HomeMy WebLinkAbout20110367.tiff SITE SPECIFIC DEVELOPMENT PLAN AND USE BY SPECIAL
REVIEW (USR) APPLICATION
1 FOR PLANNING DEPARTMENT USE DATE RECEIVED.
• RECEIPT#/AMOUNT# IS CASE#ASSIGNED:
I APPLICATION RECEIVED BY PLANNER ASSIGNED:• -
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Parcel Number - j - I3
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12 digit number Mound on lax I D information.obtainable at the Weld County Assessor's Office or www co weld cc us
f • . Section Township North, Range (_-_:.J.Nest
Legal Description ._ . . .i r•�, • - •_:„.� �•. ;+,`t,r Q, T'` L.ti,
Flood Plain 1 4 Zone District . Total Acreage: /'.IL 7 ( . Overlay District:
Geological Hazard: MA- . Airport Overlay District !v ig
FEE OWNERS) OF THE PROPERTY
Name
Work Pnorie# • • • <Home Phone# ° . :•, •f; :-Email
Address •. • • •
Address:
CitylState/Zip Code • •
Name •- `
Work Phone# • . Home Phone# • • •Email • .-•(.. s.- •.V% . t t'0.1
Address-
Address
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City:StateiZip Code • t-
Name
• Work Phone# Home Phone # Email
Address •
Address.
City/State/Zip Code
APPLICANT OR AUTHORIZED AGENT (See Below.Authorrzatron must accompany applications signed by Authorized Agent)
Name Ci fi' 'Ll l 5T C r 1 K 5c tr e r.S CA. 6
Work Phone# -Home Phone# Email
Address
Address
City/State/Zip Code
PROP. SED USE ,t
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I We: hereby depose and state under penalties of perjury that all statements, proposals. and/or plans submitted
with or contained within the application are true and correct to the best of my (our)knowledge. Signatures of all fee
owners of property must sign this application If an Authorized Agent signs. a letter of authorization from all fee
owners must be included with the application. If a corporation is the fee owner, notarized evidence must be included
indig tIng that the signatory has to legal authority to sign for the orporatio .
L Signazture: Oer or Authorized Agent Date Signatur-: Owner or Au orized Date
ID
EXHIBIT
2011-0367
• We would like to be able to park up to6 trucks on our property on a regular basis
with the option of having the rest able to come in for safety meetings usually held once a
quarter. We have a total of 19 trucks.
The ones that would be parked here on a regular basis arc 3 trucks that are being
driven everyday and then there is a complete truck and tanker that is a spare unit. We
also have another spare tractor. We haul crude oil from the field tanks to the refinery,
pipeline or rail cars so our equipment is very specialized and we have the spare set ups in
case one of our other trucks goes down for major work.
The spare truck and tanker unit and the spare tractor would be parked on the far
north east side of the property. Two of the other trucks and tankers would be parked on
the east side of the shop building. One truck might be parked on the west side of the shop
if we had the 51h truck here. The spare units and 2 sets of trucks and tankers would not be
very visible because of the shop building on the one side and the trees on the other side.
We only do very minimal repair or maintenance work here. (ie: change light
bulbs, grease joints). All major work done on the trucks or tankers are done at regular
repair shops (Colorado Kenworth, Shupe's Truck Service, Beall Trailers and Kersten
Trailers).
We are required by our insurance company and federal regulations to keep our
drivers up on safety issues so we hold quarterly meetings. These are held during the day
and some of our drivers come to the meetings in between loads that they are hauling, so
would need to be able to park their truck on the property while attending these meetings.
•
•
• 1. Park up to 6 of our tanker trucks on a regular basis and have the option of being
able to have the other trucks in for safety meetings (one day) for a total of up to
20 trucks. Safety meetings are held at least once a quarter to meet federal and
insurance requirements.
2 & 3. The trucks that would park here on a regular basis would be our extra units
and the others would leave the yard at the beginning of the drivers' day and return
when done. The trucks would not be going in and out of the driveway more than one
time per day.
4. The land to the south, west and north of us is farm land and for a landscaping
business. The land to the east is a residence. There are two tank batteries around our
property also. One of these is on the west side and the other on the northeast side.
The crude oil in these tank batteries are what our trucks haul to the refinery, rail cars
or pipeline.
5.
a. On a regular basis there will be up to six drivers that come in to take their truck
out. There are also 1 or 2 office employees that would be coming in.
b. There are about 25 total employees for safety meetings only.
c. Our total operations are 24/7. but the office employees are only here 8 a.m. to 4
p.m. Monday through Friday. The drivers work different days and times depending upon
whether they work day or night shift. Day drivers start at about 3 a.m. and finish by 4
p.m. The Night shift drivers start about 2 p.m. and finish by 3 a.m.
d. N/A
e. N/A
f. The trucks are semi tractors with tanker trailers or trucks with a body tank that
pull a pup tank trailer. Each unit's empty weight is between 23,000 and 33.000.
g. Eaton, Galeton or Union Colony
h. North Weld County Water District
i. Septic permit #SP04-00297
j. N/A
6. There are trees planted on the North and West side of the property. The area around
the shop where the trucks would be parked is well maintained and graveled to prevent
ruts.
7. N/A
8. N/A
9. N/A
10. There is no storage or stockpile of wastes. There is storage of windshield washer
fluid. oil and antifreeze bottles in the shop building. There are also extra tires for the
trucks and trailers in the shop building. There are no oil changes or major repair done on
the property. The bottles stored are for use in the trucks between services. We have
MSDS sheets for all stored supplies that are in a book in the shop. There are also fire
• extinguishers and oil absorbency pads in the shop.
• RE Rod and Karen Steely updated application info 122010.txt
From: steelyks@aol .com
Sent: Monday, December 20, 2010 9:13 PM
To: Chris Gathman
subject: RE: Rod and Karen Steely
Chris Gathman
weld county Planning
There are some differences to our original application. we should only have 3
or 4 trucks parked at this location. There should only be about 2 or 3
employees coming in to take the trucks out for work. The office is also no
longer in the house so there are no employees coming and going from the
office. we also have purchased a shop so we will no longer need to have any
of our safety meetings in the shop building on this property.
Thank you.
Rod and Karen Steely
20759 Hwy 392
Greeley, CO 80631
•
Page 1
laenun KCSLULS Page 1 or 2
WELD COUNTY ASSESSOR
• PROPERTY PROFILE
Account#: R3130404 Parcel#: 080316400001
Tax Area: 3868 Bordering County:
Acres: 4.71
Township Range Section Quart. Sec. Subdivison Name Block# Lot#
06 - 65 - 16 -4 _ -
Owners Name& Address: Property Address:
STEELY RODNEY L& Street: 20759 392 HWY
20759 HWY 392 City: WELD
GREELEY, CO 80631
Additional Owners:
STEELY KAREN S
Business/Complex:
Sales Summary
Sale Date Sale Price Deed Type Reception #
4/4/2005 $482,500 WD 3274467
Legal Description
PT S2 16-6-65 LOT A REC REXEMPT RE-3779 (.29R) SITUS: 20759 392 HWY WELD 000000000
• Land Valuation Summary
Land Type Abst Code Unit of Number of Actual Value Assessed
Measure Units Value
Residential 1112 Acres 4.71
Land Subtotal: 4.71 $169,560 $13,500
Buildings Valuation Summary
Bldg# Property Type Actual Value AssesseValud
1 Residential
2 Out Building
Improvements Subtotal: $257,465 $20,490
Total Property Value $427,025 $33,990
Building Details
Account#: R3130404 Parcel#: 080316400001
Owners Name&Address: Property Address:
STEELY RODNEY L& Street: 20759 392 HWY
20759 HWY 392 City: WELD
GREELEY, CO 80631
• Building# Property Type
1 Residential
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laenuty KCSUlts Page 2 oft
Individual Built As Detail
Built As: Ranch 1 Story Year Built: 2004
• Exterior: Frame Stucco HVAC: Central Air to Air
Interior Finish: Drywall Built As SQ Ft: 2086
#of Baths: 4 Roof Type:
# of Bdrms: 5 Roof Cover: Composition Shingle
# of Stories: 1
Rooms: 0 Units: 0
Garage:
Attached SQ Ft: 650 Detached SQ Ft: 0
Basement:
Total SQ Ft: 2079 Finished SQ Ft: 1977
Account#: R3130404 Parcel#: 080316400001
Owners Name& Address: Property Address:
STEELY RODNEY L& Street: 20759 392 HWY
20759 HWY 392 City: WELD
GREELEY, CO 80631
Building# Property Type
2 Out Building
Individual Built As Detail
Built As: Shed - Utility Year Built: 2005
Exterior: HVAC: None
Interior Finish: Built As SQ Ft: 3024
# of Baths: 0 Roof Type:
# of Bdrms: 0 Roof Cover:
• #of Stories: 1
Rooms: o Units: 0
Garage:
Attached SQ Ft: Detached SQ Ft:
Basement:
Total SQ Ft: Finished SQ Ft:
•
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MATERIAL SAFETY DATA SHEET
EQUILON MSDS: 9249E-09 10/17/96
FAIIYLENE GLYCOL - ANTIFREEZE GRADE
EPHONE NUMBER:
24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE
EQUIVA SERVICES: 877-276-7283 877-276-7285
CHEMTREC: 800-424-9300
NAME AND ADDRESS
EQUILON ENTERPRISES LLC
PRODUCT STEWARDSHIP
P.O. BOX 674414
HOUSTON, TX 77267-4414
SECTION I NAME
PRODUCT: ETHYLENE GLYCOL - ANTIFREEZE GRADE
CHEM NAME: EG
CHEM FAMILY: GLYCOL
SHELL CODE: 32371 94000
HEALTH HAZARD: 3 FIRE HAZARD: 1 REACTIVITY: 0
SECTION II-A PRODUCT/INGREDIENT
NO. COMPOSITION CAS NO. PERCENT
ETHYLENE GLYCOL - ANTIFREEZE GRADE MIXTURE 100
1 ETHYLENE GLYCOL 107-21-1 90-100
2 DIETHYLENE GLYCOL 111-46-6 0-10
SECTION II-B ACUTE TOXICITY DATA
NO. ACUTE ORAL LD50 ACUTE DERMAL LD50 ACUTE INHALATION LC50
1 4 . 0 G/KG (RAT) NONE NONE
2 14 . 8 G/KG (RAT) 11 . 9 G/KG (RAT) NONE
SECTION III HEALTH INFORMATION
THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA
HAZARD COMMUNICATION STANDARD (29 CFR 1910 . 1200) .
EYE CONTACT: BASED ON PRESENCE OF COMPONENT 1, PRODUCT IS MODERATELY TO
SEVERELY IRRITATING TO THE EYES. VAPORS CAN ALSO CAUSE SEVERE
EYE IRRITATION.
SKIN CONTACT: PRODUCT IS MILDLY IRRITATING TO THE SKIN AND SLIGHTLY TOXIC ON
PROLONGED OR REPEATED CONTACT.
INHALATION: VAPORS OR AEROSOLS MAY BE MODERATELY TO SEVERELY IRRITATING TO
THE RESPIRATORY SYSTEM AND MAY BE TOXIC ON PROLONGED OR REPEATED
EXPOSURE.
STION: BASED ON PRESENCE OF COMPONENT 1, PRODUCT MAY BE HARMFUL OR FATAL
IF SWALLOWED; MAY PRODUCE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION
AND KIDNEY DAMAGE WHICH MAY BE FATAL. INGESTION OF COMPONENT 2
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MAY ALSO PRODUCE LIVER DAMAGE.
SIGNS AND SYMPTOMS: IRRITATION AS NOTED ABOVE. EARLY TO MODERATE CNS
DEPRESSION MAY BE EVIDENCED BY GIDDINESS, HEADACHE,
• DIZZINESS AND NAUSEA; IN EXTREME CASES, UNCONSCIOUSNESS
AND DEATH MAY OCCUR. KIDNEY DAMAGE MAY BE EVIDENCED BY
CHANGES IN URINE OUTPUT, URINE APPEARANCE OR EDEMA
(SWELLING FROM FLUID RETENTION) . LIVER DAMAGE MAY BE
EVIDENCED BY LOSS OF APPETITE, JAUNDICE (YELLOWISH SKIN
COLOR) AND SOMETIMES PAIN IN THE UPPER ABDOMEN ON THE
RIGHT SIDE.
AGGRAVATED MEDICAL CONDITIONS:
PREEXISTING SKIN, EYE, AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY
EXPOSURE TO THIS PRODUCT. IMPAIRED KIDNEY AND LIVER FUNCTIONS FROM
PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
OTHER HEALTH EFFECTS:
INTENTIONAL ABUSE, MISUSE OR OTHER MASSIVE EXPOSURE MAY CAUSE MULTIPLE ORGAN
DAMAGE AND/OR DEATH.
SEE SECTION VI FOR ADDITIONAL INFORMATION.
SECTION IV OCCUPATIONAL EXPOSURE LIMITS
COMP OSHA ACGIH
NO. PEL/TWA PEL/CEILING TLV/TWA TLV/STEL OTHER
1 50 PPM 39 . 4 PPM*
* CEILING (AEROSOL)
S TION V EMERGENCY AND FIRST AID PROCEDURES
EYE CONTACT: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION.
SKIN CONTACT: FLUSH SKIN WITH WATER. IF IRRITATION OCCURS, GET MEDICAL
ATTENTION.
INHALATION: REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS
DIFFICULT. GET MEDICAL ATTENTION.
INGESTION: DO NOT GIVE LIQUIDS IF VICTIM IS UNCONSCIOUS OR VERY DROWSY.
OTHERWISE, GIVE NO MORE THAN 2 GLASSES OF WATER AND INDUCE
VOMITING BY GIVING 30CC (2 TABLESPOONS) SYRUP OF IPECAC. * IF
IPECAC IS UNAVAILABLE, GIVE 2 GLASSES OF WATER AND INDUCE
VOMITING BY TOUCHING FINGER TO BACK OF VICTIM' S THROAT. KEEP
VICTIM' S HEAD BELOW HIPS WHILE VOMITING. GET MEDICAL ATTENTION.
NOTE TO PHYSICIAN: *IF VICTIM IS A CHILD, GIVE NO MORE THAN 1 GLASS OF WATER
AND 15CC (1 TABLESPOON) SYRUP OF IPECAC. IF SYMPTOMS SUCH
AS LOSS OF GAG REFLEX, CONVULSIONS OR UNCONSCIOUSNESS OCCUR
BEFORE EMESIS, GASTRIC LAVAGE SHOULD BE CONSIDERED
FOLLOWING INTUBATION WITH A CUFFED ENDOTRACHEAL TUBE.
SECTION VI SUPPLEMENTAL HEALTH INFORMATION
CASE REPORTS OF SENSITIZATION (ALLERGY) HAVE BEEN PUBLISHED BUT ALLERGY TO
ETHYLENE GLYCOL IS NOT A COMMON PHENOMENON.
IN ONE STUDY, WHEN ETHYLENE GLYCOL WAS ADMINISTERED IN THE DIET AT DAILY DOSES
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UP TO 1 . 0 G/KG TO PREGNANT RATS, NO MATERNAL TOXICITY, NO EMBRYOTOXICITY NOR
TERATOGENICITY WERE OBSERVED. IN A MORE RECENT STUDY, WHEN ETHYLENE GLYCOL WAS
ADMINISTERED BY GAVAGE AT DAILY DOSES OF 1 . 25 G/KG AND ABOVE TO PREGNANT RATS,
T 750 MG/KG AND ABOVE TO PREGNANT MICE, THERE WAS AN INCREASE IN THE NUMBER
O MALFORMED FETUSES AT ALL DOSE LEVELS. EXCEPT AT THE LOWEST DOSE LEVEL IN
MICE, THERE WAS ALSO EVIDENCE OF MATERNAL TOXICITY AT ALL DOSE LEVELS.
IN ONE STUDY, DIETHYLENE GLYCOL ADMINISTERED ORALLY AT HIGH DOSES TO PREGNANT
RATS AND MICE CAUSED TOXICITY TO THE EMBRYOFETUS INCLUDING DECREASED FETAL BODY
WEIGHTS AND INCREASED VARIATIONS, BUT NO BIRTH DEFECTS WERE OBSERVED. THERE
WAS ALSO MATERNAL TOXICITY INCLUDING SOME LETHALITY.
IN ANOTHER STUDY, DIETHYLENE GLYCOL ADMINISTERED TO HAMSTERS BY I . P. INJECTION
AT DOSES OF 2 . 5 - 4 . 48 G/KG ON THE 8TH DAY OF GESTATION RESULTED IN NEURAL TUBE
ABNORMALITIES IN ALL DOSE GROUPS BUT NOT IN THE CONTROLS. THERE WAS EVIDENCE
OF MATERNAL TOXICITY IN TREATED ANIMALS. UNDER THE CONDITIONS OF THIS STUDY,
DEG CAUSED DEVELOPMENTAL EFFECTS IN HAMSTERS. THE SIGNIFICANCE OF THIS
INFORMATION TO MAN IS UNKNOWN.
SECTION VII PHYSICAL DATA
BOILING POINT (DEG F) : SPECFIC GRAVITY (H2O = 1) : VAPOR PRESSURE (MM HG) :
374-464 1 . 12 @ . 06 @ 68 DEG F
60 DEG. F
MELTING POINT (DEG F) : SOLUBILITY IN WATER: VAPOR DENSITY (AIR = 1) :
9 COMPLETE 2 . 1
VOC: 100%
9 . 308 LB/GAL
4IPORATION RATE (NORMAL BUTYL ACETATE = 1) :<0 . 01
APPEARANCE AND ODOR:COLORLESS, SLIGHTLY VISCOUS LIQUID. MILD ODOR.
PHYS/CHEM PROPERTIES: SEE ABOVE FOR DETAILS
SECTION VIII FIRE AND EXPLOSION HAZARDS
FLASH POINT AND METHOD: 250 DEG F TCC
FLAMMABLE LIMITS/PERCENT VOLUME IN AIR: LOWER: N/AP HIGHER: N/AP
EXTINGUISHING MEDIA:
USE WATER FOG, "ALCOHOL" FOAM, DRY CHEMICAL OR CO2 .
SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS:
MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE SPACE
WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES AND
RUBBER BOOTS) , INCLUDING A POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED
BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
NONE IDENTIFIED
SECTION IX REACTIVITY
STABLITY: STABLE HAZARDOUS POLYMERIZATION WILL NOT OCCUR
CONDITIONS AND MATERIALS TO AVOID:
AEEP AWAY FROM STRONG OXIDIZING AGENTS.
DOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING
COMBUSTION.
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SECTION X EMPLOYEE PROTECTION
IRATORY PROTECTION:
F EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SEC. IV) USE A
NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR
1910 . 134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING
RESPIRATOR FOR ORGANIC VAPORS.
PROTECTIVE CLOTHING
AVOID CONTACT WITH EYES. WEAR CHEMICAL GOGGLES IF THERE IS LIKELIHOOD OF
CONTACT WITH EYES. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. WEAR
CHEMICAL-RESISTANT GLOVES AND OTHER CLOTHING AS REQUIRED TO MINIMIZE CONTACT.
TEST DATA FROM PUBLISHED LITERATURE AND/OR GLOVE AND CLOTHING MANUFACTURERS
INDICATE THE BEST PROTECTION IS PROVIDED BY NITRILE, NEOPRENE, PVC OR NATURAL
RUBBER GLOVES.
ADDITIONAL PROTECTIVE MEASURES :
USE VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS. EYE WASH
FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE FOR EMERGENCY USE.
SECTION XI ENVIRONMENTAL PROTECTION
SPILL OR LEAK PROCEDURES:
MAY BURN ALTHOUGH NOT READILY IGNITABLE. USE CAUTIOUS JUDGMENT WHEN CLEANING
UP LARGE SPILLS. *** LARGE SPILLS *** WEAR RESPIRATOR AND PROTECTIVE
CLOTHING AS APPROPRIATE. SHUT OFF SOURCE OF LEAK IF SAFE TO DO SO. DIKE AND
CONTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK
RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND OR OTHER SUITABLE MATERIAL;
ISPOSE OF PROPERLY. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE. ***
SMALL SPILLS *** TAKE UP WITH AN ABSORBENT MATERIAL AND DISPOSE OF PROPERLY.
SECTION XII SPECIAL PRECAUTIONS
STORE IN A COOL, DRY PLACE WITH ADEQUATE VENTILATION. KEEP AWAY FROM FLAMES
AND HIGH TEMPERATURES .
WASH WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET
FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
DO NOT PRESSURIZE DRUM CONTAINERS TO EMPTY THEM.
NOT FOR USE IN THE MANUFACTURE OF FOODS OR PHARMACEUTICALS.
SECTION XIII TRANSPORTATION REQUIREMENTS
DEPARTMENT OF TRANSPORTATION CLASSIFICATION:
CLASS 9 (OTHER REGULATED SUBSTANCES) , III
DOT PROPER SHIPPING NAME:OTHER REGULATED SUBSTANCES, LIQUID, N.O. S. (CONTAINS
ETHYLENE GLYCOL)
OTHER REQUIREMENTS:NA3082 , GUIDE 171 . REGULATED ONLY IN PACKAGES THAT CONTAIN
5000 LBS OR GREATER OF ETHYLENE GLYCOL.
•TION XIV OTHER REGULATORY CONTROLS
THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL
SUBSTANCES.
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PROTECTION OF STRATOSPHERIC OZONE (PURSUANT TO SECTION 611 OF THE CLEAN AIR ACT
' AMENDMENTS OF 1990) : PER 40 CFR PART 82 , THIS PRODUCT DOES NOT CONTAIN NOR WAS
IT DIRECTLY MANUFACTURED WITH ANY CLASS I OR CLASS II OZONE DEPLETING
iliSTANCES.
ACCORDANCE WITH SARA TITLE III, SECTION 313, THE ATTACHED ENVIRONMENTAL DATA
SHEET (EDS) SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS.
SECTION XV STATE REGULATORY INFORMATION
THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES; OTHER PRO
UCT SPECIFIC HEALTH AND SAFETY DATA IN OTHER SECTIONS OF THE MSDS MAY ALSO BE A
PLICABLE FOR STATE REQUIREMENTS. FOR DETAILS ON YOUR REGULATORY REQUIREMENTS Y
U SHOULD CONTACT THE APPROPRIATE AGENCY IN YOUR STATE.
STATE LISTED COMPONENT CAS NO PERCENT STATE CODE
ETHYLENE GLYCOL 107-21-1 90-100 CA, CT, FL, IL,
LA, MA, ME, MN,
NJ, PA, RI
DIETHYLENE GLYCOL 111-46-6 0-10 CA, MN, PA, RI
CA = CALIFORNIA HAZ. SUBST. LIST; CA65C, CA65R, CA65C/R = CALIFORNIA SAFE
DRINKING WATER AND TOXICS ENFORCEMENT ACT OF 1986 OR PROPOSITION 65 LIST; CT =
CONNECTICUT TOXIC. SUBST. LIST; FL = FLORIDA SUBST. LIST; IL = ILLINOIS TOX.
SUBST. LIST; LA = LOUISIANA HAZ . SUBST. LIST; MA = MASSACHUSETTS SUBST.
LIST; ME = MAINE HAZ. SUBST. LIST; MN = MINNESOTA HAZ . SUBST. LIST; NJ =
NEW JERSEY HAZ . SUBST. LIST; PA = PENNSYLVANIA HAZ. SUBST. LIST; RI = RHODE
ISLAND HAZ. SUBST. LIST.
S•TION XVI SPECIAL NOTES
THIS MSDS REVISION HAS CHANGES IN SECTIONS XII AND XIII.
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE
TO US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED
HEREIN. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY,
PROCESS, USE OR DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY
COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH
RESPECT TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE
APPROPRIATE GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH
MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT
DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN
AS A RESULT OF THAT DATA, IS THE PROPERTY OF EQUIVA SERVICES, LLC AND IS NOT TO
BE THE SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF
IVA SERVICES, LLC.
ENVIRONMENTAL DATA SHEET
EQUILON EDS: 9249E
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ETHYLENE GLYCOL - ANTIFREEZE GRADE
' TELEPHONE NUMBER:
24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE
• EQUIVA SERVICES: 877-276-7283 877-276-7285
CHEMTREC: 800-424-9300
NAME AND ADDRESS
EQUILON ENTERPRISES
PRODUCT STEWARDSHIP
P.O. BOX 674414
HOUSTON, TX 77267-4414
PRODUCT CODE: 94000
SECTION I PRODUCT COMPOSITION
NO. COMPOSITION CAS PERCENT
P ETHYLENE GLYCOL - ANTIFREEZE GRADE MIXTURE 100
1 ETHYLENE GLYCOL 107-21-1 90-100
2 DIETHYLENE GLYCOL 111-46-6 0-10
SECTION II SARA TITLE III INFORMATION
NO. EHS RQ EHS TPQ SEC-313 313 CATEGORY 311/312 CATEGORY
(*1) (*2) (*3 ) (*4) (*5)
P H-1, H-2
• YES
*1 = REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE, SEC 302
*2 = THRESHOLD PLANNING QUANTITY, EXTREMELY HAZARDOUS SUBSTANCE, SEC 302
*3 = TOXIC CHEMICAL, SEC 313
*4 = CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372 . 65 C) , MUST BE USED ON TOXIC
RELEASE INVENTORY FORM
*5 = CATEGORY (FOR AGGREGATE REPORTING REQUIREMENTS UNDER SARA 311, 312)
HEALTH: H-1 = IMMEDIATE (ACUTE) HEALTH HAZARD
H-2 = DELAYED (CHRONIC) HEALTH HAZARD
PHYSICAL: P-3 = FIRE HAZARD
P-4 = SUDDEN RELEASE OF PRESSURE HAZARD
P-5 = REACTIVE HAZARD
SECTION III ENVIRONMENTAL RELEASE INFORMATION
EPA - COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT.
UNDER EPA-CERCLA ( "SUPERFUND" ) RELEASES TO AIR, LAND OR WATER WHICH EXCEED
THE REPORTABLE QUANTITY MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER,
800-424-8802 .
THE REPORTABLE QUANTITY (RQ) FOR A RELEASE OF THIS PRODUCT IS 5, 000 LBS. ,
WHICH IS BASED ON THE PRESENCE OF COMPONENT #1 .
AllPION IV RCRA INFORMATION
IF THIS PRODUCT BECOMES A WASTE, IT WOULD NOT BE A HAZARDOUS WASTE BY RCRA
http://www.equivashellmsds.com/msds.asp?id=170707(6of7)[1/14/2002 12:34:14 PM]
• CRITERIA (40 CFR 261) . PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN
COMPLIANCE WITH LOCAL REGULATIONS.
isINFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS
IEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED
REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE
THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE
PRODUCT DESCRIBED HEREIN.
SHELL OIL COMPANY
P.O. BOX 4320
HOUSTON, TX 77210
FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE CALL
(713) 241-2252
FOR EMERGENCY ASSISTANCE PLEASE CALL
SHELL: (713 ) 473-9461
CHEMTREC: (800) 424-9300
}
•
•
http://www.equivashellmsds.com/msds.asp?id=170707(7 of 7)[1/14/2002 12:34:14 PM]
• EnCana Corporation Material Safety Data Sheet Crude Oil(Sweet) Page I of 2
SECTION 1 -MATERIAL IDENTIFICATION AND USE
Material Name: CRUDE OIL(SWEET)
Use: Process stream,fuels and lubricants production
WHMIS Classification: Class B,Div.2; Class D,Div.2,Sub-Div. A and B
Fire: 4 Reactivity: 0 Health: 3 Inventory No.:
TDG: UN: 1267 Class: 3
Packing Group: I(boiling point less than 35 deg.C)
11(boiling point 35 deg.C or above,and flash point less than 23 deg.C)
Shipping Name: PETROLEUM CRUDE OIL
Manufacturer/Supplier: ENCANA CORPORATION
#1800,855-2n°Street S.W.,P.O. BOX 2850
CALGARY,ALBERTA,T2P 2S5
Emergency Telephone: 403-645-3333
Chemical Family: Complex mixture of aliphatic and aromatic hydrocarbons.
SECTION 2-HAZARDOUS INGREDIENTS OF MATERIAL
Hazardous Approximate C.A.S. LD50/LCS0 Exposure
Ingredients Concentrations(%) Nos. Specify Species Limits
& Route
Crude oil 100 8002-05-9 LD50,rat,skin,>2 g/kg 5 mg/m3(OEL)
Benzene 0.1 71-43-2 LD50,rat,oral,930 mg/kg 1 ppm(OEL),
LC50,rat,4 hr,13200 ppm 0.5 ppm(TLV)
• OEL=8 hr.Alberta Occupational Exposure Limit;TLV=Threshold Limit Value(8 hrs)
SECTION 3-PHYSICAL DATA FOR MATERIAL
Physical State: Liquid Vapour Pressure(mmHg):0.5-200 @ 20 deg.C.
Specific Gravity: 0.7-0.95 Odour Threshold(ppm): N.Av.
Vapour Density(air-1): 2.5-5.0 Evaporation Rate: N.Av.
Percent Volatiles,by volume: N.Av. Boiling Pt.(deg.C): 38-570
pH: N.Av. Freezing Pt.(deg.C):<-40
Coefficient of Water/Oil Distribution: <0.1
Odour& Appearance: brown/black/green viscous liquid,hydrocarbon odour
(N.AV.=not available N.App.=not applicable)
SECTION 4-FIRE AND EXPLOSION
Flammability: Yes Conditions: Material will ignite at normal temperatures.
Means of Extinction: Foam,CO2,dry chemical. Explosive accumulations can build up in areas of poor ventilation.
Special Procedures: Use water spray to cool fire-exposed containers,and to disperse vapors if spill has not
ignited. Cut off fuel and allow flame to burn out.
Flash Point(deg.C)&Method: <-40 to 60(TCC)
Upper Explosive Limit(%by vol.): 8 Sensitivity to Impact: No
Lower Explosive Limit(%by vol.): 0.8 Sensitivity to Static Discharge: Yes,may ignite
Auto-Ignition Temp.(deg.C): >260 TDG Flammability Classification: 3
Hazardous Combustion Products:Carbon monoxide,carbon dioxide
SECTION 5—REACTIVITY DATA
• Chemical Stability: Yes Conditions: Heat
Incompatibility: Yes Substances: Oxidizing agents(eg.chlorine)
Reactivity: Yes Conditions: Heat,strong sunlight
Hazardous Decomposition Products: Carbon monoxide,carbon dioxide
i
• Encana Corporation Material Safety Data Sheet Crude Oil(Sweet) Page 2 of 2
SECTION 6-TOXICOLOGICAL PROPERTIES OF PRODUCT
Routes of Entry:
Skin Absorption: Yes Skin Contact:Yes(liquid) Eye Contact: Yes
Inhalation: Acute: Yes Chronic: Yes Ingestion: Yes
Effects of Acute Exposure:Vapour may cause irritation of eyes,nose and throat,dizziness and drowsiness. Contact with
skin may cause irritation and possibly dermatitis. Absorbed through intact skin. Contact of liquid with eyes may cause
severe irritation.
Effects of Chronic Exposure: Due to presence of benzene and n-hexane,long term exposure may increase the risk of
anaemia,leukemia and nervous system damage.
Sensitization to Product: No.
Exposure Limits of Product: 1 ppm (Alberta 8 hr OEL for benzene)
Irritancy: Yes
Synergistic Materials: None reported
Carcinogenicity: Yes Reproductive Effects: Possibly Teratogenicity: Possibly Mutagenicity: Possibly
SECTION 7-PREVENTIVE MEASURES
Personal Protective Equipment: Use positive pressure self-contained breathing apparatus,supplied air breathing
apparatus,or cartridge respirator approved for organic vapours where concentrations may exceed exposure limits(note:
cartridge respirator not suitable for oxygen deficiency or IDLH situations).
Gloves: Viton(nitrite adequate for short exposure to liquid)
Respiratory: SCBA,SABA or cartridge respirator approved for organic vapours
Eye: Chemical splash goggles
Footwear: As per safety policy Clothing: As per fire protection policy
• Engineering Controls: Use only in well ventilated areas. Mechanical ventilation required in confined areas. Equipment
must be explosion proof.
Leaks&Spills: Stop leak if safe to do so.Use personal protective equipment. Use water spray to cool containers.
Remove all ignition sources. Provide explosion-proof clearing ventilation,if possible. Prevent from entering confined
spaces. Dyke and pump into containers for recycling or disposal. Notify appropriate regulatory authorities.
Waste Disposal: Contact appropriate regulatory authorities for disposal requirements.
Handling Procedures&Equipment: Avoid contact with liquid. Avoid inhalation. Bond and ground all transfers.
Avoid sparking conditions.
Storage Requirements: Store in a cool,dry,well ventilated area away from heat,strong sunlight,and ignition sources.
Special Shipping Information: N.Av.
SECTION 8-FIRST AID MEASURES
Skin: Flush skin with water,removing contaminated clothing. Get medical attention if irritation persists or
large area of contact. Decontaminate clothing before re-use.
Eye: Immediately flush with large amounts of luke warm water for 15 minutes,lifting upper and lower lids at
intervals. Seek medical attention if irritation persists.
Inhalation: Ensure own safety.Remove victim to fresh air. Give oxygen,artificial respiration,or CPR if needed.
Seek medical attention immediately.
Ingestion: Give 2-3 glasses of milk or water to drink. DO NOT INDUCE VOMITING. Keep warm and at rest.
Get immediate medical attention.
SECTION 9-PREPARATION DATE OF MSDS
• Prepared By: EnCana Environment,Health and Safety(EHS)
Phone Number: (403)645-2000 Preparation Date: July 10,2008 Expiry Date:July 10,2011
n' noble MATERIAL SAFETY DATA SHEET
• % energy
• 1. Product and Company Identification
Material name Crude Oil
Version# 02
Revision date 01-06-2009
Product use Fuel
Manufacturer/Supplier Noble Energy, Inc.
100 Glenborough Dr., Suite 100
Houston,TX 77067 US
24-hour Contact Phone Number: 1-760-476-3962(access code is
333053)
2. Hazards Identification
Emergency overview WARNING! Flammable.Will be easily ignited by heat,spark or flames.
Aspiration hazard: Harmful or fatal if swallowed. Can enter lungs and cause damage. Causes skin
and eye irritation.
OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200(Hazard Communication).
Potential health effects
Routes of exposure Inhalation. Ingestion. Skin contact. Eye contact.
Eyes Causes eye irritation. Eye contact may result in corneal injury. Do not get this material in contact
with eyes.
Skin Causes skin irritation. Do not get this material in contact with skin.
Inhalation Irritating to respiratory system. May cause cancer by inhalation. Prolonged inhalation may be
harmful. Do not breathe dust/fume/gas/mist/vapors/spray.Vapors may cause drowsiness and
dizziness.
• Ingestion Do not ingest. Harmful or fatal if swallowed. Can enter lungs and cause damage.Components of
the product may be absorbed into the body by ingestion.
Target organs Blood. Bone. Central nervous system. Eyes. Respiratory system. Skin.
Chronic effects Cancer hazard. Possible risk of harm to the unborn child. Possible risk of impaired fertility. May
cause damage to the liver and kidneys. Prolonged skin contact may defat the skin and produce
dermatitis. Conjunctiva. May cause central nervous system disorder(e.g., narcosis involving a
loss of coordination, weakness,fatigue, mental confusion,and blurred vision)and/or damage.
Cyanosis. Unconsciousness.
Signs and symptoms Irritation of nose and throat. Irritation of eyes and mucous membranes. Unconsciousness.
Corneal damage. Narcosis. Cyanosis. Decrease in motor functions. Behavioral changes.
Conjunctivitis. Defatting of the skin. Rash. Irritation.
Potential environmental effects Components of this product are hazardous to aquatic life.
3. Composition / Information on Ingredients
Components CAS# Percent
Petroleum Distillate 8002-05-9 >95
Hexane 110-54-3 0.9-1.5
Benzene 71-43-2 0.5-2
Ethylbenzene 100-41-4 0-1
4. First Aid Measures
First aid procedures
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Get medical attention.
• Skin contact Remove contaminated clothes and rinse skin thoroughly with water for at least 15 minutes. Get
medical attention if irritation develops or persists.
Material name:Crude Oil CPH MSDS HE
1522 Version#:02 Revision date:01-06-2009 Print date:03-31-2009 1/f
Inhalation Move injured person into fresh air and keep person calm under observation. If breathing is
difficult, give oxygen. Get medical attention immediately.
Ingestion Give one or two glasses or water if patient is alert and able to swallow. Seek immediate medical
attention. Do not induce vomiting.
• Notes to physician Oxygen, if needed. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
General advice In case of shortness of breath, give oxygen. Ensure that medical personnel are aware of the
material(s)involved, and take precautions to protect themselves. Keep victim under observation.
Keep victim warm. If exposed or concerned: get medical attention/advice.
5. Fire Fighting Measures
Flammable properties Containers may explode when heated. Flammable by OSHA criteria. Runoff to sewer may cause
fire or explosion hazard.
Extinguishing media
Suitable extinguishing Water.Water fog. Foam. Dry chemical powder. Carbon dioxide(CO2).
media
Unsuitable extinguishing Do not use a solid water stream as it may scatter and spread fire.
media
Protection of firefighters
Specific hazards arising Fire may produce irritating, corrosive and/or toxic gases.
from the chemical
Protective equipment and In case of fire and/or explosion do not breathe fumes.Wear full protective clothing, including
precautions for firefighters helmet, self-contained positive pressure or pressure demand breathing apparatus, protective
clothing and face mask. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters
(1/2 mile) in all directions; also consider initial evacuation for 800 meters(1/2 mile)in all
directions.ALWAYS stay away from tanks engulfed in flame. Fight fire from maximum distance or
use unmanned hose holders or monitor nozzles.Withdraw immediately in case of rising sound
from venting safety devices or any discoloration of tanks due to fire. Move containers from fire
area if you can do it without risk. Use water spray to cool unopened containers. Cool containers
with flooding quantities of water until well after fire is out. For massive fire, use unmanned hose
holders or monitor nozzles; if this is impossible,withdraw from area and let fire bum.
Specific methods In the event of fire and/or explosion do not breathe fumes. In the event of fire, cool tanks with
water spray. Use water spray to cool unopened containers.
• 6. Accidental Release Measures
Personal precautions Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Keep people away from
and upwind of spill/leak.Ventilate closed spaces before entering. Ensure adequate ventilation. Do
not touch damaged containers or spilled material unless wearing appropriate protective clothing.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Methods for containment Eliminate all ignition sources(no smoking,flares, sparks, or flames in immediate area). Stop the
flow of material, if this is without risk. Prevent entry into waterways, sewers, basements or
confined areas. Dike the spilled material,where this is possible.
Methods for cleaning up Wipe up with absorbent material (e.g. cloth,fleece). Should not be released into the environment.
Large Spills: Dike far ahead of liquid spill for later disposal. Use a non-combustible material like
vermiculite, sand or earth to soak up the product and place into a container for later disposal.
Small Spills: Clean contaminated surface thoroughly.After removal flush contaminated area
thoroughly with water. This material and its container must be disposed of as hazardous waste.
Never return spills in original containers for re-use.
Other information Clean up in accordance with all applicable regulations.
7. Handling and Storage
Handling Avoid exposure-obtain special instructions before use. Do not empty into drains. Keep away from
sources of ignition-No smoking. Do not smoke.Wear personal protective equipment. May be
ignited by open flame.Vapors may form explosive mixtures with air.Avoid contact with skin. Do
not breathe dust/fume/gas/mist/vapors/spray.Avoid release to the environment. Do not get this
material in contact with eyes. Use only with adequate ventilation.Avoid prolonged exposure. Do
not handle or store near an open flame, heat or other sources of ignition.All equipment used
when handling the product must be grounded.Wash thoroughly after handling.
•
Material name:Crude Oil cPH MSOS US
1522 Version#:02 Revision date:01-06-2009 Print date:03-31-2009 2/8
Storage Avoid exposure-obtain special instructions before use. The pressure in sealed containers can
increase under the influence of heat. Do not handle or store near an open flame, heat or other
sources of ignition. This material can accumulate static charge which may cause spark and
become an ignition source. Prevent electrostatic charge build-up by using common bonding and
grounding techniques. Store in cool place. Keep in a well-ventilated place. Keep container tightly
closed. Keep in an area equipped with sprinklers. Keep this material away from food, drink and
• animal feed. Keep out of the reach of children. Use care in handling/storage.
8. Exposure Controls/ Personal Protection
Occupational exposure limits
ACGIH
Components Type Value
Benzene(7143-2) STEL 2.5 ppm
TWA 0.5 ppm
Ethylbenzene(100-41-4) STEL 125 ppm
TWA 100 ppm
Hexane(110-54-3) TWA 50 ppm
U.S. -OSHA
Components Type Value
Benzene(71-43-2) Ceiling 25 ppm
STEL 5 ppm
TWA 10 ppm
Ethylbenzene(100-41-4) PEL 100 ppm
435 mg/m3
STEL 545 mg/m3
125 ppm
TWA 435 mg/m3
100 ppm
Hexane(110-54-3) PEL 500 ppm
1800 mg/m3
TWA 180 mg/m3
50 ppm
• Engineering controls Use process enclosures, local exhaust ventilation,or other engineering controls to control
airborne levels below recommended exposure limits. Provide adequate ventilation and minimize
the risk of inhalation of vapors and mists.
Personal protective equipment
Eye/face protection Wear approved safety goggles.
Skin protection Apron and long sleeves are recommended.
Respiratory protection Avoid exposure-obtain special instructions before use.Wear positive pressure self-contained
breathing apparatus(SCBA).Avoid breathing dust/fume/gas/mist/vapors/spray. If engineering
controls do not maintain airborne concentrations below recommended exposure limits(where
applicable)or to an acceptable level(in countries where exposure limits have not been
established), an approved respirator must be worn. In the United States of America, if respirators
are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152,
January 8, 1998. Respirator type: High-efficiency particulate respirator. Seek advice from local
supervisor.
General hygiene When using, do not eat, drink or smoke.Always observe good personal hygiene measures, such
considerations as washing after handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove contaminants. Do not get this material in
contact with eyes. Avoid contact with skin. Keep away from food and drink. Handle in accordance
with good industrial hygiene and safety practice.
9. Physical & Chemical Properties
Appearance Liquid.
Color Gold.
Odor Aromatic.
Odor threshold Not available.
• Physical state Liquid.
Form Liquid.
Material name:Crude Oil CPH MSDS US
1522 Version#:02 Revision date:01-06-2009 Print date:03-31-2009 3/8
pH Not available.
Melting point Not available.
Freezing point Not available.
Boiling point 50- 1099.4°F(10-593°C)
• Flash point <80°F(<26.7°C)
Evaporation rate Not available.
Flammability Not available.
Flammability limits in air, 10
upper,%by volume
Flammability limits in air, 1
lower,%by volume
Vapor pressure <500 mmHg @ 60°F
Vapor density Not available.
Specific gravity Not available.
Relative density Not available.
Solubility(water) Insoluble
Partition coefficient Not available.
(noctanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
10. Chemical Stability & Reactivity Information
Chemical stability Stable under normal temperature conditions.
Conditions to avoid Heat, flames and sparks.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition Carbon monoxide.
products
• Possibility of hazardous Hazardous polymerization does not occur.
reactions
11. Toxicological Information
Toxicological data
Product Test Results
Crude Oil Acute Other LD50 Mouse:29574 mg/kg estimated
Components Test Results
Ethylbenzene(100-41-4) Acute Dermal LD50 Rabbit: 17800 mg/kg
Acute Oral LD50 Rat: 3500 mg/kg
Acute Other LD50 Mouse: 2272 mg/kg
Hexane(110-54-3) Acute Dermal LD50 Rabbit: >2 g/kg
Acute Oral LD50 Rat: 24 g/kg
Benzene(7143-2) Acute Inhalation LC50 Mouse: 9980 mg/I
Acute Inhalation LC50 Rat: 10000 mg/I 7 Hours
Acute Oral LD50 Mouse:4700 mg/kg
Acute Oral LD50 Rat: 3306 mg/kg
Acute Other LD50 Rat: 2890 pg/kg
Sensitization Not available.
US ACGIH Threshold Limit Values:Skin designation
Benzene(CAS 71-032) Can be absorbed through the skin.
Hexane(CAS 110-54-3) Can be absorbed through the skin.
Acute effects Causes skin,eye and respiratory tract irritation.
• Chronic effects Hazardous by OSHA criteria. Prolonged inhalation may be harmful. Repeated absorption may
cause disorder of central nervous system,liver, kidneys and blood. Prolonged exposure may
cause chronic effects.
Material name:Crude Oil can MSDS US
1522 Version#:02 Revision date:01-06-2009 Print date:03-31-2009 4/8
•
Subchronic effects Blood disorder may occur after ingestion. Blood disorder may occur after prolonged inhalation.
Blood disorder may occur after prolonged skin contact.
Carcinogenicity Hazardous by OSHA criteria. Cancer hazard.
ACGIH Carcinogens
• Benzene(CAS 71-43-2) Group Al Confirmed human carcinogen.
Ethylbenzene(CAS 100-41-4) Group A3 Confirmed animal carcinogen with unknown relevance
to humans.
IARC Monographs.Overall Evaluation of Carcinogenicity
Benzene(CAS 71-43-2) 1 Human carcinogen.
Ethylbenzene(CAS 100-41-4) 2B Possible carcinogen.
Petroleum Distillate(CAS 8002-05-9) 3 Classification not possible from current data.
US NTP Report on Carcinogens: Known carcinogen
Benzene(CAS 71-43-2) Known carcinogen.
US OSHA Specifically Regulated Substances:Cancer hazard
Benzene(CAS 71-43-2) Cancer hazard.
Epidemiology Hazardous by OSHA criteria.
Mutagenicity Not available.
Neurological effects Hazardous by OSHA criteria.
Reproductive effects Avoid exposure to women during early pregnancy.
Teratogenicity Not available.
Further information Symptoms may be delayed.
12. Ecological Information
Ecotoxicological data
Components Test Results
Ethylbenzene(100-41-4) EC50 Water flea(Daphnia magna): 1.37-4.4 mg/I 48 Hours
LC50 Rainbow trout,donaldson trout(Oncorhynchus mykiss):
4.2 mg/I 96 Hours
Hexane(110-54-3) LC50 Fathead minnow(Pimephales promelas):2.101 -2.981
• mg/I 96 Hours
Benzene(71-43-2) EC50 Water flea(Daphnia magna): 8.76-15.6 mg/I 48 Hours
LC50 Rainbow trout,donaldson trout(Oncorhynchus mykiss):
5.3 mg/I 96 Hours
Petroleum Distillate(8002-05-9) LC50 Cutthroat trout(Oncorhynchus clarki): 2.1 -4.3 mg/I 96
Hours
Ecotoxicity Components of this product are hazardous to aquatic life.
Persistence and degradability Not available.
Bioaccumulation I No data available.
Accumulation
Mobility in environmental No data available.
media
13. Disposal Considerations
Waste codes D018:Waste Benzene
D001:Waste Flammable material with a flash point<140 F
US RCRA Hazardous Waste U List:Reference
Benzene(CAS 71-43-2) U019
Disposal instructions Dispose of this material and its container at hazardous or special waste collection point.
Incinerate the material under controlled conditions in an approved incinerator. Must be incinerated
in a suitable incineration plant holding a permit delivered by the competent authorities. Do not
dispose of waste into sewer. Do not allow this material to drain into sewers/water supplies.
Dispose in accordance with all applicable regulations.
14. Transport Information
DOT
• Basic shipping requirements:
UN number UN1267
Proper shipping name Petroleum crude oil
Material name:Crude Oil GPH MSDS U`.
1522 Version#:02 Revision date:01-06-2009 Print date:03-31-2009 5/1
Hazard class Packing 3
group Additional III
information:
Special provisions 144, B1, 153, T2,TP1
• Packaging exceptions 150
Packaging non bulk 203
Packaging bulk 242
ERG number 128
IATA
Basic shipping requirements:
UN number 1267
Proper shipping name Petroleum crude oil
Hazard class 3
Packing group Ill
IMDG
Basic shipping requirements:
UN number 1267
Proper shipping name PETROLEUM CRUDE OIL
Hazard class 3
Packing group III
FLAMMABLE • •
3
• DOT IATA IMDG
15. Regulatory Information
US federal regulations This product is a"Hazardous Chemical"as defined by the OSHA Hazard Communication
Standard,29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
US EPCRA(SARA Title III)Section 313-Toxic Chemical:De minimis concentration
Benzene(CAS 71-43-2) 0.1 %
Ethylbenzene(CAS 10041-4) 0.1 %
Hexane(CAS 110-54-3) 1.0%
Petroleum Distillate(CAS 8002-05-9) 0.1 %N590 Substance is not eligible for the de minimis exemption
except for the purposes of supplier notification requirements.
US EPCRA(SARA Title III)Section 313-Toxic Chemical:Listed substance
Benzene(CAS 71-43-2) Listed.
Ethylbenzene(CAS 100-414) Listed.
Hexane(CAS 110-54-3) Listed.
Petroleum Distillate(CAS 8002-05-9) N590 Listed.
US EPCRA(SARA Title III)Section 313-Toxic Chemical: Reportable threshold
Petroleum Distillate(CAS 8002-05-9) 100 LBS N590
CERCLA(Superfund)reportable quantity(Ibs)
Petroleum Distillate: 100
Hexane: 5000
Benzene: 10
Ethylbenzene: 1000
• Material name:Crude Oil CPH MSDS Ut
1522 Version#:02 Revision date:01-06-2009 Print date:03-31-2009 61 E
Superfund Amendments and Reauthorization Act of 1986(SARA)
Hazard categories Immediate Hazard-Yes
Delayed Hazard-Yes
Fire Hazard-Yes
• Pressure Hazard-No
Reactivity Hazard-No
Section 302 extremely No
hazardous substance
Section 311 hazardous Yes
chemical
Inventory status
Country(s)or region Inventory name On inventory(yes/no)*
Australia Australian Inventory of Chemical Substances(AICS) Yes
Canada Domestic Substances List(DSL) Yes
Canada Non-Domestic Substances List(NDSL) No
China Inventory of Existing Chemical Substances in China(IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances(EINECS)
Europe European List of Notified Chemical Substances(ELINCS) No
Japan Inventory of Existing and New Chemical Substances(ENCS) No
Korea Existing Chemicals List(ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States&Puerto Rico Toxic Substances Control Act(TSCA) Inventory Yes
*A"Yes"indicates that all components of this product comply with the inventory requirements administered by the goveming country(s)
State regulations WARNING: This product contains a chemical known to the State of California to cause cancer
and birth defects or other reproductive harm.
US-California Proposition 65-Carcinogens&Reproductive Toxicity(CRT): Listed substance
• Benzene(CAS 71-43-2) Listed.
Ethylbenzene(CAS 100-41-4) Listed.
US-California Proposition 65-CRT: Listed date/Carcinogenic substance
Benzene(CAS 71-43-2) Listed: February 27, 1987 Carcinogenic.
Ethylbenzene(CAS 100-41-4) Listed: June 11, 2004 Carcinogenic.
US-California Proposition 65-CRT:Listed date/Developmental toxin
Benzene(CAS 71-43-2) Listed: December 26, 1997 Developmental toxin.
US-California Proposition 65-CRT:Listed date/Male reproductive toxin
Benzene(CAS 71-43-2) Listed: December 26, 1997 Male reproductive toxin.
US-New Jersey Community RTK(EHS Survey): Reportable threshold
Benzene(CAS 71-43-2) 500 LBS
Ethylbenzene(CAS 100-41-4) 500 LBS
Hexane(CAS 110-54-3) 500 LBS
Petroleum Distillate(CAS 8002-05-9) 500 LBS
US-Pennsylvania RTK-Hazardous Substances: Listed substance
Benzene(CAS 71-43-2) Listed.
Ethylbenzene(CAS 100-41-4) Listed.
Hexane(CAS 110-54-3) Listed.
Petroleum Distillate(CAS 8002-05-9) Listed.
US-Pennsylvania RTK-Hazardous Substances:Special hazard
Benzene(CAS 71-43-2) Special hazard.
16. Other Information
Further information HMIS®is a registered trade and service mark of the NPCA.
HMIS®ratings Health:2*
Flammability: 3
Physical hazard:0
• NFPA ratings Health: 2
Flammability: 3
Instability:0
Material name:Crude Oil CPH MSDS us
1522 Version#:02 Revision date:01-06-2009 Print date:03-31-2009 7/E
Disclaimer The information provided herein is believed to be accurate as of the date of issue, but is offered
without guarantee. The information provided may not be complete, as it is not practicable to
provide all scientific information in the format of this document. Further, additional information
may be necessary under exceptional conditions of use, or because of applicable laws or
regulations. Noble Energy, Inc. does not assume any liability arising out of product use even if
• safety procedures are followed as outlined herein. The user has the responsibility for evaluating
the adequacy of the information under the conditions of use and obtaining additional information
where uncertainty exists. No express or implied guarantees are made as to the effects of use,the
results to be obtained, or the safety and toxicity of the product in any specific application. The
user assumes all risks of use of the product. Noble Energy, Inc.expressly disclaims all warranties
of every kind including warranties of merchantability and fitness for any particular purpose.
Nothing herein is intended to be construed as permission or recommendation for use of the
product in any manner which might infringe existing patents.
Communication with Employees and Purchasers: This Material Safety Data Sheet(MSDS)alerts
the reader to potential safety and health hazards. It also contains valuable reference material
relating to the safe use and handling of the product. Make sure that this information is shared
with all employees and purchasers who use or handle the product. It is an important part of the
OSHA hazard communication program.
ABBREVIATIONS:TLV-Threshold Limit Value MSDS-Material Safety Data Sheet STEL-
Short-term Exposure Limit PEL-Permissible Exposure Limit DOT-Department of Transportation
(USA) CAS-Chemical Abstract Service Number ACGIH-American Conference of Government
Industrial Hygienists NFPA-National Fire Protection Association(USA) IARC-International
Agency for Research on Cancer OSHA-Occupational Safety and Health Administration TSCA—
Toxic Substance Control Act The information in the sheet was written based on the best
knowledge and experience currently available.
Issue date 01-06-2009
This data sheet contains This document has undergone significant changes and should be reviewed in its entirety.
changes from the previous
version in section(s):
•
•
Material name:Crude Oil CPH MSDS U
6/
1522 Version#:02 Revision date:01-06-2009 Print date:03-31-2009
Material Safety Data Sheet
•
SUNCOR
ENERGY
FUEL OIL 2 DYED
WHMIS Pictograms) WHMIS (Classification) Protective Clothing
Q83-Combustible Liquid
D2A-Materials Causing Other Toxic
Effects,Very Toxic Material ••-
D28-Materials Causing Other Toxic
Effects,Toxic Material
NFPA Hazard Class HMIS Hazard Class
Health 2 Hazardous Health 2
Flammability 2 Flashpoint below 200 F Flammability 2
Reactivity 0 Stable Physical Hazard 0
Specific hazards Personal Protective Safety Glasses, Gloves
Equipment
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name ; FUEL OIL 2 DYED
Product type : Suncor Product
MSDS Number : SEP000000044
Material number ; 100486
• CAS-No. : 68476-30-2
Synonyms Petroleum distillate, No. 2 Fuel Oil, Fuel Oil 2 Northern
Dyed
Intended Use ; Consumer products: Home heating oil. Petrochemical
industry: Fuel oil. Fuel additive.
Manufacturer : Suncor Energy Inc.
36 York Mills Road
North York, Ontario Canada
M2P 2C5
EMERGENCY CONTACT INFORMATION
Suncor Energy Products Inc. (519)337-2301 (24-hr)
Canutec(613)996-6666
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS-No. Concentration
Sulphur 7704-34-9 0.0000-0.5000 %
FUEL OIL 68476-30-2 100.0000 %
DyeD390 <=0.018%
SECTION 3. HAZARDS IDENTIFICATION
Potential Health Effects
• Eyes : Causes eye irritation.
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Material Safety Data Sheet
SUNCOR
ENERGY
FUEL OIL 2 DYED
Skin : May cause irritation, drying and blistering.
May cause irritation and allergy; burning, itching, redness and
bumps.
Prolonged skin contact may cause skin irritation.
The product may be absorbed through the skin.
Inhalation : May cause nose, throat, and lung irritation.
Major effects of exposure
Headache
Nausea
Dizziness
Loss of balance
Lack of coordination
other central nervous effects
Unconsciousness
respiratory failure and death.
Irritating to mucous membranes
Inhalation of aerosol may cause irritation to the upper
respiratory tract.
Ingestion : Harmful or fatal if swallowed.
Aspiration hazard if swallowed -can enter lungs and cause
damage.
• Ingestion may cause gastrointestinal irritation, nausea,
vomiting and diarrhoea.
Chronic Exposure : Repeated or prolonged exposure to the substance can
produce target organ damage.
Primary Routes of Entry : Inhalation
Eye contact
Skin Absorption
Ingestion
Target Organs : Central nervous system
Eyes
Skin
Upper respiratory tract
Lungs
Nasal inner lining
Gastrointestinal tract
Carcinogenic Effects : IARC Group 3 -Not Classifiable as to Human Carcinogenicity
Fuel Oil 2 Clear
Middle distillates have produced skin cancer in laboratory
animal experiments when repeatedly applied without washing
between applications.
SECTION 4. FIRST AID MEASURES
• Eye contact : In case of eye contact, remove contact lens and rinse
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Material Safety Data Sheet
• SUENERNCOR
FUEL OIL 2 DYED
immediately with plenty of water, also under the eyelids,for at
least 15 minutes.
Seek medical advice.
Skin contact : In case of contact, immediately flush eyes or skin with plenty of
water for at least 15 minutes while removing contaminated
clothing and shoes.
Wash contaminated clothing before re-use.
If redness or swelling develops, obtain medical assistance.
Destroy contaminated shoes.
Inhalation : Remove to fresh air.
If breathing is irregular or stopped, administer artificial
respiration.
In case of shortness of breath, give oxygen.
Seek medical advice.
Ingestion : Do not induce vomiting without medical advice.
Never give anything by mouth to an unconscious person.
Loosen tight clothing such as collar, tie, belt or waistband.
Small amounts which accidentally enter mouth should be
rinsed out until taste is gone.
Seek medical advice.
•
SECTION 5.FIRE-FIGHTING MEASURES
Flash point : 45 °C (113 °F)
Method: Pensky Martens closed cup
Autoignition temperature : 257 °C (495°F)
Flammability : Combustible. Containers may explode or rupture if exposed to
heat
Flammability in Presence of : Flammable in presence of
open flames
sparks
Slightly flammable in presence of
shock
heat
oxidizing materials
Explosibility in Presence of : Explosive in presence of
oxidizing materials
Fire fighting information
Suitable extinguishing : Extinguishing media-small fires, Dry chemical, Carbon dioxide
• media (CO2), Extinguishing media-large fires,Water spray,fog,
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SUNCOR
ERGY
FUEL OIL 2 DYED
Foam, Do NOT use water jet., Cool containers/tanks with
water spray.
Special protective : Wear self-contained breathing apparatus when fire fighting in
equipment for fire-fighters confined space.
Wear structural fire fighters protective clothing.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Ensure adequate ventilation.
Wear proper protective equipment as specified in the protective
equipment section.
Methods for cleaning up : Ensure adequate ventilation.
Wear proper protective equipment as specified in the protective
equipment section.
Remove all sources of ignition.
Clean-up methods-small spillage
Soak up with inert absorbent material.
Scrape or gather material and place in a suitable container for
disposal.
Prevent ignition; stop leak;ventilate area.
Clean-up methods -large spillage
• Prevent further leakage or spillage if safe to do so.
Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local/national regulations(see section 13).
Protect against water.
Try to prevent the material from entering drains or water
courses.
Ensure product is not present at a concentration level above
the TLV.
Check TLV on MSDS or consult local authorities.
In Canada, advise the Ministry of the Environment.
Additional advice : For dispersion properties, refer to Section 9, Solubility.
SECTION 7. HANDLING AND STORAGE
Handling Precautions
Handling : Keep away from open flames, hot surfaces and sources of
ignition.
Ensure all equipment is electrically grounded before beginning
transfer operations.
Do not ingest.
Do not breathe vapors, mist or gas.
Wear suitable protective equipment.
In case of insufficient ventilation, wear suitable respiratory
equipment.
• If ingested, seek medical advice immediately and show the
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Material Safety Data Sheet
• SUNCOR
ENFUEL OIL 2 DYED
container or the label.
Avoid prolonged contact with eyes,skin and clothing.
Never siphon by mouth.
After handling, always wash hands thoroughly with soap and
water.
Storage
Further information on : Store in a place accessible by authorized persons only.
storage conditions Store in a cool, well ventilated area away from incompatible
materials.
Keep containers tightly closed and sealed until ready for use.
Keep away from heat and sources of ignition.
Advice on mixed storage : Reactive with:
Oxidizing agents
Slightly reactive with acids.
SECTION 8. EXPOSURE CONTROLS!PERSONAL PROTECTION
Engineering measures : Adequate ventilation to ensure that Occupational Exposure
Limits are not exceeded.
• Mechanical ventilation recommended.
Ensure that eyewash station and safety shower are proximal to
the work-station location.
Eye protection : Wear monogoggles or safety glasses when handling the
product.
Wear face-shield if splashing hazard is likely.
Hand protection : Gloves recommended to protect against contact with product.
The following materials are acceptable:
Nitrite rubber
Neoprene
PVC
Viton
polyvinyl alcohol
Skin and body protection : Avoid contact with skin.
Wear long sleeve clothing or coveralls.
Flame retardant antistatic protective clothing
If contact is unavoidable,wear chemical resistant clothing.
Respiratory protection : Concentration in air determines protection needed.
Half-mask air purifying respirator with organic vapor cartridges
is acceptable to 10 times the exposure limit.
Full-face air purifying respirator with organic vapor cartridges is
acceptable to 50 times the exposure limit not to exceed the
cartridge limit of 1000 ppm.
Use a positive pressure-demand full-face supplied air
• respirator or SCBA for exposures above 50 times the exposure
5/9
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Material Safety Data Sheet
• SUENERNCOR
FUEL OIL 2 DYED
limit.
If exposure is above IDLH(immediately dangerous to life&
health)or there is the possibility of an uncontrolled release or
exposure levels are unknown then use a positive pressure-
demand full-face supplied air respirator with escape bottle or
SCBA.
Legislated occupational threshold limits
Sulphur 7704-34-9 CAD AB OEL TWA 10 mg/m3
FUEL OIL 68476-30-2 CAD ON OEL TWA 100 mg/m3
Expressed as as total hydrocarbons
Form of exposure Vapor and aerosol.
ACGIH TWA 100 mg/m3
Expressed as as total hydrocarbons
Form of exposure Vapor and aerosol.
Note: State/Provincial, local or other agencies or advisory groups may have established more
stringent limits. Consult an industrial hygienist or similar professional, or your local authorities for
further information.
Other information
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
• Colour : light red
Odour : Kerosene
Physical state : liquid
Boiling point/range : 160-370 °C (320-698 °F )
Evaporation rate : times slower 600 compared to Ethyl Ether= 1
Vapour pressure : 0.2 kPa at 20°C (68 °F)
Relative density : 0.830-0.875
Specific gravity : 0.830-0.875
Note: Water= 1
Solubility in other solvents : Note: Insoluble in, cold water, hot water
Viscosity, dynamic : 268 mPa.s
Viscosity, kinematic : 1.70-3.60 mm2/s
Relative vapour density : 8
Note:Air= 1
• 619
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Material Safety Data Sheet
• SUNCOR
ENERGY
FUEL OIL 2 DYED
SECTION 10. STABILITY AND REACTIVITY
Materials to avoid : Reactive with:
Oxidizing agents
Slightly reactive with acids.
Hazardous decomposition : Carbon monoxide and asphyxiants on combustion.
products
SECTION 11.TOXICOLOGICAL INFORMATION
Acute oral toxicity : LD50 rat
Dose: 12,000 mg/kg
Test substance: Fuel Oil
LD 50 Rat
Dose: >8,437 mg/kg
Test substance: Sulfur
LD 50 Rat
Dose: 8,000 mg/kg
Test substance: Dye
• Acute dermal toxicity : LD 50 Rat
Dose: 4,000 mg/kg
Test substance: Dye
Acute inhalation toxicity : LC 50 Mammal
Exposure time: 4 h
Dose: 1.660 mg/I
Test substance:Sulfur
SECTION 12. ECOLOGICAL INFORMATION
Products of biodegradation : Possibly hazardous short/long term degradation products are
to be expected.
SECTION 13. DISPOSAL CONSIDERATIONS
Advice on disposal : In Canada,follow federal, provincial and local regulations.
Do not flush to drain/storm sewer.
Contract to authorized disposal service.
SECTION 14.TRANSPORT INFORMATION
DOT Proper shipping name : DIESEL FUEL
UN-No. : 1202
Class : 3
• Packing group : Ill
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SUNCOR
ENERGY
FUEL OIL 2 DYED
TDG Proper shipping name : DIESEL FUEL
UN-No. : 1202
Class : 3
Packing group : III
IATA UN Number : 1202
Description of the goods : DIESEL FUEL
Class : 3
Packaging group : III
ADRIRID-Labels : 3
Packing instruction(cargo : 310
aircraft)
Packing instruction : 309
(passenger aircraft)
Packing instruction : Y309
(passenger aircraft)
IMDG Substance No. : UN 1202
Description of the goods : DIESEL FUEL
Class : 3
Packaging group : Ill
ADRIRID-Labels : 3
EmS Number : F-E
•
SECTION 15. REGULATORY INFORMATION
HMIS Hazard Class
Health 2
Flammability 2
Physical Hazard 0
Personal Protective Safety Glasses,
Equipment Gloves
NFPA Hazard Rating Flammability
Reactivity
0
Health
Special
WHMIS Classification : B3-Combustible Liquid, D2A-Materials Causing
Other Toxic Effects, Very Toxic Material, D2B -
Materials Causing Other Toxic Effects,Toxic
Material
WHMIS(Pictograms)
00
• TSCA Status : Listed on TSCA
FUEL OIL 68476-30-2
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Material Safety Data Sheet
• SUENERNCOR
FUEL OIL 2 DYED
Dye D 390
Sulphur 7704-34-9
DSL Status : All components of this product are on the Canadian DSL list.
FUEL OIL 68476-30-2
Dye D 390
Sulphur 7704-34-9
SARA 311/312 Hazards : FUEL OIL 2 DYED 68476-30-2
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
SECTION 18.OTHER INFORMATION
Date Validated : 04/10/2007
Other : Keep out of the reach of children.
considerations for Only approved metal/plastic containers should be used for storage.
product
Containers are hazardous when empty as product vapor or liquid
• remains.
References Regulations respecting the handling,offering for transport and transporting of dangerous
goods.Clear Language Regulation 2002
SAX,N.I.Dangerous Properties of Industrial Materials.Toronto,Van Nostrand Reinold,
6th ed.1984.
Validation date of previous version 2004/04/29
General contact information B.Burrell:(519)383-3657
NO WARRANTY OF MERCHANTABILITY,FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER
WARRANTY,EXPRESS OR IMPLIED,IS MADE AS CONCERNS THE INFORMATION HEREIN PROVIDED. The
information provided herein relates only to the specific product designated and may not be valid where such product is
used in combination with any other materials or in any process. Further,since the conditions and methods of use of the
product and information referred to herein are beyond the control of Suncor,Suncor expressly disclaims any and a9
liability as to any results obtained or arising from any use of the product or such information. No statement made herein
shall be considered as a permission or recommendation for the use of any product in a manner that may infringe existing
patents. As soon as reasonably practicable after Suncor is aware of any inaccurate information,Suncor will update the
MSDS. However,Suncor cannot guarantee the accuracy,currency or completeness of the information at all times.
• 919
Version 1 Revision Date 04/10/2007 Print Date 02/01/2008
•
HS
MATERIAL SAFETY DATA SHEET
Section 1 -CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHS Inc. Transportation Emergency(CHEMTREC): 1-800-424-9300
P.O.Box 64089 Technical Information: 1-651-355-8443
Mail station 525 MSDS Information: 1-651-355-8438
St.Paul,MN 55164-0089
PRODUCT NAME:No. 1 DIESEL FUEL MSDS:0143-M2A0-Rev.13(02/08/07)
COMMON NAME:No. 1 Distillate Fuel,No. 1 High Sulfur Diesel(Dyed) CHEMICAL FORMULA:Mixture
No. 1 Low Sulfur Diesel(Dyed),No. 1 Ultra Low Sulfur Diesel(Dyed/Undyed)
CHEMICAL NAME:Petroleum Distillate CHEMICAL FAMILY: A mixture of Paraffinic,
Olefinic,Naphthenic,and Aromatic Hydrocarbon.
Section 2-COMPOSITION AND INFORMATION ON INGREDIENTS
INGREDIENTS PERCENTAGES PEL(OSHA) TLV(ACGIH) CAS#
(by weight) TWA TWA
Petroleum
Distillates 0-100 N/D 200 ppm 8008-20-6
Biphenyl 0.5-1.5 0.2 ppm 92-52-4
• Naphthalene 0-3 10 ppm 91-20-3
Xylene 0-2.5 100 ppm 1330-20-7
1,2,4-Trimethylbenzene 0-2 25 ppm 95-63-6
Note:The National Institute for Occupational Safety and Health has published a Recamtrnded Exposure Limit(REL)of 100 mg/S TWA or»14 ppm based on an average
molecular weight of 170 for kerosene like factions.
(TWA)-Time Weighted Average is the employee's avenge airborne exposure in any 8-hour work shift of a 40-hour work week which shall not be exceeded.
(STEL)-Short Term Exposure Limit is the employee's I 5-minute time weighted avenge exposure which shall not be exceeded at any time doing a work day unless another time
limit is specified
Section 3-HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
A clear to light yellow liquid with a hydrocarbon odor. May contain dye.
OSHA HAZARD CLASSES
Based on OSHA definitions, the following ingredients in this product are hazardous. The OSHA physical and health hazard
categories are shown below.
Petroleum Hydrocarbon-Combustible,toxic(moderate),target organ(skin).
1,2,4-Trimethylbenzene-Flammable,toxic,irritant,target organ(Central Nervous System,blood).
POTENTIAL HEALTH EFFEC IS
ROUTES OF ENTRY: Eye Contact,Dermal,Inhalation,Ingestion.
• Page 1 of 5
• No. I Diesel Fuel
• ACUTE EFFECTS OF OVEREXPOSURE:
Eyes-Minor irritation
Skin-Slight irritation
Inhalation-Vapors may cause dizziness or asphyxiation
Ingestion - Central nervous system depression, peripheral nervous system depression,narcosis, asphyxiation, gastrointestinal
disturbances.Aspiration of vomitus can cause serious pneumonitis,particularly in young children.
CHRONIC EFFECTS OF OVEREXPOSURE: Dermatitis from chronic exposure. Products of similar composition were tested on
laboratory animals,and weak to moderately positive results were found in mouse skin cancer studies,mixed and inconsistent results were
found in mutagenicity studies, and negative results were found in rat teratology studies. There is no direct evidence that this material
causes skin cancer in humans.This material is not listed as a carcinogen by NTP,IARC,or OSHA.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:May aggravate pre-existing dermatitis or respiratory illness.
CARCINOGENICITY: Petroleum Hydrocarbon NTP: No IARC: No OSHA: No
1,2,4-Trimethylbenzene NTP: No IARC: No OSHA: No
Section 4-FIRST AID MEASURES
EMERGENCY AND FIRST AID PROCEDURES:
Eye Contact: If material contacts the eye, flush thoroughly with water for at least 15 minutes, occasionally lifting upper and
lower lids,until no evidence of chemical remains.Get medical attention.
Skin Contact:Remove contaminated clothing.Wash affected areas with soap and water.
• Inhalation: Move person to fresh air. If a large amount has been inhaled,keep victim warm and get medical attention.Begin
rescue breathing procedures if not breathing.
Ingestion:Do NOT induce vomiting.Get medical attention immediately.If spontaneous vomiting occurs,lower victim's head in
an effort to prevent vomits from entering the lungs.Never give anything by mouth to an unconscious person.
Section 5-FIRE-FIGHTING MEASURES
FLASH POINT: 100-150°F(38-66°C)TCC AUTO IGNITION TEMP:410°F
FLAMMABLE LIMITS IN AIR LOWER UPPER
%BY VOLUME 0.7 5.0
EXTINGUISHING MEDIA:Dry Chemical,Foam,Carbon Dioxide(CO2),Water(fog pattern)
SPECIAL FIRE FIGHTING PROCEDURES:Water may be ineffective on flames,but should be used to keep fire-exposed containers
cool. Water or foam sprayed into container of hot burning product could cause frothing and endanger fire fighters. Large fires, such as
tank fires, should be fought with caution. If possible, pump the contents from the tank and keep adjoining structures cool with water.
Avoid spreading burning liquid with water used for cooling purposes.Do not flush down public sewers.Avoid inhalation of vapors.Fire
fighters should wear self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARDS:Vapors are heavier than air and may travel along the ground to a source of ignition
(pilot light,heater,electric motor)some distance away. Containers,drums(even empty)can explode when heat(welding,cutting,etc.)is
applied.
HAZARD RATINGS: NFPA 704: Health 1 Fire 2 Reactivity 0
HMIS: Health 1 Fire 2 Reactivity 0
• Page 2 Of 5
• No.1 Diesel Fuel
• Section 6-ACCIDENTAL RELEASE MEASURES
STEPS TO TAKE IF MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition. Notify emergency response
personnel as appropriate. If facility or operation has an "Oil or Hazardous Substance Contingency Plan", "Spill Prevention Control &
Countermeasures(SPCC)Plan" or equivalent,activate its procedures. Prohibit persons not wearing protective equipment from entering
the area.Stop leak at source,contain spill to prevent spreading. Small spills can be removed with inert absorbent.Dike areas of large spill
to prevent runoff to sewers,streams,etc.Ventilate area.Avoid breathing vapors.
Section 7-HANDLING AND STORAGE
HANDLING AND STORAGE: Transport, handle and store in accordance with OSHA Regulation 29 CFR 1910.106, and applicable
D.O.T.Regulation.Caution:Misuse of empty containers can be hazardous.Empty containers can be hazardous since emptied containers
retain product residue(vapor, liquid,and/or solid).Cutting or welding empty containers might cause fire,explosion or toxic fumes from
residues.
Section 8-EXPOSURE CONTROL-PERSONAL PROTECTION
ENGINEERING CONTROLS:Provide adequate local or dilution ventilation to keep vapors below permissible concentrations.
RESPIRATORY EQUIPMENT: Personnel should never enter areas of high concentrations without proper respiratory protection. If
exposure limits for product or components are exceeded, NIOSH-approved respiratory protection equipment should be worn. Proper
selection of respirators should be determined by adequately trained personnel,based on the contaminants,the degree of potential exposure
and published respiratory protection factors. Self-contained breathing apparatus or supplied air respiratory protection required for entry
into tanks,vessels,or other confined spaces containing kerosene.
EYE PROTECTION:Chemical type goggles or face shield where contact with liquid or mist may occur.
• PROTECTIVE CLOTHING:Wear impervious clothing and gloves when contact with skin may occur.
OTHER (SAFETY SHOWERS, EYE WASH STATIONS, ETC.): Water should be available for flushing and washing when
exposure exists.
Section 9-PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE:A clear to light yellow liquid,may ODOR:Hydrocarbon odor.
contain red dye.
BOILING POINT:340°F-570°F SPECIFIC GRAVITY(water-1):0.82
VAPOR PRESSURE:<50 mmHg @ 100°F VAPOR DENSITY(air-1):>1
SOLUBLE IN WATER:Insoluble EVAPORATION RATE(ether-1):>1
pH: N/D
Section 10-STABILITY AND REACTIVITY
STABILITY:
STABLE X
UNSTABLE
INCOMPATIBILITY:
CONDITIONS TO AVOID:Heat,flame,all ignition sources and static electricity.
• MATERIALS TO AVOID:Strong oxidizing agents.
Page 3 Of 5
• No. 1 Diesel Fuel
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide,carbon dioxide, and other petroleum decomposition products
• (hydrocarbons).
HAZARDOUS POLYMERIZATION:Has not been reported to occur under normal temperatures and pressures.
Section 11 -TOXICOLOGY INFORMATION
Note: CHS has not conducted specific toxicity tests on this product. Our hazard evaluation is based from similar
ingredients,technical literature,and/or professional experience.
Section 12-ECOLOGICAL INFORMATION
Note: CHS has not conducted specific ecological tests on this product.
Section 13-DISPOSAL CONSIDERATION
WASTE DISPOSAL PROCEDURES:Recycle as much of the recoverable product as possible.Do not flush to drain or storm sewer or
otherwise release to the environment.Dispose of non-recyclable material according to federal,state and local regulations.
Section 14-TRANSPORTATION
•
DOT PROPER SHIPPING NAME:Fuel Oil#1 DOT HAZARD CLASS:Flammable Liquid
DOT IDENTIFICATION NUMBER:NA 1993 DOT EMER RESPONSE GUIDE NO.: 128
(Formerly#27)
Rupem Shipping Name-Fuel Oil#1;Hazard Class-3;UN/NA Identification f-NA 1993;Packing Group HI;Placard-FLAMMABLE LIQUID.
Section 15-REGULATORY INFORMATION
This product contains the following toxic chemicals subject to the reporting requirements of SARA Section 313 of the Emergency
Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372:
CAS Number Chemical Name Percent by Weight
95-63-6 1,2,4-Trimedrylbenzene 0-2%
91-20-3 Naphthalene 0-3%
SARA SECTION 311-312 HAZARD CATEGORIES(40 CFR 370.2):
FIRE:Yes SUDDEN RELEASE OF PRESSURE:N0REACI7VE:No ACUTE: Yes CHRONIC:Yes
• Page 4 Of 5
• No I Diesel Fuel
• Section 16-OTHER INFORMATION
Prepared By: Hue Lam Date: February 08,2007
Title: EHS Compliance Specialist Supersedes: December 24%2003
Reason for Issue: Periodic review and update
THE INFORMATION CONTAINED IN THIS MSDS RELATES ONLY TO THE SPECIFIC MATERIAL IDENTIFIED. IT DOES NOT COVER USE OF THAT
MATERIAL IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PARTICULAR PROCESS. IN COMPLIANCE WITH 29 C.F.R. 1910.1200(g),
CHS HAS PREPARED THIS MSDS IN SEGMENTS, WITH THE INTENT THAT THOSE SEGMENTS BE READ'TOGETHER AS A WHOLE WilHDuI
TEXTUAL OMISSIONS OR ALTERATIONS. CHS BELIEVES THE INFORMATION CONTAINED HEREIN TO BE ACCURATE, BUT MAKES NO
REPRESENTATION,GUARANTEE,OR WARRANTY,EXPRESS OR IMPLIED.ABOUT THE ACCURACY,RELIABILITY,OR COMPLETENESS OF THE
INFORMATION OR ABOUT THE FITNESS OF CONTENTS HEREIN FOR EITHER GENERAL OR PARTICULAR PURPOSES. PERSONS REVIEWING
THIS MSDS SHOULD MAKE THEIR OWN DETERMINATION AS TO THE MATERIAL'S SUITABILITY AND COMPLETENESS FOR USE IN THEIR
PARTICULAR APPIJCATIONSra.).
OUR ENERGY
COMES THROUGH."
Genes®is a registered trademark of CHS Inc.
•
• Page 5 Of 5
• INDUSTRY STANDARD SPECIFICATION FOR KEROSENE
(ASTM D 3699-90 SUMMARY)
1-K 2-K
Color Clear Clear
(Saybolt No., minimum) (+16) (+16)
Sulfur,%wt.,max. 0.04 0.30"
Distillation Temp.,°F
10%recovered,max. 401 401
End Point,max. 572 572
Flash Point, °F, minimum 100 100
Freezing Point,°F,max. -22 -22
Viscosity @ 40°C.cSt
minimum 1.0 1.0
maximum 1.9 1.9
Burning Quality Pass Pass
Corrosion,copper strip rating, No. 3 No. 3
max. (3 hrs.@ 100°C)
A: Required to contain a sufficient amount of red dye to meet tax agency regulations if
• sulfur content is above 0.05%.
1-K Kerosene: Special low sulfur grade kerosene suitable for use in non-flue-connected
kerosene burner appliances and for use in wick-fed illuminating lamps.
2-K Kerosene: Regular grade kerosene suitable for use in flue-connected burner
appliances.
•
Material Safety Data Sheet
prnwamtw
NFPA HMIS(U.S.A.) Rating Protective Clothing DOT(pictograms)
Tire Hazard Health Hazard 2• 0 Insignificant Not«.wa�ae for transport
ili
3 Non evmua pour le transport
Fire Hazard 3 r Slight
Health t 0 Reactivity 2 Moderate
Specific hazard Reactivity 0 3 High
Personal Protection H 4 Extreme
Section 1. Chemical Product and Company Identification
Product Name CRUDE OIL (SWEET) Code W272
DSL See Section 15
Synonym Sweet Crude TSCA See Section 15
Manufacturer PETRO-CANADA In case of Petro-Canada:403-296-3000
P.O. Box 2844 Emergency Canutec Transportation:
150—6th Avenue South-West 613-996-6666
Calgary,Alberta Poison Control Centre:
T2P 3E3 Consult local telephone
directory for emergency
Material Uses Raw product for oil refineries to produce fuels and other petroleum number(s).
based organic products.
Section II. Composition and Information on Ingredients
Exposure Limit'(AWIN)
Name CAS# %(WIW) TLV-TWA(8 h) STEL CEILING
Petroleum crude oil' 8002-05-9 100 Not established Not Not
established established
'Contains small amounts of benzene,polynuclear
aromatic hydrocarbons(PNAs), sulphur(trace), and
oxygenated compounds.
Manufacturer
ecommendation
ACGIH TLV: 0.5 ppm for benzene
STEL:2.5 ppm for benzene
Other Exposure Consult local,state, provincial or territory authorities for acceptable exposure limits.
Limits
Section III.Hazards Identification.
Potential Health Flammable liquid. Exercise caution when handling this material. May cause cancer. May cause heritable
Effects genetic effects (mutagenicity). Contact with this product may cause skin and eye irritation.This product
contains an ingredient or ingredients,which have been shown to cause chronic toxic effects. Inhalation of this
product may cause respiratory tract irritation and Central Nervous System(CNS)Depression,symptoms of
which may include;weakness, dizziness, slurred speech, drowsiness, unconsciousness and in cases of
severe overexposure; coma and death. Ingestion of this product may cause gastro-intestinal irritation.
Aspiration of this product may result in severe irritation or burns to the respiratory tract. For more information
refer to Section 11 of this MSDS.
Section IV. First Aid Measures
Eye Contact Avoid direct contact. Quickly and gently blot or brush chemical off the face. Immediately flush the
contaminated eye(s)with lukewarm,gently flowing water for 15-20 minutes,while holding the eyelid(s)open. If
a contact lens is present, DO NOT delay irrigation or attempt to remove the lens. Take care not to rinse
contaminated water into the unaffected eye or onto the face. Immediately obtain medical attention.
Skin Contact As quickly as possible, remove contaminated clothing, shoes and leather goods (e.g., watchbands, belts,
etc.).Avoid direct contact.Wear chemical resistant protective clothing if necessary. Quickly and gently, blot
or brush away excess chemical. Immediately wash with lukewarm, gently flowing water and non-abrasive
soap for 15-20 minutes. Immediately obtain medical attention. Completely decontaminate clothing, shoes and
leather goods before reuse or discard.
Inhalation Take proper precautions to ensure your own safety before attempting rescue(e.g.wear appropriate protective
equipment). If breathing has stopped,trained personnel should begin artificial respiration(AR)or, if the heart
has stopped, immediately start cardiopulmonary resuscitation (CPR)or automated external defibrillation
(AED). Quickly transport victim to an emergency care facility.
Ingestion NEVER give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing.
Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 60 to 240 mL
(2 to 8 oz.)of water. If vomiting occurs naturally, have victim rinse mouth with water again. If breathing has
stopped, trained personnel should begin artificial respiration(AR)or, if the heart has stopped, immediately
start cardiopulmonary resuscitation (CPR) or automated external defibrillation (AED). Quickly transport victim
to an emergency care facility.
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CRUDE OIL(SWEET) Page Number:2
Note to Physician Not available
Section V. Fire-fighting Measures
flammability Flammable liquid. Flammable Limits Varies with crude sources, but typically
LEL may be as low as 0.5%and UEL may
be as high as 15%.
Flash Points CLOSED CUP: <40°C (104°F). Varies with Auto-Ignition Varies with crude sources.
crude sources. Temperature
Fire Hazards in Easily ignites under almost all normal Explosion Hazards Do not cut, weld, heat, drill or pressurize
Presence of temperature conditions. Extremely in Presence of empty container. Containers may explode
Various Substances flammable in presence of open flames, Various Substances in heat of fire. Vapours may form
sparks, shocks, heat, oxidizing materials. explosive mixtures with air. Runoff to
Vapours are heavier than air. They will sewer may create fire or explosion hazard.
spread along ground and collect in low or Liquid may accumulate static charge.
confined areas(sewers, basements, tanks),
and may travel considerable distance to
sources of ignition and flash back.
Products of Carbon oxides(CO, CO2), nitrogen oxides(NOx), sulphur oxides(SOx), sulphur compounds(H2S), smoke
Combustion and irritating vapours as products of incomplete combustion.
Fire Fighting NAERG2004, GUIDE 128, flammable/combustible liquid (non-polar/water-immiscible). CAUTION: This
Media and product has a low flash point, use of water spray when fighting fire may be inefficient. SMALL FIRE: Use
Instructions DRY chemicals,CO2,water spray or foam. LARGE FIRE: Use water spray,fog or foam. DO NOT use water
jet. If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters(1 mile)in all directions; also,
consider initial evacuation for 1600 meters(1 mile) in all directions. DO NOT extinguish a leaking gas flame
unless leak can be stopped. Shut off fuel to fire if it is possible to do so without hazard. If this is impossible,
withdraw from area and let fire burn out under controlled conditions. Withdraw immediately in case of rising
sound from venting safety device or any discolouration of tank due to fire. Cool containing vessels with water
spray in order to prevent pressure build-up, autoignition or explosion. Avoid flushing spilled material into
sewers, streams or other bodies of water. Self-contained breathing apparatus (SCBA) will be required if
approaching the fire from downwind,or to enter enclosed areas or buildings.
Section VI.Accidental Release Measures
aterial Release Extinguish all ignition sources. Notify appropriate authorities immediately. IN THE EVENT OF A LARGE
or Spill SPILL CONSIDER THE FOLLOWING CONTROL MEASURES:Avoid breathing vapours or mists of material.
Avoid contact with spilled material. Ventilate area. Do not allow spilled materials to come into to contact with
incompatible materials (see Section 10). Use appropriate inert absorbent material to absorb spilled product.
Do not use paper or other flammable materials to absorb product. Collect used absorbent for later disposal.
Stop leak if safe to do so. Evacuate non-essential personnel. Ensure clean-up personnel wear appropriate
personal protective equipment. Ground and bond all equipment used to clean up the spilled material, as it
may be a static accumulator. Do not allow spilled material to enter sewer systems as vapours may accumulate
and may cause an explosion/fire hazard. Consult current National Emergency Response Guide Book
(NAERG)for appropriate spill measures if necessary.
Section VII.Handling and Storage
Handling FLAMMABLE MATERIAL. Handle with care. Avoid contact with any sources of ignition, flames, heat, and
sparks.Avoid skin contact.Avoid eye contact.Avoid inhalation of product vapours or mists. Do not ingest this
product.Avoid contact with any incompatible or reactive materials.Avoid confined spaces and areas with poor
ventilation. Exercise caution when washing/drying clothing contaminated with flammable materials. Empty
containers may contain product residue. Do not pressurize, cut, heat, or weld empty containers. Do not
reuse containers without commercial cleaning and/or reconditioning. Ensure all equipment is
grounded/bonded. Personnel who handle this material should practice good personal hygiene during and after
handling to help prevent accidental ingestion of this product.Wear proper personal protective equipment(See
Section 8).
Storage Store as flammable material.Store away from heat and sources of ignition.Store away from incompatible and
reactive materials (See section 5 and 10). Avoid direct sunlight. Ensure the storage containers are
grounded/bonded.
iiSection VIII. Exposure Controls/Personal Protection
Engineering For normal application, special ventilation is not necessary. If users operations generate vapours or mist, use
Controls ventilation to keep exposure to airborne contaminants below the exposure limit. Make-up air should always
be supplied to balance air removed by exhaust ventilation. Ensure that eyewash station and safety shower
are close to work-station.
Personal Protection - The selection of personal protective equipment varies,depending upon conditions of use.
Eyes Chemical splash goggles should be worn when handling this material.
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CRUDE OIL(S WEEP Page Number:3
Body If this material may come in contact with the body during handling and use, we recommend wearing
appropriate protective clothing to prevent contact with the skin. (Contact your PPE provider for more
information.)
Respiratory A NIOSH-approved positive-pressure, air-supplied respirator or self-contained breathing apparatus may be
permissible under certain circumstances where airborne concentrations are expected to exceed exposure
limits.
Hands If this material may come in contact with the hands during handling and use, we recommend wearing gloves
of the following material(s): polyvinyl alcohol (PVA) , fluoro-elastomer . Consult your PPE provider for
breakthrough times and the specific glove that is best for you based on your use patterns. It should be
realized that eventually any material regardless of their imperviousness, will get permeated by chemicals.
Therefore, protective gloves should be regularly checked for wear and tear.At the first signs of hardening and
cracks,they should be changed.
Feet Wear appropriate footwear to prevent product from coming in contact with feet and skin.
Section IX. Physical and Chemical Properties
Physical State and Viscous liquid. Viscosity Not available.
Appearance
Colour Light to dark brown, varies with crude Pour Point Varies with crude sources.
sources.
Odour Mild petroleum oil like. Softening Point Not applicable.
Odour Threshold Not available. Dropping Point Not applicable.
Boiling Point Varies with crude sources. Penetration Not applicable.
Density 0.7 to 1.1 (Water= 1) Oil/Water Dist.Coeff.Not measurable. The product is more
soluble in oil.
Vapour Density Heavier than air. tonicity(in water) Insoluble in water.
Vapour Pressure Not available. Dispersion Properties Nonvolatile and immobile.
Volatility Not available. Solubility Insoluble in water.
Section X. Stability and Reactivity
Corrosivity Not available
Stability The product is stable under normal Hazardous Will not occur under normal working
handling and storage conditions. Polymerization conditions.
Incompatible Reactive with oxidizing agents and Decomposition May release COx, NOx, SOx, smoke and
Substances/ interhalogens. Products irritating vapours when heated to
Conditions to Avoid decomposition.
Section XI. Toxicological Information
Routes of Entry Skin contact,eye contact,inhalation and ingestion.
Acute Lethality Acute toxicity information is not available for the product as a whole,therefore, data for some of the
ingredients is provided below:
Toxicity of crude oil varies depending on the geological source.
Crude oil(8002-05-9):
Acute oral toxicity(LD50): >4300 mg/kg(rat).
Benzene(71-43-2):
Acute Oral toxicity(LD50): 930 mg/kg(rat)
Acute Dermal toxicity(LD50): 9400 mg/kg(rabbit)
Acute Inhalation toxicity(LC50): 13,200 ppm/4h(rat)
Chronic or Other Toxic Effects
Dermal Route. This product contains a component (at >= 1%) that can cause skin irritation. Therefore, this
product is considered to be a skin irritant. Prolonged or repeated contact may defat and dry skin,
and cause dermatitis.
Inhalation Route Inhalation of this product may cause respiratory tract irritation. Inhalation of this product may cause
Central Nervous System(CNS) Depression, symptoms of which may include;weakness, dizziness,
slurred speech, drowsiness, unconsciousness and in cases of severe overexposure; coma and
II
death.
Oral Route. Ingestion of this product may cause gastro-intestinal irritation. Aspiration of this product may result
in severe irritation or burns to the respiratory tract. Ingestion of this product may cause Central
Nervous System(CNS)Depression,symptoms of which may include;weakness, dizziness, slurred
speech,drowsiness,unconsciousness and in cases of severe overexposure;coma and death.
t Continued on Next Page Internet:www.pebocanada.carmsde Available in French
I
CRUDE OIL(SWEET) Page Number:4
Eye Irritation/Inflammation: This product contains a component(at>=1%)that can cause eye irritation. Therefore,this product
is considered to be an eye irritant.
Immunotoxicity: Not available
• Skin Sensitization: Contact with this product is not expected to cause skin sensitization, based upon the available data
and the known hazards of the components.
Respiratory Tract Sensitization: Contact with this product is not expected to cause respiratory tract sensitization, based upon the
available data and the known hazards of the components.
Mutagenic: This product contains a component(s)at>= 0.1%that has been shown to cause mutagenicity in
laboratory tests. Therefore,this product is considered to be a mutagen.(Benzene]
Reproductive Toxicity: This product is not known to contain any components at>=0.1%that have been shown to cause
reproductive toxicity. Therefore, based upon the available data and the known hazards of the
components,this product is not expected to be a reproductive toxin.
Tcratogenicity/Embryotoxicity: This product is not known to contain any components at >=0.1%that have been shown to cause
teratogenicity and/or embryotoxicity. Therefore, based upon the available data and the known
hazards of the components,this product is not expected to be a teratogen/embryotoxin.
Carcinogenicity(ACGIH): This product contains the following chemical(s) at >=0.1% that are listed as carcinogenic
compounds. Therefore this product is considered to be carcinogenic.
(Considered to be Al by the ACGIH. Benzene,71-43-2)
Carcinogenicity(IARC): This product contains the following chemical(s) at >=0.1% that are listed as carcinogenic
compounds. Therefore this product is considered to be carcinogenic.
(Considered to be carcinogenic to humans(group 1)by IARC. Benzene,71-43-2)
Carcinogenicity(NTP): This product contains the following chemical(s) at >=0.1% that are listed as carcinogenic
compounds. Therefore this product is considered to be carcinogenic.
(Known to be a human carcinogen according to NTP. Benzene, 71-43-2)
Carcinogenicity(IRIS): This product contains the following chemical(s) at >=0.1% that are listed as carcinogenic
compounds. Therefore this product is considered to be carcinogenic.
(Considered to be carcinogenic by IRIS. Benzene,71-43-2)
Carcinogenicity(OSHA). This product contains the following chemical(s) at >=0.1% that are listed as carcinogenic
compounds. Therefore this product is considered to be carcinogenic.
(Considered to be carcinogenic by OSHA. Benzene,71-43-2)
Other Considerations No additional remark.
1 Section XII.Ecological Information
Environmental Fate Not available Persistence/ Not available
Bioaccumulation
Potential
BODS and COD Not available Products of Not available
Biodegradation
Additional Remarks No additional remark.
Section XIII. Disposal Considerations
Waste Disposal Spent/used/waste product may meet the requirements of a hazardous waste. Consult your local or regional
authorities. Ensure that waste management processes are in compliance with government requirements and
local disposal regulations.
Section XIV. Transport Information
DOT Classification Not evaluated. Special Provisions Not applicable
for Transport
Section XV.Regulatory Information
Other This product is acceptable for use under the provisions of WHMIS-CPR.All components of this formulation
Regulations are listed on the CEPA-DSL(Domestic Substances List).
All components of this formulation are listed on the US EPA-TSCA Inventory.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR)and the MSDS contains all of the information required by the CPR.
Please contact Product Safety for more information.
DSD/DPD(EEC) Not evaluated. WHMIS(Canada)B-2, D-2A, D-2B
NOT EVALUATED FOR TDC(Canada)
ADR(Europe) EUROPEANTMNSPORT (Pictograms) A
(Pictograms) NON EVALUE POUR LE .
TRANSPORT EUROPEEN.
$ Continued on Next Page Internet www.petrn-cenada.ce/meds Available in French
' CRUDE OIL(SWEET) Page Number:5
• Section XVI. Other Information
References Available upon request.
mists Marque de commerce de Petro-Canada-Trademark
liklossary
ACGIH - American Conference of Governmental Industrial HCS-Hazardous Communication System
Hygienists HMIS-Hazardous Material Information System
ADR-Agreement on Dangerous goods by Road(Europe) ARC-International Agency for Research on Cancer
ASTM-American Society for Testing and Materials IRIS-Integrated Risk Information System
BOD5-Biological Oxygen Demand in 5 days LD50/LC50-Lethal Dose/Concentration kill 50%
CAS-Chemical Abstract Services LDLo/LCLo-Lowest Published Lethal Dose/Concentration
CEPA-Canadian Environmental Protection Act NFPA-National Fire Prevention Association
CERCLA - Comprehensive Environmental Response, NIOSH-National Institute for Occupational Safety&Health
Compensation and Liability Act NPRI-National Pollutant Release Inventory
CFR-Code of Federal Regulations NSNR-New Substances Notification Regulations(Canada)
CHIP - Chemical Hazard Information and Packaging Approved NTP-National Toxicology Program
Supply List OSHA-Occupational Safety&Health Administration
COD-Chemical Oxygen Demand PEL-Permissible Exposure Limit
CPR-Controlled Products Regulations RCRA-Resource Conservation and Recovery Act
DOT-Department of Transportation(U.S.A.) SARA-Superfund Amendments and Reorganization Act
DSCL - Dangerous Substances Classification and Labeling STEL-Short Term Exposure Limit(15 minutes)
(Europe) TDG-Transportation Dangerous Goods(Canada)
DSD/DPD - Dangerous Substance or Dangerous Preparations TDLo/TCLo-Lowest Published Toxic Dose/Concentration
Directives(Europe) TLV-TWA-Threshold Limit Value-Time Weighted Average
DSL-Domestic Substance List(Canada) TLm-Median Tolerance Limit
EEC/EU-European Economic Community/European Union TSCA-Toxic Substances Control Act
EINECS-European Inventory of Existing Commercial Chemical USEPA-United States Environmental Protection Agency
Substances USP-United States Pharmacopoeia
EPCRA-Emergency Planning And Community Right-To-Know Act WHMIS-Workplace Hazardous Material Information System
FDA-Food and Drug Administration
FIFRA-Federal Insecticide,Fungicide,and Rodenticide Act
For Copy of MSDS Prepared by Product Safety - DSR on
Internet:www.petro-canada.ca/msds 5/22/2008.
Data entry by Product Safety-DSR.
Western Canada,telephone:403-296-7672;fax:403-2%-5147
For Product Safety Information:(905)804-4752
•To the best of our knowledge,the information contained herein is accurate. However,neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final
determination of suitability of any material is the sole responsibility of the user.All materials may present unknown hazards and
should be used with caution. Although certain hazards are described herein,we cannot guarantee that these are the only hazards that
exist.
0
Initial Preparation Date: 4/5/1989
• Last Revision Date: 9/3/2003
Effective Date: 8/1/2005
MATERIAL SAFETY DATA SHEET
PRODUCT IDENTITY: ALL WEATHER ANTIFREEZE & COOLANT
1. CHEMICAL PRODUCT& COMPANY INFORMATION
OLD WORLD INDUSTRIES, INC.
4065 COMMERCIAL AVENUE
NORTHBROOK, ILLINOIS 60062
PHONE: 847-559-2000
EMERGENCY PHONE: 1-800-424-9300(CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Material CAS# %by Wt alai TLV(ACGIH)
Ethylene Glycol 107-21-1 90-95 50 ppm 50 ppm
Diethylene Glycol 111-46-6 0-5 None None
•
Dipotassium Phosphate 7758-11-4 1 -2 None None
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Slight odor. May be fatal if swallowed Vapors can cause eye irritation.
Lowest Known LD50(Oral) 107-21-I 5840 mg/kg(Rats)
Lowest Known LD50(Skin) 107-21-1 9530 mg/kg(Rabbits)
HAZARD RATING SYSTEM
NFPA: HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0
HMIS: HEALTH: 2 FLAMMABILITY: l REACTIVITY: 0
KEY: 0—Minimal I —Slight 2-Moderate 3-Serious 4-Severe
•
ALL WEATHER Antifreeze 1
• POTENTIAL HEALTH EFFECTS
Routes of Exposure: Inhalation,Ingestion,Skin Contact/Absorption,Eye Contact
Eye: May cause slight transient(temporary)eye irritation. Corneal injury is unlikely. Vapors or mists may cause
eye irritation.
Skin: Prolonged or repeated exposure not likely to cause significant skin irritation. A single prolonged exposure is
not likely to result in the material being absorbed through skin in harmful amounts. Repeated skin exposure may
result in absorption of harmful amounts. Massive contact with damaged skin or of material sufficiently hot to burn
skin may result in absorption of potential lethal amounts.
Ingestion: Single dose oral toxicity is considered to be moderate. Excessive exposure may cause central nervous
system effects, cardiopulmonary effects (metabolic acidosis), and kidney failure. Small amounts swallowed
incidental to normal handling operations are not likely to cause injury; however, swallowing amounts larger than
that may cause serious injury,even death.
Inhalation: At room temperature,exposures to vapors are minimal due to physical properties;higher temperatures
may generate vapor levels sufficient to cause adverse effects.
Systemic (Other Target Organ) Effects: Repeated excessive exposures may cause severe kidney and also liver
and gastrointestinal effects. Signs and symptoms of excessive exposure may be central nervous system effects.
Signs and symptoms of excessive exposure may be nausea and/or vomiting. Signs and symptoms of excessive
exposure may be anesthetic or narcotic effects. Observations in animals include formation of bladder stones after
repeated oral doses of ethylene glycol. Reports of kidney failure and death in burn patients suggest the ethylene
•
glycol may have been a factor. The use of topical applications containing this material may not be appropriate in
severely burned patients or individuals with impaired renal function.
Cancer Information: Based on data from long-term animal studies, ethylene glycol is not believed to pose a
carcinogenic risk to man.
Teratology (Birth Defects): Exposure to ethylene glycol has caused birth defects in laboratory animals only at
doses toxic to the mother.
Reproductive Effects: Ethylene glycol has not interfered with reproduction in animal studies except at very high
doses.
CHRONIC,PROLONGED OR REPEATED OVEREXPOSURE
Effects of Repeated Overexposure: Repeated inhalation of ethylene glycol mist may produce signs of central
nervous system involvement,particularly dizziness and nystagmus.
Other Effects of Overexposure: repeated skin contact with ethylene glycol may, in a very small proportion of
cases, cause sensitization with the development of allergic contact dermatitis. The incidence is significantly less
than 1%with the undiluted material.
•
ALL WEATHER Antifreeze 2
• 4. FIRST AID MEASURES
Ensure physician has access to this MSDS.
TREATMENT
Eyes: Immediately flush eyes with large amounts of water for 15 minutes, lifting lower and upper lids. Get medical
attention as soon as possible. Contact lenses should never be worn when working with this chemical.
Skin: Flush area of skin contact immediately with large amounts of water for at least 15 minutes while removing
contaminated clothing. If irritation persists after flushing,get medical attention promptly. Wash clothing before re-
use.
Inhalation: If inhaled, immediately remove victim to fresh air and call emergency medical care. If not breathing,
give artificial respiration. If breathing is difficult,give oxygen.
Ingestion: Obtain medical attention immediately. If patient is fully conscious, give two glasses of water. Do not
induce vomiting. If medical advice is delayed, and if the person has swallowed a moderate volume of material (a
few ounces), then give three to four ounces of hard liquor, such as whisky. For children, give proportionally less
liquor,according to weight.
Notes to Physician:
It is estimated that the lethal oral dose to adults is of the order of 1.0 ml/kg. Ethylene glycol is metabolized by
alcohol dehydrogenate to various metabolites including glyceraldehydes,glycolic acid and oxalic acid which cause
an elevated anion-gap metabolic acidosis and renal tubular injury. The signs and symptoms in ethylene glycol
•
poisoning are those of metabolic acidosis, CNS depression, and kidney injury. Urinalysis may show albuminuria,
hematuria and oxaluria. Clinical chemistry may reveal anion-gap metabolic acidosis and uremia. The currently
recommended medical management of ethylene glycol poisoning includes elimination of ethylene glycol and
metabolites,correction of metabolic acidosis and prevention of kidney injury. It is essential to have immediate and
follow up urinalysis and clinical chemistry. There should be particular emphasis on acid-base balance and renal
function tests. A continuous infusion of 5%sodium bicarbonate with frequent monitoring of electrolytes and fluid
balance is used to achieve correction of metabolic acidosis and forced diuresis. As a competitive substrate for
alcohol dehydrogenate, ethanol is antidotal. Given in the early stages of intoxication, it blocks the formulation of
nephrotoxic metabolites. A therapeutically effective blood concentration of ethanol is in the range 100-150 mg/di,
and should be achieved by a rapid loading dose and maintained by intravenous infusion. For severe and/or
deteriorating cases,hemodialysis may be required. Dialysis should be considered for patients who are symptomatic,
have severe metabolic acidosis,a blood ethylene glycol concentration greater than 25 md/dl,or compromise of renal
functions.
A more effective intravenous antidote for physician use is 4-methylpyrazole, a potent inhibitor of alcohol
dehydrogenases,which effectively blocks the formation of toxic metabolites of ethylene glycol. It has been used to
decrease the metabolic consequences of ethylene glycol poisoning before metabolic acidosis coma, seizures, and
renal failure have occurred. A generally recommended protocol is a loading dose of 15 mg/kg followed by 10
mg/kg every 12 hours for 4 doses and then 15 mg/kg every 12 hours until ethylene glycol concentrations are below
20 mg/100 ml. Slow intravenous infusion is required. Since 4-methyplyrozole is dialyzable,increased dosage may
be necessary during hemodialysis. Additional therapeutic measures may include the administration of cofactors
involved in the metabolism of ethylene glycol. Thiamine(100 mg)and pyridoxine(50 mg)should be given every
six hours.
•
ALL WEATHER Antifreeze 3
• Pulmonary edema with hypoxemia has been described in a number of patients following poisoning with ethylene
glycol. The mechanism of production has not been elucidated, but it appears to be non-cardiogenic in origin in
several cases. Respiratory support with mechanical ventilation and positive end expiratory pressure may be
required. There may be cranial nerve involvement in the late stages of toxicity from swallowed ethylene glycol. In
particular, effects have been reported involving the seventh, eighth and ninth cranial nerves, presenting with
bilateral facial paralysis,diminished hearing and dysphasia.
5. FIRE FIGHTING MEASURES
Flammable Properties
Flash Point: 119°C(247°F)
Method Used: Setaflash
Autoignition Temperature: Autoignition temperature for ethylene glycol is 398°C(748°F).
Flammability Limits-%of vapor concentration at which product can ignite in presence of spark.
Lower Flammability Limit: 3.2%
Upper Flammability Limit: 15.3%
Hazardous Combustion Products: Hazardous combustion products may include and are not limited to carbon
monoxide,carbon dioxide and trace amounts of aldehydes and organic acids. When available oxygen is limited,as
in a fire or when heated to very high temperatures by a hot wire or plate, carbon monoxide and other hazardous
compounds such as aldehydes might be generated.
• Extinguishing Media: Water fog or fine spray. Alcohol resistant foams (ATC type) are preferred if available.
General purpose synthetic foams (including AFFF) or protein foams may function, but much less effectively.
Carbon dioxide. Dry chemical. Do not use direct water stream. May spread fire.
Fire Fighting Instructions: No fire and explosion hazards expected under normal storage and handling conditions
(i.e. ambient temperatures). However, ethylene glycol or solutions of ethylene glycol and water can form
flammable vapors with air if heated sufficiently. Keep people away. Isolate fire area and deny unnecessary entry.
Protective Equipment for Fire Fighters: Wear positive-pressure,self-contained breathing apparatus(SCBA)and
protective fire fighting clothing(includes fire-fighting helmet,coat,pants,boots and gloves).
6. ACCIDENTAL RELEASE MEASURES
Protect People: Material is moderately toxic when ingested. Take adequate precautions to keep people,especially
children away from spill site. PVC-coated rubber gloves and monogoggles or face shield can be used during
cleanup of spill site. Product on surfaces can cause slippery conditions. Practice reasonable care and cleanliness.
Avoid breathing spray mists if generated. Keep out of reach of children. Product may become a solid at
temperatures below-18°C(0°F). Do not store near food,foodstuffs,drugs or potable water supplies.
Protect the Environment: Do not dump used product or diluted material into sewers, on the ground, or into any
body of water.
Cleanup: Small spills: Soak up with absorbent material. Large spills: Dike and pump into suitable containers for
• disposal. Ensure compliance with all applicable statues that require notification of appropriate government officials.
ALL WEATHER Antifreeze 4
• 7. HANDLING AND STORAGE
Steps to be Taken in Case Material is Released or Spilled: Eliminate all sources of ignition in vicinity of the
spilled or released fluid.
Other Precautions: Use normal precautions in handling any combustible liquid. Keep container closed when not
in use. Store away from heat or open flame.Product on surfaces can cause slippery conditions. Practice reasonable
care and cleanliness. Avoid breathing spray mists if generated. Keep out of reach of children. Product may
become a solid at temperatures below -18°C (0"F). Do not store near food, foodstuffs, drugs or potable water
supplies.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Protection: Respiratory protection is required if airborne concentration exceeds TLV. At any
detectable concentration any self-contained breathing apparatus with a full face piece and operated in a pressure-
demand or other positive pressure mode or any supplied-air respirator with a full face piece and operated in a
pressure-demand or other positive pressure mode in combination with an auxiliary self-contained breathing
apparatus operated in pressure-demand or other positive pressure mode.
Escape: Any air-purifying full face piece respirator(gas mask)with a chin-style or front-or back-mounted organic
vapor canister or any appropriate escape-type self-contained breathing apparatus.
Skin Protection: Protective gloves recommended when prolonged skin contact cannot be avoided. Polyethylene;
• Neoprene;Nitrile;Polyvinyl alcohol;Natural Rubber,Butyl Rubber. Safety shower should be available.
Eye Protection: Safety goggles and face shield. Emergency eyewash should be available. Contact lenses should
not be worn when working with this chemical.
Engineering Controls: Use general or local exhaust ventilation to meet TLV requirements.
EXPOSURE LIMITS
Component Exposure Limits Skin Form
Ethylene glycol 100 mg/m3 CEILING ACGIH Aerosol
Ethylene glycol 125 mg/m3 CEILING OSHA-vacated
50 ppm CEILING OSHA—vacated
100 mg/m3 CEILING UCC Aerosol and Vapor
Diethylene glycol 50 ppm TWA8 AIHA WEEL Aerosol and Vapor
Diethylene glycol 10 mg/m3 TWA8 AIHA WEEL Aerosol
In the Exposure Limits Chart above, if there is no specific qualifier(i.e., Aerosol) listed in the Form Column for a
particular limit,the listed limit includes all airborne forms of the substance that can be inhaled.
A "blank" in the Skin column indicates that exposure by the cutaneous (skin) route is not a potential significant
contributor to overall exposure.
•
ALL WEATHER Antifreeze 5
• 9. PHYSICAL/CHEMICAL PROPERTIES
Boiling Range: 171 - 175°C(339-348°F)
Freeze Point: -18°C(0°F)
Specific Gravity(Water=1): 1.12
Pounds/Gallons: 9.3
Vapor Pressure(mm of Hg)@ 20C: <0.1
Vapor Density(air-1): 2.1
Water Solubility: Complete
Evaporation Rate(BuAc=1): Nil
%Volatile By Volume: 97.0
Appearance: Green
Odor: Mild
pH(50%Water Solution): 10.5-11.0
10. STABILITY& REACTIVITY DATA
Stability: Stable
Conditions to Avoid: Keep away from flame
Incompatibility(Materials to Avoid): Strong acid or oxidizing agents
Hazardous Decomposition Products: Incomplete combustion may produce CO gas
Hazardous Polymerization: Will not occur
• 11. TOXICOLOGICAL INFORMATION
Skin: The dermal LD50 has not been determined.
Ingestion: The lethal dose in humans is estimated to be 100 ml (3 ozs.). The oral LD50 for rats is in the 6000-
13,000-mg/kg range.
Mutagenicity (The Effects on Genetic Material): In vitro mutagenicity studies were negative. Animal
mutagenicity studies were negative.
Significant Data with Possible Relevance to Humans: Ethylene glycol has been shown to produce dose-related
teratogenic effects in rats and mice when given by gavage or in drinking water at high concentrations or doses. The
no-effect doses for developmental toxicity for ethylene glycol given by gavage over the period of organogenesis has
been shown to be 150 mg/kg/day for the mouse and 500 mg/kg/day for the rat. Also,in a preliminary study to asses
the effects of exposure of pregnant rats and made to aerosis at concentrations of 150, 1000 and 25000 mg/m3 for 6
hours a day throughout the period of organogenesis,teratogenic effects were produced at the highest concentration,
but only in mice. The conditions of these latter experiments did not allow a conclusion as to whether the
developmental toxicity was mediated by inhalation of aerosol percutaneous absorption of ethylene glycol from
contaminated skin, or swallowing ethylene glycol as a result of grooming the wetted coat. In a further study,
comparing effects from high aerosol concentration by whole-body or nose-only exposure, it was shown that nose-
only exposure resulted in maternal toxicity (1000 and 25000 mg/m3) and developmental toxicity with minimal
evidence of teratogenicity (2500 mg/m3). The no-effects concentration (based on maternal toxicity) was 500
mg/m3. In a further study in mice, no teratogenic effects could be produced when ethylene glycol was applied to
• skin of pregnant mice over the period of organogenesis. The above observations suggest that ethylene glycol is to
be regarded as an animal teratogen. There is currently no available information to suggest that ethylene glycol has
caused birth defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental
ALL WEATHER Antifreeze 6
toxicity. Exposure to high aerosol concentrations is only minimally effective in producing developmental toxicity.
• The major route for producing developmental toxicity is perorally. Two chronic feeding studies, using rats and
mice, have not produced any evidence that ethylene glycol causes dose-related increases in tumor incidence or a
different pattern of tumors compared with untreated controls. The absence of carcinogenic potential for ethylene
glycol has been supported by numerous in vitro genotoxicity studies showing that it does not produce mutagenic or
clastogenic effects.
A chronic dietary feeding study of diethylene glycol with rats showed mild kidney injury at 1%, while
concentrations of 2%and 4%caused more marked kidney injury. In addition,at 2%and 4%of diethylene glycol in
the diet, some rats developed benign papillary tumors in the urinary bladder. These have been attributed to the
presence of urinary bladder calcium oxalate stones. No evidence for carcinogenicity was found with a chronic skin-
painting study with diethylene glycol in mice. The absence of a direct chemical carcinogenic effect addords with
the results in vitro genotoxicity studies that show that it does not produce mutagenic or clastogenic effects. A
feeding study employing up to 5.0% diethylene glycol in the diet failed to produce any teratogenic effects. In a
mouse continuous breeding study with large doses of diethylene glycol in drinking water, there was evidence for
reproductive toxicity at 3.5%(equivalent to 6.1 g/kg/day)as reduced number of litter, live pups per litter and live
pup weight. No such effects were seen at 1.75%(approximately 3.05 g/kg/day). The relevance of these very high
dosages to human health is uncertain. Pregnant rats receiving undiluted diethylene glycol by gavage over the period
of organogenesis had toxic effects at 4.0 and 8.0 mI/kg/day as mortality, decreased body weight, decreased food
consumption increased water consumption and increased liver and kidney weights. Fetotoxicity was seen only at
these maternally toxic dosages. Decreased fetal body weight occurred at 8.0 ml/kg/day, and increased skeletal
variants at 4.0 and 8.0 ml/kg/day. No embryotixic or teratogenic effects were seen. Neither maternal toxicity nor
fetotoxicity occurred at 1.0 m1/kg/day. In a study with mice also receiving undiluted diethylene glycol over the
period of organogenesis,maternal toxicity occurred at 2.5 and 10.0 mUkg/day,but not at 0.5 mI/kg/day. Definitive
developmental toxicity was not seen in this species.
• ACUTE TOXICITY
Peroral: The lethal dose in humans is estimated to be 3 oz.or 100 ml.
Rat: LD50(6000—13000)mg/kg
Percutaneous:
Rabbit: LD50=>22270 mg/kg;24 h occluded
Inhalation:
Rat: 8-hour exposure,substantially saturated vapor studies,dynamic generation method
Mortality: 0/6
Inhalation: Mist/vapor study,rat,at 170°C,8-hour exposure=2.2 mg/1
Mortality: 0/6
Inhalation:
Rat: 8-hour exposure,fog= 10000 ppm;65°-70°C
Mortality: 0/6
•
ALL WEATHER Antifreeze 7
• IRRITATION
Skin:
Rabbit: 24-hour occluded contact,0.5 ml
Results: Minor erythema and edema
Skin:
Human: Primary irritation patch test,48-hour occluded,0.2 ml
Results: Evidence of irritation
Eye:
Rabbit: 0.1 ml
Results: Minor transient iritis,conjunctival irritation with discharge
REPEATED EXPOSURE
In a 7-day dietary study with rats, a significant increase in kidney weights in females was observed at 5.0 gm/kg.
The NOEL was 2.5 gm/kg.
In a 24-month dietary study with rats, increased mortality in males was observed at the highest dose, 1.0 gm/kg/day.
There were multiple signs: mineralization of several organs, including the cardiac vessels, cardiac muscle, vas
deferens, stomach and pulmonary vessels; cellular hyperplasia of the parathyroids, hemosiderosis of the spleen,
myocardial fibrosis, portal fibrosis of the liver, bile duct hyperplasia and hydronephrosis and oxylate nephrosis of
the kidneys. Ethylene glycol was not oncogenic.
In a 90-day dietary study with dogs,repeated exposures to 2.5 gm/kg resulted in acute renal failure and deaths. The
• NOAEL was 1.0 gm/kg.
SENSITIZATION(ANIMAL AND HUMAN STUDIES)
Repeated skin contact with ethylene glycol may, in a very small proportion of cases, cause sensitization with the
development of allergic contact dermatitis. The incidence is significantly less than 1%with the undiluted material.
REPRODUCTIVE TOXICITY
A three-generation study indicated that ethylene glycol did not affect reproductive parameters at dietary
concentrations up to 1.0 gm/kg/day in any generation.
CHRONIC TOXICITY AND CARCINOGENICITY
Two chronic feeding studies,using rats and mice,have not produced any evidence that ethylene glycol causes dose-
related increases in tumor incidence or a different pattern of tumors compared with untreated controls. The absence
of a carcinogenic potential for ethylene glycol has been supported by numerous in vitro genotoxicity studies
showing that it does not produce mutagenic or clastogenic effects.
GENETIC TOXICOLOGY
In Vitro: Ethylene glycol was devoid of genotoxic activity in an Ames test, forward gene mutation and sister
chromatid exchange(SCE)studies in Chinese Hamster Ovary(CHO)cells and an in vitro cytogenetics study.
•
ALL WEATHER Antifreeze 8
• In Vivo: Ethylene glycol by three different routes (intravenous, peroral and percutaneous) demonstrates apparent
first-order pharmacokinetic behavior for the disposition in and the elimination from the plasma. Dose-dependent
changes occur for the elimination of metabolites in the urine and as 14CO2 after single doses for the intravenous and
peroral,but not the percutaneous route. The hypothesis from literature sources exists that developmental toxicity is
caused by a metabolite of ethylene glycol, called glycolic acid, and not parent ethylene glycol. Under most
conditions of ethylene glycol exposure, the glycolic acid metabolite is present in the blood in very low levels.
However, it can become the major metabolite following large doses of ethylene glycol due to saturation of glycolic
acid oxidation and/or elimination. When levels of this acidic metabolite exceed the capacity of matemal blood
buffers to neutralize it, a maternal metabolic acidosis ensues, which has been hypothesized to be the true agent
responsible for ethylene glycol induced developmental toxicity. Research suggests that ethylene glycol
developmental toxicity is due to a dose-rate dependent toxicokinetic shift leading to glycolate accumulation and
metabolic acidosis.
ADDITIONAL STUDIES
Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage
or in drinking water at high concentrations or doses. The no-effect doses for developmental toxicity for ethylene
glycol given by gavage over the period of organogenesis has been shown to be 150 mg/kg/day for the mouse and
500 mg/kg/day for the rat. Also, in a preliminary study to assess the effects of exposure of pregnant rats and mice
to aerosols at concentrations of 150, 1000 and 2500 mg/m3 for 6 hours a day throughout the period of
organogenesis,teratogenic effects were produced at the highest concentration,but only in mice. The conditions of
these latter experiments did not allow a conclusion as to whether the developmental toxicity was mediated by
inhalation of aerosol,percutaneous absorption of ethylene glycol from contaminated skin,or swallowing of ethylene
glycol as a result of grooming the wetted coat. In a further study, comparing effects from high aerosol
concentration by whole-body or nose-only exposure, it was shown that nose-only exposure resulted in maternal
• toxicity(1000 and 2500 mg/m3)and developmental toxicity with minimal evidence of teratogenicity(2500 mg/m3).
The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no
teratogenic effects could be produced when ethylene glycol was applied to the skin of pregnant mice over the period
of organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal teratogen.
There is currently no available information to suggest that ethylene glycol has caused birth defects in humans.
Cutaneous application of ethylene glycol is ineffective in producing developmental toxicity. Exposure to high
aerosol concentrations is only minimally effective in producing developmental toxicity.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL FATE
Movement& Partitioning: Bioconcentration potential is low(BCF less than 100 or Log Kow less than 3). Log
octanol/water partition coefficient (log Kow) is -1.36. Henry's Law Constant (H) is 6.0E-08 atm-m3/mol.
Bioconcentration factor(BCF)is 10 in golden orfe.
Degradation & Transformation: Biodegradation under aerobic static laboratory conditions is high (BOD20 or
BOD28/ThOD greater than 40%). 5-Day biochemical oxygen demand (BOD5) is 0.78 p/p. 10-Day biochemical
oxygen demand (BOD10) is 1.06 p/p. 20-Day biochemical oxygen demand (BOD20) is 1.15 p/p. Theoretical
oxygen demand(THOD)is calculated to be 1.29 p/p. Biodegradation may occur under both aerobic and anaerobic
conditions (in either the presence or absence of oxygen). Inhibitory concentration (IC50) in OECD "Activated
Sludge, Respiration Inhibition Test"(Guideline#209)is< 1000 mg/L. Degradation is expected in the atmospheric
environment within days to weeks.
•
ALL WEATHER Antifreeze 9
• Ecotoxicology: Material is practically non-toxic to aquatic organisms on an acute basis (LC50 greater than 100
mg/L in most sensitive species). Acute LC50 for fathead minnow (Pimephales promelas) is 51000 mg/L. Acute
LC50 for bluegill (Lepomis macrochirus)is 27549 mg/L. Acute LC50 for rainbow trout(Oncorhynchus mykiss)is
about 18000-46000 mg/L. Acute LC50 for guppy (Poecilia reticulata) is 49300 mg/L. Acute LC50 for water flea
(Daphnia magna)is 46300-51100 mg/L. Acute LC50 for the cladoceran Ceriodaphnia dubia is 10000-25800 mg/L.
Acute LC50 for crayfish is 91430 mg/L. Acute LC50 for brine shrimp (Artemia salina) is 20000 mg/L. Acute
LC50 for golden orfe(Leuciscus idus) is greater than 10000 mg/L. Acute LC50 for goldfish(Carassius auratus) is
greater than 5000 mg/L. Growth inhibition EC50 for green alga Selenastrum capricomutum is 9500-13000 mg/L.
HOD(%Oxygen Consumption):
Day 5 Day 10 Day 15 Day 20 Day 30
51% 80% 97%
ECOTOXICITY
Toxicity to Micro-organisms:
Bacterial/NA: 16 h;IC50
Result Value: >10000 mg/I
Toxicity to Aquatic Invertebrates:
Daphnia:48 h;LC50
Result Value: >100000 mg/I
Toxicity to Fish
•
Fathead Minnow: 94 h;LC50
Result Value: 70000 mg/1
FURTHER INFORMATION
Chemical Oxygen Demand(COD)—Measured: 1.29 mg/mg
Theoretical Oxygen Demand(THOD)—Calculated: 1.30 mg/mg
Octanol/Water Partition Coefficient—Measured: -1.36
13. DISPOSAL CONSIDERATIONS
DO NOT discharge to sewer. Wear appropriate personal protection. Take up with sand, vermiculite, or similar
inert material. Dispose in accordance with federal,state and local regulations.
•
ALL WEATHER Antifreeze 10
14. TRANSPORT INFORMATION
• U.S. DEPARTMENT OF TRANSPORTATION
Non-Bulk
Not regulated by the US D.O.T.(in quantities under 5,000 lbs in any one inner package)
Bulk
Proper Shipping Name: Environmentally Hazardous Substance,LIQUID N.O.S. (ETHYLENE GLYCOL)
Technical Name: ETHYLENE GLYCOL
ID Number: UN 3082
Hazard Class: 9
Packing Group: PG III
Reportable Quantity: 5,000 lb.
IATA
Non-Bulk
Not Regulated by IATA
IMDG
Non-Bulk
Not regulated by IMDG(in quantities under 5,000 lbs in any one inner package)
15. REGULATORY INFORMATION
• THIS PRODUCT CONTAINS COMPONENT(S)CITED ON THE FOLLOWING REGULATIONS.
Chemical Name Cas Number
Ethylene Glycol 107-21-1
United States-TSCA
Inventory: Listed
Water Standards: No data available
Atmospheric Standards: Clean Air Act(1990)-List of Hazardous Air Contaminants: listed
CERCLA: Reportable Quantity(RQ): 5,000 pounds(532 gallons)
OSHA Hazard Communication
Standard: This product is a "hazardous chemical" as defined by the OSHA Hazard
Communication Standard,29 CFR 1910.1200.
SARA Title HI: Section 311/312-Categories: Acute hazard;chronic hazard
Section 312 - Inventory Reporting: Ethylene glycol is subject to Tier I and/or
Tier II annual inventory reporting.
Section 313 - Emission Reporting: Ethylene glycol is subject to Form R
reporting requirements.
• Section 302-Extremely Hazardous Substances: Ethylene glycol is not listed.
ALL WEATHER Antifreeze 11
State Right-To-Know:
• California-Exposure Limits-Ceilings: vapor-50 ppm ceiling; 125 mg/m3 ceiling
Director's List of Hazardous Substances: listed
Florida-Hazardous Substances List: listed
Massachusetts-Right-to-Know List: listed
Minnesota-Haz. Subs.List: listed(particulate and vapor)
New Jersey-Right-to-Know List(Total): Present greater than 1.0%
Pennsylvania Right-to-Know List: environmental hazard
Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations(CPR)and the MSDS contains all the information required.
WHMIS Information: D2A - material has potential toxic effects. Refer elsewhere in the MSDS for specific
warnings and safe handling information. Refer to the employer's workplace education program.
California Proposition 65(Safe Drinking Water and Toxic Enforcement Act of 1986): The normal consumer
use of this product does not result in exposure to chemicals known to the state of California to cause Cancer and/or
reproductive harm above the significant risk level for carcinogens or the maximum allowable dose levels for
reproductive toxins. Warnings are not required for consumer packaging. However, industrial or other occupational
•
use of this product at higher frequency and using larger quantities of this product may result in exposures exceeding
these levels and are labeled accordingly.
California SCAQMD Rule 443.1 (South Coast Air Quality Management District Rule 443.1, Labeling of
Materials Containing Organic Solvents):
VOC: Vapor pressure 0.06 mmHg at 20°C
• 1113.38 g/I
16. OTHER INFORMATION
Contact:Thomas Cholke Phone: (847)559-2225
Old World Industries,Inc. makes no warranty,representation or guarantee as to the accuracy,sufficiency or
completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity
and suitability of his own use,handling and disposal of this product. Since actual use by others is beyond our
control, no warranty,expressed or implied, is made by Old World Industries, Inc. as to the effects of such
use,the results to be obtained or the safety and toxicity of this product,nor does Old World Industries,Inc.
assume liability arising out of the use by others of this product referred to herein. The data in this MSDS
relates only to the specific material designated herein and does not relate to use in combination with any
other material or in any process.
•
ALL WEATHER Antifreeze 12
• Initial Preparation Date: 11/10/2004
Last Revision Date: None
Effective Date: 8/1/2005
MATERIAL SAFETY DATA SHEET
PRODUCT IDENTITY: PEAK® -20° WASH
1. CHEMICAL PRODUCT& COMPANY INFORMATION
OLD WORLD INDUSTRIES, INC.
4065 COMMERCIAL AVENUE
NORTHBROOK, ILLINOIS 60062
PHONE: 847-559-2000
EMERGENCY PHONE: 1-800-424-9300(CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
MATERIAL CAS# %BY WT 8-Hour Time Weijhted Avg. (TWA)
• Methanol 67-56-1 <33 200 ppm (260 Mg/M3)
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Slight odor. May be fatal if swallowed Vapors can cause eye irritation.
LD50 Rat(Oral): 16,884 mg/kg (33%methanol concentration)
LD50 Rabbit(Skin): 60 g/kg (33%methanol concentration)
Carcinogency: No
National Toxicology Program: No
International Agency for Research on Cancer: No
OSHA Regulated: Yes
•
Peak Wash-20
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• HAZARD RATING SYSTEM
HMIS: HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: A
KEY: 0-Minimal 1 -Slight 2-Moderate 3 -Serious 4-Severe A-Safety
glasses
POTENTIAL HEALTH EFFECTS
Health Hazards(Acute and Chronic):
Acute:
Acute methanol intoxication is manifested initially by signs of narcosis. This is followed by a latent period in which
formic acid accumulates in the body causing metabolic acidosis. Severe abdominal, leg, and back pain occur and
visual degeneration can lead to blindness.
1. Humans—Ingestion of 80 to 150 mL of methanol is usually fatal to humans (HSDB 1994). One worker
died from exposure to vapor ranging from 4,000 to 13,000 ppm over 12 hours (ACGIH 1991). The
concentration of 4,000 ppm is roughly equivalent to a total of 1,140 mg/kg over the 12-hour period (see
end note 2). Poisoning by nonlethal doses can be described in three stages: (1)narcotic stage similar to
ethanol;(2)latent period of 10-15 hours;(3)visual disturbances and central nervous system lesions(Rowe
and McCollister 1981). Visual disturbances can lead to blindness due to edema of the retina and atrophy of
the optic nerve head (HSDB 1994). Third-stage CNS lesions include headache, dizziness, abdominal,
back, and leg pain, delirium that can lead to coma, and nausea (HSDB 1994). Formic acid production
• causes severe metabolic acidosis(Rowe and McCollister 1981).
2. Animals—Oral LD50 values for methanol is animals are 0.4 g/kg in the mouse,6.2 to 13 g/kg in the rat,
14.4 g/kg in the rabbit,and 2 to 7 g/kg in the monkey(Rowe and McCollister 1981). The LD50 for dermal
application to rabbits is 20 mL/kg(approximately 16 g/kg)(Rowe and McCollister 1981). Dose-response
data for inhalation vary with species, dose, and duration (8,800 ppm for 8 hours to 152,800 ppm for 94
minutes). Symptoms of intoxication include incoordination, salivation, lethargy, narcosis, and death
(Rowe and McCollister 1981).
Subchronic/Chronic:
Chronic exposure to methanol,either orally or by inhalation,causes headache, insomnia,gastrointestinal problems,
and blindness in humans and hepatic and brain alterations in animals. EPA has derived an oral RfD (reference
dose) (see end note 3) for methanol of 0.5 mg/kg/day, based on the absence of liver and brain effects in animals
exposed by mouth to 500 mg/kg/day.
1. Humans—"Chronic"exposure to methanol vapors(no time or dose given)caused conjunctivitis,headache,
giddiness, insomnia, gastric disturbances, and bilateral blindness (ACGIH 1991). Marked vision loss
occurred in one worker exposed to 1,200 to 8,000 ppm vapor for 4 years(ACGIH 1991).
2. Animals — No effects were seen in rats given 1% (approximately 140 mg/kg/day) methanol in drinking
water for 6 months (Rowe and McCollister 1981). Hepatic abnormalities (proteinic degeneration, altered
RNA metabolism) occurred in rhesus monkeys given 3 to 6 g/kg for 3 to 20 weeks and in rats given 10,
100,or 500 mg/kg/day for one month(Rowe and McCollister 1981). Rabbits chronically fed methanol(no
dose or time given)had increasing blood levels, brain and eye edema, and myelin thinning(HSDB 1994).
Male and female rats were gavaged with 100, 500, or 2,500 mg/kg/day for 90 days (U.S. EPA 1994).
Increased levels of SGPT and SAP as well as decreased brain weights were seen in both sexes at the
• highest dose; a no-observed-adverse effect level (NOAEL) for the study was 500 mg/kg/day. Based on
Peak Wash-20
2
• these data,the U.S. EPA(1994)calculated a chronic RID(see end note 4)for methanol of 0.5 mg/kg/day.
No toxic effects were seen in dogs exposed by inhalation to either 10,000 ppm for 3 minutes, 3x/day, for
100 days or to 450 or 500 ppm, 8 hours/day for 379 days(Rowe and McCollister 1981). Ultrastructural
changes were observed in the photoreceptor cells of rabbits exposed to 46.6 ppm for 6 months(Rowe and
McCollister 1981). Rowe and McCollister (1981) concluded that the effects of combined oral and
inhalation exposure appear to be additive. Rats exposed by inhalation to 16.8 ppm, 4 hours/day, for 6
months and administered 0.7 mg/kg/day orally had changes in blood morphology, oxidation-reduction
processes,and liver function(Rowe and McCollister 1981).
Carcinogenicity:
No information was found on the carcinogenicity of methanol in the secondary sources searched.
1. Humans—No information was found in the secondary sources searched concerning the carcinogenicity of
methanol to humans.
2. Animals—No information was found in the secondary sources searched concerning the carcinogenicity of
methanol to animals. The NTP has assigned a project leader for methanol and the design of the study is in
progress(NTP 1994).
4. FIRST AID MEASURES
Ensure physician has access to this MSDS.
Routes of Entry: Inhalation,Skin,Ingestion
• Signs and Symptoms of Exposure:
Eye Contact: May cause eye irritation.
Skin Contact: Frequent or prolonged contact may cause skin irritation experienced as burning, drying,
cracking and redness.
Inhalation: May cause nose and throat irritation. High concentrations may cause acute central nervous
system depression characterized by headaches,dizziness,nausea and confusion.
Skin Absorption Health Risks and Symptoms of Exposure: Harmful quantities of Methyl Alcohol may
affect eyes and central nervous system.
Ingestion Health Risks and Symptoms of Exposure: May cause nausea, abdominal pain, headache,
shortness of breath,visual impairment and blindness. Severe poisoning can cause coma and death.
Medical Conditions Generally Aggravated by Exposure: Ingestion of large amounts of Methyl Alcohol
has been shown to damage organs including liver, kidney, pancreas, heart, lungs and brain. Although this
rarely occurs,survivors of severe intoxication may suffer permanent neurological damage. Overexposure may
aggravate pre-existing disorders of the eyes.
People have died as a result of drinking large amounts of methanol. Drinking smaller, non-lethal amounts of
methanol adversely affects the human nervous system. Effects range from headaches to incoordination similar to
• that associated with drunkenness. Delayed effects such as severe abdominal, leg, and back pain can follow the
Peak Wash-20
3
• inebriation effects of methanol. Loss of vision and even blindness can also occur after exposure to amounts of
methanol causing inebriation. These effects are not likely to occur at levels of methanol that are normally found in
the environment.
Human health effects associated with breathing or otherwise consuming smaller amounts of methanol over long
periods of time are not known. Workers repeatedly exposed to methanol have experienced several adverse effects.
Effects range from headaches to sleep disorders and gastrointestinal problems to optic nerve damage. Laboratory
studies show that repeat exposure to large amounts of methanol in air or in drinking water cause similar adverse
effects in animals.
TREATMENT
Eyes: Flush with large quantities of water for 15 minutes and seek medical attention.
Skin: Remove contaminated clothing and wash contaminated skin with large amounts of soap and water. If
irritation persists,get medical attention. Launder clothing before reuse.
Inhalation: Remove to fresh air. If breathing has stopped,apply artificial respiration. If breathing is difficult,give
oxygen provided a qualified operator is available. Get medical attention.
Ingestion: Notes to Physician: This product contains methanol which can cause intoxication and central nervous
system depression. Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause
metabolic acidosis,visual disturbances and blindness. Since metabolism is required for these toxic symptoms,their
onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway
and has been used to prevent methanol metabolism. Ethanol administration is indicated in symptomatic patients or
• at blood hemodialysis. Preexisting disorders of the following organs (or organ systems) may be aggravated by
exposure to this material: skin, lung (for example, asthma-like conditions), liver, kidney, central nervous system,
pancreas, heart). Exposure to this material may aggravate any preexisting condition sensitive to a decrease in
available oxygen,such as chronic lung disease,coronary artery disease or anemias.
If swallowed, induce vomiting of conscious patient immediately by giving two glasses of water and pressing finger
down throat. Drink a large amount of water,milk or sodium bicarbonate to dilute material in stomach. (Never give
anything by mouth to an unconscious person.) Call Poison Control Center, hospital emergency room or physician
immediately.
5. FIRE FIGHTING MEASURES
FIRE ct EXPLOSION HAZARD DATA
Flammable Properties
Flash Point: 92°F
Method Used: TCC
Flammability Limits-%of vapor concentration at which methanol can ignite in presence of spark.
LEL: 6.0%
UEL: 36.0%
•
Peak Wash—20
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• Hazardous Combustion Products: Methanol
Extinguishing Media: Foam, dry chemical, carbon dioxide or any Class B extinguishing agent. Water may be
unsuitable as an extinguishing medium but helpful in keeping adjacent containers cool
Fire Fighting Instructions: Use water spray to cool fire exposed containers.
Water may be ineffective but may be used to cool exposed containers to prevent pressure buildup and possible auto-
ignition or explosion when exposed to extreme heat. If water is used,fog nozzles are preferable.
Unusual Fire and Explosion Hazards: Handle as flammable liquid. Vapors are heavier than air and may travel
along the ground or may be moved by ventilation. Vapors form an explosive mixture in air between the upper and
lower explosive limits which can be ignited by many sources,such as pilot lights,open flames,electrical motors and
switches.
Protective Equipment For Fire Fighters: Wear NIOSH approved self-contained breathing apparatus with full
face piece and protective clothing to prevent contact with skin and eyes.
6. ACCIDENTAL RELEASE MEASURES
Small Spill
Absorb liquid on vermiculite,floor absorbent or other absorbent material.
. Large Spill
Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks). Persons not wearing
protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source.
Prevent from entering drains, sewers, streams or other bodies of water. Prevent from spreading. If runoff occurs,
notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb
unrecoverable product. Transfer contaminated absorbent, soil and other materials to containers for disposal.
Prevent run-off to sewers,streams or other bodies of water. If run-off occurs,notify proper authorities as required,
that a spill has occurred.
7. HANDLING AND STORAGE
Do not swallow. Store in closed containers in a cool, dry, well-ventilated area. Keep away from sparks and open
flame.
Respiratory Protection: Use approved NIOSH respirator when TLV is exceeded.
Ventilation: Provide sufficient ventilation to maintain exposure below TLV.
Protective Gloves: Wear appropriate impermeable gloves.
Eye Protection: Use chemical safety glasses,goggles and face shields for eye protection.
Other Protective Clothing or Equipment: Long sleeves and apron are recommended.
•
Peak Wash-20
5
• Work/Hygienic Practices: Avoid prolonged or repeated skin contact.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection:
Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also
permit other type safety glasses. Consult your safety representative.
Skin Protection:
Wear resistant gloves (consult your safety equipment supplier). To prevent repeated or prolonged skin contact,
wear impervious clothing and boots.
Respiratory Protection:
If workplace exposure limit(s) of product or any component is exceeded (see exposure guidelines), a
NIOSH/MSHA approved air supplied respiratory is advised in absence of proper environmental control. OSHA
regulations also permit other NIOSH/MSHA respirators (negative pressure type) under specified conditions (see
your industrial hygienist). Engineering or administrative controls should be implemented to reduce exposure.
Engineering Controls:
Provide sufficient mechanical(general and/or local exhaust)ventilation to maintain exposure below TLV(s).
Exposure Guidelines:
• Component
Methyl Alcohol(67-56-1)
OSHA VPEL 200.000 ppm—TWA(skin)
OSI-IA VPEL 250.000 ppm—STEL(skin)
ACGIH TLV 200.000 ppm—TWA(skin)
ACG1H TLV 250.000 ppm—STEL(skin)
9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Range: 177° F- 181° F
Specific Gravity(Water=1): .96 @ 20°C
Vapor Pressure(mm of Hg): 43 @ 20°C
Vapor Density(Air-1): Heavier than air
Water Solubility: Soluble
Appearance: Clear blue liquid
Odor: Mild alcohol odor
Evaporation Rate: Greater than m-butyl acetate
10. STABILITY AND REACTIVITY
Stability: Stable
Conditions to Avoid: Ignition sources,such as heat,sparks and flames
•
Peak Wash-20
6
• Incompatibility(Materials to Avoid): Strong acids and strong oxidizing agents
Hazardous Decomposition Products: Burning can produce carbon monoxide and/or carbon dioxide. Carbon
monoxide is highly toxic if inhaled;carbon dioxide in sufficient concentrations an act as an asphyxiant.
Hazardous Polymerization: Will not occur
11. TOXICOLOGICAL INFORMATION
Mutagenicity(The Effects On Genetic Material):
Genotoxicity:
Methanol was negative for cell transformation in Syrian hamster embryo cells (clonal assay and viral enhanced),
sister chromatid exchange in vitro, and for aneuploidy and chromosome aberrations in Neurospora crassa
(GENETOX 1992). The micronucleus test and the assay for chromosome aberrations in mammalian polychromatic
erythrocytes were inconclusive(GENETOX 1992).
Developmental/Reproductive Toxicity:
No information was found on the developmental toxicity of methanol in humans. Methanol can cause adverse
effects in the developing offspring in rats at doses that cause overt maternal intoxication.
. 1. Humans — No information was found in the secondary sources searched regarding the developmental or
reproductive toxicity of methanol to humans. However, one of the breakdown products of the artificial
sweetener aspartame is methanol. Increased blood methanol levels did not lead to increased formic acid
levels in women receiving up to 200 mg/kg aspartame(no other details reported)and no evidence of fetal
risk was detected(HSDB 1994).
2. Animals — Rats were exposed by inhalation, 7 hours/day, to 5,000 or 10,000 ppm methanol on gestation
days 1-19 or to 20,000 ppm on days 7-15. Maternal intoxication (unsteadiness) occurred at the highest
dose and coincided with extra or rudimentary ribs and urinary or cardiovascular defects in the fetuses
(ACGIH 1991). Male rats had significantly lowered testosterone levels after inhalation exposure to 200
ppm methanol for 6 weeks; at 10,000 ppm a change in luteinizing hormone was also observed (HSDB
1994).
Neurotoxicity:
Methanol causes central nervous system depression in humans and animals as well as degenerative changes in the
brain and visual system.
1. Humans — Methanol causes narcosis similar to ethanol intoxication and nonlethal doses can lead to
blindness. Autopsy of individuals after lethal doses revealed edema and hyperemia of the brain and
degeneration of the ganglion cells of the retina(Rowe and McCollister 1981).
2. Animals — Acute methanol intoxication in animals causes CNS depression as observed by narcosis,
incoordination, lethargy,drowsiness,and prostration(Rowe and McCollister 1981).
•
Peak Wash-20
7
• Significant Data With Possible Relevance To Humans:
Pharmacokinetics:
1. Absorption — Methanol is readily absorbed after oral, inhalation, or dermal exposure. Oral doses in
humans of 71 to 84 mg/kg resulted in blood levels of 4.7 to 7.6 mg/100 mL of blood within 3 hours(Rowe
and McCollister 1981). Inhalation of 500 to 1,000 ppm methanol for 3 to 4 hours gave urine
concentrations of 1 to 3 mg methanol/100 mL of urine at the end of exposure (Rowe and McCollister
1981). Based on urinary methanol levels,the rate of absorption of the chemical appears to be proportional
to the concentration of vapor inhaled (HSDB 1994). The rate of dermal absorption increased for 35
minutes then decreased over the next 25 minutes(no other details given)(HSDB 1994).
2. Distribution—Methanol distributes rapidly in dogs exposed to 4,000 to 15,000 ppm for 12 hours to 5 days;
the highest concentrations of the chemical were found in blood,eye fluid,bile,and urine(HSDB 1994).
3. Metabolism —Methanol is oxidized in the human liver by the enzyme alcohol dehydrogenase(Rowe and
McCollister 1981). Metabolic products include formaldehyde and formic acid(HSDB 1994). The rate of
metabolism for methanol(25 mg/kg/hr)is much slower than for ethanol(175 mg/kg/hr)and is independent
of concentrations in the blood(HSDB 1994). Formic acid is responsible for the toxic effects of methanol
(ACGIH 1991).
4. Excretion— Methanol is excreted either as parent compound in the urine or expired air, or as the formic
acid metabolite in urine(Rowe and McCollister 1981; HSDB 1994). The amount of formic acid excreted
varies greatly with species from I% in rabbits to 20%in dogs; humans are intermediate(HSDB 1994). In
humans, the half-life of methanol elimination in expired air after oral or dermal exposure is 1.5 hours
(HSDB 1994).
• 12. ECOLOGICAL INFORMATION
ENVIRONMENTAL FATE
Methanol evaporates when exposed to air. It dissolves completely when mixed with water. Most direct releases of
methanol to the environment are to air. Methanol also evaporates from water and soil exposed to air. Once in air,it
breaks down to other chemicals. Microorganisms that live in water and in soil can also break down methanol.
Because it is a liquid that does not bind well to soil, methanol that makes it way into the ground can move through
the ground and enter groundwater. Plants and animals are not likely to store methanol.
Methanol by itself is not likely to cause environmental harm at levels normally found in the environment. Methanol
can contribute to the formation of photochemical smog when it reacts with other volatile organic carbon substances
in air.
•
Peak Wash-20
8
• Movement&Partitioning:
The miscibility of methanol in water and a low KOC (9) indicate that the chemical will be highly mobile in soil
(HSDB 1994). Volatilization half-lives from a model river and an environmental pond were estimated at 4.8 days
and 51.7 days, respectively (HSDB 1994). Methanol can be removed from the atmosphere in rain water (HSDB
1994).
Degradation&Transformation:
1. Air— Once in the atmosphere, methanol exists in the vapor phase with a half life of 17.8 days (HSDB
1994). The chemical reacts with photochemically produced hydroxyl radicals to produce formaldehyde
(HSDB 1994). Methanol can also react with nitrogen dioxide in polluted air to form methyl nitrite(HSDB
1994).
2. Soil — Biodegradation is the major route of removal of methanol from soils. Several species of
Methylobacterium and Methylomonas isolated from soils are capable of utilizing methanol as a sole carbon
source(CHEMFATE 1994).
3. Water— Most methanol is removed from water by biodegradation. The degradation products of methane
and carbon dioxide were detected from aqueous cultures of mixed bacteria isolated from sewage sludge
(CHEMFATE 1994). Aerobic,Gram-negative bacteria(65 strains)isolated from seawater,sand,mud,and
weeks of marine origin utilized methanol as a sole carbon source (CHEMFATE 1994). Aquatic
hydrolysis,oxidation,and photolysis are not significant fate processes for methanol(HSDB 1994).
4. Biota— Bioaccumulation of methanol in aquatic organisms is not expected to be significant based on an
• estimated bioconcentration factor of 0.2(HSDB 1994).
Ecotoxicology:
1. Toxicity to Aquatic Organisms — Methanol has low acute toxicity to aquatic organisms; lethal
concentrations are much greater than 100 mg/L. Ninety-six hour LC50 values for fish are 28,100 mg/L for
Pimephales promelas (fathead minnow), 20,100 mg/L for Oncorhynchus mykiss (rainbow trout), and
>28,000 mg/L for Albumus albumus(bleak)(AQUIRE 1994). Forty-eight hour LC50 values for Cyprinus
carpio (common carp) and Carassius auratus (goldfish) are 28,000 mg/L and 1,700 mg/L, respectively
(AWQUIRE 1994). Growth inhibition occurred for 4 strains of Anabaena(blue-green algae)over a range
of EC50s of 2.57%-3.13%for 10-14 days(AQUIRE 1994). The LC50 for Anemia salina(brine shrimp)is
>10,000 mg/L in 24 hours and that for Culex restuans (mosquito) is 20,000 mg/L in 18 hours(AQUIRE
1994).
2. Toxicity to Terrestrial Organisms—No information was found in the secondary sources searched regarding
the toxicity of methanol to terrestrial organisms. However,based on the range of oral LD50s,0.4 to 14.2
g/kg, for monkeys,rats,mice,and rabbits(Rowe and McCollister 1981), it is unlikely that methanol would
be toxic to terrestrial animals at environmental levels.
3. Abiotic Effects—Methanol reacts with nitrogen dioxide in polluted atmospheres to produce methyl nitrite
(HSDB 1994). According to the definition provided in the Federal Register(1992),methanol is a volatile
organic compound (VOC) substance. As a VOC, methanol can contribute to the formation of
photochemical smog in the presence of other VOCs.
• 13. DISPOSAL CONSIDERATIONS
Peak Wash—20
9
• Waste Disposal Method: Dispose in accordance with federal,state and local regulations.
14. TRANSPORT INFORMATION
(U.S. D.O.T.)—U.S.Department of Transportation
Proper Shipping Name: Consumer Commodity ORM-D
Per 49 CFR Part 173.10(PG III, inner packaging no more than 5.0 L)
(IATA)International Air Dangerous Good Regulations
Proper Shipping Name: Flammable Liquid,n.o.s.(Methanol)
ID#: UN 1993
Class: 3
Hazard Label: Flammable Liquid
PG: Ill
Ltd.Qty.Packaging Instruction: Y309(Max qty.per package 10L)
Special Provision: A3
(IMDG)International Maritime Dangerous Goods
Not IMDG regulated according to IMDG Code—Page 3003 Part 1.1.1
•
15. REGULATORY INFORMATION
THIS PRODUCT CONTAINS COMPONENT(S)CITED ON THE FOLLOWING REGULATIONS:
CHEMICAL NAME CAS NUMBER
Methanol 67-56-1
U.S. Federal Regulations
TSCA(Toxic Substances Control Act)Status—TSCA(UNITED STATES)
The intentional ingredients of this product are listed.
CERCLA RQ—40 CFR 302.4(a)
Component RQ(Ibs)
Methyl Alcohol 5,000
SARA 302 Components—40 CFR 355 Appendix A
None
Section 311/312 Hazard Class—40 CFR 370.2
Immediate(X) Delayed(X) Fire(X) Reactive() Sudden Release of Pressure()
•
Peak Wash-20
10
• SARA 313 Components—40 CFR 372.65
Section 313 Component(s) CAS Number %
Methanol 67-56-I 33
International Regulations
Inventory Status—DSL(CANADA)
The intentional ingredients of this product are listed.
WHMIS Information: B2,DIA
ECL(SOUTH KOREA)
The intentional ingredients of this product are listed.
EINECS(EUROPE)
The intentional ingredients of this product are listed.
ENCS(JAPAN)
The intentional ingredients of this product are listed.
State and Local Regulations—California Proposition 65
None
New Jersey RTK (Right-to-Know)Label Information
Methyl Alcohol 67-56-I
• Pennsylvania RTK (Right-to-Know)Label Information
Methanol 67-56-1
Atmospheric Standards: The Clean Air Act Amendments of 1990 list methanol as a hazardous air pollutant.
16. OTHER INFORMATION
Contact:Tom Cholke Phone: (847)559-2225
Old World Industries,Inc. makes no warranty,representation or guarantee as to the accuracy,sufficiency or
completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity
and suitability of his own use,handling and disposal of this product. Since actual use by others is beyond our
control, no warranty, expressed or implied, is made by Old World Industries, Inc. as to the effects of such
use,the results to be obtained or the safety and toxicity of this product, nor does Old World Industries, Inc.
assume liability arising out of the use by others of this product referred to herein. The data in this MSDS
relates only to the specific material designated herein and does not relate to use in combination with any
other material or in any process.
•
Peak Wash—20
11
Shell Rotella T 15W-40 ICJ-4)
MSDS#71630E
• Version 17.1
Effective Date 06/22/2009
Material Safety Data Sheet According to OSHA Hazard Communication Standar 910.9 CFR
1200
1. MATERIAL AND COMPANY IDENTIFICATION
Material Name : Shell Rotella T 15W-40(CJ-4)
Uses : Engine oil.
Manufacturer/Supplier : SOPUS Products
PO BOX 4427
Houston,TX 77210-4427
USA
MSDS Request : 877-276-7285
Emergency Telephone Number
Spill Information : 877-242-7400
Health Information : 877-504-9351
2. COMPOSITION/INFORMATION ON INGREDIENTS
Highly refined mineral oils and additives.
The highly refined mineral oil contains<3% (w/w) DMSO-extract, according to IP346.
• 3. HAZARDS IDENTIFICATION
Emergency Overview
Appearance and Odour : Amber. Liquid at room temperature. Slight hydrocarbon.
Health Hazards : Not classified as dangerous for supply or conveyance.
Safety Hazards : Not classified as flammable but will bum.
Environmental Hazards : Not classified as dangerous for the environment.
Health Hazards : Not expected to be a health hazard when used under normal
conditions.
Health Hazards
Inhalation : Under normal conditions of use, this is not expected to be a
primary route of exposure.
Skin Contact : Prolonged or repeated skin contact without proper cleaning can
clog the pores of the skin resulting in disorders such as oil
acne/folliculitis.
Eye Contact : May cause slight irritation to eyes.
Ingestion : Low toxicity if swallowed.
Other Information : Used oil may contain harmful impurities.
Signs and Symptoms : Oil acne/folliculitis signs and symptoms may include formation
of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Aggravated Medical : Pre-existing medical conditions of the following organ(s)or
Condition organ system(s)may be aggravated by exposure to this
material: Skin.
Environmental Hazards : Not classified as dangerous for the environment.
Additional Information : Under normal conditions of use or in a foreseeable emergency,
• 1/7
Print Date 07/28/2009 MSDS US
Shell Rotella T 15W-40(CJ-4)
MSDSR 71630E
• Version 17.1
Effective Date 06/22/2009
According to OSHA Hazard Communication Standard,1 29 910.1200
2
Material Safety Data Sheet
this product does not meet the definition of a hazardous
chemical when evaluated according to the OSHA Hazard
Communication Standard,29 CFR 1910.1200.
4. FIRST AID MEASURES
General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs,obtain medical attention.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically.
5. FIRE FIGHTING MEASURES
Clear fire area of all non-emergency personnel.
• Flash point : Typical 400°C/752°F (COC)
Upper/lower : Typical 1 - 10%(V)(based on mineral oil)
Flammability or
Explosion limits
Auto ignition temperature : > 320°C/608°F
Specific Hazards : Hazardous combustion products may include:A complex
mixture of airborne solid and liquid particulates and gases
(smoke). Carbon monoxide. Unidentified organic and inorganic
compounds.
Suitable Extinguishing : Foam,water spray or fog. Dry chemical powder,carbon
Media dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
Protective Equipment for : Proper protective equipment including breathing apparatus
Firefighters must be worn when approaching a fire in a confined space.
6. ACCIDENTAL RELEASE MEASURES
Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe all relevant local and international regulations.
Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains,ditches or rivers by using sand,earth,or
other appropriate bamers.
Clean Up Methods : Slippery when spilt. Avoid accidents,dean up immediately.
Prevent from spreading by making a barrier with sand, earth or
other containment material. Reclaim liquid directly or in an
• 2/7
Print Date 07/28/2009 MSDS_US
Shell Rotella T 15W-40(CJ-0)
MSDS#71630E
• Version 17.1
Effective Date 06/22/2009
According to OSHA Hazard Communication Standa 9'29 FR
Material Safety Data Sheet
absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.
7. HANDLING AND STORAGE
General Precautions : Use local exhaust ventilation if there is risk of inhalation of
vapours, mists or aerosols. Properly dispose of any
contaminated rags or cleaning materials in order to prevent
fires. Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.
Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling
vapour and/or mists. When handling product in drums, safety
footwear should be worn and proper handling equipment
should be used.
Storage : Keep container tightly closed and in a cool,well-ventilated
place. Use properly labelled and closeable containers. Storage
Temperature: 0-50°C/32- 122°F
Recommended Materials : For containers or container linings, use mild steel or high
density polyethylene.
• Unsuitable Materials : PVC.
Additional Information : Polyethylene containers should not be exposed to high
temperatures because of possible risk of distortion.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Material Source Type ppm mg/m3 Notation
Oil mist, ACGIH TWA(Mist.) 5 mg/m3
mineral
Oil mist, ACGIH STEL(Mist.) 10 mg/m3
mineral
Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions.Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations.Where material is heated,sprayed or
mist formed,there is greater potential for airborne
concentrations to be generated.
Personal Protective : Personal protective equipment(PPE)should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
• Sr
Print Date 07/28/2009 MSDS_US
Shell Rotella T 15W-40(CJ-4)
MSDS#71630E
• Version 17.1
Effective Date 06/22/2009
According to OSHA Hazard Communication Standard,
91 0
Material Safety Data Sheet 10
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers.Where
air-filtering respirators are suitable,select an appropriate
combination of mask and fitter. Select a filter suitable for
combined particulate/organic gases and vapours[boiling point
>65°C(149°F)].
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards(e.g. Europe: EN374,
US: F739)made from the following materials may provide
suitable chemical protection: PVC, neoprene or nitrile rubber
gloves. Suitability and durability of a glove is dependent on
usage,e.g.frequency and duration of contact,chemical
resistance of glove material, glove thickness,dexterity.Always
seek advice from glove suppliers. Contaminated gloves should
be replaced. Personal hygiene is a key element of effective
hand care. Gloves must only be worn on dean hands.After
using gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturizer is recommended.
Eye Protection : Wear safety glasses or full face shield if splashes are likely to
• occur.
:Protective Clothing Skin protection not ordinarily required beyond standard issue
work clothes.
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate.
Environmental Exposure : Minimise release to the environment.An environmental
Controls assessment must be made to ensure compliance with local
environmental legislation.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Amber. Liquid at room temperature.
Odour : Slight hydrocarbon.
pH : Not applicable.
Initial Boiling Point and : >280°C/536 °F estimated value(s)
Boiling Range
Pour point : Typical-20°C 1-4 "F
Flash point : Typical 400°C/752°F(COC)
Upper/lower Flammability : Typical 1 - 10%(V)(based on mineral oil)
or Explosion limits
Auto-ignition temperature > 320°C/608°F
Vapour pressure : <0.5 Pa at 20°C/68°F(estimated value(s))
Specific gravity : Typical 0.85
Water solubility : Negligible.
n-octanol/water partition : >6(based on information on similar products)
coefficient(log Pow)
• 4/7
Print Date 07/28/2009 MSDS_US
Shell Retells T 15W-40(CJ-4)
MSDS#71630E
Version 17.1
Effective Date 06/22/2009
• Material Safety Data Sheet According to OSHA Hazard Communication Standard,29
FR
1910. 0
Kinematic viscosity : Typical 118 mm2/s at 40°C/104°F
Vapour density(air=1) : > 1 (estimated value(s))
Evaporation rate(nBuAc=1) : Data not available
10. STABILITY AND REACTIVITY
Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous Decomposition : Hazardous decomposition products are not expected to form
Products during normal storage.
11. TOXICOLOGICAL INFORMATION
Basis for Assessment Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50> 5000 mg/kg
Acute Dermal Toxicity : Expected to be of low toxicity: LD50>5000 mg/kg
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
• Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Product contains mineral oils of types shown to be non-
carcinogenic in animal skin-painting studies. Highly refined
mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer(IARC). Other
components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use.The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal.ALL used oil should be handled
with caution and skin contact avoided as far as possible.
Continuous contact with used engine oils has caused skin
cancer in animal tests.
12. ECOLOGICAL INFORMATION
Ecotoxicological data have not been determined specifically for this product. Information given is
based on a knowledge of the components and the ecotoxicology of similar products.
Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LUEUIL50>
• 5/7
Print Date 07/28/2009 MSDS_US
Shell Rotella T 15W-40(CJ-4)
MSDS#71630E
• Version 17.1
Effective Date 06/22/2009
Material Safety Data Sheet According to OSHA Hazard Communication Standard,29 CFR
tstal2oo
100 mg/I(to aquatic organisms) (LUEL50 expressed as the
nominal amount of product required to prepare aqueous test
extract). Mineral oil is not expected to cause any chronic
effects to aquatic organisms at concentrations less than 1 mg/I.
Mobility . Liquid under most environmental conditions. Floats on water. If
it enters soil, it will adsorb to soil particles and will not be
mobile.
Persistence/degradability : Expected to be not readily biodegradable. Major constituents
are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
Bioaccumulation : Contains components with the potential to bioaccumulate.
Other Adverse Effects : Product is a mixture of non-volatile components,which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential,photochemical
ozone creation potential or global warming potential.
13. DISPOSAL CONSIDERATIONS
Material Disposal . Recover or recycle if possible. It is the responsibility of the
waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
• applicable regulations. Do not dispose into the environment, in
drains or in water courses.
Container Disposal : Dispose in accordance with prevailing regulations, preferably
to a recognised collector or contractor.The competence of the
collector or contractor should be established beforehand.
Local Legislation : Disposal should be in accordance with applicable regional,
national,and local laws and regulations.
14. TRANSPORT INFORMATION
US Department of Transportation Classification(49CFR)
This material is not subject to DOT regulations under 49 CFR Parts 171-180.
IMDG
This material is not classified as dangerous under IMDG regulations.
IATA(Country variations may apply)
This material is not classified as dangerous under IATA regulations.
15. REGULATORY INFORMATION
The regulatory information is not intended to be comprehensive.Other regulations may apply to this
material.
Federal Regulatory Status
Notification Status
• 6/7
Print Date 07/28/2009 MSDS_US
Shell Rotella T 15W-40(CJ-4)
MSDS#71630E
• Version 17.1
Effective Date 06/22/2009
Material Safety Data Sheet According to OSHA Hazard Communication Standard,29 CFR
1910.1200
EINECS All components listed or
polymer exempt.
DSL All components listed.
TSCA All components listed.
SARA Hazard Categories(311/312)
No SARA 311/312 Hazards.
State Regulatory Status
California Safe Drinking Water and Toxic Enforcement Act(Proposition 65)
This material does not contain any chemicals known to the State of California to cause cancer,birth
defects or other reproductive harm.
• 16. OTHER INFORMATION
NFPA Rating(Health, : 0, 1, 0
Fire, Reactivity)
MSDS Version Number : 17.1
MSDS Effective Date : 06/22/2009
MSDS Revisions : A vertical bar(I)in the left margin indicates an amendment
from the previous version.
MSDS Regulation : The content and format of this MSDS is in accordance with the
OSHA Hazard Communication Standard,29 CFR 1910.1200.
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : The information contained herein is based on our current
knowledge of the underlying data and is intended to describe
the product for the purpose of health,safety and environmental
requirements only. No warranty or guarantee is expressed or
implied regarding the accuracy of these data or the results to
be obtained from the use of the product.
• 7/7
Print Date 07/28/2009 MSDS US
rags i ui J
DRACKETT PRODUCTS CO -- WINDEX GLASS CLEANER BLUE - RETAIL -- 7930-00F040924
• ------ Product Identification --_- --
Product ID:WINDEX GLASS CLEANER BLUE - RETAIL
MSDS Date:04/22/1992
FSC:7930
NIIN:00F040924
MSDS Number: BXMRC
__= Responsible Party =—
Company Name:DRACKETT PRODUCTS CO
Address:8600 GOVERNORS HILL RD STE 300
City:CINCINNATI
State:OH
ZIP:45249-5000
Country:US
Info Phone Num:513-583-3900/800-242-1677
Emergency Phone Num:513-583-3900/800-242-1677
CAGE:DRACK
__= Contractor Identification =—
Company Name:DRACKETT CO
Address:5020 SPRING GROVE AVE
Box:City:CINCINNATI
State:OH
ZIP:45232-1926
Country:US
Phone:513-632-7409
CAGE:85234
Company Name:DRACKETT PRODUCTS CO
• Address:5020 SPRING GROVE AVE
City:CINCINNATI
State:OH
ZIP: 45232-1988
Country:US
Phone:513-632-1500
CAGE:DRACK
Composition/Information on Ingredients -- _.----
Ingred Name: ISOPROPANOL (ISOPROPYL ALCOHOL) , 2-PROPANOL, DIMETHYL
CARBINOL
CAS: 67-63-0
RTECS #:NT8050000
Fraction by Wt: <3%
Other REC Limits:400 PPM
OSHA PEL:400 PPM
ACGIH TLV:400 PPM
Ingred Name:2-BUTOXYETHANOL (ETHYLENE GLYCOL MONOBUTYL ETHER) , BUTYL
CELLOSOLVE, BUTYL GLYCOL, GLYCOL ETHER EB
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: <2%
Other REC Limits:25 PPM (SKIN)
OSHA PEL:50 PPM (SKIN)
ACGIH TLV:25 PPM (SKIN)
• --------- Hazards identification --- - -
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Routes of Entry: Inhalation:NO Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION.
• Explanation of Carcinogenicity:NONE
Effects of Overexposure:SENSATION OF IRRITATION.
First Aid Measures
First Aid:EYES/SKIN: FLUSH W/WATER. INGESTION: DRINK MILK/WATER FREELY.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
Fire Fighting Measures ------
Flash Point Method:SCC
Flash Point: 129F
Extinguishing Media:USE WATER, DRY ALCOHOL-TYPE/ALL PURPOSE FOAM, DRY
CHEMICAL, CO2/OTHER CLASS B EXTINGUISHING AGENTS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT INCLUDING
PRESSURE DEMAND SELF CONTAINED BREATHING APPARATUS & TURNOUT
EQUIPMENT.
Unusual Fire/Explosion Hazard:COMBUSTIBLE. KEEP AWAY FROM HEAT &
FLAMES.
------ Accidental Release Measures
Spill Release Procedures:FLUSH AREA W/WATER. KEEP OUT OF WATERSHEDS &
WATER SYSTEMS.
Handling and Storage
• Handling and Storage Precautions:UNPLUG ELECTRICAL APPLIANCES BEFORE
USING PRODUCT ON THEM.
Exposure Controls/Personal Protection
Supplemental Safety and Health
Physical/Chemical Properties - --- _
Boiling Pt:B.P. Text:212F
Vapor Pres: 17.6
Vapor Density:1.2
Spec Gravity:0.99
pH: ll
Evaporation Rate & Reference: (BU AC =1) : 0.3
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR BLUE LIQUID W/SLIGHT AMMONIA ODOR.
--" Stability and Reactivity Data
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT, FLAMES.
Disposal Considerations - - - - - -._-._ -"""-
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
• Disclaimer (provided with this information by the compiling agencies) :
This information is formulated for use by elements of the Department
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5
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
• disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
•
•
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• CATO OIL AND GREASE CO INC -- MYSTIK JT-6 MULTI-PURPOSE DI-TEMP GREASE -- 9150-
01-112-8209
• Product Identification
Product ID:MYSTIK JT-6 MULTI-PURPOSE Di-TEMP GREASE
MSDS Date:01/02/1991
FSC: 9150
NIIN:01-112-8209
MSDS Number: BSSKR
__= Responsible Party =__
Company Name:CATO OIL AND GREASE CO INC
Address:915 MARTIN LUTHER KING
Box:26868
City:OKLAHOMA CITY
State:OK
ZIP:73126
Country:US
Info Phone Num:405-270-6200
Emergency Phone Num:800-424-9300
CAGE:3F020
__= Contractor Identification =__
Company Name:CATO OIL AND GREASE CO INC
Address: 915 MARTIN LUTHER KING
Box:26868
City:OKLAHOMA CITY
State:OK
ZIP:73126
Country:US
• Phone:405-424-3311
CAGE:3F020
Composition/Information on Ingredients
Ingred Name:HYDROTREATED HEAVY NAPHTHENIC DISTILLATE,
PETROLEUM/LUBRICATING OIL BASE STOCK
CAS: 64742-52-5
RTECS #:PY8035000
Fraction by Wt: 50-75%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3 OIL MIST
ACGIH TLV:5 MG/M3 OIL MIST
Ingred Name:LITHIUM 12 HYDROXYSTEARATE
CAS:7620-77-1
Fraction by Wt: 5-20%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SOLVENT,DEWAXED RESIDUAL OIL (PETROLEUM)
CAS: 64742-62-7
Fraction by Wt: 5-20%
Other REC Limits:NONE RECOMMENDED
Ingred Name:PROPRIETARY ADDITIVE: 5189
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
• Ingred Name:PROPRIETARY ADDITIVE: 5192
Fraction by Wt: 1-5%
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t Other REC Limits:NONE RECOMMENDED
Ingred Name:PROPRIETARY ADDITIVE: 5397
• Fraction by Wt: 5-20%
Other REC Limits:NONE RECOMMENDED
Ingred Name:PROPRIETARY ADDITIVE: 5168
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:LITHIUM AZELATE SOAP
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Hazards Identification
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION- BREATHING PETROLEUM OIL
MIST CAN CAUSE RESPIRATORY IRRITATION OR DISCOMFORT. SKIN- CAUSES
IRRITATION. IF INJECTED UNDER SKIN, NECROSIS COULD RESULT. EYES-
CAUSES IRRITATION. COULD CAUSE PROLONGED VISION IMPAIRMENT.
INGESTION- MAY CAUSE IRRITATION. POSSIBLE ASPIRATION HAZARD.
Effects of Overexposure:INGESTION- MAY CAUSE NAUSEA OR DIARRHEA.
Medical Cond Aggravated by Exposure:NONE
First Aid Measures --— -------"
First Aid:INHALATION- MOVE PERSON TO FRESH AIR. IF BREATHING HAS
STOPPED, GIVE ARTIFICIAL RESPIRATION AND GET MEDICAL ATTENTION.
• SKIN- WASH EXPOSED PROTION WITH SOAP AND WATER. LAUNDER SOILED
CLOTHES BEFORE REU SE. IF INJECTED UNDER THE SKIN, GET MEDICAL
ATTENTION IMMEDIATELY. EYES- IMMEDIATELY FLUSH WITH WATER FOR A
MINIMUM OF 15 MINUTES, OCCASIONALLY LIFTING THE LIDS. INGESTION- DO
NOT INDUCE VOMITING.
Fire Fighting Measures
Flash Point:CLASS 1
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:WATER STREAM MAY SPREAD FIRE, USE WATER SPRAY
ONLY TO COOL CONTAINERS NOT ON FIRE.
Unusual Fire/Explosion Hazard:WILL NOT FLASH SPONTANEOUSLY. MAY IGNITE
IF EXPOSED TO OPEN FLAME.
Accidental Release Measures ----- ---- ---
Spill Release Procedures:PICK UP AND PLACE IN CONTAINER FOR DISPOSAL.
Handling and Storage -- --—- ---- "- ---" --
Handling and Storage Precautions:STORE CLEAN, DRY, BELOW 120F TO
PRESERVE FOR INTENDED USE. DO NOT STORE WITH STRONG OXIDIZERS.
Other Precautions:AVOID BREATHING OIL MISTS OR OTHER VAPORS. AVOID
CONTACT WITH SKIN AND EYES. USE WITH ADEQUATE VENTILATION.
Exposure Controls/Personal Protection
• Respiratory Protection:UP TO 25 MG/M3, HALF-MASK ORGANIC VAPOR
RESPIRATOR. UP TO 50 MG/M3, FULL-FACE ORGANIC VAPOR RESPIRATOR OR
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FULL-FACE SELF-CONTAINED BREATHING RESPIRATOR. GREATER THAN 50
MG/M3, USE SELF-CONTAINED BREAT HING APPARATUS WITH POSSITIVE
PRESSURE.
• Ventilation:MAINTAIN LOCAL OR DILUTION VENTILATION TO KEEP AIR
CONCENTRATION BELOW PEL/TLV. REQUEST ASSISTANCE TO DETERMINE CONC.
Protective Gloves:USE NITRILE OR NEOPRENE GLOVES.
Eye Protection:SAFETY GLASSES, CHEMICAL GOGGLES.
Other Protective Equipment:NONE NORMALLY REQUIRED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE
Physical/Chemical Properties
HCC:V6
Vapor Density:> AIR
Spec Gravity:0. 94
Evaporation Rate & Reference:<l (N-BUTYL ACETATE=1)
Appearance and Odor:RED GREASE.
-- Stability and Reactivity Data
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:AVOID CONDITIONS THAT WOULD GENERATE AN
OIL MIST. DO NOT EXPOSE THE PRODUCT TO STRONG OXIDIZERS OR
EXCESSIVE HEAT.
Hazardous Decomposition Products:CARBON (SMOKE) , CARBON MONOXIDE,
VARIOUS HYDROCARBONS AND OXIDE OF ZINC. OTHER TOXIC GASES MAY
EVOLVE ON BURNING.
• - Disposal Considerations __ _--
Waste Disposal Methods:UTILIZE LICENSED WASTE DISPOSAL COMPANY.
CONSIDER RECYCLING OR CONTROLLED INCINERATION. UTILIZE PERMITTED
INDUSTRIAL WASTE DISPOSAL SITE. FOLLOW ALL LOCAL, STATE AND FEDERAL
GUIDELINES.
Disclaimer (provided with this information by the compiling agencies) :
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
•
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CATO OIL AND GREASE CO -- 6484B-001 MYSTIK JT-6 MULTI-PURPOSE GREASE
MSDS Safety Information
• FSC: 9150
NIIN: 01-112-8209
MSDS Date: 01/03/1996
MSDS Num: BZXTK
Product ID: 6484B-001 MYSTIK JT-6 MULTI-PURPOSE GREASE
MFN: 03
Responsible Party
Cage: 3F020
Name: CATO OIL AND GREASE CO
Address: 915 MARTIN LUTHER KING BLVD
Box: 26868
City: OKLAHOMA CITY OK 73126-5000
Info Phone Number: 405-270-6200
Emergency Phone Number: 405-270-6200
Proprietary Ind: Y
Review Ind: Y
Published: Y
Preparer Co. when other than Responsible Party Co.
Cage: 3F020
Name: CATO OIL AND GREASE CO INC
Address: 915 MARTIN LUTHER KING
Box: 26868
City: OKLAHOMA CITY OK 73126
• Contractor Summary
Cage: 3F020
Name: CATO OIL AND GREASE CO INC
Address: 915 MARTIN LUTHER KING
Box: 26868
City: OKLAHOMA CITY OK 73126
Phone: 405-424-3311
Item Description Information
Item Name: GREASE,AUTOMOTIVE
Type of Container: CARTRIDGE
Ingredients
- - —
Name: *** PROPRIETARY ***
Health Hazards Data
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
• Effects of Exposure: INHALATION: CAN CAUSE RESPIRATORY IRRITATION & MAY BE
HARMFUL. SKIN/EYES: IRRITATION, MAY CAUSE CANCER. INGESTION: MAY CAUSE
IRRITATION & POSSIBLE ASPIRATION HAZARD.
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•
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: IRRITATION, DISCOMFORT, NAUSEA, DIARRHEA.
Medical Cond Aggravated By Exposure: PRE-EXISTING SKIN DISORDERS.
• First Aid: INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. SKIN: WASH
W/SOAP & WATER. EYES: FLUSH W/WATER FOR A MINIMUM OF 15 MINS. INGESTION:
DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.
Handling and Disposal
Spill Release Procedures: PICKUP & PLACE IN CONTAINER FOR DISPOSAL.
Waste Disposal Methods: DISPOSE/RECYCLE/INCINERATE IAW/FEDERAL, STATE &
LOCAL REGULATIONS. UTILIZE LICENSED/PERMITTED INDUSTRIAL WASTE DISPOSAL SITE.
Handling And Storage Precautions: STORE CLEAN, DRY, BELOW 120E FOR INTENDED
USE. DON'T STORE W/STRONG OXIDIZERS. USE W/ADEQUATE VENTILATION. EMPTY
CONTAINERS RETAIN RESIDUE.
Other Precautions: KEEP AWAY FROM CHILDREN. AVOID BREATHING OIL MISTS/OTHER
VAPORS. AVOID CONTACT W/SKIN & EYES. DON'T
PRESSURIZE/CUT/WELD/BRAZE/SOLDER/DRILL/GRIND/EXPOSE CONTAINER TO SOURCES OF
IGNITION. DON'T ATTEMPT TO CLEAN. (SEE SUPP)
Fire and Explosion Hazard Information
Extinguishing Media: CO2, DRY CHEMICAL/FOAM.
Fire Fighting Procedures: WATER STREAM MAY SPREAD FIRE. USE WATER SPRAY ONLY TO
COOL CONTAINERS NOT ON FIRE.
Unusual Fire/Explosion Hazard: WILL NOT FLASH SPONTANEOUSLY. MAY IGNITE IF
EXPOSED TO OPEN FLAME. BURNING OF ORGANIC ANTIMONY COMPONENT MAY PRODUCE
OXIDES OF ANTIMONY, SULFUR & NITROGEN.
Control Measures
IIIRespiratory Protection: UP TO 25 PPM, USE HALF MASK ORGANIC VAPOR RESPIRATOR/UP
TO 50 PPM, USE FULL FACE ORGANIC VAPOR RESPIRATOR/FULL FACE SELF CONTAINED
RESPIRATOR/>50 PPM, USE SCBA W/POSITIVE PRESSURE.
Ventilation: MAINTAIN LOCAL/DILUTION TO KEEP AIR CONCENTRATION BELOW PEL/TLV.
Protective Gloves: NITRILE/NEOPRENE
Eye Protection: SAFETY GLASSES/CHEMICAL GOGGLES
Other Protective Equipment: FACESHIELD.
Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health: EMPTY DRUMS SHOULD BE COMPLETELY DRAINED,
PROPERLY BUNGED & PROMPTLY RETURNED TO A DRUM RECONDITIONER.
•
Physical/Chemical Properties
Vapor Density: >1
Spec Gravity: 0.89
Evaporation Rate & Reference: SLOWER THAN N-BU AC
Appearance and Odor: AMBER GREASE
Reactivity Data
Stability Indicator: YES
Stability Condition To Avoid: EXCESSIVE HEAT
Materials To Avoid: STRONG OXIDIZERS
Hazardous Decomposition Products: INCOMPLETE COMBUSTION: CARBON (SMOKE) , CO,
VARIOUS HYDROCARBONS & OXIDES OF ANTIMONY.
Hazardous Polymerization Indicator: NO
•
Toxicological Information
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Page 3 of 4
Ecological Information
MSDS Transport Information
Regulatory Information
Other Information
Transportation Information
Responsible Party Cage: 3F020
Trans ID NO: 108265
Product ID: 6484B-001 MYSTIK JT-6 MULTI-PURPOSE GREASE
MSDS Prepared Date: 01/03/1996
Review Date: 10/16/1996
MFN: 3
Net Unit Weight: 0.75 LBS
Multiple KIT Number: 0
Review IND: Y
Type Of Container: CARTRIDGE
Additional Data: NONE
Detail DOT Information
DOT PSN Code: ZZZ
• DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
Detail IMO information
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
Detail IATA Information
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
Detail AFI Information
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
HAZCOM Label
Product ID: 6484B-001 MYSTIK JT-6 MULTI-PURPOSE GREASE
Cage: 3F020
Company Name: CATO OIL AND GREASE CO INC
Street: 915 MARTIN LUTHER KING
PO Box: 26868
City: OKLAHOMA CITY OK
Zipcode: 73126
Health Emergency Phone: 405-270-6200
. Label Required IND: Y
Date Of Label Review: 12/16/1998
Status Code: C
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Page 4 of 4
•
Label Date: 12/16/1998
Origination Code: G
• Hazard And Precautions: INHALATION: CAN CAUSE RESPIRATORY IRRITATION & MAY
BE HARMFUL. SKIN/EYES: IRRITATION, MAY CAUSE CANCER. INGESTION: MAY CAUSE
IRRITATION & POSSIBLE ASPIRATION HAZARD.
IRRITATION, DISCOMFORT,
NAUSEA, DIARRHEA.
Disclaimer (provided with this information by the compiling agencies) : This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
•
•
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CATO OIL & GREASE CO. -- MYSTIK JT-8 SUPER HEAVY DUTY MOTOR OILS -- 9150-
00F0 12447
• - Product Identification
Product ID:MYSTIK JT-8 SUPER HEAVY DUTY MOTOR OILS
MSDS Date:07/21/1988
FSC:9150
NIIN: 001012447
MSDS Number: BJCNG
= Responsible Party =__
Company Name:CATO OIL & GREASE CO.
Box:26868
City:OKLAHOMA CITY
State:OK
ZIP:73126
Info Phone Num: (405) 424-3311
Emergency Phone Num: (405) 424-3311
Preparer's Name:EDWARD W. GORDON
CAGE:E0800
__= Contractor Identification ===
Company Name:CATO OIL & GREASE/OKLAHOMA CITY, OK 73126
Box:26868
CAGE:E0800
Company Name:CATO OIL AND GREASE CO INC
Address: 915 MARTIN LUTHER KING
Box:26868
City:OKLAHOMA CITY
State:OK
• ZIP:73126
Coutr Country:US
Phone:405-424-3311
CAGE:3F020
Company Name:KERR-MCGEE REFINING CORP KERR-MCGEE CENTER
Box:24046
City:OKLAHOMA CITY
State:OK
ZIP:73124
Country:US
Phone:B00-424-9300/713-831-4700 (HOUSTON)
CAGE:5H561
-------- Composition/Information on Ingredients
Ingred Name:ZINC (SARA III)
CAS:7440-66-6
RTECS #:ZG8600000
Fraction by Wt: 0.14%
OSHA PEL: 10 MG ZNO/M3
ACGIH TLV:10 MG ZNO/M3; 9192
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:PETROLEUM DISTILLATE, PETROLEUM OIL, AROMATIC PETROLEUM
SOLVENT
CAS: 8002-05-9
• RTECS #:5E7175000
Fraction by Wt: 74-88%
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Ingred Name:ADDITIVES
Fraction by Wt: 12-26%
• Hazards Identification
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION. INGESTION: HARMFUL,
IRRITATION, NAUSEA, DIARRHEA, & POSSIBLE ASPIRATION. INHALATION:
RESPIRATORY IRRITATION & DISCOMFORT. SKIN: MINOR IRRITATION.
Explanation of Carcinogenicity:USED MOTOR OIL HAS CAUSED SKIN CANCER IN
ANIMAL TESTS.
Effects of Overexposure:EYES: IRRITATION. INGESTION: HARMFUL,
IRRITATION, NAUSEA, DIARRHEA, & POSSIBLE ASPIRATION. INHALATION:
RESPIRATORY IRRITATION & DISCOMFORT. SKIN: MINOR IRRITATION.
--- -- First Aid Measures
First Ai.d: INHALATION: MOVE PERSON TO FRESH AIR. GIVE ARTIFICIAL
RESPIRATION. GET MED ATT. SKIN: WASH W/SOAP & WATER. LAUNDER SOILED
CLOTHES BEFORE REUSE. EYES: FLUSH W/WATER FOR 15 MIN. SEEK MED ATT.
INGESTION: DON'T INDUCE VOMITING. CONTACT PHYSICIAN.
-- Fire Fighting Measures
Flash Point Method:COC
Flash Point:400F
Extinguishing Media:CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:WATER STREAM MAY SPREAD FIRE. USE WATER SPRAY
ONLY TO COOL CONTAINERS NOT ON FIRE.
• Unusual Fire/Explosion Hazard:WILL FORM FLAMMABLE MIXTURES W/AIR WHEN
HEATED TO APPROXIMATELY 400F. WILL NOT FLASH SPONTANEOUSLY.
Accidental Release Measures
Spill Release Procedures:NOTIFY EMERGENCY RESPONSE PERSONNEL. EVACUATE
AREA. REMOVE IGNITION SOURCES. BUILD DIKE TO CONTAIN FLOW. REMOVE
FREE LIQUID. DON'T FLUSH TO SEWER & OPEN WATER. PICK UP RESIDUE
W/INERT-ABSORBANT & PLAC E IN CLOSED CONTAINER FOR DISPOSAL.
Handling and Storage
Handling and Storage Precautions:AVOID CONTACT W/USE OILS. STORE CLEAN,
DRY <120F, 50C TO PRESERVE FOR INTENDED USE. DON'T STORE W/STRONG
OXIDIZERS.
Other Precautions:STORE AS OSHA CLASS IIIB COMBUSTIBLE LIQUID.
Exposure Controls/Personal Protection
Respiratory Protection:USE W/ADEQUATE VENTILATION. USE HALF-MASK/FULL
FACE SELF-CONTAINED RESPIRATOR.
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO KEEP > 5 MG/CUM.
Protective Gloves:NITRILE, NEOPRENE
Eye Protection:SAFETY GLASSES, GOGGLES, FACE SHIELD
Work Hygienic Practices:REQUEST ASSISTANCE OF SAFETY/INDUSTRIAL HYGIENE
PERSONNEL.
Supplemental Safety and Health
• Physical/Chemical Properties - --- ---�
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• Boiling Pt:B.P. Text:>600F
Vapor Pres:<0. 1
Spec Gravity:0.87-0. 90
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AMBER LIQUID, MILD PETROLEUM
Stability and Reactivity Data
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:IGNITION SOURCES
Hazardous Decomposition Products:CO, HYDROCARBONS, SMOKE, CO2
Disposal Considerations
Waste Disposal Methods:UTILIZE LICENSED WASTE DISPOSAL COMPANY.
CONSIDER RECYCLING & CONTROLLED INCINERATION. UTILIZE PERMITTED
INDUSTRIAL WASTE DISPOSAL SITE. FOLLOW ALL LOCAL, STATE & FEDERAL
GUIDELINES.
Disclaimer (provided with this information by the compiling agencies) :
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
S
•
http://hazard.com/msds/f2/bjc/bjcng.html 9/14/2009
Hello