTD Simulator: S/N 249 RTD Simulator S/N 250 RTD Simulator: S/N 253 RTD Simulator: S/N 254 RTD Simulator S/N 256 RTD Simulator: S/N 257 RTD Simulator: S/N 292 RTD Simulator: S/N 293 RTD Simulator: S/N 294 RTD Simulator: S/N 313 RTD Simulator SIN 314 RTD Simulator: S/N 315 RTD Simulator: S/N 316 RTD Simulator S/N 317 RTD Simulator: S/N 318 RTD Simulator Temperature Equivalent Set Point NOTES: Test Meter As-Rcvd As -Revd As-Rcvd As-Rcvd As -Revd As-Rcvd As-Rcvd As -Revd As-Rcvd As-Rcvd As-Rcvd As-Rcvd rest 2s) Test 2 Test 2 Test 2 Test 2 Test 2 Test 2 Test 2 Test 2 Test 2 Test 2 Test 2 Test 2 Difference Test 3 Test 3 Test 3 Test 3 Test 3 Test 3 Test 3 Test 3 Test 3 Test 3 Test 3 Test 3 Test 3 Test 3 Test 3 Test Meter Set Poi NO N/A See Notes 35.6° F 95° F 154.4° F Set Point: 35.6 Set Point: 35.6° F Set Point: 35.6° F Set Point: 35.6° F Set Point: 35.6° F Set Point: 35.6° F Set Point: 35.6° F Set Point: 35.6° F Set Point: 35.6° F Set Point: 35.6° F Set Point: 35.6° F Set Point: 35.6° F Set Point: 35.6° F Set Point: 35.6° F Difference 95°ES 154.4° F 95° F 95° F 95° F 95° F 95° F 95° F 95° F 95° F 95° F 95° F 95° F 95° F 95° F 154.4° FM' 154.4° F 154.4° F 154.4° F 154.4° F 154.4° F 154.4° F 154.4° F 154.4° F 154.4° F 154.4° F 154.4° F 154.4° F Test Meter Difference The encl osed ADM Calibration Standards for Pressure and Temperature form(s) is/are an integral part of this calibration and must remain with this Certificate of Calibration. Note: There may be more than one such form included that pertains to this calibration. Shortridg� Instruments, Inc. 7855 East Redfield -Road Scottsdale, Arizona 85260 (480) 991-6744 • Fax (480) 443-1267 • www.shortridge.com ADM RecalibratGlistgtlA2n07255-RT-644 2of2 339 of 381 08/24/20 Shortridge Instruments, Inc. AirData Multimeter Calibration Equipment Order Number: p a 1 O 9--41)1 Serial Number: YV\ tit -2 1 1 Test Type: ABSOLUTE PRESSURE STANDARDS ADM #02-R S/N: 41741/42451 Heise Model: PPM -2 Mfgd by Dresser industries Calibrated by Ashcroft ADM #04-R S/N: 41743/42453 Heise Model: PPM -2 Mfgd by Dresser Industries Calibrated by Ashcroft ADM #06-R S/N: 41742/42452-1 Heise Model: PPM -2 Mfgd by Dresser Industries Calibrated by Ashcroft ADM #08-R S/N: 42186/43328 Heise Model: PPM -2 Mfgd by Dresser Industries Calibrated by Ashcroft ADM #10-R S/N: 42203/43352 Heise Model: PPM -2 Mfgd by Dresser Industries Calibrated by Ashcroft ADM #12A -R S/N: 45605/48491 Heise Model: PPM -2 Mfgd by Dresser Industries Calibrated by Ashcroft ADM #14-R S/N: 43412/45043-2 Heise Model: PPM -2 Mfgd by Dresser Industries Calibrated by Ashcroft ADM #16-R S/N: 43413/45044 Heise Model: PPM -2 Mfgd by Dresser Industries Calibrated by Ashcroft ADM #18-R S/N: 44581/46845 Heise Model: PPM -2 Mfgd & Calibrated by Ashcroft, Inc. ADM #20-R S/N: 44582/46847 Heise Model: PPM -2 Mfgd & Calibrated by Ashcroft, Inc. #02-5, 04-R, 06-R, 08-R, 10-R, 12A -R, 14-5, 16-R Rated Accuracy: 0.05% Is (0.0305 in Hg) Range: 0-30 psia #18-R, 20-R Rated Accuracy: 0.05% fs (0.0305 in Hg) Range: 0-60 in Hg ADM #01-L ADM #01-R ADM #02-L ADM #03A -L ADM #03A -R ADM #04-L ADM #05-L ADM #05-R ADM #06-L ADM #07-L ADM #07-R ADM #08-L ADM #09-L ADM #09-R ADM #10-L ADM #11-L ADM #11-R ADM #12A -L ADM #13-L ADM #13-R ADM #14-L ADM #15-L ADM #15-R ADM #16-L ADM #17-L ADM #17-R ADM #18-L ADM #19-L ADM #19-R ADM #20-L S/N: 41739/42449 S/N: 41739/42446 S/N: 41741/42454 S/N: 45570/48461 S/N: 45570/48460 S/N: 41743/42456 S/N: 41740/42450 S/N: 41740/42447 S/N: 41742/42455 S/N: 42185/42186 S/N: 42185/43326 S/N: 42186/43329 S/N: 42202/43351 S/N: 42202/43350 S/N: 42203/43353 S/N: 43165/44551-1 S/N: 43165/44730 S/N: 45605/48490-1 S/N: 43415/45041 S/N: 43415/45039 S/N: 43412/45045 S/N: 43416/45042 S/N: 43416/45040 S/N: 43413/45046 S/N: 44579/46842 S/N: 44579/46841 S/N: 44581/46846 S/N: 44580/46844 S/N: 44580/46843 S/N: 44582/46848 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 Heise Model: PPM -1 #01-L, 03A -L, 05-L, 07-L, 09-L, 11-L, 13-L, 15-L, 17-L, 19-L #01-R, 03A -R, 05-R, 07-R, 09-R, 11-R, 13-R, 15-R, 17-R, 19-R #02-L, 04-L, 06-L, 08-L, 10-L, 12A -L, 14-L, 16-L, 18-L, 20-L Initial Calibration Date: 04/27/20 Calibration Date: 11/06/20 Calibration Date: 08/24/20 Calibration Date: 03/13/20 Calibration Date: 01/27/21 Calibration Date: 07/29/20 Calibration Date: 10/13/20 Calibration Date: 02/27/20 Calibration Date: 01/23/21 Calibration Date: 07/09/20 Resolution: 0.01 Resolution: 0.001 DIFFERENTIAL PRESSURE STANDARDS Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 05/05/20 Mfgd by Dresser industries Calibrated by Ashcroft Calibration Date: 05/05/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 05/04/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 11/11/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 11/11/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 11/09/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 09/03/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 09/03/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 09/03/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 03/13/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 03/11/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 03/13/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 01/26/21 Mfgd by Dresser industries Calibrated by Ashcroft Calibration Date: 01/26/21 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 01/26/21 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 07/30/20 Mfgd by Dresser industries Calibrated by Ashcroft Calibration Date: 07/30/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 08/11/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 10/21/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 10/21/20 Mfgd by Dresser industries Calibrated by Ashcroft Calibration Date: 10/21/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 03/03/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 03/03/20 Mfgd by Dresser Industries Calibrated by Ashcroft Calibration Date: 03/03/20 Mfgd & Calibrated by Ashcroft, Inc. Calibration Date: 01/26/21 Mfgd & Calibrated by Ashcroft, Inc. Calibration Date: 01/26/21 Mfgd & Calibrated by Ashcroft, Inc. Calibration Date: 01/26/21 Mfgd & Calibrated by Ashcroft, Inc. Calibration Date: 06/23/20 Mfgd & Calibrated by Ashcroft, Inc. Mfgd & Calibrated by Ashcroft, inc. Rated Accuracy: > 0.07% fs (0.000175 in wc) Rated Accuracy: > 0.06% fs ( 0.003 in wc) Rated Accuracy: > 0.06% fs (0.03 in wc) Calibration Date: 06/23/20 Calibration Date: 06/19/20 Range: 0.0-0.25 in we Range: 0.0-5.0 in we Range: 0.0-50.0 in wc Shortridge Instruments, Inc. 7855 East Redfield Road Scottsdale, Arizona 85260 (480) 991-6744 • Fax (480) 443-1267 • www.shortridge.com Res.: 0.00001 Res.: 0.0001 Res.: 0.001 Due Date: 04/2021 Due Date: 11/2021 Due Date: 08/2021 Due Date: 03/2021 Due Date: 01/2022 Due Date: 07/2021 Due Date: 09/2021 Due Date: 02/2021 Due Date: 10/2021 Due Date: 06/2021 Uncertainty: < 0.0358 Uncertainty: < 0.0358 Due Date: 04/2021 Due Date: 04/2021 Due Date: 04/2021 Due Date: 11/2021 Due Date: 11/2021 Due Date: 11/2021 Due Date: 08/2021 Due Date: 08/2021 Due Date: 08/2021 Due Date: 03/2021 Due Date: 03/2021 Due Date: 03/2021 Due Date: 01/2022 Due Date: 01/2022 Due Date: 01/2022 Due Date: 07/2021 Due Date: 07/2021 Due Date: 07/2021 Due Date: 09/2021 Due Date: 09/2021 Due Date: 09/2021 Due Date: 02/2021 Due Date: 02/2021 Due Date: 02/2021 Due Date: 10/2021 Due Date: 10/2021 Due Date: 10/2021 Due Date: 06/2021 Due Date: 06/2021 Due Date: 06/2021 Uncertainty: < 0.00035 Uncertainty: < 0.00348 Uncertainty: < 0.0346 ADM Cal Stnds Rev 16/08/24/20 1 of 2 G P043AS-007255-RT-644 340 of 381 02/08/21 Shortridge instruments, Inc. AirData Multimeter Calibration Equipment Customer Order Number, Meter Serial Number, and Test Type are referenced on page 1 LOW VELOCITY EQUIVALENT CONFIRMATION STANDARDS Vel Eqv Transfer Standard S/N: M02009 Vel Eqv Transfer Standard S/N: M02903 Vel Eqv Transfer Standard S/N: M10839 Vel Eqv Transfer Standard S/N: M10840 Vel Eqv Transfer Standard S/N: M10897 Vel Eqv Transfer Standard S/N: M10901 Vel Eqv Transfer Standard S/N: M13492 Vel Eqv Transfer Standard S/N: M19325 Model ADM -870C Model ADM -870C Model ADM -870C Model ADM -870C Model ADM -870C Model ADM -870C Model ADM -870C Model ADM -870C Rated Accuracy: Velocity ± 1.5 % ± 3.5 fpm RTD Simulator S/N: 249 RTD Simulator S/N: 250 RTD Simulator S/N: 253 RTD Simulator S/N: 254 RTD Simulator S/N: 256 RTD Simulator S/N: 257 RTD Simulator S/N: 292 RTD Simulator S/N: 293 RTD Simulator S/N: 294 RTD Simulator S/N: 313 RTD Simulator S/N: 314 RTD Simulator S/N: 315 RTD Simulator S/N: 316 RTD Simulator S/N: 317 RTD Simulator S/N: 318 Model RTD-1000/500 Model RTD-1000/500 Model RTD-1000/500 Model RTD-1000/500 Model RTD-1000/500 Model RTD-1000/500 Model RTD-1000/500 Model RTD-1000/500 Model RTD-1000/500 Model RTD-1000/500 Model RTD-1000/500 Model RTD-1000/500 Model RTD-1000/500 Model RTD-1000/500 Model RTD-1000/500 Rated Accuracy: 0.025% of setting Mfgd & Calibrated by Shortridge Instruments, Inc. Mfgd & Calibrated by Shortridge Instruments, Inc. Mfgd & Calibrated by Shortridge Instruments, Inc. Mfgd & Calibrated by Shortridge Instruments, Inc. Mfg'd & Calibrated by Shortridge Instruments, Inc. Mfg'd & Calibrated by Shortridge Instruments, inc. Mfg'd & Calibrated by Shortridge Instruments, inc. Mfgd & Calibrated by Shortridge Instruments, Inc. Range: 100-5000 fpm Resolution: 0.1 TEMPERATURE STANDARDS Mfgd by General Resistance Mfgd by General Resistance Mfgd by General Resistance Mfgd by General Resistance Mfgd by General Resistance Mfgd by General Resistance Mfgd by General Resistance Mfgd by General Resistance Mfgd by General Resistance Mfgd by General Resistance Mfgd by General Resistance Mfgd by General Resistance Mfgd by General Resistance Mfgd by General Resistance Mfgd by General Resistance Calibrated by IET Labs Calibrated by IET Labs Calibrated by IET Labs Calibrated by IET Labs Calibrated by IET Labs Calibrated by IET Labs Calibrated by IET Labs Calibrated by IET Labs Calibrated by LET Labs Calibrated by IET Labs Calibrated by JET Labs Calibrated by IET Labs Calibrated by IET Labs Calibrated by IET Labs Calibrated by IET Labs Range: 100.00 C to 11111.10 Calibration Date: 12/16/20 Calibration Date: 12/16/20 Calibration Date: 12/16/20 Calibration Date: 12/16/20 Calibration Date: 01/26/21 Calibration Date: 12/16/20 Calibration Date: 08/18/20 Calibration Date: 06/25/20 Due Date: 12/2021 Due Date: 12/2021 Due Date: 12/2021 Due Date: 12/2021 Due Date: 01/2022 Due Date: 12/2021 Due Date: 08/2021 Due Date: 06/2021 Uncertainty: <5.00 fpm at 100 fpm; <7.50 fpm at 500 fpm Thermometer #1 S/N 8A089/Thermistor S/N A410660 Model 1504/5610 Mfgd by Hart Scientific Calibrated by Fluke Thermometer #2 SIN 8B104/Thermistor SIN 871507 Model 1504/5610 Mfgd by Hart Scientific Calibrated by Fluke Thermometer #5 S/N B11780/Thermistor S/N B10505 Model 1504/5610 Mfgd by Hart Scientific Calibrated by Fluke Thermometer #6 S/N 611782/Thermistor S/N B10509 Model 1504/5610 Mfgd by Hart Scientific Calibrated by Fluke Thermometer #7 S/N B49938/Thermistor S/N B482202 Model 1504/5610 Mfgd and Calibrated by Fluke Resolution: 0.001 ° F Combined Uncertainty with Baths: s 0.040° F Calibration Date: 04/02/20 Calibration Date: 04/02/20 Calibration Date: 04/02/20 Calibration Date: 05/04/20 Calibration Date: 05/04/20 Calibration Date: 05/04/20 Calibration Date: 01/03/20 Calibration Date: 01/03/20 Calibration Date: 01/03/20 Calibration Date: 03/16/18 Calibration Date: 03/16/18 Calibration Date: 03/16/18 Calibration Date: 04/16/18 Calibration Date: 04/16/18 Calibration Date: 04/16/18 Resolution: 0.01 fl Due Date: 03/2024 Due Date: 03/2024 Due Date: 03/2024 Due Date: 04/2024 Due Date: 04/2024 Due Date: 04/2024 Due Date: 01/2024 Due Date: 01/2024 Due Date: 01/2024 Due Date: 03/2022 Due Date: 03/2022 Due Date: 03/2022 Due Date: 04/2022 Due Date: 04/2022 Due Date: 04/2022 Uncertainty: s 32 ppm Rated Accuracy(combined): 0.0324° F Range: 32° F to 176° F Temp Transfer Standard S/N M00136 Model ADM -870 Temp Transfer Standard S/N M96100 Model ADM -870 Rated Accuracy: 0.03° F Range: 33° F to 158° F Total combined Uncertainty for MultiTemp and TemProbe testing : s 0.046° F Mfgd & Calibrated by Shortridge Instruments, Inc. Mfgd & Calibrated by Shortridge Instruments, Inc. Resolution: 0.01° F Calibration Date: 08/27/19 Calibration Date: 11/04/20 Calibration Date: 11/04/20 Calibration Date: 02/24/20 Calibration Date: 09/26/19 Calibration Date: 10/20/20 Calibration Date: 03/09/20 Uncertainty: < 0.023° F Due Date: 08/2021 Due Date: 11/2022 Due Date: 11/2022 Due Date: 02/2022 Due Date: 09/2021 Due Date: 10/2021 Due Date: 03/2021 This form must remain with the Certificate of Calibration corresponding to the Customer Order Number and Meter Serial Number referenced on page 1. Shortridge Instruments, Inc. 7855 East Redfield Road Scottsdale, Arizona 85260 (480) 991-6744 • Fax (480) 443-1267 • www.shortridge.com ADM Cal Sj X255-RT-644 3412 ?f2381 02/08/21 tilti EPA Method 5 Meter Box Calibration by Calibrated Critical Orifice, MONTROSE 1 I r T i^ ski RO S E i `, I ', I' Leak Check, English Meter and Thermocouple Box Units, English Calibration K' Factor Check Meter box ID: M5-2 Date: 3/1/21 Yd: 0.9912 Meter ID (if applicable): 18gs4640 Location: Den -AT Orifice set ID: 1531s No. of orifices used (min. 3) 3 AH@: 1 '795 Calibrated by: TC Barometricpressure(in. Hg): 24.82 in. Hg Expires: 9/1/21 Theoretical critical vacuum 11.71 in. Hg IMPORTANT IMPORTANT Meter Box Orifice For valid The Critical Calibration test results, Orifice the Coefficient, Actual Vacuum K', must should be 1 to 2 be entered in English in. Hg greater than units, (ft)^3*(deg the Theoretical Critical Vacuum shown above R)^0.5/((in.Hg)*(min)). Volume Initial Temps. Final Temps. Orifice K' Orifice -- Ambient Temperature -- AH (in H2O) Time (min) Initial (cu ft) Final (cu ft) Net (cu ft) Inlet (deg F) Outlet (deg F) Inlet (deg F) Outlet (deg F) Serial# (number) Coefficient (see above) Vacuum (in Hg) Initial (deg F) Final (deg F) Average (deg F) 1.10 9.00 841.572 847.200 5.628 59 59 59 59 18 0.4918 17.0 64 64 64.0 0.85 11.00 847.200 853.514 6.314 59.0 59.0 60.0 60.0 16 0.4431 17.5 64.0 64.0 64.0 0.46 13.50 853.514 859.231 5.717 60.0 60.0 62.0 61.0 12 0.3207 19.0 64.0 64.0 64.0 --- SAMPLE INDICATED RATE --- VS. ACTUAL --- DRY GAS METER --- VOLUME CORRECTED ORIFICE VOLUME CORRECTEE VOLUME NOMINAL -- DRY GAS CALIBRATION Yd METER -- FACTOR CALIBRATION ORIFICE FACTOR AH@ AH (in. H2O) Sample Rate (scfm) Vm(std) (cu ft) Vcr(std) (cu ft) Vcr (cu ft) Value (number) Variation (number) Value (in H2O) Variation (in H2O) 1.10 0.533 4.763 4.799 5.744 1.0076 0.016 1.836 0.042 0.85 0.480 5.335 5.285 6.325 0.9906 -0.001 1.746 -0.048 0.46 0.348 4.813 4.694 5.618 0.9753 -0.016 1.801 0.006 QA Criteria: For Calibration Factor Y, the ratio of the reading of the calibration meter to the dry gas meter, Average Yd 0.9912 acceptable tolerance of individual values from the average is +1-0.02. Average AH@ 1.7945 Variation of Yd's PASS For Orifice Calibration Factor AH@, the orifice differential pressure in inches of H2O that equates to 0.75 cfm of air Variation of AH@ PASS at 68 F and 29.92 inches of Hg, acceptable tolerance of individual values from the average is +1-0.2. Vacuum Criteria PASS Meter Box Pressure Leak Check Meter Box Vacuum Leak Check Test Pressure, (in H2O): 6 Should be 5-7 in. H2O Test Vacuum, (in. Hg): 21 Coarse adjust valve fully open, fine adjust fully closed, sample inlet plugged Leak Rate, (in H2O/min): 0 Must be zero (manometer level stable for 1 minute) Leak Rate, (cfm): 0 Must be zero (meter dial stable for 1 minute) Meter Box Thermocouple Readout Calibration Check Input Temperature Allowable Temp. Dev.* Low High Stack Probe Filter Exit Aux. Meter In / Out Thermocouple simulator 32 7 25 39 30 31 29 29 28 29 Make: omega 68 8 60 76 67 67 66 66 65 64 Model: CL3512A 120 9 111 129 118 117 116 117 115 117 Serial Number 14000534 250 11 239 261 249 248 249 Cal Date: 10/20/2016 350 12 338 362 348 348 347 500 14 486 514 498 700 17 683 717 700 900 20 880 920 899 * Reading values must be within 1.5% of reference thermometer values (based on absolute temperature scale) for calibration to be acceptable. Performed by: Name: Tyler Conway Singature Date: Approved by: Name: Singature Date: Meter box 6 -month calibration form (orifices) R0 G P043AS-007255-RT-644 342 of 381 ilbillit$ Meter Box Calibration by EPA Calibrated Method 5 Critical Orifice: Post -Test, MO'NTROSE English Meter Box Units, English K' Factor L . \ I i. U r. N+ I I ,` - Meter box ID: M5-2 Date: 4/20/21 Current Cal. Yd: 0.9912 Meter ID (if applicable): 18654640 Location: DENVER, CO Orifice set ID: 1531s No. of runs (default 3) 3 Post-test Yd: 1.0038 Calibrated by (initials): TC Barometric pressure (in. Hg): 24.82 in. Hg Current 6 -month calibration Yd: 0.9912 Theoretical critical vacuum: 11.71 in. Hg Post-test Result: PASS Date of 6 -month calibration: 9/10/20 IMPORTANT IMPORTANT Meter Box Orifice For valid The Critical Calibration test results, Orifice Coefficient, the Actual Vacuum K', must should be 1 to 2 in. Hg greater than be entered in English units, (ft)^3*(deg the Theoretical R)^0.5/((in.Hg)*(min)). Critical Vacuum shown above Volume Initial Temps. Final Temps. Orifice K' Orifice -- Ambient Temperature -- AH (in H2O) Time (min) Initial (cu ft) Final (cu ft) Net (cu ft) Inlet (deg F) Outlet (deg F) Inlet (deg F) Outlet (deg F) Serial# (number) Coefficient (see above) Vacuum (in Hg) Initial (deg F) Final (deg F) Average (deg F) 1.70 8.00 0.045 6.448 6.403 57 57 58 58 23 0.6299 15.0 64 64 63.9 1.70 11.00 6.448 15.269 8.821 58 58 60 59 23 0.6299 15.0 64 64 64.0 1.70 8.00 15.269 21.702 6.433 60 59 62 59 23 0.6299 15.0 64 64 64.0 --- SAMPLE RATE --- --- DRY GAS METER --- ORIFICE INDICATED VS. ACTUAL VOLUME VOLUME CORRECTED CORRECTED VOLUME NOMINAL -- DRY GAS CALIBRATION Yd METER -- FACTOR ORIFICE CALIBRATION FACTOR AH@ AH (in. H2O) Sample Rate (scfm) Vm(std) (cu ft) Vcr(std) (cu ft) Vcr (cu ft) Value (number) Variation (number) Value (in H2O) Variation (in H2O) 1.70 0.68 5.444 5.465 6.538 1.0037 0.000 1.73 0.002 1.70 0.68 7.482 7.513 8.991 1.0041 0.000 1.73 0.000 1.70 0.68 5.444 5.464 6.539 1.0037 0.000 1.73 -0.002 QA Criteria: For Calibration Factor Y, the ratio of the reading of the calibration meter to the dry gas meter, Average Yd 1.0038 acceptable tolerance of individual values from the average is +/-0.02. Average AH@ 1.7321 Variation of Yd's PASS For Orifice Calibration Factor AH@, the orifice differential pressure in inches of H20 that equates to 0.75 cfm of air Variation of AH@ PASS at 68 F and 29.92 inches of Hg, acceptable tolerance of individual values from the average is +/-0.2. Vacuum Criteria PASS Meter Box Vacuum Leak Check Test Vacuum, (in. Hg): 21 Coarse adjust valve fully open, fine adjust fully closed, sample inlet plugged Leak Rate, (cfm): 0 Must be zero (meter dial stable for 1 minute) Meter box post-test calibration form (orifices) R3 G P043AS-007255-RT-644 343 of 381 MONTROSE L e I RONMLINTAL EPA Method 5 Meter Box Calibration by Calibrated Critical Orifice, Leak Check, and Thermocouple Calibration Check English Meter Box Units, English K' Factor Meter box ID: M5-19 Meter ID (if applicable): 1611031 Orifice set ID: 1531s Calibrated by: JK Expires: 6/17/21 Date: 12/17/20 Location: Denver Office No. of orifices used (min. 3) 3 Barometric pressure (in. Hg): 24.54 in. Hg Theoretical critical vacuum 11.58 in. Hg Yd: 1.0071 AH@: 1.874 Meter Box Orifice Calibration IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 in. Hg greater than the Theoretical Critical Vacuum shown above IMPORTANT The Critical Orifice Coefficient, K', must be entered in English units, (ft)^3*(deg R)^0.5/((in.Hg)*(min)). Volume Initial Temps. Final Temps. Orifice K' Orifice Coefficient (see above) -- Ambient Temperature -- AH (in H2O) Time (min) Initial (cu ft) Final (cu ft) Net (cu ft) Inlet (deg F) Outlet (deg F) Inlet (deg F) Outlet (deg F) Serial# (number) Vacuum (in Hg) Initial (deg F) Final (deg F) Average (deg F) 1.10 9.00 296.913 302.515 5.602 60.0 60.0 61.0 61.0 SN 1531s-18 0.4918 18.0 64.0 64.0 64.0 0.49 13.00 302.515 307.867 5.352 61.0 61.0 63.0 63.0 SN 1531s-12 0.3207 19.5 64.0 64.0 64.0 1.80 10.50 307.867 316.389 8.522 63.0 63.0 64.0 64.0 SN 1531 s-23 0.6299 17.0 64.0 64.0 64.0 --- SAMPLE RATE --- INDICATED VS. ACTUAL OH (in. H2O) Sample Rate (scfm) 1.10 0.527 0.49 0.344 1.80 0.675 --- DRY GAS METER --- VOLUME CORRECTED Vm(std) (cu ft) 4.674 4.445 7.085 For Calibration Factor Y, the ratio of the reading of the calibration meter to the dry gas meter, acceptable tolerance of individual values from the average is +/-0.02. ORIFICE VOLUME VOLUME CORRECTED NOMINAL Vcr(std) (cu ft) Vcr (cu ft) 4.745 5.744 4.469 5.410 7.090 8.583 For Orifice Calibration Factor zH@, the orifice differential pressure in inches of H20 that equates to 0.75 cfm of air at 68 F and 29.92 inches of Hg, acceptable tolerance of individual values from the average is +/-0.2. -- DRY GAS METER -- CALIBRATION FACTOR Yd Value (number) Variation (number) 1.0151 0.008 1.0055 -0.002 1.0008 -0.006 ORIFICE CALIBRATION FACTOR AH@ Value (in H2O) Variation (in H2O) 1.852 -0.022 1.935 0.060 1.837 -0.038 QA Criteria: Average Yd 1.0071 Average AH@ 1.8744 Variation of Yd's PASS Variation of AH@ PASS Vacuum Criteria PASS Meter Box Pressure Leak Check Test Pressure, (in H20): 6 Leak Rate, (in H2O/min): 0 Should be 5-7 in. H2O Must be zero (manometer level stable for 1 minute) Meter Box Vacuum Leak Check Test Vacuum, (in. Hg): 22 Leak Rate, (cfm): 0 Coarse adjust valve fully open, fine adjust fully closed, sample inlet plugged Must be zero (meter dial stable for 1 minute) Meter Box Thermocouple Readout Calibration Check Input Temperature Allowable Temp. Dev.* Low High 32 7 25 39 68 8 60 76 120 9 111 129 250 11 239 261 350 12 338 362 500 14 486 514 700 17 683 717 900 20 880 920 Stack Probe Filter Exit Aux. Meter In/Out 32 33 33 33 33 68 68 68 68 68 121 121 121 121 121 250 251 250 350 350 350 500 702 900 * Reading values must be within 1.5% of reference thermometer values (based on absolute temperature scale) for calibration to be acceptable. Performed by: Name: Jon Kinney Thermocouple simulator Make: Practical Instrument Electronics Model: 520.00 Serial Number 107078 Cal Date: 5/12/2020 Singature Date: Approved by: Name: �' P 4 .� � 44 Singature Date: 44 ra 0 0 0 Meter box 6 -month calibration form (orifices) R0 et\ii) EPA Method 5 di I Meter Box Calibration by Calibrated Critical Orifice: Post -Test, MONTROSE English Meter Box Units, English K Factor ! ONIMLN 1 l 1 Meter box ID: M5-19 Date: 4/262021 Current Cal. Yd: 1.0071 Meter ID (if applicable): 1611031 Location: DENVER, CO Orifice set ID: CO -1721s No. of runs (default 3) 3 Post-test Yd: 1.0192 Calibrated by (initials): DJS Barometric pressure (in. Hg): 24.28 in. Hg Current 6 -month calibration Yd: 1.0071 Theoretical critical vacuum: 11.45 in. Hg Post-test Result: PASS Date of 6 -month calibration: 12/17/21 IMPORTANT IMPORTANT Meter Box Orifice For valid The Critical Calibration test results, Orifice the Actual Vacuum Coefficient, K', must should be 1 to 2 in. Hg greater than the be entered in English units, (ft)^3*(deg Theoretical R)^0.5/((in.Hg)*(min)). Critical Vacuum shown above Volume Initial Temps. Final Temps. Orifice K' Orifice -- Ambient Temperature -- AH (in H2O) Time (min) Initial (cu ft) Final (cu ft) Net (cu ft) Inlet (deg F) Outlet (deg F) Inlet (deg F) Outlet (deg F) Serial# (number) Coefficient (see above) Vacuum (in Hg) Initial (deg F) Final (deg F) Average (deg F) 0.91 10.00 515.145 521.558 6.413 61 61 62 62 19 0.5028 19.0 62 62 62.0 0.91 8.00 532.077 537.176 5.099 64 64 65 65 19 0.5028 19.0 63 63 63.0 0.91 9.00 526.350 532.077 5.727 63 63 64 64 19 0.5028 19.0 62 63 62.5 --- SAMPLE RATE --- --- DRY GAS METER --- ORIFICE INDICATED VS. ACTUAL VOLUME VOLUME CORRECTED CORRECTED VOLUME NOMINAL -- DRY GAS CALIBRATION Yd METER -- FACTOR ORIFICE CALIBRATION FACTOR AH@ AH (in. H2O) Sample Rate (scfm) Vm(std) (cu ft) Vcr(std) (cu ft) Vcr (cu ft) Value (number) Variation (number) Value (in H2O) Variation (in H2O) 0.91 0.53 5.281 5.343 6.512 1.0117 -0.007 1.47 0.003 0.91 0.53 4.175 4.271 5.215 1.0228 0.004 1.47 -0.002 0.91 0.53 4.698 4.807 5.864 1.0230 0.004 1.47 -0.001 QA Criteria: For Calibration Factor Y, the ratio of the reading of the calibration meter to the dry gas meter, Average Yd 1.0192 acceptable tolerance of individual values from the average is +/-0.02. Average AH@ 1.4697 Variation of Yd's PASS For Orifice Calibration Factor AH@, the orifice differential pressure in inches of H20 that equates to 0.75 cfm of air Variation of Al -I@ PASS at 68 F and 29.92 inches of Hg, acceptable tolerance of individual values from the average is +/-0.2. Vacuum Criteria PASS Meter Box Vacuum Leak Check Test Vacuum, (in. Hg): 23 Coarse adjust valve fully open, fine adjust fully closed, sample inlet plugged Leak Rate, (cfm): 0 Must be zero (meter dial stable for 1 minute) Performed by: Name: David Smith Signature Date: 4.26.2021 Approved by: Name: Signature Date: Meter box post-test calibration form (orifices) R3 G P043AS-007255-RT-644 345 of 381 METHOD 6 DRY GAS METER POST -CALIBRATION USING METRIC REFERENCE METER 1) Connect meterbox to Reference Meter. 2) Record barometric pressure before and after calibration procedure. 3) Run at (approx.) 0.5, 1.0 & 2.0 LPM sample rate for as long as it takes to collect at least 10 cubic liters at each rate (approx. 20, 10 & 5 min) 4) Record data and information in the GREEN cells; YELLOW cells are calculated. 5) If the Post -Cal Y differs from the Pre -Cal by less than 5%, no adjustments are necessary. DATE: OPERATOR: RUN # 11/24/2020 caw METER ID #: REFERENCE METER Y: 30B -2A 1.0125 REFERENCE METER DGM TEMP. (W) DGM READINGS (m3) INITIAL FINAL NET (Vcr) BAROMETRIC PRESSURE (in Hg): INITIAL FINAL 24.71 24.71 30B DRY GAS METER FLOW RATE (LPM) DGM TEMP. (W) DGM READINGS (L) INITIAL FINAL NET (Vm) ELAPSED TIME (MIN) 0 MONTROSE AIR QUALITY SERVICES (1) Vcr (STD) (m3) (2) Vm (STD) (m3) (3) Y (unitless) 1 2 3 DATE: OPERATOR: RUN # 58 28.2006 28.2106 59 28.2106 28.2207 60 28.2207 28.2358 11/24/2020 caw 0.0100 0.0101 0.0151 METER ID #: REFERENCE METER Y: 1 57 0.000 10.016 0.5 59 0.000 10.095 2 61 0.000 15.178 30B -2B 1.0125 REFERENCE METER DGM TEMP. (°F) DGM READINGS (m3) INITIAL FINAL NET (Vcr) BAROMETRIC PRESSURE (in Hg): INITIAL 10.016 10.095 15.178 10.15 20.00 7.50 0.0085 0.0086 0.0128 0.0084 1.009 0.0085 1.013 0.0127 1.009 AVERAGE DRY GAS METER CALIBRATION FACTOR, Y = PRETEST CALIBRATION FACTOR, Y = 1.000 DIFFERENCE = 1.04% (<5)/c FINAL 24.71 24.71 30B DRY GAS METER FLOW RATE (LPM) DGM TEMP. (°F) DGM READINGS (L) INITIAL FINAL NET (Vm) 1.010 ELAPSED TIME (MIN) 0 (1) Vcr (STD) (ms) (2) Vm (STD) (m') (3) Y (unitless) 1 2 3 60 28.2358 28.2456 60 28.2456 28.2555 59 28.2555 28.2654 0.0098 0.0099 0.0099 1 64 0.000 10.062 0.5 65 0.000 10.104 2 65 0.000 10.151 10.062 10.104 10.151 10.00 20.00 5.00 0.0083 0.0084 0.0084 0.0084 0.994 0.0084 1.002 0.0084 0.999 AVERAGE DRY GAS METER CALIBRATION FACTOR, Y = PRE-TEST CALIBRATION FACTOR, Y = 1.000 0.998 G P043AS-007255-RT-644 346 of 381 DIFFERENCE = 0.19% (<5°/c) M30B-2 PreCal 11.24.20 METHOD 30B DRY GAS METER POST -CALIBRATION USING METRIC REFERENCE METER 1) Connect meterbox to Reference Meter. 2) Record barometric pressure before and after calibration procedure. 3) Run at maximum tested sample rate for a period of 20 minutes. 4) Record data and information in the GREEN cells; YELLOW cells are calculated. 5) If the Post -Cal Y differs from the Pre -Cal by less than 5%, no adjustments are necessary. DATE: OPERATOR: RUN # 4/20/2021 TC METER ID #: REFERENCE METER Y: 30B -2A 0.998 REFERENCE METER DGM TEMP. (°F) DGM READINGS (m3) INITIAL FINAL NET (Vcr) BAROMETRIC PRESSURE (in Hg): INITIAL FINAL 24.83 24.83 30B DRY GAS METER FLOW RATE (LPM) DGM TEMP. (°F) DGM READINGS (L) INITIAL FINAL NET (Vm) MONTROSE AI I QUALITY SERVICES ELAPSED TIME (MIN) 0 (1) Vcr (STD) (me) (2) Vm (STD) (me) (3) Y (unitless) 1 2 3 DATE: OPERATOR: RUN # 57 30.3667 30.3802 58 30.3802 30.3901 58 30.3901 30.4028 4/20/2021 TC 0.0135 0.0099 0.0127 METER ID #: REFERENCE METER Y: 1 61 0.000 13.663 1 62 0.000 9.744 1 63 0.000 12.786 30B -2B 0.998 REFERENCE METER DGM TEMP. (°F) DGM READINGS (m3) INITIAL FINAL NET (Vcr) BAROMETRIC PRESSURE (in Hg): INITIAL 13.663 9.744 12.786 14.00 10.00 13.00 0.0114 0.0084 0.0107 0.0115 0.994 0.0082 1.022 0.0107 1.001 AVERAGE DRY GAS METER CALIBRATION FACTOR, Y = PRE-TEST CALIBRATION FACTOR, Y = 1.010 DIFFERENCE = 0.45% (<5%) FINAL 24.83 24.82 30B DRY GAS METER FLOW RATE (LPM) DGM TEMP. (°F) DGM READINGS (L) INITIAL FINAL NET (Vm) 1.005 ELAPSED TIME (MIN) 0 (1) Vcr (STD) (ms) (2) V,,, (STD) (m3) (3) Y (unitless) 1 2 3 69 30.4028 30.4094 73 30.4094 30.4171 70 30.4171 30.4268 0.0066 0.0077 0.0097 1 65 0.000 6.916 1 65 0.000 7.735 1 66 0.000 9.757 6.916 7.735 9.757 7.00 8.00 10.00 0.0055 0.0063 0.0080 0.0058 0.945 0.0065 0.979 0.0081 0.985 AVERAGE DRY GAS METER CALIBRATION FACTOR, Y = PRE-TEST CALIBRATION FACTOR, Y = 0.998 0.969 G P043AS-007255-RT-644 347 of 381 DIFFERENCE = 2.86% (<5%) 30B Post Cal 4.20.2021 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix D.3 Instrumental Test Method QA/QC Data G P043AS-007255-RT-644 348 of 381 1 MONTROSE I AIR QUALIFY tiERvIEFS PROJ-007255 Biochar Now Kiln #56 4/14/2021 Initial Linearity Gas O2 CO2 NO,, CO TVOC Span 100 Concentration Low Mid High Low Mid High Low Mid High Low Mid High Zero Low Mid High Value Initial Response 0 10.52 21.73 0 7.937 17.48 0 144.9 246.7 0 2490 4536 0 25.06 51.08 84.81 -0.01 10.5 21.8 0.03 8.16 17.5 0.03 146 247 0.02 2,475 4,540 0.22 25.6 50.7 84.9 Error 0.0% 0.0% 0.1% 0.2% 1.3% 0.1% 0.0% 0.3% 0.1% 0.0% 0.3% 0.1% 0.2% 0.6% 0.4% 0.1% OK? Y Y Y Y Y Y V Y Y V Y V Y Y Y Y G P043AS-007255-RT-644 349 of 381 PROJ-007255 Biochar Now Kiln #56 4/14/2021 Analyzer Bias Checks Gas Analyzer Gas Concentration Value Response Initial Bias Run 1 Start Time 8:28 Run Length 120 Stop Time 10:40 Post Cal Bias Drift Run 2 Start Time 11:47 Run Length 120 Stop Time 13:58 Post Cal Bias Drift Run 3 Start Time 15:00 Run Length 120 Stop Time 17:16 Post Cal Bias Drift O2 Low Span 0 0.0 0.0% 0.1% 0.0 0.0% 0.0% -0.7% 0.8% 0.0 0.0% 0.0% -0.6% 0.1% 0.0 -0.1% 0.1% -0.7% 0.1% 10.52 10.5 10.4 10.4 10.4 CO2 Low Span 0 0.1 0.3% 1.1% 0.1 0.3% 0.0% 0.1% 0.9% 0.1 0.2% 0.1% -0.1% 0.2% 0.1 0.4% 0.2% -0.3% 0.2% 7.94 8.13 8.15 8.11 8.07 NOx Low Span 0 -0.1 0.0% 0.1% 0.5 0.2% 0.3% -0.1% 0.2% 0.5 0.2% 0.0% 0.2% 0.3% 0.4 0.2% 0.0% -0.4% 0.6% 144.90 145.2 144.9 145.6 144.3 CO Low Span 0.00 2.19 0.0% 1.4% -0.27 -0.1% 0.1% -0.5% 1.9% -0.08 0.0% 0.0% -1.5% 1.1% 0.69 0.0% 0.0% 0.1% 1.7% 2490.00 2,556 2,534 2,486 2,561 TVOC Low Span 0 0.2 0.2% 0.6% 0.0 -0.2% 0.4% -0.9% 1.4% 0.4 0.2% 0.4% 0.2% 1.1% 0.2 0.0% 0.2% -1.4% 1.6% 25.06 25.6 24.7 25.8 24.2 ≤5 ≤5% ≤3°% ≤5% ≤3 % ≤5% 3% G P043AS-007255-RT-644 350 of 381 PROJ-007255 Biochar Now Kiln #65 4/13/2021 Initial Linearity Gas O2 CO2 NO,, CO TVOC Span 100 Concentration Low Mid High Low Mid High Low Mid High Low Mid High Zero Low Mid High Value Initial Response 0 10.52 21.73 0 7.937 17.48 0 144.9 246.7 0 2490 4536 0 25.06 51.08 84.81 0.0 10.5 21.8 0.0 8.01 17.6 -0.1 145.3 247.4 -0.2 2,476 4,539 0.0 25.4 51.0 85.6 Error OK? 0.0% Y 0.0% Y 0.1% Y 0.0% Y 0.4% Y 0.5% Y 0.0% V 0.2% Y 0.3% Y 0.0% V 0.3% Y 0.1% V 0.0% Y 0.3% Y 0.1% Y 0.8% Y G P043AS-007255-RT-644 351 of 381 PROJ-007255 Biochar Now Kiln #65 4/13/2021 Analyzer Bias Checks Gas Analyzer Gas Concentration Value Response Initial Bias Run 1 Start Time 8:11 Run Length 120 Stop Time 10:34 Post Cal Bias Drift Run 2 Start Time 11:57 Run Length 120 Stop Time 14:09 Post Cal Bias Drift Run 3 Start Time 15:25 Run Length 120 Stop Time 17:45 Post Cal Bias Drift O2 Low Span 0 0.0 0.0% -0.1% 0.0 0.1% 0.1% 0.1% 0.2% 0.0 0.1% 0.1% 0.4% 0.3% 0.0 0.1% 0.0% 0.4% 0.0% 10.52 10.5 10.5 10.6 10.6 CO2 Low Span 0 0.0 0.0% 0.0% 0.0 0.1% 0.1% 0.3% 0.3% 0.0 0.3% 0.2% 0.2% 0.1% 0.0 0.3% 0.0% 0.2% 0.1% 7.937 7.94 8.00 7.98 7.97 NOx Low Span 0 0.0 0.0% 0.2% 0.2 0.1% 0.1% -1.3% 1.5% 0.2 0.1% 0.0% -0.4% 0.9% 0.4 0.2% 0.1% -1.0% 0.7% 144.90 145 142 145 143 CO Low Span 0 1.3 0.0% -0.4% 0.0 0.0% 0.1% -1.1% 0.8% -0.1 0.0% 0.0% -1.2% 0.1% 0.0 0.0% 0.0% -1.2% 0.0% 2490 2472 2420 2416 2418 TVOC Low Span 0 0.0 0.0% 0.3% 0.2 0.2% 0.2% -0.5% 0.9% -0.2 -0.2% 0.4% -0.5% 0.0% -0.2 -0.2% 0.0% 0.1% 0.7% 25.06 25.4 24.8 24.8 25.5 ≤5 ≤5% <3% <5% ≤3 % 5% 3% G P043AS-007255-RT-644 352 of 381 PROJ-007255 Biochar Now Kiln #74 4/15/2021 Initial Linearity Gas O2 CO2 NO,, CO TVOC Span 100 Concentration Low Mid High Low Mid High Low Mid High Low Mid High Zero Low Mid High Value Initial Response 0 10.52 21.73 0 7.937 17.48 0 144.9 246.7 0 1399 2490 0 25.06 51.08 84.81 0.0 10.5 21.8 0.0 7.91 17.6 0.1 145 247 -0.1 1,379 2,458 0.3 25.3 51.0 85.8 Error OK? 0.0% Y 0.1% Y 0.1% Y 0.1% Y 0.1% Y 0.6% Y 0.0% V 0.2% Y 0.1% Y 0.0% V 0.8% Y 1.3% V 0.3% Y 0.2% Y 0.1% Y 1.0% Y G P043AS-007255-RT-644 353 of 381 PROJ-007255 Biochar Now Kiln #74 4/15/2021 Analyzer Bias Checks Gas Analyzer Gas Concentration Value Response Initial Bias Run 1 Start Time 10:20 Run Length 120 Stop Time 12:44 Post Cal Bias Drift Run 2 Start Time 13:50 Run Length 120 Stop Time 15:58 Post Cal Bias Drift Run 3 Start Time 16:58 Run Length 120 Stop Time 19:04 Post Cal Bias Drift O2 Low Span 0 0.0 0.0% 0.0% 0.0 0.1% 0.1% -0.1% 0.1% 0.0 0.2% 0.1% 0.0% 0.1% 0.0 0.2% 0.0% 0.2% 0.2% 10.52 10.5 10.5 10.5 10.6 CO2 Low Span 0 0.0 0.1% 0.8% 0.0 -0.1% 0.2% -0.6% 1.4% 0.0 0.1% 0.2% -0.2% 0.4% 0.1 0.2% 0.2% 0.2% 0.4% 7.937 8.08 7.98 8.04 8.10 NOx Low Span 0 0.3 0.1% 0.0% 0.4 0.0% 0.1% 0.1% 0.1% 0.3 0.0% 0.0% -0.1% 0.2% 0.1 -0.1% 0.1% 0.1% 0.2% 144.9 144.8 145.0 144.6 145 CO Low Span 0.00 1.1 0.0% 0.0% -0.5 -0.1% 0.1% 0.3% 0.3% 0.1 0.0% 0.0% -0.4% 0.7% 0.5 0.0% 0.0% -0.5% 0.1% 1399 1398 1,405 1389 1386 TVOC Low Span 0 0.32 0.3% 0.2% 0.0 -0.4% 0.7% 0.3% 0.1% 0.1 -0.3% 0.1% 0.5% 0.2% -0.2 -0.5% 0.3% -0.6% 1.1% 25.06 25.26 25.6 25.8 24.6 ≤5 ≤5% ≤3°% ≤5% ≤3 % ≤5% 3% G P043AS-007255-RT-644 354 of 381 PROJ-007255 BioChar 4/13/2021 EPA Method 7E §8.2.4 NO2 to NO Converter Efficiency Test Time NO. ppm 18:07:18 45.95 18:07:33 46.02 18:07:48 46.15 18:08:03 46.18 18:08:18 46.21 18:08:33 46.23 18:08:48 46.25 18:09:03 Gas Value, ppm Average, ppm Efficiency, Limit 46.31 50.27 46.17 91.85 90 G P043AS-007255-RT-644 355 of 381 Airgas an Air Liquide company Airgas Specialty Gases Airgas USA, LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.corn CERTIFICATE OF ANALYSIS Grade of Product: EPA Protocol Part Number: Cylinder Number Laboratory: PGVP Number: Gas Code: E03N181 E15A0017 EB0086950 124 - Tooele (SAP) - UT B72021 CO2, O2, BAL N Expiration Date: Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certification Date: Feb 04, 2029 153-402018934-1 149.7 CF 2015 PSIG 590 Feb 04, 2021 Certification performed in accordance with "EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)" document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. I Component ANALYTICAL RESULTS Concentration Requested Actual Concentration Protocol Method Total Relative Uncertainty Assay Dates I I CARBON DIOXIDE OXYGEN NITROGEN 8.000 % 10.50 % Balance 7.937 10.52% G1 G1 CALIBRATION STANDARDS Type Lot ID Cylinder No Concentration +/- 0.7% NIST Traceable +/- 0.8% NIST Traceable 02/04/2021 02/04/2021 Uncertainty Expiration Date NTRM 13060405 CC411744 7.489 % CARBON DIOXIDE/NITROGEN 0.6% May 14, 2025 NTRM 98051010 SG9161286BAL 12.05 % OXYGEN/NITROGEN 0.7% Dec 14, 2023 I Instrument/Make/Model Analytical Principle Last Multipoint Calibration ANALYTICAL EQUIPMENT I I IHoriba VIA -510 SV4MEUTJ CO2 Horiba MPA-510 W603MM58 O2 CO2 NDIR (Dixon) O2 Paramagnetic (Mason) Feb 04, 2021 Feb 01, 2021 Triad Data Available Upon Request Signature on file Approved for Release G P043AS-007255-RT-644 356 of 381 Page 1 of 153-402018934-1 Airgas an Air Liquide company Airgas Specialty Gases Airgas USA, LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.corn CERTIFICATE OF ANALYSIS Grade of Product: EPA Protocol Part Number: Cylinder Number Laboratory: PGVP Number: Gas Code: E03N161 E15A0287 CC415516 124 - Tooele (SAP) - UT B72019 CO2, O2, BAL N Expiration Date: Reference Number: 153-401541913-1 Cylinder Volume: 158.0 CF Cylinder Pressure: 2015 PSIG Valve Outlet: 590 Certification Date: Jul 08, 2019 Jul 08, 2027 Certification performed in accordance with "EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)" document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. I Component ANALYTICAL RESULTS Concentration Requested Actual Concentration Protocol Method Total Relative Uncertainty Assay Dates I I IInstrument/Make/Model CARBON DIOXIDE OXYGEN NITROGEN Type Lot ID 18.00 % 21.00 % Balance Cylinder No 1T48 % 21.73 % G1 G1 CALIBRATION STANDARDS Concentration +/- 0.5% NIST Traceable +/- 0.2% NIST Traceable 07/08/2019 07/08/2019 Uncertainty Expiration Date NTRM 06011806 K012669 23.04 % CARBON DIOXIDE/NITROGEN 0.5% Jun 27, 2022 NTRM 12062019 CC367606 22.883 % OXYGEN/NITROGEN 0.050% May 14, 2024 ANALYTICAL EQUIPMENT Analytical Principle Last Multipoint Calibration Instrument/Make/Model IHoriba VIA -510 SV4MEUTJ CO2 Horiba MPA-510 W603MM58 O2 CO2 NDIR (Dixon) O2 Paramagnetic (Mason) Jun 13, 2019 Jun 13, 2019 Triad Data Available Upon Request Signature on file Approved for Release G P043AS-007255-RT-644 357 of 381 Page 1 of 153-401541913-1 Airgas an Air Liquide company Airgas Specialty Gases Airgas USA, LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.corn CERTIFICATE OF ANALYSIS Grade of Product: EPA Protocol Part Number: Cylinder Number Laboratory: PGVP Number: Gas Code: E03N 199E 15AC3R0 CC481001 124 - Tooele (SAP) - UT B72020 CO,NO,NOX,BALN Expiration Date: Reference Number: 153-401827157-1 Cylinder Volume: 144.4 CF Cylinder Pressure: 2015 PSIG Valve Outlet: 660 Certification Date: Jun 16, 2020 Jun 16, 2028 Certification performed in accordance with "EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)" document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. Component Requested Concentration ANALYTICAL RESULTS Actual Concentration Protocol Method Total Relative Uncertainty Assay Dates NOX CARBON MONOXIDE N ITRIC OXIDE N ITROGEN 145.0 PPM 145.0 PPM 145.0 PPM Balance 144.9 PPM 143.5 PPM 144.8 PPM G1 G1 G1 +/- 1.3% NIST Traceable +/- 0.6% NIST Traceable +/- 1.3% NIST Traceable 06/09/2020, 06/16/2020 06/09/2020 06/09/2020, 06/16/2020 I Type Lot ID Cylinder No CALIBRATION STANDARDS Concentration Uncertainty Expiration Date NTRM PRM NTRM GMIS 09010219 12376 17060207 7302017111 KAL004817 D562879 CC481799 CC511391 98.48 PPM CARBON MONOXIDE/NITROGEN 10.01 PPM NITROGEN DIOXIDE/NITROGEN 100.3 PPM NITRIC OXIDE/NITROGEN 4.634 PPM NITROGEN DIOXIDE/NITROGEN The SRM, PRM or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. Instrument/Make/Model ANALYTICAL EQUIPMENT Analytical Principle 0.5% 2.0% 1.0% 2.0% Oct 16, 2024 Aug 17, 2018 Jul 23, 2023 Aug 15, 2021 Last Multipoint Calibration Nicolet 6700 AHR0801550 CO LCO N icolet 6700 AHR0801550 NO MNO N icolet 6700 AHR0801550 NO2 impurity FTIR FTIR FTIR NO2 impurity Jun 03, 2020 May 20, 2020 May 20, 2020 Triad Data Available Upon Request PERMANENT NOTES:TRC ENVIRONMENTAL i i Signature on file Approved for Release G P043AS-007255-RT-644 358 of 381 Page 1 of 153-401827157-1 Airgas an Air Liquide company Airgas Specialty Gases Airgas USA, LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.corn CERTIFICATE OF ANALYSIS Grade of Product: EPA Protocol Part Number: Cylinder Number Laboratory: PGVP Number: Gas Code: E03N 199E 15A0360 EB0094057 124 - Tooele (SAP) - UT B72017 CO,NO,NOX,BALN Expiration Date: Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certification Date: Mar 28, 2025 153-124609540-2 144.4 CF 2015 PSIG 660 Mar 28, 2017 Certification performed in accordance with "EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)" document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. Component ANALYTICAL RESULTS Requested Actual Protocol Total Relative Concentration Concentration Method Uncertainty Assay Dates NOX CARBON MONOXIDE N ITRIC OXIDE N ITROGEN 250.0 PPM 250.0 PPM 250.0 PPM Balance 246.7 PPM 251.3 PPM 246.0 PPM G1 G1 G1 +/- 1.1% NIST Traceable +/- 0.6% NIST Traceable +/- 1.0% NIST Traceable 03/21/2017, 03/28/2017 03/21/2017 03/21/2017, 03/28/2017 IType Lot ID I Instrument/Make/Model Cylinder No CALIBRATION STANDARDS Concentration Uncertainty Expiration Date NTRM 14060320 PRM 12367 NTRM 15060323 GMIS 0315201603 CC432212 APEX1099237 CC448273 CC502257 252.5 PPM CARBON MONOXIDE/NITROGEN 9.82 PPM NITROGEN DIOXIDE/NITROGEN 241.0 PPM NITRIC OXIDE/NITROGEN 4.875 PPM NITROGEN DIOXIDE/NITROGEN The SRM, PRM or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EQUIPMENT Analytical Principle 0.3 1.6% 0.5 1.6 Feb 21, 2020 May 29, 2016 Mar 30, 2021 Mar 15, 2019 Last Multipoint Calibration N icolet 6700 AHR0801550 CO MCO FTIR Mar 01, 2017 N icolet 6700 AHR0801550 NO MNO FTIR Mar 09, 2017 Nicolet 6700 AHR0801550 NO2 impurity FTIR NO2 impurity Mar 09, 2017 Triad Data Available Upon Request i i Signature on file Approved for Release G P043AS-007255-RT-644 359 of 381 Page 1 of 153-124609540-2 Airgas an Air Liquide company Airgas Specialty Gases Airgas USA, LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.corn CERTIFICATE OF ANALYSIS Grade of Product: EPA Protocol Part Number: Cylinder Number Laboratory: PGVP Number: Gas Code: E02N 199E 15W0030 CC500460 124 - Tooele (SAP) - UT B72019 NO2,BALN Expiration Date: Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certification Date: Dec 02, 2022 153-401657910-1 144.0 CF 2015 PSIG 660 Dec 02, 2019 Certification performed in accordance with "EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)" document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. Component Requested Concentration ANALYTICAL RESULTS Actual Concentration Protocol Total Relative Method Uncertainty Assay Dates INITROGEN DIOXIDE NITROGEN 50.00 PPM Balance 50.27 PPM G1 +/- 2.0% NIST Traceable 11/25/2019, 12/02/2019 CALIBRATION STANDARDS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date GMIS 401206801105 CC513733 58.35 PPM NITROGEN DIOXIDE/NITROGEN 1.8% PRM 12388 D685030 59.5 PPM NITROGEN DIOXIDE/NITROGEN 1.7% The SRM, PRM or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. Instrument/Make/Model ANALYTICAL EQUIPMENT Analytical Principle Last Multipoint Calibration May 02, 2022 Feb 20, 2020 I MKS FTIR NO2 018143349 FTIR Dec 02, 2019 Triad Data Available Upon Request PERMANENT NOTES:OXYGEN ADDED TO MAINTAIN STABILITY. Signature on file Approved for Release G P043AS-007255-RT-644 360 of 381 Page 1 of 153-401657910-1 Airgas an Air Liquide company Airgas Specialty Gases Airgas USA, LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.corn CERTIFICATE OF ANALYSIS Grade of Product: EPA Protocol Part Number: Cylinder Number Laboratory: PGVP Number: Gas Code: E03N 199E 15A06P6 ALM-061874 124 - Tooele (SAP) - UT B72017 CO,NO,NOX,BALN Expiration Date: Reference Number: 153-400983601-1 Cylinder Volume: 144.4 CF Cylinder Pressure: 2015 PSIG Valve Outlet: 660 Certification Date: Sep 13, 2017 Se • 13. 2025 Certification performed in accordance with "EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)" document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. Component Requested Concentration ANALYTICAL RESULTS Actual Concentration Protocol Method Total Relative Uncertainty Assay Dates NOX CARBON MONOXIDE N ITRIC OXIDE N ITROGEN 1400 PPM 1400 PPM 1400 PPM Balance 1396 PPM 1399 PPM 1395 PPM G1 G1 G1 +/- 0.8% NIST Traceable +/- 1.1% NIST Traceable +/- 0.8% NIST Traceable 09/06/2017, 09/13/2017 09/06/2017 09/06/2017, 09/13/2017 I Type Lot ID CALIBRATION STANDARDS Cylinder No Concentration Uncertainty Expiration Date NTRM/CM PRM NTRN GMIS 12060711 12367 15060212 1114201604 CC356038 APEX1099237 CC449792 CC507567 2498 PPM CARBON MONOXIDE/NITROGEN 9.82 PPM NITROGEN DIOXIDE/NITROGEN 997.2 PPM NITRIC OXIDE/NITROGEN 4.955 PPM NITROGEN DIOXIDE/NITROGEN The SRM, PRM or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. Instrument/Make/Model ANALYTICAL EQUIPMENT Analytical Principle +/- 0.6% 1.6% 0.5 2.0% Dec 21, 2017 May 29, 2016 Nov 02, 2020 Nov 14, 2019 Last Multipoint Calibration Nicolet 6700 AHR0801550 CO HCO N icolet 6700 AHR0801550 NO HNO N icolet 6700 AHR0801550 NO2 impurity FTIR FTIR FTIR NO2 impurity Aug 17, 2017 Sep 07, 2017 Sep 07, 2017 Triad Data Available Upon Request Signature on file Approved for Release G P043AS-007255-RT-644 361 of 381 Page 1 of 153-400983601-1 Airgas an Air Liquide company Airgas Specialty Gases Airgas USA, LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.corn CERTIFICATE OF ANALYSIS Grade of Product: EPA Protocol Part Number: Cylinder Number Laboratory: PGVP Number: Gas Code: E02N 199E 15A0138 CC701952 124 - Tooele (SAP) - UT B72020 CO,BALN Expiration Date: Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certification Date: May 18, 2028 153-401812783-1 144.4 CF 2015 PSIG 350 May 18, 2020 Certification performed in accordance with "EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)" document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. Component Requested Concentration ANALYTICAL RESULTS Actual Protocol Concentration Method Total Relative Uncertainty Assay Dates ICARBON MONOXIDE NITROGEN Type Lot ID 2500 PPM Balance Cylinder No 2490 PPM G1 CALIBRATION STANDARDS Concentration +/- 1.1% NIST Traceable 05/18/2020 Uncertainty Expiration Date I NTRM 08012254 KAL004707 2466 PPM CARBON MONOXIDE/NITROGEN 0.5% May 09, 2024 Instrument/Make/Model ANALYTICAL EQUIPMENT Analytical Principle Last Multipoint Calibration I Horiba VIA -510 4143358002 HCO CO NDIR (Dixon) May 18, 2020 Triad Data Available Upon Request Signature on file Approved for Release G P043AS-007255-RT-644 362 of 381 Page 1 of 153-401812783-1 Airgas an Air Liquide company Airgas Specialty Gases Airgas USA, LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.corn CERTIFICATE OF ANALYSIS Grade of Product: EPA Protocol Part Number: Cylinder Number Laboratory: PGVP Number: Gas Code: E02 N 199E 15A0473 EB0091197 124 - Tooele (SAP) - UT B72017 CO,BALN Expiration Date: Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certification Date: Feb 01, 2025 153-124601011-1 144.4 CF 2015 PSIG 350 Feb 01, 2017 Certification performed in accordance with "EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)" document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. Component Requested Concentration ANALYTICAL RESULTS Actual Protocol Concentration Method Total Relative Uncertainty Assay Dates ICARBON MONOXIDE NITROGEN Type Lot ID 4500 PPM Balance 4536 PPM G1 CALIBRATION STANDARDS Cylinder No Concentration +/- 0.4% NIST Traceable 02/01/2017 Uncertainty Expiration Date I NTRM/CM 13060225 CC401972 4950 PPM CARBON MONOXIDE/NITROGEN +/- 0.4% Feb 15, 2019 Instrument/Make/Model ANALYTICAL EQUIPMENT Analytical Principle Last Multipoint Calibration I Horiba VIA -510 46E0F8YY LCO CO NDIR (Dixon) Jan 19, 2017 Triad Data Available Upon Request Signature on file Approved for Release G P043AS-007255-RT-644 363 of 381 Page 1 of 153-124601011-1 Airgas an Air Liquide company Airgas Specialty Gases Airgas USA, LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.corn CERTIFICATE OF ANALYSIS Grade of Product: EPA Protocol Part Number: Cylinder Number Laboratory: PGVP Number: Gas Code: E02N 199E 15A0556 CC476309 124 - Tooele (SAP) - UT B72018 PPN,BALN Expiration Date: Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certification Date: Dec 03, 2026 153-401367398-1 144.4 CF 2015 PSIG 350 Dec 03, 2018 Certification performed in accordance with "EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)" document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. Component Requested Concentration ANALYTICAL RESULTS Actual Protocol Concentration Method Total Relative Uncertainty Assay Dates IPROPANE NITROGEN Type 25.00 PPM Balance Lot ID 25.06 PPM G1 +/- 1.1% NIST Traceable 12/03/2018 CALIBRATION STANDARDS Cylinder No Concentration Uncertainty Expiration Date I NTRM 17061011 ND61547 49.13 PPM PROPANE/AIR 0.4% Jul 21, 2023 Instrument/Make/Model ANALYTICAL EQUIPMENT Analytical Principle Last Multipoint Calibration I Nicolet 6700 AMP0900119 C3H8 LC3H8 FTIR Nov 29, 2018 Triad Data Available Upon Request Signature on file Approved for Release G P043AS-007255-RT-644 364 of 381 Page 1 of 153-401367398-1 Airgas an Air Liquide company Airgas Specialty Gases Airgas USA, LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.corn CERTIFICATE OF ANALYSIS Grade of Product: EPA Protocol Part Number: Cylinder Number Laboratory: PGVP Number: Gas Code: E02N 199E 15A0931 CC114869 124 - Tooele (SAP) - UT B72019 PPN,BALN Expiration Date: Reference Number: 153-401560888-1 Cylinder Volume: 144.4 CF Cylinder Pressure: 2015 PSIG Valve Outlet: 350 Certification Date: Jul 30, 2019 Jul 30, 2027 Certification performed in accordance with "EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)" document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. Component Requested Concentration ANALYTICAL RESULTS Actual Protocol Concentration Method Total Relative Uncertainty Assay Dates IPROPANE NITROGEN Type 50.00 PPM Balance Lot ID 51.08 PPM G1 +/- 0.9% NIST Traceable 07/30/2019 CALIBRATION STANDARDS Cylinder No Concentration Uncertainty Expiration Date I NTRM 17061011 ND61547 49.13 PPM PROPANE/AIR 0.4% Jul 21, 2023 Instrument/Make/Model I Nicolet 6700 AMP0900119 C3H8 LC3H8 ANALYTICAL EQUIPMENT Analytical Principle FTIR Last Multipoint Calibration Jul 03, 2019 Triad Data Available Upon Request Signature on file Approved for Release G P043AS-007255-RT-644 365 of 381 Page 1 of 153-401560888-1 Airgas an Air Liquide company Airgas Specialty Gases Airgas USA, LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.corn CERTIFICATE OF ANALYSIS Grade of Product: EPA Protocol Part Number: Cylinder Number Laboratory: PGVP Number: Gas Code: E02N 199E 15A0581 CC129134 124 - Tooele (SAP) - UT B72019 PPN,BALN Expiration Date: Reference Number: 153-401539889-1 Cylinder Volume: 144.4 CF Cylinder Pressure: 2015 PSIG Valve Outlet: 350 Certification Date: Jul 09, 2019 Jul 09, 2027 Certification performed in accordance with "EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)" document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. Component Requested Concentration ANALYTICAL RESULTS Actual Protocol Concentration Method Total Relative Uncertainty Assay Dates IPROPANE NITROGEN Type 85.00 PPM Balance Lot ID 84.81 PPM G1 +/- 0.5% NIST Traceable 07/09/2019 CALIBRATION STANDARDS Cylinder No Concentration Uncertainty Expiration Date I NTRM 17061011 ND61547 49.13 PPM PROPANE/AIR 0.4% Jul 21, 2023 Instrument/Make/Model ANALYTICAL EQUIPMENT Analytical Principle Last Multipoint Calibration I Nicolet 6700 AMP0900119 C3H8 LC3H8 FTIR Jul 03, 2019 Triad Data Available Upon Request ■ ■ ■ _a • • Myr Signature on file Approved for Release G P043AS-007255-RT-644 366 of 381 Page 1 of 153-401539889-1 Thermo Fisher SCIENTIFIC To Whom It May Concern: lievadd leader is serving some in an effort to assist our customers with meeting the requirements of the Instrumental Methods for testing, 3A, 6C, 7E. 10. and 20, we are providing a summary of interferences for certain Thermo Scientific analyzers. The requirement for conducting analyzer interference checks for potential interfering gases is the responsibility of the testing organizations. The Methods do, however, allow the manufacturer of instruments to provide this data. Test are required to be conducted on the same "make and model" as those being used for method testing. The information contained in the accompanying tables pertains to the "make" of analyzers under the names of; Thermo Electron Corporation, Thermo Environmental Instruments and Thermo Scientific. The "model" are models; Model 42 for NO, Nth, NO., Model 43 forSO2, and Model L1-101 for CO2. The specific pollutant detection and analytical technology for each of the above listed specific models have remained the same for the various series of analyzers manufactured over the past years. Therefore, the interference test results shown for iSeries analyzers would produceessentially the same results for C Series and earlier Series of these models. The potential interference gases test results shown in the tables to follow indicate that none of the Thermo Scientific analyzers tested have a collective analytical detection interference that would sum more than 0.06% of analyzer span value. The acceptance criterion is; the sum of the interference responses must not he greater than 2.5% of analyzer span value. If you have any questions regarding the information contained herein please do no hesitate to contact us. Thermo Fisher Scientific Frank Duckett Product Manager, Continuous Gas Analyzers Air Quality instruments Air Quality Instruments ErpOiroornerital Insicume'ds 27 Forge Parkway, Frarfln, MA 02038 (5 8) 520-0430 (508) 520-1480 fax www ,Ilhennorisher.corn G P043AS-007255-RT-644 367 of 381 Thermo Fisher SCIENTIFIC Thermo Scientific Model 42-NO2-NO Analyzer Potential Interference Gas Responses Potentiallnterferent Model 421L5 Model 4zl 't Test Gas Concentration NO 1 NO2 1 NOx 11 NO NO2 NOS CO2 5.20% 0.001 0.004 0,004 0.003 0.004 0.001 CO2 15.60% 0 0.003 1 0.003 j r 0.001 0.004 0.005 112O 1.00°1 0 0 0 0.003 0.001 0.004 NO 0.1 15 15 -0.00 14.99 14.E 15 ppm NO215 ppm 1.1 14 15 II 0.4 15 14.6 I2O 10 ppm 0 0 , 0 i 0 0 0 CO 50 ppm 0 0 0 1 0 0 0 5O2 21 ppm -0.01 0 -0.01 1 0.007 0 0.007 CH4 50 ppm 0 r 0 0 0 0 0 HO 10 ppm 0 0.005 0.006 ! 0 0.004 0.004 NH3' 10 ppm 0 1 0 I 0.17 8.9 45 9.1 0 Sum of Responses 0.011 0.01 0.02 0.011 0.009 0,02 Span Value 160 152 4 160 160 152 160 % of Calibration Span 0.01% 0.01% 1 0.01% 0.01% 0.01 % 0.01% Acceptance Criteria found in Section 13.4 of Method 7E is the sum of responses must not be greater than 2.5% of the analyzer calibration span value. 1NH3 interferent results shown for the Model 42iHL was not used in calculation of interference response check because it is a known interferent with an approximate 1 ppm to 1 ppm positive bias in analyzers using stainless steel NO2to NO converters_ Thermo recommends that NO analyzers with stainless steel ► O2 to NO converters must use a NH3 scrubber when testing sources with potential NH3 in the flue gas_ This document is subject to change without notice. iNvAv.therrnoftsher.cpern G P043AS-007255-RT-644 368 of 381 Thera F Slier 5 CIENTIFIC Thermo Scientific Model 43 O2 and Model 4101 + O2Analyzer Potential Interference Gas Responses Potential Interferent Model 431LH Model 4101141. Test p Gas Concentration 502 CO2 , CO2 5.20% 0.03 5.2 CO2 15.60% 0,14 t 15.5 H20 1.00% -0.05 0 NO 15 ppm 0.2 0 NO215 ppm 0.05 0 N20 10 ppm 0 A 0 CO 50 ppm 0 0 SO2 1 21 ppm 21 0 Ct-I4 1 50 ppm 0 1 0 w HCI 10 ppm 0 0 N H2 10 ppm 0 0 Sum of Responses 0.45 0 Span Value 800 16 of Calibration Span 0.06% 0% Acceptance Criteria found in Section 13.4 of Method 7E is the sum of responses must not be greater than 2.5% of the analyzer calibration span value. This document is subject to change without noticea www iherrnolisher, corn G P043AS-007255-RT-644 369 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix D.4 Accreditation Information/Certifications G P043AS-007255-RT-644 370 of 381 1 MONTROSE I AIR QUALIFY tiERvIEFS STA C *dirt STACK TESTING ACCREDITATION COUNCIL American Association for Laboratory Accreditation Accredited Air Emission Testing Body A2LA has accredited MONTROSE AIR QUALITY SERVICES In recognition of the successful completion of the joint A2LA and Stack Testing Accreditation Council (STAC) evaluation process, this laboratory is accredited to perform testing activities in compliance with ASTM D7036:2004 - Standard Practice for Competence of Air Emission Testing Bodies. Presented this 1 1 th day of February 2020. Vice President, Accreditation Services For the Accreditation Council Certificate Number 3925.01 Valid to February 28, 2022 This accreditation program is not included under the A2LA ILAC Mutual Recognition Arrangement. G P043AS-007255-RT-644 371 of 381 LET IT BE KNOWN THAT HAS SUCCESSFULLY PASSED A COMPREHENSIVE EXAMINATION AND SATISFIED EXPERIENCE REQUIREMENTS IN ACCORDANCE WITH THE GUIDELINES ISSUED BY THE SES QUALIFIED SOURCE TEST INDIVIDUAL REVIEW BOARD FOR MAWUAL GAS VOLUME .MEASUREMENTS AND ISOKINETIC PARTICULATE SAMPLING METHODS ISSUED THIS 21ST DAY F NOVEMBER 2018 AND EFFECTIVE UNTIL NOVEMBER BE O` H, 2023 G Poo AS -0 S 7255-RT-644 372 of 381 Ti Qualified Source Testing Individual LET IT BE KNOWN THAT JEFFREY S. GOLDFINE HAS SUCCESSFULLY PASSED A COMPREHENSIVE EXAMINATION AND SATISFIED EXPERIENCE REQUIREMENTS IN ACCORDANCE WITH THE GUIDELINES ISSUED BY THE SES QUALIFIED SOURCE TEST INDIVIDUAL REVIEW BOARD FOR GASEOUS POLLUTANTS INSTRUMENTAL SAMPLING METHODS ISSUED THIS 11TH DAY OF MARCH 2017 AND EFFECTIVE UNTIL MARCH 10TH, 2022 Peter R. Westlin, QSTI/QSTO Review Board ,4 a , r r 7 t Peter S. Pakalnis, QSTI/QSTO Review Board thekarc Theresa Lowe, QS TUQS TO Review Board G P043AS-007255-RT-644 J. Wade Bice, QSTI/QSTO Review Board 1 ,f Karen D. kaJiyra-Mills , QSTUQSTO Review Board Bruce Randall QSTI/QSTO Review Board 373 of 381 CERTIFICATE NO. 2008-198 gineering, Inc. Solutions for a Changing Environment Certification of Visible Opacity Reading Tyler Conway qua/ified to conduct EPA Method 9 Tests for visible °pacify in accordance with the methods established for such qualificat/on in 4C? CFR Part 60 Appendix A. Certification Date: April 09, 2021 Expiration Date: October 09, 2021 G P043AS-007255-RT-644 AeroMet Instructor: Jim Breese 374 of 381 AEROMET ENGINEERING INC. CERTIFIES THAT Tyler Conway Liu .�i Q3 Oni CC3 Od Col OOO tee) � E On 694 ine Os 10/09/2021 4) a w 04/09/2021 a) Coil 73 336 9 V. C CD J L CERTIFICATE OF COMPLETION David Smith This document certifies that this individual has passed a comprehensive examination and is now a Qualified Individual (QI) as defined in Section 8.3 of ASTM O7036-04 for the following method(s): Certificate Number: 043-2019-17 EPA Method 308 QATEOFISSUE: 10/28/19 _ 10/28/24 1 Tate Strickler, Accreditation Director DATE OF EXPIRATION: N V R rkfrii4 r, 1 G P043AS-007255-RT-644 375 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report Appendix D.5 Quality Assurance Program Summary and Equipment Calibration Schedule G P043AS-007255-RT-644 376 of 381 4,/\, ONTRO E wI AIR QUALIFY tiERvIEFS QUALITY ASSURANCE PROGRAM SUMMARY AND CERTIFICATIONS Montrose Air Quality Services, LLC (Montrose) ensures the quality and validity of its emission measurement and reporting procedures through a rigorous quality assurance (QA) program. The program is developed and administered by internal QA personnel and encompasses seven major areas: 1. Development and use of an internal QA manual 2. QA reviews of reports, laboratory work, and field testing 3. Equipment calibration and maintenance 4. Chain of custody 5. Continuous training 6. Knowledge of current test methods 7. Agency certification Each of these areas is discussed individually below. Quality Assurance Manual. Montrose has prepared a QA Manual according to EPA guidelines and ASTM D-7036. The manual serves to document and formalize all of Montrose's QA efforts. The manual is constantly updated, and each employee involved in technical services for emission measurements is required to read, understand its contents, and sign a statement that all work they perform will conform to its practices. The manual includes details on the other seven QA areas discussed below. QA Reviews. Montrose 's review procedure includes review of each source test report by the QA Manager or equivalent position including data input, calculations and averages, and report text. The laboratory manager or equivalent reviews all laboratory work, and the qualified individual on -site reviews all field work and data sheets. The most important review is the one that takes place before a test program begins. The QA Manager works with testing personnel to prepare and review test protocols. Test protocol review includes selection of appropriate test procedures, evaluation of any interferences or other restrictions that might preclude use of standard test procedures, and evaluation and/or development of alternate procedures. Equipment Calibration and Maintenance. The equipment used to conduct the emission measurements is maintained according to the manufacturer's instructions to ensure proper operation. In addition to the maintenance program, calibrations are carried out on each measurement device according to the schedule outlined below. The schedules for maintenance and calibrations are given in Tables A-1 and A-2. Quality control checks are also conducted in the field for each test program. A partial list of checks made as part of each continuous analyzer system test series is included below as an example of the field QA procedures. • Sample acquisition and conditioning system leak check • 3 -point analyzer calibrations (all analyzers) G P043AS-007255-RT-644 377 of 381 • Complete system calibration check ("dynamic calibration" through entire sample system) • Periodic analyzer calibration checks are conducted at the start and end of each test run. Any change between pre- and post-test readings are recorded. • All calibrations are conducted using EPA Protocol gases certified by the manufacturer • Calibration and continuous analyzer performance data are fully documented, and are included in each source test report Chain of Custody. Montrose maintains full chain of custody documentation on all samples and data sheets. In addition to normal documentation of changes between field sample custodians, laboratory personnel, and field test personnel, Montrose documents every individual who handles any test component in the field (e.g., probe wash, impinger loading and recovery, filter loading and recovery, etc.). Samples are stored in a locked area to which only laboratory personnel have access. Neither other Montrose employees nor cleaning crews have keys to this area. Training. Personnel training is essential to ensure quality testing. Montrose has formal and informal training programs which may include some or all of the following: 1. Attendance at EPA -sponsored training courses 2. A requirement for all technicians to read, understand, and sign Montrose 's QA Manual 3. In-house training and Montrose meetings on a regular basis 4. Maintenance of training records 5. Administration of internal qualified individual (QI) tests for all methods performed 6. Participation in the Qualified Source Testing Individual (QSTI) program administered by the Source Evaluation Society (SES) Knowledge of Current Test Methods. With the constant updating of standard test methods and the wide variety of emerging test methods, it is essential that any qualified source tester keep abreast of new developments. Montrose subscribes to services which provide updates on EPA reference methods, and on EPA and local agency rules and regulations. Additionally, source test personnel regularly attend and present papers at testing and emission -related seminars and conferences. Audit Program. Montrose participates in the TNI Stationary Source Audit Sample (SSAS) audit program for all methods for which audit samples are available. G P043AS-007255-RT-644 378 of 381 TABLE A-1 SAMPLING INSTRUMENTS AND EQUIPMENT CALIBRATION SCHEDULE Instrument Type Frequency of Calibration1 Standard of Comparison or Method of Calibration Acceptance Limits Orifice Meter(large) Dry Gas Meter Critical Orifice S -Type Pitot (for use with EPA -type sampling train) Vacuum Gauges Temperature Measurement (thermocouples) Temperature Readout Devices Analytical Balance Probe Nozzles Continuous Analyzers 12 months 6 months or when repaired 6 months 6 months 12 months 12 months 6 months 12 months (check prior to each use) 12 months Every field day, Depends upon use, frequency and performance Calibrated dry test meter Calibrated dry test meter Calibrated dry test meter EPA Method 2 NIST-traceable gauge NBS mercury thermometer or NBS calibrated platinum RTD Thermocouple simulator NIST-traceable weights Nozzle diameter check As specified by manufacturers' operating manuals, EPA NBS gases and/or reference methods ± 2% of volume measured ± 2% of volume measured ± 0.5% of average K' Geometric measurements within method -specified ranges ≤ 1.0 in Hg difference ±4 °F for <400 °F ± 1.5% for >400 °F ± 2% full scale reading ± 0.5 mg of stated weight Range <± 0.10 mm for micrometer three measurements Satisfy all limits specified in operating specifications I The tabulated calibration frequencies are minimum standards. In certain instances, calibrations are performed more frequently. G P043AS-007255-RT-644 379 of 381 TABLE A-2 EQUIPMENT MAINTENANCE SCHEDULE Based on Manufacturer's Specifications and Montrose's Experience Equipment Performance Requirement Maintenance Interval2 Corrective Action Pumps Flow Measuring Device Sampling Instruments Mobile Van Sampling Systems Sampling Lines 1. Absence of leaks 2. Ability to draw manufacturer required vacuum and flow 1. Free mechanical movement 2. Absence of malfunction 1. Absence of malfunction 2. Proper response to zero, span gas Absence of leaks Sample degradation less than 2% 6 months 6 months As required by the manufacturer Depends on nature of use After each test or test series I. Visual inspection 2. Clean 3. Replace worn parts 4. Leak check 1. Visual inspection 2. Clean 3. Calibrate As recommended by manufacturer 1. Change filters 2. Leak check 3. Check for system contamination Blow filtered air through line until d ry 2 The tabulated maintenance intervals are minimum standards. In certain instances, maintenance is performed more frequently. G P043AS-007255-RT-644 380 of 381 Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report THIS IS THE LAST PAGE OF THIS DOCUMENT If you have any questions, please contact one of the following individuals by email or phone. Name: Jeff Goldfine Title: Client Project Manager Region: Great Plains Region, Denver Office Email: JGoldfine@montrose-env.com Phone: 312-919-2609 Name: Timothy Wojtach Title: Account Manager Region: Great Plains Region, Denver Office Email: TWojtachmontrose-env.com Phone: 303-670-0530 G P043AS-007255-RT-644 381 of 381 (y1 MONTROSE I AIR QUALIFY NI-RI:RAS Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report TABLE 1-4 SUMMARY OF AVERAGE EMISSIONS RESULTS - KILN 74 (KILN 3) APRIL 15th, 2021 Parameter/Units Average Results Total Particulate Matter (PM) lb/hr lb/ton Particulate Matter (PM1o) lb/hr lb/ton Particulate Matter (PM2.5) lb/hr lb/ton Total Particulate Matter (PM/PMIo/PM2.5) lb/hr lb/ton Opacity5 Nitrogen Oxides (NOX) lb/hr lb/ton Carbon Monoxide (CO) lb/hr lb/ton Total Hydrocarbons, as Propane (VOC) lb/hr lb/ton Methanol (MeOH) lb/hr lb/ton 5 Opacity results are calculated as the highest six -minute average observed. 0.00691 0.0604 0.0108 0.0942 0.00948 0.0828 0.0131 0.114 0.0 0.363 3.17 0.219 1.91 <0.00617 <0.0538 <0.00124 <0.0106 G P043AS-007255-RT-644 10 of 381 fisAL MONTROSE AIR QUALITY SERVICES Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report TABLE 1-3 SUMMARY OF AVERAGE EMISSIONS RESULTS - KILN 65 (KILN 1) APRIL 14th, 2021 ) L O W H U D E O H3 03 D U W L F X O D W H ODWWHU OE KU OE WRQ 30 OE OE 3 KU WRQ 0 30 3GD OE OE 2SD D 1 OE OE KU WRQ FLW &2 KU WRQ OE WRQ u 9 2 & fisAL MONTROSE AIR QUALITY SERVICES Biochar Now Berthoud, Colorado 2021 Emissions Source Test Report TABLE 1-2 SUMMARY OF AVERAGE EMISSIONS RESULTS - KILN 56 (KILN 2) APRIL 13th, 2021 Parameter/Units Average Results Filterable Particulate Matter (PM) lb/hr lb/ton Particulate Matter (PM1o) lb/hr lb/ton Particulate Matter (PM2.5) lb/hr lb/ton Total Particulate Matter (PM/PMIo/PM2.5) lb/hr lb/ton Opacity3 Nitrogen Oxides (NOX) lb/hr lb/ton Carbon Monoxide (CO) lb/hr lb/ton Total Hydrocarbons, as Propane (VOC) lb/hr lb/ton Methanol (MeOH) lb/hr lb/ton 3 Opacity results are calculated as the highest six -minute average observed. 0.00677 0.0562 0.00816 0.0677 0.00687 0.0570 0.0104 0.0862 0.0 0.425 3.53 0.179 1.49 <0.00497 <0.0412 <8.99 x 10-4 <7.47 x 10-3 G P043AS-007255-RT-644 8 of 381 fisAL MONTROSE AIR QUALITY SERVICES Notice of Inquiry Weld County Department of Planning Services Pre -application Case # PRE23-0273 Date of Inquiry 11/8/2023 4 Municipality Fort Lupton CPA Name of Person Inquiring Michael Dente Property Owner NGL Water Solutions DJ LLC Planner Diana Aungst Planner Phone Number 970-400-3524 Planner Address daungst@weld.gov 1,: Email Legal Description Lot B of RECX17-0182; N2 28 1 66 Parcel Number 147128100013 and 147128100012 Nearest Intersection CR 6 and CR 31 of Inquiry Biochar processing facility and saltwater injection facility Type 1n .. _: 'tom?: .,h .<•.. ,. L�A1Si.tr..a _:n'Xei` rE$t e SiL:^> o r " r2 .ls.'2•'2•1%AfeJL� •a.x . The above person met with County Planning staff about developing a parcel of land inside your designated Intergovernmental Agreement/Coordinated Planning Agreement Boundary. County Planner's signature Would you like to pursue annexation of this property? NO YES Date of Contact /Z�y3 y /6/i,/ Comments: (4 (s ---a-t-Et___ t e--2 ------.9-0-i--(A. ,-,-2 (9--u ( oo (c,e)r- eaf .X4 botivvrb L't tikie-4-(A, ,,i NIt l � i au Gv' ` �'P�S �n Gtil, li ^--G tini>5o,-o Cam- W -e, (-Q,L-kh- fJ✓c--- 0. C ��I // /" /tc-rt,.c / 7�0 Is -1, Signature of Municip ity Representative Title � Date Please sign and date to acknowledge that the applicant has contacted you and return this signed form to Weld County Department of Planning Services. Weld County Planning Department 1402 N 17th Ave, PO BOX 758, Greeley, CO 80632 970-400-6100 www.weld.gov 20230310 •J; """`f 17/441 144 Weld County Treasurer Statement of Taxes Due Account Number R8953432 Assessed To Parcel 147128100013 NGL WATER SOLUTIONS DJ LLC 865 ALBION ST STE 400 DENVER, CO 80220-4809 Legal Description PT N2 28-1-66 LOT 13 REC EXEMPT RECX 17-0182 Year Tax Charge 2023 Total Tax Charge Tax Interest $382.32 $0.00 Situs Address Fees Payments Balance $0 00 ($382.32) $0.00 $0.00 Grand Total Due as of 06/27/2024 $0.00 Tax Billed at 2023 Rates for Tax Area 2507 - 2507 Authority WELD COUNTY SCHOOL DIST RES-FORT LUPTON CENTRAL COLORADO WATER (CCW GREATER BRIGHTON FIRE AIMS JUNIOR COLLEGE HIGH PLAINS LIBRARY Taxes Billed 2023 * Credit Levy Mill Levy 12.0240000* 17.1970000 0.8910000 16 7440000 6 3360000 3 1960000 Amount $81 52 $11660 $6.04 $113.53 $42.96 $21.67 56.3880000 $382 32 Values AG -FLOOD 1RRR1GATED LAND AG -WASTE LAND Total Actual $25,637 $5 Assessed $6,770 $10 $25,642 $6,780 ALL TAX LIEN SALE AMOUNTS ARE SUBJECT TO CHANGE DUE TO ENDORSEMENT OF CURRENT TAXES BY THE LIENHOLDER OR TO ADVERTISING AND DISTRAINT WARRANT FEES CHANGES MAY OCCUR AND THE TREASURER'S OFFICE WILL NEED TO BE CONTACTED PRIOR TO REMITTANCE AFTER THE FOLLOWING DATES: PERSONAL PROPERTY, REAL PROPERTY, AND MOBILE HOMES - AUGUST 1. TAX LIEN SALE REDEMPTION AMOUNTS MUST BE PAID BY CASH OR CASHIER'S CHECK. POSTMARKS ARE NOT ACCEPTED ON TAX LIEN SALE REDEMPTION PAYMENTS. PAYMENTS MUST BE IN OUR OFFICE AND PROCESSED BY THE LAST BUSINESS DAY OF THE MONTH. Weld County Treasurer's Office 1400 N 17th Avenue PO Box 458 Greeley, CO 80632 Phone: 970-400-3290 Pursuant to the Weld County Subdivision Ordinance, the attached Statement of Taxes Due Issued by the Weld County Treasurer are evidence that as of this date, all current and prior year taxes related tq this parcel have been paid in full. I Signed: Date: I , m tad 1 T . Li' reel WC, weiey, Uu tiUbiel or PO Box 458, Greeley, CO 80632. (970) 400-3290 Page 1 of 1 Weld County Treasurer Statement of Taxes Due Account Number R8953431 Assessed To Legal Description PT N2 28-1-66 LOT A REC EXEMPT RECX17-0182 Parcel 147128100012 NGL WATER SOLUTIONS DJ LLC 865 ALBION ST STE 400 DENVER, CO 80220-4809 Situs Address Year Tax Charge 2023 Tax Interest $34.96 $0.00 Fees Payments Balance $0.00 ($34.96) $0,00 Total Tax Charge $0.00 Grand Total Due as of 06/27/2024 Tax Billed at 2023 Rates for Tax Area 2507 - 2507 Authority WELD COUNTY SCHOOL D1ST RE8-FORT LUPTON CENTRAL COLORADO WATER (CCW GREATER BRIGHTON FIRE AIMS JUNIOR COLLEGE HIGH PLAINS LIBRARY Taxes Billed 2023 * Credit Levy Mill Levy 12 0240000* 17 1970000 0 8910000 16 7440000 6 3360000 3.1960000 Amount $7.46 $10.66 $0.55 $1038 $393 $1 98 56.3880000 $34.96 Values AG -FLOOD IRRR]GATED LAND AG -WASTE LAND Total Actual $2,306 $2 $0.00 Assessed $610 $10 $2,308 $620 ALL TAX LIEN SALE AMOUNTS ARE SUBJECT TO CHANGE DUE TO ENDORSEMENT OF CURRENT TAXES BY THE LIENHOLDER OR TO ADVERTISING AND DISTRAINT WARRANT FEES. CHANGES MAY OCCUR AND THE TREASURER'S OFFICE WILL NEED TO BE CONTACTED PRIOR TO REMITTANCE AFTER THE FOLLOWING DATES: PERSONAL PROPERTY, REAL PROPERTY, AND MOBILE HOMES - AUGUST 1. TAX LIEN SALE REDEMPTION AMOUNTS MUST BE PAID BY CASH OR CASHIER'S CHECK. POSTMARKS ARE NOT ACCEPTED ON TAX LIEN SALE REDEMPTION PAYMENTS. PAYMENTS MUST BE IN OUR OFFICE AND PROCESSED BY THE LAST BUSINESS DAY OF THE MONTH. Weld County Treasurer's Office 1400 N 17th Avenue PO Box 458 Greeley, CO 80632 Phone: 970-400-3290 Pursuant to the Weld County Subdivision Ordinance, the attached Statement of Taxes Due issued by the Weld County Treasurer are evidence that as of this date, all current and prior year taxes related tthis parcel have been paid in full. Signed: Date: Ltfl1202if 1400 N. 17th Avenue, Greeley, CO 80631 or PO Box 458, Greeley, CO 80632. (970) 400-3290 Page 1 of 1 Hello